一种高熵混合金属氧化物及其制备方法和应用

The preparation of high-entropy mixed metal oxides via a one-step calcination pyrolysis method using Prussian blue analogue precursors solves the problems of insufficient catalyst activity and complex preparation in existing technologies, and achieves highly efficient catalytic degradation of organic pollutants by persulfate.

CN122399779APending Publication Date: 2026-07-17YANCHENG INST OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
YANCHENG INST OF TECH
Filing Date
2026-04-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing advanced oxidation technologies, single metal oxide catalysts have limited active sites, slow reaction kinetics, easy dissolution of metal ions leading to secondary pollution and insufficient cycle stability. High-entropy oxides have complicated synthesis processes, component segregation and limited specific surface area, making it difficult to meet the broad-spectrum adaptability requirements of complex component pollutants.

Method used

Using Prussian blue analogues as precursors, high-entropy mixed metal oxides are prepared by one-step calcination and pyrolysis, achieving uniform mixing of multiple metal ions, simplifying the preparation process and improving catalytic activity.

Benefits of technology

The prepared high-entropy mixed metal oxides exhibit far superior catalytic activity compared to traditional single-metal or simple bimetallic oxides when catalyzing the degradation of organic pollutants by persulfate, and the process is simple and easy to scale up.

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Abstract

本发明属于环境功能材料及水污染控制技术领域,具体涉及一种高熵混合金属氧化物及其制备方法和应用。制备方法包括:将过渡金属盐和络合剂混合溶解,加入铁盐,静置陈化,得到混合金属普鲁士蓝类似物前驱体;将混合金属普鲁士蓝类似物前驱体煅烧热处理,即得所述高熵混合金属氧化物;所述过渡金属盐包括Co盐、Ni盐、Mn盐和Zn盐中的任意一种或几种。本发明通过利用前驱体实现金属均匀混合,形成高熵固溶体相,该材料催化过硫酸盐降解有机污染物,30分钟内可实现双酚A完全降解,催化效率达100%,Co含量降低75%,工艺简便可控。
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