一种BiVO4 / TiC / C-C光电催化材料及其制备方法和应用

By constructing a BiVO4/TiC/CC gradient composite structure, the problems of low separation efficiency of photogenerated electron-hole pairs and fast carrier recombination rate in BiVO4 photoelectrocatalytic materials were solved, achieving high efficiency and stability in photoelectrocatalytic performance, suitable for photoelectrocatalytic water splitting to produce hydrogen.

CN122406286APending Publication Date: 2026-07-17SHAANXI UNIV OF SCI & TECH
View PDF 0 Cites 0 Cited by

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHAANXI UNIV OF SCI & TECH
Filing Date
2026-03-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing BiVO4 photoelectrocatalytic materials suffer from problems such as low separation efficiency of photogenerated electron-hole pairs, fast recombination rate of photogenerated carriers, and slow kinetics of surface oxygen evolution reaction, which result in their photoelectro-response current density and stability failing to meet the requirements of practical applications.

Method used

By constructing a BiVO4/TiC/CC gradient composite structure, the highly conductive TiC and carbon cloth substrate are used as electron transport channels to optimize the charge transport path. Furthermore, an embedded composite structure with a TiC bottom layer and a BiVO4 surface layer is formed through gradient electrodeposition, which enhances the interfacial bonding force and synergistically regulates the surface electronic structure.

Benefits of technology

It significantly improves photocurrent density, reduces the overpotential of oxygen evolution reaction, extends carrier lifetime, and enhances the structural stability and mechanical strength of the material, meeting the needs of long-term industrial applications.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN122406286A_ABST
    Figure CN122406286A_ABST
Patent Text Reader

Abstract

本发明公开了一种BiVO4 / TiC / C‑C光电催化材料及其制备方法和应用,属于功能材料技术领域;该制备方法先通过高温烧结制得TiC粉末、水热法制备BiVO4粉体,再将二者分别制成分散均匀的前驱体溶液,以预处理后的碳布为基底,通过梯度电泳沉积先镀TiC层再镀BiVO4层,烘干后得到目标光电催化材料;本发明构建了BiVO4 / TiC / C‑C梯度复合结构,实现光吸收、载流子分离与表面催化的功能协同,TiC与碳布形成高效电子传输通道,抑制光生电子‑空穴对复合,TiC与BiVO4协同调控表面电子结构提升析氧动力学;且材料界面结合牢固,结构稳定性和机械强度优异,能抵抗电解液侵蚀,制得的材料可作为光阳极材料应用于碱性环境光催化电解水过程,析氧性能优异。
Need to check novelty before this filing date? Find Prior Art