一种激光选区熔化原位氧化物颗粒强化TC4钛合金及其制备方法

By generating Y2O3 nanoparticles in situ during the SLM process, the problems of insufficient plasticity and corrosion resistance of TC4 titanium alloy were solved, achieving a synergistic improvement in high strength, excellent plasticity and good corrosion resistance.

CN122406017APending Publication Date: 2026-07-17XINJIANG UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
XINJIANG UNIVERSITY
Filing Date
2026-05-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The SLM forming process of TC4 titanium alloy has problems such as insufficient plasticity, uneven microstructure and insufficient corrosion resistance. Directly added oxide particles have problems such as insufficient particle dispersion and weak interfacial bonding.

Method used

YH2 was used as a precursor to generate Y2O3 nano-oxide particles in situ in the SLM high-temperature molten pool. By controlling the amount of YH2 added and the ball milling conditions through composite powder preparation and laser selective melting process, uniformly distributed Y2O3 particles were formed, and the orientation of α′ martensite laths and grains was regulated to improve the microstructure and properties of the material.

Benefits of technology

While maintaining high strength, the plasticity and corrosion resistance of TC4 titanium alloy were improved, and the synergistic control of microstructure refinement and texture was achieved, thereby enhancing the overall performance of the material.

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Abstract

本发明属于金属增材制造技术领域,具体涉及一种激光选区熔化原位氧化物颗粒强化TC4钛合金及其制备方法。通过引入YH2作为前驱体,通过低速球磨将其与TC4球形粉末均匀混合,在SLM高温熔池中使YH2分解并与体系中的氧发生反应,原位生成Y2O3纳米颗粒。本发明在不改变TC4合金基本体系的前提下,于成形阶段原位构建稳定氧化物颗粒;在适量YH2添加条件下,可促进α′马氏体板条细化、晶粒取向分散和织构弱化,并在保持较高强度水平的同时改善塑性,同时降低自腐蚀电流密度、拓宽钝化区间,实现对TC4合金显微组织、力学性能和钝化稳定性的协同调控。
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