复合正极活性材料及其制备方法、锂离子电池和用电装置

By using a double-layer coating structure and a gradient concentration design, the interfacial stability problem of lithium-rich cathode materials under high pressure, high temperature and air exposure conditions has been solved, achieving high energy density, long life and high reliability lithium-ion battery performance.

CN122417809APending Publication Date: 2026-07-17YUANSONG (NINGBO) TECHNOLOGY CO LTD +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
YUANSONG (NINGBO) TECHNOLOGY CO LTD
Filing Date
2026-01-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium-rich cathode materials have insufficient interfacial stability under high pressure, high temperature and air exposure conditions, and are prone to side reactions with electrolyte, leading to capacity decay and increased internal resistance.

Method used

The composite positive electrode active material adopts a double-layer coating structure and gradient concentration design. The core consists of a lithium-containing matrix coated with a first coating layer and a second coating layer. The first coating layer is composed of transition metal oxides such as molybdenum and vanadium, while the second coating layer is composed of more stable transition metal oxides such as niobium, tantalum, and tungsten. The concentration of transition metals gradually decreases from the outside to the inside. A robust interface is formed by precisely controlling the reaction temperature and sequence.

Benefits of technology

It significantly improves the interfacial stability of the material under high voltage, high temperature and air exposure conditions, suppresses lattice oxygen release and transition metal dissolution, extends battery cycle life, and maintains good lithium-ion migration ability and surface wettability.

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Abstract

本申请实施例提供一种复合正极活性材料及其制备方法、锂离子电池和用电装置,其中复合正极活性材料包括内核、至少覆盖部分内核的第一包覆层以及至少覆盖部分第一包覆层的第二包覆层;内核包括含锂基体;第一包覆层包括第一过渡金属氧化物和第一含锂过渡金属氧化物;第二包覆层包括第二过渡金属氧化物第二含锂过渡金属氧化物;第一包覆层和 / 或第二包覆层中的过渡金属的浓度自远离内核的外侧向靠近内核的内侧逐渐降低。本申请实施例提供的复合正极活性材料及其制备方法,通过含锂过渡金属相与过渡金属之间的协同作用,显著提高了界面及表面氧的热稳定性和电化学稳定性,兼顾了高压、高温及空气暴露条件下的界面稳定性。
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