Environment-friendly silicone rubber insulator cleaning and repairing protective agent, preparation method and application thereof

CN122979044APending Publication Date: 2026-10-27STATE GRID JIANGSU ELECTRIC POWER CO LTD +1
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Patent Information

Application Number
CN202610814191.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-06-08
Publication Date
2026-10-27

AI Technical Summary

Technical Problem

[0005]本发明提供一种环境友好型硅橡胶绝缘子清洁修复防护剂及其制备方法和应用,有效解决现有硅橡胶绝缘子清洗维护中存在的清洗剂VOC含量较高、环境友好性不足、对复杂污秽去除能力有限、与硅橡胶基材相容性不足、清洗后表面憎水性能恢复不稳定和抗再污染能力不足以及户外紫外、湿热环境下清洗修复后表面防护效果持续性不足等问题,实现硅橡胶绝缘子表面清洁、性能修复和防护的一体化处理

Benefits of technology

[0016]本发明的有益效果在于:本发明提供一种环境友好型硅橡胶绝缘子清洁修复防护剂及其制备方法和应用,相比现有人工擦拭、清水冲洗和传统清洗剂处理方式,本发明通过低浓度、低VOC基础溶剂体系与清洗剂、修复剂、表面防护剂及功能助剂的协同作用,在提高复杂污秽去除效率的同时,降低环境污染和人员健康风险,改善硅橡胶绝缘子清洗后表面微观缺陷,促进憎水性能恢复,增强表面防护和抗再污染能力,提高清洗修复后硅橡胶表面的耐紫外老化能力和长期防护稳定性,从而实现硅橡胶绝缘子绿色、高效、长效的清洁修复防护一体化维护。

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Abstract

The application discloses an environment-friendly silicone rubber insulator cleaning, repairing and protecting agent as well as a preparation method and application thereof, and belongs to the technical field of power equipment cleaning. The cleaning, repairing and protecting agent comprises the following components in percentage by mass: 90-96% of a base solvent, 1-3% of a cleaning agent, 0.5-2% of a repairing agent, 0.5-2% of a surface protecting agent and 0.1-0.5% of a functional additive, and the sum of the percentage by mass of the components is 100%. The cleaning agent comprises a fluorine-containing cleaning component and an organic silicon cleaning component. The repairing agent is one or more of a silane coupling agent, a siloxane repairing component and a polysiloxane repairing component. The surface protecting agent is one or more of SiO2, TiO2 and Al2O3 functional particles. The functional additive comprises a pH regulator and a dispersion stabilizer. The application can realize integrated treatment of the cleaning, performance repairing and protection of the surface of the silicone rubber insulator.
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Description

Technical Field

[0001] This invention belongs to the field of power equipment cleaning technology, and relates to a silicone rubber insulator cleaning agent, and more particularly to an environmentally friendly silicone rubber insulator cleaning, repair and protection agent, its preparation method and application. Background Technology

[0002] Silicone rubber insulators, as important external insulation components in power transmission and transformation systems, are widely used in outdoor substations, converter stations, and transmission lines. These insulators are exposed to the natural environment for extended periods, making them susceptible to various pollutants such as coastal salt spray, industrial dust, acidic and alkaline pollutants, and biological deposits in high-humidity environments. The adhesion of pollutants to the surface of silicone rubber insulators involves not only physical adsorption processes such as van der Waals forces, electrostatic adsorption, and capillary action, but also chemical bonding with active groups formed on the silicone rubber surface after aging. This results in a complex and firmly adhered contamination layer structure, making cleaning quite difficult.

[0003] Current maintenance methods for silicone rubber insulators mainly include manual wiping, rinsing with water, and treatment with traditional cleaning agents. Manual wiping and rinsing with water are inefficient, labor-intensive, and insufficient in removing stubborn dirt. Although traditional cleaning agents can remove surface contaminants to some extent, some cleaning agents have problems such as high volatile organic compound content, insufficient environmental friendliness, poor compatibility with silicone rubber substrates, and unstable recovery of the surface's hydrophobic properties after cleaning.

[0004] Furthermore, existing treatment methods primarily focus on cleaning, rarely considering the surface repair and recontamination protection of silicone rubber insulators after cleaning. During long-term operation, silicone rubber insulators may develop microscopic defects, decreased hydrophobicity, and an increased risk of re-contamination. If only surface contamination is removed without improving the microscopic condition and protective capabilities of the cleaned surface, the maintenance effect will be limited in duration and may still affect the long-term operational reliability of the insulators. Summary of the Invention

[0005] This invention provides an environmentally friendly cleaning, repair, and protective agent for silicone rubber insulators, its preparation method, and its application. It effectively solves the problems existing in the cleaning and maintenance of silicone rubber insulators, such as high VOC content of cleaning agents, insufficient environmental friendliness, limited ability to remove complex dirt, insufficient compatibility with silicone rubber substrates, unstable recovery of surface hydrophobic properties after cleaning, insufficient resistance to re-contamination, and insufficient sustainability of surface protection effect after cleaning and repair under outdoor ultraviolet and humid heat environments. It achieves integrated treatment of surface cleaning, performance repair, and protection of silicone rubber insulators.

[0006] To achieve the above objectives, the present invention adopts the following technical solution: In a first aspect, the present invention provides an environmentally friendly cleaning, repair, and protective agent for silicone rubber insulators, comprising the following components by mass percentage: 90-96% base solvent, 1-3% cleaning agent, 0.5-2% repair agent, 0.5-2% surface protectant, and 0.1-0.5% functional additives, wherein the sum of the mass percentages of each component is 100%; the cleaning agent includes fluorinated cleaning components and organosilicon cleaning components; the repair agent is one or more of silane coupling agents, siloxane repair components, and polysiloxane repair components; the surface protectant is one or more of SiO2, TiO2, and Al2O3 functional particles; and the functional additives include pH adjusters and dispersants.

[0007] To optimize the above technical solution, the specific measures also include: Furthermore, the base solvent is a mixed solvent system formed by glycerol and / or glycerol oligomers and water; the volume ratio of glycerol and / or glycerol oligomers to water is 1:3~5.

[0008] Furthermore, in the cleaning agent, the fluorinated cleaning component is one or more of short-chain fluorocarbon surfactants, fluorinated polyether surfactants, and perfluorobutyl sulfonate surfactants; the organosilicon cleaning component is one or more of polyether-modified polydimethylsiloxane, trisiloxane surfactants, and siloxane-polyether copolymers; the mass ratio of the fluorinated cleaning component to the organosilicon cleaning component is 1:0.5~3.

[0009] Furthermore, in the repair agent, the silane coupling agent is one or more of γ-aminopropyltriethoxysilane, γ-glycidoxypropyltrimethoxysilane, methyltrimethoxysilane, and vinyltriethoxysilane; the siloxane-based repair component is one or more of oligomethylsiloxane and hydroxyl silicone oil; and the polysiloxane-based repair component is one or more of hydroxyl-terminated polydimethylsiloxane and amino-modified polysiloxane.

[0010] Further, the particle size of the functional particles is 20nm to 200nm; the surface protective agent is two or three of the functional particles SiO2, TiO2, and Al2O3; when the surface protective agent includes the three functional particles SiO2, TiO2, and Al2O3, the mass ratio of SiO2, TiO2, and Al2O3 is 1~2:1~2:0.5~1.5; before preparing the silicone rubber insulator cleaning, repair, and protective agent, the functional particles are first subjected to dispersion and stabilization treatment; the dispersion and stabilization treatment is to perform surface coating, adsorption, or composite dispersion treatment on the functional particles by means of a cleaning agent, repair agent, and / or polymeric dispersion stabilizer.

[0011] Further, the dispersion stabilization treatment method is as follows: the functional particles are added to a mixed solvent of water and glycerol containing a polymeric dispersion stabilizer, dispersed under ultrasonic conditions of 300-500W for 10-20 min, and then dispersed under high shear at 8000-12000 r / min for 10-20 min to obtain a pre-dispersion of the functional particles with dispersion stabilization; the polymeric dispersion stabilizer is one or more of polyethylene glycol, polyvinylpyrrolidone, and sodium polyacrylate; the mass ratio of the functional particles, the polymeric dispersion stabilizer and the mixed solvent of water and glycerol is 1:0.05-0.2:5-20.

[0012] Furthermore, in the functional additives, the pH adjuster is one or more of citric acid, sodium citrate, sodium dihydrogen phosphate, disodium hydrogen phosphate, and triethanolamine; and the dispersing stabilizer is one or more of polyethylene glycol, polyvinylpyrrolidone, and sodium polyacrylate.

[0013] Furthermore, the functional additives also include weather-resistant synergistic additives, which are one or more of water-based hindered amine light stabilizers and water-based ultraviolet absorbers; the water-based hindered amine light stabilizers are one or more of piperidine hindered amine light stabilizers and triazine hindered amine light stabilizers; the water-based ultraviolet absorbers can be selected from one or more of benzophenone ultraviolet absorbers and benzotriazole ultraviolet absorbers.

[0014] Secondly, the present invention also provides a method for preparing the above-mentioned environmentally friendly silicone rubber insulator cleaning, repair, and protective agent, comprising the following steps: Step 1: Adding the raw materials of the base solvent to a stirring vessel and stirring at 300-500 r / min for 10-15 min at 25-35°C to form a base solvent; Step 2: Adding the raw materials of the cleaning agent to the base solvent and stirring at 500-800 r / min for 30-40 min at 30-40°C to uniformly disperse the fluorinated cleaning component and the organosilicon cleaning component in the base solvent to obtain a cleaning pre-dispersion liquid; Step 3: Adding the raw materials of the repair agent to the cleaning pre-dispersion liquid. Step 4: Add the surface protective agent that has undergone dispersion stabilization treatment to the cleaning and repair mixture, and perform composite dispersion by combining ultrasonic dispersion and high shear dispersion. The ultrasonic power is 300-500W, the high shear speed is 10000-15000r / min, the dispersion time is 20-30min, and the dispersion temperature does not exceed 40℃. Step 5: Add functional additives and adjust the pH of the system to 6.5-7.5. Continue stirring at 500-800r / min for 20-30min to complete the homogenization treatment and obtain the silicone rubber insulator cleaning, repair and protective agent.

[0015] Thirdly, the present invention also provides the application of the above-mentioned environmentally friendly silicone rubber insulator cleaning, repair and protection agent in the cleaning, repair or protection of silicone rubber insulators.

[0016] The beneficial effects of this invention are as follows: This invention provides an environmentally friendly cleaning, repair, and protective agent for silicone rubber insulators, its preparation method, and its application. Compared with existing manual wiping, water rinsing, and traditional cleaning agent treatment methods, this invention, through the synergistic effect of a low-concentration, low-VOC base solvent system with cleaning agents, repair agents, surface protectants, and functional additives, improves the efficiency of removing complex contaminants while reducing environmental pollution and human health risks. It also improves the microscopic defects on the surface of silicone rubber insulators after cleaning, promotes the recovery of hydrophobic properties, enhances surface protection and resistance to re-contamination, and improves the UV aging resistance and long-term protective stability of the silicone rubber surface after cleaning and repair. Thus, it achieves green, efficient, and long-lasting integrated maintenance of silicone rubber insulators through cleaning, repair, and protection. Detailed Implementation

[0017] The present invention will be further described in detail below through specific embodiments, but it should not be construed as limiting the scope of the subject matter of the present invention to the following embodiments. All technologies implemented based on the above content of the present invention fall within the scope of the present invention.

[0018] Unless otherwise specified, the experimental methods used in the following examples are conventional methods, and the reagents, methods and equipment used are conventional reagents, methods and equipment in this technical field.

[0019] This invention provides an environmentally friendly silicone rubber insulator cleaning, repair and protective agent, comprising the following components by mass percentage: 90-96% base solvent, 1-3% cleaning agent, 0.5-2% repair agent, 0.5-2% surface protective agent, and 0.1-0.5% functional additive, wherein the sum of the mass percentages of each component is 100%.

[0020] In some embodiments, the base solvent is a mixed solvent system formed by glycerol and / or glycerol oligomers and water. Preferably, the volume ratio of glycerol and / or glycerol oligomers to water is 1:3 to 5, so that glycerol and / or glycerol oligomers exist in the base solvent in a low concentration. This base solvent can reduce the risk of volatile organic compound release and improve the compatibility of the treatment agent with the silicone rubber substrate.

[0021] The cleaning agents include fluorinated cleaning components and silicone cleaning components.

[0022] In some embodiments, the fluorinated cleaning component is one or more of short-chain fluorocarbon surfactants, fluorinated polyether surfactants, and perfluorobutyl sulfonate surfactants, used to reduce the interfacial tension between the contaminant layer and the silicone rubber surface, enhancing the wetting, penetration, and peeling capabilities of the contaminant layer. The silicone cleaning component is one or more of polyether-modified polydimethylsiloxane, trisiloxane surfactants, and siloxane-polyether copolymers, used to improve the compatibility between the cleaning, repairing, and protective agent and the silicone rubber substrate, and to provide conditions for the uniform action of the repairing agent and the surface protective agent on the silicone rubber surface. Preferably, the mass ratio of the fluorinated cleaning component to the silicone cleaning component is 1:0.5~3, and the two work synergistically to give the cleaning, repairing, and protective agent both low interfacial tension and good silicone rubber surface spreading compatibility, thereby improving the penetration and peeling effect on the composite contaminant layer.

[0023] The repair agent is one or more of the following: silane coupling agent, siloxane repair component, and polysiloxane repair component; In some embodiments, the silane coupling agent is one or more of γ-aminopropyltriethoxysilane, γ-glycidoxypropyltrimethoxysilane, methyltrimethoxysilane, and vinyltriethoxysilane. The siloxane-based repair component is one or more of oligomethylsiloxane and hydroxyl silicone oil. The polysiloxane-based repair component is one or more of hydroxyl-terminated polydimethylsiloxane and amino-modified polysiloxane. The repair agent can form a low surface energy repair layer on the surface of the cleaned silicone rubber insulator, improving surface micro-defects caused by aging, dirt adhesion, or the cleaning process, and promoting the recovery of the hydrophobic properties of the silicone rubber insulator surface; simultaneously, the silane coupling agent can undergo adsorption, condensation, or coupling with the functional particles in the surface protective agent, improving the adhesion stability of the functional particles on the silicone rubber surface.

[0024] The surface protective agent is one or more functional particles selected from SiO2, TiO2, and Al2O3. It enhances the protective effect of the surface after cleaning and repair, reducing the likelihood of re-adhesion of contaminants. Specifically, SiO2 improves surface micro- and nano-roughness and resistance to re-contamination, TiO2 enhances the surface's photo-assisted degradation ability against organic contaminants, and Al2O3 improves the wear resistance and structural stability of the protective layer. The combination of these three components forms a composite protective layer on the surface of silicone rubber insulators, providing hydrophobic recovery, resistance to re-contamination, and weather protection.

[0025] Preferably, the surface protectant is two or three of the functional particles selected from SiO2, TiO2, and Al2O3. When the surface protectant includes the three functional particles SiO2, TiO2, and Al2O3, the mass ratio of SiO2, TiO2, and Al2O3 is 1~2:1~2:0.5~1.5.

[0026] In some implementations, the particle size of the functional particles is 20 nm to 200 nm.

[0027] In some embodiments, the functional particles undergo dispersion and stabilization treatment before the preparation of the silicone rubber insulator cleaning, repair, and protective agent. This dispersion and stabilization treatment involves surface coating, adsorption, or composite dispersion of the functional particles using a cleaning agent, repair agent, and / or polymeric dispersion stabilizer.

[0028] Preferably, the dispersion stabilization treatment method is as follows: Functional particles are added to a mixed solvent of water and glycerol containing a polymeric dispersion stabilizer, and dispersed under ultrasonic conditions of 300-500W for 10-20 min, followed by high-shear dispersion at 8000-12000 r / min for 10-20 min (allowing the polymeric dispersion stabilizer to be adsorbed or coated onto the surface of the functional particles), resulting in a pre-dispersion of functional particles with stable dispersion. The polymeric dispersion stabilizer is one or more of polyethylene glycol, polyvinylpyrrolidone, and sodium polyacrylate. Preferably, the mass ratio of functional particles, polymeric dispersion stabilizer, and the mixed solvent of water and glycerol is 1:0.05-0.2:5-20. The mixed solvent of water and glycerol is considered the base solvent, and its amount is included in the mass percentage of the base solvent.

[0029] Functional additives include pH adjusters and dispersants.

[0030] In some embodiments, the pH adjuster is one or more of citric acid, sodium citrate, sodium dihydrogen phosphate, disodium hydrogen phosphate, and triethanolamine, used to adjust the pH of the system to 6.5-7.5 to reduce adverse effects on the silicone rubber substrate. The dispersing stabilizer is one or more of polyethylene glycol, polyvinylpyrrolidone, and sodium polyacrylate, used to improve the dispersion uniformity of functional particles in the system and reduce the tendency of sedimentation and agglomeration during storage.

[0031] In some embodiments, the functional additives further include weather-resistant synergists, which are one or more of water-based hindered amine light stabilizers and water-based ultraviolet absorbers, used to improve the UV aging resistance and long-term protection capability of the silicone rubber insulator surface after cleaning and repair. The water-based hindered amine light stabilizer is one or more of piperidine-based hindered amine light stabilizers and triazine-based hindered amine light stabilizers; the water-based ultraviolet absorber can be selected from one or more of benzophenone-based ultraviolet absorbers and benzotriazole-based ultraviolet absorbers.

[0032] The preparation method of the above-mentioned environmentally friendly silicone rubber insulator cleaning, repair and protective agent includes the following steps: Step 1: Add the raw materials of the base solvent to the mixing tank and stir at 300-500 r / min for 10-15 min at 25-35℃ to form a uniform and transparent base solvent.

[0033] Step 2: Add the cleaning agent raw materials to the base solvent and stir at 500-800 r / min for 30-40 min at 30-40℃ to ensure uniform dispersion of the fluorinated cleaning component and the silicone cleaning component in the base solvent, thus obtaining a pre-dispersion cleaning solution. The fluorinated cleaning component reduces the interfacial tension of the system, while the silicone cleaning component further improves the spreading compatibility of the system on the silicone rubber surface, giving the resulting silicone rubber insulator cleaning, repair, and protective agent good wetting and penetration capabilities.

[0034] Step 3: Add the raw materials of the repair agent to the pre-dispersion cleaning solution, and continue stirring at 30~40℃ for 20~30 minutes to obtain the cleaning and repair mixture.

[0035] Step 4: Add the surface protective agent that has undergone dispersion stabilization treatment to the cleaning and repair mixture, and perform composite dispersion by combining ultrasonic dispersion and high shear dispersion. The ultrasonic power is 300~500W, the high shear speed is 10000~15000r / min, the dispersion time is 20~30min, and the dispersion temperature does not exceed 40℃. This allows the functional particles to be evenly distributed in the system under the action of the repair agent, thereby forming a continuous or semi-continuous composite protective structure on the surface of the silicone rubber insulator.

[0036] Step 5: Add functional additives and adjust the pH of the system to 6.5~7.5. Continue stirring at 500~800 r / min for 20~30 min to complete the homogenization process and obtain the silicone rubber insulator cleaning, repair and protection agent.

[0037] The above-mentioned environmentally friendly silicone rubber insulator cleaning, repair and protection agent is used for cleaning, repair or protection of silicone rubber insulators.

[0038] The technical solution of the present invention will be further described in detail below with reference to specific embodiments: Example 1 This embodiment provides an environmentally friendly silicone rubber insulator cleaning, repair and protective agent suitable for industrial complex pollution environments. By mass percentage, it includes the following components: 94.5% base solvent, 2.0% cleaning agent, 1.5% repair agent, 1.5% surface protectant and 0.5% functional additives.

[0039] The base solvent is a mixed solvent system of glycerol and / or glycerol oligomers with deionized water, in a volume ratio of 1:4. The cleaning agent is a compound system of short-chain fluorocarbon surfactants and polyether-modified polydimethylsiloxane, in a mass ratio of 1:1.5. The repair agent is a compound system of γ-aminopropyltriethoxysilane and hydroxyl-terminated polydimethylsiloxane. The surface protectant is a compound functional particle system of TiO2 and Al2O3, in a mass ratio of 1:1. Functional additives include sodium citrate, polyvinylpyrrolidone, and piperidine-based waterborne hindered amine light stabilizers.

[0040] Its preparation method includes the following steps: Step 1: Add glycerol and / or glycerol oligomer and deionized water to a stirred tank and stir for 12 minutes at 30°C and 400 r / min to obtain a homogeneous and transparent base solvent.

[0041] Step 2: Add cleaning agent to the obtained base solvent, stir and disperse at 35℃ and 700r / min for 35min to obtain cleaning pre-dispersion.

[0042] Step 3: Add the repair agent to the obtained cleaning pre-dispersion solution, and continue stirring for 25 minutes at 35℃ and 600r / min to obtain the cleaning and repair mixture.

[0043] Step 4: Add the surface protective agent that has been dispersed and stabilized to the obtained cleaning and repair mixture, and disperse it for 25 minutes using 400W ultrasonic power and 12000r / min high shear speed, while controlling the dispersion temperature to not exceed 40℃.

[0044] Step 5: Add functional additives, adjust the pH of the system to 7.0, and continue stirring at 600 r / min for 25 min to complete the homogenization process and obtain the cleaning, repair and protective agent.

[0045] The cleaning, repairing, and protective agent obtained in this embodiment is suitable for maintenance scenarios involving silicone rubber insulators with high levels of industrial dust, acidic and alkaline pollutants, and complex deposits. It exhibits good dirt removal capabilities, resistance to re-contamination, and dispersion stability.

[0046] Example 2 This embodiment provides an environmentally friendly silicone rubber insulator cleaning, repair and protective agent, which comprises the following components by weight percentage: 96.0% base solvent, 1.0% cleaning agent, 1.5% repair agent, 1.0% surface protectant and 0.5% functional additives.

[0047] The base solvent is composed of glycerol and / or glycerol oligomers and deionized water in a volume ratio of 1:3. The cleaning agent is a compound system of fluorinated polyether surfactant and siloxane-polyether copolymer in a mass ratio of 1:1. The repair agent is methyltrimethoxysilane. The surface protectant is a compound functional particle of SiO2 and Al2O3 in a mass ratio of 2:1. Functional additives include citric acid, sodium citrate, and polyethylene glycol.

[0048] Its preparation method includes the following steps: Step 1: Mix glycerol and / or glycerol oligomer with deionized water and stir for 10 min at 25°C and 300 r / min to obtain a homogeneous and transparent base solvent.

[0049] Step 2: Add cleaning agent to the obtained base solvent and disperse at 30℃ and 500r / min for 30min to obtain cleaning pre-dispersion.

[0050] Step 3: Add the repair agent to the obtained pre-dispersion cleaning solution, and continue stirring for 20 minutes at 30℃ and 500r / min to obtain the cleaning and repair mixture.

[0051] Step 4: Add a surface protectant to the obtained cleaning and repair mixture, and perform composite dispersion for 20 minutes using 300W ultrasonic power and 10000r / min high shear speed, with the dispersion temperature controlled at no more than 40℃.

[0052] Step 5: Add functional additives to the obtained dispersion, adjust the pH of the system to 7.2, and continue stirring at 500 r / min for 20 min to complete the homogenization process and obtain the cleaning, repair and protection agent.

[0053] The cleaning, repairing and protective agent obtained in this embodiment can still achieve good dirt removal, water repellency restoration and low VOC effect under the condition of low dosage of cleaning agent and surface protectant.

[0054] The above are merely preferred embodiments of the present invention. The scope of protection of the present invention is not limited to the above embodiments. All technical solutions falling within the scope of the present invention's concept are within the scope of protection of the present invention. It should be noted that for those skilled in the art, any improvements and modifications made without departing from the principle of the present invention should be considered within the scope of protection of the present invention.

Claims

1. An environmentally friendly cleaning, repair, and protective agent for silicone rubber insulators, characterized in that: It includes the following components by mass percentage: 90-96% base solvent, 1-3% cleaning agent, 0.5-2% repair agent, 0.5-2% surface protectant, and 0.1-0.5% functional additives, and the sum of the mass percentages of each component is 100%; The cleaning agent includes a fluorinated cleaning component and an organosilicon cleaning component; The repair agent is one or more of the following: silane coupling agent, siloxane repair component, and polysiloxane repair component; The surface protective agent is one or more of the functional particles of SiO2, TiO2, and Al2O3; The functional additives include pH adjusters and dispersant stabilizers.

2. The environmentally friendly silicone rubber insulator cleaning, repair, and protective agent according to claim 1, characterized in that: The base solvent is a mixed solvent system formed by glycerol and / or glycerol oligomers and water; the volume ratio of glycerol and / or glycerol oligomers to water is 1:3~5.

3. The environmentally friendly silicone rubber insulator cleaning, repair, and protective agent according to claim 1, characterized in that: In the cleaning agent, the fluorinated cleaning component is one or more of short-chain fluorocarbon surfactants, fluorinated polyether surfactants, and perfluorobutyl sulfonate surfactants; The organosilicon cleaning component is one or more of polyether-modified polydimethylsiloxane, trisiloxane surfactant, and siloxane-polyether copolymer; The mass ratio of the fluorine-containing cleaning component to the organosilicon cleaning component is 1:0.5~3.

4. The environmentally friendly silicone rubber insulator cleaning, repair, and protective agent according to claim 1, characterized in that: In the repair agent, the silane coupling agent is one or more of γ-aminopropyltriethoxysilane, γ-glycidoxypropyltrimethoxysilane, methyltrimethoxysilane, and vinyltriethoxysilane; The siloxane-based repair component is one or more of oligomethylsiloxane and hydroxyl silicone oil; The polysiloxane-based repair component is one or more of hydroxyl-terminated polydimethylsiloxane and amino-modified polysiloxane.

5. The environmentally friendly silicone rubber insulator cleaning, repair, and protective agent according to claim 1, characterized in that: The particle size of the functional particles is 20nm to 200nm; The surface protective agent is two or three of the functional particles of SiO2, TiO2, and Al2O3; When the surface protectant comprises three functional particles, SiO2, TiO2 and Al2O3, the mass ratio of SiO2, TiO2 and Al2O3 is 1~2:1~2:0.5~1.5; Before preparing the silicone rubber insulator cleaning, repair and protective agent, the functional particles are first subjected to dispersion and stabilization treatment; The dispersion stabilization treatment involves surface coating, adsorption, or composite dispersion of functional particles using cleaning agents, repair agents, and / or polymeric dispersion stabilizers.

6. The environmentally friendly silicone rubber insulator cleaning, repair, and protective agent according to claim 5, characterized in that: The dispersion stabilization treatment method is as follows: add the functional particles to a mixed solvent of water and glycerol containing a polymeric dispersion stabilizer, disperse under ultrasonic conditions of 300~500W for 10~20min, and then disperse under high shear of 8000~12000r / min for 10~20min to obtain a pre-dispersion of functional particles with dispersion stabilization. The polymeric dispersion stabilizer is one or more of polyethylene glycol, polyvinylpyrrolidone, and sodium polyacrylate. The mass ratio of the functional particles, the polymeric dispersant stabilizer, and the water and glycerol mixed solvent is 1:0.05~0.2:5~20.

7. The environmentally friendly silicone rubber insulator cleaning, repair, and protective agent according to claim 1, characterized in that: In the aforementioned functional additives, the pH adjuster is one or more of citric acid, sodium citrate, sodium dihydrogen phosphate, disodium hydrogen phosphate, and triethanolamine; The dispersion stabilizer is one or more of polyethylene glycol, polyvinylpyrrolidone, and sodium polyacrylate.

8. The environmentally friendly silicone rubber insulator cleaning, repair and protective agent according to claim 1, characterized in that: The functional additives also include weather-resistant synergists, which are one or more of water-based hindered amine light stabilizers and water-based ultraviolet absorbers. The aqueous hindered amine light stabilizer is one or more of piperidine-based hindered amine light stabilizers and triazine-based hindered amine light stabilizers; The aqueous ultraviolet absorber may be selected from one or more of benzophenone-based ultraviolet absorbers and benzotriazole-based ultraviolet absorbers.

9. The preparation method of the environmentally friendly silicone rubber insulator cleaning, repair and protective agent as described in any one of claims 1 to 8, characterized in that: Includes the following steps: Step 1: Add the raw materials of the base solvent to a stirred tank and stir at 300-500 r / min for 10-15 min at 25-35℃ to form the base solvent; Step 2: Add the raw materials of the cleaning agent to the base solvent, and stir at 500-800 r / min for 30-40 min at 30-40℃ to uniformly disperse the fluorine-containing cleaning component and the organosilicon cleaning component in the base solvent to obtain a cleaning pre-dispersion. Step 3: Add the raw materials of the repair agent to the pre-dispersed cleaning solution, and continue stirring at 30-40°C for 20-30 minutes to obtain the cleaning and repair mixture; Step 4: Add the surface protectant that has undergone dispersion stabilization treatment to the cleaning and repair mixture, and perform composite dispersion by combining ultrasonic dispersion and high shear dispersion, wherein the ultrasonic power is 300~500W, the high shear speed is 10000~15000r / min, the dispersion time is 20~30min, and the dispersion temperature does not exceed 40℃; Step 5: Add functional additives and adjust the pH of the system to 6.5~7.

5. Continue stirring at 500~800 r / min for 20~30 min to complete the homogenization process and obtain the silicone rubber insulator cleaning, repair and protection agent.

10. The application of the environmentally friendly silicone rubber insulator cleaning, repair and protection agent as described in any one of claims 1 to 8 in the cleaning, repair or protection of silicone rubber insulators.