一种高透光低雾度的热致变色钙钛矿玻璃及其制备方法和应用

By optimizing the material ratio and annealing environment, a thermochromic perovskite glass with high light transmittance and low haze was prepared, solving the problems of harsh preparation process and insufficient optical performance in the existing technology, and achieving efficient improvement in optical performance and enhanced adaptability.

CN122403785APending Publication Date: 2026-07-17SOUTHEAST UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SOUTHEAST UNIV
Filing Date
2026-03-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing thermochromic perovskite smart windows have demanding fabrication processes, limited optical performance, high haze, low transmittance, high color-changing temperature, and are difficult to adapt to different climates and usage requirements, thus restricting their industrial application.

Method used

By optimizing the material ratio and annealing environment of organic-inorganic hybrid halide perovskites, using air annealing instead of inert atmosphere protection, and combining spin coating and UV ozone treatment, thermochromic perovskite glass with high light transmittance and low haze was prepared.

Benefits of technology

It significantly reduces production costs, improves hot and cold visible light transmittance, reduces haze, and enables rapid and reversible optical switching to meet different application needs.

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Abstract

本发明公开了一种高透光低雾度的热致变色钙钛矿玻璃及其制备方法和应用,该方法按照6:1的摩尔比称取有机铵盐和金属卤化物,有机铵盐优选甲胺碘,金属卤化物优选氯化铅,将称好的有机铵盐和金属卤化物加入主溶剂中搅拌溶解,配制成钙钛矿前驱体溶液;依次使用去离子水、无水乙醇、异丙醇对玻璃基底进行超声清洗,吹干后进行UV臭氧处理;采用旋涂法将钙钛矿前驱体溶液在玻璃基底表面成膜;在相对湿度30%‑70%的常规空气环境中,对表面已成膜的玻璃基底进行退火处理,得到高透光低雾度的热致变色钙钛矿玻璃。本发明在显著降低了生产门槛的同时,还能明显提升热致变色钙钛矿玻璃的光学性能,并具有优良的热致变色调控能力,应用场景广泛。
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