Marine reef preform based on low-concentration carbon dioxide mineralization and preparation method thereof

By using low-concentration carbon dioxide flue gas pretreatment and an enhanced mass transfer carbonization reactor, combined with dynamic agitation and transient depressurization technology, the problem of high mass transfer resistance of low-concentration carbon dioxide gas was solved, enabling the low-energy preparation of artificial reef prefabricated components suitable for marine organism attachment.

CN122404019APending Publication Date: 2026-07-17HUANENG CLEAN ENERGY RES INST +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUANENG CLEAN ENERGY RES INST
Filing Date
2026-04-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, when using low-concentration carbon dioxide gas for solid waste carbonization and artificial reef preparation, the gas-liquid-solid mass transfer resistance is large and the reaction rate is slow, which leads to the need to add a high-energy-consuming gas purification process and increase the preparation cost.

Method used

By employing low-concentration carbon dioxide flue gas pretreatment, and through an enhanced mass transfer carbonization reactor and dynamic stirring mechanism, a microporous structure is generated in the mold using a porous gas distribution plate and transient decompression technology, thereby achieving inorganic mineralization reaction and avoiding the gas purification process.

Benefits of technology

This technology enables the direct utilization of low-concentration carbon dioxide, reduces energy consumption, generates microporous artificial reef prefabricated components suitable for marine organism attachment, and lowers manufacturing costs.

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Abstract

本发明公开了基于低浓度二氧化碳矿化的海洋鱼礁预制件及其制备方法,获取含低浓度二氧化碳烟气并预处理保留低浓度特性;将含钙组分固相原料与水混合成浆料,在强化传质碳化反应器中引入预处理后烟气,使烟气被分割形成微气泡进入浆料进行初级碳化反应;将浆料带压注入专用模具中成型为预制件,在浆料达到半凝固状态时触发瞬态释压操作,利用压降效应促使浆料内微气泡膨胀破裂以在预制件表层原位造孔;将造孔后的预制件移入受控气氛下进行深度碳化养护,以降低并稳定预制件的表面酸碱度,得到海洋鱼礁预制件。本发明免除了提纯浓缩能耗,原位生成适宜海洋底栖生物附着的连通与半连通微孔结构以及中性碳酸盐矿物层。
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