A complete equipment for synergic treatment and resource utilization of gasification fine slag and desizing slag
Patent Information
- Application Number
- CN202522394363.4
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2025-11-11
- Publication Date
- 2026-10-27
- Estimated Expiration
- 2035-11-11
AI Technical Summary
[0002]气化细渣与退浆渣是两种典型的工业固废,其中气化细渣是煤炭在气化炉中高温气化后经除尘系统收集得到的细微颗粒物,退浆渣是纺织行业在退浆工序产生的高浓度有机废水经预处理后形成的固体或半固体废弃物,它们的传统处置方式均存在资源浪费和环境污染风险
1.通过转换模块将经过第一固液分离装置分离后的酸渣制备成硅酸钠粗液,使得外部碱液与酸渣在碱溶反应装置中进行充分混合反应,然后通过第二固液分离装置进行碱液和碱渣的分离,让固液分离后的硅酸钠粗液通过硅酸钠粗液管路输送至胶黏剂制备装置中,以实现自产胶黏剂作为后续制备碳基吸附剂的原料,通过结构集成与流程优化,将气化细渣和退浆渣均在系统内转化为原料或产品,实现气化细渣和退浆渣两种固废的协同处理,从而实现双固废处理过程中内循环与近零排放,并且提升了设备的处理效率与控制精度,为双固废资源化利用提供了可行路径。
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Figure CN224895192U_ABST
Abstract
Description
Technical Field
[0001] This application relates to the technical field of industrial solid waste resource utilization, and in particular to a complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag. Background Technology
[0002] Gasification slag and desizing slag are two typical industrial solid wastes. Gasification slag is the fine particulate matter collected by the dust removal system after coal is gasified at high temperature in a gasifier. Desizing slag is a solid or semi-solid waste formed after pretreatment of high-concentration organic wastewater generated in the desizing process in the textile industry. Their traditional disposal methods both involve resource waste and environmental pollution risks.
[0003] Because gasification slag and textile desizing slag have different properties, manufacturers usually process and recycle them separately. Manufacturers need to develop different treatment plans to achieve the reuse of coal gasification slag and textile desizing slag. This results in low integration between the treatment equipment for the two types of solid wastes and insufficient overall system coordination. At the same time, there is a lack of material circulation design throughout the entire process, which leads to a large consumption of fresh raw materials during the production process. This restricts the industrial application and economic benefits of the dual solid waste co-resource utilization technology. Utility Model Content
[0004] In order to achieve the co-processing of coal gasification slag and textile desizing slag, this application provides a complete set of equipment for the co-processing and resource utilization of gasification slag and desizing slag.
[0005] This application provides a complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag, which adopts the following technical solution: A complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag includes a deslurry slag treatment module and a gasification fine slag treatment module. The deslurry slag treatment module is used to prepare a carbon-based adsorbent after processing the deslurry slag, and the gasification fine slag treatment module is used to prepare a coagulant after processing the gasification fine slag. The gasification fine slag treatment module includes an acid leaching reaction device and a first solid-liquid separation device, in which the first solid-liquid separation device performs solid-liquid separation on the acid leaching liquid after processing by the acid leaching reaction device. The deslurry slag treatment module includes an ultrafiltration device and an adhesive preparation device. The adhesive preparation device is used to prepare adhesive from PVA concentrate separated by an ultrafiltration device. It also includes a conversion module for preparing crude sodium silicate solution from the acid residue after solid-liquid separation. The conversion module includes an alkali dissolution reaction device and a second solid-liquid separation device. The alkali dissolution reaction device is provided with an alkali inlet for supplying external alkali solution. The second solid-liquid separation device is provided with a crude sodium silicate solution pipeline connected to the adhesive preparation device. The second solid-liquid separation device is used to transport the crude sodium silicate solution after solid-liquid separation to the adhesive preparation device.
[0006] By adopting the above technical solution, the acid slag separated by the first solid-liquid separation device is prepared into crude sodium silicate solution through a conversion module. This allows the external alkaline solution and acid slag to be fully mixed and reacted in the alkaline dissolution reaction device. Then, the alkaline solution and alkaline slag are separated by the second solid-liquid separation device. The crude sodium silicate solution after solid-liquid separation is then transported to the adhesive preparation device through the crude sodium silicate solution pipeline, so as to realize the self-produced adhesive as a raw material for the subsequent preparation of carbon-based adsorbents. Through structural integration and process optimization, both gasification fine slag and desizing slag are converted into raw materials or products within the system, realizing the synergistic treatment of the two solid wastes, thereby achieving internal circulation and near-zero emissions in the dual solid waste treatment process. This also improves the equipment's processing efficiency and control precision, providing a feasible path for the resource utilization of dual solid wastes.
[0007] Optionally, the first solid-liquid separation device has an acid slag outlet, the alkali dissolution reaction device has an alkali-soluble solid inlet, and a second conveying mechanism is provided between the first solid-liquid separation device and the alkali dissolution reaction device. The second conveying mechanism is used to convey the acid slag from the acid slag outlet to the alkali-soluble solid inlet.
[0008] By adopting the above technical solution, a second conveying mechanism is provided between the first solid-liquid separation device and the alkali dissolution reaction device, so that the second conveying mechanism can transport the acid slag from the acid slag outlet to the alkali dissolution solid feed inlet, thereby realizing the utilization of the acid slag generated during the gasification fine slag treatment process. The acid slag can enter the conversion module to provide raw materials for the preparation of sodium silicate crude solution, reducing the steps required for manufacturers to process acid slag and bringing higher economic benefits.
[0009] Optionally, the desizing slag treatment module further includes a granulation device and a curing device. The granulation device is used to mix the adhesive prepared by the desizing slag treatment module and the alkali slag separated by the second solid-liquid separation device in proportion and then granulate them. The curing device is used to cure the carbon-based adsorbent.
[0010] By adopting the above technical solution, the alkaline slag generated by the conversion module and the self-produced adhesive are mixed, granulated and solidified through the granulation device and the solidification device, and finally carbon-based adsorbent is produced. This allows the alkaline slag obtained after the gasification fine slag reaction and the self-produced adhesive to be fully utilized. This not only realizes the synergistic treatment of gasification fine slag and deslurry slag, but also opens up a continuous production process from raw materials to products. Thus, an internal cycle is built in the dual solid waste treatment system, realizing the full resource utilization of waste.
[0011] Optionally, the second solid-liquid separation device is provided with an alkali residue outlet, the granulation device is provided with a solid material inlet, and a third conveying mechanism is provided between the second solid-liquid separation device and the granulation device.
[0012] By adopting the above technical solution, a third conveying mechanism is provided between the second solid-liquid separation device and the granulation device, which enables the third conveying mechanism to transport the alkali residue from the alkali residue outlet to the solid material inlet, so as to realize the treatment of the alkali residue. After the alkali residue reacts with the adhesive to form granules and solidify, a carbon-based adsorbent is generated, thereby achieving solid waste treatment more efficiently.
[0013] Optionally, the adhesive preparation device has an adhesive outlet, the adhesive outlet is provided with an adhesive pipeline, the granulation device has an adhesive inlet, and the two ends of the adhesive pipeline are respectively connected to the adhesive outlet and the adhesive inlet.
[0014] By adopting the above technical solution, the adhesive outlet and adhesive inlet are connected to the two ends of the adhesive pipeline respectively, so that the adhesive can enter the granulation device through the adhesive pipeline for granulation reaction, providing a raw material basis for the subsequent preparation of carbon-based adsorbents, and further realizing the full resource utilization of dual solid wastes.
[0015] Optionally, the first solid-liquid separation device is equipped with a circulation pipeline, which includes a density detection unit and an electromagnetic reversing valve. The density detection unit is used to detect the density of the acid leaching solution in the circulation pipeline in real time. The electromagnetic reversing valve is equipped with a finished coagulant delivery pipe, and the outlet of the finished coagulant delivery pipe is equipped with a finished coagulant storage tank for storing the coagulant. When the density detection unit detects that the density of the acid leaching solution is lower than a set value, the electromagnetic reversing valve guides the acid leaching solution to flow into the circulation pipeline. When the density detection unit detects that the density of the acid leaching solution is greater than or equal to the set value, the electromagnetic reversing valve guides the acid leaching solution to flow into the finished coagulant delivery pipe.
[0016] By adopting the above technical solution, a density detection unit and an electromagnetic reversing valve are installed on the circulation pipeline, making the circulation pipeline a dynamic sampling channel. The density detection unit can detect the density change of the acid leaching solution in the circulation pipeline in real time and continuously. The reversing valve can switch the pipeline according to the density value of the acid leaching solution detected by the density detection unit in real time, so that the acid leaching solution can flow into the finished coagulant delivery pipeline only when it reaches a certain set value. The acid leaching solution that does not reach the set value needs to return to the circulation pipeline to continue the reaction, reducing the occurrence of incomplete leaching of target components due to insufficient acid leaching solution density, thereby improving the product quality of the subsequent finished coagulant.
[0017] Optionally, the ultrafiltration device has a supernatant outlet, the supernatant outlet is provided with an ultrafiltration supernatant pipeline, the acid leaching reaction device has an acid leaching liquid inlet, and the two ends of the ultrafiltration supernatant pipeline are respectively connected to the supernatant outlet and the acid leaching liquid inlet.
[0018] By adopting the above technical solution, the supernatant outlet and the acid leaching liquid inlet are connected to the two ends of the ultrafiltration supernatant pipeline, respectively. This allows the supernatant after the desizing sludge is separated by the ultrafiltration device to enter the acid leaching reaction device through the supernatant pipeline, supplementing the raw materials for the acid leaching reaction of the gasified fine sludge. This enables both the supernatant and concentrated water of the desizing wastewater to be converted into raw materials or products within the system, further realizing the full resource utilization of both solid wastes.
[0019] Optionally, both the acid leaching reaction device and the alkali dissolution reaction device are equipped with heating jackets, which are used to heat the acid leaching reaction device and the alkali dissolution reaction device to the reaction temperature.
[0020] By adopting the above technical solution, both the acid leaching reaction device and the alkali dissolution reaction device are equipped with heating jackets. The heating jackets can heat the acid leaching reaction device and the alkali dissolution reaction device to a specific reaction temperature and accelerate the reaction rate of the solution, ensuring that the reactants can react completely and providing a stable and constant temperature reaction environment for the acid leaching reaction device and the alkali dissolution reaction device.
[0021] Optionally, the acid immersion reaction device, the alkali dissolution reaction device, and the adhesive preparation device are respectively equipped with an acid immersion stirring device, an alkali dissolution stirring device, and an adhesive stirring device.
[0022] By adopting the above technical solution, a stirring device is provided in the acid leaching reaction device, the alkali dissolution reaction device, and the adhesive preparation device. This allows the stirring device to uniformly and fully stir and mix the materials in the adhesive preparation device, thereby accelerating the dissolution and reaction process between the materials and improving the overall reaction rate.
[0023] In summary, this application includes at least one of the following beneficial technical effects: 1. The acid slag separated by the first solid-liquid separation device is converted into crude sodium silicate solution through a conversion module. This allows the external alkaline solution and acid slag to be fully mixed and reacted in the alkaline dissolution reaction device. Then, the alkaline solution and alkaline slag are separated by the second solid-liquid separation device. The crude sodium silicate solution after solid-liquid separation is then transported to the adhesive preparation device through the crude sodium silicate solution pipeline. This enables the self-produced adhesive to be used as a raw material for the subsequent preparation of carbon-based adsorbents. Through structural integration and process optimization, both gasification fine slag and desizing slag are converted into raw materials or products within the system, achieving the synergistic treatment of the two solid wastes. This results in internal circulation and near-zero emissions during the treatment of the two solid wastes, and improves the processing efficiency and control precision of the equipment, providing a feasible path for the resource utilization of the two solid wastes.
[0024] 2. A second conveying mechanism is provided between the first solid-liquid separation device and the alkali dissolution reaction device, which enables the acid slag to be transported from the acid slag outlet to the alkali dissolution solid feed inlet. This allows the acid slag generated during the gasification fine slag treatment process to be utilized. The acid slag can then enter the conversion module to provide raw materials for the preparation of sodium silicate crude solution, reducing the steps required for acid slag treatment by the manufacturer and bringing higher economic benefits. Attached Figure Description
[0025] Figure 1 This is a structural schematic diagram of an embodiment of this application.
[0026] Figure reference numerals: 1. Desizing residue treatment module; 11. Ultrafiltration device; 111. Wastewater inlet; 112. Concentrate outlet; 113. Supernatant outlet; 114. Ultrafiltration supernatant pipeline; 115. Ultrafiltration concentrate pipeline; 12. Adhesive preparation device; 121. PVA concentrate inlet; 122. Sodium silicate inlet; 123. Phosphoric acid inlet; 124. Adhesive stirring device; 125. Adhesive outlet; 126. Adhesive pipeline; 13. Granulation device; 131. Solid material inlet; 132. Adhesive inlet; 133. Extrusion die; 134. Fourth conveying mechanism; 14. Curing device; 141. Heating zone; 2. Gasification fine residue treatment module; 21. Crushing device; 211. First conveying mechanism; 22. Acid leaching reaction device; 221. Acid leaching solid inlet; 222. Acid leaching solution 223. Solid inlet; 224. Acid leaching outlet; 225. Circulating liquid inlet; 226. Hydrochloric acid inlet; 227. Acid leaching stirring device; 228. Heating jacket; 23. First solid-liquid separation device; 231. Acid slag outlet; 232. Acid liquid outlet; 233. Second conveying mechanism; 24. Circulation pipeline; 241. Density detection unit; 242. Electromagnetic reversing valve; 243. Circulation pump; 244. Finished coagulant conveying pipe; 25. Finished coagulant storage tank; 3. Conversion module; 31. Alkali dissolution reaction device; 311. Alkali dissolution solid inlet; 312. Alkali liquid inlet; 313. Alkali dissolution outlet; 314. Alkali dissolution stirring device; 32. Second solid-liquid separation device; 321. Alkali slag outlet; 322. Alkali liquid outlet; 323. Sodium silicate crude liquid pipeline; 324. Third conveying mechanism; 4. Central control system. Detailed Implementation
[0027] The following is in conjunction with the appendix Figure 1 This application will be described in further detail.
[0028] This embodiment discloses a complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag. (Refer to...) Figure 1A complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag includes a deslurry slag treatment module 1, a gasification fine slag treatment module 2, a conversion module 3, and a central control system 4. The deslurry slag treatment module 1 is used to prepare carbon-based adsorbents after processing the deslurry slag. The gasification fine slag treatment module 2 is used to prepare coagulants after processing the gasification fine slag. The conversion module 3 is used to prepare sodium silicate crude liquid from the acid slag generated in the gasification fine slag treatment module 2. The central control system 4 is used for centralized monitoring and automatic control.
[0029] Reference Figure 1 The gasification fine slag treatment module 2 includes a crushing device 21, an acid leaching reaction device 22, and a first solid-liquid separation device 23. The crushing device 21 is used to crush the gasification fine slag, and the first solid-liquid separation device 23 is used to separate the acid leaching liquid after treatment by the acid leaching reaction device 22. A first conveying mechanism 211 is fixedly connected between the crushing device 21 and the acid leaching reaction device 22. The acid leaching reaction device 22 has an acid leaching solid feed inlet 221. After being crushed by the crushing device 21, the gasification fine slag is conveyed from the acid leaching solid feed inlet 221 to the acid leaching reaction device 22 by the first conveying mechanism 211.
[0030] Reference Figure 1 The acid leaching reactor 22 is equipped with a hydrochloric acid inlet 225, which is connected to an external hydrochloric acid supply source. This external hydrochloric acid is used to prepare an acid solution of a specified concentration. The acid leaching reactor 22 is also equipped with an acid leaching agitator 226, which ensures thorough reaction between the gasified slag and the acid solution. An external heating jacket 227 is provided on the outside of the acid leaching reactor 22 to heat it to a specific reaction temperature. The acid leaching reactor 22 is also equipped with an acid leaching outlet 223, which is connected to the inlet of a first solid-liquid separation device 23. This first solid-liquid separation device 23 has an acid solution outlet 232 and an acid residue outlet 231. The reacted slurry is discharged from the acid leaching outlet 223 to the first solid-liquid separation device 23 for solid-liquid separation. The acid solution and acid residue are discharged from the acid solution outlet 232 and acid residue outlet 231, respectively.
[0031] Reference Figure 1The first solid-liquid separation device 23 is equipped with a circulation pipeline 24. The inlet end of the circulation pipeline is connected to the acid outlet 232 of the first solid-liquid separation device 23. The acid leaching reaction device 22 has a circulation liquid inlet 224, and the outlet end of the circulation pipeline is connected to the circulation liquid inlet 224 of the acid leaching reaction device 22. The circulation pipeline 24 is equipped with a density detection unit 241 for real-time detection of the density of the acid leaching solution in the circulation pipeline 24. The density detection unit 241 is a densitometer. The circulation pipeline is equipped with an electromagnetic reversing valve 242, which is located on the side of the density detection unit 241 away from the acid leaching reaction device 22. The electromagnetic reversing valve 242 is equipped with a finished coagulant delivery pipe 244. The inlet of the finished coagulant delivery pipe 244 is connected to the switching outlet of the electromagnetic reversing valve 242, and the outlet of the finished coagulant delivery pipe 244 is connected to a finished coagulant storage tank 25.
[0032] Reference Figure 1 A circulation pump 243 is installed on the circulation pipeline. The circulation pump 243 is used to drive the substandard acid leaching solution back to the acid leaching reaction device 22 for secondary treatment. When the density detection unit 241 detects that the density of the acid leaching solution is lower than the set value, the electromagnetic reversing valve 242 guides the acid leaching solution to the circulation pipeline 24. The circulation pump 243 drives the acid leaching solution to return to the acid leaching reaction device 22 for reuse through the circulation pipeline 24 and the circulation liquid inlet 224. When the density detection unit 241 detects that the density of the acid leaching solution is greater than or equal to the set value, the electromagnetic reversing valve 242 switches the passage and guides the acid leaching solution to the finished coagulant delivery pipe 244. The acid leaching solution, as a qualified liquid coagulant product, is discharged into the finished coagulant storage tank 25 through the finished coagulant delivery pipe 244 for storage or sale.
[0033] Reference Figure 1 The desizing residue treatment module 1 includes an ultrafiltration unit 11 and an adhesive preparation unit 12. The adhesive preparation unit 12 is equipped with an adhesive stirring device 124 and is used to prepare adhesive from the PVA concentrate separated by the ultrafiltration unit 11. The ultrafiltration unit 11 has a wastewater inlet 111, a concentrate outlet 112, and a supernatant outlet 113. The supernatant outlet 113 is equipped with an ultrafiltration supernatant pipeline 114. The acid leaching reaction unit 22 has an acid leaching liquid inlet 222. The two ends of the ultrafiltration supernatant pipeline 114 are connected to the supernatant outlet 113 and the acid leaching liquid inlet 222, respectively. The adhesive preparation unit 12 has a PVA concentrate inlet 121, and an ultrafiltration concentrate pipeline 115 connects the concentrate outlet 112 and the PVA concentrate inlet 121. The adhesive preparation device 12 is provided with a phosphoric acid inlet 123, which is connected to an external phosphoric acid supply source.
[0034] Reference Figure 1The desizing wastewater enters the ultrafiltration unit 11 from the wastewater inlet 111. The separated PVA concentrate is transported to the PVA concentrate inlet 121 of the adhesive preparation unit 12 via the concentrate outlet and the ultrafiltration concentrate pipeline 115. The supernatant is transported to the acid leaching liquid inlet of the acid leaching reaction unit 22 via the supernatant outlet 113 and the ultrafiltration supernatant pipeline 114.
[0035] Reference Figure 1 The conversion module 3 includes an alkali dissolution reaction device 31 and a second solid-liquid separation device 32. The alkali dissolution reaction device 31 is externally equipped with a heating jacket 227 for heating, and internally equipped with an alkali dissolution stirring device 314. The alkali dissolution reaction device 31 has an alkali inlet 312 for supplying external alkali solution, which is connected to an external alkali supply source. The alkali dissolution reaction device 31 has an alkali-dissolving solid feed inlet 311 and an alkali-dissolving discharge outlet 313. A second conveying mechanism 233 is provided between the first solid-liquid separation device 23 and the alkali dissolution reaction device 31, used to convey acid residue from the acid residue outlet 231 to the alkali-dissolving solid feed inlet 311. After the acid leaching residue reacts with the alkali solution added from the alkali inlet 312 in the alkali dissolution reaction device 31, the slurry is discharged from the alkali-dissolving discharge outlet 313 into the second solid-liquid separation device 32.
[0036] Reference Figure 1 The second solid-liquid separation device 32 has an alkali outlet 322, and the adhesive preparation device 12 has a sodium silicate inlet 122. A crude sodium silicate pipeline 323 connects the alkali outlet 322 and the sodium silicate inlet 122. The crude sodium silicate obtained after separation by the second solid-liquid separation device 32 is transported from the alkali outlet 322 to the sodium silicate inlet 122 of the adhesive preparation device 12 via the crude sodium silicate pipeline 323, thus realizing the self-production of crude sodium silicate.
[0037] Reference Figure 1 The desizing slag treatment module 1 also includes a granulation device 13 and a curing device 14. The granulation device 13 is used to mix the adhesive prepared by the desizing slag treatment module 1 and the alkaline slag separated by the second solid-liquid separation device 32 in proportion and then granulate it. The curing device 14 is used to cure the carbon-based adsorbent.
[0038] Reference Figure 1The granulation device 13 has an adhesive inlet 132 and a solid material inlet 131. The adhesive preparation device 12 has an adhesive outlet 125, and the adhesive outlet 125 is equipped with an adhesive pipeline 126. The two ends of the adhesive pipeline 126 are connected to the adhesive outlet 125 and the adhesive inlet 132, respectively. The second solid-liquid separation device 32 has an alkali residue outlet 321. A third conveying mechanism 324 is provided between the second solid-liquid separation device 32 and the granulation device 13. The separated alkali residue is fed from the alkali residue outlet 321 into the solid material inlet 131 of the granulation device 13 via the third conveying mechanism 324.
[0039] Reference Figure 1 The granulation device 13 is provided with an extrusion die at its end. The diameter of the extrusion die 133 is 2-5mm. The curing device 14 is provided with a heating zone 141. The outlet of the granulation device 13 and the inlet of the curing device 14 are connected by a fourth conveying mechanism 134.
[0040] Reference Figure 1 In the granulation device 13, alkaline residue is mixed with self-produced adhesive in a certain proportion and granulated by extrusion die 133. The resulting granular blank is fed into the curing device 14 by the fourth conveying mechanism 134 and heat-treated and cured at the set temperature provided by the heating zone 141 to finally obtain the carbon-based adsorbent product.
[0041] Reference Figure 1 The central control system 4 is electrically connected to the density detection unit 241, the electromagnetic reversing valve 242, the circulating pump 243, the first conveying mechanism 211, the second conveying mechanism 233, the third conveying mechanism 324, the fourth conveying mechanism 134, the acid soaking stirring device 226, the alkali dissolving stirring device 314, and the adhesive stirring device 124.
[0042] The implementation principle of a complete set of equipment for the synergistic treatment and resource utilization of gasification fine slag and desizing slag in this application embodiment is as follows: Desizing wastewater is separated into PVA concentrate and supernatant by ultrafiltration device 11. PVA concentrate enters adhesive preparation device 12 through ultrafiltration concentrate pipeline 115 for adhesive preparation. Supernatant enters acid leaching reaction device 22 to prepare acid leaching solution. Gasification fine slag is processed by crushing device 21 and then enters acid leaching reaction device 22 through first conveying mechanism 211 for reaction. Acid slag is conveyed to alkali dissolution reaction device 31 through second conveying mechanism 233. Finally, sodium silicate crude solution is generated by second solid-liquid separation device 32. Sodium silicate crude solution enters adhesive preparation device 12 through sodium silicate crude solution pipeline 323 for adhesive preparation. Alkali slag separated by second solid-liquid separation device 32 is mixed with self-produced adhesive, granulated and solidified to finally obtain carbon-based adsorbent.
[0043] Unless otherwise defined, the technical or scientific terms used in this application shall have the ordinary meaning understood by one of ordinary skill in the art to which this application pertains. The terms "first," "second," "third," and similar terms used in this application specification and claims do not indicate any order, quantity, or importance, but are merely used to distinguish different components. The terms "an" or "a" and similar terms do not indicate a quantity limitation, but rather indicate the presence of at least one. The terms "comprising" or "including" and similar terms mean that the elements or objects preceding "comprising" or "including" encompass the elements or objects listed following "comprising" or "including" and their equivalents, and do not exclude other elements or objects. "Above," "below," "left," "right," etc., are used only to indicate relative positional relationships; when the absolute position of the described object changes, the relative positional relationship may also change accordingly.
[0044] The above description is only a preferred embodiment of this application and is not intended to limit this application. Any modifications, equivalent substitutions, improvements, etc., made within the design concept of this application should be included within the protection scope of this application.
Claims
1. A complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag, comprising a deslurry slag treatment module (1) and a gasification fine slag treatment module (2), wherein the deslurry slag treatment module (1) is used to prepare a carbon-based adsorbent after processing the deslurry slag, and the gasification fine slag treatment module (2) is used to prepare a coagulant after processing the gasification fine slag, wherein the gasification fine slag treatment module (2) comprises an acid leaching reaction device (22) and a first solid-liquid separation device (23), wherein the first solid-liquid separation device (23) performs solid-liquid separation on the acid leaching liquid after processing by the acid leaching reaction device (22), wherein the deslurry slag treatment module (1) comprises an ultrafiltration device (11) and an adhesive preparation device (12), wherein the adhesive preparation device (12) is used to prepare an adhesive from the PVA concentrate separated by the ultrafiltration device (11), characterized in that: It also includes a conversion module (3), which is used to prepare sodium silicate crude liquid from the acid residue after solid-liquid separation. The conversion module (3) includes an alkali dissolution reaction device (31) and a second solid-liquid separation device (32). The alkali dissolution reaction device (31) is provided with an alkali inlet (312) for supplying external alkali. The second solid-liquid separation device (32) is provided with a sodium silicate crude liquid pipeline (323) connected to the adhesive preparation device (12). The second solid-liquid separation device (32) is used to transport the sodium silicate crude liquid after solid-liquid separation to the adhesive preparation device (12).
2. The complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag according to claim 1, characterized in that: The first solid-liquid separation device (23) is provided with an acid slag outlet (231), and the alkali dissolution reaction device (31) is provided with an alkali dissolution solid feed inlet (311). A second conveying mechanism (233) is provided between the first solid-liquid separation device (23) and the alkali dissolution reaction device (31). The second conveying mechanism (233) is used to convey the acid slag from the acid slag outlet (231) to the alkali dissolution solid feed inlet (311).
3. The complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag according to claim 1, characterized in that: The deslurry slag treatment module (1) further includes a granulation device (13) and a curing device (14). The granulation device (13) is used to mix the adhesive prepared by the deslurry slag treatment module (1) and the alkali slag separated by the second solid-liquid separation device (32) in proportion and then granulate it. The curing device (14) is used to cure the carbon-based adsorbent.
4. The complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag according to claim 3, characterized in that: The second solid-liquid separation device (32) is provided with an alkali residue outlet (321), the granulation device (13) is provided with a solid material inlet (131), and a third conveying mechanism (324) is provided between the second solid-liquid separation device (32) and the granulation device (13).
5. The complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag according to claim 3, characterized in that: The adhesive preparation device (12) has an adhesive outlet (125) and an adhesive pipeline (126) on the adhesive outlet (125). The granulation device (13) has an adhesive inlet (132) and the two ends of the adhesive pipeline (126) are respectively connected to the adhesive outlet (125) and the adhesive inlet (132).
6. The complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag according to claim 1, characterized in that: The first solid-liquid separation device (23) is provided with a circulation pipeline (24), and the circulation pipeline (24) is provided with a density detection unit (241) and an electromagnetic reversing valve (242). The density detection unit (241) is used to detect the density of the acid leaching solution in the circulation pipeline (24) in real time. The electromagnetic reversing valve (242) is provided with a finished coagulant conveying pipe (244), and a finished coagulant storage tank (25) for storing coagulant is provided at the outlet of the finished coagulant conveying pipe (244). When the density detection unit (241) detects that the density of the acid leaching solution is lower than the set value, the electromagnetic reversing valve (242) guides the acid leaching solution to flow to the circulation pipeline (24). When the density detection unit (241) detects that the density of the acid leaching solution is greater than or equal to the set value, the electromagnetic reversing valve (242) guides the acid leaching solution to flow to the finished coagulant conveying pipe (244).
7. The complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag according to claim 1, characterized in that: The ultrafiltration device (11) is provided with a supernatant outlet (113), and the supernatant outlet (113) is provided with an ultrafiltration supernatant pipeline (114). The acid leaching reaction device (22) is provided with an acid leaching liquid inlet (222). The two ends of the ultrafiltration supernatant pipeline (114) are respectively connected to the supernatant outlet (113) and the acid leaching liquid inlet (222).
8. The complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag according to claim 1, characterized in that: Both the acid leaching reaction device (22) and the alkali dissolution reaction device (31) are equipped with heating jackets (227), which are used to heat the acid leaching reaction device (22) and the alkali dissolution reaction device (31) to the reaction temperature.
9. The complete set of equipment for the co-processing and resource utilization of gasification fine slag and deslurry slag according to claim 1, characterized in that: The acid leaching reaction device (22), the alkali dissolution reaction device (31), and the adhesive preparation device (12) are respectively equipped with an acid leaching stirring device (226), an alkali dissolution stirring device (314), and an adhesive stirring device (124).