Method for efficient extraction of valuable metals from polymetallic nodules

By selectively extracting copper and converting it into reduced copper powder, combined with iron powder reduction and acidity control, the problems of high energy consumption and low leaching rate in polymetallic nodules were solved, achieving efficient and low acid consumption extraction of valuable metals and simplifying the process.

CN122405976APending Publication Date: 2026-07-17INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES
Filing Date
2026-04-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polymetallic nodule extraction processes suffer from problems such as high energy consumption, large acid consumption, low leaching rate of valuable metals, and complex valence states of the leachate. In particular, during wet leaching, the leaching of iron leads to increased acid consumption and complicated subsequent separation.

Method used

By selectively extracting copper and converting it into reduced copper powder, the leaching rate of iron is controlled to be low. Other valuable metals are then reduced using iron powder. Combined with appropriate amounts of acid medium and reducing agent, efficient leaching of valuable metals is achieved, and acid consumption is reduced.

Benefits of technology

It achieves low acid consumption and high leaching rate of valuable metals, simplifies the process, improves the leaching rate of nickel, cobalt, manganese and copper, and reduces the leaching rate of iron, directly obtaining reduced copper powder and reducing the complexity and cost of subsequent separation steps.

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Abstract

本发明提供一种多金属结核中有价金属高效提取的方法,所述方法包括如下步骤:(1)混合多金属结核、第一硫酸和水,得混合料浆;所述混合料浆依次经第一搅拌反应和第一固液分离,得到预提铜液和脱铜结核;(2)混合铁粉和步骤(1)所述预提铜液,并依次经第二搅拌反应和第二固液分离,得到还原铜粉和沉铜后液;(3)混合第二硫酸、还原剂、步骤(1)中所述脱铜结核和步骤(2)中所述沉铜后液,并经第三搅拌反应和第三固液分离,得到有价金属浸出液。本发明能够有效实现Mn、Co、Ni和Cu的高效浸出的同时实现铁的分离,应用前景广阔。
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