A novel double-sided photo-thermal catalytic reactor
Patent Information
- Application Number
- CN202522269935.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2025-10-27
- Publication Date
- 2026-08-28
- Estimated Expiration
- 2035-10-27
AI Technical Summary
由于光能穿透催化剂床层的厚度有限,双侧光照设计可使催化剂床层两侧同时受光,显著提升光照利用率,因此成为高效光热催化反应的优选方案,例如,部分双侧光照反应器采用十字形结构,通过两侧通光口实现双向光照,以提高催化剂的光吸收效率,但是两通光口距离过短,光照升温和炉膛内部的高温都有可能影响窗口的密封性,不利于反应长期稳定的进行
[0020]1、本实用新型通过双侧导光柱对称照射与扁平状催化剂承载端的协同设计,实现了对催化剂的高效、均匀辐照,显著提升了光能利用效率和反应均匀性,T字型结构布局优化了进气、反应与排气路径,使气体流动更为顺畅,反应过程更为紧凑高效;
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Figure CN224686847U_ABST
Abstract
Description
Technical Field
[0001] This utility model relates to the field of photocatalysis technology, specifically to a novel double-sided photothermal catalytic reactor. Background Technology
[0002] Gas-solid phase photothermal catalysis is a catalytic chemical reaction carried out in a high-temperature gas phase environment in the presence of a solid catalyst. It is widely used in many important research fields such as carbon dioxide reduction, degradation of gaseous pollutants, nitrogen fixation, and methane oxidation. To meet the comprehensive requirements of light, heating, gas-solid phase contact and airtightness in the reaction process, researchers have developed a variety of tubular reactors. Their core differences are mainly reflected in the light irradiation method and the catalyst loading method.
[0003] Regarding illumination methods, existing reactors are mainly divided into two categories: single-sided illumination and double-sided illumination. Since light energy has limited penetration through the thickness of the catalyst bed, double-sided illumination design allows both sides of the catalyst bed to be illuminated simultaneously, significantly improving light utilization. Therefore, it has become the preferred solution for efficient photothermal catalytic reactions. For example, some double-sided illumination reactors adopt a cross-shaped structure, achieving bidirectional illumination through light-transmitting openings on both sides to improve the light absorption efficiency of the catalyst. However, if the distance between the two light-transmitting openings is too short, the temperature rise from illumination and the high temperature inside the furnace may affect the sealing of the window, which is not conducive to the long-term stable operation of the reaction.
[0004] Therefore, a novel double-sided photothermal catalytic reactor is needed to improve the above problems. Utility Model Content
[0005] Therefore, this invention provides a novel double-sided photothermal catalytic reactor to solve the above-mentioned problems in the prior art.
[0006] To achieve the above objectives, this utility model provides the following technical solution:
[0007] According to a first aspect of the present invention, a novel double-sided photothermal catalytic reactor includes:
[0008] The main structure is T-shaped, with an air intake at one end, which is connected to the interior of the main structure.
[0009] The exhaust structure is bolted to the lower end of the main structure.
[0010] A set of symmetrically arranged light guide columns, with the light guide columns on both sides distributed inside the two ends of the outer tube;
[0011] The catalyst tank has a flat support end at its upper end, which is located between the adjacent ends of the light guide columns on both sides. The catalyst tank is hollow inside, and the support end contains a catalyst.
[0012] A gas guide pipe is used to connect the catalyst tank and the exhaust structure, guiding the gas produced by the reaction to the exhaust structure for discharge. The gas guide pipe is connected to the bottom of the catalyst tank through a graphite sleeve.
[0013] Furthermore, the main structure includes an outer tube, which is a T-shaped and hollow tubular structure. Both ends of the outer tube are fixedly connected to irradiation ends, and the lower end of the outer tube is provided with a lower connecting end.
[0014] Furthermore, heat sinks are provided at both ends of the outer tube.
[0015] Furthermore, the ends of the two light guide pillars that are far apart have convex ends with a diameter larger than that of the light guide pillars, and a viewing window is provided on the outer side of the convex ends.
[0016] Furthermore, the interior of the window component is provided with a groove, and a sealing ring is provided inside the groove.
[0017] Furthermore, the exhaust structure includes a docking post, the upper end of which is provided with a docking ring that mates with the lower docking end. The docking post is hollow inside, and an exhaust component is inserted into the middle of the lower end of the docking post.
[0018] Furthermore, the exhaust component is hollow inside and has a temperature measuring protrusion at its lower end, and an exhaust protrusion is provided on the side of the exhaust component. Both the exhaust protrusion and the temperature measuring protrusion are connected to the interior of the exhaust component.
[0019] This utility model has the following advantages:
[0020] 1. This utility model achieves efficient and uniform irradiation of the catalyst through the synergistic design of symmetrical irradiation by double-sided light guide columns and flat catalyst support end, which significantly improves light energy utilization efficiency and reaction uniformity. The T-shaped structure layout optimizes the intake, reaction and exhaust paths, making the gas flow smoother and the reaction process more compact and efficient.
[0021] 2. This utility model enhances the system's thermal management capabilities by integrating heat sinks, ensuring long-term operational stability. It employs sealing connection methods such as graphite ferrules to ensure sealing reliability at high temperatures, enabling the reactor to possess excellent catalytic performance, operational stability, and ease of maintenance. Attached Figure Description
[0022] To more clearly illustrate the embodiments of this utility model or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings in the following description are merely exemplary, and those skilled in the art can derive other embodiments based on the provided drawings without creative effort.
[0023] The structures, proportions, sizes, etc. illustrated in this specification are only for the purpose of assisting those skilled in the art in understanding and reading the content disclosed herein, and are not intended to limit the implementation conditions of this utility model. Therefore, they have no substantial technical significance. Any modifications to the structure, changes in the proportional relationships, or adjustments to the size, without affecting the effects and purposes that this utility model can produce, should still fall within the scope of the technical content disclosed in this utility model.
[0024] Figure 1 An exploded schematic diagram of a novel double-sided photothermal catalytic reactor provided for some embodiments of this utility model.
[0025] Figure 2 This is a three-dimensional structural schematic diagram of a novel double-sided photothermal catalytic reactor provided for some embodiments of the present invention.
[0026] Figure 3 This is a cross-sectional view of a novel double-sided photothermal catalytic reactor provided for some embodiments of the present invention.
[0027] In the figure: 1. Outer tube body; 2. Heat sink; 3. Irradiation end; 4. Air inlet end; 5. Lower docking end; 6. Docking ring; 7. Exhaust component; 8. Air outlet protrusion; 9. Temperature measuring protrusion; 10. Light guide column; 11. Viewing window component; 12. Catalyst tank; 13. Air guide pipe; 14. Docking column; 15. Sealing ring; 16. Connector. Detailed Implementation
[0028] The following specific embodiments illustrate the implementation of this utility model. Those skilled in the art can easily understand other advantages and effects of this utility model from the content disclosed in this specification. Obviously, the described embodiments are only some, not all, of the embodiments of this utility model. Based on the embodiments of this utility model, all other embodiments obtained by those skilled in the art without creative effort are within the protection scope of this utility model.
[0029] Example 1
[0030] like Figures 1 to 3As shown, a novel double-sided photothermal catalytic reactor according to the first aspect of this utility model includes a main structure, which is T-shaped and mainly consists of an outer tube 1. The outer tube 1 serves as the core support and sealing cavity, and its interior is hollow. At each of the two ends of the T-shape, an irradiation end 3 is fixedly connected, forming a channel for light to enter the reactor. An air inlet end 4 is provided at one end of the main structure, which communicates with the internal cavity of the main structure, allowing the reaction gas to enter the system. The exhaust structure is bolted to the main structure. The lower end is fitted with a symmetrically arranged set of light guide columns 10, with the two light guide columns 10 distributed inside the two ends of the outer tube body 1; the catalyst tank 12, the upper end of which is provided with a flat bearing end, the bearing end is located between the adjacent ends of the two light guide columns 10, the inside of the catalyst tank 12 is hollow, and the bearing end is provided with catalyst; the gas guide pipe 13 is used to connect the catalyst tank 12 and the exhaust structure, and guides the gas generated by the reaction to the exhaust structure for discharge, the gas guide pipe 13 is connected to the bottom of the catalyst tank 12 through a graphite sleeve.
[0031] In the above embodiments, it should be noted that, considering the heat generated during the photothermal catalysis process, in order to ensure the long-term stable operation of the reactor, multiple sets of heat sinks 2 are provided on the tube walls at both ends of the outer tube 1, especially in the area near the irradiation end 3. These heat sinks 2 can effectively increase the heat dissipation area, accelerate heat dissipation, and prevent damage to optical elements or impact on the catalytic reaction due to excessive temperature. On the inner side of the two irradiation ends 3, i.e., inside the outer tube 1, a set of light guide columns 10 are symmetrically arranged. The function of the light guide columns 10 is to conduct and converge the light introduced from the irradiation end 3. Each light guide column 10 has a larger diameter protrusion at the end away from the center, which helps in the reception of light and stable installation.
[0032] The technical effect achieved by the above embodiment is as follows: a window 11 is provided on the outer side of the protrusion. The window 11 not only plays a sealing role to prevent gas leakage, but also protects the internal light guide column 10 from contamination. In order to ensure the sealing of the connection between the window 11 and the irradiation end 3, a sealing ring 15 is embedded in the groove opened inside the window 11.
[0033] The core area where the catalytic reaction occurs is the catalyst tank 12, which is hollow inside and has a flat support end at its upper end. This flat support end is precisely positioned between the adjacent ends of the two light guide columns 10, so that the light emitted from the two light guide columns 10 can evenly and concentratedly illuminate the support end. The catalyst is placed inside the support end. During operation, the reaction gas introduced from the gas inlet 4 flows over the catalyst surface and undergoes a photothermal catalytic reaction under the illumination of the light from both sides and the action of the catalyst.
[0034] Example 2
[0035] like Figures 1 to 3 As shown, a novel double-sided photothermal catalytic reactor includes all the components of Example 1, except that a dedicated flow guiding and exhaust structure is provided for efficient collection of the gaseous products generated in the reaction. At the bottom of the catalyst tank 12, a gas guide pipe 13 is connected via a graphite sleeve. The graphite sleeve has good high-temperature resistance and sealing performance, and can adapt to the working environment inside the reactor. The other end of the gas guide pipe 13 extends downwards and connects to the exhaust structure.
[0036] The technical effect achieved by the above embodiment is as follows: the exhaust structure is tightly connected to the lower docking end 5 at the lower end of the main structure by bolts. The exhaust structure mainly includes a docking column 14, the upper end of which is provided with a docking ring 6 that matches the lower docking end 5 to ensure a stable and sealed connection. The docking column 14 is hollow inside, forming a gas collection cavity. An exhaust component 7 is inserted into the middle of its lower end. The gas generated by the reaction first enters the internal cavity of the docking column 14 through the gas guide pipe 13, and then flows into the exhaust component 7. The exhaust component 7 is also hollow inside, and its side is provided with an outlet protrusion 8 for discharging the final product gas out of the reactor.
[0037] Example 3
[0038] like Figures 1 to 3 As shown, a novel double-sided photothermal catalytic reactor is included in all the contents of Example 1. The difference is that, in order to monitor the reaction temperature, a temperature measuring protrusion 9 is provided at the lower end of the exhaust component 7, which can be used to install a temperature sensor to monitor the temperature of the exhaust gas in real time and provide a reference for controlling the reaction conditions.
[0039] Working principle: The reactant gas enters the outer tube 1 from the inlet end 4 and comes into contact with the catalyst on the supporting end of the catalyst tank 12. At the same time, light emitted from an external light source enters from the irradiation ends 3 on both sides, is conducted and converged by the light guide column 10, and simultaneously irradiates the catalyst from both sides, stimulating the photothermal catalytic reaction. The gaseous products generated by the reaction are discharged through the gas guide pipe 13 at the bottom of the catalyst tank 12, enter the exhaust structure below, and are finally discharged from the gas outlet protrusion 8 on the side of the exhaust component 7. Throughout the process, the double-sided illumination ensures uniform heating and photoexcitation of the catalyst, the flat supporting end increases the illumination area and gas contact area, and the T-shaped structure rationally plans the gas path and light path, making the reactor structure compact and highly efficient.
[0040] Although the present invention has been described in detail above with general descriptions and specific embodiments, some modifications or improvements can be made to it, which will be obvious to those skilled in the art. Therefore, all such modifications or improvements made without departing from the spirit of the present invention fall within the scope of protection claimed by the present invention.
[0041] The terms such as "upper," "lower," "left," "right," and "middle" used in this specification are merely for clarity of description and are not intended to limit the scope of implementation of this utility model. Any changes or adjustments to their relative relationships, without substantially altering the technical content, shall also be considered within the scope of implementation of this utility model.
Claims
1. A novel double-sided photothermal catalytic reactor, characterized in that, include: The main structure is T-shaped, and an air inlet (4) is provided at one end of the main structure. The air inlet (4) is connected to the interior of the main structure. The exhaust structure is bolted to the lower end of the main structure. A set of symmetrically arranged light guide columns (10) are distributed inside both ends of the outer tube (1); Catalyst tank (12), the upper end of the catalyst tank (12) is provided with a flat bearing end, the bearing end is located between the adjacent ends of the light guide columns (10) on both sides, the inside of the catalyst tank (12) is hollow, and the bearing end is provided with a catalyst; The gas guide pipe (13) is used to connect the catalyst tank (12) and the exhaust structure to guide the gas generated by the reaction to the exhaust structure for discharge. The gas guide pipe (13) is connected to the bottom of the catalyst tank (12) through a graphite sleeve.
2. The novel double-sided photothermal catalytic reactor according to claim 1, characterized in that: The main structure includes an outer tube (1), which is a T-shaped and hollow tubular structure. Both ends of the outer tube (1) are fixedly connected to irradiation ends (3), and the lower end of the outer tube (1) is provided with a lower docking end (5).
3. The novel double-sided photothermal catalytic reactor according to claim 2, characterized in that: Heat sinks (2) are provided at both ends of the outer tube (1).
4. The novel double-sided photothermal catalytic reactor according to claim 2 or 3, characterized in that: The two light guide pillars (10) have a convex end at one end that is far apart from each other. The diameter of the convex end is larger than the diameter of the light guide pillar (10), and a window (11) is provided on the outside of the convex end.
5. The novel double-sided photothermal catalytic reactor according to claim 4, characterized in that: The window component (11) has a groove inside, and a sealing ring (15) is provided inside the groove.
6. The novel double-sided photothermal catalytic reactor according to any one of claims 1-3 and 5, characterized in that: The exhaust structure includes a docking column (14), and the upper end of the docking column (14) is provided with a docking ring (6) that engages with the lower docking end (5). The docking column (14) is hollow inside, and an exhaust component (7) is inserted into the middle of the lower end of the docking column (14).
7. The novel double-sided photothermal catalytic reactor according to claim 6, characterized in that: The exhaust component (7) is hollow inside and has a temperature measuring protrusion (9) at its lower end. The exhaust component (7) also has an air outlet protrusion (8) on its side. Both the air outlet protrusion (8) and the temperature measuring protrusion (9) are connected to the interior of the exhaust component (7).