COMPOSITION MOUSSANTE
Patent Information
- Authority / Receiving Office
- FR · FR
- Patent Type
- Patents
- Current Assignee / Owner
- LOREAL SA
- Filing Date
- 2021-10-21
- Publication Date
- 2026-07-24
AI Technical Summary
Existing cleansing products with high oil content struggle to achieve desirable foaming properties, leading to perceived inefficacy in cleaning and makeup removal, while also potentially irritating keratinous materials like the skin.
A foaming composition comprising at least one oil, an interface stabilizer, and a surfactant system including alkyl sulfosuccinate, amphoteric surfactant, and optionally nonionic surfactant, with the interface stabilizer being a polyurethane polymer, to enhance rheology, thickening, and stabilize foams, even at high oil contents.
The composition achieves improved foaming properties, stability, and skin care benefits, ensuring effective cleaning and makeup removal without irritation, even with high oil content, and maintains skin freshness.
Abstract
Description
Description Title of the invention: FOAMING COMPOSITION Technical field The present invention relates to a foaming composition, more particularly, the present invention relates to a foaming composition for the cleansing and / or removal of makeup from keratinous materials. art context Cleansing and removing makeup are essential for skincare. In particular, it's crucial for makeup users to have an effective makeup remover. It needs to be as effective as possible because oily residues, such as dirt, excess sebum, traces of daily cosmetics, and makeup—especially waterproof products—accumulate in skin folds and can clog pores, leading to breakouts. To date, there are several types of makeup removers or cleansers, for example, rinse-off anhydrous cleansing oils and gels, solid makeup removers, two-phase makeup removers, makeup remover lotions or creams, etc. Among them, foaming cleansers are preferred, as they cleanse thanks to surfactants and suspend oily residues and pigments from makeup products, for example. Good foaming properties, ease of rinsing, and skin-care benefits—such as leaving skin feeling soft and moisturized after rinsing—are very important for cosmetic foaming cleansers. Traditionally, skin-cleansing and makeup-removing products contain a high oil content, or are even purely oil-based. These products often have poor foaming properties, making it a challenge for manufacturers to achieve desirable foaming properties in oil-rich products. From the consumer's perspective, the amount of foam is directly linked to the perceived cleaning effectiveness of the formula. Generally, the greater the volume of foam produced and the more stable the foam, the more effective the cleaning action of the formula is perceived to be. Nowadays, it has become increasingly important that cleansing compositions ensure effective cleaning of keratinous materials, produce noticeable and desirable foams, do not irritate the eyes or keratinous materials, and leave keratinous materials feeling fresh and clean, even for Products with a high oil content. Therefore, there is a need to formulate such a composition for the cleansing and / or removal of keratinous materials. Summary of the invention According to the first aspect, the present invention relates to a foaming composition, comprising: (a) at least one oil, (b) at least one interface stabilizer for improving the rheology of the composition and strengthening and stabilizing the foams formed therein, and (c) a surfactant system, comprising, consisting substantially of, or consisting of, at least one alkyl sulfosuccinate, at least one amphoteric surfactant, and optionally, at least one nonionic surfactant. Furthermore, the interface stabilizer according to the present invention is a polyurethane polymer. Preferably, the polyurethane polymer is formed by the reaction of a prepolymer (i) with a coreactive (ii), and is optionally terminated by a terminal cap agent (iii), in which the prepolymer (i) is formed by the reaction of polyhydroxylated compounds, polyisocyanates, and optionally low molecular weight diols. By means of the specific interface stabilizer, the composition according to the present invention achieves not only improved rheology, thickening efficiency, clarity and non-sticky feel, but also foams perceived with desirable volume, density and stability. For the surfactant system, the alkyl sulfosuccinate may be chosen from mono- or dialkyl sulfosuccinates in which the alkyl radicals have 4 to 24 carbon atoms and the counter-ion to the sulfonic acid group is chosen from alkali metal cations and ammonium ions; the amphoteric surfactant may be chosen from secondary or tertiary aliphatic amine derivatives optionally quaternized, preferably chosen from alkyl (Cy-C) betaines, alkyl (Ce-Czo) amido-alkyl (C1-Cs) betaines, and mixtures thereof; and the nonionic surfactant may be an alkyl polyglucoside having a Cs-C3 alkyl group and a fraction derived from a reducing saccharide containing 5 to 6 carbon atoms, preferably a glucose motif. At least one oil is selected from among oils of vegetable or animal origin, ester oils, ether oils, silicone oils, hydrocarbon oils, and mixtures thereof, in which at least one oil is present in an amount exceeding approximately 10% by weight, and even exceeding approximately 40% by weight, relative to the total weight of the composition; provided that where silicone oils and / or hydrocarbon oils are present, the amount of each of the silicone oils and hydrocarbon oils ranges from approximately 0% by weight to approximately 10% by weight, per relative to the total weight of the composition. As an example, the weight ratio of the interface stabilizer to at least one oil ranges from about 1:500 to about 1:1, and preferably from about 1:200 to about 1:10. According to the second aspect, the present invention relates to a combination for improving the properties of foam, even for products with a high oil content, comprising, consisting substantially of, or even consisting of a surfactant system and at least one interface stabilizer to improve the rheology of the composition and strengthen and stabilize the foams formed therein, in which "product with a high oil content" means that the oil is present in an amount greater than 10% by weight, and even greater than 40% by weight, relative to the total weight of the product. Those skilled in the art know that, for cleaning products, the foam properties are strongly influenced by the oil content, and a product with a high oil content normally has very poor foaming properties. Thanks to the combination according to the present invention, products with a high oil content can achieve good to excellent foaming properties even at very high oil contents, for example, an oil content greater than 10% by weight, and even greater than 40% by weight, relative to the total weight of the product. For example, the foaming compositions according to the present invention are in the form of an emulsion, lotion, balm or cream. According to the third aspect, the present invention relates to the use of a polyurethane polymer, in particular formed by the reaction of a prepolymer (i) with a coreactive (ii), and optionally terminated by a terminal cap agent (iii), in which the prepolymer (i) is formed by the reaction of polyhydroxylated compounds, polyisocyanates, and optionally low molecular weight diols, to improve the rheology of an emulsified system and to strengthen and stabilize the foams formed therein. Other subjects and features, aspects and advantages of the present invention will become even clearer upon reading the detailed description and examples that follow. DETAILED DESCRIPTION OF THE INVENTION In what follows, and unless otherwise stated, the limits of a range of values are included within that range, particularly in the expressions "between" and "from ... to ...". Throughout this application, the term "including" should be interpreted as encompassing all the features specifically mentioned. that optional, additional, and unspecified features. As used here, the use of the term "comprising" also discloses the embodiment in which no features other than those specifically mentioned are present (i.e., "consisting of"). In the case of "consisting essentially of," all additional compositions, materials, and / or components that materially affect the basic and new features are excluded from such an embodiment, but all compositions, materials, and / or components that do not materially affect the basic and new features may be included in the embodiment. By "keratinous materials" we mean human keratinous materials and more specifically the skin and scalp, and more particularly the skin of the face. Surfactant system The composition according to the present invention comprises a surfactant system, which includes, consists substantially of, or even consists of at least one alkyl sulfosuccinate as an anionic surfactant and at least one amphoteric surfactant, and optionally at least one nonionic surfactant. The total amount of surfactants included in the surfactant system ranges from about 0.5 to about 30% by weight, preferably from about 1 to about 20% by weight, or from about 5 to about 15% by weight, relative to the total weight of the composition. Useful but not exhaustive examples of surfactants that can be used in the surfactant system are provided below. Alkyl sulfosuccinate The composition according to the present invention comprises at least one anionic surfactant selected from alkyl sulfosuccinates, including monoalkyl sulfosuccinates and dialkyl sulfosuccinates. Preferably, the alkyl sulfosuccinates present in the composition according to the present invention are selected from mono- or dialkyl sulfosuccinates in which the alkyl radicals have from 4 to 24 carbon atoms, preferably from 6 to 18 carbon atoms, and more particularly from 6 to 14 carbon atoms. Different or identical alkyl radicals may be present in a dialkyl sulfosuccinate molecule, with identical radicals being preferred. The alkyl radicals may be linear, branched, or cyclic, saturated or unsaturated, and substituted or unsubstituted. Sulfosuccinates can be chosen from alkali metal salts such as sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and especially amino alcohol salts or alkaline earth metal salts such as magnesium salts. According to a particular embodiment of the invention, the sulfosuccinates are chosen from alkali metal salts and more particularly sodium salt, including disodium salts for mono-alkyl sulfosuccinates and sodium salts for dialkyl sulfosuccinates. Preferably, the alkyl sulfosuccinate is chosen from mono- or di-alkyl sulfosuccinates in which the alkyl radicals have 6 to 14 carbon atoms and the counter-ion to the sulfonic acid group is chosen from alkali metal cations and ammonium ions. Des exemples non limitatifs de sulfosuccinates de dialkyle sont diéthylhexyl sulfo- succinate de sodium, dinonyl sulfosuccinate de sodium, diisononyl sulfosuccinate de sodium, dioctyl sulfosuccinate de sodium, diheptyl sulfosuccinate de sodium, dihexyl sulfosuccinate de sodium, dicapryl sulfosuccinate de sodium, didécyl sulfosuccinate de sodium, diundécyl sulfosuccinate de sodium, dilauryl sulfosuccinate de sodium, dicocoyl sulfosuccinate de sodium, ditridécyl sulfosuccinate de sodium, dipropylheptyl sulfosuccinate de sodium, dicyclohexyl sulfosuccinate de sodium, diéthylhexyl sulfo- succinate d’ammonium, dinonyl sulfosuccinate d’ammonium, diisononyl sulfo- succinate d’ammonium, dioctyl sulfosuccinate d’ammonium, diheptyl sulfosuccinate d’ammonium, dihexyl sulfosuccinate d’ammonium, dicapryl sulfosuccinate d’ammonium, didécyl sulfosuccinate d’ammonium, diundécyl sulfosuccinate d’ammonium, dilauryl sulfosuccinate d’ammonium, dicocoyl sulfosuccinate d’ammonium,ditridécyl sulfosuccinate d’ammonium, dipropylheptyl sulfosuccinate d’ammonium, dicyclohexy]l sulfosuccinate d’ammonium, diéthylhexyl sulfosuccinate de potassium, dinonyl sulfosuccinate de potassium, diisononyl sulfosuccinate de potassium, dioctyl sulfosuccinate de potassium, diheptyl sulfosuccinate de potassium dihexyl sulfosuccinate de potassium, dicapryl sulfosuccinate de potassium, didécyl sul- fosuccinate de potassium, diundécyl sulfosuccinate de potassium, dilauryl sulfo- succinate de potassium, dicocoyl sulfosuccinate de potassium, ditridécyl sulfosuccinate de potassium, dipropylheptyl sulfosuccinate de potassium, dicyclohexyl sulfosuccinate de potassium, le diéthylhexy1 sulfosuccinate de sodium étant très particulièrement préféré. , Non-limiting examples of mono-alkyl sulfosuccinates include diammonium lauryl sulfosuccinate, disodium cetearyl sulfosuccinate, disodium cetyl sulfosuccinate, disodium coco-sulfosuccinate, disodium isodecyl sulfosuccinate, disodium isostearyl sulfosuccinate, disodium lauryl sulfosuccinate, disodium oleyl sulfosuccinate, disodium stearyl sulfosuccinate, and disodium tridecyl sulfosuccinate, with disodium lauryl sulfosuccinate being particularly preferred. Advantageously, the alkyl sulfosuccinate(s) is / are present in an amount ranging from about 0.5% by weight to about 15% by weight, preferably of about 1% by weight to about 10% by weight, or about 2% by weight to about 8% by weight, relative to the total weight of the composition. Amphoteric surfactant The composition according to the present invention comprises at least one amphoteric surfactant selected from secondary or tertiary aliphatic amine derivatives fa- optionally quaternized. The amphoteric surfactant chosen from optionally quaternized secondary or tertiary aliphatic amine derivatives contains at least one anionic group, for example a carboxylate, sulfonate, sulfate, phosphate or phosphonate group, in which the aliphatic group or at least one of the aliphatic groups is a linear or branched chain comprising 8 to 22 carbon atoms. Examples include alkyl (C-Czp) betaines, sulfobetaines, (alkyl Cz-Cao) amido (alkyl C;-C;) betaines and (alkyl Cz-Czp) amido (alkyl C,-C;) sulfo-betaines. Among the alkyl (Cz-Cz0) betaines, examples include behenylbetaine, cetylbetaine, co-coylbetaine, and decylbetaine. Cocoylbetaine is preferred among the alkylbetaines, for example, in products sold by Rhodia under the brand name Mirataine® BB / FLA. Among the derivatives of optionally quaternized secondary or tertiary aliphatic amines that can be used, the following compounds of formulas (ID) and (III) can also be mentioned: R,-CON(Z)CH--(CH),-N*(R,)(R,)(CH,COO-) (ID in which: R, represents a C,O-Cap alkyl or alkenyl group derived from an R,-COOH acid preferably present in hydrolyzed coconut oil, a heptyl group, a nonyl group or an undecyl group, R represents a B-hydroxyethyl group. R represents a carboxymethyl group; m is equal to 0, 1] or 2, Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group; R, -CON(Z)CH,-(CH-).-N(B)(B') ID in which: B represents -CH,CH,OX", with X' representing -CH,-COOH, CH,-COOZ”, CH,CH 2-COOH, -CH,CH,-COOZ', or a hydrogen atom, B' represents -(CHz),-Y', with z = 1 or 2, and Y' representing -COOH, -COOZ”, -CH2 -CHOH-SO;H or -CH,-CHOH-SO4Z>, m° is equal to 0, 1 or 2, Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group, Z' represents an ion derived from an alkali or alkaline earth metal, such as sodium, potassium or magnesium; an ammonium ion; or an ion resulting from an organic amine and in particular from an amino alcohol, such as monoethanolamine, diethanolamine and triethanolamine, monoisopropanolamine, diisopropanolamine or triisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3-propanediol and tris(hydroxymethyl)aminomethane, Ry represents an alkyl or alkenyl group in Cy5-Czp of an acid R,COOH preferably present in hydrolyzed linseed or coconut oil, an alkyl group, in particular an alkyl group in C,,, and its iso form, or an unsaturated group in C,,,. Compounds conforming to the formula (IT) are preferred. Among the compounds meeting the formula (IT), we can cite cocamidopropyl betaine, for example the product sold under the brand name Dehyton PK 45 by Cognis (BASE). We can also use compounds with formula (IV): R,'-NH-CH(Y'')-(CH),-C(0)-NH-(CH»)nN{Rç)(Re) (IV) in which: - R,» represents an alkyl or alkenyl group in C1o-Czp of an acid R,--C(O)OH preferably present in hydrolyzed linseed or coconut oil; - Y'' represents the group -C(O)OH, -C(O)OZ”", -CH,-CH(OH)-SO;H or the group - CH,-CH(OH)-SO;-Z”, with Z”' representing a cationic counter-ion resulting from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion resulting from an organic amine; - Ra and R represent, independently of each other, an alkyl or hydroxyalkyl radical in C,-C, ; and - net n° represent, independently of each other, an integer ranging from 1 to 3 Among the compounds corresponding to formula (IV), we can notably mention the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoas-partamide, such as that marketed by the company Chimex under the name Chimexane HB. Preferably, amphoteric surfactants are chosen from alkyl (Cgs-C20) betaines, alkyl (C;-C»0) amido-alkyl (C,-C;) betaines, and mixtures thereof. Preferably, the amphoteric surfactant is chosen from cocamidopropyl betaine, cocoyl betaine, or a mixture thereof. Advantageously, the amphoteric surfactant is present in an amount ranging from about 0.5% by weight to about 20% by weight, preferably from about 1% by weight to about 10% by weight, or from about 2% by weight to about 5% by weight, relative to the total weight of the composition. Non-ionic surfactant The composition according to the present invention optionally comprises at least one non-ionic surfactant selected from an alkyl polyglucoside, an alkyl glycoside, an acyl glucamide and mixtures thereof, and preferably selected from an alkyl polyglucoside. Furthermore, the alkyl polyglucoside preferably has the following formula (I): ROG, (D in which R is a C4-Cao alkyl group, G is a fraction derived from a reducing saccharide containing 5 to 6 carbon atoms, preferably a glucose motif, and Xx' represents the average degree of polymerization of the alkyl polyglucoside. Preferably, R is a Cs-Cu alkyl group. For a particular alkyl polysaccharide molecule, x' can only take integer values. In any physical sample of alkyl polyglucosides, there will generally be molecules with different values of x. The physical sample can be characterized by the average value of x', which may take non-integer values. In the specification, the values of x' should be understood as average values. The hydrophilic portion of the alkyl polyglucoside contains on average approximately 1 to 10, preferably 1.4 to 3, saccharide units. These saccharide units can be galactoside, glucoside, lactoside, fructoside, glucosyl, fructosyl, lactosyl, and / or galactosyl, and preferably glucoside. Mixtures of these saccharide fractions can be used in the alkyl polyglucoside. Glucoside is the preferred saccharide fraction; other saccharide fractions will act similarly, but because glucoside is the preferred saccharide fraction, the remaining disclosure will focus on the alkyl polyglucoside. The hydrophobic group on the alkyl polyglucoside is an alkyl group, branched or unbranched, unsaturated or saturated, containing from about 4 to about 40 carbon atoms on average. Preferably, the alkyl group is primarily a saturated alkyl group with a linear chain at C3. The useful alkyl polyglucosides of the present invention are also disclosed in U.S. Patent 4,565,647, of Llenado, issued January 21, 1986, having a hydrophobic group containing from about 6 to about 30 carbon atoms, preferably from about 10 to about 16 carbon atoms, and a hydrophilic polysaccharide group, for example a polyglycoside, containing from about 1.3 to about 10, preferably from about 1.3 to about 3, more preferably from about 1.3 to about 2.7 saccharide motifs. Any reducing saccharide containing 5 or 6 carbon atoms can be used; for example, glucose, galactose, and galactosyl moieties can be substituted for glucosyl moieties (optionally, the hydrophobic group is attached to positions 2, 3, 4, etc., thus yielding a glucose or galactose as opposed to a glucoside or galactoside). Intersaccharide bonds can be, for example, between the first position of the additional saccharide motifs and positions 2, 3, 4, and / or 6 of the preceding saccharide motifs. Examples of alkyl polyglucosides include, but are not limited to: caprylyl / capryl glucoside, decyl glucoside, lauryl glucoside, octyl glucoside, sodium lauryl glucose carboxylate (and) lauryl glucoside, and coco glucoside. Typically, the non-ionic surfactant is chosen from the group consisting of caprylyl / capryl glucoside, coco glucoside, lauryl glucoside and decyl glucoside, and more typically caprylyl / capryl glucoside and decyl glucoside. Preferred alkyl polyglucosides are available under trade names, for example: For coco-glucoside: Plantacare® 818 UP sold by Cognis, For decyl glucoside: Plantacare® 2000 UP sold by Cognis, For caprylyl / capryl glucoside: OramixTM CG 110 sold by Seppic, For lauryl glucoside: Plantaren® 1200 N UP sold by Cognis, For octyl glucoside: Rewosan sold by Rewo, For sodium lauryl glucose carboxylate: Plantapon® LGC SORB. Advantageously, the nonionic surfactant is present in an amount ranging from about 0% by weight to about 15% by weight, preferably from about 1% by weight to about 10% by weight, or from about 2% by weight to about 5% by weight, relative to the total weight of the composition. Oil As used here, the term "oil" refers to a fatty compound or substance that is in the form of a liquid or paste (not a solid) at room temperature (25°C) under atmospheric pressure (760 mmHg). Oils commonly used in cosmetics can be used alone or in combination. The oil can be chosen from oils of vegetable or animal origin, synthetic oils and mixtures thereof. Examples of vegetable oils include, for example, linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, sasanqua oil, castor oil, safflower oil, jojoba oil, sunflower oil, almond oil, rapeseed oil, sesame oil, soybean oil, peanut oil, and mixtures thereof. Examples of animal oils or fats include, for example, oil of lard, beef fat, mutton fat, chicken oil, snake oil, oviductus ranae, fish oil, horse fat, lanolin oil and mixtures thereof. Examples of synthetic oils include ester oils, ether oils, artificial triglycerides, hydrocarbon oils, silicone oils, and mixtures thereof. Ester oils are preferably liquid esters of aliphatic monoacids or polyacids in C1-C15, preferably in C10-C1, saturated or unsaturated, linear or branched, and of aliphatic monoalcohols or polyalcohols in C1-C25, preferably in C1-C19, saturated or unsaturated, linear or branched, the total number of carbon atoms of the esters being greater than or equal to 10. Preferably, for monoalcohol esters, at least one of the alcohol and acid from which the esters of the present invention are derived is branched. Examples of monoesters of monoacids and monoalcohols include alkyl palmitates such as ethyl palmitate, ethylhexyl palmitate or isopropyl palmitate, dicaprylyl carbonate, alkyl myristates such as isopropyl myristate or ethyl myristate, isocetyl stearate, 2-ethylhexyl isononanoate, isononyl isononanoate, isodecyl neopentanoate and isostearyl neopentanoate. One can also use esters of dicarboxylic or tricarboxylic acids in C4-Cz and of alcohols in C,-C,, as well as esters of monocarboxylic, dicarboxylic or tricarboxylic acids and unsweetened alcohols in C,-C» dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy. Examples include: diethyl sebacate; isopropyl lauroyl sarcosinate; diisopropyl sebacate; bis(2-ethylhexyl) sebacate; diisopropyl adipate; di-n-propyl adipate; dioctyl adipate; bis(2-ethylhexyl) adipate; diisostearyl adipate; bis(2-ethylhexyl) maleate; triisopropyl citrate; triisocetyl citrate; triisostearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate; neopentylglycol diheptanoate; diethylene glycol dii-sononanoate. Ester oils can be made from sugar esters and diesters of fatty acids in the C3-C4 group, and preferably in the C1-C3 group. The term "sugar" here refers to oxygenated hydrocarbon compounds containing multiple alcohol groups, with or without aldehyde or ketone groups, and comprising at least four carbon atoms. These sugars can be monosaccharides, oligosaccharides, or polysaccharides. Examples of suitable sugars that can be mentioned include sucrose (or saccharose), glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose and lactose, and derivatives of these, including alkyl derivatives, such as methyl derivatives, for example methylglucose. Sugar esters of fatty acids can be chosen in particular from the group comprising the esters or mixtures of esters of sugars described above and of linear or branched fatty acids, saturated or unsaturated, in Cs-C4, and preferably in C,2-C2. If they are unsaturated, these compounds may have one to three conjugated or non-conjugated carbon-carbon double bonds. The esters according to this variant can also be chosen from monoesters, diesters, triesters, tetraesters and polyesters, and mixtures thereof. These esters may be, for example, oleates, laurates, palmitates, myristates, behenates, cocoates, stearates, linoleates, linolenates, caprates and arachidonates of C,-C, preferably C,-C;p alkyl, or mixtures thereof such as, notably, mixed esters of oleopalmitate, oleostearate and palmitostearate, and pentaerythrityl tetraethyl hexanoate. In particular, monoesters and diesters are used, including mono- or dioleates, stearates, behenates, oleopalmitates, linoleates, linolenates and oleostearates of sucrose, glucose or methylglucose. One example that can be mentioned is the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate. Examples of preferable ester oils include diisopropyl adipate, dioctyl adipate, 2-ethylhexyl hexanoate, ethyl laurate, cetyl octanoate, octyldodecyl octanoate, isodecyl neopentanoate, myristyle propionate, 2-ethylhexyl 2-ethylhexanoate, 2-ethylhexyl octanoate, 2-ethylhexyl caprylate / caprate, methyl palmitate, ethyl palmitate, isopropyl palmitate, dicaprylyl carbonate, isopropyl lauroyl sarcosinate, isononyl isononanoate, ethylhexyl palmitate, isohexyl laurate, hexyl laurate, isocetyl stearate, and isostearate. isopropyl, isopropyl myristate, isodecyl oleate, glyceryl tri(2-ethylhexanoate), pentaerythrithyl tetra(2-ethylhexanoate), 2-ethylhexyl succinate, diethyl sebacate, and mixtures thereof. Examples of artificial triglycerides include, for example, caprylyl / capryl triglyceride, glyceryl trimyristate, glyceryl tripalmitate, glyceryl trilinolenate, glyceryl trilaurate, glyceryl tricaprate, glyceryl tricaprylate, glyceryl tri(caprate / caprylate) and glyceryl tri(caprate / caprylate / linolenate). An ether oil is an oil of formula R,OR; in which R, and R denote independently a linear, branched or cyclic C,-C alkyl group, preferably a Cs-Cy3 alkyl group, and preferably a C;-C,2 alkyl group. It may be preferable that R, and R> be identical. Linear alkyl groups that can be mentioned include a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a group tridecyl, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group, behenyl group, docosyl group, tricosyl group and tetracosyl group. Branched alkyl groups that can be mentioned include a 1-methylpropyl group, a 2-methylpropyl group, a t-butyl group, a 1,1-dimethylpropyl group, a 3-methylhexyl group, a 5-methylhexyl group, an ethylhexyl group, a 2-ethylhexyl group, a 5-methyloctyl group, a 1-ethylhexyl group, a 1-butylpentyl group, a 2-butyloctyl group, an isotridecyl group, a 2-pentylnonyl group, a 2-hexyldecyl group, an isostearyl group, a 2-heptylundecyl group, a 2-octyldodecyl group 1,3-dimethylbutyl, a 1-(1-methylethyl)-2-methylpropyl group, a 1,1,3,3-tetramethylbutyl group, a 3,5,5-trimethylhexyl group, a 1-(2-methylpropyl)-3-methylbutyl group, a 3,7-dimethyloctyl group and a 2-(1,3,3-trimethylbutyl)-5,7,7-trimethyloctyl group. The cyclic alkyl groups that can be mentioned include a cyclohexyl group, a 3-methylcyclohexyl group and a 3,3,5-trimethylcyclohexyl group. Advantageously, the oil ether is selected from dicaprylyl ether, dicapryl ether, dilauryl ether, diisostearyl ether, dioctyl ether, non-nylphenyl ether, dodecyl dimethylbutyl ether, cetyl dimethylbutyl ether, cetyl isobutyl ether, and mixtures thereof. Examples of silicone oils include, for example, linear organopolysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenopolysiloxane and the like; cyclic organopolysiloxanes such as cyclohexasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane and the like; and mixtures thereof. Preferably, silicone oil is chosen from among liquid polydialkylsiloxanes, in particular liquid polydimethylsiloxanes (PDMS) (dimethicones) and liquid polyorganosiloxanes comprising at least one aryl group. These silicone oils can also be organo-modified. The organo-modified silicones usable according to the present invention are silicone oils as defined above and comprise in their structure one or more organo-functional groups attached via a hydrocarbon group. Organopolysiloxanes are defined in more detail in Walter Noll's book, Chemistry and Technology of Silicones (1968), Academic Press. They can be volatile or non-volatile. When they are volatile, silicones are particularly chosen from those with a boiling point between 60°C and 260°C, and even more particularly from: (i) Cyclic polydialkylsiloxanes comprising 3 to 7, and preferably 4 to 5, silicon atoms. Examples include octamethylcyclotetrasiloxane, sold notably under the names Volatile Silicone® 7207 by Union Carbide or Silbione® 70045 V2 by Rhodia; decamethylcyclopentasiloxane, sold under the names Volatile Silicone © 7158 by Union Carbide and Silbione® 70045 VS by Rhodia; and dodecamethylcyclopentasiloxane, sold under the name Silsoft 1217 by Momentive Performance Materials, and mixtures thereof. Also included are dimethylsiloxane / methylalkylsiloxane cyclocopolymers, such as Silicone Volatile® FZ 3109, sold by Union Carbide, with the formula: 111 sen [SN rorrrrreecererornece: pe D Dh sm Vetements cedédatésértéae, CH, CH, 3 * + with dD*: <S-0— etavec D: "SiI<O— to ES t CH, This We can also mention mixtures of cyclic polydialkylsiloxanes with organosilicon compounds, such as the mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol (50 / 50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1'-bis(2,2,2°,2,3,3'-hexatrimethylsilyloxy)neopentane; (ii) Volatile linear polydialkylsiloxanes containing 2 to 9 silicon atoms and having a viscosity less than or equal to Sx10⁶ m' / s at 25 °C. An example is decamethyltetrasiloxane, sold notably under the name SH 200 by Toray Silicone. Silicones belonging to this category are also described in the article published in Cosmetics and Toiletries, vol. 91, January 1976, pages 27 to 32, Todd & Byers, "Volatile Silicone Fluids for Cosmetics." The viscosity of silicones is measured at 25 °C according to ASTM 445 Annex C. Non-volatile polydialkylsiloxanes can also be used. These non-volatile silicones are most often chosen from among the polydialkylsiloxanes, of which polydimethylsiloxanes containing trimethylsilyl terminal groups are particularly noteworthy. Examples of these polydialkylsiloxanes include, but are not limited to, the following commercial products: - Silbione® oils from series 47 and 70 047 or Mirasil® oils marketed by Rhodia, for example oil 70 047 V 500 000; - the Mirasil® series oils sold by the Rhodia company; - oils from the 200 series of Dow Corning, such as DC200 with a viscosity of 60,000 mm? / s; - Viscasil® oils from General Electric and certain oils in the SF series (SF 96, SF 18) of General Electric. We can also mention polydimethylsiloxanes containing dimethylsilanol terminal groups known as dimethiconol (CTFA), such as the oils in the 48 series from the Rhodia company. Examples of silicones containing aryl groups include polydiarylsiloxanes, notably polydiphenylsiloxanes and polyalkylarylsiloxanes. Products sold under the following names may be included as examples: - Rhodia's Silbione® oils from the 70 641 series: - the oils from the Rhodorsil® 70 633 and 763 series by Rhodia: - Dow Corning 556 Cosmetic Grade Fluid oil from Dow Corning; - silicones from Bayer's PK series, such as product PK20; - certain oils from the General Electric SF series, such as SF 1023, SF 1154, SF 1250 and SF 1265. Organomodified liquid silicones may contain polyethyleneoxy and / or polypropyleneoxy groups. Examples include KF-6017 silicone from Shin-Etsu, and Silwet® L722 and L77 oils from Union Carbide. Hydrocarbon oils can be chosen from: -lower Ce-C16 alkanes, linear or branched, optionally cyclic. Examples that can be mentioned include hexane, undecane, dodecane, tridecane, and isoparaffins, for example isohexadecane, isododecane and isodecane; and - linear or branched hydrocarbons containing more than 16 carbon atoms, such as liquid paraffins, liquid petrolatum, polydecenes, poly(Cs20 olefins) and hydrogenated polyisobutenes such as ParleamÔ, and squalane. Preferred examples of hydrocarbon oils include, for instance, linear or branched hydrocarbons such as isohexadecane, isododecane, squalane, mineral oil (e.g., liquid paraffin), paraffin, petroleum jelly or petrolatum, naphthalenes and the like; hydrogenated polyisobutene, isoeicosane and decene / butene copolymer; and mixtures thereof. In one embodiment, the composition according to the present invention comprises oils of vegetable or animal origin and / or ester oils, and optionally hydrocarbon oils and / or silicone oils. In a preferred embodiment, the composition according to the present invention comprises oils of vegetable origin. In a preferred embodiment, the composition according to the present invention comprises oils of vegetable origin, and C,-C;p alkyl palmitate and / or C:-C;n alkyl myristate, and in particular sunflower oil, and ethylhexyl palmitate and / or isopropyl myristate. In a preferred embodiment, the composition according to the present invention includes vegetable oils, and hydrocarbon oils and / or silicone oils; and in particular sunflower oil, and dimethicones and / or isododecane. In a preferred embodiment, the composition according to the present invention comprises ester oils, and hydrocarbon oils and / or silicone oils; and in particular ethylhexyl palmitate and / or isopropyl myristate, and dimethicones and / or isododecane. Advantageously, the oil is present in a quantity greater than about 10% by weight, preferably ranging from about 25% by weight to about 85% by weight, or ranging from about 40% by weight to about 70% by weight, relative to the total weight of the composition. In addition, when hydrocarbon oils and / or silicone oils are present, the amount of each of the hydrocarbon oils and silicone oils is equal to or less than about 10% by weight, preferably about 0.5% by weight to about 8% by weight, or about 1% by weight to about 5% by weight, relative to the total weight of the composition. Interface stabilizer The composition according to the present invention comprises at least one interface stabilizer. As used here, the term "interface stabilizer" refers to a substance capable of maintaining the stability of the interface between the aqueous phase and the oily phase in an emulsified system, and preferably, the interface stabilizer can strengthen and stabilize the foams formed in the emulsified system. In this aspect, the interface stabilizer according to the present invention plays a different role from that of a blowing agent, because a blowing agent is used to generate foams, for example a suitable surfactant, while said interface stabilizer is capable of strengthening and stabilizing the foams after their generation. Preferably, the interface stabilizer according to the present invention is a polyurethane polymer. The polyurethane polymer is conventionally formed by the reaction of a prepolymer (i) with a coreactive (ii), and is optionally terminated by a terminal capping agent (iii). The prepolymer (i) can be formed by the reaction of polyhydroxylated compounds, such as dihydroxyl or trihydroxyl compounds, polyisocyanates, for example diisocyanates, and optionally low molecular weight diols which are optionally substituted by ionic groups or potential ionic groups. Suitable polyhydroxylated compounds include those having at least two hydroxyl groups, such as two or three hydroxyl groups, and having average number molecular weights ranging from about 700 to about 16,000, such as, by For example, from approximately 750 to approximately 5,000. Non-limiting examples of high molecular weight compounds include polyester polyols, polyether polyols, polyhydroxylated polycarbonates, polyhydroxylated polyacetals, polyhydroxylated polyacrylates, polyhydroxylated polyester amides, polyhydroxylated polyalkadienes, and polyhydroxylated polythioethers. In various embodiments, polyhydroxylated polyester polyols, polyether polyols, and polycarbonates may be selected. Mixtures of these compounds are also within the scope of disclosure. The polyester diol(s) may optionally be prepared from aliphatic, cycloaliphatic or aromatic dicarboxylic or polycarboxylic acids, or anhydrides thereof, and dihydric or trihydric alcohols such as diols or triols selected from aliphatic, alicyclic or aromatic diols or triols. Aliphatic dicarboxylic or polycarboxylic acids may be chosen from, for example, succinic, fumaric, glutaric, 2,2-dimethylglutaric, adipic, itaconic, pimelic, suberic, azelaic, sebacic, maleic, malonic, 2,2-dimethylmalonic, nonanedicarboxylic, decanedicarboxylic, dodecanedioic, 1,3-cyclohexanedicarboxylic, 1,4-cyclohexanedicarboxylic, 2,5-norboranedicarboxylic, diglycolic, thiodipropionic, 2,5-naphthalenedicarboxylic, 2,6-naphthalenedicarboxylic, phthalic, terephthalic, isophthalic, oxanic, O-phthalic, tetrahydrophthalic, hexahydrophthalic or trimellitic. In some embodiments, the acid anhydrides may be selected from o-phthalic, trimellitic, or succinic acid anhydrides, or mixtures thereof. By way of non-limiting example only, the dicarboxylic acid may be adipic acid. Dihydric alcohols may be selected from ethanediol, ethylene glycol, diethylene glycol, triethylene glycol, trimethylene glycol, tetraethylene glycol, 1,2-propanediol, dipropylene glycol, tripropylene glycol, tetrapropylene glycol, 1,3-propanediol, 1,4-butanediol, 1,3-butanediol, 2,3-butanediol, 1,5-pentanediol, 1,6-hexanediol, 2,2-dimethyl-1,3-propanediol, 1,4-dihydroxycyclohexane, 1,4-dimethylolcyclohexane, cyclohexanedimethanol, 1,8-octanediol, 1,10-decanediol, 1,12-dodecanediol, neopentyl glycol, or mixtures thereof. Cycloaliphatic and / or aromatic dihydroxylated compounds may also be suitable as dihydric alcohol(s) for the preparation of polyester polyol(s). Trihydric alcohols may be selected from alkylidene triols, such as isobutanetriol, neopentanetriol, and neohexanetriol, for example, trimethylpropane. Polyester polyols can also be chosen from homopolymers or lactone copolymers, which are, in at least some embodiments, obtained by addition reactions of lactones or mixtures of lactones, such as γ-butyrolactone, γ-caprolactone, β-caprolactone, ε-caprolactone and / or methyl-ε-caprolactone with the appropriate polyfunctional group, for example, difunctional or trifunctional, such as, for example, the dihydric or trihydric alcohols mentioned above. The corresponding caprolactone polymers may be selected in at least some embodiments. Polyester polyol can be obtained by polycondensation of dicarboxylic acids, such as adipic acid, with polyols, for example diols, such as hexanediol, neopentyl glycol, or mixtures thereof. Polycarbonates containing hydroxyl groups include those known per se, such as products obtained by the reaction of diols, such as (1,3)-propanediol, (1,4)-butanediol, and / or (1,6)-hexanediol, diethylene glycol, triethylene glycol, or tetraethylene glycol with diaryl carbonates, for example diphenyl carbonate or phosgene. Polyether polyols can be obtained in any known manner by reacting starting compounds containing reactive hydrogen atoms with alkylene oxides, such as, for example, ethylene oxide, propylene oxide, butylene oxide, styrene oxide, tetrahydrofuran, or epichlorohydrin, or with mixtures of these alkylene oxides. In some embodiments, the polyethers contain no more than about 10% by weight of ethylene oxide units. For example, polyethers obtained without the addition of ethylene oxide may be selected. Furthermore, the above-mentioned polyether polyols may contain a fraction derived from dimerized fatty alcohols, for example, hydrogenated dilinolyl alcohol. Vinyl polymer-modified polyethers are also suitable according to various disclosure embodiments. Products of this type can be obtained by polymerization, for example, of styrene and acrylonitrile in the presence of polyethers. Among the polythioethers that can be selected are condensation products obtained from thiodiglycol itself and / or with other glycols, dicarboxylic acids, formaldehyde, aminocarboxylic acids, and / or amino alcohols. The resulting products are either mixed polythioethers, polythioether esters, or polythioether amide esters, depending on the co-components. Polyacetals include, but are not limited to, compounds that can be prepared from aldehydes, for example formaldehyde, and glycols, such as diethylene glycol, triethylene glycol, 4,4*-(dihydroxy)diphenyl-dimethylmethane ethoxylated, and (1,6)-hexanediol. Polyacetals useful according to various non-limiting embodiments disclosures can also be prepared by polymerization of cyclic acetals. Polyhydroxypolyesteramides and polyamines include, for example, predominantly linear condensation products obtained from saturated or unsaturated polybasic carboxylic acids or anhydrides thereof, and from saturated or unsaturated polyvalent amino alcohols, diamines or polyamines, and mixtures thereof. Monomers for the production of polyacrylates with hydroxyl functionality include acrylic acid, methacrylic acid, crotonic acid, maleic anhydride, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate, 3-hydroxypropyl methacrylate, glycidyl acrylate, glycidyl methacrylate, 2-isocyanatoethyl acrylate and 2-isocyanatoethyl methacrylate. Polyisocyanates include, for example, organic diisocyanates with molecular weights ranging from about 100 to about 1,500, as well as from about 112 to about 1,000, or from about 140 to about 400. Diisocyanates are those chosen from the general formula R(NCO3), in which Ra represents a divalent aliphatic hydrocarbon group comprising about 4 to 18 carbon atoms, a divalent cycloaliphatic hydrocarbon group comprising about 5 to 15 carbon atoms, or a divalent aromatic hydrocarbon group comprising about 6 to 15 carbon atoms. Examples of organic diisocyanates that may be chosen include, but are not limited to, tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, dodecamethylene diisocyanate, cyclohexane-1,3-diisocyanate, and cyclohexane-1,4-diisocyanate. 1-isocyanato-3-isocyanatomethyl-3,5,5-trimethylcyclohexane (isophorone diisocyanate or IPDI), bis(4-isocyanatocyclohexyl)-methane, 1,3-bis(isocyanatomethyl)-cyclohexane and 1,4-bis(isocyanatomethyl)cyclohexane and bis(4-isocyanato-3-methylcyclohexyl)methane. Diisocyanate mixtures may also be used. In some embodiments, the diisocyanates are selected from aliphatic and cycloaliphatic diisocyanates. For example, 1,6-hexamethylene diisocyanate, isophorone diisocyanate, and dicyclohexylmethane diisocyanate, as well as mixtures thereof, may be selected. Low molecular weight diols can, in at least some embodiments, stiffen the polymer chain. The term "low molecular weight diols" refers to diols having a molecular weight range from about 50 to about 800, for example, from about 60 to 700, or from about 62 to 200. They can, in various embodiments, contain aliphatic groups, Alicyclic or aromatic. In some embodiments, the compounds contain only aliphatic groups. The diols that may be chosen can optionally have up to about 20 carbon atoms and may be selected, for example, from ethylene glycol, diethylene glycol, propane-1,2-diol, propane-1,3-diol, butane-1,4-diol, 1,3-butylene glycol, neopentyl glycol, butylethylpropanediol, cyclohexanediol, 1,4-cyclohexanedimethanol, hexane-1,6-diol, bisphenol A (2,2-bis(4-hydroxyphenyl)propane), hydrogenated bisphenol A (2,2-bis(4-hydroxycyclohexyl)-propane), or mixtures thereof. Optionally, the low molecular weight diols may contain ionic or potentially ionic groups. Suitable low molecular weight diols containing ionic or potentially ionic groups may be selected from those described in U.S. Patent No. 3,412,054. In various embodiments, the compounds may be selected from dimethylolbutanoic acid (DMBA), dimethylolpropionic acid (DMPA), and caprolactone polyester diol containing carboxyl groups. If low molecular weight diols containing ionic or potentially ionic groups are selected, they may, for example, be used in an amount such that less than about 0.30 meq of -COOH is present per gram of polyurethane in the polyurethane dispersion. In some embodiments, low molecular weight diols containing ionic or potentially ionic groups are not used. Coreactives (ii) are compounds containing functional groups such as hydroxyl or amine groups, adapted to react with isocyanate groups in preference to the carboxyl group. More specifically, the coreactives (il) are aliphatic, cycloaliphatic, or aromatic hydrocarbons substituted with at least two hydroxyl or amine groups, and optionally substituted with ionic or potentially ionic groups. In various embodiments, the compounds may optionally be selected from alkylene diamines, such as hydrazine, ethylenediamine, propylenediamine, 1,4-butylenediamine, and piperazine. In various embodiments, the compounds may be selected from alkylene diols, such as ethylene glycol, 1,4-butanediol (1,4-BDO or BDO), and 1,6-hexanediol. As used here, ionic or potentially ionic groups may include groups comprising ternary or quaternary ammonium groups, groups convertible into such groups, carboxyl groups, carboxylate groups, sulfonic acid groups, and sulfonate groups. At least partial conversion of convertible groups into salt groups of the type mentioned may occur before or during mixing with water. Special compounds may be selected from dimethylolbutanoic acid (DMBA) and dimethylolpropionic acid. (DMPA), or carboxyl-function polyester comprising excess equivalents of dicarboxylic acid having reacted with lesser equivalents of glycol or caprolactone polyester diol containing a carboxyl. The terminal cap agent (iii) can be derived from compounds having the formula: R- NH-R°, in which R represents a hydrogen atom or an alkylene radical having optionally a hydroxyl end and R° represents an alkylene radical having optionally a hydroxyl end. Suitable capping agents include compounds such as monoamines, particularly secondary monoamines or monoalcohols. Examples include: methylamine, ethylamine, propylamine, butylamine, octylamine, laurylamine, stearylamine, isononyloxypropylamine, dimethylamine, diethylamine, dipropylamine, dibutylamine, N-methylaminopropylamine, diethyl(methyl)aminopropylamine, morpholine, piperidine, diethanolamine and suitable substituted derivatives thereof, amide-amines of primary diamines and monocarboxylic acids, monocetimes of primary diamines, primary / tertiary amines such as N,N-dimethylaminopropylamine and similar. The final capping agent may be chosen from Cy-C,O alcohols, such as methanol, butanol, hexanol, 2-ethylhexyl alcohol, isodecyl alcohol, and mixtures thereof, or chosen from fatty alcohols, such as stearyl alcohol, cetanol, eicosanol, and mixtures thereof, and amino alcohols such as aminomethylpropanol (AMP) are also suitable. By way of non-limiting example, polyurethane polymer includes, but is not limited to, a copolymer of isophthalic acid / adipic acid / hexylene glycol / neopentyl glycol / dimethylolpropanoic acid / isophorone diisocyanate (INCI name: Polyurethane-1, such as LUVISET® PU R, BASF), a copolymer of hexylene glycol, neopentyl glycol, adipic acid, saturated methylene diphenyl diisocyanate monomers, and dimethylolpropanoic acid (INCI name: Polyurethane-2), a copolymer of PPG-17, PPG-34, isophorone diisocyanate, and dimethylolpropanoic acid monomers (INCI name: Polyurethane-4), a copolymer of isophthalic acid, adipic acid, hexylene glycol, neopentyl glycol, and dimethylolpropanoic acid. panoic acid, isophorone diisocyanate and bis-ethylaminoisobutyldimethicone monomers (INCI name: Polyurethane-6), a copolymer of isophorone diisocyanate, cyclohexanedimethanol, dimethylol butanoic acid,of polyalkylene glycol and N-methyl diethanolamine (INCI name: Polyurethane-10), a copolymer of trimethylolpropane, neopentyl glycol, dimethylolpropionic acid, polytetramethylene ether glycol and isocyanato methylethylbenzene (INCI name: Polyurethane-12), a copolymer of isophorone diisocyanate, dimethylolpropionic acid and 4,4*-isopropylidenediphenol having reacted with propylene oxide, ethylene oxide and PEG / PPG-17 / 3 (INCI name: Polyurehane-14), , a copolymer of isophorone diisocyanate, adipic acid, triethylene glycol and dimethylolpropionic acid (INCI name: Polyurethane-15), a polymer of 2-methyl-2,4-pentanediol, with 2,2-dimethyl-1,3-propanediol, hexanedioic acid, methylenedicyclohexanediisocyanate and acid 2,2-Di(hydroxymethyl)propanoic acid, hydrolyzed, tris(2-hydroxyethyl)amine salts, reaction products with 1,2-ethanediamine (INCI name: Polyurethane-17), a complex polymer formed by the reaction of polyperfluoroethoxymethoxy difluorohydroxyethyl ether and isophorone diisocyanate (IPDI) to form a prepolymer, the prepolymer then reacting with the triethylamine salt of 3-hydroxy-2-(hydroxymethyl)-2-methyl-1-propionic acid (INCI name: Polyurethane-27), a complex polymer formed by the reaction of dimethylolpropionic acid and a polyester composed of adipic acid, hexylene glycol, neopentyl glycol with methylene dicyclohexyldiisocyanate (SMDI) to form a prepolymer, which is neutralized with triethylamine and whose chain is then lengthened with hydrazine (INCI name: Polyurethane-33);those sold under the Baycusan® brand by Bayer, such as Baycusan® C1000 (INCI name: Polyurethane-34), Baycusan® C1001 (INCI name: Polyurethane-34), Baycusan® C1003 (INCI name: Polyurethane-32), Baycusan® C1004 (INCI name: Polyurethane-35), Baycusan® C1008 (INCI name: Polyurethane-48), a copolymer formed by reacting hydrogenated polybutanediol, 1,6-hexamethylene diisocyanate, hydrogenated dilinolyl alcohol, and 1,4-butanediol, and capped with stearyl alcohol, under the trade name Oilkemia™ 5S Polymer available from Lubrizol Corporation (INCI name: Polyurethane-79), and Oilkemia™ 5S CC Polymer available from Lubrizol Corporation (INCI name: HDI / TRIMETHYLOL HEXYLLACTONE CROSSPOLYMER). ; In one embodiment, the polyhydroxylated compounds are polyester polyols, and preferably, homopolymers or copolymers of lactones, such as γ-butyrolactone, γ-caprolactone, γ-caprolactone, ε-caprolactone and / or methyl-ε-caprolactone, with dihydric or trihydric alcohols, such as butanediol and trimethylolpropane. In another embodiment, the polyhydroxylated compounds are polyether polyols, preferably obtained by reaction of starting compounds which contain reactive hydrogen atoms with alkylene oxides, for example butylene oxide, and in particular polyether polyols containing a fraction derived from dimerized fatty alcohols, for example hydrogenated dilinoleyl alcohol. In one embodiment, the polyisocyanate is selected from diisocyanates containing aliphatic, cycloaliphatic, and aromatic hydrocarbon groups, in particular 1,6-hexamethylene diisocyanate, isophorone diisocyanate, and dicyclohexylmethane diisocyanate. In one embodiment, the coreactive is chosen from compounds containing functional groups such as hydroxyl or amine groups, suitable for reacting with isocyanate groups in preference to the carboxyl group, and is preferably chosen from alkylenediamines, such as hydrazine, ethylenediamine, propylenediamine, 1,4-butylenediamine, piperazine, and alkylenediols, such as ethylene glycol, 1,4-butanediol and 1,6-hexanediol. In one embodiment, the terminal cap agent is selected from monoamines, alkanolamines, amide-amines, C,-C;p alcohols, and fatty alcohols, such as stearyl alcohol, and mixtures thereof. According to the present invention, particularly preferable polyurethane polymers are the crosslinked polymer HDI / trimethylol hexyllactone; and a copolymer formed by the reaction of hydrogenated polybutanediol, 1,6-hexamethylene dii-socyanate, hydrogenated dilinoleyl alcohol, and 1,4-butanediol, and capped with stearyl alcohol; and for example, the products under the trade names OilkemiaTM 5S CC POLYMER and OilkemiaTM 5S POLYMER available from Lubrizol Corporation. Advantageously, the interface stabilizer is present in an amount ranging from about 0.01% by weight to about 10% by weight, preferably from about 0.05% by weight to about 5% by weight, or from about 0.1% by weight to about 2% by weight, relative to the total weight of the composition. Furthermore, the interface stabilizer according to the present invention can provide improved rheology, thickening efficiency, clarity, and a non-sticky feel for the product containing it. In other words, the interface stabilizer according to the present invention also serves as a thickener or gelling agent. Traditionally, thickeners or gelling agents can also be selected from amides, for example, polyamide 8 or cocamide MEA; acrylates, such as C0.39 alkyl polyacrylate or C0.30 alkyl acrylate crosslinked polymer; gums, for example, xanthan gum; cellulose derivatives, for example, hydroxypropylcellulose; and silicone crosslinked polymers, for example, vinyldimethicone crosslinked polymer. However, traditional thickeners or gelling agents, such as polyamides, acrylates, and gums, cannot play a role in strengthening and stabilizing the foams formed in the emulsified system, and some of them even worsen the foaming performance of the emulsified system. Surprisingly, the inventor discovered that the interface stabilizer according to the present invention not only improves rheology, thickening efficiency, clarity, and non-sticky feel, but also strengthens and stabilize the foams formed in the emulsified system. By means of the interface stabilizer according to the present invention, foaming performance can be improved by more than about 20%, more than about 50%, and even up to about 100%, compared to the emulsified system which does not include such an interface stabilizer, in which the term "foaming performance" has a common meaning in the cosmetic field, including but not limited to the volume, density and stability of foams in an emulsified system. Aqueous phase Generally, the composition according to the present invention comprises at least one aqueous phase. The aqueous phase of the composition according to the present invention comprises water and optionally one or more water-miscible or at least partially water-miscible compounds, for example lower C, to C polyols; or monoalcohols, such as ethanol and isopropanol. The term "polyol" should be understood as any organic molecule containing at least two free hydroxyl groups. Examples of polyols include glycols, such as butylene glycol, propylene glycol, and isoprene glycol, caprylyl glycol, glycerol (i.e., glycerin), and polyethylene glycols. The aqueous phase may represent from approximately 20% by weight to approximately 80% by weight, preferably from approximately 20% by weight to approximately 60% by weight, or from approximately 30% by weight to approximately 60% by weight, relative to the total weight of the composition. Other ingredients The composition according to the present invention may also include other ingredients, known elsewhere in cosmetic compositions, such as the cosmetic active, for example hydroxyacetophenone, and various common adjuvants, for example sequestering agents such as EDTA and etidronic acid, preservatives such as phenoxyethanol and salicylic acid, opacifiers, perfumes, and so on. Combination The combination according to the present invention comprises, substantially consists of, or even consists of a surfactant system and at least one interface stabilizer, for improving foam properties, even for products with a high oil content. More specifically, the surfactant system comprises at least one alkyl sulfosuccinate as an anionic surfactant and at least one amphoteric surfactant, and optionally at least one nonionic surfactant, as mentioned above. Preferably, the alkyl sulfosuccinate is chosen from mono- or di-alkyl sulfosuccinates, the amphoteric surfactant is chosen from alkyl (in Cg-C»0) Amido-alkyl (C,-C;) betaines, and the nonionic surfactant are selected from alkyl polyglucosides, where the alkyl sulfosuccinate, the amphoteric surfactant, and the nonionic surfactant, and their quantities, are defined as above. Furthermore, the interface stabilizer and its quantities are defined as above. In one embodiment, the present invention discloses a combination for improving the foam properties of high-oil products, comprising a surfactant system consisting of at least one monoalkyl sulfosuccinate, at least one dialkyl sulfosuccinate and at least one alkyl (Cs-C30) amido-alkyl (C,-C) betaine, and an interface stabilizer which is a polyurethane polymer; preferably, the present invention discloses a combination for improving the foam properties of high-oil products, comprising a surfactant system consisting of cocamidopropyl betaine, disodium lauryl sulfosuccinate and sodium diethylhexyl sulfosuccinate, and a polyurethane polymer as mentioned above. In another embodiment, the present invention discloses a combination for improving the foam properties of high-oil products, comprising a surfactant system consisting of at least one mono-alkyl sulfosuccinate and at least one alky (Cs-Czo) amido-alky (C,-C«) betaine, and an interface stabilizer which is a polyurethane polymer; preferably, the present invention discloses a combination for improving the foam properties of high-oil products, comprising a surfactant system consisting of cocamidopropyl betaine and disodium lauryl sulfosuccinate, and a polyurethane polymer as mentioned above. In yet another embodiment, the present invention discloses a combination for improving the foam properties of high-oil products, comprising a surfactant system consisting of at least one dialkyl sulfosuccinate, at least one alkyl polyglucoside and at least one alkyl (in Cz-Cz0) amido-alkyl (in C,-C5) betaine, and an interface stabilizer which is a polyurethane polymer; preferably, the present invention discloses a combination for improving the foam properties of high-oil products, comprising a surfactant system consisting of cocamidopropyl betaine, caprylyl / capryl glucoside and sodium diethylhexyl sulfosuccinate, and a polyurethane polymer as mentioned above. As used here, the term "high oil content" means that the total amount of oils in a product represents more than about 10% by weight, and even more than about 40% by weight, relative to the total weight of the product. The "product" in the expression "high-oil product" preferably comes in the form of an emulsion, lotion, balm, or cream, and is preferably used for cleansing and / or removing makeup from keratinous materials, particularly from facial skin. Until now, for cleaning products, the foaming properties have been strongly influenced by the oil content, and a product with a high oil content normally has very poor foaming properties. Thanks to the combination according to the present invention, it is possible to obtain good to excellent foaming properties even with a very high oil content, for example, an oil content exceeding approximately 10% by weight, and even exceeding approximately 40% by weight, relative to the total weight of the product. Foaming composition The foaming composition according to the present invention comprises a surfactant system, at least one oil, an interface stabilizer, and an optional aqueous phase, particularly for cleansing and / or removing makeup from keratinous materials, especially facial skin, and optionally in the form of an emulsion, lotion, balm or cream. More specifically, the surfactant system comprises at least one alkyl sulfosuccinate as an anionic surfactant and at least one amphoteric surfactant, and optionally at least one nonionic surfactant. The surfactant system, each surfactant it contains, and the quantities of the surfactant system and each surfactant are defined as above. At least one oil is selected from vegetable or animal oils, ester oils, ether oils, hydrocarbon oils, silicone oils, and mixtures thereof; and the interface stabilizer is selected from a polyurethane polymer. The at least one oil, the interface stabilizer, and their quantities are defined as above. The aqueous phase comprises water and optionally at least one monoalcohol and / or polyol as defined above. Alternatively, the foaming composition according to the present invention comprises the above combination and at least one oil, wherein both the combination and the at least one oil are defined as above. The weight ratio of the polyurethane polymer to at least one oil ranges from about 1:500 to about 1:1, preferably between about 1:200 and about 1:10, or between about 1:100 and about 1:25. Compositions containing less polyurethane polymer than the above ranges may not achieve desirable foaming performance, and compositions containing more polyurethane polymer than the above ranges may instead inhibit foam strengthening. Thanks to the specific components and specific weight ratio of the polymer polyurethane on at least one oil, the cleaning composition according to the present invention allows effective cleaning of keratinous materials, perceived and desirable foams, and no irritation of the eyes and keratinous materials, leaving the keratinous materials fresh and clean. Method and use The composition according to the present invention can be used for a cleansing and / or makeup removal process of keratinous materials, such as skin, in particular the face, by being applied to the keratinous materials. The composition according to the invention can be applied by any means allowing uniform distribution, in particular with a finger, or cotton, a stick, a brush, gauze, or a spatula, and can be removed by rinsing with water. Thus, according to another aspect, the present invention relates to a method for cleaning and / or removing makeup from keratinous materials, in particular from the skin, comprising applying to the keratinous materials, in particular the skin, the composition according to the present invention, and rinsing off said composition after an optional time. According to yet another aspect, the present invention relates to the use of the combination according to the present invention to improve the properties of the foam, even for products with a high oil content. According to yet another aspect, the present invention relates to the use of a polyurethane polymer, in particular formed by the reaction of a prepolymer (i) with a coreactive (ii), and optionally terminated by a terminal capper (iii), in which the prepolymer (i) is formed by the reaction of polyhydroxylated compounds, polyisocyanates, and optionally low molecular weight diols, to improve the rheology of an emulsified system and to strengthen and stabilize the foams formed therein. The present invention is illustrated in more detail by the examples described below, which are given by way of non-limiting illustration. EXAMPLES The main raw materials used, their trade names and their suppliers are listed in Table 1. [Table 1] [NOM INCI NOM |POURNISSEU COMMERCIAL DIETHYLHEXYL SODIUM SUL- |TEGO SULFO- | |EVONIK FOSUCCINATE SUCCINATEDO |GOLDSCHMI 75 [DISODIUM LAURYL SULFO- | |FS401P GUANGZHOU DISODIUM LAURYL SULFO- |FS4O1P GUANGZHOU SUCCINATE FLOWER'S SONG FINE CHEMIC COCAMIDOPROPYL BETAINE | |DEHYTONPK45 |BASF CAPRYLYL / CAPRYL ORAMIX CG 110L |SEPPIC GLUCOSIDE CAPRYLIC / CAPRIC TRI- OILKEMIA 5S CC [LUBRIZOL GLYCERIDE (and) HY- POLYMER DROGENATED POLY(C6-20 OLEFIN) (and) HDI / TRIMETHYLOL HEXYLLACTONE | CROSSPOLYMER POLYURETHANE-79 (and) OILKEMIA 55 [LUBRIZOL CAPRYLIC / CAPRIC TRI- POLYMER GLYCERIDE HELIANTHUS ANNUUS REFINED AAK KAMANI (SUNFLOWER) SEED OIL SUNFLOWER OIL |PRIVATE ETHYLHEXYL PALMITATE CEGESOFT C24 |BASF ISOPROPYL MYRISTATE ISOPROPYLMYRI [BASF POLYURETHANE-79 (and) to OILKEMIA 5S [LUBRIZOL CAPRYLIC / CAPRIC TRI- POLYMER GLYCERIDE HELIANTHUS ANNUUS REFINED AAK KAMANI (SUNFLOWER) SEED OIL SUNFLOWER OIL |PRIVATE ETHYLHEXYL PALMITATE CEGESOFT C24 BASF ISOPROPYL MYRISTATE ISOPROPYLMYRI BASF STATE |DIMETHICONE KF-96 A-6CS SHIN ETSU ISODODECANE ISODODECANE |INEOS ACRYLATE CROSSPOLYMER POLYMER |POLYAMIDE-8 OLEOCRAFT LP- |CRODA 20-PA-(MV) Inventive examples 1, 1' ct 2 ct comparative examples 1 to 5 The compositions according to inventive formulas IE. 1, l' and 2 and comparative formulas EC. 1 to 5 were prepared with the ingredients listed in Table 2 (the contents are expressed as weight percentages of the ingredients relative to the total weight of each composition, unless otherwise indicated): [Tables 2] C10.0 alkyl acrylate cross-linked polymer, xanthan gum OIL [50 [50 |s0 [50 [50 [50 [50 |50 HELIANTHUS | ANNUUS (SUNFLOWER) SEEDS RSS [3488 [3.488 [3488 [3.488 [3488 [3488 [3488 | SODIUM SULFOSUCCINATE Preparation procedure: The compositions were prepared as follows: 1) Mix water, cocamidopropyl betaine, glycerin and caprylyl / capryl glucoside at 65°C in the main tank to obtain premix 1, 2) Mix the oil / oil mixture with the crosslinked caprylic / capric triglyceride polymer (and) hydrogenated poly(Ce.20 olefin) (and) HDU / trimethylol hexyllactone or polyurethane-79 or polyamide-8 or C10-30 alkyl polyacrylate at 90 °C in an annex under stirring to obtain premix 2, and 3) Mix premix 1 with premix 2, and cool to room temperature, then add sodium diethylhexyl sulfosuccinate; or (l) Mix water, cocamidopropyl betaine, glycerin, caprylyl / capryl glucoside and C10.20 acrylate / alkyl acrylate crosslinked polymer or xanthan gum at 65 °C in the main tank to obtain premix 1, 2') Add the oil / oil mixture to an annex at room temperature to obtain premix 2, and 3') Mix the premix | with premix 2, and cool to room temperature, then add sodium diethylhexyl sulfosuccinate. Foaming performance evaluation Preparation procedure: 1) take 0.5 ml of each composition to be tested with a syringe, and 3 x 1 ml of water with pipettes; 2) Rinse hands under tap water for 2 seconds and place 0.5 ml of product onto the palm with the syringe, then add 1 ml of water with a pipette; 3) make back-and-forth movements for 20 rounds (2 circles / second) and pause to gather the foam in the palm to prevent it from running if necessary; 4) Add another 1 ml of water with a pipette and make back-and-forth movements for 20 revolutions (2 circles / second), pausing to collect the foam in the palm of your hand to prevent it from running if necessary; and 5) Gather all the foam in one palm. The foaming property was evaluated by the volume and density of the foam obtained at the end of the hand rubbing (40 turns), regardless of the bubble size. A score on a scale of 0 to 15 was assigned, where 0 meant the foaming property was nonexistent, 1 to 4 meant poor foaming property, 5 to 7 meant average foaming property, 8 to 11 meant good foaming property, and 12 to 15 meant excellent foaming property. Foam stability was evaluated by the volume of foam obtained after 30 s. A score in a range of 0 to 15 was given, where 0 meant that the foam property was zero, 1 to 4 meant a weak foam property, 5 to 7 meant an average foam property, 8 to 11 meant a good foam property, and 12 to 15 meant an excellent high foam property. The results have been summarized in Table 3. [Tables 3] Properties |IE.1* |IE1 |IE2 |CE.1 |CE.2 |CE.3 |CE.4 |CE.5 Properties |14 | [12 9 4 | 1 2 foaming Stability of [12 [12 |r Je [qe qu foaming According to Tables 2 and 3 above, it can be seen that the compositions, i.e. IE. 1, IE. 1' and IE. 2, comprising the specific interface stabilizer according to the present invention, have indeed achieved excellent foaming performance, including both foaming properties and foaming stability, since all have obtained scores of 12 or more. In contrast, compositions containing traditional thickeners, for example those included in ECs 2 to 5, did not provide improved foaming performance and even deteriorated foaming performance compared to composition EC 1, which did not include the thickeners listed in ECs 2 to 5 or the interface stabilizer according to the present invention. However, the interface stabilizer of the present invention not only improved the rheology and thickening efficiency of the compositions, as is known to those skilled in the art, but also strengthened and stabilized the foams formed in these compositions. Inventive examples 1, 3, 4 and 4' The compositions according to inventive formulas IE. 1, 3, 4 and 4' were prepared with the ingredients listed in Table 4 (the contents are expressed as percentages) (by weight of ingredients relative to the total weight of each composition, unless otherwise indicated): [Tables 4] |IE. 1 (IE. 3 |IE. 4 (IE. & @ js es les 2,147 J2147 J2,147 |2,147 D # p 5 _|o5 [2208 [5 [3.5 [5 Jo |50 |50 |50 Preparation procedure: The compositions were prepared as follows: 1) Mix water, cocamidopropyl betaine, glycerin and caprylyl / capryl glucoside, if present, at 65 °C in the main tank to obtain premix 1; 2) Mix the oil / oil mixture with the crosslinked caprylic / capric triglyceride polymer (and) hydrogenated C420 poly(olefin) (and) HDI / trimethylol hexyllactone or polyurethane-79 at 90 °C in an annex under agitation to obtain premix 2; and 3) Mix premix 1 with premix 2, and cool to room temperature, then add disodium lauryl sulfosuccinate and / or sodium diethylhexyl sulfosuccinate. Foaming performance evaluation The foaming property and foaming stability of the compositions obtained were evaluated as described above. The results have been summarized in Table 5. [Tables 5] |IE.4 |IE.4 [Properties |1E.1 [14 (3 [Lo [12 [12 12 |Lo [1 [1 Foaming properties Foam stability According to Tables 4 and 5 above, it can be seen that the compositions, i.e. IE. 1, 3, 4 and 4' comprising the specific combination of the surfactant system and the interface stabilizer according to the present invention, have indeed obtained good to excellent foaming performance, including both foaming properties and foaming stability, even at a high content of 50% by weight of the oil, since all have obtained scores greater than 8. Inventive examples 1, 5, 5°, 6, 6°, 7 and 7 The compositions according to inventive formulas IE. 1, 5, 5', 6, 6°, 7 and 7” were prepared with the ingredients listed in Table 6 (the contents are expressed as weight percentages of the ingredients relative to the total weight of each composition, unless otherwise indicated): [Tables 6] |50 ss qe qe ETHYLHEXYL ISODODECAN DIMETHICONE Preparation procedure: The compositions were prepared as follows: 1) Mix water, cocamidopropyl betaine, glycerin and caprylyl / capryl glucoside at 65°C in the main tank to obtain premix 1; 2) Mix the oil / oil mixture with the crosslinked caprylic / capric triglyceride polymer (and) hydrogenated Ce-20 poly(olefin) (and) HDV / trimethylol hexyllactone or polyurethane-79 at 90 °C in an annex under stirring to obtain premix 2; and 3) Mix premix 1 with premix 2, and cool to room temperature, then add sodium diethylhexyl sulfosuccinate. Foaming performance evaluation The foaming property and foaming stability of the compositions obtained were evaluated as described above. The results have been summarized in Table 7. [Tables 7] Properties |IE1 |IES |IES |IE6 |E6 |IE7 |E7 Properties | 14 | 12 | 2 9 8 8 Foaming Stability of | 12 | 11 | It 8 qe qe qe foaming According to Tables 6 and 7 above, it can be seen that the compositions, i.e. IE. 1, 5, 5', 6, 6°, 7 and 7', comprising the specific oil / oil mixture according to the present invention, have indeed obtained good to excellent foaming performance, including both foaming properties and foaming stability, since all have obtained scores of 8 or more. E inventives 1, 8 and 8' if6 The compositions according to inventive formulas IE. 1, 8 and 8' and comparative formula CE. 6 were prepared with the ingredients listed in Table 8 (the contents are expressed as weight percentages of the ingredients relative to the total weight of each composition, unless otherwise indicated): [Tables 8] [0.2 0.2 |50 [10 [10 [lo Components _|xE. 1 ES ES cs WATER QS QS QS QS COCAMIDOPROPYL BETAINE [2,147 | |2147 2147 |2147 GLYCERIN 2 to 2 2 CAPRYLYL / CAPRYL [2208 |2208 [2.208 [2208 GLUCOSIDE DIETHYLHEXYL SULFO- 3488 |3488 [2488 |3488 SODIUM SUCCINATE TRHO5 CROSS-CROSS-CUT POLYMER |o2 CAPRYLIC / CAPRIC GLYCERIDE (and) HYDROGENATED POLY(OLEFIN | EN Cs2) (and) HDI / TRIMETHYLOL HEXYLLACTONE POLYURETHANE-79 (and) TRI- 0.2 CAPRYLIC / CAPRIC GLYCERIDE HELIANTHUS ANNUUS (SUNFLOWER) SEED OIL [50 | 10 | 10 | 10 Preparation procedure: The compositions were prepared as follows: 1) Mix water, cocamidopropyl betaine, glycerin and caprylyl / capryl glucoside at 65 °C in the main vessel to obtain premix 1; 2) Mix the oil / oil mixture with the crosslinked caprylic / capric triglyceride polymer (and) hydrogenated Ce.20 poly(olefin) (and) HDI / trimethylol hexyllactone or polyurethane-79, if present, at 90 °C in an annex under stirring to obtain premix 2; and. 3) Mix premix 1 with premix 2, and cool to room temperature, then add sodium diethylhexyl sulfosuccinate. Foaming performance evaluation The foaming property and foaming stability of the compositions obtained were evaluated as described above. The results have been summarized in Table 9. From Tables 8 and 9 above, it could be observed that the compositions, i.e. IE. 1, 8 and 8', comprising a specific weight ratio of the interface stabilizer to the oil / oil mixture according to the present invention, did indeed achieve good to excellent foaming performance, including both foaming properties and foaming stability, since all obtained scores greater than 8. Conversely, the composition not including the interface stabilizer of the present invention, i.e., CE.6, achieved only average foaming performance for foam stability, receiving a score of only 6. It can be seen that the specific interface stabilizer of the present invention effectively provided improved foaming performance for the composition, since compositions IE.8 and 8', having the same quantity of oil, achieved better foam stability than composition CE.6.
Claims
Demands
1. Foaming composition, comprising: (a) at least one oil, (b) at least one polymer interface stabilizer to improve the rheology of the composition and strengthening and stabilizing the foams that are there are formed, and (c) a surfactant system, comprising, substantially consisting of, or even made up of at least one alkyl sulfosuccinate, at least one amphoteric surfactant, and Optionally, at least one non-ionic surfactant.
2. Foaming composition according to claim 1, wherein the stabilizer- The interface reader is a polyurethane polymer, which is made of preference formed by the reaction of the prepolymer (i) with a coreactive (ii), and optionally terminates with a terminal cap agent, in which the prepolymer (1) is formed by the reaction of compounds polyhydroxylated compounds, such as a dihydroxyl compound or a tri- compound hydroxyl; of polyisocyanates, for example diisocyanates; and fa- optionally of low molecular weight diols which are faculta- tively substituted by ionic groups or ionic groups potential.
3. Foaming composition according to claim 2, wherein the The polyhydroxylated compound is selected from polyester polyols; preferentially homopolymers or copolymers of lactones, such as y- butyrolactone, y-caprolactone, 6-caprolactone, e-caprolactone and / or methyl-e-caprolactone, with dihydric or trihydric alcohols, such as butanediol and trimethylolpropane; or chosen from the po- 1. Ether polyols, preferably obtained by reaction of compounds of starting point containing hydrogen atoms that react with oxides of alkylene, for example butylene oxide, and in particular the po- lyether polyols containing a fraction derived from dimerized fatty alcohols, for example hydrogenated dilinoleyl alcohol; The polyisocyanate is chosen from among the aliphatic polyisocyanates, cy- cloaliphatic and aromatic compounds, preferably diisocyanates, and including 1,6-hexamethylene diisocyanate, diisocyanate of isophorone and dicyclohexylmethane diisocyanate; the coreactive agent is chosen from compounds containing functional groups functional groups such as hydroxyl or amine groups, adapted to react with isocyanate groups in preference to the carboxyl group, and is of preference chosen from among the alkylenediamines, such as hydrazine, ethy- lenediamine, propylenediamine, 1,4-butylenediamine and piperazine, and alkylenediols, such as ethylene glycol, 1,4-butanediol and 1,6-hexanediol; and / or The terminal cap agent is chosen from monoamines, alkanolamines, amide-amines, C,-C; alcohols, and fatty alcohols, for example alcohol stearyl.
4. Foaming composition according to any one of the preceding claims preceding, in which at least one alkyl sulfosuccinate is chosen among the alkyl mono- or di-sulfosuccinates in which the Alkyl radicals have from 4 to 24 carbon atoms, preferably from 6 to 18 carbon atoms, or 6 to 14 carbon atoms and the counter-ion at The sulfonic acid group is chosen from among the alkali metal cations. and ammonium ions; preferably, alkyl sulfosuccinate is chosen among disodium lauryl sulfosuccinate, diethylhexyl sulfosuccinate sodium and a mixture thereof, and at least one alkyl sulfosuccinate is present in an amount ranging from 0.5% by weight to 15% by weight, preferably from 1% by weight to 10% by weight, or from 2% by weight to 8% by weight, relative to the weight total composition.
5. Foaming composition according to any one of the preceding claims previous, in which the amphoteric surfactant is chosen from among the derivatives of secondary or optionally tertiary aliphatic amines quaternized; preferably, it is chosen from alkyl (in Cg-Czo) betaines, alkyl (C-C) amido-alkyl (C-C) betaines, and mixtures of these, and in particular cocamidopropyl betaine, co- coylbetaine, and a mixture thereof, and the amphoteric surfactant is present in an amount ranging from 0.5% in weight at 20% by weight, preferably from 1% to 10% by weight, or from 2% by weight to 5% by weight, relative to the total weight of the com- position.
6. Composition according to any one of the preceding claims, in which at least one oil is chosen from among the oils of origin vegetable or animal oils, ester oils, ether oils, silicone oils, hydrocarbon oils, and mixtures thereof; Preferably, ester oils are liquid esters of monoacids or aliphatic polyacids in CyO-Czp, saturated or unsaturated, linear or branched, and aliphatic monoalcohols or polyalcohols in C>-C10, saturated or unsaturated, linear or branched, the total number of atoms of carbon of the esters being greater than or equal to 10; and in particular for the esters of monoalcohols, at least one of the alcohol and acid of which are derived from the esters being branched.
7. Composition according to claim 6, wherein at least one oil includes at least one oil of vegetable or animal origin and / or at least one C10-C20 saturated aliphatic monoacid ester(s) and of saturated C2-C10 aliphatic monoalcohol(s), and faculta- tively at least one silicone oil and / or at least one hydro- oil carbonaceous, in which the oil of vegetable or animal origin is preferably vegetable oil, particularly sunflower oil; the ester of saturated aliphatic monoacid(s) in C,p-Cx and aliphatic monoalcohol(s) saturated phatic(s) at C>-C,0 is preferably chosen from palmitate ethylhexyl, isopropyl myristate and a mixture thereof; oil silicone is preferably chosen from among the dimethicones; and the oil The preferred hydrocarbon is isododecane.
8. Combination for improving the properties of a foam, even for products with a high oil content, including, consisting of sen- possibly in, or even consisting of, a surfactant system and at least an interface stabilizer to improve the rheology of the composition and to strengthen and stabilize the foams formed there, in which the interface stabilizer is a poly- polymer urethane, and the surfactant system consists of a mono- or di- alkyl sulfosuccinate, a C;-C»0 alkyl amido-alkyl (C,-C6) betaine, and an alkyl polyglucoside; The term "high oil content product" means that oil is present in an amount exceeding 10% by weight, and even exceeding 40% by weight, in relation to the total weight of the product.
9. Foaming composition for cleansing and / or removing makeup Keraline materials, especially from facial skin, and preferably in the form of an emulsion, lotion, balm or cream, comprising the combination according to claim 8 and at least one selected oil among vegetable oils, ester oils, dimethicones, hydro- linear or branched carbides, and mixtures thereof; Preferably, at least one oil includes at least one oil of vegetable origin, and / or at least one C;-C;0 alkyl palmitate, and / or at least one C-Cyp alkyl myristate, and optionally at least a dimethicone and / or an isododecane, and at least one oil is present in a quantity greater than 10% by weight, or even greater than 40% by weight, relative to the total weight of the composition.
10. Use of a polyurethane polymer, in particular that is formed by the reaction of a prepolymer (i) with a coreactive (ii), and optionally is terminated by a terminal cap agent (iii), in which the pre- polymer (i) is formed by the reaction of polyhydroxylated compounds, of polyisocyanates, and optionally low molecular weight diols, to improve the rheology of an emulsified system and strengthen and stabilize the foams formed within it.