一种光-热双固化氮化硅陶瓷材料及其制备方法与应用

By employing photo-thermal dual curing technology and silicon nitride powder surface oxidation treatment, the problems of processing damage and interlayer bonding strength in photocured 3D printed silicon nitride ceramic green bodies have been solved, enabling the manufacturing of complex structural ceramic parts with high precision and high yield.

CN122403997APending Publication Date: 2026-07-17YANSHAN UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
YANSHAN UNIV
Filing Date
2026-05-11
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing photopolymer 3D printing silicon nitride ceramic green body processing damage cannot be healed, interlayer bonding strength is low, sintering is prone to cracking, and powder modification process is complex, resulting in low yield of complex structure ceramic parts.

Method used

The photo-thermal dual-curing technology is adopted. By introducing a latent crosslinking agent and a thermal latent catalyst, an interpenetrating polymer network is formed that is first photocured and then thermally cured. Combined with the high-temperature oxidation of silicon nitride powder to generate a SiO2 transition layer, the compatibility and refractive index matching between the powder and the resin are improved.

Benefits of technology

It significantly enhances the healing ability of processing damage and the interlayer bonding strength, reduces sintering cracking, improves the yield and mechanical properties of ceramic parts, and simplifies the powder modification process.

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Abstract

本发明属于陶瓷材料技术领域,涉及一种光‑热双固化氮化硅陶瓷材料及其制备方法与应用。按重量份计,包含氮化硅陶瓷粉体40~110份、烧结助剂5~20份、偶联剂1~5、自由基聚合单体10~40份、潜伏性交联剂0.5~5份、热潜伏催化剂0.1~1份、自由基光引发剂 0.1~5份、稀释剂3~25份和分散剂1~5份。本发明通过顺序双固化机制,在光固化形成第一重交联网络后,利用热后固化触发巯基‑环氧点击反应形成第二重交联网络,增强层间结合强度并愈合加工产生的微损伤,解决了单光固化生坯加工损伤大、烧结易开裂的问题,适用于航空航天陶瓷型芯高精度制造。
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