一种三元复合锂离子正极材料及其制备方法

By modifying the preparation method of lithium nickel cobalt manganese oxide materials, and combining Zr-Al doping and graphene oxide coating, the problems of insufficient cycle stability and conductivity of lithium nickel cobalt manganese oxide ternary materials are solved, thereby improving the overall performance of lithium-ion batteries.

CN122417869APending Publication Date: 2026-07-17HUNAN YUNENG NEW ENERGY BATTERY MATERIALS CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUNAN YUNENG NEW ENERGY BATTERY MATERIALS CO LTD
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing ternary materials such as nickel-cobalt-manganese lithium oxide have shortcomings in terms of cycle stability and conductivity, which affect the performance of lithium-ion batteries.

Method used

By combining modified lithium nickel cobalt manganese oxide, conductive agents, and binders, and employing specific preparation process steps, including stirring, centrifugation, drying, ball milling, sintering, and coating, Zr-Al doped lithium nickel cobalt manganese oxide is formed, and then coated with graphene oxide to improve the structural stability and electrical conductivity of the material.

Benefits of technology

It significantly improves the cycle life and electrochemical performance of lithium-ion batteries, enhances the conductivity and structural stability of materials, reduces the degree of electrochemical polarization, and improves the first charge-discharge coulombic efficiency.

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Abstract

本发明涉及锂离子电池领域,具体为一种三元复合锂离子正极材料及其制备方法,用于解决现有的镍钴锰酸锂三元材料在循环稳定性、电导率等电化学性能存在不足的问题;通过在镍钴锰酸锂中掺杂Zr‑Al,有效抑制充放电过程中的相变和晶格畸变,提高结构稳定性,从而提升循环寿命,能稳定晶体结构,减少阳离子混排,减少循环过程中的体积变化,提高循环性能,改善材料的电子电导率;Co(OH)2可以与材料表面的残锂进行反应,阻止电极与电解液之间副反应的发生,提高材料的电化学性能,使用氧化石墨烯包覆镍钴锰酸锂提供有效的物理隔离,阻隔电解液与正极材料的直接接触,有效抑制副反应,促进颗粒间的电子传输,降低阻抗。
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