Self-powered system integrated with transparent organic photovoltaics and application thereof
Patent Information
- Application Number
- CN202611132312.7
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2026-07-28
- Publication Date
- 2026-10-13
AI Technical Summary
这带来了几个严峻挑战:(1)续航能力不足:高性能处理器、无线通信模块和各类传感器的功耗日益增长,与电池能量密度的提升速度形成了剪刀差,导致设备需要频繁充电,严重影响用户体验和设备的连续监测能力;(2)体积与重量制约:为延长续航而增加电池容量,会直接导致设备体积和重量增加,这与智能设备小型化、轻量化、便携化的发展趋势背道而驰,尤其在可穿戴设备领域,笨重的电池是影响佩戴舒适性的主要因素之一;(3)环境与维护成本:大量一次性电池的使用带来了资源消耗和废弃处理的环境压力
[0015]本发明提供了一种集成透明有机光伏的自供电体系,包括透明有机光伏组件和能源管理系统;所述透明有机光伏组件从下至上依次包括基底、透明电极层、第一传输层、有机活性层、第二传输层、顶电极和耐候封装层;所述能源管理系统包括电源转换模块、能源管理控制器和储能单元。本发明提供的自供电体系将透明有机光伏组件和能源管理系统进行一体化设计,透明有机光伏组件吸收光能并转换为直流电,能源管理系统中的电源转换模块将光伏组件输出的直流电升压并转换为稳定的直流电,适配智能设备的工作电压;同时能源管理系统中的能源管理控制器可以实时检测总发电量、储能单元的剩余电量及智能设备的工作状态,当发电量≥智能设备实时功耗时,光伏组件直接为智能设备供电,多余电能存入储能单元;当发电量<智能设备实时功耗时,储能单元与光伏组件协同供电,若储能单元电量较低时,自动切换至市电供电;能源管理控制器将供电状态信息通过智能设备的无线通信模块上传至后台管理平台,同时根据后台反馈的使用计划,提前调整储能策略,保障高峰时段供电稳定。实施例的结果显示,本发明提供的集成透明有机光伏的自供电体系用于智能外卖柜后,对于12v 20Ah(240Wh)的电池容量,放电深度为80%,有效可用电量为192Wh,阴雨天的日均取放30次纯电池续航时间约为0.94天,日均取放10次纯电池续航时间约为1.17天;用于户外观光电梯后,日发电量为4.8kWh,光伏自给率达到39.5%,满充后的续航时间约6.6天,夜间低频运行模式的续航时间约为36.4h;用于智能眼镜后,理论充电所需时间约为2.79h,电池充满后仅靠电池供电的续航时间约20h,从80%开始的续航时间约16h。
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Figure CN122908359A_ABST
Abstract
Description
Technical Field
[0001] This invention relates to the field of smart device technology, and in particular to a self-powered system integrating transparent organic photovoltaics and its application. Background Technology
[0002] With the rapid development of the Internet of Things, artificial intelligence, and sensing technologies, smart devices are gradually permeating all aspects of life, from wearable health monitoring devices to industrial wireless sensor networks. However, the continuous operation of these devices is facing a fundamental bottleneck: energy supply.
[0003] Currently, the vast majority of smart devices, especially portable and wearable devices, rely heavily on traditional chemical batteries (such as lithium-ion batteries) as their primary or sole energy source. This presents several serious challenges: (1) Insufficient battery life: The increasing power consumption of high-performance processors, wireless communication modules, and various sensors creates a gap with the rate of improvement in battery energy density, leading to frequent charging of devices and severely impacting user experience and continuous monitoring capabilities; (2) Size and weight constraints: Increasing battery capacity to extend battery life directly leads to an increase in device size and weight, which runs counter to the trend of miniaturization, lightweighting, and portability of smart devices. In particular, in the field of wearable devices, bulky batteries are one of the main factors affecting wearing comfort; (3) Environmental and maintenance costs: The use of a large number of disposable batteries brings environmental pressure from resource consumption and waste disposal. Summary of the Invention
[0004] The purpose of this invention is to provide a self-powered system integrating transparent organic photovoltaics and its application. The self-powered system provided by this invention can convert light energy into electrical energy for storage and consumption by smart devices. At the same time, it can also detect the total power generation, the remaining power of the energy storage unit and the working status of the smart devices in real time, thereby adjusting the energy storage strategy in advance and ensuring stable power supply during peak periods.
[0005] To achieve the above-mentioned objectives, the present invention provides the following technical solution: This invention provides a self-powered system integrating transparent organic photovoltaics, including transparent organic photovoltaic modules and an energy management system; The transparent organic photovoltaic module comprises, from bottom to top, a substrate, a transparent electrode layer, a first transport layer, an organic active layer, a second transport layer, a top electrode, and a weather-resistant encapsulation layer; The energy management system includes a power conversion module, an energy management controller, and an energy storage unit.
[0006] Preferably, the substrate is a rigid transparent substrate or a flexible transparent substrate.
[0007] Preferably, the transparent electrode layer is an ITO and Ag composite conductive material; the ITO and Ag composite conductive material includes an ITO bottom layer + an Ag ultrathin layer or an ITO bottom layer + an Ag ultrathin layer + an ITO top layer.
[0008] Preferably, the thickness of the ITO bottom layer is 50~150nm; the thickness of the Ag ultrathin layer is 8~12nm; and the thickness of the ITO top layer is 30~50nm.
[0009] Preferably, the organic active layer comprises a narrow bandgap conjugated polymer and a non-fullerene acceptor, wherein the mass ratio of the narrow bandgap conjugated polymer to the non-fullerene acceptor is (1~3):(1-3).
[0010] Preferably, the narrow bandgap conjugated polymer is one or more of PTB7-Th, PBDB-T, PM6, and D18.
[0011] Preferably, the non-fullerene acceptor is a perylene diimide, an ITIC series, or a Y6 series; the perylene diimide is one or more of TBDPDI-C5, TBDPDI-C11, SdiPDI, PFPDI-TT, and PFPDI-T; the ITIC series is one or more of ITIC-Th1, ITIC-Th2, ITIC-Th3, ITIC-2Cl-δ, ITIC-2Cl-γ, ITIC-2Cl-β, α-ITIC-2Cl, IDIC, and IT4F; and the Y6 series is one or more of Y6, L8-BO, L8-HD, L8-OD, BTP-eC9, BTP-Cy-4F, BTP-Cy-4Cl, Y6-PhC6, Y6-nC8, Y6-phOC6, and Y6-NO2.
[0012] Preferably, the thickness of the first transport layer is 15~30nm, and the thickness of the second transport layer is 15~30nm.
[0013] This invention provides the application of the self-powered system integrating transparent organic photovoltaics described above in smart devices.
[0014] Preferably, the smart device is a smart food delivery locker, an outdoor sightseeing elevator, or smart glasses.
[0015] This invention provides a self-powered system integrating transparent organic photovoltaics, including a transparent organic photovoltaic module and an energy management system; the transparent organic photovoltaic module includes, from bottom to top, a substrate, a transparent electrode layer, a first transmission layer, an organic active layer, a second transmission layer, a top electrode, and a weather-resistant encapsulation layer; the energy management system includes a power conversion module, an energy management controller, and an energy storage unit. The self-powered system provided by this invention integrates transparent organic photovoltaic (OLED) modules and an energy management system. The OLED modules absorb light energy and convert it into direct current (DC). The power conversion module in the energy management system boosts the DC output from the OLED modules and converts it into stable DC, adapting to the operating voltage of smart devices. Simultaneously, the energy management controller in the energy management system can monitor the total power generation, the remaining power of the energy storage unit, and the operating status of the smart devices in real time. When the power generation is greater than or equal to the real-time power consumption of the smart devices, the OLED modules directly power the smart devices, and excess energy is stored in the energy storage unit. When the power generation is less than the real-time power consumption of the smart devices, the energy storage unit and the OLED modules work together to provide power. If the energy storage unit's power is low, it automatically switches to mains power. The energy management controller uploads the power supply status information to the backend management platform through the wireless communication module of the smart devices. At the same time, based on the usage plan feedback from the backend, it adjusts the energy storage strategy in advance to ensure stable power supply during peak hours. The results of the embodiments show that when the self-powered integrated transparent organic photovoltaic system provided by the present invention is used in a smart food delivery locker, for a 12V 20Ah (240Wh) battery capacity, the depth of discharge is 80%, the effective usable power is 192Wh, the pure battery life is about 0.94 days for an average of 30 pick-ups and drop-offs per day on cloudy or rainy days, and about 1.17 days for an average of 10 pick-ups and drop-offs per day; when used in an outdoor sightseeing elevator, the daily power generation is 4.8kWh, the photovoltaic self-sufficiency rate reaches 39.5%, the full-charge life is about 6.6 days, and the life in low-frequency operation mode at night is about 36.4 hours; when used in smart glasses, the theoretical charging time is about 2.79 hours, the full-charge battery life is about 20 hours, and the life from 80% battery capacity is about 16 hours. Attached Figure Description
[0016] Figure 1 A schematic diagram of the smart food delivery locker provided for application example 1; Figure 2 A physical image of the outdoor sightseeing elevator provided in Application Example 2; Figure 3 A schematic diagram of an outdoor sightseeing elevator provided for application example 2; Figure 4 A schematic diagram of the smart glasses provided for application example 3. Detailed Implementation
[0017] This invention provides a self-powered system integrating transparent organic photovoltaics, including transparent organic photovoltaic modules and an energy management system; The transparent organic photovoltaic module comprises, from bottom to top, a substrate, a transparent electrode layer, a first transport layer, an organic active layer, a second transport layer, a top electrode, and a weather-resistant encapsulation layer; The energy management system includes a power conversion module, an energy management controller, and an energy storage unit.
[0018] In this invention, the transparent organic photovoltaic module comprises, from bottom to top, a substrate, a transparent electrode layer, a first transport layer, an organic active layer, a second transport layer, a top electrode, and a weather-resistant encapsulation layer.
[0019] In this invention, the substrate is preferably a rigid transparent substrate or a flexible transparent substrate; the rigid transparent substrate is preferably made of quartz glass, silicate glass, or soda-lime glass; the thickness of the rigid transparent substrate is preferably 1.1~1.5 mm, more preferably 1.2~1.4 mm, and even more preferably 1.3 mm; the flexible transparent substrate is preferably made of polyethylene terephthalate (PET), polyimide (PI), or polycarbonate (PC); the degree of polymerization of PET is preferably 102~200; the degree of polymerization of PI is preferably 150~300; the degree of polymerization of PC is preferably 60~120; the thickness of the flexible transparent substrate is preferably 0.1~0.3 mm, more preferably 0.2 mm. In this invention, different substrates can be used according to the required mechanical properties, thereby achieving physical protection; at the same time, the high light transmittance of the above substrates can reduce light loss.
[0020] In this invention, the transparent electrode layer is preferably an ITO and Ag composite conductive material; the ITO and Ag composite conductive material preferably comprises an ITO bottom layer + an Ag ultrathin layer or an ITO bottom layer + an Ag ultrathin layer + an ITO top layer; the thickness of the ITO bottom layer is preferably 50-150 nm; the sheet resistance of the ITO bottom layer is preferably 6-15 Ω / sq; the thickness of the Ag ultrathin layer is preferably 8-12 nm; and the thickness of the ITO top layer is preferably 30-50 nm. In embodiments of this invention, the thickness of the ITO bottom layer can be 50 nm, 60 nm, 70 nm, 80 nm, 90 nm, 100 nm, 110 nm, 120 nm, 130 nm, 140 nm, or 150 nm; the thickness of the Ag ultrathin layer can be 8 nm, 9 nm, 10 nm, 11 nm, or 12 nm; and the thickness of the ITO top layer can be 30 nm, 35 nm, 40 nm, 45 nm, or 50 nm. The transparent electrode layer provided by this invention retains the high light transmittance of ITO while utilizing the high conductivity of the Ag layer to solve the problem of high sheet resistance of a single ITO electrode, thereby optimizing the efficiency of the transparent electrode layer.
[0021] In this invention, the material of the first transport layer is preferably PEDOT:PSS, MoO3, or NiO. x The first transport layer is preferably 15-30 nm thick, more preferably 20-25 nm thick, and can be AZO, ZnO, SnO2, or AZO. In this invention, when the transparent organic photovoltaic module has an inversion structure, the first transport layer is an electron transport layer; when it has a positive structure, the first transport layer is a hole transport layer.
[0022] In this invention, the organic active layer preferably comprises a narrow bandgap conjugated polymer and a non-fullerene acceptor; the narrow bandgap conjugated polymer is preferably one or more of PTB7-Th, PBDB-T, PM6, and D18; the non-fullerene acceptor is preferably a perylene diimide (PDI), ITIC series, or Y6 series; the perylene diimide is preferably one or more of TBDPDI-C5, TBDPDI-C11, SdiPDI, PFPDI-TT, and PFPDI-T; the ITIC series is preferably ITIC-Th1, ITIC-Th2, or ITIC-Th3. The active layer comprises one or more of ITIC-2Cl-δ, ITIC-2Cl-γ, ITIC-2Cl-β, α-ITIC-2Cl, IDIC, and IT4F; the Y6 series is preferably one or more of Y6, L8-BO, L8-HD, L8-OD, BTP-eC9, BTP-Cy-4F, BTP-Cy-4Cl, Y6-PhC6, Y6-nC8, Y6-phOC6, and Y6-NO2; the mass ratio of the narrow bandgap conjugated polymer to the non-fullerene acceptor is preferably (1~3):(1~3), more preferably (1~2):(1~2). In this invention, the organic active layer has high absorption of infrared and ultraviolet light, and the visible light transmittance (10~50%) is adjustable, which can significantly improve the light absorption efficiency. At the same time, it has stronger electron-withdrawing ability and energy level regulation, and greatly improves electron mobility, so that the photoelectric conversion efficiency (PCE) of the organic active layer is ≥8%.
[0023] In this invention, the thickness of the organic active layer is preferably 50-200 nm. In embodiments of this invention, the thickness of the organic active layer can be 50 nm, 60 nm, 80 nm, 100 nm, 120 nm, 140 nm, 150 nm, 160 nm, 180 nm, or 200 nm. By controlling the thickness of the organic active layer, this invention can further improve its photoelectric conversion efficiency.
[0024] In this invention, the material of the second transport layer is preferably MoO3 or NiO. xThe material used is SnO2, ZnO, SnO2, or AZO; the thickness of the second transport layer is preferably 15-30 nm, more preferably 20-25 nm. In this invention, when the transparent organic photovoltaic module has an inversion structure, the second transport layer is a hole transport layer; when it has a positive structure, the second transport layer is an electron transport layer.
[0025] In this invention, the thickness of the top electrode is preferably 80-150 nm, more preferably 100-120 nm; the material of the top electrode is preferably silver, copper, or aluminum. In this invention, when the second transport layer is an electron transport layer, the top electrode cooperates with the electron transport layer. The electron transport layer is responsible for extracting electrons from the active layer and transporting them laterally, while the top electrode is responsible for "merging" these electrons and sending them out of the device. Good interfacial contact is essential between the two. When the second transport layer is a hole transport layer, the top electrode cooperates with the hole transport layer to improve hole injection efficiency.
[0026] In this invention, the weather-resistant encapsulation layer is preferably a polyolefin elastomer film; the polyolefin elastomer film is preferably a copolymer of ethylene and octene; the degree of polymerization of the copolymer of ethylene and octene is preferably 800-2500, more preferably 1000-2000, and even more preferably 1400-1500; the thickness of the weather-resistant encapsulation layer is preferably 0.4-0.5 mm. In embodiments of this invention, the thickness of the weather-resistant encapsulation layer can be 0.4 mm, 0.41 mm, 0.42 mm, 0.43 mm, 0.44 mm, 0.45 mm, 0.46 mm, 0.47 mm, 0.48 mm, 0.49 mm, or 0.5 mm. In this invention, the weather-resistant encapsulation layer can absorb and mitigate the thermal stress generated inside the device due to drastic changes in ambient temperature (i.e., temperature shock), thereby protecting the device from damage; at the same time, the weather-resistant encapsulation layer can also improve the waterproof insulation and ultraviolet blocking performance of the transparent organic photovoltaic module, thereby significantly improving the service life of the weather-resistant encapsulation layer.
[0027] The transparent organic photovoltaic module provided by this invention can form a gradient protection system of "shell-frame-core" through the arrangement of substrate, transparent electrode layer, organic active layer and weather-resistant encapsulation layer. It has the characteristics of anti-ultraviolet aging (ultraviolet blocking rate of more than 90%), high and low temperature resistance (-40℃~80℃), rainwater erosion resistance and salt spray corrosion resistance, and is suitable for complex installation environments such as outdoor and semi-outdoor.
[0028] In this invention, the number of transparent organic photovoltaic modules is preferably ≥1, more preferably ≥2. When the number of transparent organic photovoltaic modules is 2 or more, the connection method of the transparent organic photovoltaic modules is preferably parallel or series, more preferably parallel. By connecting multiple transparent organic photovoltaic modules in the above manner, this invention can achieve integrated power generation; by setting them in parallel, multiple transparent organic photovoltaic modules can generate electricity independently, and even if one fails, it will not affect the other transparent organic photovoltaic modules.
[0029] In this invention, the energy management system includes a power conversion module, an energy management controller, and an energy storage unit. In this invention, the energy management system is used to convert, regulate, and store the electrical energy generated by the transparent organic photovoltaic modules, thereby achieving a stable power supply for the self-powered system.
[0030] In this invention, the power conversion module is preferably a DC-DC boost module; the energy storage unit is preferably a battery pack or a supercapacitor; and the capacity of the energy storage unit is preferably 5200~10500mAh. This invention does not impose any special limitations on the specific sources of the power conversion module, energy management controller, and energy storage unit; commercially available products well-known to those skilled in the art can be used.
[0031] In this invention, the energy management system and the transparent organic photovoltaic module form a collaborative power supply system, which realizes energy storage when there is sufficient sunlight and power supply in low light / night / rainy weather. At the same time, it has an automatic switching backup function with other power sources to ensure emergency power supply in case of power failure.
[0032] This invention does not impose any special limitations on the connection method between the transparent organic photovoltaic module and the energy management system; it can be determined based on the technical common sense of those skilled in the art. In embodiments of this invention, the transparent organic photovoltaic module can be connected to the power conversion module in the energy management system.
[0033] In this invention, the self-powered system integrating transparent organic photovoltaics preferably further includes auxiliary photovoltaic modules; the auxiliary photovoltaic modules are preferably connected in parallel with the transparent organic photovoltaic modules and then connected to a micro energy management system; the auxiliary photovoltaic modules are preferably transparent organic photovoltaic modules or opaque photovoltaic panels; the opaque photovoltaic panels are preferably made of crystalline silicon or perovskite. In this invention, the composition of the transparent organic photovoltaic modules is preferably the same as that of the aforementioned transparent organic photovoltaic modules, and will not be repeated here. In this invention, the auxiliary photovoltaic modules can complement the transparent organic photovoltaic modules with a "light transmission + high efficiency" system, used to increase power generation during periods of strong sunlight and supplement power supply for high-power scenarios of smart devices.
[0034] The self-powered system integrating transparent organic photovoltaics (OLEDs) provided by this invention integrates transparent OLED modules and an energy management system. The transparent OLED modules absorb light energy and convert it into direct current (DC). The power conversion module in the energy management system boosts the DC output from the OLED modules and converts it into stable DC to match the operating voltage of smart devices. Simultaneously, the energy management controller in the energy management system can monitor the total power generation, the remaining power of the energy storage unit, and the operating status of the smart devices in real time. When the power generation is greater than or equal to the real-time power consumption of the smart devices, the OLED modules directly power the smart devices, and excess energy is stored in the energy storage unit. When the power generation is less than the real-time power consumption of the smart devices, the energy storage unit and the OLED modules work together to provide power. If the energy storage unit's power is low, it automatically switches to mains power. The energy management controller uploads the power supply status information to the backend management platform through the wireless communication module of the smart devices. At the same time, based on the usage plan feedback from the backend, it adjusts the energy storage strategy in advance to ensure stable power supply during peak hours.
[0035] This invention does not impose any particular limitation on the preparation method of the self-powered integrated transparent organic photovoltaic system. Any preparation method well-known to those skilled in the art can be used, as long as the layers are composited and do not separate. In this invention, the layers are macroscopically physically stacked, and the interlayer bonding forces are van der Waals forces, intermolecular hydrogen bonds, or interfacial electrostatic potentials.
[0036] The present invention also provides the application of the self-powered system integrating transparent organic photovoltaics described above in smart devices.
[0037] This invention does not impose any specific limitations on the type or source of the intelligent device; any intelligent device well-known to those skilled in the art can be used. In embodiments of this invention, the intelligent device may be a smart food delivery locker, an outdoor sightseeing elevator, or smart glasses.
[0038] In this invention, when the smart device is a smart food delivery locker, the smart food delivery locker preferably includes a cabinet body, storage compartments, a cabinet control system, and storage compartment functional modules.
[0039] The present invention does not impose any special limitations on the specific shape and size of the cabinet, which can be determined based on the technical common sense of those skilled in the art.
[0040] The present invention does not impose any special limitations on the specific number, size and distribution of the storage compartments, which can be determined based on the technical common sense of those skilled in the art.
[0041] In this invention, the cabinet control system preferably includes a main control board, a touch display panel, and a wireless communication module; the wireless communication module is preferably 4G, 5G, or Wi-Fi. This invention does not impose any special limitations on the specific model or source of the main control board and touch display panel; commercially available cabinet control systems well-known to those skilled in the art can be used.
[0042] In this invention, the storage compartment functional module preferably includes an electronic lock, a temperature and humidity sensor, a lighting module, and a sterilization module; the sterilization module is preferably an ultraviolet germicidal lamp or an ozone sterilization module. This invention does not impose any special limitations on the specific composition and source of the electronic lock, temperature and humidity sensor, and lighting module; commercially available storage compartment functional modules well-known to those skilled in the art can be used.
[0043] In this invention, the transparent organic photovoltaic (OLED) modules in the self-powered integrated transparent organic photovoltaic (PV) system are preferably integrated into the transparent cabinet door of the storage compartment, the top transparent cover of the cabinet, or the side transparent decorative panel of the cabinet. The transparent PV modules are preferably connected to the micro energy management system via concealed wires in series or parallel. The wires are preferably hidden inside the frame of the cabinet. This invention does not impose any special limitations on the size of the transparent PV modules; based on the technical knowledge of those skilled in the art, they can be determined to correspond to the size of the transparent cabinet door, the top transparent cover of the cabinet, or the side transparent decorative panel of the cabinet. By using the above-described method to set up the transparent PV modules, this invention can fully utilize the vacant, sun-facing position of the smart delivery cabinet to increase power generation, while also ensuring the aesthetics and safety of the cabinet.
[0044] In this invention, the energy management controller of the energy management system in the self-powered system integrating transparent organic photovoltaics is preferably electrically connected to the main control board and storage compartment functional modules of the cabinet control system. By connecting these three components, this invention can dynamically adjust the operating parameters of each functional module based on the real-time power generation of the transparent organic photovoltaic modules, the remaining power of the energy storage unit, and the frequency of use of the takeaway cabinet. For example, it can dynamically adjust the brightness of the lighting module and the working time of the sterilization module, reduce the brightness of the touch display panel or put it into an off state during off-peak hours, and prioritize the power supply to the electronic lock, wireless communication module, and emergency lighting when the power generation is insufficient.
[0045] In this invention, when the self-powered system integrating transparent organic photovoltaics includes auxiliary photovoltaic modules, the auxiliary photovoltaic modules are preferably installed on the top of the smart delivery locker. They are connected to the micro energy management system via concealed wires in series or parallel, with the wires hidden inside the upper frame of the locker. By installing auxiliary photovoltaic modules, this invention can fully utilize the top space of the smart delivery locker, further increasing power generation and supplementing power for high-power scenarios such as centralized disinfection of the delivery locker and high-frequency locking / unlocking during peak hours.
[0046] In this invention, the transparent organic photovoltaic (OLED) modules and auxiliary OLED modules in the self-powered system integrating transparent organic photovoltaics absorb light energy and convert it into direct current (DC). The power conversion module in the energy management system boosts the DC output from the OLED modules and converts it into stable DC, adapting to the operating voltage of the delivery locker's electrical system. Simultaneously, the energy management controller in the energy management system can monitor the total power generation, the remaining power of the energy storage unit, and the working status of the smart delivery locker (standby / peak usage / disinfection) in real time. When the power generation is greater than or equal to the real-time power consumption of the delivery locker, the OLED modules directly power the locker control system and storage compartment modules, and excess energy is stored in the energy storage unit. When the power generation is less than the real-time power consumption of the delivery locker, the energy storage unit and OLED modules work together to supply power. If the energy storage unit's power is low, it automatically switches to mains power. The energy management controller uploads the power supply status information to the back-end management platform through the locker control system's wireless communication module. At the same time, based on the usage plan feedback from the back-end, it adjusts the energy storage strategy in advance to ensure stable power supply during peak hours.
[0047] This invention integrates a self-powered transparent organic photovoltaic system with a food delivery locker, embedding photovoltaic modules in the locker's transparent door and other locations to achieve a balance between selective absorption and conversion of infrared and ultraviolet light and visible light transmission, thus balancing power generation and the ability to observe items inside the locker. A micro-energy management system handles energy conversion, regulation, and storage, providing a stable power supply to the locker system. This overcomes the bottlenecks of traditional smart food delivery lockers, which rely on mains power, have cumbersome outdoor wiring, and high energy consumption. Furthermore, by employing energy management methods adapted to different usage scenarios, it optimizes energy allocation, making it suitable for outdoor and semi-outdoor environments such as residential communities, office buildings, and industrial parks. It boasts advantages such as green energy saving, convenient installation, and stable operation, aligning with low-carbon development policies.
[0048] In this invention, when the intelligent device is an outdoor sightseeing elevator, the outdoor sightseeing elevator preferably includes an elevator car, a transparent viewing curtain wall, an elevator drive system, and a car function module.
[0049] The present invention does not impose any special limitations on the specific size and shape of the elevator car, which can be determined based on the technical common sense of those skilled in the art.
[0050] The present invention does not impose any special limitations on the specific size and shape of the transparent viewing wall; it can be determined based on the technical common sense of those skilled in the art.
[0051] The present invention does not have any special limitation on the specific source of the elevator drive system, and any commercially available elevator drive system known to those skilled in the art can be used.
[0052] In this invention, the car functional module preferably includes a car lighting system, a ventilation system, a display and interaction module, and an emergency alarm module; the display and interaction module is preferably a transparent display panel; and the display and interaction module is preferably integrated into the car of the outdoor sightseeing elevator. This invention does not impose any special limitations on the specific integration area of the display and interaction module; it can be selected based on the technical knowledge of those skilled in the art. This invention also does not impose any special limitations on the specific configuration of the car lighting system, ventilation system, and emergency alarm module; they can be determined based on the technical knowledge of those skilled in the art.
[0053] In this invention, the transparent organic photovoltaic (OLED) modules in the self-powered integrated transparent OLED system are preferably integrated onto the outer surface of the transparent viewing wall. The length of a single OLED module is preferably 400-1200 mm, and the width is preferably 300-600 mm. The spacing between adjacent OLED modules is preferably 5-10 mm. The connecting wires of the OLED modules are preferably located within the joints of the spacing. The gaps between adjacent modules are preferably filled with weather-resistant sealant. By adopting the above-mentioned configuration, this invention ensures that the transparent viewing wall has excellent light transmittance, does not affect the viewing experience of the outdoor sightseeing elevator, fully utilizes solar energy to achieve stable power generation for the outdoor sightseeing elevator, and simultaneously guarantees good waterproof and dustproof performance of the transparent viewing wall.
[0054] In this invention, the energy management controller of the energy management system in the self-powered system integrating transparent organic photovoltaics is preferably electrically connected to the transparent organic photovoltaic modules, the elevator drive system, and the car function module. In this invention, the energy management controller dynamically adjusts the brightness of the lighting system, the airflow of the ventilation system, and the operating mode of the display and interaction module based on the power generation. When the power generation is insufficient, priority is given to ensuring power supply to the emergency alarm module. By adopting the above connection method, the power supply strategy can be dynamically adjusted according to the real-time power generation of the transparent organic photovoltaic modules, the remaining power of the energy storage unit, and the elevator operating status.
[0055] In this invention, when the self-powered system of integrated transparent organic photovoltaics includes auxiliary photovoltaic modules, the auxiliary photovoltaic modules are preferably installed at the top of the elevator shaft of the external light-emitting elevator; the auxiliary photovoltaic modules are preferably connected in parallel with the transparent organic photovoltaic modules and then connected to the energy management system. This invention, by installing auxiliary photovoltaic modules, can fully utilize the solar energy at the top of the elevator shaft to increase power generation during periods of strong sunlight, providing auxiliary power for starting the elevator drive system.
[0056] In this invention, the transparent organic photovoltaic (PV) module and auxiliary PV module in the self-powered system integrating transparent organic photovoltaics absorb light energy and convert it into direct current (DC). The power conversion module in the energy management system boosts the DC output from the PV module and converts it into a stable 24V or 36V DC, adapting to the working voltage of the elevator electrical system. Simultaneously, the energy management controller monitors the total power generation, the remaining power of the energy storage unit, and the elevator's operating status (standby / start / running / braking) in real time. When the power generation is greater than or equal to the elevator's real-time power consumption, the transparent organic PV module directly powers the elevator drive system and the car's functional modules, with excess energy stored in the energy storage unit. When the power generation is less than the elevator's real-time power consumption, the energy storage unit and the transparent organic PV module work together to provide power. If the energy storage unit's power is low, it automatically switches to mains power. The energy management controller feeds back the power supply status information to the elevator's main control system, which dynamically adjusts the drive system's operating parameters and the car's functional modules' working modes based on the power generation to achieve optimal energy allocation.
[0057] This invention integrates a self-powered transparent organic photovoltaic system with the viewing wall of an outdoor sightseeing elevator, achieving a balance between selective absorption and conversion of infrared and ultraviolet light and visible light transmission, thus meeting both power generation and viewing needs. A micro-energy management system handles power conversion, regulation, and storage, providing a stable power supply to the outdoor sightseeing elevator. This overcomes the bottleneck of traditional outdoor sightseeing elevators' reliance on mains power and high energy consumption. Furthermore, a multi-scenario adaptive energy management method optimizes energy allocation. Suitable for outdoor settings such as commercial complexes and scenic spots, this invention offers advantages such as green energy saving, excellent viewing experience, and stable operation, aligning with the "dual-carbon" policy direction.
[0058] In this invention, when the smart device is smart glasses, the smart glasses preferably include a frame, lenses, and functional modules.
[0059] This invention does not impose any special limitations on the specific dimensions and shapes of the frames and lenses; these can be determined based on the technical knowledge of those skilled in the art. In the embodiments of this invention, the temples of the frames preferably adopt an arc-shaped curved surface structure.
[0060] In this invention, the functional module preferably includes at least one of a microprocessor, a display module, and a sensing module; the functional module is preferably disposed within the eyeglass frame. This invention does not impose any special limitations on the specific location or arrangement of the functional module within the eyeglass frame; it can be arranged according to the technical common sense of those skilled in the art, as long as it allows the functional module to exist stably within the eyeglass frame.
[0061] In this invention, the transparent organic photovoltaic (OLED) modules in the self-powered system integrating transparent organic photovoltaics are preferably integrated into the edge area of the smart glasses lens and / or the surface of the frame. The integration method is preferably a hybrid integration method, more preferably a ring-shaped arrangement at the lens edge and an arrangement on the temple. The ring width of the ring-shaped arrangement at the lens edge is preferably 2-8 mm, more preferably 3-7 mm, and even more preferably 4-6 mm. The temple arrangement is preferably a method of fitting the transparent organic photovoltaic module to the curved surface of the temple. The transparent organic photovoltaic modules in the ring-shaped arrangement at the lens edge and the temple arrangement are preferably connected in parallel and then connected to the energy management system. In this invention, the transparent organic photovoltaic module in the ring-shaped arrangement at the lens edge is the core power supply unit, and the transparent organic photovoltaic module in the temple arrangement is an auxiliary power supply unit. This arrangement method can increase the contact area between the transparent organic photovoltaic module and the light, thereby improving power generation efficiency. Simultaneously, the transparent organic photovoltaic modules are distributed in a ring shape at the lens edge, without obstructing the central field of view of the lens. After encapsulation, the overall thickness of the temple is moderate, ensuring wearing comfort.
[0062] In this invention, the energy management system of the integrated transparent organic photovoltaic self-powered system is preferably connected to the transparent organic photovoltaic modules and functional modules. By connecting the energy management system and functional modules, this invention can dynamically adjust the operating parameters of the functional modules based on the real-time power generation of the transparent organic photovoltaic modules. It can also dynamically adjust the brightness of the display module or the sampling frequency of the sensor module within the functional modules based on the power generation, prioritizing power supply to the core functions of the display module when power generation is insufficient.
[0063] In this invention, the transparent organic photovoltaic (PV) module and auxiliary PV module in the self-powered system integrating transparent organic photovoltaics absorb light energy and convert it into direct current (DC). The power conversion module in the energy management system boosts the DC output from the PV module and converts it into stable DC to match the operating voltage of the functional modules in the smart glasses. Simultaneously, the energy management controller monitors the total power generation, the remaining power of the energy storage unit, and the operating status of the smart glasses in real time. When the power generation is greater than or equal to the real-time power consumption of the functional modules, the transparent organic PV module directly powers the functional modules and simultaneously charges the energy storage unit. When the power generation is less than the real-time power consumption of the functional modules, the energy storage unit and the transparent organic PV module work together to supply power. The energy management system feeds back the power generation information to the microprocessor, which dynamically adjusts the operating parameters of the functional modules to optimize energy consumption.
[0064] This invention breaks through the bottlenecks of short battery life and heavy weight of traditional smart glasses by using a flexible and transparent integrated design of transparent organic photovoltaic modules. At the same time, it further optimizes energy consumption through an energy management method that dynamically adjusts the working parameters of the power generation function module. It is suitable for multiple scenarios such as AR near-eye display and outdoor adaptive dimming, and has the advantages of lightweight, long battery life and good visual experience.
[0065] The technical solutions of this invention will be clearly and completely described below with reference to the embodiments thereof. Obviously, the described embodiments are only a part of the embodiments of this invention, and not all of them. All other embodiments obtained by those skilled in the art based on the embodiments of this invention without creative effort are within the scope of protection of this invention.
[0066] Example 1 A self-powered system integrating transparent organic photovoltaics includes transparent organic photovoltaic modules, auxiliary photovoltaic modules, and an energy management system; The transparent organic photovoltaic module consists of, from bottom to top, a substrate, a transparent electrode layer, a first transport layer, an organic active layer, a second transport layer, a top electrode, and a weather-resistant encapsulation layer; The substrate is a flexible transparent substrate, the material of which is polycarbonate (PI), the degree of polymerization of PI is 150~300, and the thickness of the flexible transparent substrate is 0.2mm. The transparent electrode layer is a composite conductive material of ITO and Ag, specifically consisting of an ITO bottom layer + an Ag ultrathin layer + an ITO top layer; the thickness of the ITO bottom layer is 100 nm, the thickness of the Ag ultrathin layer is 10 nm, and the thickness of the ITO top layer is 40 nm. The first transport layer is made of ZnO; the thickness of the first transport layer is 30 nm. The organic active layer is composed of a narrow bandgap conjugated polymer and a non-fullerene acceptor; the narrow bandgap conjugated polymer is PM6, the non-fullerene acceptor is Y6, and the mass ratio of the narrow bandgap conjugated polymer to the non-fullerene acceptor is 1:1; the thickness of the organic active layer is 150 nm. The material of the second transport layer is SnO2; the thickness of the second transport layer is 30nm; The top electrode is made of copper; the thickness of the top electrode is 100 nm. The weather-resistant encapsulation layer is a polyolefin elastomer film, which is a copolymer of ethylene and octene with a degree of polymerization of 800-2500; the thickness of the weather-resistant encapsulation layer is 0.45 mm. The energy management system consists of a power conversion module, an energy management controller, and an energy storage unit; the power conversion module is a DC-DC boost module, and the energy storage unit is a supercapacitor with a capacity of 10500mAh. The auxiliary photovoltaic module is made of the same material as the transparent organic photovoltaic module; The transparent organic photovoltaic module and the auxiliary photovoltaic module are connected in parallel and then connected to the power conversion module in the energy management system.
[0067] Application Example 1 The self-powered system integrating transparent organic photovoltaics provided in Example 1 is applied to a smart food delivery locker: The smart food delivery locker consists of a locker body, storage compartments, a locker control system, and storage compartment functional modules. The cabinet control system consists of a main control board, a touch display panel, and a wireless communication module; the wireless communication module can be connected via 4G, 5G, or Wi-Fi. The storage compartment functional module consists of an electronic lock, a temperature and humidity sensor, a lighting module, and a sterilization module; the sterilization module is an ultraviolet germicidal lamp. In the self-powered system integrating transparent organic photovoltaics, the transparent organic photovoltaic modules are integrated into the transparent cabinet door of the storage compartment, the transparent top cover of the cabinet, or the transparent decorative panel on the side of the cabinet; the transparent organic photovoltaic modules are connected to the micro energy management system in parallel through hidden wires; the wires are hidden inside the frame of the cabinet; In the self-powered system of integrated transparent organic photovoltaics, the energy management controller of the energy management system is electrically connected to the main control board and storage compartment functional module of the cabinet control system. The auxiliary photovoltaic module is installed on the top of the smart food delivery cabinet and is connected to the micro energy management system in parallel via concealed wires, which are hidden inside the upper frame of the cabinet.
[0068] The schematic diagram of the smart food delivery locker provided in Example 1 of this invention is as follows: Figure 1 As shown. By Figure 1 It can be seen that the transparent organic photovoltaic modules in the self-powered system are mainly concentrated on the surface of the storage compartments of the smart delivery locker; the auxiliary photovoltaic modules are mainly concentrated on the top of the smart delivery locker, while the energy management system and wires are hidden inside the smart delivery locker, which will not affect the appearance of the smart delivery locker or its light transmittance.
[0069] Test Example 1 The application effect of the self-powered system integrating transparent organic photovoltaics in the smart food delivery locker provided in Use Case 1 was tested. The specific tests were as follows: Set at standard high intensity light 1000W / m 2 Down, Area of a single piece: 0.3m × 0.4m = 0.12m 2 , Total paving area: 20 pieces × 0.12 = 2.4m 2 , Peak power (Pmax) = Area × 1000W / m 2 × Efficiency (7%) = 2.4 × 1000 × 0.07 = 168W; Daily power generation: (Based on a conservative estimate of the national average effective sunshine duration of 4 hours / day from 10:00 to 14:00) = 168W × 4h = 672Wh (approximately 0.67 kWh / day). For a 12V 20Ah (240Wh) battery with a discharge depth of 80%, the effective usable capacity is 80% × 240Wh = 192Wh; Shortest daylight hours: Standby daily power consumption: 6W × 24h = 144Wh / day Single dispensing / refill: 167mAh@12V = 2.004Wh / cycle With a moderate flow rate of 30 feeds / discharges per day, the total daily power consumption is 144 + 2 * 30 = 204 Wh / day. Peak usage: 50 times / day, total daily power consumption = 144 + 2 * 50 = 244Wh / day If the items are retrieved and placed 30 times a day, the required sunshine duration is approximately 204 ÷ 168 ≈ 1.21 hours (about 73 minutes). If the items are retrieved and placed 50 times a day, the required sunshine duration is approximately 244 ÷ 168 ≈ 1.45 hours (about 87 minutes). Battery life on rainy days: The effective usable battery capacity remains at 192Wh. With an average of 30 pick-up and drop-off cycles per day, the battery life is approximately 0.94 days (about 22.5 hours). With an average of 10 times of taking it out and putting it in per day, the pure battery life is approximately 1.17 days (about 28 hours).
[0070] As can be seen, the self-powered system of integrated transparent organic photovoltaic provided in Embodiment 1 of the present invention can generate a large amount of electricity under sunlight conditions when used in smart food delivery lockers, ensuring stable power supply during peak hours.
[0071] Example 2 A self-powered system integrating transparent organic photovoltaics includes transparent organic photovoltaic modules, auxiliary photovoltaic modules, and an energy management system; The transparent organic photovoltaic module consists of, from bottom to top, a substrate, a transparent electrode layer, a first transport layer, an organic active layer, a second transport layer, a top electrode, and a weather-resistant encapsulation layer; The substrate is a rigid transparent substrate, the material of which is quartz glass, and the thickness of the substrate is 0.2mm; The transparent electrode layer is a composite conductive material of ITO and Ag, specifically consisting of an ITO bottom layer + an Ag ultrathin layer + an ITO top layer; the thickness of the ITO bottom layer is 100 nm, the thickness of the Ag ultrathin layer is 10 nm, and the thickness of the ITO top layer is 35 nm. The first transport layer is made of ZnO; the thickness of the first transport layer is 30 nm. The organic active layer is composed of a narrow bandgap conjugated polymer and a non-fullerene acceptor; the narrow bandgap conjugated polymer is D18, the non-fullerene acceptor is L8-BO, and the mass ratio of the narrow bandgap conjugated polymer to the non-fullerene acceptor is 1:1.2; the thickness of the organic active layer is 150 nm. The material of the second transport layer is SnO2; the thickness of the second transport layer is 30nm; The top electrode is made of copper; the thickness of the top electrode is 100 nm. The weather-resistant encapsulation layer is a polyolefin elastomer film, which is a copolymer of ethylene and octene with a degree of polymerization of 800-2500; the thickness of the weather-resistant encapsulation layer is 0.45 mm. The energy management system consists of a power conversion module, an energy management controller, and an energy storage unit; the power conversion module is a DC-DC boost module, and the energy storage unit is a supercapacitor with a capacity of 10500mAh. The auxiliary photovoltaic module is made of the same material as the transparent organic photovoltaic module; The transparent organic photovoltaic module and the auxiliary photovoltaic module are connected in parallel and then connected to the power conversion module in the energy management system.
[0072] Application Example 2 The self-powered system integrating transparent organic photovoltaics provided in Example 2 is applied to an outdoor sightseeing elevator: The outdoor sightseeing elevator consists of an elevator car, a transparent viewing curtain wall, an elevator drive system, and a car function module. The car's functional modules consist of a car lighting system, a ventilation system, a display and interaction module, and an emergency alarm module; the display and interaction module is a transparent display panel; the display and interaction module is integrated into the outdoor sightseeing elevator. Figure 2 (within the yellow area) In the self-powered system of integrated transparent organic photovoltaics, the transparent organic photovoltaic modules are integrated onto the outer surface of the transparent viewing curtain wall; the length and width of a single transparent organic photovoltaic module are as follows: Figure 2 As shown; the spacing between adjacent components in the transparent organic photovoltaic module is 10mm; the connecting wires of the transparent organic photovoltaic module are located within the gap, and the gap between adjacent components is filled with weather-resistant sealant; In the self-powered system integrating transparent organic photovoltaics, the energy management controller of the energy management system is electrically connected to the transparent organic photovoltaic modules, the elevator drive system, and the car function module. The auxiliary photovoltaic module is installed at the top of the elevator shaft of the external light elevator; preferably, the auxiliary photovoltaic module is connected in parallel with the transparent organic photovoltaic module and then connected to the energy management system.
[0073] A physical image of the outdoor sightseeing elevator provided in Application Example 2 of this invention is shown below. Figure 2 As shown; a schematic diagram of the outdoor sightseeing elevator provided in Application Example 2 of the present invention is shown. Figure 3 As shown. By Figure 2 and Figure 3 It can be seen that the transparent organic photovoltaic modules in the self-powered system are mainly concentrated on the surface of the transparent viewing curtain wall of the outdoor sightseeing elevator; the auxiliary photovoltaic modules are mainly concentrated on the top of the outdoor sightseeing elevator, while the energy management system and wires are hidden in the gaps of the outdoor sightseeing elevator, which will not affect the appearance of the outdoor sightseeing elevator or its light transmittance.
[0074] Test Example 2 The length and width of one side of the curtain wall are 3m and 4m, which can accommodate 56 batteries of 30cm and 40cm each. Area of a single piece: 0.3m × 0.4m = 0.12m 2 , Total paving area for 3 layers: 56 pieces × 0.12m 2 ×3 floors = 20.16m 2 , Set at standard high intensity light 1000W / m 2 Down Pmax = Total area × Standard irradiance × Module conversion efficiency × System overall efficiency = 20.16 × 1000 × 7% × 0.85 = 1199.5W Daily power generation (conservatively estimated based on the national average effective sunshine duration of 4 hours / day from 10:00 to 14:00) = 1199.5W × 4h = 4.8kWh A = Photovoltaic power supply directly to the load (consumed immediately during the day, without going through batteries). B = The amount of electricity that the photovoltaic system charges into the energy storage battery (charged into the battery and stored for use at night). D = the amount of electricity released by the energy storage battery. Egrid = Electricity replenished by the power grid. Lithium battery charge / discharge cycle efficiency: 90%, i.e., D = B × 0.90. The elevator and car's average daily total energy consumption is 11.6 kWh (drive 9.5 + function 2.1), with a nighttime load of 11.6 kWh × 30% = 3.48 kWh. Based on the actual operation pattern of the elevator during the day, the photovoltaic direct supply load A is set at 2.6kWh (during the elevator operation period from 8:00 to 17:00 during the day, photovoltaic power is given priority to direct supply). The amount of electricity charged into the battery, B = E_total - A = 4.8 - 2.6 = 2.2 kWh. The battery can release a charge D = B × 0.90 = 2.2 × 0.90 = 1.98 kWh. The grid-supplemented electricity (Egrid) = Total load - AD = 11.6 - 2.6 - 1.98 = 7.02 kWh. The actual total electricity contribution from photovoltaic power generation = A + D = 2.6 + 1.98 = 4.58 kWh. The photovoltaic self-sufficiency rate on that day was 4.58 / 11.6 = 39.5%. For a 12V 20Ah (15 kWh) battery capacity, with a SOC of 35%, the corresponding energy capacity is 15kWh × 35% = 5.25kWh. To charge the battery from 35% in the morning to the system's set "full charge protection threshold" of 85% (12.75kWh of battery capacity). The required net charge is: 12.75 - 5.25 = 7.5 kWh. The average daily net increase in battery capacity = charging amount 2.2 - discharging amount 1.98 = 0.22 kWh. Therefore, the cumulative number of consecutive sunny days required to reach full charge is approximately 7.5 / 0.22 ≈ 34 days (22 consecutive days of equally sunny weather). Usage time after full charge (reaching 85% SOC): Assuming the battery reaches 85% SOC (12.75kWh) after a series of sunny days, in pure standby mode (power consumption approximately 80W). Battery life = 12.75kWh / 0.08kW = 159.4h (approximately 6.6 days). Nighttime low-frequency operation mode (elevator operates intermittently, with an average power consumption of approximately 0.35kW). Battery life = 12.75 / 0.35 ≈ 36.4 hours.
[0075] It can be seen that the self-powered system of integrated transparent organic photovoltaic provided in Embodiment 2 of the present invention has a long battery life when used in outdoor sightseeing elevators.
[0076] Example 3 A self-powered system integrating transparent organic photovoltaics includes transparent organic photovoltaic modules, auxiliary photovoltaic modules, and an energy management system; The transparent organic photovoltaic module consists of, from bottom to top, a substrate, a transparent electrode layer, a first transport layer, an organic active layer, a second transport layer, a top electrode, and a weather-resistant encapsulation layer; The substrate is a flexible transparent substrate, the material of which is polycarbonate, and the thickness of which is 0.2 mm. The transparent electrode layer is a composite conductive material of ITO and Ag, specifically consisting of an ITO bottom layer + an Ag ultrathin layer + an ITO top layer; the thickness of the ITO bottom layer is 100 nm, the thickness of the Ag ultrathin layer is 10 nm, and the thickness of the ITO top layer is 40 nm. The first transport layer is made of ZnO; the thickness of the first transport layer is 30 nm. The organic active layer is composed of a narrow bandgap conjugated polymer and a non-fullerene acceptor; the narrow bandgap conjugated polymer is PTB7-Th, the non-fullerene acceptor is ITIC-Th1, and the mass ratio of the narrow bandgap conjugated polymer to the non-fullerene acceptor is 1:1.2; the thickness of the organic active layer is 150 nm. The material of the second transport layer is SnO2; the thickness of the second transport layer is 30nm; The top electrode is made of copper; the thickness of the top electrode is 100 nm. The weather-resistant encapsulation layer is a polyolefin elastomer film, which is a copolymer of ethylene and octene with a degree of polymerization of 800-2500; the thickness of the weather-resistant encapsulation layer is 0.45 mm. The energy management system consists of a power conversion module, an energy management controller, and an energy storage unit; the power conversion module is a DC-DC boost module, and the energy storage unit is a supercapacitor with a capacity of 10500mAh. The auxiliary photovoltaic module is made of the same material as the transparent organic photovoltaic module; The transparent organic photovoltaic module and the auxiliary photovoltaic module are connected in parallel and then connected to the power conversion module in the energy management system.
[0077] Application Example 3 The self-powered system integrating transparent organic photovoltaics provided in Example 3 is applied to smart glasses: The smart glasses consist of a frame, lenses, and functional modules; the temples of the frame have an arc-shaped curved surface structure. The functional module consists of a microprocessor, a display module, and a sensing module; the functional module is located inside the frame. The transparent organic photovoltaic module is integrated into the edge area of the smart glasses lens and the surface of the frame; the integration method is a ring-shaped arrangement at the lens edge and a temple arrangement; the ring width of the ring-shaped arrangement at the lens edge is 5mm; the temple arrangement method is that the transparent organic photovoltaic module and the curved surface of the temple are bonded together; the transparent organic photovoltaic modules in the ring-shaped arrangement at the lens edge and the temple arrangement are connected in parallel and then connected to the energy management system; The energy management system and transparent organic photovoltaic modules are connected to the functional modules.
[0078] A schematic diagram of the smart glasses provided in Example 3 of this invention is shown below. Figure 4 As shown. By Figure 4 It can be seen that the transparent organic photovoltaic modules in the self-powered system are mainly concentrated in the edge area of the smart glasses lens and the surface of the frame; the functional modules are located inside the frame.
[0079] Test Example 3 Set at standard high intensity light 1000W / m 2 Below, the energy storage unit is a 3.7V / 150mAh lithium polymer soft-pack battery (nominal capacity 0.555Wh, adapted to the curved space of the temples). Area of a single piece: 0.03m × 0.04m = 1.2 × 10 -3 m 2 , Total paving area: 2 patches × 1.2 × 10⁻³ = 2.4 × 10 -3 m 2 , Theoretical peak power (Pmax) = area × 1000 W / m 2 ×efficiency (7%) = 2.4 × 10 -3 ×1000×0.07=0.168W; In actual scenarios where curved temple surfaces are fitted together, non-noon solar incidence angles lead to coupling losses. The measured maximum output power (after voltage regulation by the energy management system) is as follows: P actual peak value = 0.168W × 92% (MPPT) × 95% (curved optocoupler) ≈ 0.147W Daily power generation (conservatively estimated based on the national average effective sunshine duration of 4 hours / day from 10:00 to 14:00) = 0.147W × 4h = 0.588Wh. Average daily power consumption (based on 10 message notifications per hour and a cumulative screen-on time of 20 seconds): 28mW Daily consumption: 28mW × 24h = 0.672Wh Charging capacity: On a standard day with strong sunlight, the energy required to charge from 20% to 80% is: 0.555Wh × (80% - 20%) = 0.333Wh. Net charging power: 0.147W - 0.028W = 0.119W Theoretically required time: 0.333Wh ÷ 0.119W = 2.79h It only takes 2.79 hours (10:00~12:50) to charge the battery from 20% to over 80%; Battery life, when the battery is fully charged: Starting from 100% (0.555Wh), powered solely by the battery (without sunlight): battery life = 0.555Wh ÷ 0.028W = 19.8h (approximately 20h). Starting from 80% (0.444Wh) (the starting point of your daily cycle): Battery life = 0.444Wh ÷ 0.028W = 15.9h (approximately 16h).
[0080] As can be seen, the self-powered system of integrated transparent organic photovoltaic provided in Embodiment 3 of the present invention, when used in smart glasses, has a short charging time and a long battery life.
[0081] The above description is only a preferred embodiment of the present invention. It should be noted that for those skilled in the art, several improvements and modifications can be made without departing from the principle of the present invention, and these improvements and modifications should also be considered within the scope of protection of the present invention.
Claims
1. A self-powered system integrating transparent organic photovoltaics, comprising transparent organic photovoltaic modules and an energy management system; The transparent organic photovoltaic module comprises, from bottom to top, a substrate, a transparent electrode layer, a first transport layer, an organic active layer, a second transport layer, a top electrode, and a weather-resistant encapsulation layer; The energy management system includes a power conversion module, an energy management controller, and an energy storage unit.
2. The self-powered system according to claim 1, characterized in that, The substrate is either a rigid transparent substrate or a flexible transparent substrate.
3. The self-powered system according to claim 1, characterized in that, The transparent electrode layer is an ITO and Ag composite conductive material; the ITO and Ag composite conductive material includes an ITO bottom layer + an Ag ultrathin layer or an ITO bottom layer + an Ag ultrathin layer + an ITO top layer.
4. The self-powered system according to claim 3, characterized in that, The thickness of the ITO bottom layer is 50~150nm; the thickness of the Ag ultrathin layer is 8~12nm; and the thickness of the ITO top layer is 30~50nm.
5. The self-powered system according to claim 1, characterized in that, The organic active layer comprises a narrow bandgap conjugated polymer and a non-fullerene acceptor, wherein the mass ratio of the narrow bandgap conjugated polymer to the non-fullerene acceptor is (1~3):(1~3).
6. The self-powered system according to claim 5, characterized in that, The narrow bandgap conjugated polymer is one or more of PTB7-Th, PBDB-T, PM6, and D18.
7. The self-powered system according to claim 5, characterized in that, The non-fullerene acceptors are perylene diimides, ITIC series, or Y6 series; the perylene diimides are one or more of TBDPDI-C5, TBDPDI-C11, SdiPDI, PFPDI-TT, and PFPDI-T; the ITIC series are one or more of ITIC-Th1, ITIC-Th2, ITIC-Th3, ITIC-2Cl-δ, ITIC-2Cl-γ, ITIC-2Cl-β, α-ITIC-2Cl, IDIC, and IT4F; and the Y6 series are one or more of Y6, L8-BO, L8-HD, L8-OD, BTP-eC9, BTP-Cy-4F, BTP-Cy-4Cl, Y6-PhC6, Y6-nC8, Y6-phOC6, and Y6-NO2.
8. The self-powered system according to claim 1, characterized in that, The thickness of the first transport layer is 15~30nm, and the thickness of the second transport layer is 15~30nm.
9. The application of the self-powered system of integrated transparent organic photovoltaic as described in any one of claims 1 to 8 in smart devices.
10. The application according to claim 9, characterized in that, The smart devices mentioned are smart food delivery lockers, outdoor sightseeing elevators, or smart glasses.