20Cr25NiNbRE austenitic stainless steel, and preparation method and application thereof

By introducing cerium microalloying and multi-stage hot working processes into 20Cr25NiNb austenitic stainless steel, the hot brittleness and grain boundary problems of existing materials have been solved, and the high-temperature ductility and service stability have been improved, making it suitable for ultra-supercritical boilers and high-temperature nuclear power reactor internals.

CN122406110APending Publication Date: 2026-07-17INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing 20Cr25NiNb austenitic stainless steel has problems such as significant hot brittleness, continuous precipitation at grain boundaries, high Cr depletion tendency at grain boundaries, and insufficient processing plasticity reserve during high-temperature service and hot working, which leads to increased risk of forging cracking and unstable mechanical properties.

Method used

By introducing trace amounts of cerium (Ce) for microalloying, combined with ultra-high purity smelting and vacuum pressurized nitrogen alloying technology, the content of harmful impurities is controlled. A multi-stage hot processing process is adopted, including ingot homogenization, three upsetting and three drawing deformation, intermediate annealing and solution treatment, to achieve inclusion refinement, microstructure homogenization and grain refinement.

Benefits of technology

It significantly improves the high-temperature thermal ductility and microstructure stability of the material, enhances its high-temperature service reliability and hot processing safety, reduces grain boundary embrittlement tendency, and improves its high-temperature ductility and resistance to hot cracking.

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Abstract

本发明属于超超临界锅炉与高温核电堆内构件用不锈钢材料及加工技术领域,涉及一种20Cr25NiNbRE奥氏体不锈钢及其制备方法和应用。所述奥氏体不锈钢的成分为:C、Cr、Ni、Mn、Si、Mo、Nb、N、B、Ce、Al、Ti、P、S、O、H和Fe。本发明采用真空加压熔炼与控氮技术,并增加了“短时退火+二次三镦三拔”的多阶段热机械处理路径。本发明通过成分净化、Ce功能化调控及创新热加工处理工艺的协同作用,有效克服了传统20Cr25NiNb奥氏体不锈钢的高温热脆性与组织不稳定问题,在保持高强度与抗氧化性能的同时,明显提升高温热延展性与长期服役可靠性。
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