一种锰酸锂材料在页岩气废水选择性电化学提锂中的应用

By using aluminum-fluorine co-doped lithium manganese oxide materials, the selectivity and stability issues of lithium extraction from shale gas wastewater have been solved, achieving efficient and low-energy lithium recovery, and making it suitable for rapid lithium extraction in complex ionic matrices.

CN122403586APending Publication Date: 2026-07-17UNIV OF SCI & TECH OF CHINA
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
UNIV OF SCI & TECH OF CHINA
Filing Date
2026-06-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to efficiently and selectively extract lithium from shale gas wastewater with low energy consumption, and traditional methods suffer from insufficient stability and selectivity of lithium manganese oxide materials.

Method used

A spinel-type lithium manganese oxide material (LMO-Al-F) modified with aluminum fluorine co-doping was used as a lithium-ion sieve electrode. It was prepared by solid-state sintering and applied to a rocking-chair capacitor deionization system to achieve selective insertion and release of lithium ions.

Benefits of technology

It improves lithium selectivity and adsorption capacity, reduces energy consumption, and enhances the material's cycle stability and lithium selectivity, making it suitable for rapid and efficient lithium extraction in complex ionic matrices.

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Abstract

本发明涉及一种锰酸锂材料在页岩气废水选择性电化学提锂中的应用。本发明具体应用:铝氟共掺杂锰酸锂材料为铝和氟共同改性的尖晶石型锰酸锂,其中,铝取代部分锰位点以提高锰平均价态并强化体相尖晶石结构,氟取代部分氧位点或富集于材料表面以形成含氟钝化层;所述铝氟共掺杂锰酸锂材料作为锂离子筛电极的活性材料,在电化学提锂体系中实现对锂离子的选择性嵌入和释放。本发明通过固相烧结法成功制备铝氟共掺杂LMO颗粒,并将其作为RCDI电极用于水中锂回收,系统研究LMO及系列改性材料对锂相对于钠、镁的选择性。
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