Novel organo-metal composition for agriculture

Description

TECHNICAL FIELD OF THE INVENTION:

[0001] The present invention relates to a composition comprising a novel combination of Oragnometalo compounds with specific antimicrobial and antioxidant property for agricultural and non-agricultural applications. More particularly, the present invention relates to organometalo composition comprising Zinc octoate and copper octoates with weight ratio of 1:1BACKGROUND AND PRIOR ART OF THE INVENTION:

[0002] Earlier organo metal complexes such as zinc octoates are reported to be used as hydrogen sulfide scavengers. Petroleum asphalt is produced as a residue of a thermal separation refinery process as per the teachings of European Patent Publication No. 0121377 and 000 421 683 A1.

[0003] US5000835 describes use of oil soluble metal carboxylates as hydrogen sulphide scavengers. This patent describes the reaction between H 2 S and metal carboxylates with 6 to 24 carbon atoms. In these metal carboxylates, the carbonyl group functions as a carrier for the oppositely charged metal and places the metal into a form which is soluble in an organic environment and able to make contact with dissolved hydrogen sulfide. When the metal in the metal carboxylates reacts with dissolved hydrogen sulfide, the two forms an insoluble metal sulfide, which eliminates the toxic and corrosive properties of the hydrogen sulfide.

[0004] The organo metallic complexes of Arsenic, Antimony and Bismuth reported to be used as pesticides from early 60's (Agricultural and Biocidal Applications of Organometalics. Richard J. Daum. M&T Chemicals, Inc., Research laboratory, Rahway, N.J). US 2015 / 258057 teaches the microbicidal properties of Zn carboxylates and of Cu carboxylates. WO 2016 / 201512 teaches that Zn octoate and Cu octoate are antifungal agents.SUMMARY OF THE INVENTION:

[0005] The present invention discloses a organometalo composition comprising novel combination of organo metal compounds having antimicrobial and antioxidant property for agriculture and non-agriculture applications with a specific ratio of 1:1 by weight Zinc octoate and copper octoates.DESCRIPTION OF DRAWINGS:

[0006] Figure 1 shows 3M (enterobactereaceae) plates test for various pronos initially. Figure 2 shows 3M (enterobactereaceae) plates test for various pronos after 24 hrs. Figure 3 shows3M (enterobactereaceae) plates test for various pronos after 48 hrs. DETAILED DESCRIPTION OF INVENTION:

[0007] The invention will now be described in detail in connection with certain preferred and optional embodiments, so that various aspects thereof may be fully understood and appreciated.

[0008] Accordingly, the present invention provides a composition comprising combination of one or more oragnometalo compounds with specific antimicrobial and antioxidant property for agricultural and non-agricultural applications.

[0009] In a specific embodiment, the organometalo compounds of the present invention comprises Zinc octoate and copper octoates with a weight ratio of 1:1.

[0010] In another embodiment, the other organometalo compounds are selected from the group consisting of silicates, phosphate / phosphites and benzoates of Zinc and copper.

[0011] In another preferred embodiment, the oragnometalo composition optionally comprises trace metals selected from iron, manganese, magnesium, ammonium, calcium, potassium, boron, molybdenum; non-metals such as nitrogen, phosphorous, sulphur and organic moieties such as acetates, propionates, benzoates, gallates etc, to improve plant resistance to reduce plant efficacy disorders or symptoms thereof mediated by such metallo enzymes.

[0012] Accordingly, in another preferred embodiment, the present invention provides a composition of Zinc and Copper octoates optionally with Iron and Manganese to activate Super Oxide Dismutage-(SOD) thereby providing methods of treating diseases, disorders or symptoms thereof mediated by such metallo enzymes.

[0013] In another preferred embodiment, the present invention provides a composition of Zinc and Copper octoates optionally with Benzoates, acetates, gallates and propionates of metals to improve plant resistance to reduce plant efficacy disorders or symptoms thereof mediated by such metallo enzymes.

[0014] In yet another preferred embodiment, the present invention provides a composition of Zinc and Copper octoates alongwith silicates and Phosphates / phosphites.

[0015] Accordingly, in another preferred embodiment, the present invention provides the composition of Zinc and Copper octoates with silicates and Phosphates with Silicates: Phosphates: octoates having ratios of 5:3:2 to improve plant resistance to disorders or symptoms thereof.

[0016] In another embodiment, the composition of the present invention comprises the combination of Zinc and copper silicates, Phosphites and octoates in the ratio of 5: 3:2 to improve plant resistance to disorders or symptoms thereof.

[0017] In yet another embodiment, the composition of the present invention the combination of Zinc and copper silicates, Phosphates, phosphites and octoates in the ratio of 5: 1.5: 1.5: 2 to improve plant resistance to disorders or symptoms thereof.

[0018] In a further embodiment, the composition comprises the combination of Zinc and copper silicates, Phosphates, octoates and benzoates in the ratio of 5: 3: 1: 1 to improve plant resistance to disorders or symptoms thereof.

[0019] In yet another embodiment, the present invention has demonstrated the anti-microbial property of the organometalo compositions of the present invention. The use of copper and zinc octoates even in 10% in the composition also effectively ingibits the growth of the mycobacteriumenterobacteria and E-coli, as shown in table 3 and figures 1 to 3, indicating that the claimed compositions can be used as foliar application for the treatement of bacterial and funagl deseases from the plants. Other features and embodiments of the invention will become apparent by the following examples which are given only for the purpose of illustration of the invention rather than limiting its intended scope. Various changes and modifications to the disclosed embodiments will be apparent to those skilled in the art.EXAMPLES Example-1:

[0020] Oraganometalo compositions comprising Zinc and Copper Octoates with Metal silicates and Metal phosphates in a specific ratio in 5:3:2 ratio is shown in table 1 below. Table 1 (first two rows are not covered by the present claims)COMPOSITION WEIGHT IN G THEORITICAL %Zn & % Cu Zinc and Copper silicates in 1:150 GEACH 3 %Zinc and Copper Phosphates in 1:130 GEACH 6 %Zinc and Copper Octoates in 1:120 GEACH 2 % Example-2: (not covered by the present claims)

[0021] Composition comprising Zinc and Copper Octoates with silicates and Phosphates and with or without Iron and Manganese alongwith specific ratio of Nitrogen, Phosphorous and Potassium having ratios of 5:3:2 and with Trace elements, as shown in table 2, to improve plant resistance to disorders or symptoms thereof. Table 2 ORGANOMETALLIC COMPOUND ALONG WITH NPK s.no Name of raw material Chilli Vegetable grades (brinjal, okra, cabbage, cauliflower, beans,gaurds) Chilli flowering 7-3-23 Fruit development and maturity 8-2-27 Weight in grams Weight in grams 1SILICATES1001002PHOSPHATES60603OCTOATES40404UREA22505KNO3 13-0-455114446SOP 00-00-50(Sulphate of potash)007MAP(Monoammonium phosphate)008MKP(Mono Potassium Phosphate)009Ca- PROPIONATE33.333.310Ca-ACETATE33.333.311Ca-PHOSPHATE (HAP)33.333.312BOROVIN12012013MgSO4 anhydrous132614MnSO4.H2O28015FeSO4.7H2O0016BORIC ACID0017Fe-EDTA01018Mn-EDTA04019AMMONIUM MOLYBDATE00.0220ANTI CAKING610TOTAL 1000 1000 Example 3:

[0022] The anti-microbial property of the organometalo compositions of the present invention is demonstrated in the below table 3 and shown in figures 1 to 3. The use of combination of copper and zinc octoates(1:1) even in 10% in the compositions of copper and zinc (1:1) silicates, phosphates, phosphites and benzoates, effectively inhibits the growth of the enterobacteria and E-coli, when compared to silicates, phosphates, phosphites and benzoates alone or their combinations. Therefore, the combination of copper and zinc octoates (1:1) even in 10% in the compositions of silicates, phosphates, phosphites and benzoates effectively inhibits the growth of the enterobacteria and E-coli, when compared to the compositions that are devoid of octoates as demonstrated in table 3 below. Table 3: 3M (ENTEROBACTEREACEAE) PLATES TEST FOR VARIOUS PRONOS (S.NOs. 4 and 6-11 not covered by the present claims)S.NO DESCRIPTION with Ratios of SILICATES-PHOSPHATES-OCTOATESDILUTION FOR 3 M % of Anti microbial property 150-30-20 SILICATES-PHOSPHATES-OCTOATES(PRONOS-1)1G / LIT100 %250-30-20 SILICATES-PHOSPHITES -OCTOATES(PRONOS-2)1G / LIT100 %350-15-15-20 SILICATES-PHOSPHATES-PHOSPHITES-OCTOATES(PRONOS-3)1G / LIT100 %450-30-20 SILICATES-PHOSPHATES-BENZOATES(PRONOS-4)1G / LIT90 %550-30-10-10 SILICATES-PHOSPHATES-OCTOATES-BENZOATES(PRONOS-5)1G / LIT100 %6COPPER AND ZINC SILICATES -50-50 (1:1)1G / LIT80%7COPPER AND ZINC PHOSPHATES-50-50 (1:1)1G / LITNIL8COPPER AND ZINC PHOSPHITES-50-50 (1:1)1G / LITNIL9.COPPER AND ZINC BENZOATES - 50-50 (1:1)1G / LIT80%10.COPPER OCTOATE-1001G / LIT70%11.ZINC OCTOATE-1001G / LIT60%12COPPER AND ZINC OCTOATE-50-50 (1:1)1G / LIT100% Procedure:

[0023] Various formulation(Pronos) as referred above in table 3 was prepared by dissolving 1gm of the formulation in one litre of contaminated water containing Ecoli or Enterobactereacea. The samples were placed on the 3M plates(3M Petrifilm Enterobacteriaceae Count Plate) and incubated all the plates for 24 hours period. After 24 hours a clear indication of Anti-Microbial property was observed from the color change in the 3M paltes.

[0024] Each 3M -Plate have self-indicated with selected Media for Ecoli and Entero bacteacea. These 3M Petrifilm Enterobacteriaceae Count Plate is a sample-ready-culture medium system that contains modified Violet Red Bile Glucose (VRBG) nutrients, a cold-watersoluble gelling agent, and a tetrazolium indicator that facilitates colony enumeration. 3M Petrifilm Enterobacteriaceae Count Plates are used for the enumeration of Enterobacteriaceae in the food, beverage and bottled water industries. Enterobacteriaceae are oxidase-negative, Gram-negative rods that ferment glucose to produce acid and / or gas. Enterobacteriaceae colonies will appear as red colonies associated with yellow zones, red colonies associated with gas bubbles, red colonies associated with yellow zones and with gas bubbles (source: 3M Petrifilm ™< ).Color Indication plate for Microbial species:

[0025] 3M-Plate-Violet color for Entero Bactreacea 3-M Plate-Pink color for E-COLI

[0026] As the count of the Enterobacteriaceae increases, the color of the gel lightens from violet to yellow or cream colored. Similarly, As the count of the e-coli increases, the color of the gel lightens from dark pink to light pink colored.Results:

[0027] Above all formulations containing copper and zinc octoate(1:1) gives clear indication of 100 % Anti microbial property against Enterobacteriaceae and E. Coli.

[0028] Based on the above results the claimed compositions can be used as foliar application in agriculture fileds for the treatment of bacterial and funagl deseases from the plants like phytopathogens are tested and found its controlled.Example 4: SAMPL .NOs. 2-8 and 10-11 not covered by the present claims)

[0029] Example 4, illustrates various formulation prepared using octoates of zinc and copper along with phosphates, silicates, benzoates, propionates and NPK, for agricultural applications as provided under tables 4 to 10. Table 7: Table 7 shows various combinations of Zn and Cu silicates, phosphates and Octoates. (samples 2 and 16 not covered by the present claims)1:1 silicates 1:1 phosphates Zn-Octoate Cu-Octoate Sample weight sample-1 (1:1 Zn Octoate + Copper Octoate)0 0 50 50 100 sample-2 (Copper Octoate)0 0 0 100 100 SAMPLE-16 (60-40-10)54.436.44.64.6100SAMPLE-17 (50-30-20)50301010100 Table 8 : (only samples 1 and 9A-9C are according to the present claims ) Table 8 shows various compositions of zinc octoate, copper octoate without Zinc / copper Phosphate and Zinc / copper Silicates either alone or in combination thereof.PER ACRE DOSE S NO Composition 1-A 1-B Sample -1Zinc Octoate0.5 gm1 gmCopper Octoate0.5 gm1 gm2-A 2-B Sample -2Copper Octoate1 gm2 gmSample -3(CS + CP) = 100 gm / acre with Copper Octoate 1 gmSample -4(CS + CP) = 200 gm / acre with Copper Octoate 1 gmSample -5(CS + CP) = 100 gm / acre with Zinc Octoate 1 gmSample -6(CS + CP) = 200 gm / acre with Zinc Octoate 1 gmSample -7Zinc Phosphate + Zinc Silicate=100 gm / acreSample -8Zinc Phosphate + Zinc Silicate=200 gm / acre9-A 9-B 9-C Sample -9CS / ZS50 gm50 gm125gmCP / ZP50 gm50 gm75 gmCopper Octoate0.5 gm1 gm0.5 gmZinc Octoate0.5 gm1 gm0.5 gmSample -10CS+CP(1:1)Sample -11Sucrose OctoateInsect & Microbe s Table 9 Table 9 discloses a composition containing pronos 1 to 3 along with other agricultural ingredients with Stevia extract.DORMULIN-3 VEGETATIVE WITH BIO FILM BREAKERS + STEVIA EXTRCT S.NO RAW MATERIAL Qty / MT 1Pronos -11002Pronos-2603Pronos-3404MgSO 4 .H 2 O1105MnSO 4 .H 2 O1006FeSO 4 .7H 2 O507AMMONIUM MOLYBDATE58FULVIC ACID2009UREA3010Roxite10011SOP10012BOROVIN1213STEVIA EXT-CHLOROFORM1 ML14STICKING AGENT(JEEMOX)315DISPERSANT(JEEMOL DW)9016TOTAL WEIGHT1000 Table 10: DORMULIN-3 FLOWERING VARIANTS 2. stevia extract 3. KOH & urea 4. Pot.benzoate & Pot.peroxy mono sulfate 5. Calcium thio sulfate S.NO RAW MATERIAL Qty IN GQty IN GQty IN GQty IN G1Pronos -11001001001002Pronos-2606060603Pronos-3404040404Calcium ACETATE505050505AMMONIUM MOLYBDATE55556FULVIC ACID2502502502507calcium propionate505050508SOP200001999KOH FLAKES01000010BOROVIN12012012012011UREA0100001210 % STEVIA EXT-CHLOROFORM1 ML1 ML1 ML13POTASSIUM BENZOATE100014POTASSIUM PEROXY MONO SULFATE100015CALCIUM THIOSULFATE116STICKING AGENT(JEEMOX)000017DISPERSANT(JEEM OL DW)12012012012018Jeesperse5555TOTAL WEIGHT 1000 1000 1000 1000

Claims

1. Organometalo composition comprising zinc octoate and copper octoate, wherein the zinc octoate and copper octoate is in a weight ratio of 1:1.

2. The organometalo composition as claimed in claim 1, wherein the composition further comprises trace metals selected from iron, manganese, magnesium, ammonium, calcium, potassium, boron, molybdenum; non-metals selected from nitrogen, phosphorous and sulphur and organic moieties selected from acetates, propionates and benzoates.

3. The organometalo composition as claimed in claim 1, further comprising compounds having antimicrobial and antioxidant property selected from the group consisting of silicates, phosphate, phosphites and benzoates of zinc and copper.

4. The organometalo composition as claimed in claim 3, wherein the composition comprises the combination of zinc and copper silicates, phosphates and octoates in the weight ratio of 5:3:2.

5. The organometalo composition as claimed in claim 3, wherein the composition comprises the combination of zinc and copper silicates, phosphites and octoates in the weight ratio of 5:3:2.

6. The organometalo composition as claimed in claim 3, wherein the composition comprises the combination of zinc and copper silicates, phosphates, phosphites and octoates in the weight ratio of 5:1.5:1.5:2.

7. The organometalo composition as claimed in claim 3, wherein the composition comprises the combination of zinc and copper silicates, phosphates, octoates and benzoates in the weight ratio of 5:3:1:1.

8. Use of a composition according to any one of claims 1 to 7, for improving plant resistance to disorders and symptoms thereof.