一种交联型纤维素醚、其制备方法及其应用

CN122404579APending Publication Date: 2026-07-17CHONGQING LIHONG FINE CHEM

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHONGQING LIHONG FINE CHEM
Filing Date
2026-05-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional cellulose ether production processes struggle to simultaneously achieve high viscosity (>20000 mPa·s) and high degree of substitution (>1.50), as high alkali content leads to degradation of the cellulose backbone, affecting product performance.

Method used

A method for preparing cross-linked cellulose ethers was adopted, which involves alkalizing the cellulose ether with a mixture of sodium hydroxide, an organic alcohol aqueous solution, and a cross-linking agent to form a controllable covalent cross-linking network, thereby protecting the cellulose backbone and preparing cross-linked cellulose ethers with high substitution degree and high viscosity.

Benefits of technology

It achieves a balance between high degree of substitution (DS>1.50) and high degree of polymerization. The product has a viscosity of over 20,000 mPa·s at 1% solution, exhibiting ultra-high performance and suitable for high-end applications.

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Abstract

本公开涉及有机高分子化合物技术领域,提供了一种交联型纤维素醚、其制备方法及其应用,其中,所述交联型纤维素醚的制备方法,包括以下步骤:S1将氢氧化钠、有机醇的水溶液和纤维素醚混合,碱化反应;所述纤维素醚包括羟甲基纤维素钠、羟丙基甲基纤维素和羟乙基纤维素中的一种或多种;S2在碱化反应结束的体系中加入交联剂进行微交联反应,再采用盐酸进行中和以终止反应,得到交联型纤维素醚。在交联型纤维素醚的制备方法中,本公开通过引入交联剂在CMC、HPMC、HEC任意分子间构建可控交联网络,实现了高取代与高粘度的协同统一。
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