一种多维纳米相复合的镍基多功能海洋防护涂层的制备方法

By introducing a bilayer structure of Ni-Co-MSN and Ni-W-LDH into the nickel-based coating and combining it with an electrodeposition process, the problems of hydrogen barrier, corrosion prevention and wear resistance of nickel-based composite coatings in marine environments were solved, achieving a highly efficient multi-protection effect.

CN122406339APending Publication Date: 2026-07-17ZHENGZHOU UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHENGZHOU UNIV
Filing Date
2026-06-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing nickel-based composite coatings are insufficient in hydrogen barrier performance in marine environments, and their corrosion resistance is insufficient to meet the requirements of long-term service. They are also difficult to achieve multiple functions such as hydrogen barrier, corrosion resistance and wear resistance. Furthermore, thick coatings are prone to cracking and peeling.

Method used

The design employs a dual-layer structure, with an inner layer of Ni-Co-MSN and an outer layer of Ni-W-LDH. A multi-dimensional nanophase composite coating is constructed using a two-step electrodeposition technique. Three-dimensional MSN nanoparticles are used to construct hydrogen traps, and two-dimensional LDH nanosheets are used to construct a labyrinth barrier. The combination of DC and pulse electrodeposition processes achieves functional layering and interface enhancement.

Benefits of technology

It significantly improves hydrogen barrier performance by over 90%, corrosion resistance by over 100 times, and wear resistance by a significant margin, completely solving the problems of coating cracking and interface peeling, and achieving multi-functional synergistic protection for metal equipment in marine environments.

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Abstract

本发明公开了一种多维纳米相复合的镍基多功能海洋防护涂层的制备方法,属于涂层防护技术领域。该方法包括:对钢基体进行预处理;分别制备介孔二氧化硅纳米球MSN和钨酸根插层的锌铝层状双氢氧化物LDH纳米片;分别配制含有MSN的Ni‑Co镀液和含有LDH的Ni‑W镀液;采用双步电沉积法,先在基体表面直流电沉积Ni‑Co‑MSN内层,再脉冲电沉积Ni‑W‑LDH外层,得到双层复合涂层。本发明通过三维MSN与二维LDH的维度互补、直流与脉冲组合沉积的工艺协同以及双层结构的分层配置,实现了阻氢、防腐、耐磨的多功能一体化防护,氢渗透电流降低91.7%,电荷转移电阻较空白基体提升20倍以上,具有显著的技术进步和工业应用价值。
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