一种硅基铁合金氧化物纳米阵列电极及其制备方法和应用

By constructing silicon-based iron alloy oxide nanoarray electrodes in situ on a silicon substrate, the problems of poor conductivity and insufficient cycle stability were solved, achieving high specific surface area and excellent electrochemical performance, which is suitable for integrated applications of micro supercapacitors and micro batteries.

CN122417698APending Publication Date: 2026-07-17TAIYUAN UNIVERSITY OF TECHNOLOGY
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
TAIYUAN UNIVERSITY OF TECHNOLOGY
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to directly construct controllable and highly ordered three-dimensional nanostructures of iron-based oxides on silicon substrates, resulting in poor conductivity, limited specific surface area, insufficient cycle stability, and poor compatibility with silicon-based microelectronic processes, which limits the application of iron-based oxide electrodes in micro supercapacitors.

Method used

A method for fabricating silicon-based iron alloy oxide nanoarray electrodes is adopted. By depositing iron alloy thin films through magnetron sputtering, combined with anodic oxidation and heat treatment, nanotube arrays or honeycomb porous structures are constructed in situ on silicon substrates to form ordered three-dimensional nanostructures. This simplifies the process and enhances the conductivity and pseudocapacitive properties of the material.

Benefits of technology

It significantly improves the specific capacitance, rate performance, and cycle stability of the electrode, reduces the manufacturing cost, achieves compatibility and integration with silicon-based microelectronics manufacturing processes, is suitable for mass production, and is applicable to micro supercapacitors and micro batteries.

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Abstract

本发明公开了一种硅基铁合金氧化物纳米阵列电极及其制备方法和应用,属于微纳储能材料与器件技术领域,制备方法包括以下步骤:S1、将硅基底超声清洗,在氩气气氛下进行铁合金薄膜沉积;S2、将铁合金薄膜作为阳极,置于电解液中进行阳极氧化处理,得到硅基铁合金纳米阵列;S3、将硅基铁合金纳米阵列热处理,得到硅基铁合金氧化物纳米阵列电极。本发明采用上述的一种硅基铁合金氧化物纳米阵列电极的制备方法,通过铁基合金设计与阳极氧化技术相结合,在硅基底上原位构筑结构可控的有序三维纳米阵列结构,从而实现低成本制备高比表面积、高导电性及优良电化学性能的电极材料,并实现与硅基微电子制造工艺的兼容集成。
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