Fragrance compositions

Description

FIELD OF THE INVENTION

[0001] The present disclosure relates to the field of perfumery. In particular, the present disclosure provides compositions having an increased and / or improved long-lastingness and / or fragrance profile. In addition, the present disclosure provides methods of using such compositions to increase and / or improve the long-lastingness and / or fragrance profile of a fragrance composition.BACKGROUND

[0002] In the perfumery industry there is a constant need to find new technologies for prolonging the perception of perfumes over time. Such a need is particularly marked when dealing with perfumes rich in highly volatile perfuming ingredients which evaporate quickly, such that the fragrance intensity and / or fragrance profile, as perceived by the user and others, decreases and / or changes with time. The perceived extent of this decrease and / or change is further enhanced by the rapid evaporation of ethanol, present in high amounts in fragrances and "eau de toilette" (colognes), as well as in body splashes. Maintaining intensity and / or profile over time is one important consideration for a commercial fragrance composition. Indeed, consumers look for fragrance compositions that last all day long. For example, it is commonly accepted that a fragrance composition has to maintain a good intensity and / or fragrance profile for at least 8 hours to satisfy this consumer need, the main challenge being to maintain the intensity of the highly volatile perfuming ingredients.

[0003] Perfumers select perfuming ingredients to blend into a fragrance composition with the goal of achieving a specific fragrance profile of strength and character. In so doing, perfumers are required to bear in mind differences in the individual character and volatility of the perfuming ingredients that are the components of the full fragrance composition. Conventional fragrance compositions have fragrance profile characterized by a greater amount of low volatile perfuming ingredients and lower amounts of the more volatile perfuming ingredients. The low volatile perfuming ingredients are known as "base notes", while the more volatile perfuming ingredients can be further divided into high volatile perfuming ingredients, identified as "top or head notes", and medium volatile perfuming ingredients, identified as "middle or heart notes' WO 2016 / 200759 A1 describes a composition comprising from about 10 wt% to about 30 wt% of low volatile fragrance materials having a vapor pressure less than 0.001 Torr (0.000133 kPa) at 25°C and at least one substantially non-odorous fragrance modulator.

[0004] The differences in the volatilities of the perfuming ingredients that are used to formulate fragrance compositions may result in some limitations. For example, a common complaint by consumers is that middle notes tend to fade too quickly after application of the fragrance composition. Additionally, the character of the middle notes may be undesirably altered by the presence of large amounts of the base notes during the period known as the "dry-down" phase.

[0005] Thus, it is desirable to have a fragrance composition which retains a significant portion of its initial fragrance character over time, hence, the floral, fruity or spicy characters of the 'heart notes' are perceived for many hours It is also desirable that the fragrance strength of the fragrance composition remains noticeable to the consumer over longer periods of time. It is also desirable to be able to create new to the world fragrance profiles wherein one, or several, well-recognized heart note characters, are maintained over time.

[0006] Therefore, there remains a need for a composition that is perceived by the consumer over a long duration following application. There is also a need for a composition which exhibits enhanced intensity of the fragrance profile over time.SUMMARY

[0007] One aspect presented herein, provides a composition as defined in claim 1.

[0008] In one aspect, the fragrance component present in an amount from 0.04 to 20 wt%, relative to the total weight of the composition.

[0009] In one aspect, the composition further comprises water, in an amount of less than or equal to 15 wt% relative to the total weight of the composition.

[0010] In one aspect, the composition further comprises water, in an amount 5 to 15 wt% relative to the total weight of the composition.

[0011] In one aspect, the composition further comprises water, in an amount 0 to 5 wt% relative to the total weight of the composition.

[0012] In one aspect, the composition further comprises at least one hydrophilic solvent. In one aspect, the at least one hydrophilic solvent is selected from the group consisting of: propylene glycol, dipropylene glycol, ethylene glycol, triethyl citrate, disiopropyl glycol monomethyl ether, diethylene glycol monoethyl ether; triacetin, methylmethoxybutanol, benzyl alcohol, propylene glycol n-butyl ether; a glycol ether, an ester of diethylene glycol, and a cellosolve derivative. In one aspect, the glycol ether is a glycol ether sold under the tradename DOWANOL. In one aspect, the ether of diethylene glycol is sold under the tradename CARBITOL.

[0013] In one aspect, the glycol ether sold under the tradename DOWANOL is selected from the group consisting of: DOWANOL ™< DPMA Glycol Ether; DOWANOL ™< PM Glycol Ether; DOWANOL EPH ELP; DOWANOL ™< EPh; DOWANOL ™< PnB Glycol Ether; DOWANOL ™< TPnB; DOWANOL ™< DPnB Glycol Ether; DOWANOL ™< TPM Glycol Ether; DOWANOL ™< PPh Glycol Ether; DOWANOL ™< PnP Glycol Ether; DOWANOL ™< DPH 255 Glycol Ether; DOWANOL ™< PGDA Glycol Ether; DOWANOL ™< DPM Glycol Ether; DOWANOL ™< TPnB-H Gly Ether; DOWANOL ™< Solvents for Home & Personal Care; DOWANOL ™< DPnP Glycol Ether; DOWANOL ™< PMA Glycol Ether; DOWANOL ™< DiPPh Glycol Ether.

[0014] In one aspect, the cellosolve derivative is selected from the group consisting of: propyl cellosolve, butyl cellosolve, hexyl cellosolve, and cellosolve.

[0015] In one aspect, the high volatility component comprises the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C in an amount from 0.1 to 40 wt% of the fragrance component.

[0016] In one aspect, the medium volatility component comprises the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C in an amount from 20 to 45 wt% of the fragrance component.

[0017] In one aspect, the fragrance component further comprises at least one perfume raw material having a first vapor pressure less than 0.0008 Torr at 22°C in an amount from 10 to 55 wt% of the fragrance component.

[0018] In one aspect, the fragrance component further comprises at least one perfume raw material having a first vapor pressure less than 0.0008 Torr at 22°C in an amount from 30 to 55 wt% of the fragrance component.

[0019] In one aspect, the fragrance component further comprises at least one perfume raw material having a first vapor pressure less than 0.0008 Torr at 22°C in an amount from 10 to 30 wt% of the fragrance component.

[0020] Also described herein (not according to the invention) is a perfuming consumer product comprising the composition according to an aspect presented herein.

[0021] Also described herein (not according to the invention) is a perfuming composition comprising the composition according to an aspect presented herein.

[0022] Also described herein (not according to the invention) is a perfuming consumer product comprising the perfuming composition according to an aspect presented herein.

[0023] The perfuming consumer product can be a perfume, eau de toilette, home care product or a personal care product.

[0024] One aspect presented herein provides a method for modifying or enhancing the odor properties of a body surface, such as hair or skin, comprising contacting or treating the body surface with a composition according to the aspects presented herein.BRIEF DESCRIPTION OF THE FIGURES

[0025] While the specification concludes with claims particularly pointing out and distinctly claiming the invention, it is believed that the invention will be better understood from the following description of the accompanying figures wherein: Figure 1 provides a graphical representation of a conventional perfume structure. Figure 2 shows a representation of the Hansen Space defined in three directions by the three Hansen solubility parameters, wherein R 0 is the radius of the sphere of solubility characteristic of the solute. R a represents the distance between the solute solubility parameter (center of the sphere of solubility) and the solvent solubility parameter. Figure 3 provides shows the effect of the modulator on the amount of a perfume raw material in solution over time. The solid lines denote the ratio of actual recorded values of the amount of a perfume raw material (A PRM ) to by the amount of an internal standard (A INSTD ) in the presence of 15 wt% modulator, relative to the total weight of the composition (a 15 ), or without modulator (a 0 ). The dashed lines denote the predicted ratios in a solution containing either 5 wt% modulator, relative to the total weight of the composition (a 5 ), or 10 wt% modulator, relative to the total weight of the composition (a 10 ) over time. Figure 4 provides a graphical representation of perfume structures according to several aspects presented herein. Figure 5 inter alia shows compounds suitable for use as the at least one modulator according to the invention (IPM, Hedione, and Nerolidol). Figure 6 denotes perfume raw materials wherein the second vapor pressure is different in a modulator comprising 15 wt% PPG-20 methyl glucose ether ("MGE"), relative to the total weight of the composition, compared to a modulator comprising 10 wt% PPG-20 methyl glucose ether and 5 wt% isocetyl alcohol ("ICA") (not according to the invention). Figure 7 shows the effect of either HEDIONE or IPM on the retention of the fragrance component of a sample over time. Figure 8 a-c shows the effect of either HEDIONE or IPM on the amount of various perfume raw materials released into a headspace, following 1, 4, and 6 hours dry down, respectively. Figure 9 a and b shows the effect of either HEDIONE or benzyl salicylate (not according to the invention) on the retention of the fragrance component of a sample over time, following 1, and 4 hours dry down, respectively. Figure 10 shows the effect of either HEDIONE or benzyl salicylate (not according to the invention) on the retention of the fragrance component of a sample over time, following 0, 1, and 4 hours dry down, respectively. Figure 11 a and b shows the effect of either HEDIONE or benzyl salicylate (not according to the invention) on the retention of the fragrance component of a sample over time, following 1, and 4 hours dry down, respectively. Figure 12 shows the effect of either HEDIONE or benzyl salicylate (not according to the invention) on the retention of the fragrance component of a sample over time, following 0, 1, and 4 hours dry down, respectively. DETAILED DESCRIPTION Compositions According to Some Aspects Presented Herein:

[0026] The words "perfume" and "fragrance" are used here interchangeably to designate the component in the fragrance composition that is formed of perfuming ingredients, i.e. ingredients capable of imparting or modifying the odor of skin or hair.

[0027] By a "perfuming ingredient" it is meant here a compound of current use in perfumery, which is used essentially for its ability to smell pleasantly and to be capable of imparting hedonic effect, or a pleasant odor to the products into which it is incorporated, or to the surfaces, such as skin or hair, to which it is applied, on its own or in admixture with other such ingredients. In other words, a perfuming ingredient has the ability to impart or modify, in a positive or pleasant way, the odor of a composition or surface. When the latter has a malodor, the perfuming ingredient may also be capable of covering such malodor so as to render the overall perceived odor pleasant.

[0028] A "perfuming ingredient" may encompass any suitable perfume raw material for fragrance uses, including materials such as, for example, alcohols, aldehydes, ketones, esters, ethers, acetates, nitriles, terpene hydrocarbons, nitrogenous or sulfurous heterocyclic compounds and essential oils. However, naturally occurring plant and animal oils and exudates comprising complex mixtures of various chemical components are also know for use as "perfuming ingredient(s)". The individual perfume raw materials which comprise a known natural oil can be found by reference to Journals commonly used by those skilled in the art such as "Perfume and Flavourist" or "Journal of Essential Oil Research", or listed in reference texts such as the book by S. Arctander, Perfume and Flavor Chemicals, 1969, Montclair, New Jersey, USA and more recently re-published by Allured Publishing Corporation Illinois (1994). Additionally, some perfume raw materials are supplied by the fragrance houses as mixtures in the form of proprietary specialty accords. Non-limiting examples of the perfuming ingredients useful herein include pro- fragrances such as acetal pro-fragrances, ketal pro-fragrances, ester pro-fragrances, hydrolyzable inorganic-organic pro-fragrances, and mixtures thereof. The perfuming ingredient may be released from the pro-fragrances in a number of ways. For example, by way of a non-limiting illustration, the fragrance may be released as a result of simple hydrolysis, or by a shift in an equilibrium reaction, or by a pH-change, or by enzymatic release.

[0029] As used herein, the term "fragrance profile" means the description of how the fragrance perceived by the human nose evolves over time from when it is first applied. It is a result of the combination of the top, middle and base notes, if present, of a fragrance. A fragrance profile is composed of 2 characteristics: 'intensity' and 'character'. The 'intensity' relates to the perceived strength whilst 'character' refers to the odor impression or quality of the perfume, i.e., fruity, floral, woody, etc.

[0030] By "modulator" or "fixative" it is understood here an agent having the capacity to affect the manner in which the odor, in particular its evaporation rate and intensity, of the compositions incorporating the modulator or fixative can be perceived by an observer or user thereof, over time, as compared to the same perception in the absence of the modulator or fixative.

[0031] As used herein, the terms "include", "includes" and "including" are meant to be non-limiting.

[0032] Referring to Figure 1, conventional fragrance compositions have fragrance profile characterized by a greater amount of low volatile perfuming ingredients and lower amounts of the more volatile perfuming ingredients. The low volatile perfuming ingredients are known as "base notes", while the more volatile perfuming ingredients can be further divided into high volatile perfuming ingredients, identified as "top or head notes", and medium volatile perfuming ingredients, identified as "middle or heart notes".

[0033] Without intending to be limited to any particular theory, top notes tend to smell citrusy, green, light, fresh, and comprise typically from about 0.1 wt% to 40 wt%, relative to the total weight of the fragrance composition. Top notes tend to evaporate quickly due to their high volatility and are characterized by vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C (Calculated using Advanced Chemistry Development (ACD / Labs) Software VI 1.02 ( ©< 1994-2013 ACD / Labs)). Typically, perfumers use top notes to deliver the initial impression of the composition but do not rely on them to contribute much to its overall fragrance profile over time after application.

[0034] Middle or heart notes make up from about 0.1 wt% to about 40 wt%, relative to the total weight of the fragrance composition. Generally, middle / heart notes become dominant to the untrained nose from several minutes after application and can last up to a few hours afterwards. Middle / heart notes are associated with floral aromas (e.g., jasmin, rose), fruity, aromatic, marine or spicy aromas and have an intermediate volatility in the vapor pressure range of 0.0008 (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C.

[0035] Base or bottom notes can exist at greater than 30 wt% relative to the total weight of the perfume formulation. Alternatively, base notes can exist from about 45 wt% to about 80 wt% relative to the total weight of the perfume formulation. Base notes are characterized as animalic, woody, sweet, amber or musky, not being very volatile and having a vapor pressure less than 0.0008 Torr at 22°C. Typically, base notes are not perceived as dominant until several hours after the application of the fragrance composition, or during "dry-down". Base notes may be relied upon to improve the strength of the overall fragrance profile over time and replace the heart notes when these are declining, The consequence of using base notes at high levels is that they impart particular odor characters, such as for example, musky, woody, ambery, warm and sweet, which overpower and dominate the fragrance character over time. Some of these base notes have become such common materials (e.g., hedione, galaxolide, etc.) that many fragrance dry-downs appear repetitive, boring, non-memorable and uninteresting to consumers. However, if base notes are reduced or excluded then the fragrance strength weakens over time and does not last for a sufficient duration.

[0036] As used herein, the term "vapor pressure" means the partial pressure in air at a defined temperature for a given chemical species. It defines a chemical species' desire to be in the gas phase rather than the liquid or solid state. The higher the vapor pressure, the greater the proportion of the material that will, at equilibrium, be found in a closed headspace. It is also related to the rate of evaporation of a perfuming ingredient which is defined in an open environment where material is leaving the system. According to the invention, the vapor pressure is determined according to the reference program Advanced Chemistry Development (ACD / Labs) Software Version 11.02, ( ©< 1994-2013). Examples of methods suitable to determine vapor pressure are disclosed in International Patent Application Publication No. WO 2015 / 089246 A1.

[0037] As used herein, the term "impact" means the efficacy or intensity of a perfume raw material during the first moments of product performance. For example, a top note may be noticed immediately when sniffing at the perfume bottle or some seconds after applying the product to the skin.

[0038] As used herein, the term "diffusion" is a measure of the distance over which the fragrance or perfume raw material is noticeable soon after application; high diffusion, for example, is desirable in a bath foam or a dishwashing detergent.

[0039] As used herein, the term "tenacity" means the long-term effectiveness of the perfume raw material in the perfumed product, such as upon the skin after use of a perfume or a toilet soap.

[0040] As used herein, the term "volume" means the effectiveness of the perfume raw material over distance, sometime after application.

[0041] In one aspect, the fragrance component is present in the composition in an amount of from 1 wt% to about 40 wt%, alternatively less than about 25 wt%, alternatively less than about 20 wt%, alternatively less than about 15 wt%, alternatively less than about 10 wt% or alternatively less than about 8 wt%, relative to the total weight of the composition. Alternatively, the fragrance component is present in an amount of from about 0.04 wt%, 0.3 wt%, 1 wt%, 8 wt% or 10 wt%, to about 15 wt%, 20 wt%, 25 wt%, 30 wt%, or 40 wt% relative to the total weight of the composition.

[0042] As used herein, the term "composition" includes a fine fragrance composition intended for application to a body surface, such as for example, skin or hair, i.e., to impart a pleasant odor thereto, or cover a malodour thereof. They are generally in the form of perfume concentrates, perfumes, eau de parfums, eau de toilettes, aftershaves, colognes, body splashes, or body sprays. The fine fragrance compositions may be ethanol based compositions. The term "composition" may also include a cosmetic composition, which comprises a fragrance material for the purposes of delivering a pleasant smell to drive consumer acceptance of the cosmetic composition. The term "composition" may also include cleaning compositions, such as fabric care composition or home care compositions, including air care compositions, for use on clothing or other substrates such as hard surfaces (e.g., dishes, floors, countertops). Additional non- limiting examples of "composition" may also include facial or body powder, foundation, body / facial oil, mousse, creams (e.g., cold creams), waxes, sunscreens and blocks, bath and shower gels, lip balms, self-tanning compositions, masks and patches. Further non-limiting illustrative examples are described below.

[0043] As used herein, the term "consumer" means both the user of the composition and the observer nearby or around the user.

[0044] One aspect presented herein, provides a composition, wherein the composition comprises: a. ethanol, in an amount from 30 to 75 wt% relative to the total weight of the composition; b. a fragrance component present in an amount from 0.04 to 40 wt%, relative to the total weight of the composition, wherein the fragrance component comprises: i. a high volatility component an amount from 0.08 to 55 wt% of the fragrance component, comprising a. a first at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C; and b. a second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C; ii. a medium volatility component in an amount from 0.08 to 85 wt% of the fragrance component, comprising: a. a first at least one perfume raw material having a first vapor pressure range of 0.0008 (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C; and b. a second at least one perfume raw material having a first vapor pressure range of 0.0008 (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C; and c. at least one modulator selected from the group consisting of: 3,7,11-trimethyl-1,6,10-dodecatrien-3-ol; Methyl 2-(3-oxo-2-pentylcyclopentyl)ethanoate; methyl 2-[(1R,2S)-3-oxo-2-pentylcyclopentyl]acetate; methyl 2-[(1R,2R)-3-oxo-2-[(Z)-pent-2-enyl]cyclopentyl]acetate; propan-2-yl tetradecanoate; and combinations thereof; in an amount from 5.0 to 20 wt%, relative to the total weight of the composition; wherein the first vapor pressure of the at least one first perfume raw material of the high volatility component is determined in the absence of the at least one modulator; wherein the first vapor pressure of the at least one second perfume raw material of the high volatility component is determined in the absence of the at least one modulator; wherein the at least one modulator changes the first vapor pressure of the at least one second perfume raw material of the high volatility component to a second vapor pressure; wherein the second vapor pressure of the at least one second perfume raw material of the high volatility component is in the range of 0.0008 (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C; wherein the first vapor pressure range of the at least one first perfume raw material of the medium volatility component is determined in the absence of the at least one modulator; wherein the first vapor pressure range of the at least one second perfume raw material of the medium volatility component is determined in the absence of the at least one modulator; wherein the at least one modulator changes the first vapor pressure range of the at least one second perfume raw material of the medium volatility component to a second vapor pressure; and wherein the second vapor pressure of the at least one second perfume raw material of the medium volatility component is less than 0.0008 Torr (0.1067 Pa) at 22°C; wherein the vapor pressure is determined according to the reference program Advanced Chemistry Development Software Version 11.02.

[0045] In some aspects, the fragrance component present in an amount from 0.04 to 20 wt%, relative to the total weight of the composition.

[0046] In some aspects, the composition further comprises water, in an amount of less than or equal to 15 wt% relative to the total weight of the composition.

[0047] In some aspects, the composition further comprises water, in an amount 5 to 15 wt% relative to the total weight of the composition.

[0048] In some aspects, the composition further comprises water, in an amount 0 to 5 wt% relative to the total weight of the composition.

[0049] In another aspect, water may be present in any of the compositions presented, and more specifically, it shall not exceed about 15 wt%, alternatively about 14 wt% or less, alternatively about 13 wt% or less, alternatively about 12 wt% or less, alternatively about 11 wt% or less, alternatively about 10 wt% or less, alternatively about 9 wt% or less, alternatively about 8 wt% or less, alternatively about 7 wt% or less, alternatively about 6 wt% or less, alternatively about 5 wt% or less, alternatively about 4 wt% or less, alternatively about 3 wt% or less, alternatively about 2 wt% or less, alternatively about 1 wt% or less, relative to the total weight of the composition. Alternatively, water may be present in an amount of from about 10 wt or 20 wt to about 40 wt%, relative to the total weight of the composition. When the composition is a cosmetic composition the level of water should not be so high that the product becomes cloudy thus negatively impacting the product aesthetics. It is understood that the amount of water present in the composition may be from the water present in the ethanol used in the composition, as the case may be.

[0050] The fragrance component may also further comprise a low volatility component, comprising perfume raw materials having vapor pressure less than 0.0008 Torr (0.1067 Pa) at 22°C.

[0051] In some aspects, the effect of the at least one modulator on the fragrance profile, particularly the portion of the fragrance profile which is derived from volatile fragrance materials (i.e., top and middle notes), can be improved. By "improved" it is meant that the fragrance character of the composition, particular the components contributed by the volatile fragrance materials, can be perceived by the consumer at later time points such as, for example, 2 hours, 4 hours, 6 hours, 8 hours, 10 hours, and possibly all the way up to 24 hrs. after application as compared to controls, i.e., conventional compositions, or compositions wherein the fragrance component comprises: a high volatility component, comprising perfume raw materials having a vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C; and a medium volatility component, comprising perfume raw materials having a vapor pressure range of 0.0008 (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C, lacking a modulator.

[0052] Alternatively, by "improved" it can mean that the perception of the components contributed by the volatile fragrance materials, by the consumer, is markedly increased or enhanced as compared to the controls. "Increased" or "enhanced" perception of the fragrance profile means that the consumer perceives the fragrance profile of a composition as not changing from its initial impression or the changes are minimal from when the composition was first applied to when it dissipates.

[0053] Alternatively, by "improved" it can mean that the perception of the components contributed by the volatile fragrance materials can be perceived by the consumer during dry-down.

[0054] Typically, it has been difficult to remove the water from perfume compositions, such as, for example, an eau de toilette, without negatively impacting the fragrance profile perceived by a user. Without intending to be limited to any particular theory, for any given perfume raw material in a perfume composition, the perfume raw material forms an equilibrium between a liquid phase and a vapor phase. The presence of water drives the equilibrium of the perfume raw material toward the vapor phase, and thus increases the concentration of the perfume raw material in the head-space. Removing the water, decreases the concentration of the perfume raw materials in the head-space, and therefore decreases the perception of the perfume raw material.

[0055] The concentration of the perfume raw material in the head-space may be greater for a highly volatile perfume raw material, compared to a less-volatile perfuming raw material. Additionally, the perception of the perfuming raw material may be greater for a perfuming raw material having a lower odor detection threshold, compared to a perfuming raw material having a higher odor detection threshold. However, the performance of the perfuming composition may be negatively impacted by the use of highly volatile and / or low odor detection threshold perfume raw materials to counteract the removal of water.

[0056] In some embodiments, the present application provides at least one modulator that allows the removal of water from perfume compositions without negatively impacting the performance of the perfuming compositions.

[0057] Referring to Figure 3, the amount of any given perfume raw material in solution does not remain constant. Rather, the perfume raw material diffuses into the headspace, and the concentration of the perfume raw material in solution declines with time. Without intending to be limited to any particular theory, a consumer will be able to detect and recognize the presence of the perfume raw material, once the concentration of the perfume raw material is above a threshold concentration (referred to herein as the odor recognition threshold).

[0058] In Figure 3, the decline in concentration of the perfume raw material in solution is recorded as the ratio of actual recorded values of the amount of a perfume raw material (A PRM ) to by the amount of an internal standard (A INSTD ). In the absence of the at least one modulator, the rate of decrease of the concentration of the perfume raw material in solution has a first value (shown as the a 0 line on the graph, defined herein d(A PRM / A INSTD ) / dt 1 / 2< ). In some aspects, the presence of the at least one modulator changes the first value to a lower, second value. In the example shown in Figure 3, the at least one modulator having a concentration of 15 wt%, relative to the total weight of the composition decreases d(A PRM / A INSTD ) / dt 1 / 2< to a second value (shown as the a 15 line on the graph). Accordingly, the presence of the at least one modulator may delay the time at which a consumer may be able to detect and recognize the presence of the perfume raw material. Alternatively, the presence of the at least one modulator may prolong the duration that the consumer may be able to detect and recognize the presence of the perfume raw material. Alternatively, the presence of the at least one modulator may prevent a consumer from being able to detect and recognize the presence of the perfume raw material.

[0059] The extent by which the at least one modulator influences d(A PRM / A INSTD ) / dt 1 / 2< is dependent on a variety of factors, such as, for example, the concentration of the at least one modulator, the composition of the at least one modulator, the volatility of the perfume raw material in the modulator, and the like.

[0060] In some aspects, the extent by which the at least one modulator influences d(A PRM / A INSTD ) / dt 1 / 2< at any modulator concentration (x% w / w) is determined by comparing the decrease in the ratio of A PRM / A INSTD in the presence of a known concentration of the at least one modulator (such as, for example 15% w / w) over the square root of time, with the decrease in the ratio of A PRM / A INSTD at second known concentration of the at least one modulator, such as, for example 0% w / w, over the square root of time.

[0061] In some aspects, the extent by which the at least one modulator influences d(A PRM / A INSTD ) / dt 1 / 2< at any modulator concentration (a x ) is determined by comparing d(A PRM / A INSTD ) / dt 1 / 2< in the presence of a known concentration of the at least one modulator

[0062] (such as, for example 15% w / w - a 15 ), with d(A PRM / A INSTD ) / dt 1 / 2< at second known concentration of the at least one modulator, such as, for example 0% w / w (a 0 ).

[0063] In some aspects, a 15 and a 0 are used to calculate a x , using the following equation: a x = a 15 + a 0 − a 15 15 − x / 15 − 0

[0064] In some instances a 15 , a 10 , as, or a 0 may be used to predict the amount of the perfume raw material present in solution at a given time.

[0065] In another aspect, the square of the ratio of a x / a 0 may be used to calculate the second vapor pressure of the perfume raw material in the presence of the at least one modulator at x wt%.

[0066] For example, by way of illustration, using the at least one modulator at a concentration of 15 wt%, relative to the total weight of the composition, the vapor pressure of the perfume raw material in the presence of the at least one modulator (referred to herein as the second vapor pressure of the perfume raw material) may be calculated as follows: a 15 / a 0 2 * P vap = P * vap . wherein: P vap = the first vapor pressure of the perfume raw material P* vap = the second vapor pressure of the perfume raw material

[0067] Accordingly, described herein (not according to the invention) is a method to predict how the at least one modulator may delay the time at which a consumer may be able to detect and recognize the presence of the perfume raw material. Alternatively, described herein (not according to the invention) is a method to predict how the at least one modulator may prolong the duration that the consumer may be able to detect and recognize the presence of the perfume raw material. Alternatively, described herein (not according to the invention) is a method to predict how the at least one modulator may prevent a consumer from being able to detect and recognize the presence of the perfume raw material. Without intending to be limited to any particular theory, the second vapor pressure of the perfume raw material may be a factor which may predict how a modulator may alter the consumer's perception of the perfume raw material in the manner described above.

[0068] Accordingly, described herein (not according to the invention) is a method to calculate the second vapor pressure of a given perfume raw material in the presence of the at least one modulator at a given concentration.

[0069] Accordingly, described herein (not according to the invention) is a method to ascertain, for any modulator and / or any concentration of modulator, the second vapor pressure for a perfume raw material. Moreover, based on the second vapor pressure, described herein (not according to the invention) is a method to classify, based on the particular modulator, and the concentration of the modulator, a palette of perfume raw ingredients according to whether, in the presence of the at least one modulator, the particular perfume raw material either: i. remains available for selection for use in the high volatility component, wherein the second vapor pressure of the perfume raw material is greater than 0.08 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 1); ii. no longer remains available for selection for use in the high volatility component, but becomes available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw material has a range of 0.0008 to 0.08 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 2); iii. remains available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw has a range of 0.0008 to 0.08 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 3; iv. no longer remains available for selection for use in the medium volatility component, but becomes available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw material is less than 0.0008 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 4); or v. remains available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw is less than 0.0008 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 5);

[0070] In some aspects, a perfume raw material may no longer remain available for selection for use in the medium volatility component because the perfume raw material may become suppressed (i.e. not perceived by the consumer) in the presence of the modulator. Examples of suitable perfume raw materials are shown in Table 6.

[0071] In some aspects, a perfume raw material remains available for selection for use in the low volatility component the perfume raw material may become suppressed (i.e. not perceived by the consumer) in the presence of the modulator. Examples of suitable perfume raw materials are shown in Table 7.

[0072] Additional examples of classified suitable perfume raw materials maybe found in Examples 1 and 2, and the tables listed therein. Referring to Examples 1 and 2, in some aspects, the particular modulator may affect the classification of the particular perfume raw material.

[0073] Also described herein (not according to the invention) is a method to calculate the second vapor pressure of a given perfume raw material in the presence of a particular the at least one modulator at a given concentration comprises the steps of: a. determining A PRM / A INSTD for the perfume raw material in solution, in the absence of the at least one modulator (A 0 ) over time; b. determining A PRM / A INSTD the perfume raw material in solution, in the presence of the at least one modulator at known concentration of modulator (A x ) over time; c. determining the vapor pressure of the perfume raw material in solution, in the absence of the at least one modulator (P vap ); and d. calculating, based on A 0 , A x , a 0 and a x ; and e. calculating, based on a 0 , a x , and P vap , the second vapor pressure for the perfume raw material in solution, in the presence of the modulator at known concentration of the at least one modulator (P* vap ).

[0074] In some aspects, the calculated second vapor pressure allows a perfumer to formulate a fragrance profile with an accord, such as, for example, a floral, or a fruity, or an aromatic, or a spicy, or an oriental accord characteristic of the middle notes, which can last for very long periods, especially throughout the life of the composition after its application, without giving way to the stronger odors of the base notes. Moreover, in some aspects, the calculated second vapor pressure allows a perfumer to utilize modulators in a manner that does not affect the consumer's initial perception of a fragrance profile: For example, a perfumer may select, based on a perfume raw materials calculated second vapor pressure, a top note that does not decrease in volatility in the presence of a modulator at a particular concentration.

[0075] In some aspects, the calculated second vapor pressure allows a perfumer to modify a fragrance profile and / or intensity of an existing composition formulated as a first consumer product to have the same fragrance profile and / or intensity when the existing composition is formulated as a second consumer product. For example, by way of illustration, a composition may be incorporated into a fine fragrance and the methods presented herein may allow a perfumer to reproduce the same fragrance profile and / or intensity of the fine fragrance in a soap, cream, household cleaner, and the like.

[0076] Formulation of the Fragrance Component: Referring to Figure 4, described herein (not according to the invention) is a method to construct various compositions utilizing perfume raw ingredients from a palette of raw ingredients that have as been classified according to whether particular perfume raw material either: i. remains available for selection for use in the high volatility component, wherein the second vapor pressure of the perfume raw material is greater than 0.08 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 1); ii. no longer remains available for selection for use in the high volatility component, but becomes available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw material has a range of 0.0008 to 0.08 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 2); iii. remains available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw has a range of 0.0008 to 0.08 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 3; iv. no longer remains available for selection for use in the medium volatility component, but becomes available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw material is less than 0.0008 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 4); or v. remains available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw is less than 0.0008 Torr at 22°C (examples of suitable perfume raw materials are shown in Table 5);

[0077] In some aspects, a perfume raw material may no longer remain available for selection for use in the medium volatility component because the perfume raw material may become suppressed (i.e. not perceived by the consumer) in the presence of the modulator. Examples of suitable perfume raw materials are shown in Table 6.

[0078] In some aspects, a perfume raw material remains available for selection for use in the low volatility component the perfume raw material may become suppressed (i.e. not perceived by the consumer) in the presence of the modulator. Examples of suitable perfume raw materials are shown in Example 1 and Table 7.

[0079] Additional examples of classified suitable perfume raw materials maybe found in Examples 1 and 2, and the tables listed therein. Referring to Examples 1 and 2, in some aspects, the particular modulator may affect the classification of the particular perfume raw material.

[0080] Such a solution as presented herein provides enhanced longevity of the fragrance profile, particularly amongst those compositions formulated from volatile fragrance materials having medium to high vapor pressure ranges, without having to rely on the presence or significant amounts of the low volatile fragrance materials, which has a tendency to overpower and alter the overall character of a fragrance. This provides the perfumer options to formulate accords having new fragrance profiles. Table 1: Examples of perfume raw materials that remain available for selection for use in the high volatility component, wherein the second vapor pressure of the perfume raw material is greater than greater than 0.08 Torr at 22°C. COMMON NAME IUPAC NAME ETHYL BUTYRATEButanoic acid, ethyl esterBUTYL ACETATEAcetic acid, butyl esterAMYL ACETATE3-Methylbutyl acetateN 302(2E)-2-HexenalACETATE DE PRENYLE3-Methyl-2-buten-1-yl acetatePINENE MELANGE(1R,5R)-6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptaneETHYL 2-METHYLPENTANOATE (APPLINATE)Ethyl (2R)-2-methylpentanoateCAPROATE D'ETHYLEEthyl hexanoateEUCALYPTOL1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octaneIFFOCIMENE(3E)-3,7-Dimethyl-1,3,6-octatrieneLIMONENE 1 X DIST FAB(4R)-4-Isopropenyl-1-methylcyclohexeneHEXYL ACETATEHexyl acetatePIPOL ACETATE(3Z)-3-Hexen-1-yl acetateBUTYRATE D'AMYLE3-Methylbutyl butyratePIPOL DIST(3Z)-3-Hexen-1-olALDEHYDE BENZOIQUEBenzaldehydeACETOACETATE D'ETHYLEEthyl 3-oxobutanoateLIFFAROME(3Z)-3-Hexen-1-yl methyl carbonateALLYL CAPROATEAllyl hexanoatePHENYLACETALDEHYDEDIMETHYLACETAL (VERT DE LILAS)(2,2-Dimethoxyethyl)benzeneROSE OXIDE(2R,4R)-4-Methyl-2-(2-methyl-1-propen-1-yl)tetrahydro-2H-pyranBENZOATE DE METHYLEMethyl benzoateGALBANOLENE SUPER(3E,5Z)-1,3,5-UndecatrieneMETHYL PAMPLEMOUSSE6,6-Dimethoxy-2,5,5-trimethyl-2-hexeneBENZYL ACETATE EXTRABenzyl acetateHCMMethyl 2-octynoate Table 2: Examples of perfume raw materials that no longer remain available for selection for use in the high volatility component, but become available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw material has a range of 0.0008 to 0.08 Torr at 22°C. COMMON NAME IUPAC NAME ALDEHYDE MNA(2R)-2-MethylundecanalMELONAL(2R)-2,6-Dimethyl-5-heptenalZESTOVER(1RS,2RS)-2,4-dimethyl-3-cyclohexene-1-carbaldehyde (A)(1RS,2SR)-2,4-dimethyl-3-cyclohexene-1-carbaldehyde (B)ALDEHYDE C 9NonanalTRANS DECENAL(4E)-4-DecenalDIMETOL2,6-Dimethyl-2-heptanolPELARGODIENAL(2E,6Z)-2,6-NonadienalMENTHONE PURIFIEE2-Isopropyl-5-methylcyclohexanoneCAMPHRE(1R,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-oneFructoneEthyl (2-methyl-1,3-dioxolan-2-yl)acetatCITRONELLAL(3R)-3,7-Dimethyl-6-octenalPK EXTRAp-CresolESTRAGOLE1-Allyl-4-methoxybenzeneALDEHYDE C 10DecanalStyrallyl acetate(1R)-1-Phenylethyl acetateVIOLETTYNE 10 MIP(3E)-1,3-Undecadien-5-ynePIPOL ISOBUTYRATE(3Z)-3-Hexen-1-yl 2-methylpropanoateFIRASCONEmethyl (1RS,2SR)-2,6,6-trimethyl-3-cyclohexene-1-carboxylate (A)methyl (1RS,2RS)-2,6,6-trimethyl-3-cyclohexene-1-carboxylate (B)BENZOATE D'ETHYLEethyl benzoateDIHYDROMYRCENOL PURE(6R)-2,6-Dimethyl-7-octen-2-olALLYL HEPTANOATEAllyl heptanoateBenzyl alcoholPhenylmethanolROMASCONEMethyl (1R)-2,2-dimethyl-6-methylenecyclohexanecarboxylateBUTYRATE DE PIPOL(3Z)-3-Hexen-1-yl butyrateSAFRANAL2,6,6-Trimethyl-1,3-cyclohexadiene-1-carbaldehydeDELPHONE(2R)-2-PentylcyclopentanonePHENYLACETATE DE METHYLEMethyl phenylacetateOXANE(2R,4S)-2-Methyl-4-propyl-1,3-oxathianeLINALYL ACETATE AR(3R)-3,7-Dimethyl-1,6-octadien-3-yl acetateACETATE DE LINALYLE BJ(3R)-3,7-Dimethyl-1,6-octadien-3-yl acetateTETRALINOL PUR(3R)-3,7-Dimethyl-3-octanolPROPIONATE DE BENZYLEBenzyl propionateVerdox(1R,2R)-2-(2-Methyl-2-propanyl)cyclohexyl acetateDORISYLtrans-4-(2-Methyl-2-propanyl)cyclohexyl acetateCARBINOL MUGUET2-Methyl-4-phenyl-2-butanolISOBORNYL ACETATE(1R,2R)-1,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPT-2-YL ACETATEETHYL PHENYL ACETATEEthyl phenylacetateALDEHYDE C 11 LIQUEUndecanal Table 3: Examples of perfume raw materials remain available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw has a range of 0.0008 to 0.08 Torr at 22°C. COMMON NAME IUPAC NAME NONENOL(6Z)-6-Nonen-1-olPHENYL ETHYL ALCOHOL2-PhenylethanolCITRAL TOTAL(2E)-3,7-Dimethyl-2,6-octadienalSALICYLATE DE METHYLEmethyl 2-hydroxybenzoateANETHOLE1-Methoxy-4-[(1E)-1-propen-1-yl]benzeneCARVONE GAUCHE-5-Isopropenyl-2-methyl-2-cyclohexen-1-oneMOC2-Nonynoic acid, methyl ester2-PHENYL ETHYL ACETATE2-Phenylethyl acetateBENZYLACETONE PUR4-Phenyl-2-butanoneBASE XXI(2E,6Z)-2,6-Nonadien-1-ol2-PHENYLETHYL FORMATE2-Phenylethyl formateSTEMONE(+-)-(3E)-5-methyl-3-heptanone oxime (A)(+-)-(3Z)-5-methyl-3-heptanone oxime (B)OCTALACTONE G5-Butyldihydro-2(3H)-furanoneALLYL AMYL GLYCOLATEAllyl (3-methylbutoxy)acetateTerpenyl acetate2-(4-Methyl-3-cyclohexen-1-yl)-2-propanyl acetateACETATE DE TERPENYLE EXTRA2-[(1R)-4-Methyl-3-cyclohexen-1-yl]-2-propanyl acetateKOAVONE(+-)-3,5,6,6-tetramethyl-4-methylidene-2-heptanone (A)(+-)-(4E)-3,4,5,6,6-pentamethyl-4-hepten-2-one (B)(+-)-(3Z)-3,4,5,6,6-pentamethyl-3-hepten-2-one (C)(+-)-(3E)-3,4,5,6,6-pentamethyl-3-hepten-2-one (D)ALDEHYDE C 11 LENIQUE10-UndecenalDIMETHYLOCTANOL(3R)-3,7-Dimethyl-1-octanolALDEHYDE C 12LauraldehydeMENTHOL NAT(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanolTIGLATE DE PIPOL(3Z)-3-Hexen-1-yl (2E)-2-methyl-2-butenoateINDOLE1H-IndoleTerpineol ord(+-)-ALPHA-TERPINEOLAlpha terpineol(+-)-ALPHA-TERPINEOLALCOOL PHENYLPROPYLIQUE3-Phenyl-1-propanolDAMASCENATE D'ETHYLEETHYL 2,6,6-TRIMETHYL-1,3-CYCLOHEXADIENE-1-CARBOXYLATEALDEHYDE CINNAMIQUE(2E)-3-PhenylacrylaldehydeVELOUTONE2,2,5-Trimethyl-5-pentylcyclopentanoneNeryl acetate(2Z)-3,7-dimethyl-2,6-octadien-1-yl acetateACETATE DE GERANYLE SYNTH FCGeranyl acetateGeranyl acetateGeranyl acetateIndocolore1-Phenylvinyl acetateALDEHYDE ANISIQUE SPECIAL REDIST4-MethoxybenzaldehydeCITRONELLYL NITRILE(3R)-3,7-Dimethyl-6-octenenitrileISOSPIRENE TOTAL2,6,9,10-Tetramethyl-1-oxaspiro[4.5]deca-3,6-dieneCORANOL4-Cyclohexyl-2-methyl-2-butanolFLORHYDRAL(3R)-3-(3-Isopropylphenyl)butanalSCLAREOLATEPropyl (2S)-2-[(2-methyl-2-butanyl)oxy]propanoatePAMPLEWOOD3-Methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decaneMETHYLANTHRANILATE DE METHYLEMethyl 2-(methylamino)benzoateCITRONELLOL(3R)-3,7-Dimethyl-6-octen-1-olANTHRANILATE DE METHYLE DISTMethyl 2-aminobenzoateACETATE DE CARBINOL BDM2-Methyl-1-phenyl-2-propanyl acetateCitronellyl acetate(3R)-3,7-Dimethyl-6-octen-1-yl acetateACETATE DE VERDYLETricyclo[5.2.1.02,6]dec-3-en-8-yl acetateCedramber8-MethoxycedraneHEXENYL HEXENOATE (WILLIAMS ESTER)(3Z)-3-Hexen-1-yl (3Z)-3-hexenoateMETHYLISOEUGENOL1,2-Dimethoxy-4-[(1E)-1-propen-1-yl]benzeneHELIOTROPINE ORD1,3-Benzodioxole-5-carbaldehydeDelta damascone(2E)-1-[(1S,2S)-2,6,6-Trimethyl-3-cyclohexen-1-yl]-2-buten-1-oneFOLIAVER(2R)-3-(4-Methoxyphenyl)-2-methylpropanalISOBUTYRATE DE PHENYLETHYLE2-Phenylethyl 2-methylpropanoateCAPROATE D'HEXYLEHexyl hexanoateACETATE DE CINNAMYLE(2E)-3-Phenyl-2-propen-1-yl acetateBourgeonal3-[4-(2-Methyl-2-propanyl)phenyl]propanalCyclohexylpropionate d'allyle2-Propen-1-yl cyclohexanepropionateCyclosal(2R)-3-(4-Isopropylphenyl)-2-methylpropanalGamma nonalactone5-Pentyldihydro-2(3H)-furanoneDAMAROSE ALPHA(2E)-1-[(1R)-2,6,6-Trimethyl-2-cyclohexen-1-yl]-2-buten-1-oneDECALACTONE5-Hexyldihydro-2(3H)-furanoneNEOBUTENONE ALPHA1-(5,5-dimethyl-1-cyclohexen-1-yl)-4-penten-1-oneSULFOX 1 DIPG(2R,5R)-5-Methyl-2-(2-sulfanyl-2-propanyl)cyclohexanoneACROPAL3-(4-Methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehydeMPGEEthyl 3-methyl-3-phenyl-2-oxiranecarboxylateETHYL LINALLOL(3R,6E)-3,7-Dimethyl-1,6-nonadien-3-olPROPIONATE DE VERDYLETRICYCLO[5.2.1.0(2,6)]DEC-3-EN-8-YL PROPANOATE (A)TRICYCLO[5.2.1.0(2,6)]DEC-4-EN-8-YL PROPANOATE (B)NUSSOL EXTRA2-Hydroxy-3-methyl-2-cyclopenten-1-oneSCENTENAL8(9)-METHOXY-TRICYCLO[5.2.1.0(2,6)]DECANE-3(4)-CARBALDEHYDEPRECYCLEMONE B1-Methyl-4-(4-methyl-3-penten-1-yl)-3-cyclohexene-1-carbaldehydeJASMINLACTONE(6R)-6-[(2Z)-2-Penten-1-yl]tetrahydro-2H-pyran-2-oneCYCLOGALBANATEAllyl cyclohexyloxyacetateISORALDEINE 70 P(1E)-1-[(1R)-2,6,6-Trimethyl-2-cyclohexen-1-yl]-1-penten-3-oneLILYFLORE(2,5-Dimethyl-2,3-dihydro-1H-inden-2-yl)methanolJavanol(1'S,3'R)-{1-METHYL-2-[(1',2',2'-TRIMETHYLBICYCLO[3. 1.0]HEX-3'-YL)METHYL]CYCLOPROPYL}METHANOLEthylvanilline3-Ethoxy-4-hydroxybenzaldehyde Table 4: Examples of perfume raw materials that no longer remain available for selection for use in the medium volatility component, but become available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw material is less than 0.0008 Torr at 22°C. COMMON NAME IUPAC NAME NONENOL(6Z)-6-Nonen-1-olPHENYL ETHYL ALCOHOL2-PhenylethanolCITRAL TOTAL(2E)-3,7-Dimethyl-2,6-octadienalSALICYLATE DE METHYLEmethyl 2-hydroxybenzoateANETHOLE1-Methoxy-4-[(1E)-1-propen-1-yl]benzeneCARVONE GAUCHE(5R)-5-Isopropenyl-2-methyl-2-cyclohexen-1-oneMOC2-Nonynoic acid, methyl ester2-PHENYL ETHYL ACETATE2-Phenylethyl acetateBENZYLACETONE PUR4-Phenyl-2-butanoneBASE XXI(2E,6Z)-2,6-Nonadien-1-ol2-PHENYLETHYL FORMATE2-Phenylethyl formateSTEMONE(+-)-(3E)-5-methyl-3-heptanone oxime (A) (+-)-(3Z)-5-methyl-3-heptanone oxime (B)OCTALACTONE G5-Butyldihydro-2(3H)-furanoneALLYL AMYL GLYCOLATEAllyl (3-methylbutoxy)acetateTerpenyl acetate2-(4-Methyl-3-cyclohexen-1-yl)-2-propanyl acetateACETATE DE TERPENYLE EXTRA2-[(1R)-4-Methyl-3-cyclohexen-1-yl]-2-propanyl acetate(+-)-3,5,6,6-tetramethyl-4-methylidene-2-heptanone (A)KOAVONE(+-)-(4E)-3,4,5,6,6-pentamethyl-4-hepten-2-one (B)(+-)-(3Z)-3,4,5,6,6-pentamethyl-3-hepten-2-one (C)(+-)-(3E)-3,4,5,6,6-pentamethyl-3-hepten-2-one (D)ALDEHYDE C 11 LENIQUE10-UndecenalDIMETHYLOCTANOL(3R)-3,7-Dimethyl-1-octanolALDEHYDE C 12LauraldehydeMENTHOL NAT(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanolTIGLATE DE PIPOL(3Z)-3-Hexen-1-yl (2E)-2-methyl-2-butenoateINDOLE1H-IndoleTerpineol ord(+-)-ALPHA-TERPINEOLAlpha terpineol(+-)-ALPHA-TERPINEOLALCOOL PHENYLPROPYLIQUE3-Phenyl-1-propanolDAMASCENATE D'ETHYLEETHYL 2,6,6-TRIMETHYL-1,3-CYCLOHEXADIENE-1-CARBOXYLATEALDEHYDE CINNAMIQUE(2E)-3-PhenylacrylaldehydeVELOUTONE2,2,5-Trimethyl-5-pentylcyclopentanoneNeryl acetate(2Z)-3,7-dimethyl-2,6-octadien-1-yl acetateACETATE DE GERANYLE SYNTH FCGeranyl acetateGeranyl acetateGeranyl acetateIndocolore1-Phenylvinyl acetateALDEHYDE ANISIQUE SPECIAL REDIST4-MethoxybenzaldehydeCITRONELLYL NITRILE(3R)-3,7-Dimethyl-6-octenenitrileISOSPIRENE TOTAL2,6,9,10-Tetramethyl-1-oxaspiro[4.5]deca-3,6-dieneCORANOL4-Cyclohexyl-2-methyl-2-butanolFLORHYDRAL(3R)-3-(3-Isopropylphenyl)butanalSCLAREOLATEPropyl (2S)-2-[(2-methyl-2-butanyl)oxy]propanoatePAMPLEWOOD3-Methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decaneMETHYLANTHRANILATE DE METHYLEMethyl 2-(methylamino)benzoateCITRONELLOL(3R)-3,7-Dimethyl-6-octen-1-olANTHRANILATE DE METHYLE DISTMethyl 2-aminobenzoateACETATE DE CARBINOL BDM2-Methyl-1-phenyl-2-propanyl acetateCitronellyl acetate(3R)-3,7-Dimethyl-6-octen-1-yl acetateACETATE DE VERDYLETricyclo[5.2.1.02,6]dec-3-en-8-yl acetateCedramber8-MethoxycedraneHEXENYL HEXENOATE (WILLIAMS ESTER)(3Z)-3-Hexen-1-yl (3Z)-3-hexenoateMETHYLISOEUGENOL1,2-Dimethoxy-4-[(1E)-1-propen-1-yl]benzeneHELIOTROPINE ORD1,3-Benzodioxole-5-carbaldehydeDelta damascone(2E)-1-[(1S,2S)-2,6,6-Trimethyl-3-cyclohexen-1-yl]-2-buten-1-oneFOLIAVER(2R)-3-(4-Methoxyphenyl)-2-methylpropanalISOBUTYRATE DE PHENYLETHYLE2-Phenylethyl 2-methylpropanoateCAPROATE D'HEXYLEHexyl hexanoate Table 5: Examples of perfume raw materials that remain available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw is less than 0.0008 Torr at 22°C. COMMON NAME IUPAC NAME PARADISONEMethyl [(1R,2S)-3-oxo-2-pentylcyclopentyl]acetateHedioneMethyl [(1S,2S)-3-oxo-2-pentylcyclopentyl]acetateMUSC DTI1-[1,1-Dimethyl-6-(2-methyl-2-propanyl)-2,3-dihydro-1H-inden-4-yl]ethanonAldehyde hexylcinnamique(2E)-2-BenzylideneoctanalSANDALORE3-Methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-pentanolIso E (or Derambrene)1-(2,3,8,8-Tetramethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenyl)ethanoneDERAMBRENE1-(2,3,8,8-Tetramethyl-1,2,3,5,6,7,8,8a-octahydro-2-naphthalenyl)ethanoneAMIONE(1E)-1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-oneNorlimbanol1-(2,2,6-Trimethylcyclohexyl)-3-hexanolAMBRINOL2,5,5-Trimethyl-1,2,3,4,4a,5,6,7-octahydro-2-naphthalenolGalaxolide 70 BB(4R,7S)-4,6,6,7,8,8-Hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromeneCORPS PRALINE3-Hydroxy-2-methyl-4H-pyran-4-oneDARTANOL(2E)-2-Ethyl-4-[(1R)-2,2,3-trimethyl-3-cyclopenten-1-yl]-2-buten-1-olTRANSLUZONE7-(2-Methyl-2-propanyl)-2H-1,5-benzodioxepin-3(4H)-oneEBANOL(E)-3-METHYL-5-(2,2,3-TRIMETHYL-3-CYCLOPENTEN-1-YL)-4-PENTEN-2-OLMousse cristalMETHYL 2,4-DIHYDROXY-3,6-DIMETHYLBENZOATELIMBANOL(+-)-1-(2,2,3,6-TETRAMETHYL-CYCLOHEXYL)-3-HEXANOLHabanolide(12E)-Oxacyclohexadec-12-en-2-oneEthyl praline2-Ethyl-3-hydroxy-4H-pyran-4-oneFIRSANTOL2-Methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-1-olPipol salicylate(3Z)-3-Hexen-1-yl salicylateMuscone(3R)-3-MethylcyclopentadecanoneBENZYL SALICYLATEBenzyl salicylateAmbrettolide(10E)-Oxacycloheptadec-10-en-2-oneRomandolide2-{(1RS)-1-[(1SR)-3,3-dimethylcyclohexyl]ethoxy}-2-oxoethyl propionate (A)2-{(1RS)-1-[(1RS)-3,3-dimethylcyclohexyl]ethoxy}-2-oxoethyl propionate (B)2-oxo-2-{[(1RS,2RS)-2,6,6-trimethylcycloheptyl]oxy}ethyl propionate (C)2-oxo-2-{[(1RS,2SR)-2,6,6-trimethylcycloheptyl]oxy}ethyl propionate (D)EXALTONECyclopentadecanoneVERTOFIX COEUR1-(Cedr-8-en-9-yl)ethanoneEXALTOLIDEOxacyclohexadecan-2-oneLyral(1R)-4-(4-Hydroxy-4-methylpentyl)-3-cyclohexene-1-carbaldehydeMuscenone dextro(3R,5E)-3-Methyl-5-cyclopentadecen-1-one Table 6: Examples of perfume raw materials that no longer remain available for selection for use in the medium volatility component because the perfume raw material becomes suppressed (i.e. not perceived by the consumer) in the presence of the modulator. COMMON NAME IUPAC NAME Nerol(Z)-3,7-DIMETHYL-2,6-OCTADIEN-1-OLGERANIOL(E)-3,7-DIMETHYL-2,6-OCTADIEN-1-OLACETATE DE NOPYLE2-(6,6-DIMETHYL-BICYCLO[3.1.1]HEPT-2-EN-2-YL)ETHYL ACETATEFLOROL(+-)-TETRAHYDRO-2-ISOBUTYL-4-METHYL-4(2H)-PYRANOLINDOMETHYLENE4,4A,5,9B-TETRAHYDRO-INDENO[1,2-D]-1,3-DIOXINIsoeugenol2-methoxy-4-[(1E)-1-propen-1-yl]phenolRESEDA BODY2-BENZYL-4,4,6-TRIMETHYL-1,3-DIOXANEMETHYLIONONE GAMMA COEUR(+-)-(E)-3-METHYL-4-(2,6,6-TRIMETHYL-2-CYCLOHEXEN-1-YL)-3-BUTEN-2-ONEIRALIA(+-)-(3E)-3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one (A)(+-)-(1E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1-penten-3-one (B)HELIOPROPANAL(+-)-3-(1,3-BENZODIOXOL-5-YL)-2-METHYLPROPANALFARENAL(+-)-2,6,10-TRIMETHYL-9-UNDECENALCORPS RHUBARBE(+-)-1,3-DIMETHYL-3-PHENYLBUTYL ACETATEMETHYL JASMONATEmethyl {(1RS,2RS)-3-oxo-2-[(2Z)-2-penten-1-yl]cyclopentyl}acetate Table 7: Examples of perfume raw materials that no longer remain available for selection for use in the low volatility component because the perfume raw material becomes suppressed (i.e. not perceived by the consumer) in the presence of the modulator. COMMON NAME IUPAC NAME CEDRENOL(+-)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-olHexyl salicylateHEXYL 2-HYDROXYBENZOATEGalaxolide 70 DIPG(+-)-4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromeneGalaxolide 70 MIP Extra(+-)-4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromeneBacdanol(+-)-2-ETHYL-4-(2,2,3-TRIMETHYL-3-CYCLOPENTEN-1-YL)-2-BUTEN-1-OLDioxycarbinol2-BENZYL-1,3-DIOXOLANE-4-METHANOL (A)2-BENZYL-1,3-DIOXAN-5-OL (B)Polysantol(-)-(2R,4E)-3,3-dimethyl-5-[(1R)-2,2,3-trimethyl-3-cyclopenten-1-yl]-4-penten-2-ol (A)(-)-(2S,4E)-3,3-dimethyl-5-[(1R)-2,2,3-trimethyl-3-cyclopenten-1-yl]-4-penten-2-ol (B)NIRVANOL(+)-(2S,4E)-3,3-dimethyl-5-[(1S)-2,2,3-trimethyl-3-cyclopenten-1-yl]-4-penten-2-ol (A)(+)-(2R,4E)-3,3-dimethyl-5-[(1S)-2,2,3-trimethyl-3-cyclopenten-1-yl]-4-penten-2-ol (B)MYRRHONE(+-)-(E)-4-(2,2,C-3,T-6-TETRAMETHYL-R-1-CYCLOHEXYL)-3-BUTEN-2-ONE (A)(+-)-(E)-4-(2,2,T-3,T-6-TETRAMETHYL-R-1-CYCLOHEXYL)-3-BUTEN-2-ONE (B)ASTROTONE1,4-dioxacycloheptadecane-5,17-dione

[0081] In one aspect, perfume raw materials suitable to include in a composition according to an embodiment presented herein are selected from the perfume raw materials set forth in Table 8. Table 8: Examples of perfume raw materials that may be utilized with at least one modulator having a vapor pressure of less than 0.0008 Torr at 22°C and Hansen solubility parameters according to several aspects presented herein COMMON NAME IUPAC NAME CINNAMYL PROPIONATE(E)-3-PHENYL-2-PROPENYL PROPANOATEALCOHOL C 121-dodecanolTRIDECYLENIC ALDEHYDE(2E)-2-tridecenalCETALOX LAEVODodecahydro-3a,6,6,9a-tetramethylnaphtho(2,1-b)furanSANDALORE(+-)-3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-pentanolGAMMA UNDECALACTONE5-heptyloxolan-2-oneTRICYCLONE(1R-(1alpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-oneEXALTONEcyclopentadecanoneUNDECALACTONE DELTA(+-)-5-heptyldihydro-2(3H)-furanone 6-hexyltetrahydro-2H-pyran-2-oneNEROLIDOL3,7,11-TRIMETHYL-1,6,10-DODECATRIEN-3-OLHELVETOLIDE ®< (+)-(1S,1'R)-2-[1-(3',3'-DIMETHYL-1'-CYCLOHEXYL)ETHOXY]-2-METHYLPROPYL PROPANOATEMUGUET ALDEHYDE ARR(+-)-(3,7-DIMETHYL-6-OCTENYLOXY)ACETALDEHYDECEDROXYDE ®< (+-)-(4Z,8E)-1,4,8-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene(+-)-(4Z,8E)-1,5,8-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-dienePIPOL SALICYLATE(3Z)-3-hexen-1-yl salicylateBACDANOL(+-)-2-ETHYL-4-(2,2,3-TRIMETHYL-3-CYCLOPENTEN-1-YL)-2-BUTEN-1-OLJASMOLACTONE DELTA(+-)-(Z)-8-DECEN-5-OLIDE(+-)-(E)-8-DECEN-5-OLIDEDARTANOL ®< (-)-(2E)-2-ethyl-4-[(1R)-2,2,3-trimethyl-3-cyclopenten-1-yl]-2-buten-1-olROMANDOLIDE ®< 2-{(1RS)-1-[(1 SR)-3,3-dimethylcyclohexyl]ethoxy}-2-oxoethyl propionate2-oxo-2-{[(1RS,2SR)-2,6,6-trimethylcycloheptyl]oxy}ethyl propionate2-{(1RS)-1-[(1RS)-3,3-dimethylcyclohexyl]ethoxy}-2-oxoethyl propionate2-oxo-2-{[(1RS,2RS)-2,6,6-trimethylcycloheptyl]oxy}ethyl propionateNOOTKATONE PURE(+)-(4R,4aS,6R)-4,4a-dimethyl-6-(1-propen-2-yl)-4,4a,5,6,7,8-hexahydro-2(3H)-naphthalenoneNORLIMBANOL ®< DEXTRO(+)-(3R)-1-[(1R,6S)-2,2,6-trimethylcyclohexyl]-3-hexanol(+)-(3S)-1-[(1R,6S)-2,2,6-trimethylcyclohexyl]-3-hexanol1-[(1S,6S)-2,2,6-trimethylcyclohexyl]-3-hexanolAMIONE(1E)-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,6-heptadien-3-one(+-)-(1E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-oneHEDIONE ®< methyl 2-((1RS,2RS)-3-oxo-2-pentylcyclopentyl)acetateHEXYL SALICYLATEHEXYL 2-HYDROXYBENZOATEEXALTOLIDE ®< oxacyclohexadecan-2-oneCETALOX ®< (3aRS,5aSR,9aSR,9bRS)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furanAMBROX ®< (-)-(3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furanMUSCONE(+-)-3-methylcyclopentadecanoneEXALTENONE(Z)-4-CYCLOPENTADECEN-1-ONEAMBRETTOLIDE(10E)-oxacycloheptadec-10-en-2-oneDODECALACTONE CP(+-)-5-octyldihydro-2(3H)-furanonePARADISONE ®< methyl 2-[(1R,2S)-3-oxo-2-pentylcyclopentyl]acetateMETHYL JASMONATEmethyl {(1RS,2RS)-3-oxo-2-[(2Z)-2-penten-1-yl]cyclopentyl}acetateGALAXOLIDE4,6,6,7,8,8-hexamethyl-1,3,4,7-tetrahydrocyclopenta[g]isochromeneCYCLOPENTADECANOLIDEOxacyclohexadecan-2-oneNORLIMBANOL ®< 1-[(1RS,6SR)-2,2,6-trimethylcyclohexyl]-3-hexanolDODECALACTONE DELTA(+-)-6-heptyltetrahydro-2H-pyran-2-oneAMBROX ®< SUPER(-)-(3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furanBENZYL BENZOATEBENZYL BENZOATEMUSC X1-TERT-BUTYL-3,5-DIMETHYL-2,4,6-TRINITROBENZENEAMYLCINNAMIC ALDEHYDE R(2E)-2-benzylideneheptanalHEXYLCINNAMIC ALDEHYDE(2E)-2-benzylideneoctanalLIMBANOL ®< (+-)-1-(2,2,3,6-TETRAMETHYL-CYCLOHEXYL)-3-HEXANOLCIVETTONE(9Z)-9-cycloheptadecen-1-oneMUSK KETONE1-(4-tert-butyl-2,6-dimethyl-3,5-dinitrophenyl)ethanoneVULCANOLIDE ®< (6RS,7RS)-3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydro-2-naphthalenecarbaldehydeIPMpropan-2-yl tetradecanoate

[0082] In some aspects, the composition according to the invention constructed using the method described herein comprises: a. ethanol, in an amount from 30 to 75 wt% relative to the total weight of the composition; b. a fragrance component present in an amount from 0.04 to 40 wt%, relative to the total weight of the composition, wherein the fragrance component comprises: i. a high volatility component an amount from 0.08 to 55 wt% of the fragrance component, comprising a. a first at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C; and b. a second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C; ii. a medium volatility component in an amount from 0.08 to 85 wt% of the fragrance component, comprising: a. a first at least one perfume raw material having a first vapor pressure range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) Torr at 22°C; and b. a second at least one perfume raw material having a first vapor pressure range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C; and c. at least one modulator selected from the group consisting of: 3,7,11-trimethyl-1,6,10-dodecatrien-3-ol; Methyl 2-(3-oxo-2-pentylcyclopentyl)ethanoate; methyl 2-[(1R,2S)-3-oxo-2-pentylcyclopentyl]acetate; methyl 2-[(1R,2R)-3-oxo-2-[(Z)-pent-2-enyl]cyclopentyl]acetate; propan-2-yl tetradecanoate; and combinations thereof; in an amount from 5.0 to 20 wt%, relative to the total weight of the composition; wherein the first vapor pressure of the at least one first perfume raw material of the high volatility component is determined in the absence of the at least one modulator; wherein the first vapor pressure of the at least one second perfume raw material of the high volatility component is determined in the absence of the at least one modulator; wherein the at least one modulator changes the first vapor pressure of the at least one second perfume raw material of the high volatility component to a second vapor pressure; wherein the second vapor pressure of the at least one second perfume raw material of the high volatility component is in the range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C; wherein the first vapor pressure range of the at least one first perfume raw material of the medium volatility component is determined in the absence of the at least one modulator; wherein the first vapor pressure range of the at least one second perfume raw material of the medium volatility component is determined in the absence of the at least one modulator; wherein the at least one modulator changes the first vapor pressure range of the at least one second perfume raw material of the medium volatility component to a second vapor pressure; and wherein the second vapor pressure of the at least one second perfume raw material of the medium volatility component is less than 0.0008 Torr (0.1067 Pa) at 22°C.

[0083] In some aspects, the fragrance component present in an amount from 0.04 to 20 wt%, relative to the total weight of the composition.

[0084] In some aspects, the composition further comprises water, in an amount of less than or equal to 15 wt% relative to the total weight of the composition.

[0085] In some aspects, the composition further comprises water, in an amount 5 to 15 wt% relative to the total weight of the composition.

[0086] In some aspects, the composition further comprises water, in an amount 0 to 5 wt% relative to the total weight of the composition.

[0087] In certain aspects, the compositions of the present invention comprise at least 5, at least 10, at least 15 or at least 20 perfume raw materials. If there is more than one perfume raw material, then the ranges provided hereinabove cover the total weight of all of the perfume raw materials.

[0088] In some aspects, the first at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C is present at 0.008, 0.009, 0.01, 0.015, 0.02, 0.025, 0.03, 0.035, 0.04, 0.045, 0.04, 0.045, 0.05, 0.055, 0.06, 0.065, 0.07, 0.075, 0.08, 0.085, 0.09, 0.095, 0.1, 0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, 0.55, 0.6, 0.65, 0.7, 0.75, 0.8, 0.85, 0.9, 0.95, 1, 1.15, 1.2, 1.25, 1.3, 1.35, 1.4, 1.45, 1.5, 1.55, 1.6, 1.65, 1.7, 1.75, 1.8, 1.85, 1.9, 1.95, 2, 2.15, 2.2, 2.25, 2.3, 2.35, 2.4, 2.45, 2.5, 2.55, 2.6, 2.65, 2.7, 2.75, 2.8, 2.85, 2.9, 2.95, 3, 3.15, 3.2, 3.25, 3.3, 3.35, 3.4, 3.45, 3.5, 3.55, 3.6, 3.65, 3.7, 3.75, 3.8, 3.85, 3.9, 3.95, 4, 4.15, 4.2, 4.25, 4.3, 4.35, 4.4, 4.45, 4.5, 4.55, 4.6, 4.65, 4.7, 4.75, 4.8, 4.85, 4.9, 4.95, 5, 5.15, 5.2, 5.25, 5.3, 5.35, 5.4, 5.45, 5.5, 5.55, 5.6, 5.65, 5.7, 5.75, 5.8, 5.85, 5.9, 5.95, 6, 6.15, 6.2, 6.25, 6.3, 6.35, 6.4, 6.45, 6.5, 6.55, 6.6, 6.65, 6.7, 6.75, 6.8, 6.85, 6.9, 6.95, 7, 7.15, 7.2, 7.25, 7.3, 7.35, 7.4, 7.45, 7.5, 7.55, 7.6, 7.65, 7.7, 7.75, 7.8, 7.85, 7.9, 7.95, 8, 8.15, 8.2, 8.25, 8.3, 8.35, 8.4, 8.45, 8.5, 8.55, 8.6, 8.65, 8.7, 8.75, 8.8, 8.85, 8.9, 8.95, 9, 9.15, 9.2, 9.25, 9.3, 9.35, 9.4, 9.45, 9.5, 9.55, 9.6, 9.65, 9.7, 9.75, 9.8, 9.85, 9.9, 9.95, 10, 15, 20, 25, 30, 35, 40, 45, 50, or 55 wt% of the fragrance component.

[0089] In some aspects, first at least one perfume raw material having a first vapor pressure range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C is present at 0.008, 0.009, 0.01, 0.015, 0.02, 0.025, 0.03, 0.035, 0.04, 0.045, 0.04, 0.045, 0.05, 0.055, 0.06, 0.065, 0.07, 0.075, 0.08, 0.085, 0.09, 0.095, 0.1, 0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, 0.55, 0.6, 0.65, 0.7, 0.75, 0.8, 0.85, 0.9, 0.95, 1, 1.15, 1.2, 1.25, 1.3, 1.35, 1.4, 1.45, 1.5, 1.55, 1.6, 1.65, 1.7, 1.75, 1.8, 1.85, 1.9, 1.95, 2, 2.15, 2.2, 2.25, 2.3, 2.35, 2.4, 2.45, 2.5, 2.55, 2.6, 2.65, 2.7, 2.75, 2.8, 2.85, 2.9, 2.95, 3, 3.15, 3.2, 3.25, 3.3, 3.35, 3.4, 3.45, 3.5, 3.55, 3.6, 3.65, 3.7, 3.75, 3.8, 3.85, 3.9, 3.95, 4, 4.15, 4.2, 4.25, 4.3, 4.35, 4.4, 4.45, 4.5, 4.55, 4.6, 4.65, 4.7, 4.75, 4.8, 4.85, 4.9, 4.95, 5, 5.15, 5.2, 5.25, 5.3, 5.35, 5.4, 5.45, 5.5, 5.55, 5.6, 5.65, 5.7, 5.75, 5.8, 5.85, 5.9, 5.95, 6, 6.15, 6.2, 6.25, 6.3, 6.35, 6.4, 6.45, 6.5, 6.55, 6.6, 6.65, 6.7, 6.75, 6.8, 6.85, 6.9, 6.95, 7, 7.15, 7.2, 7.25, 7.3, 7.35, 7.4, 7.45, 7.5, 7.55, 7.6, 7.65, 7.7, 7.75, 7.8, 7.85, 7.9, 7.95, 8, 8.15, 8.2, 8.25, 8.3, 8.35, 8.4, 8.45, 8.5, 8.55, 8.6, 8.65, 8.7, 8.75, 8.8, 8.85, 8.9, 8.95, 9, 9.15, 9.2, 9.25, 9.3, 9.35, 9.4, 9.45, 9.5, 9.55, 9.6, 9.65, 9.7, 9.75, 9.8, 9.85, 9.9, 9.95, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, or 85 wt% of the fragrance component.

[0090] In one aspect, the high volatility component comprises the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C in an amount from 0.1 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 1.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 2.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 3.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 4.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 5.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 6.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 7.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 8.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.2 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.3 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.35 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.4 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.45 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.5 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.55 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.6 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.65 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.7 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.75 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.8 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.85 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.9 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 9.95 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 10 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 15 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 20 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 30 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 35 to 40 wt% of the fragrance component.

[0091] Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C is present in an amount ranging from 0.1 to 35 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 30 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 25 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 20 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 15 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 10 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.2 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1.1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 1 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.9 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.8 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.7 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.6 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.5 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.4 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.3 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr at 22°C is present in an amount ranging from 0.1 to 0.2 wt% of the fragrance component.

[0092] In some aspects, the second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C is present at 0.1, 0.15, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, 0.5, 0.55, 0.6, 0.65, 0.7, 0.75, 0.8, 0.85, 0.9, 0.95, 1, 1.15, 1.2, 1.25, 1.3, 1.35, 1.4, 1.45, 1.5, 1.55, 1.6, 1.65, 1.7, 1.75, 1.8, 1.85, 1.9, 1.95, 2, 2.15, 2.2, 2.25, 2.3, 2.35, 2.4, 2.45, 2.5, 2.55, 2.6, 2.65, 2.7, 2.75, 2.8, 2.85, 2.9, 2.95, 3, 3.15, 3.2, 3.25, 3.3, 3.35, 3.4, 3.45, 3.5, 3.55, 3.6, 3.65, 3.7, 3.75, 3.8, 3.85, 3.9, 3.95, 4, 4.15, 4.2, 4.25, 4.3, 4.35, 4.4, 4.45, 4.5, 4.55, 4.6, 4.65, 4.7, 4.75, 4.8, 4.85, 4.9, 4.95, 5, 5.15, 5.2, 5.25, 5.3, 5.35, 5.4, 5.45, 5.5, 5.55, 5.6, 5.65, 5.7, 5.75, 5.8, 5.85, 5.9, 5.95, 6, 6.15, 6.2, 6.25, 6.3, 6.35, 6.4, 6.45, 6.5, 6.55, 6.6, 6.65, 6.7, 6.75, 6.8, 6.85, 6.9, 6.95, 7, 7.15, 7.2, 7.25, 7.3, 7.35, 7.4, 7.45, 7.5, 7.55, 7.6, 7.65, 7.7, 7.75, 7.8, 7.85, 7.9, 7.95, 8, 8.15, 8.2, 8.25, 8.3, 8.35, 8.4, 8.45, 8.5, 8.55, 8.6, 8.65, 8.7, 8.75, 8.8, 8.85, 8.9, 8.95, 9, 9.15, 9.2, 9.25, 9.3, 9.35, 9.4, 9.45, 9.5, 9.55, 9.6, 9.65, 9.7, 9.75, 9.8, 9.85, 9.9, 9.95, 10, 15, 20, 25, 30, 35, or 40 wt% of the fragrance component.

[0093] In one aspect, the medium volatility component comprises the second at least one perfume raw material having a first vapor pressure range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C in an amount from 20 to 45 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 25 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 30 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 35 to 40 wt% of the fragrance component.

[0094] Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C is present in an amount ranging from 20 to 40 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 35 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 30 wt% of the fragrance component. Alternatively, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present in an amount ranging from 20 to 25 wt% of the fragrance component.

[0095] In some aspects, the second at least one perfume raw material having a first vapor pressure range of 0.0008 to 0.08 Torr at 22°C is present at 20, 25, 30, 35, 40, or 45 wt% of the fragrance component.

[0096] In one aspect, the fragrance component further comprises at least one perfume raw material having a first vapor pressure less than 0.0008 Torr at 22°C in an amount from 10 to 55 wt% of the fragrance component.

[0097] In one aspect, the fragrance component further comprises at least one perfume raw material having a first vapor pressure less than 0.0008 Torr at 22°C in an amount from 30 to 55 wt% of the fragrance component.

[0098] In one aspect, the fragrance component further comprises at least one perfume raw material having a first vapor pressure less than 0.0008 Torr at 22°C in an amount from 10 to 30 wt% of the fragrance component.

[0099] The at Least One Modulator: The compositions presented herein further comprise at least one modulator selected from the group consisting of: 3,7,11-trimethyl-1,6,10-dodecatrien-3-ol; Methyl 2-(3-oxo-2-pentylcyclopentyl)ethanoate; methyl 2-[(1R,2S)-3-oxo-2-pentylcyclopentyl]acetate; methyl 2-[(1R,2R)-3-oxo-2-[(Z)-pent-2-enyl]cyclopentyl]acetate; propan-2-yl tetradecanoate; and combinations thereof. Without intending to be limited to any particular theory, the at least one modulator is configured to allow a perfumer to formulate a fragrance profile with an accord, such as, for example, a floral, or a fruity, or an aromatic, or a spicy, or an oriental accord characteristic of the middle notes, which can last for very long periods, especially throughout the life of the composition after its application, without giving way to the stronger odors of the base notes. In addition the modulator is configured to allow a perfumer to utilize modulators in a manner that does not affect the consumer's initial perception of a fragrance profile: For example, a perfumer may select, based on a perfume raw materials calculated second vapor pressure, a top note that does not decrease in volatility in the presence of a modulator at a particular concentration. Moreover, the modulator is configured to reduce, prevent, or ameliorate the formation of a film on the consumer's skin.

[0100] In another aspect, the at least one modulator is configured to allow the removal of water from perfume compositions without negatively impacting the performance of the perfuming compositions. Table 9: Examples of some modulators (modulators according to the invention are indicated mTorrMPa 1 / 2< (µg / l air)NAMEIUPAC namePvapδ D δ p δ H VolatilityALCOHOL C 12dodecanol0.69914.0483.3229.3177.01SANDALORE3-Methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol0.62015.8483.3099.4987.02METHYLISOEUGENOL(E)-1,2-Dimethoxy-4-(prop-1-en-1-yl)benzene0.57116.3935.7378.7025.48EXALTONECyclopentadecanone0.47417.0812.4543.1755.73NEROLIDOL (according to the invention)3,7,11-trimethyl-1,6,10-dodecatrien-3-ol0.44416.3153.1869.9245.32MUGUET ALDEHYDE ARR6,10-Dimethyl-3-oxa-9-undecenal0.44016.3062.6916.4814.7CEDROXYDE ®< (4E,8E)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene0.42417.0112.8924.0895.03JASMOLACTONE DELTA6-[(E)-pent-2-enyl]oxan-2-one0.37916.7547.2515.8563.43ROMANDOLIDE ®< Aceticacid,(1-oxopropoxy)-,1-(3,3-dimethylcyclohexyl)ethyl0.29214.5123.0397.2994.25NOOTKATONE PURE4-α,5-Dimethyl-1,2,3,4,4α,5,6,7-octahydro-7-keto-3-isopropenylnaphthalene0.27016.9685.5666.7733.18AMIONE(+-)-(1E)-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-one (A); (1E)-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,6-heptadien-3-one (B)0.24116.3873.3015.5423.01HEDIONE ®< (according to the invention)Methyl 2-(3-oxo-2-pentylcyclopentyl)ethanoate0.21816.8523.7595.5102.66HEXYL SALICYLATEhexyl 2-hydroxybenzoate0.21617.9267.41310.1602.58EXALTOLIDE ®< oxacyclohexadecan-2-one0.19517.3034.6213.8992.52MUSCONE3-methylcyclopentadecan-1-one0.14016.7122.2863.1321.8EXALTENONEcyclopentadec-4-en-1-one0.13916.7252.5114.0941.67AMBRETTOLIDE(8E)-1-oxacycloheptadec-8-en-2-one0.13916.944.3864.5081.89PARADISONE ®< methyl 2-[(1R,2S)-3-oxo-2-pentylcyclopentyl]acetate0.13416.8523.7595.5101.63METHYL JASMONATEmethyl 2-[(1R,2R)-3-oxo-2-[(Z)-pent-2-enyl]cyclopentyl]acetate0.13216.4263.8616.2301.59GALAXOLIDE4,6,6,7,8,8-hexamethyl-1,3,4,7-tetrahydrocyclopenta[g]isochromene0.11417.2161.8744.7451.59DODECALACTONE DELTA6-heptyloxan-2-one0.08417.225.9574.4850.896BENZYL BENZOATEbenzyl benzoate0.07419.1567.6506.2940.848AMYLCINNAMIC ALDEHYDE(2E)-2-benzylideneheptanal0.06317.982.4095.6900.682HEXYLCINNAMIC ALDEHYDE(2E)-2-benzylideneoctanal0.06117.9372.2305.4750.708CIVETTONE(9Z)-cycloheptadec-9-en-1-one0.03116.7132.2093.8440.424IPM (according to the invention)propan-2-yl tetradecanoate0.00016.22.0004.0000

[0101] The at least one modulator is present in an amount from 5 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.1 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.2 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.3 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.4 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.5 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.6 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.7 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.8 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 5.9 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.1 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.2 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.3 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.4 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.5 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.6 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.7 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.8 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 6.9 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.1 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.2 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.3 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.4 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.5 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.6 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.7 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.8 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 7.9 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.1 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.2 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.3 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.4 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.5 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.6 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.7 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.8 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 8.9 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.1 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.2 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.3 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.4 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.5 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.6 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.7 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.8 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 9.9 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 10 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 10 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 11 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 12 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 13 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 14 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 15 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 16 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 17 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 18 to 20 wt%, relative to the total weight of the composition. Alternatively, the at least one modulator is present in an amount from 19 to 20 wt%, relative to the total weight of the composition.

[0102] In some aspects, the at least one modulator is present at 5, or 5.1, or 5.2, or 5.3, or 5.4, or 5.5, or 5.6, or 5.7, or 5.8, or 5.9, or 6, or 6.1, or 6.2, or 6.3, or 6.4, or 6.5, or 6.6, or 6.7, or 6.8, or 6.9, or 7, 7.1, or 7.2, or 7.3, or 7.4, or 7.5, or 7.6, or 7.7, or 7.8, or 7.9, or 8, or 8.1, or 8.2, or 8.3, or 8.4, or 8.5, or 8.6, or 8.7, or 8.8, or 8.9, or 9, or 9.1, or 9.2, or 9.3, or 9.4, or 9.5, or 9.6, or 9.7, or 9.8, or 9.9, or 10, or 10.1, or 10.2, or 10.3, or 10.4, or 10.5, or 10.6, or 10.7, or 10.8, or 10.9, or 11, or 11.1, or 11.2, or 11.3, or 11.4, or 11.5, or 11.6, or 11.7, or 11.8, or 11.9, or 12, or 12.1, or 12.2, or 12.3, or 12.4, or 12.5, or 12.6, or 12.7, or 12.8, or 12.9, or 13, or 13.1, or 13.2, or 13.3, or 13.4, or 13.5, or 13.6, or 13.7, or 13.8, or 13.9, or 14, or 14.1, or 14.2, or 14.3, or 14.4, or 14.5, or 14.6, or 14.7, or 14.8, or 14.9, or 15, or 15.1, or 15.2, or 15.3, or 15.4, or 15.5, or 15.6, or 15.7, or 15.8, or 15.9, or 16, or 16.1, or 16.2, or 16.3, or 16.4, or 16.5, or 16.6, or 16.7, or 16.8, or 16.9, or 17, or 17.1, or 17.2, or 17.3, or 17.4, or 17.5, or 17.6, or 17.7, or 17.8, or 17.9, or 18, 18.1, or 18.2, or 18.3, or 18.4, or 18.5, or 18.6, or 18.7, or 18.8, or 18.9, or 19, or 19.1, or 19.2, or 19.3, or 19.4, or 19.5, or 19.6, or 19.7, or 19.8, or 19.9, or 20%, relative to the total weight of the composition.

[0103] In some aspects, the concentration of the at least one modulator is 15 wt%, relative to the total weight of the composition.

[0104] The compositions presented herein may further comprise additional components, such as, for example, polymers; capsules, microcapsules and nanocapsules; liposomes, absorbents; cyclic oligosaccharides and mixtures thereof. Examples of suitable additional components are described in International Patent Application Publication No. WO 2015 / 089246 A1. In some embodiments, the additional components comprise cyclodextrin. In some embodiments, the cyclodextrin further contains at least one compound having a cLogP value from 1.5 to 3.5. In some aspects, the cLogP value is from 2 to 3.

[0105] In some aspects, the at least one compound has an odor value from 1 to 10,000.

[0106] In some aspects, the at least one compound within the capsules has a C I2.5 from 0.1 and 10 µg / l. Table 10: Examples of at least one compound having a cLogP value from 1.5 to 3.5 according to several aspects presented herein COMMON NAME IUPAC NAME 2 E-HEXENYL ACETATE BIONAT KHEXYL ACETATE2-NAPHTHALENETHIOL naphthalene-2-thiol2-NONANONE NAT2-NONANONE4-ETHYL OCTANOIC ACID(+-)-4-ethyloctanoic acidALADINATE ®< (2E)-3-methyl-2-hexen-1-yl acetateALCOHOL C 6 K NAT1-hexanolALCOHOL C 6 K NAT PF1-hexanolALCOHOL C 6 PURIF1-hexanolALCOHOL C 8 REDIST1-octanolALDEHYDE C 6 FChexanalALDEHYDE C 7heptanalALDEHYDE C 8octanalALDEHYDE C 9nonanalALDOLONE ®< 7-PROPYL-2H,4H-1,5-BENZODIOXEPIN-3-ONEALLYL AMYL GLYCOLATE(+-)-ALLYL (2-METHYLBUTOXY)ACETATEALLYL PHENOXYACETATE ALLYL PHENOXYACETATEAMBRINOL OXIDE (+-)-4A,8A-EPOXY-PERHYDRO-2,5,5-TRIMETHYL-2-NAPHTHALENOLAMYL ACETATE3-METHYLBUTYL ACETATEAMYL ISOBUTYRATE3-methylbutyl 2-methylpropanoateAMYL PROPIONATE(+-)-2-METHYLBUTYL PROPANOATEANISYL ACETATE4-METHOXYBENZYL ACETATEANISYL ACETONE4-(4-methoxyphenyl)butan-2-oneAPPLINATEethyl 2-methylpentanoateAQUOZONE3-(butylamino)-4-phenoxy-5-sulfamoylbenzoic acidAROMATONE(1RS,2SR,5SR,7RS,8SR)-5-methyltricyclo[6.2.1.0~2,7~]undecan-4-oneASMAROL (+-)-1-HEXYL-1,3-PROPANEDIYL DIACETATEBENZOPHENONEBENZOPHENONEBENZYL ACETATEbenzyl acetateBENZYL ISOBUTYRATE BENZYL ISOBUTYRATEBENZYL PROPIONATE BENZYL PROPANOATEBENZYL TIGLATEBENZYL (E)-2-METHYL-2-BUTENOATEBENZYL VALERIANATEBENZYL 3-METHYLBUTANOATEBENZYLDIMETHYLCARBINOL ACETATE1,1-DIMETHYL-2-PHENYLETHYL ACETATEBORNEOL CRYST(+)-(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olBOURGEONAL3-(4-TERT-BUTYLPHENYL)PROPANALISOPROPYL METHYLBUTYRATE(+-)-ISOPROPYL 2-METHYLBUTANOATEISOPROPYL QUINOLINE8-isopropylquinolineISOPULEGOL(1R,2S,5R)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-olJASMAL(3RS,4SR)-3-pentyltetrahydro-2H-pyran-4-yl acetate TETRAHYDRO-3-PENTYL-4(2H)-PYRANYL ACETATEJASMOLACTONE DELTA (+-)-(Z)-8-DECEN-5-OLIDEJOSENOL ®< (2E)-2-METHYL-3-(4-METHYLPHENYL)-2-PROPEN-1-OLKOUMALACTONE ®< (3SR,3ARS,6SR,7ASR)-PERHYDRO-3,6-DIMETHYL-BENZO[B]FURAN-2-ONELEMONILE3,7-DIMETHYL-2,6-NONADIENENITRILELEVOCITROL(+-)-3,7-DIMETHYL-6-OCTEN-1-OLLIFFAROME(3Z)-hex-3-en-1-yl methyl carbonateLILYFLORE ®< (+-)-2,5-DIMETHYL-2-INDANMETHANOLLIME OXIDE1,3,3-trimethyl-2-oxabicyclo[2.2.2]octaneLINALOL BJ(+-)-3,7-dimethyl-1,6-octadien-3-olLYRAL(+-)-4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carbaldehydeMAGNOLAN(+-)-2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine (ISOMER A)MAYOL ®< [trans-4-(2-propanyl)cyclohexyl]methanolMELONAL2,6-Dimethyl-5-heptenalMENTHOL(-)-L-MENTHOLMENTHONE PURIFIED(2RS,5 SR)-5-methyl-2-(2-propanyl)cyclohexanoneMETHYL ANISATEMETHYL 4-METHOXYBENZOATEMETHYL BENZOATEMETHYL BENZOATEMETHYL BENZOATE NAT FIRINCMETHYL BENZOATEMETHYL CAPROATEMETHYL HEXANOATEMETHYL CINNAMATEmethyl (E)-3-phenylprop-2-enoateMETHYL CRESOTINATEMETHYL 2-HYDROXY-5-METHYLBENZOATEMETHYL CYCLOGERANATE2-cyclohexene-1-carboxylic acid 2,6,6,-trimethyl methyl esterMETHYL DISULFIDE MFMETHYL 2-METHYL-3-FURYL DISULFIDEMETHYL HEPTINECARBONATEMETHYL 2-OCTYNOATEMETHYL JASMONATE methyl {(1RS,2RS)-3-oxo-2-[(2Z)-2-penten-1-yl]cyclopentyl}tacetateMETHYL METHYL ANTHRANILATEmethyl 2-(methylamino)benzoateMETHYL SALICYLATEMETHYL 2-HYDROXYBENZOATEMETHYLCINNAMIC ALDEHYDE(2E)-2-methyl-3-phenyl-2-propenalMETHYLHEPTYLKETONEnonan-2-oneMETHYLHEXYLKETONE2-OCTANONEMETHYLISOEUGENOL 1,2-dimethoxy-4-[(1E)-1-propen-1-yl]benzene

[0107] According to the invention, ethanol is present in an amount of from about 30 to 75 wt%, relative to the total weight of the composition. Any acceptable quality of ethanol, compatible and safe for the specific intended use of the composition such as, for example, topical applications of fine fragrance or cosmetic compositions, and is convenient for use in the compositions according to the present invention.

[0108] The compositions presented herein may comprise a non-volatile solvent or a mixture of non-volatile solvents. Non-limiting examples of non-volatile solvents include benzyl benzoate, diethyl phthalate, isopropyl myristate, propylene glycol, dipropylene glycol, triethyl citrate, and mixtures thereof. These solvents often are introduced to the product via the perfume oil as many perfume raw materials may be purchased as a dilution in one of these solvents. Where non-volatile solvents are present, introduced either with the perfume materials or separately, then for the purposes of calculating the vapor pressure, the total fragrance components does not include non- volatile solvents.

[0109] In some aspects, the composition further comprises at least one hydrophilic solvent. In one aspect, the at least one hydrophilic solvent is selected from the group consisting of: propylene glycol, dipropylene glycol, ethylene glycol, triethyl citrate, disiopropyl glycol monomethyl ether, diethylene glycol monoethyl ether; triacetin, methylmethoxybutanol, benzyl alcohol, propylene glycol n-butyl ether; a glycol ether, an ester of diethylene glycol, and a cellosolve derivative. In one aspect, the glycol ether is a glycol ether sold under the tradename DOWANOL. In one aspect, the ether of diethylene glycol is sold under the tradename CARBITOL.

[0110] In some aspects, the glycol ether sold under the tradename DOWANOL is selected from the group consisting of: DOWANOL ™< DPMA Glycol Ether; DOWANOL ™< PM Glycol Ether; DOWANOL EPH ELP; DOWANOL ™< EPh; DOWANOL ™< PnB Glycol Ether; DOWANOL ™< TPnB; DOWANOL ™< DPnB Glycol Ether; DOWANOL ™< TPM Glycol Ether; DOWANOL ™< PPh Glycol Ether; DOWANOL ™< PnP Glycol Ether; DOWANOL ™< DPH 255 Glycol Ether; DOWANOL ™< PGDA Glycol Ether; DOWANOL ™< DPM Glycol Ether; DOWANOL ™< TPnB-H Gly Ether; DOWANOL ™< Solvents for Home & Personal Care; DOWANOL ™< DPnP Glycol Ether; DOWANOL ™< PMA Glycol Ether; DOWANOL ™< DiPPh Glycol Ether.

[0111] In some aspects, the cellosolve derivative is selected from the group consisting of: propyl cellosolve, butyl cellosolve, hexyl cellosolve, and cellosolve.EXAMPLES Example 1 (not according to the invention): The Effect of Modulators According to Some Aspects Presented Herein on the Second Vapor Pressure of Selected Perfume Raw Materials, Wherein the Modulator Comprises PPG-20 Methyl Glucose Ether and Isocetyl Alcohol

[0112] The first vapor pressure for the perfume raw materials indicated in Tables 11 to 15 was determined using standard methods at 22 °C. The perfume raw materials were then added to the following modulators, wherein the final concentration of the modulator was 15 wt%, relative to the total weight of the composition: 1. PPG-20 methyl glucose ether and isocetyl alcohol (1:2 ratio); 2. PPG-20 methyl glucose ether and isocetyl alcohol (1.5:1.5 ratio); 3. PPG-20 methyl glucose ether and isocetyl alcohol (2:1); or 4. PPG-20 methyl glucose ether only

[0113] The second vapor pressure for the selected perfume raw materials was then determined, and the perfume raw materials were classified as follows:

[0114] Whether, in the presence of the modulator, the selected perfume raw material either: i. remains available for selection for use in the high volatility component, wherein the second vapor pressure of the perfume raw material is greater than 0.08 Torr at 22°C; ii. no longer remains available for selection for use in the high volatility component, but becomes available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw material has a range of 0.0008 to 0.08 Torr at 22°C; iii. remains available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw has a range of 0.0008 to 0.08 Torr at 22°C; iv. no longer remains available for selection for use in the medium volatility component, but becomes available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw material is less than 0.0008 Torr at 22°C; or v. remains available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw is less than 0.0008 Torr at 22°C.

[0115] The results are shown in the tables below. Table 11: Examples of perfume raw materials that remain available for selection for use in the high volatility component, wherein the second vapor pressure of the perfume raw material is greater than greater than 0.08 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and isocetyl alcohol (1:2)PPG-20 methyl glucose ether and isocetyl alcohol (1.5:1.5)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose etherzestover*methyl pamplemoussemethyl pamplemousse*: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator Table 12: Examples of perfume raw materials that no longer remain available for selection for use in the high volatility component, but become available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw material has a range of 0.0008 to 0.08 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and isocetyl alcohol (1:2)PPG-20 methyl glucose ether and isocetyl alcohol (1.5:1.5)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose etherzestover*zestover*zestover*methyl pamplemoussemethyl pamplemousse *: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator Table 13: Examples of perfume raw materials remain available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw has a range of 0.0008 to 0.08 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and isocetyl alcohol (1:2)PPG-20 methyl glucose ether and isocetyl alcohol (1.5:1.5)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose ethercitral §< citral §< citral*citral*Aldehyde C12*Aldehyde C12*Aldehyde C12*Aldehyde C12*citronellol*citronellol*citronellol*citronellol*geraniolfoliaverfoliaverdecalactone*decalactone*decalactone*decalactone*heliopropanal*j avanolj avanolj avanol §< : Denotes a high impact perfume raw material that became a low impact perfume raw material in the presence of the modulator *: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator Table 14: Examples of perfume raw materials that no longer remain available for selection for use in the medium volatility component, but become available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw material is less than 0.0008 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and isocetyl alcohol (1:2)PPG-20 methyl glucose ether and isocetyl alcohol (1.5:1.5)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose ethergeraniolgeraniolgeraniol +< nerolnerolnerol +< nerolfoliaverfoliaverliliallilialliliallilial*heliopropanal*heliopropanal +< heliopropanal*calone*calone*calone*calone* *: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator +< : Denotes a perfume raw material that becomes suppressed in the presence of the modulator Table 15: Examples of perfume raw materials that remain available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw is less than 0.0008 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and isocetyl alcohol (1:2)PPG-20 methyl glucose ether and isocetyl alcohol (1.5:1.5)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose etherhedionehedionehedionehedionebacdanol*bacdanol*bacdanol +< bacdanol*astrotone +< astrotone +< *: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator +< : Denotes a perfume raw material that becomes suppressed in the presence of the modulator Example 2 (not according to the invention): The Effect of Modulators According to Some Aspects Presented Herein on the Second Vapor Pressure of Selected Perfume Raw Materials, Wherein the Modulator Comprises PPG-20 Methyl Glucose Ether and Various Long Chain Alcohols

[0116] The first vapor pressure for the perfume raw materials indicated in Tables 16 to 20 below was determined using standard methods at 22 °C. The perfume raw materials were then added to the following modulators, wherein the final concentration of the modulator was 15 wt%, relative to the total weight of the composition: 1. PPG-20 methyl glucose ether and octyldodecanol (2:1 ratio); 2. PPG-20 methyl glucose ether and isostearyl alcohol (2:1 ratio); 3. PPG-20 methyl glucose ether and isocetyl alcohol (2:1 ratio); or 4. 10% wt% PPG-20 methyl glucose ether only (calculated)

[0117] The second vapor pressure for the selected perfume raw materials was then determined, and the perfume raw materials were classified as follows:

[0118] Whether, in the presence of the modulator, the selected perfume raw material either: i. remains available for selection for use in the high volatility component, wherein the second vapor pressure of the perfume raw material is greater than 0.08 Torr at 22°C; ii. no longer remains available for selection for use in the high volatility component, but becomes available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw material has a range of 0.0008 to 0.08 Torr at 22°C; iii. remains available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw has a range of 0.0008 to 0.08 Torr at 22°C; iv. no longer remains available for selection for use in the medium volatility component, but becomes available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw material is less than 0.0008 Torr at 22°C; or v. remains available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw is less than 0.0008 Torr at 22°C.

[0119] The results are shown in the tables below. Table 16: Examples of perfume raw materials that remain available for selection for use in the high volatility component, wherein the second vapor pressure of the perfume raw material is greater than greater than 0.08 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and octyldodecanol (2:1)PPG-20 methyl glucose ether and isostearyl alcohol (2:1)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose ether and vehiclezestover*zestover*zestover*methyl pamplemoussemethyl pamplemoussemethyl pamplemoussemethyl pamplemousse*: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator Table 17: Examples of perfume raw materials that no longer remain available for selection for use in the high volatility component, but become available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw material has a range of 0.0008 to 0.08 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and octyldodecanol (2:1)PPG-20 methyl glucose ether and isostearyl alcohol (2:1)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose ether and vehiclezestover* *: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator Table 18: Examples of perfume raw materials remain available for selection for use in the medium volatility component, wherein the second vapor pressure of the perfume raw has a range of 0.0008 to 0.08 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and octyldodecanol (2:1)PPG-20 methyl glucose ether and isostearyl alcohol (2:1)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose ether and vehiclecitral §< citral §< citral*citral*Aldehyde C12*Aldehyde C12*citronellol*citronellol*geraniolnerol §< foliaverfoliaverdecalactone*decalactone*javanoljavanol §< : Denotes a high impact perfume raw material that became a low impact perfume raw material in the presence of the modulator *: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator Table 19: Examples of perfume raw materials that no longer remain available for selection for use in the medium volatility component, but become available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw material is less than 0.0008 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and octyldodecanol (2:1)PPG-20 methyl glucose ether and isostearyl alcohol (2:1)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose ether and vehicleAldehyde C12*Aldehyde C12*citronellol*citronellol*geraniol +< geraniolgeraniol +< nerolnerolnerol +< nerolfoliaverfoliaverdecolactone*decolactone §< liliallilialliliallilial*heliopropanal*heliopropanal*heliopropanal +< heliopropanal*javanoljavanol +< calone*calone*calone*calone* §< : Denotes a high impact perfume raw material that became a low impact perfume raw material in the presence of the modulator *: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator +< : Denotes a perfume raw material that becomes suppressed in the presence of the modulator Table 20: Examples of perfume raw materials that remain available for selection for use in the low volatility component, wherein the second vapor pressure of the perfume raw is less than 0.0008 Torr at 22°C. Modulator (15 wt%, relative to the total weight of the composition)PPG-20 methyl glucose ether and octyldodecanol (2:1)PPG-20 methyl glucose ether and isostearyl alcohol (2:1)PPG-20 methyl glucose ether and isocetyl alcohol (2:1)PPG-20 methyl glucose ether and vehiclehedionehedionehedionehedionebacdanol*bacdanol +< bacdanol +< bacdanol*astrotone +< astrotone +< astrotone +< astrotone +< *: Denotes a high impact perfume raw material that remains a high impact perfume raw material in the presence of the modulator +< : Denotes a perfume raw material that becomes suppressed in the presence of the modulator

[0120] Taken together, the data presented in Examples 1 and 2 demonstrate that the effect that one modulator may have on the second vapor pressure of a given perfume raw material may be different than another modulator. This is further illustrated in Figure 6, which denotes perfume raw materials wherein the second vapor pressure is different in a modulator comprising 15 wt% PPG-20 methyl glucose ether, relative to the total weight of the composition, compared to a modulator comprising 10 wt% PPG-20 methyl glucose ether and 5 wt% isocetyl alcohol.Example 3: The Effect of an at Least One Modulator on Fragrance Retention

[0121] The following fragrance was used in the construction of a composition according to an aspect presented herein Fragrance PRM Impact parts ALDEHYDE C 10106.400.2ALDEHYDE MNA6864.370.1CALONE ®< 2393.111CASHMERAN193.681CITRONELLOL BJ790.8520CYCLOSAL304.195DIHYDROMYRCENOL412.17102DYNASCONE ®< 7594.651FLORALOZONE690.881FLORHYDRAL329.2913FLOROL ®< 195.4950GALBANOLENESUPER742.416HELIOTROPIN1506.752LIMINAL ®< 1173.985NEROL BJ2381.3210POLYWOOD ®< 775.6320TRANS DECENAL4765.961UNDECAVERTOL163.061VIOLETTYNE 10 MIP160.201ZESTOVER187.3317

[0122] Samples of the compositions were constructed as follows, where the at least one modulator was added to the ethanol fraction, followed by the addition of the fragrance: (% wt)Fragrance5.00%Modulator (either IPM or Hedione)15.00% EtOH 40B75.00%H 2 O5.00%Total100.00%

[0123] Extraction of dry down and headspace analysis was done using GC-MS instrument and fragrance applied as described as follows: 10 µl of the composition was added to an aluminum crucible, using a positive displacement pipette. The crucible was then placed on a slide warmer, set at 32 °C, wherein the slide warmer was open to the air. The crucible was removed at 0, 2, and 4 hours, and placed into a 2 ml GC vial. When placed into the vial, 600 µl of ethanol was added to the GC vial, and the residual fragrance within the sample was determined via GC / MS. The results are shown in Figure 7. Referring to Figure 7, the presence of either IPM or HEDIONE in the composition increased the retention of the fragrance in the sample, compared to a sample lacking an at least one modulator (water control).

[0124] The rate of release of the fragrance from the sample was also determined in parallel samples. The results of the release of various perfume raw materials into the headspace are shown in Figure 8. The rate of release of perfume raw materials into the headspace observed was initially slower with either the modulator HEDIONE or IPM. However, the release of release increase, and was much greater that that observed with water, after either 4, or 6 hours dry down.Example 4: The Effect of an at Least One Modulator on Fragrance Retention

[0125] The following fragrance was used in the construction of a composition according to an aspect presented herein. StatusFragrance PRM%TOPALDEHYDE C 90.03TOPSAFRANAL0.13TOPLINALOL BJ8.68TOPDIHYDROMYRCENOL PUR9.64TOPACETATE C 96.43TopNEROL BJ8.03MiddleALDEHYDE C 120.03MiddleDAMAROSE ALPHA1.29MiddleMETHYL ANTHRANILATE0.22MiddleGERANIOL PUR7.39MiddleFLOROL ®< 25.71MiddleCIS JASMONE0.19BottomIRALIA ®< 4.18BottomMAYOL ®< 3.21BottomINDOL0.16BottomGAMMA NONALACTONE0.26BottomCYCLOSAL4.82BottomEUGENOL F0.32BottomALCOOL CINNAMIQUE ORD3.21BottomHYDROXYCITRONELLAL16.07100.00

[0126] Compositions comprising either the modulator HEDIONE at 15% or the modulator benzyl salycilate (not according to the invention) at 15 % were constructed. Fragrance retention and rate of release into a headspace from the compositions was determined according to the methods described in Example 3 above, wherein samples were taken following 1 and 4 hours dry down. The results for fragrance retention are shown in Figures 9 a and b, and 10 respectively.

[0127] Referring to Figures 9 and 10, while both HEDIONE and benzyl salicylate both increased the retention of fragrance within the crucible over time, compared to compositions comprising water instead of an at least one modulator, the amount of fragrance retained benzyl salicylate was used as the at least one modulator was less than that observed when HEDIONE was used as the at least one modulator.

[0128] Benzyl Salicylate and Hedione's Hansen solubility factors are shown below relative to the Hansen solubility factors of top and middle notes used in perfumery. DPHHEDIONE ®< 16.85 3.76 5.51 BENZYL SALICYLATE19.02 8.3011.94 TOP NOTESDPHAverage15.834.166.72STDev3.592.674.14 MIDDLE NOTESDPH-bondAverage16.854.617.66STDev2.713.073.28

[0129] Without intending to be limited to any particular theory, given the Hansen solubility factors of both HEDIONE and benzyl salicylate, the interaction of the modulator HEDIONE with top and middle notes is expected to be greater than the interaction of the modulator benzyl salicylate with top and middle notes.Example 5: The Effect of an at Least One Modulator on Fragrance Retention

[0130] The following fragrance was used in the construction of a composition according to an aspect presented herein. Fragrance PRM Impact parts ALDEHYDE C 10106.400.2ALDEHYDE MNA6864.370.1CALONE ®< 2393.111CASHMERAN193.681CITRONELLOL BJ790.8520CYCLOSAL304.195DIHYDROMYRCENOL412.17102DYNASCONE ®< 7594.651FLORALOZONE690.881FLORHYDRAL329.2913FLOROL ®< 195.4950GALBANOLENESUPER742.416HELIOTROPIN1506.752LIMINAL ®< 1173.985NEROL BJ2381.3210POLYWOOD ®< 775.6320TRANS DECENAL4765.961UNDECAVERTOL163.061VIOLETTYNE 10 MIP160.201ZESTOVER187.3317

[0131] Compositions comprising either the modulator HEDIONE at 15% or the modulator benzyl salycilate (not according to the invention) at 15 % were constructed. Fragrance retention and rate of release into a headspace from the compositions was determined according to the methods described in Example 3 above, wherein samples were taken following 1 and 4 hours dry down. The results for fragrance retention are shown in Figures 11 a and b, and 12 respectively.

[0132] Referring to Figures 11 and 12, while both HEDIONE and benzyl salicylate both increased the retention of fragrance within the crucible over time, compared to compositions comprising water instead of an at least one modulator, the amount of fragrance retained benzyl salicylate was used as the at least one modulator was less than that observed when HEDIONE was used as the at least one modulator.

[0133] Benzyl Salicylate and Hedione's Hansen solubility factors are shown below relative to the Hansen solubility factors of top and middle notes used in perfumery. DPHHEDIONE ®< 16.85 3.76 5.51 BENZYL SALICYLATE19.02 8.3011.94 TOP NOTESDPHAverage15.834.166.72STDev3.592.674.14 MIDDLE NOTESDPH-bondAverage16.854.617.66STDev2.713.073.28

[0134] Without intending to be limited to any particular theory, given the Hansen solubility factors of both HEDIONE and benzyl salicylate, the interaction of the modulator HEDIONE with top and middle notes is expected to be greater than the interaction of the modulator benzyl salicylate with top and middle notes.

Claims

1. A composition: wherein the composition comprises: a. ethanol, in an amount from 30 to 75 wt% relative to the total weight of the composition; b. a fragrance component present in an amount from 0.04 to 40 wt%, relative to the total weight of the composition, wherein the fragrance component comprises: i. a high volatility component an amount from 0.08 to 55 wt% of the fragrance component, comprising a. a first at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C; and b. a second at least one perfume raw material having a first vapor pressure greater than 0.08 Torr (10.67 Pa) at 22°C; ii. a medium volatility component in an amount from 0.08 to 85 wt% of the fragrance component, comprising: a. a first at least one perfume raw material having a first vapor pressure range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C; and b. a second at least one perfume raw material having a first vapor pressure range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C; and c. at least one modulator selected from the group consisting of: 3,7,11-trimethyl-1,6,10-dodecatrien-3-ol; Methyl 2-(3-oxo-2-pentylcyclopentyl)ethanoate; methyl 2-[(1R,2S)-3-oxo-2-pentylcyclopentyl]acetate; methyl 2-[(1R,2R)-3-oxo-2-[(Z)-pent-2-enyl]cyclopentyl]acetate; propan-2-yl tetradecanoate; and combinations thereof; in an amount from 5.0 to 20 wt%, relative to the total weight of the composition; wherein the first vapor pressure of the at least one first perfume raw material of the high volatility component is determined in the absence of the at least one modulator; wherein the first vapor pressure of the at least one second perfume raw material of the high volatility component is determined in the absence of the at least one modulator; wherein the at least one modulator changes the first vapor pressure of the at least one second perfume raw material of the high volatility component to a second vapor pressure; wherein the second vapor pressure of the at least one second perfume raw material of the high volatility component is in the range of 0.0008 Torr (0.1067 Pa) to 0.08 Torr (10.67 Pa) at 22°C; wherein the first vapor pressure range of the at least one first perfume raw material of the medium volatility component is determined in the absence of the at least one modulator; wherein the first vapor pressure range of the at least one second perfume raw material of the medium volatility component is determined in the absence of the at least one modulator; wherein the at least one modulator changes the first vapor pressure range of the at least one second perfume raw material of the medium volatility component to a second vapor pressure; and wherein the second vapor pressure of the at least one second perfume raw material of the medium volatility component is less than 0.0008 Torr (0.1067 Pa) at 22°C; wherein the vapor pressure is determined according to the reference program Advanced Chemistry Development Software Version 11.02.

2. The composition of claim 1, wherein the fragrance component present in an amount from 0.04 to 20 wt%, relative to the total weight of the composition.

3. The composition according to any one of claims 1 and 2, wherein the composition further comprises water, in an amount of less than or equal to 15 wt% relative to the total weight of the composition.

4. The composition according to any one of claims 1 to 3, wherein the composition further comprises water, in an amount 5 to 15 wt% relative to the total weight of the composition.

5. The composition according to any one of claim 1 to 4, wherein the composition further comprises water, in an amount 0 to 5 wt% relative to the total weight of the composition.

6. The composition according to any one of claims 1 to 5, wherein the at least one modulator is in an amount from 6.0 to 20 wt%, relative to the total weight of the composition.

7. The composition according to any one of claims 1 to 6, wherein the at least one modulator is in an amount from 7.0 to 20 wt%, relative to the total weight of the composition.

8. The composition according to any one of claims 1 to 7, wherein the at least one modulator is in an amount from 8.0 to 20 wt%, relative to the total weight of the composition.

9. The composition according to any one of claims 1 to 8, wherein the at least one modulator is in an amount from 9.0 to 20 wt%, relative to the total weight of the composition.

10. The composition according to any one of claims 1 to 9, wherein the at least one modulator is in an amount from 10.0 to 20 wt%, relative to the total weight of the composition.

11. The composition according to any one of claims 1 to 10, wherein the at least one modulator is in an amount from 11.0 to 20 wt%, relative to the total weight of the composition.

12. The composition according to any one of claims 1 to 11, wherein the composition further comprises at least one hydrophilic solvent.

13. The composition of claim 12, wherein the at least one hydrophilic solvent is selected from the group consisting of: propylene glycol, dipropylene glycol, ethylene glycol, triethyl citrate, disiopropyl glycol monomethyl ether, diethylene glycol monoethyl ether; triacetin, methylmethoxybutanol, benzyl alcohol, propylene glycol n-butyl ether; a glycol ether, an ester of diethylene glycol, and a cellosolve derivative.

14. A method for modifying or enhancing the odor properties of a body surface, such as hair or skin, a substrate, such as fabric, furnishings, dishes, hard surfaces and related materials, comprising contacting or treating the body surface or substrate with the composition according to any one of claim 1 to 13.