A novel anti-counterfeiting transfer material and a preparation method thereof
Patent Information
- Application Number
- CN202611123760.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2026-07-28
- Publication Date
- 2026-10-27
AI Technical Summary
但由于现有技术限制,传统防伪转移材料热烫印后分离层与聚酯薄膜分离,无法实现制备过程中聚酯薄膜、分离层的重复利用;同时传统防伪转移材料制备环节全息防伪层需要在涂覆加热固化后再进行高温模压,不仅影响制备效率、造成能耗浪费,而且全息防伪涂料在涂覆过程有机溶剂使用量大,不够环保
[0006]本发明与现有技术相比,不仅实现了聚酯薄膜、分离层的重复利用,而且制备环节更加高效、环保,同时所制产品具有绚丽的全息防伪效果。
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Abstract
Description
Technical Field
[0001] This invention relates to a novel anti-counterfeiting transfer material and its preparation method, belonging to the field of holographic anti-counterfeiting technology. This invention not only achieves the reuse of polyester film and separation layer in the preparation process of the anti-counterfeiting transfer material, but also makes the preparation process more efficient and environmentally friendly, while the resulting product has a stunning holographic anti-counterfeiting effect. Background Technology
[0002] Anti-counterfeiting transfer materials are heat transfer materials composed of multiple layers of coatings with different functions. Due to their holographic anti-counterfeiting graphic effects and ease of use, they have been widely used in various anti-counterfeiting labels, daily chemical consumer goods, and gift boxes in recent years, and are gradually expanding into high-end labeling fields such as consumer electronics and chips. However, due to current technological limitations, the release layer of traditional anti-counterfeiting transfer materials separates from the polyester film after heat stamping, making it impossible to reuse the polyester film and release layer during the preparation process. Furthermore, in the traditional anti-counterfeiting transfer material preparation process, the holographic anti-counterfeiting layer needs to be coated, heated, cured, and then subjected to high-temperature molding, which not only affects preparation efficiency and wastes energy, but also uses a large amount of organic solvents during the coating process, making it less environmentally friendly. In addition, traditional anti-counterfeiting transfer materials often use a single-color holographic anti-counterfeiting layer as the carrier of graphic information, lacking color variability, resulting in a relatively monotonous holographic anti-counterfeiting effect, and also lacking the ability to display in dark environments. Therefore, the ability to reuse polyester film and separation layer in the preparation of anti-counterfeiting transfer materials makes the preparation process more efficient and environmentally friendly, while also giving the finished products a stunning holographic anti-counterfeiting effect. This represents a breakthrough technological innovation for existing technologies and aligns with industry development trends. Summary of the Invention
[0003] The purpose of this invention is to provide a novel anti-counterfeiting transfer material and its preparation method, in which the polyester film and separation layer can be reused during the preparation process, the preparation process is more efficient and environmentally friendly, and it also has a brilliant holographic anti-counterfeiting effect.
[0004] To achieve the above objectives, the technical solution adopted by the present invention is as follows: A novel anti-counterfeiting transfer material is characterized by its structure comprising, in sequence, a polyester film, a release layer, a holographic anti-counterfeiting layer, a color-changing layer, a metal plating layer, and a hot melt adhesive layer. The release layer has high transparency and, after curing, exhibits strong adhesion to the polyester film, making it difficult to detach or migrate from the polyester film surface. However, it can effectively separate from the holographic anti-counterfeiting layer under a certain peeling force. The holographic anti-counterfeiting layer can produce different holographic anti-counterfeiting graphics based on different holographic nickel plates, and can display hot stamping graphics and a glow-in-the-dark effect in dark environments. The color-changing layer not only produces a pearlescent luster and a color-changing effect depending on the viewing angle, with a dramatic color change when the viewing angle changes, but also helps to shape the grating graphics produced after molding the holographic anti-counterfeiting layer. The hot melt adhesive layer can melt rapidly at a certain temperature and effectively bond to the substrate under pressure. 1) The polyester film is a biaxially oriented BOPET film treated with corona discharge, with a surface tension of 53-56 dyn / cm and a thickness of 10-20 μm; 2) The release layer is obtained by coating the release agent using a coating machine; the release agent, by mass parts, comprises: 6-12 parts of ethylene-methacrylic acid copolymer, 5-8 parts of fluorosilicone modified acrylic resin, 1-3 parts of vinyl-terminated silicone oil, 0.5-2 parts of short-chain hydrogen-containing polysiloxane, 0.5-2 parts of titanate, 1-5 parts of silica powder, 15-30 parts of toluene, 10-25 parts of ethyl acetate, and 1-5 parts of isopropanol; The silica powder has an average particle size of 5-6 μm and a bulk density ≥0.32 g / cm³; the short-chain hydrogen-containing polysiloxane has an active hydrogen content of 1.0–1.2%. 3) The holographic anti-counterfeiting layer is made by applying a molding coating through a coating and molding machine, which involves extrusion coating, molding, and drying in an oven. The molding coating, by weight, comprises: 8-15 parts of low-viscosity unsaturated polyester resin, 5-10 parts of acrylic modified TPU, 3-8 parts of amino resin, 0.5-2 parts of phosphorescent powder, 0.5-3 parts of β-hydroxyalkylamide, 2-6 parts of hydroxyl-terminated polybutadiene, 0.5-2 parts of zinc stearate, 1-3 parts of hydroxypropyl methylcellulose, 5-20 parts of methyl ethyl ketone, 5-15 parts of n-propyl acetate, and 1-5 parts of isobutyl acetate. The coating and molding integrated machine comprises, in sequence, an extrusion coating unit, a molding unit, and a drying tunnel unit; the low-viscosity unsaturated polyester resin has a heat distortion temperature of 80-90℃ and an acid value of 20mgKOH / g; the acrylic-modified TPU has a molecular weight of 30000-35000 and a tensile strength of 40-43 MPa; the amino resin has a molecular weight of 20000-25000 and a Tg of 60℃; the phosphorescent powder has an average particle size of 3-5μm and an excitation wavelength of 200-450nm; the β-hydroxyalkylamide has a hydroxyl value of 750-760mgKOH / g; the hydroxyl-terminated polybutadiene has a molecular weight of 1500-2000 and an average functionality of 2.5; and the hydroxypropyl methylcellulose has a methoxyl content of approximately 20%. 4) The color-changing layer is obtained by coating the color-changing paint using a coating machine; the color-changing paint comprises, by weight parts: 6-15 parts acrylic resin, 3-8 parts phenolic resin, 2-5 parts photochromic dye, 1-3 parts titanium dioxide powder, 0.5-2 parts mica powder, 10-30 parts ethyl acetate, 5-10 parts methyl ethyl ketone, and 2-8 parts pentanone. The acrylic resin has a hydroxyl value of 55-60 mg KOH / g and a Tg of 55℃; the phenolic resin has a molecular weight of 20,000-25,000 and a hydroxymethyl content of 16%, and can be rapidly cured by heat to form a dense three-dimensional network structure; the photochromic dye is a dichroic dye with a temperature resistance of 250℃ and an average particle size of 2-3 μm; the titanium dioxide powder has a refractive index of 2.8-2.9 and an average particle size of 0.15–0.20 μm; the mica powder is colorless and transparent muscovite with an iron content of <0.15% and an average particle size of 10-15 μm. 5) The metal coating is obtained by vapor deposition of metal material using a vacuum coating equipment; The metallic material is a high refractive index material, and is any one of Al, Ni or Cu with a purity of 99.9% or higher; 6) The hot melt adhesive layer is obtained by coating the hot melt adhesive coating using a coating machine; the hot melt adhesive coating comprises, by weight parts: 5-15 parts polyamide resin, 5-10 parts rosin-modified alkylphenol resin, 3-8 parts ethylene-acrylic resin, 1-3 parts rosin glycerol ester, 1-3 parts pentaerythritol ester, 3-6 parts hydrophobic nano silica powder, 15-35 parts toluene, 10-30 parts ethyl acetate, and 2-6 parts n-butyl acetate; The polyamide resin has a soft point of 65-70℃, a molecular weight of 30,000-35,000, and an equilibrium water absorption rate of <1%; the rosin-modified alkylphenol resin has an acid value of 25 mg KOH / g; the ethylene-acrylic acid resin has a softening point of 77-79℃ and a Tg of around 45℃; and the hydrophobic nano-silica powder has an average particle size of 30-35 nm and a specific surface area of 300-350 m² / g, which can significantly reduce the chance of the hot melt adhesive layer absorbing environmental moisture and negatively affecting adhesion and storage stability.
[0005] The method for preparing a novel anti-counterfeiting transfer material as described in claim 1 is characterized by comprising the following steps: 1) Using a coating machine, apply the release agent to the surface of the polyester film through a 280-300 mesh ceramic anilox roller. Control the oven temperature at (95-175) ±5℃ and the dry coating amount at 1.35-1.50 g / m². 2 A separation layer is obtained; 2) Using a coating and molding integrated machine, firstly, molding coating with a solid content of 50-80% is applied to the surface of the release layer by extrusion coating unit; then, holographic anti-counterfeiting images are imprinted using a holographic nickel plate in the molding unit; finally, the layer is thoroughly dried in the drying tunnel unit to obtain the holographic anti-counterfeiting layer; wherein, in the extrusion coating unit: by adjusting the pressure of the extrusion rollers, the dry coating amount of the holographic anti-counterfeiting layer is controlled at 1.55-1.80 g / m³. 2 Molding unit: set pressure 3-6 MPa, set roller temperature 70-90℃; Drying tunnel unit: control drying tunnel temperature (80-150) ±5℃; 3) Using a coating machine, apply the color-changing coating to the surface of the holographic anti-counterfeiting layer through a 230-250 mesh ceramic anilox roller, controlling the dry coating amount to 1.20-1.45 g / m². 2 Control the oven temperature to (85-160) ±5℃, and control the pressure roller linear pressure to 1.5-2.5 kN / cm. 4) Using vacuum coating equipment, uniformly deposit any one of Al, Ni or Cu with a purity of 99.9% or higher onto the surface of the color-changing layer, controlling the coating thickness between 550-650 angstroms to obtain a metal coating. 5) Using a coating machine, apply the hot melt adhesive coating to the metal plating surface through a 230-mesh ceramic anilox roller, controlling the dry coating amount to 1.35-1.60 g / m². 2 The temperature of the drying tunnel is controlled at (75-150) ±5℃ to obtain the hot melt adhesive layer.
[0006] Compared with existing technologies, this invention not only enables the reuse of polyester film and separation layer, but also makes the preparation process more efficient and environmentally friendly, while the resulting product has a stunning holographic anti-counterfeiting effect. Detailed Implementation
[0007] The present invention will be further described in detail below with reference to specific embodiments: Example
[0008] A novel anti-counterfeiting transfer material is characterized by comprising, in sequence, a polyester film, a release layer, a holographic anti-counterfeiting layer, a color-changing layer, a metal plating layer, and a hot melt adhesive layer. The release layer has high transparency and, after curing, exhibits strong adhesion to the polyester film, making it difficult to detach or migrate from the polyester film surface. However, it can effectively separate from the holographic anti-counterfeiting layer under a certain peeling force. The holographic anti-counterfeiting layer can produce different holographic anti-counterfeiting images and texts based on different holographic nickel plates, and can display hot stamping images and luminous effects in dark environments. The color-changing layer not only produces a pearlescent luster and a color-changing effect depending on the viewing angle, with a dramatic color change when the viewing angle changes, but also helps to shape the grating images produced after molding the holographic anti-counterfeiting layer. The hot melt adhesive layer can melt rapidly at a certain temperature and effectively bond to the substrate under pressure.
[0009] Prepare the required materials according to the table below: A method for preparing a novel anti-counterfeiting transfer material, the specific steps of which are as follows: 1) Using a coating machine, apply the release agent to the surface of the polyester film through a 280-300 mesh ceramic anilox roller. Control the oven temperature at (95-175) ±5℃ and the dry coating amount at 1.35-1.50 g / m². 2 A separation layer is obtained; 2) Using a coating and molding integrated machine, firstly, molding coating with a solid content of 50-80% is applied to the surface of the release layer by extrusion coating unit; then, holographic anti-counterfeiting images are imprinted using a holographic nickel plate in the molding unit; finally, the layer is thoroughly dried in the drying tunnel unit to obtain the holographic anti-counterfeiting layer; wherein, in the extrusion coating unit: by adjusting the pressure of the extrusion rollers, the dry coating amount of the holographic anti-counterfeiting layer is controlled at 1.55-1.80 g / m³. 2 Molding unit: set pressure 3 MPa, set roller temperature 75℃; Drying tunnel unit: control drying tunnel temperature (80-150) ±5℃; 3) Using a coating machine, apply the color-changing coating to the surface of the holographic anti-counterfeiting layer through a 230-250 mesh ceramic anilox roller, controlling the dry coating amount to 1.20-1.45 g / m². 2 Control the oven temperature to (85-160) ±5℃, and control the pressure roller linear pressure to 1.5-2.5 kN / cm. 4) Using vacuum coating equipment, Ni with a purity of 99.9% or higher is uniformly vapor-deposited onto the surface of the color-changing layer, and the coating thickness is controlled between 550-650 angstroms to obtain a metal coating. 5) Using a coating machine, apply the hot melt adhesive coating to the metal plating surface through a 230-mesh ceramic anilox roller, controlling the dry coating amount to 1.35-1.60 g / m². 2 The temperature of the drying tunnel is controlled at (75-150) ±5℃ to obtain the hot melt adhesive layer. Example
[0010] A novel anti-counterfeiting transfer material is characterized by comprising, in sequence, a polyester film, a release layer, a holographic anti-counterfeiting layer, a color-changing layer, a metal plating layer, and a hot melt adhesive layer. The release layer has high transparency and, after curing, exhibits strong adhesion to the polyester film, making it difficult to detach or migrate from the polyester film surface. However, it can effectively separate from the holographic anti-counterfeiting layer under a certain peeling force. The holographic anti-counterfeiting layer can produce different holographic anti-counterfeiting images and texts based on different holographic nickel plates, and can display hot stamping images and luminous effects in dark environments. The color-changing layer not only produces a pearlescent luster and a color-changing effect depending on the viewing angle, with a dramatic color change when the viewing angle changes, but also helps to shape the grating images produced after molding the holographic anti-counterfeiting layer. The hot melt adhesive layer can melt rapidly at a certain temperature and effectively bond to the substrate under pressure.
[0011] Prepare the required materials according to the table below: A method for preparing a novel anti-counterfeiting transfer material, the specific steps of which are as follows: 1) Using a coating machine, apply the release agent to the surface of the polyester film through a 280-300 mesh ceramic anilox roller. Control the oven temperature at (95-175) ±5℃ and the dry coating amount at 1.35-1.50 g / m². 2 A separation layer is obtained; 2) Using a coating and molding integrated machine, firstly, molding coating with a solid content of 50-80% is applied to the surface of the release layer by extrusion coating unit; then, holographic anti-counterfeiting images are imprinted using a holographic nickel plate in the molding unit; finally, the layer is thoroughly dried in the drying tunnel unit to obtain the holographic anti-counterfeiting layer; wherein, in the extrusion coating unit: by adjusting the pressure of the extrusion rollers, the dry coating amount of the holographic anti-counterfeiting layer is controlled at 1.55-1.80 g / m³. 2 Molding unit: set pressure 6 MPa, set roller temperature 90℃; Drying tunnel unit: control drying tunnel temperature (80-150) ±5℃; 3) Using a coating machine, apply the color-changing coating to the surface of the holographic anti-counterfeiting layer through a 230-250 mesh ceramic anilox roller, controlling the dry coating amount to 1.20-1.45 g / m². 2Control the oven temperature to (85-160) ±5℃, and control the pressure roller linear pressure to 1.5-2.5 kN / cm. 4) Using vacuum coating equipment, Al with a purity of 99.9% or higher is uniformly vapor-deposited onto the surface of the color-changing layer, and the coating thickness is controlled between 550-650 angstroms to obtain a metallic coating. 5) Using a coating machine, apply the hot melt adhesive coating to the metal plating surface through a 230-mesh ceramic anilox roller, controlling the dry coating amount to 1.35-1.60 g / m². 2 The temperature of the drying tunnel is controlled at (75-150) ±5℃ to obtain the hot melt adhesive layer.
[0012] The novel anti-counterfeiting transfer material prepared through the above embodiments not only realizes the reuse of polyester film and separation layer, but also makes the preparation process more efficient and environmentally friendly. At the same time, the product has a brilliant holographic anti-counterfeiting effect.
[0013] Based on the test results: (1) Example 1 uses a polyester film with a thickness of 20μm, which is slightly thicker than conventional anti-counterfeiting transfer materials. It is more suitable for flatbed hot stamping and can adapt to hot stamping of large-area graphics and irregular substrate surfaces. The flatbed hot stamping temperature is controlled at 115-165℃ and the hot stamping pressure is controlled at 3-8Mpa. If rotary hot stamping is used, the hot stamping temperature needs to be controlled at 180-220℃ and the hot stamping pressure needs to be controlled at 2-4Mpa. The hot stamping speed is slower and it is only suitable for small-area graphics. The preparation process needs to pay attention to the following: The following points should be considered: In the release agent formulation, appropriately increasing the proportion of short-chain hydrogen-containing polysiloxanes and silica powder can enhance the coating's cohesion and improve surface openness; otherwise, the stability and transfer effect of the release layer will be affected. In the molding coating formulation, increasing the proportion of low-viscosity unsaturated polyester resin and decreasing the proportion of acrylic-modified TPU ensures that the prepared holographic anti-counterfeiting layer possesses both excellent molding performance and good physical stability. During the preparation of the holographic anti-counterfeiting layer, the molding unit should be set to a lower pressure and lower temperature; otherwise, "over-pressing" may occur. (1) The image causes occasional loss of holographic anti-counterfeiting effect or dark spots; (2) Example 2 uses a polyester film with a thickness of 10μm, which is thinner than conventional anti-counterfeiting transfer materials. It has a better heat transfer effect between each coating and is more suitable for rotary hot stamping. It can adapt to high-speed hot stamping of fine graphics and continuous lines on thin paper substrates. The rotary hot stamping temperature is controlled at 165-200℃ and the hot stamping pressure is controlled at 1.5-3.5Mpa. If flat hot stamping is used, the hot stamping temperature needs to be controlled at 105-155℃. The hot stamping pressure is controlled at 4-7 MPa, which is only suitable for hot stamping on conventional graphics and substrates. It is not suitable for hot stamping on large-area graphics or irregular substrates. The following points should be noted during the preparation process: Increase the proportion of acrylic-modified TPU and hydroxypropyl methylcellulose in the molding coating formula to give the holographic anti-counterfeiting layer after shaping, curing and cross-linking excellent edge cutting properties, so as to ensure the coating accuracy during the hot stamping process; During the preparation of the holographic anti-counterfeiting layer, the molding unit should be set with relatively high pressure and temperature, otherwise the holographic anti-counterfeiting effect will be unsatisfactory.
[0014] In addition, it should be noted that: (1) The molding coating adopts the extrusion coating method, which significantly reduces the amount of organic solvent used in the coating compared with the traditional anilox roller coating. This not only saves manufacturing costs but is also very environmentally friendly; (2) Regardless of the implementation method, the solid content of the molding coating needs to be controlled at 50-80%. If the solid content is too low, uneven coating is likely to occur after extrusion coating, and regular grating patterns cannot be formed after holographic nickel plate imprinting; if the solid content is too high, extrusion coating will be difficult, and the molding unit will also find it difficult to imprint complete grating patterns at a relatively low set temperature. It should also be noted that the following technical measures are taken in this invention: the release agent uses silica powder with an average particle size of 5-6 μm and a bulk density ≥0.32 g / cm³; the molding coating uses phosphorescent powder with an average particle size of 3-5 μm and an excitation wavelength of 200-450 nm; the color-changing coating uses photochromic dye with a temperature resistance of 250℃ and an average particle size of 2-3 μm; the titanium dioxide powder with a refractive index of 2.8-2.9 and an average particle size of 0.15–0.20 μm; the mica powder with an iron content of <0.15% and an average particle size of 10-15 μm; and the hot melt adhesive coating uses hydrophobic nano-silica powder with an average particle size of 30-35 nm and a specific surface area of 300–350 m² / g. These measures are mainly determined by comprehensively considering the application performance requirements.
[0015] The above description is merely a preferred embodiment of the present invention. It should be noted that those skilled in the art can make various modifications and variations to the present invention. Any modifications, equivalent substitutions, improvements, etc., made within the scope of the inventive concept of the present invention should be included within the protection scope of the present invention.
Claims
1. A novel anti-counterfeiting transfer material, characterized in that, The structure consists of, in sequence, a polyester film, a release layer, a holographic anti-counterfeiting layer, a color-changing layer, a metal plating layer, and a hot melt adhesive layer. The release layer has high transparency and, after curing, has strong adhesion to the polyester film, making it difficult to peel off or migrate from the polyester film surface. However, it can effectively separate from the holographic anti-counterfeiting layer under certain peeling force. The holographic anti-counterfeiting layer can produce different holographic anti-counterfeiting graphics based on different holographic nickel plates, and can display hot stamping graphics and a glow-in-the-dark effect in dark environments. The color-changing layer not only produces a pearlescent luster and a color-changing effect depending on the viewing angle, with a dramatic color change when the viewing angle changes, but also helps to shape the grating graphics produced after the holographic anti-counterfeiting layer is molded. The hot melt adhesive layer can melt rapidly at a certain temperature and effectively bond to the substrate under pressure. 1) The polyester film is a biaxially oriented BOPET film treated with corona discharge, with a surface tension of 53-56 dyn / cm and a thickness of 10-20 μm; 2) The release layer is obtained by coating the release agent using a coating machine; the release agent, by mass parts, comprises: 6-12 parts of ethylene-methacrylic acid copolymer, 5-8 parts of fluorosilicone modified acrylic resin, 1-3 parts of vinyl-terminated silicone oil, 0.5-2 parts of short-chain hydrogen-containing polysiloxane, 0.5-2 parts of titanate, 1-5 parts of silica powder, 15-30 parts of toluene, 10-25 parts of ethyl acetate, and 1-5 parts of isopropanol; The silica powder has an average particle size of 5-6 μm and a bulk density ≥0.32 g / cm³; the short-chain hydrogen-containing polysiloxane has an active hydrogen content of 1.0–1.2%. 3) The holographic anti-counterfeiting layer is made by applying a molding coating through a coating and molding machine, which involves extrusion coating, molding, and drying in an oven. The molding coating, by weight, comprises: 8-15 parts of low-viscosity unsaturated polyester resin, 5-10 parts of acrylic modified TPU, 3-8 parts of amino resin, 0.5-2 parts of phosphorescent powder, 0.5-3 parts of β-hydroxyalkylamide, 2-6 parts of hydroxyl-terminated polybutadiene, 0.5-2 parts of zinc stearate, 1-3 parts of hydroxypropyl methylcellulose, 5-20 parts of methyl ethyl ketone, 5-15 parts of n-propyl acetate, and 1-5 parts of isobutyl acetate. The coating and molding integrated machine comprises, in sequence, an extrusion coating unit, a molding unit, and a drying tunnel unit; the low-viscosity unsaturated polyester resin has a heat distortion temperature of 80-90℃ and an acid value of 20mgKOH / g; the acrylic-modified TPU has a molecular weight of 30000-35000 and a tensile strength of 40-43 MPa; the amino resin has a molecular weight of 20000-25000 and a Tg of 60℃; the phosphorescent powder has an average particle size of 3-5μm and an excitation wavelength of 200-450nm; the β-hydroxyalkylamide has a hydroxyl value of 750-760mgKOH / g; the hydroxyl-terminated polybutadiene has a molecular weight of 1500-2000 and an average functionality of 2.5; and the hydroxypropyl methylcellulose has a methoxyl content of approximately 20%. 4) The color-changing layer is obtained by coating the color-changing paint using a coating machine; the color-changing paint comprises, by weight parts: 6-15 parts acrylic resin, 3-8 parts phenolic resin, 2-5 parts photochromic dye, 1-3 parts titanium dioxide powder, 0.5-2 parts mica powder, 10-30 parts ethyl acetate, 5-10 parts methyl ethyl ketone, and 2-8 parts pentanone. The acrylic resin has a hydroxyl value of 55-60 mg KOH / g and a Tg of 55℃; the phenolic resin has a molecular weight of 20,000-25,000 and a hydroxymethyl content of 16%, and can be rapidly cured by heat to form a dense three-dimensional network structure; the photochromic dye is a dichroic dye with a temperature resistance of 250℃ and an average particle size of 2-3 μm; the titanium dioxide powder has a refractive index of 2.8-2.9 and an average particle size of 0.15–0.20 μm; the mica powder is colorless and transparent muscovite with an iron content of <0.15% and an average particle size of 10-15 μm. 5) The metal coating is obtained by vapor deposition of metal material using a vacuum coating equipment; The metallic material is a high refractive index material, and is any one of Al, Ni or Cu with a purity of 99.9% or higher; 6) The hot melt adhesive layer is obtained by coating the hot melt adhesive coating using a coating machine; the hot melt adhesive coating comprises, by weight parts: 5-15 parts of polyamide resin, 5-10 parts of rosin-modified alkylphenol resin, 3-8 parts of ethylene-acrylic resin, 1-3 parts of rosin glycerol ester, 1-3 parts of pentaerythritol ester, 3-6 parts of hydrophobic nano silica powder, 15-35 parts of toluene, 10-30 parts of ethyl acetate, and 2-6 parts of n-butyl acetate. The polyamide resin has a soft point of 65-70℃, a molecular weight of 30,000-35,000, and an equilibrium water absorption rate of <1%; the rosin-modified alkylphenol resin has an acid value of 25 mg KOH / g; the ethylene-acrylic acid resin has a softening point of 77-79℃ and a Tg of around 45℃; and the hydrophobic nano-silica powder has an average particle size of 30-35 nm and a specific surface area of 300-350 m² / g, which can significantly reduce the chance of the hot melt adhesive layer absorbing environmental moisture and negatively affecting adhesion and storage stability.
2. The method for preparing a novel anti-counterfeiting transfer material as described in claim 1, characterized in that, Includes the following steps: 1) Using a coating machine, apply the release agent to the surface of the polyester film through a 280-300 mesh ceramic anilox roller. Control the oven temperature at (95-175) ±5℃ and the dry coating amount at 1.35-1.50 g / m². 2 A separation layer is obtained; 2) Using a coating and molding integrated machine, firstly, molding coating with a solid content of 50-80% is applied to the surface of the release layer by extrusion coating unit; then, holographic anti-counterfeiting images are imprinted using a holographic nickel plate in the molding unit; finally, the layer is thoroughly dried in the drying tunnel unit to obtain the holographic anti-counterfeiting layer; wherein, in the extrusion coating unit: by adjusting the pressure of the extrusion rollers, the dry coating amount of the holographic anti-counterfeiting layer is controlled at 1.55-1.80 g / m³. 2 Molding unit: set pressure 3-6 MPa, set roller temperature 70-90℃; Drying tunnel unit: control drying tunnel temperature (80-150) ±5℃; 3) Using a coating machine, apply the color-changing coating to the surface of the holographic anti-counterfeiting layer through a 230-250 mesh ceramic anilox roller, controlling the dry coating amount to 1.20-1.45 g / m². 2 Control the oven temperature to (85-160) ±5℃, and control the pressure roller linear pressure to 1.5-2.5 kN / cm. 4) Using vacuum coating equipment, uniformly deposit any one of Al, Ni or Cu with a purity of 99.9% or higher onto the surface of the color-changing layer, controlling the coating thickness between 550-650 angstroms to obtain a metal coating. 5) Using a coating machine, apply the hot melt adhesive coating to the metal plating surface through a 230-mesh ceramic anilox roller, controlling the dry coating amount to 1.35-1.60 g / m². 2 The temperature of the drying tunnel is controlled at (75-150) ±5℃ to obtain the hot melt adhesive layer.
