木质素热解油加氢脱氧催化剂和制备方法、加氢脱氧方法

By optimizing the composition and preparation method of the lignin pyrolysis oil hydrodeoxygenation catalyst, MOx-transition metal interface sites were formed, solving the problems of low conversion rate and aromatic selectivity in the existing technology. This achieved efficient conversion of phenolic compounds and aromatic selectivity, thus improving the quality of bio-jet fuel.

CN122399802APending Publication Date: 2026-07-17中国航空油料有限责任公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
中国航空油料有限责任公司
Filing Date
2026-04-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, the conversion rate and aromatic selectivity of lignin pyrolysis oil during hydrodeoxygenation are low, resulting in insufficient aromatic content in biofuel, which affects the expansion performance of aircraft rubber seals and the risk of fuel leakage.

Method used

A catalyst with MOx and transition metals mounted on a support is used. By optimizing the catalyst composition and preparation process, MOx-transition metal interface sites are formed to improve the hydrogenation and deoxygenation effect of the catalyst. Specifically, the support is silica and/or activated carbon, the MOx is cerium, titanium or zirconium, and the transition metal is palladium, platinum or ruthenium. The catalyst is prepared through mixing and impregnation, drying, calcination and reduction steps.

Benefits of technology

High efficiency of phenolic compound conversion and aromatic hydrocarbon selectivity was achieved under mild conditions (250-400℃, 0.1-2MPa), with phenolic compound conversion reaching 76.1%, aromatic hydrocarbon selectivity exceeding 90%, and reaction rate exceeding 6.6, significantly improving the quality of bio-jet fuel.

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Abstract

本发明涉及一种木质素热解油加氢脱氧催化剂和制备方法、加氢脱氧方法,涉及合成技术领域,加氢脱氧催化剂包括:载体,设置于载体上的MOx和过渡金属,x∈(1,2);以所述加氢脱氧催化剂为基准且以质量百分含量计,MOx为0.3‑6%,过渡金属为0.8‑1.2%;M包括:铈、钛或锆中的一种或至少两种的组合;过渡金属包括:钯、铂或钌中的一种或至少两种的组合。本发明提供的加氢脱氧催化剂,通过对催化剂的组成配比进行优化,使得催化剂中含有部分还原的氧化M和过渡金属形成MOx‑过渡金属界面位点结构,提升了催化剂对酚类化合物的芳烃选择性和催化转化效果,从而实现生物航煤中芳烃组分的高效制备。
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