一种大丝束PAN预氧化纤维均匀性评价方法

By using the enthalpy dispersion CV0 within the bundle of 12K PAN pre-oxidized fiber as a benchmark, and combining differential scanning calorimetry (DSC) to perform stratified sampling and thermal analysis of large-tow PAN pre-oxidized fiber, the problem of difficulty in evaluating uniformity during the pre-oxidation process of large-tow PAN fiber was solved, and precise process optimization and product quality control were achieved.

CN122409747APending Publication Date: 2026-07-17DONGHUA UNIV +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
DONGHUA UNIV
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies cannot directly, quantitatively, and precisely characterize the uniformity of the pre-oxidation process of large-tow PAN fibers, resulting in poor process controllability and large fluctuations in product quality. Furthermore, traditional evaluation methods cannot identify local non-uniform areas.

Method used

Using the enthalpy dispersion CV0 of 12K PAN pre-oxidized fiber as a benchmark, differential scanning calorimetry (DSC) was used to perform stratified sampling and thermal analysis on large-tow PAN pre-oxidized fibers of 48K and above specifications. The enthalpy dispersion CVn of exothermic heat release within and between bundles was calculated. By comparing CVn with CV0, the uniformity of large-tow PAN pre-oxidized fibers was quantitatively evaluated.

Benefits of technology

It enables precise quantitative evaluation of the uniformity of large-tow PAN pre-oxidized fibers, accurately locates uneven areas, improves the stability of the production process and the consistency of product quality, reduces the generation of defective products, and improves production efficiency and economic benefits.

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Abstract

本发明涉及一种大丝束PAN预氧化纤维均匀性评价方法,该方法以12K PAN预氧化纤维的放热焓离散度CV0为基准,针对待评价样品将其沿展宽方向等分为n束子纤维束,取样测试后计算束内放热焓离散度CVn与束间放热焓离散度CV。通过对比CVn与CV0的接近程度,以及CV≤3%指标,协同评价大丝束PAN预氧化纤维均匀性。本发明通过分层取样设计与热分析技术相结合,有效解决了48K及以上规格大丝束PAN纤维内外层预氧化均匀性难以量化评价的技术难题,可为大丝束PAN纤维预氧化工艺参数优化、生产过程质量控制提供可靠量化数据支撑,对推动高性能大丝束碳纤维稳定规模化生产具有重要实际应用价值。
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Citation Information

Patent Citations

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