一种绝缘高导热的尼龙复合材料及其制备方法

By introducing benzoxazine-grafted hexagonal boron nitride and magnesium aluminum spinel-supported nano-magnesium oxide filler into nylon materials, combined with modified polyamide compatibilizers, the problems of insufficient thermal conductivity and insulation of nylon materials are solved, and a composite material with high thermal conductivity, high insulation and moisture heat resistance and stability is realized, which is suitable for the electronic and electrical fields.

CN122404971APending Publication Date: 2026-07-17NANJING LIHUA ENG PLASTIC

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NANJING LIHUA ENG PLASTIC
Filing Date
2026-06-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyhexamethylene adipamide (PA66) nylon materials have low thermal conductivity, which cannot meet the heat dissipation requirements of high-power electronic devices. At the same time, the large difference in surface energy between inorganic fillers and nylon matrix makes them prone to agglomeration and uneven dispersion, which limits the improvement of thermal conductivity, increases interface defects, and reduces insulation and resistance to damp heat.

Method used

Benzoxazine-grafted hexagonal boron nitride and magnesium aluminum spinel-supported nano-magnesium oxide were used as fillers, and modified polyamide was used as a compatibilizer to form a continuous thermally conductive path and enhance interfacial bonding. The aromatic heterocycles of benzoxazine were used to passivate surface defects, and the magnesium aluminum spinel-supported nano-magnesium oxide blocked water vapor permeation. The modified polyamide formed multiple coordination effects to improve interfacial compatibility.

Benefits of technology

A nylon composite material with high thermal conductivity, high insulation and long-term resistance to damp heat has been developed. By constructing a continuous thermally conductive network, interfacial hydrogen bonding and multiple coordination effects, the interfacial bonding is strengthened, the interfacial thermal resistance and dielectric loss are reduced, and it is suitable for high-end applications in the field of electronics and electrical engineering.

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Abstract

本发明属于复合材料技术领域,具体涉及一种绝缘高导热的尼龙复合材料及其制备方法,以尼龙66为基体,制备苯并噁嗪接枝六方氮化硼、镁铝尖晶石负载纳米氧化镁为填料,并以改性聚酰胺作为相容剂,其中六方氮化硼片层搭接构筑连续导热通路,降低界面热阻,而苯并噁嗪芳香杂环可与尼龙分子链形成氢键,钝化填料表面缺陷、均化内部电场,保障绝缘稳定性;镁铝尖晶石负载纳米氧化镁填充体系微观孔隙,经氨基硅烷与长链烷基硅烷改性后形成疏水防护层,有效阻隔水汽渗透;改性聚酰胺分子链通过接枝含有硼羟基的氮杂环以及磷酰基,可与无机填料形成多重配位作用,并依托同源结构提升多相界面相容性,适配电子电气领域高端应用场景。
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