一种焦锑酸钠用五氧化二锑前驱体的制备方法

By oxidizing antimony ash with hydrogen peroxide in dilute nitric acid solution and combining it with ultrasonic treatment, followed by lead removal with concentrated sulfuric acid and spray pyrolysis, the problem of efficiently preparing high-quality antimony pentoxide precursor from antimony ash was solved, achieving efficient and low-cost utilization of antimony resources.

CN122403501APending Publication Date: 2026-07-17YIYANG SHENGLI MATERIAL TECHNOLOGY CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
YIYANG SHENGLI MATERIAL TECHNOLOGY CO LTD
Filing Date
2023-10-31
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are difficult to efficiently utilize antimony flue dust to directly prepare high-quality antimony pentoxide precursors for sodium pyroantimonate, and also suffer from high energy consumption and high cost.

Method used

Antimony ash is oxidized with hydrogen peroxide in dilute nitric acid solution, combined with ultrasonic-assisted treatment, followed by the addition of concentrated sulfuric acid to remove lead, and then arsenic pentoxide is prepared by spray pyrolysis, thus achieving efficient conversion of antimony and effective removal of impurities.

Benefits of technology

The preparation of antimony pentoxide precursor with high conversion rate was achieved, which reduced production costs, improved resource utilization, and enabled the recycling of dilute nitric acid solution.

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Abstract

本发明涉及有色冶金领域,提供了一种焦锑酸钠用五氧化二锑前驱体的制备方法,包括以下步骤:在超声波辅助下,向50‑80℃的稀硝酸溶液中加入锑烟灰和双氧水进行反应,经液固分离得到转化渣和转化液,所述转化渣经洗涤、烘干,得到五氧化二锑前驱体;将所述转化液的温度升高至50‑90℃后加入浓硫酸进行反应,经液固分离得到除铅渣和除铅后液;将所述除铅后液加入到喷雾热解设备中进行喷雾热解处理,得到五氧化二砷产品。本发明的实质是在稀硝酸溶液中用双氧水氧化转化实现溶解除杂和氧化转化的双重目的,从锑烟灰中直接制备出高品质焦锑酸钠用五氧化二锑前驱体。本发明具有产品质量好、氧化剂消耗少、过滤性能好和技术指标稳定等优点。
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