Resin system and method for impregnating, strengthening or electrically insulating a body bearing a winding

Abstract

The present invention relates to a resin system, wherein the resin system is in the form of a two-component system and comprises a resin as a first component and a curing agent as a second component for the purposes of curing the resin, and the first component and the second component are coordinated with one another as follows: - the parts-by-volume mixing ratio is 3 parts resin to 1 part curing agent up to 1 part resin to 3 parts curing agent; and - the ratio of the viscosities of the first component and the second component lies in a range from 1 to 5 up to 5 to 1.

Description

[0001] Description

[0002] Resin system and method for impregnating, solidifying or electrically insulating a winding-carrying body

[0003] The present invention relates to a resin system comprising a resin and a hardener. The present invention further relates to the use of such a resin system in a method for impregnating, solidifying, or electrically insulating a body carrying a winding, as well as to a method for impregnating, solidifying, or electrically insulating a body carrying a winding.

[0004] Low-voltage motors are impregnated during the manufacturing process using a liquid resin, which is then usually hardened by adding heat over a certain period of time, thus producing a thermosetting molded material and effective electrical insulation (EIS) and mechanical strengthening of the winding.

[0005] EP 3 872 962 A1 relates to a method for impregnating, solidifying or electrically insulating a body carrying single-layer or multi-layer windings, in particular for an electrical machine, wherein the body carrying the windings is dipped into a multi-component resin system or is dripped with the multi-component resin system or is sprayed with the multi-component resin system. This document further relates to an electrical machine, in particular a motor, generator or transformer, impregnated, solidified or electrically insulated by such a method and to the use of a multi-component resin system for impregnating, solidifying or electrically insulating an electrical machine.

[0006] However, solutions known from the state of the art still have further potential for improvement, particularly with regard to the best possible processability of a resin system for impregnating, solidifying or electrically insulating a body carrying a winding.

[0007] The object of the present invention is to at least partially overcome the disadvantages known from the prior art. In particular, the object of the present invention is to provide a solution that enables good processability of a resin system for impregnating, solidifying, or electrically insulating a body carrying a winding.

[0008] The object is achieved according to the invention at least in part by a resin system having the features of claim 1. The object is further achieved according to the invention at least in part by a method having the features of claim 7 and by a use having the features of claim 10. Preferred embodiments of the invention are described in the subclaims, in the description or the figures, wherein further features described or shown in the subclaims or in the description or the figures can represent an object of the invention individually or in any combination, unless the context clearly indicates the opposite.

[0009] A resin system is described, wherein the resin system is designed as a two-component system and comprises a resin as a first component and a hardener for hardening the resin as a second component, wherein the first component and the second component are coordinated with one another as follows:

[0010] The parts-by-volume mixing ratio is from 3 parts resin to 1 part hardener to 1 part resin to 3 parts hardener; and the ratio of the viscosities of the first component and the second component is in a range from 1 to 5 to 5 to 1. Such a resin system has clear advantages over prior art solutions, particularly when used in a process for impregnating, solidifying or electrically insulating a body carrying single-layer or multi-layer windings. Such a process is to be understood hereinafter in particular as treating a body carrying single-layer or multi-layer windings. The body is advantageously an electric motor or generator or a transformer. The body advantageously has a rotor and a stator.

[0011] The resin system described here is designed as a two-component system. It therefore comprises two different components that are particularly advantageously coordinated with one another, as described below.

[0012] The resin system comprises a resin as a first component. The resin system comprises a hardener for hardening the resin as a second component. The resin and hardener are advantageously matched to enable the resin to be hardened in a suitable manner. Such adaptation of the type of hardener to the type of resin is, in principle, easily possible for a person skilled in the art.

[0013] The first component and the second component, i.e. the resin and the hardener, are matched to each other in addition to the purely chemical compatibility as follows.

[0014] The parts-by-volume mixing ratio is 3 parts resin to 1 part hardener to 1 part resin to 3 parts hardener. Preferably, the parts-by-volume mixing ratio is 1.5 parts resin to 1 part hardener to 1 part resin to 1.5 parts hardener. For example, the parts-by-volume mixing ratio is 1 part resin to 1 part hardener.

[0015] Furthermore, the ratio of the viscosities of the first component and the second component, i.e. the resin and the hardener, is in a range from 1 to 5 to 5 to 1. Preferably, the ratio of the viscosities of the first component and the second component can be in a range from 1 to 2 to 2 to 1. For example, the ratio of the viscosities of the first component and the second component can be in a range from 1 to 1. This viscosity describes an initial viscosity at 25 ° C, whereby the relative viscosity ratio remains the same regardless of the temperature and the measuring method. In principle, however, the viscosity can be determined according to DIN EN ISO 2431: 2011.

[0016] It has surprisingly been shown that the above-described adaptation of resin and hardener can permit particularly advantageous properties. In particular, the above-described adaptation of the parts-by-volume mixing ratio and the ratio of the viscosities of the first and second components, i.e., of resin and hardener, can permit a particularly advantageous application, particularly in a process for impregnating, solidifying, or electrically insulating a body carrying single- or multi-layer windings, such as a component of an electrical machine or an electric motor.

[0017] By precisely adjusting the parameters described above, temperature increases during the drip-forming process, as well as during the gelling and curing processes, are not necessary to achieve a reasonable production time. Furthermore, inexpensive, static mixing tubes can be used, allowing the individual components to be mixed in-situ, eliminating the need for manual cleaning or system downtime.

[0018] According to the invention, the described processes can therefore be implemented without problems even using simple and inexpensive plant technology, and high-quality products are also produced.

[0019] In particular, inadequate groove filling with the resin due to excessive viscosity and / or reactivity can be prevented or at least significantly reduced. A tilting position of the component to be impregnated, such as the rotating stator, which is often required in the prior art, is thus no longer necessary, so that the associated comparatively cost-intensive system concepts can be dispensed with.

[0020] The chemical resin components used and the respective manufacturing processes can be closely matched to one another and to the product requirements, such as the demands on the component to be impregnated, for example the engine or the engine component. In particular, process-critical parameters such as reactivity, i.e. the time until gelation at a certain temperature, volume shrinkage during curing and the release of volatile components, such as reactive thinners, e.g. styrene, are worth mentioning here. In addition, the parameters after curing, such as mechanical and electrical strength, dielectric properties, glass transition temperature and thermal resistance are relevant and can be easily adjusted by a person skilled in the art within the scope of the invention.

[0021] It is also conceivable that a 3K resin system is used for impregnation, consolidation, or electrical insulation within the scope of the present invention. Additives for a preferably delayed thixotropy can accelerate a viscosity-increasing effect with respect to gelation. This results in an increase in manufacturing efficiency, particularly with regard to cycle time.

[0022] It may further be preferred for the resin system to be a room temperature curing system. This makes the process particularly simple and cost-effective to carry out. This embodiment can therefore prevent insufficient reactivity from having to be compensated for by increasing the temperature of the body to be treated either before, during or after treatment, such as the trickling process. This would firstly increase the investment in the system, for example due to the provision of an inductor or hot air oven, and secondly increase costs due to the energy required. A room temperature curing system is understood to be one that cures at 22°C.

[0023] With regard to the resin, it may be further preferred that the resin be selected from an epoxy resin, a silicone rubber, a polyurethane, and a polyester. It has been shown that, particularly when using such resins, the resin system can be readily implemented in the described process. Specific examples include epoxy resins or bisphenol-F-epichlorohydrin resins.

[0024] The hardener should be matched to the resin in terms of its curing mechanism. An amine hardener is particularly preferably used here, or it can be advantageous if the hardener comprises an amine hardener, such as 2,4,6-tri-(dimethylaminomethyl)phenol. An amine-based hardener has the advantage that curing can take place at room temperature, thus enabling curing, also known as cold curing. Epoxy resin is advantageous due to its pronounced mechanical properties and results in only a small change in volume during curing. Epoxy resin advantageously contains no solvents and has a VOC < 1% by weight (volatile organic compounds, or VOC for short), i.e. less than 1% by weight of the total material evaporates during the curing process.

[0025] For further technical features and advantages of the resin system, reference is made to the description of the process, the use, the examples and the figures.

[0026] Also described is a method for impregnating, solidifying or electrically insulating a body carrying single-layer or multi-layer windings, wherein the body carrying the windings is dipped into a multi-component resin system or is dripped with the multi-component resin system or is sprayed with the multi-component resin system, wherein the resin system is one as described above.

[0027] This results in the advantages described above with reference to the resin system. In particular, by adapting the described parameters, a simple and cost-effective system technology can be used, which includes, for example, passive mixers, while still enabling a high-quality result.

[0028] In an advantageous embodiment of the invention, the body supporting the windings is immersed in the multi-component resin system at room temperature, or is sprinkled with the multi-component resin system, or is sprayed with the multi-component resin system. As indicated above, this allows for a particularly cost-effective and inexpensive system technology that is also cost-effective to operate.

[0029] For example, it may be advantageous for the body carrying the windings to be immersed in the multi-component resin system or to be sprinkled with the multi-component resin system or to be sprayed with the multi-component resin system at an ambient temperature of 15 to 25 ° C, in particular 20 to 23 ° C.

[0030] In a further advantageous embodiment of the invention, the body carrying the windings is preheated to a temperature of 30 to 80 ° C, in particular 30 to 60 ° C. Preferably, the body carrying the windings is inductively preheated to a temperature of 30 to 80 ° C, in particular 30 to 60 ° C. This has the advantage that different ambient temperatures, e.g. in summer or winter, have no influence on the impregnation, solidification or electrical insulation. The body carrying the windings has, for example, a defined temperature at the beginning of the impregnation, solidification or electrical insulation process, regardless of the ambient temperature, and then cools down. The invention offers the further advantage that further work, such as the attachment of a bearing plate, which is only possible at room temperature due to thermal expansion coefficients, can be carried out promptly after the impregnation.No active cooling is necessary. Furthermore, there is no need to accept delays due to storage space being used for cooling at room temperature. This enables cost- and time-efficient production.

[0031] Furthermore, the high energy consumption mentioned above for heating the winding with currents of, for example, more than 500 A is eliminated. Controlling these currents also requires very complex power electronics in a production plant. This, too, is eliminated by the invention.

[0032] The invention also offers the advantage that no space needs to be provided in a production hall on which the impregnated bodies cool and harden, often over several days or even weeks. This has positive economic effects.

[0033] In a further advantageous embodiment, the body rotates around an axis when the body is immersed in a multi-component resin system, or is dripped with the multi-component resin system, or is sprayed with the multi-component resin system. For this purpose, the body is advantageously located on a rolling station.

[0034] It can also be advantageous for the first component and the second component to be conveyed separately from one another, the first component and the second component being mixed immediately before dipping, trickling or spraying to form the multi-component resin system. Immediately preferably means a maximum period of 10 minutes. When mixing the first and second components, the described ratio of the viscosities and the parts by volume ratios is particularly advantageous. This also particularly advantageously allows the use of a static mixer. Accordingly, it is advantageous for the first component and the second component to be mixed together in a static mixer.

[0035] The rotation of the body prevents the resin system, especially the resin, from dripping. Capillary forces draw the resin into the grooves, where it gels within a few minutes. A drip-free state should be achieved after a maximum of 20 minutes. The body can be removed from the roller station and further processed without requiring a long curing and / or cooling period.

[0036] For further technical features and advantages of the process, reference is made to the description of the resin system, the use, the examples and the figures.

[0037] Also described is a use of a resin system as described above for impregnating, solidifying or electrically insulating a body carrying a winding.

[0038] For further technical features and advantages of use, reference is made to the description of the resin system, the process, the examples and the figures.

[0039] Further details, features, and advantages of the subject matter of the invention emerge from the dependent claims and from the following description of the figures. The figures show:

[0040] FIG 1 : the impregnation process,

[0041] FIG 2 : an exemplary system for carrying out the impregnation process; and

[0042] FIG 3: a dynamoelectric rotary machine during the impregnation process. FIG 1 shows the impregnation process. In a first process step, a first component K1 and a second component K2 are provided. The first component K1 is a resin, the second component K2 is a hardener. The two components are conveyed separately in a process step S2. In a process step S3, the two components are mixed to form a multi-component resin system 10, in this case a two-component resin system, and, preferably immediately after mixing, applied to a body 7 or introduced into the body 7.

[0043] More than two components are also possible.

[0044] In a process step S4, the rotation of the body 7 distributes the multi-component resin system 10 into cavities in the body 7. If the body 7 is a stator, for example, the multi-component resin system 10 is distributed in the grooves.

[0045] FIG 2 shows an exemplary system for carrying out the impregnation process.

[0046] The first component K1 and the second component K2 are mixed in a mixing tube 3 to form the multi-component resin system 10 and are discharged as a jet 6 through a nozzle 5 onto the body 7. The body rotates in the direction of rotation R about an axis A. The mixing tube is preferably a static mixer.

[0047] The trickling system from Figure 2 thus comprises two separate conveying and dosing systems 20, 100 which contain the two components, i.e. resin and hardener. The mixing of both components should take place in a technically advantageous design via a commercially available static mixing tube 3 which, thanks to its meandering flow path arrangement, ensures swirling and thus homogeneous mixing of the two volume flows in situ, i.e. while flowing through. The static mixing tube 3 itself is, for example, a cost-effective disposable product which can be easily replaced after the system has been idle or serviced, provided that the reactive mixture contained therein has already gelled or partially hardened and thus intermediate rinsing with trickling resin for quick cleaning of the system is no longer possible.

[0048] FIG. 3 shows a dynamoelectric rotary machine 12 during the impregnation process. The figure shows a stator 70 and a rotor 71 of an electric machine. The multicomponent resin system 10 impinges on the stator 70 through the nozzle 5, while the stator 70 rotates in the direction of rotation R around the axis A.

[0049] During subsequent manufacturing steps, rotor 71 and / or stator 72 are usually exposed to elevated temperatures. This is followed, for example, by a winding temperature of approximately 80°C during shrinking of the 200°C hot aluminum housing, and a short-circuit test as the final test with a freely selectable heating of the winding. Nearly 10% curing of the resin system, if chemically possible at all, is ensured before completion.

[0050] Without any subsequent thermal processes, the resin system cures within a few days. Production flow is not disrupted, as the product is drip-free after just a few minutes, with little or no surface stickiness.

[0051] It has surprisingly been found that, in particular, the adaptation of the first and second components to one another according to the invention offers particular advantages in that they are able to ensure sufficient miscibility even through a static system.

[0052] This will be further explained in the discussion of the examples .

[0053] Examples : According to the invention, the following requirements must be met by the components of the process.

[0054] The viscosities of the individual components preferably do not exceed the value of 5000 mPas at room temperature;

[0055] The parts-by-volume mixing ratio is from 3 parts resin to 1 part hardener to 1 part resin to 3 parts hardener, with 1:1 being particularly preferred; the ratio of the viscosities of the resin and the hardener is in a range from 1:5 to 5:1, with 1:1 being particularly preferred.

[0056] The following results were found .

[0057] Table 1 shows different combinations of resin and hardener or of the first and second component.

[0058] Table 1

[0059] Furthermore, Table 2 shows the reactivity of the resin / hardener mixture at corresponding initial viscosities of the mixture of resin and hardener and at different axial lengths of the body to be treated, where axial lengths (AL) refer to the respective bodies.

[0060] Table 2

[0061] The abbreviations listed in Tables 1 and 2 should be understood as follows:

[0062] EP / Amine: amine-cured epoxy resin formulation

[0063] EP / Anhydride: anhydride-cured epoxy resin formulation RTV-1: 1-component room temperature curing silicone rubbers (condensation curing)

[0064] RTV-2: 2-component room temperature curing silicone rubbers (addition and condensation curing) LSR: Liquid silicone rubber (platinum curing)

[0065] HTV : Solid silicone rubber (addition and condensation curing)

[0066] PUR: Polyurethanes as reaction products of commercially available diisocyanates and their low-viscosity prepolymers and polyether / polyester polyols

[0067] UP: Unsaturated polyesters as condensation products of commercially available diols (e.g. ethylene glycol, 1,3-butanediol) and dicarboxylic acids / anhydrides (e.g. phthalic anhydride, maleic anhydride) dissolved in vinyl monomers, accelerated and peroxide cured.

[0068] Compared to state-of-the-art resin systems, this results in significant advantages, as shown in Table 3, which shows the processability of various resin system configurations. This particularly includes the miscibility of resin and hardener, which offers significant application-specific advantages.

[0069] Table 3

[0070] It has thus been shown that by adapting the resin and hardener according to the invention, significant advantages can be achieved in handling in a process for impregnating, solidifying or electrically insulating a body carrying single- or multi-layer windings.

[0071] Regardless of the grammatical gender of a particular term, persons with male, female or other gender identity are included.

[0072] Although the invention has been illustrated and described in detail by the preferred embodiments, the invention is not limited by the disclosed examples and other variations may be derived therefrom by those skilled in the art without departing from the scope of the invention. List of reference symbols

[0073] 3 mixing tube

[0074] 5 nozzle

[0075] 6 beam

[0076] 7 Mounting structure

[0077] 10 Resin system

[0078] 20 Border and dosing system

[0079] 70 Stator

[0080] 71 Rotor

[0081] 100 Border and dosing system

[0082] 125 rotary machine

[0083] A axis

[0084] Class Component 1

[0085] K2 Component 2

[0086] R Rotation direction

[0087] 51 process step

[0088] 52 process steps

[0089] 53 Process step

[0090] 54 Process step

Claims

Patent claims 1. Resin system (10), wherein the resin system is designed as a two-component system and comprises a resin as a first component (K1) and a hardener for hardening the resin as a second component (K2), wherein the first component (K1) and the second component (K2) are matched to one another as follows: - The parts-by-volume mixing ratio is 3 parts resin to 1 part hardener to 1 part resin to 3 parts hardener; and - The ratio of the viscosity of the resin and the hardener is in a range of 1 to 5 to 5 to 1.

2. Resin system (10) according to claim 1, characterized in that the parts-by-volume mixing ratio is 1.5 parts resin to 1 part hardener to 1 part resin to 1.5 parts hardener.

3. Resin system (10) according to claim 1 or 2, characterized in that the ratio of the viscosities of the resin and the hardener is in a range from 1 to 2 to 2 to 1.

4. Resin system (10) according to one of claims 1 to 3, characterized in that the resin system (10) is a room temperature curing system.

5. Resin system (10) according to one of claims 1 to 4, characterized in that the resin is selected from an epoxy resin, a silicone rubber, a polyurethane and a polyester.

6. Resin system (10) according to one of claims 1 to 5, characterized in that the hardener comprises an amine hardener.

7. A method for impregnating, solidifying or electrically insulating a body carrying single- or multi-layer windings, wherein the body carrying the windings is immersed in a multi-component resin system (10) or is dripped with the multi-component resin system (10) or is sprayed with the multi-component resin system (10), characterized in that the resin system (10) is one according to one of claims 1 to 6.

8. The method according to claim 7, characterized in that the first component (K1) and the second component (K2) are mixed together in a static mixer.

9. Method according to one of claims 7 or 8, characterized in that the body carrying the windings is part of an electrical machine.

10. Use of a resin system (10) according to one of claims 1 to 6 for impregnating, solidifying or electrically insulating a body carrying a winding.

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