Detergent and exfoliating hair cosmetic composition comprising salicylic acid and suspended particles

Abstract

The present invention relates to a cosmetic composition comprising (i) salicylic acid and / or at least one salt of salicylic acid in a concentration of at least 1.5% by weight, (ii) solid particles having an average number size greater than or equal to 300 µm, (iii) at least one anionic surfactant, (iv) at least one amphoteric or zwitterionic surfactant, and (v) at least one crosslinked anionic copolymer of at least one monomer A selected from vinyl carboxylic acids and at least one monomer B having at least one α,β-ethylenic unsaturation. The invention also relates to a process for treating keratinous materials, comprising at least one step of applying such a composition to said materials.

Description

Description Title of the invention: DETERGENT AND EXFOLIATING HAIR COSMETIC COMPOSITION COMPRISING SALICYLIC ACID AND PARTICLES IN SUSPENSION

[0001] — The present invention relates to a hair cosmetic composition with de- detergent and exfoliating agent, which comprises salicylic acid or a salt of such an acid, at least one anionic surfactant, at least one amphoteric or zwitterionic surfactant, solid particles and at least one particular anionic acrylic copolymer.

[0002] — The invention also relates to a process for treating keratin materials, comprising at least one step of applying a composition to said materials according to the invention.

[0003] = For cleaning and / or washing keratin materials such as hair and the scalp, the use of detergent compositions (such as shampoos) to based mainly on surfactants is common. These compositions are app- applied to wet hair and the lather generated by massage or friction with hands allows, after rinsing with water, the elimination of various initial dirt- initially present on the hair and scalp.

[0004] = However, these compositions do not always allow the complete elimination of dirt and / or to obtain a clean visual effect. In particular, in the case of users having a scalp that tends to be oily and / or gives rise to des- quamation, traditional detergent compositions do not always allow to completely eliminate organic matter (sebum, dandruff, etc.) formed during surface of the scalp and / or attached to the hair. There is therefore a need to de- develop cosmetic compositions intended for treatment and in particular for washing of keratin materials, which allow both the elimination of or- organic, in particular dandruff, when present, and to prevent their appearance.

[0005] …— Consumers are also looking for cosmetic compositions which contain greater proportions of natural and biodegradable ingredients, advan- typically silicone-free compositions, which have improved usability and good cosmetic properties, and are able to wash keratin materials without weighing them down so as to provide good conditioning properties for keratin fibers.

[0006] At the same time, users of cosmetic products are often looking for more aesthetic, even more original hair hygiene products. There is therefore a real need to develop aesthetic, long-lasting, detergent cosmetic compositions based on natural and / or biodegradable ingredients, preferably not containing silicone, and enabling excellent washing properties to be obtained. These compositions must also have good usage properties, in particular in terms of foam initiation, quality and quantity of foam generated, and viscosity. It is also of interest that these compositions confer good conditioning properties to the keratin fibers, in particular in terms of feel, smoothness, suppleness and detangling. These aims are achieved with the present invention which notably relates to a composition, preferably cosmetic, comprising: (Gi) salicylic acid and / or at least one salicylic acid salt, in a total content of at least 1.5% by weight, relative to the total weight of the composition, (ii) solid particles having a number average size greater than or equal to 300 μm, in a total content of at least 0.2% by weight relative to the total weight of the composition, (iii) at least one anionic surfactant, (iv) at least one amphoteric or zwitterionic surfactant, and (v) at least one crosslinked anionic copolymer of at least one monomer A chosen from vinyl carboxylic acids and at least one monomer B having at least one α,β-ethylenic unsaturation chosen from the monomers of the following formulas: bl) CH,=CXY with X denotes hydrogen and Y denotes a group selected from -COOR, -CsH4R", CN, -CONH,, -NHCOCH,, -CONHC(CH;),, and -CON(CH-),, or X denotes CH; and Y denotes a group selected from -COOR, -C5H4R", -CN or - CH=CH, R denoting a C1-C2 alkyl group or a C2-C2 hydroxyalkyl group, preferably a C1-C2 alkyl group or a C1-C2 hydroxyalkyl group, R' denoting hydrogen, a C,-C alkyl group; or a Ca-Ce hydroxyalkyl group: b2) CH,=CH(OCOR") with R! denotes a C1-C4 alkyl group, preferably C1-C4. b3) CH,=CH2 or CH,=CHCH,. The composition according to the invention has excellent washing power for keratin materials. It effectively removes dirt and provides a clean visual effect. In addition, the composition according to the invention has an exfoliating effect on the scalp, noticeable upon application, which effectively removes organic matter, in particular sebum and fragments of tissues likely to form dandruff. It also helps remove dandruff attached to keratin fibers. The composition according to the invention also has a keratolytic action, which in combination with the exfoliating effect described above effectively prevents regreasing of the scalp and the formation of dandruff. Keratin materials remain clean for longer and the average interval between two shampoos can be extended. It has also been found that hair treated in this way is particularly light, soft to the touch, smooth to the touch, supple, easy to detangle and manageable. Furthermore, it has been observed that the composition according to the invention has good qualities of use, in particular good foam start, good quality and good quantity of foam. The composition according to the invention has a viscosity suitable for use as a shampoo. Furthermore, it has also been found that the composition according to the invention is stable over time, at atmospheric pressure and at 25°C. More particularly, the solid particles remain in homogeneous and stable suspension, and no phenomenon of dephasing of the particles within the composition has been observed. The visually stable and homogeneous suspension of these particles significantly improves the aesthetics and originality of the composition according to the invention. By "stable and homogeneous suspension", within the meaning of the invention, it is understood that said particles are dispersed homogeneously in the composition, that is to say distributed homogeneously within the composition, and that this homogeneous dispersion persists over time, that is to say that the particles do not float, do not sink, do not settle and / or do not form agglomerates in the composition over time, in particular after at least one month of storage. Advantageously, the composition comprising the suspended particles is clear. The invention also relates to a method for treating, in particular cosmetically, keratin materials, in particular human keratin materials such as hair and the scalp, comprising at least one step of applying to said keratin materials a composition according to the invention. Other objects, characteristics, aspects and advantages of the invention will appear even more clearly on reading the description and the example which follows. In this description, and unless otherwise indicated: - the expression “at least one” is equivalent to the expression “one or more” and can be substituted for it; - the expression "between…and…" is equivalent to the expression "ranging from… to…" and can be substituted for it, and implies that the limits are included; - by the expression "greater than" and respectively the expression "less than", we mean a strictly higher, respectively strictly lower open interval, and therefore the limits are not included; - by "keratin materials", we mean more particularly human keratin materials, and more preferably hair and scalp; - by "fatty acid", we mean an organic acid comprising in its structure a linear or branched, saturated or unsaturated hydrocarbon chain comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms, more preferably from 10 to 22 carbon atoms; - by “fatty alcohol” is meant an alcohol comprising in its structure a linear or branched, saturated or unsaturated hydrocarbon chain comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms, more preferably from 10 to 22 carbon atoms. Preferably, the composition according to the invention is free of silicone. By the expression "free of silicone", it is meant that the silicone(s) possibly present in the composition are included in a total content of less than or equal to 0.1% by weight, preferably less than or equal to 0.05% by weight, more preferably less than or equal to 0.01% by weight, relative to the total weight of the composition, and better still that the composition is free of silicone (0% by weight). By "silicone" is meant any organosilicon polymer or oligomer with a linear or cyclic, branched or crosslinked structure, of variable molecular weight, obtained for example by polymerization and / or by polycondensation of suitably functionalized silanes, and consisting essentially of a repetition of main units in which the silicon atoms are linked together by oxygen atoms (siloxane bond -Si-O-Si-), optionally substituted hydrocarbon radicals being directly linked via a carbon atom to said silicon atoms; and more particularly dialkylsiloxane polymers, amino silicones, dimethiconols. Salicylic acid l. The composition according to the invention comprises one or more compound(s) chosen from salicylic acid and salicylic acid salts. Salicylic acid salt refers to any compound in which salicylic acid is in anionic form, combined with any mineral or organic cation. Salts derived from a mineral or organic base are preferably used. As a mineral base, we can notably cite alkali or alkaline earth metal hydroxides such as sodium hydroxide, potassium hydroxide or ammonia. As organic base, mention may in particular be made of amines and alkanoamines. Preferably, the composition comprises one or more compounds chosen from salicylic acid and the sodium or potassium salts of salicylic acid. Even more preferably, the composition contains salicylic acid. Preferably, the composition contains salicylic acid and / or at least one salicylic acid salt in a total content ranging from 1.5% to 8% by weight, preferably from 1.8 to 6% by weight, and better still from 2 to 5% by weight relative to the total weight of the composition. Preferably, the composition contains salicylic acid in a content of at least 1.5% by weight, better still ranging from 1.5% to 8% by weight, preferably from 1.8 to 6% by weight, and better still from 2 to 5% by weight relative to the total weight of the composition. The particles The composition according to the present invention further comprises one or more solid particles. Solid particles are small solid objects that can be of varying shapes and sizes. They can be regular or irregular in shape. In particular, they can be spherical (such as granules, pellets, balls), square, rectangular, or elongated, such as rods. The composition according to the invention comprises a total content of at least 0.2% by weight, relative to the total weight of the composition, of solid particles having a number average size greater than or equal to 300 um, preferably in the range from 300 to 1500 um, preferably from 350 to 1000 um, better still from 400 to 800 um. The number average particle size is expressed relative to the largest number average dimension of said particles. These particle sizes can be measured with a laser particle size analyzer (e.g. using a Brookhaven BI90 or Malvern device). These particle sizes can also be measured using particle size analysis sieves. The solid particles that can be used in the composition according to the invention can be chosen from mineral particles and organic particles. The solid particles are preferably chosen from organic particles and more preferably from organic particles of plant origin, in particular fragments of one or more plants. For the purposes of the present invention, the term "fragment" means a piece or part of a plant, obtained for example by uprooting or grinding the plant, or by cutting said plant. For the purposes of the present invention, the term "fragments of one or more plants" means that the composition comprises either several fragments of a single species of plant, or that the composition comprises several fragments of several different species of plants. Preferably, the composition comprises plant fragments in the form of powdered plant materials, obtained for example by grinding these materials. The plant materials may be, for example, kernels, seeds, hulls, or seeds of plants. Preferably, the composition according to the invention comprises at least one powder of plant origin, in particular at least one powder of plant materials, more preferably chosen from kernel powders such as, for example, apricot kernel powder, plum kernel powder, olive kernel powder; nut shell powders such as, for example, argan nut shell powder (INCI name Argania spinosa shell powder), walnut shell powder; seed powders such as, for example, coffee bean powder, cocoa bean powder; seed powders such as, for example, kiwi seed powder; as well as mixtures of such powders. Preferably, the composition according to the invention comprises at least two types of powders of different plant materials, for example a kernel powder and a walnut shell powder; better still an apricot kernel powder and an argan nut shell powder. Advantageously, these powders have different particle sizes. Preferably, the composition according to the invention comprises one or more solid particles of average size in number ranging from 300 to 400 μm and one or more solid particles of average size in number greater than 400 μm, more preferably ranging from 410 to 800 μm. Preferably, the composition according to the invention comprises one or more powders of plant materials of average size in number ranging from 300 to 400 μm and one or more powders of plant materials of average size in number greater than 400 μm, more preferably ranging from 410 to 800 μm. Even better, the composition according to the invention comprises one or more kernel powders, in particular apricot kernel powders, of average size in number ranging from 300 to 400 μm and one or more nut shell powders, in particular argan nut shell powders, of average size in number greater than 400 μm, more preferably ranging from 410 to 800 μm. Preferably, the composition comprises said solid particles in a total content ranging from 0.2 to 10% by weight, more preferably from 0.5 to 5% by weight, better from 0.7 to 2% by weight, and even better from 0.8 to 1.5% by weight, relative to the total weight of the composition. Preferably, the composition comprises said powders of plant materials in a total content ranging from 0.2 to 10% by weight, more preferably from 0.5 to 5% by weight, better still from 0.7 to 2% by weight, and even better still from 0.8 to 1.5% by weight, relative to the total weight of the composition. Anionic surfactants The composition according to the present invention further comprises one or more anionic surfactants. Anionic surfactant is understood to mean a surfactant, preferably non-silicone, containing, as ionic or ionizable groups, only anionic groups. In the present description, an entity is described as being “anionic” when it has at least one permanent negative charge or when it can be ionized into a negatively charged entity, under the conditions of use of the composition of the invention (medium, pH for example) and not comprising a cationic charge. Anionic surfactants can be chosen from sulfate, sulfonate and carboxylic (or carboxylate) surfactants. A mixture of these surfactants can of course be used. It is understood in this description that: - carboxylate anionic surfactants comprise at least one carboxylic or carboxylate function (-COOH or -COO7), and do not comprise a sulfate and / or sulfonate function; - the anionic sulfonate surfactants comprise at least one sulfonate function (-SO;H or -SOy), and may optionally also comprise one or more carboxylate functions, but do not comprise a sulfate function; and - anionic sulfate surfactants comprise at least one sulfate function but do not comprise a carboxylate or sulfonate function. The anionic carboxylate surfactants that can be used therefore contain at least one carboxylic or carboxylate function (-COOH or -COO-). The carboxylate anionic surfactants may be chosen from the following compounds: acylglycinates, acyllactylates, acylsarcosinates, acylglutamates; alkyl-D-galactoside-uronic acids, alkyl ether carboxylic acids, alkyl (Cs-Cap aryl) ether carboxylic acids, alkyl amidoether carboxylic acids; as well as the salts of these compounds; and mixtures thereof; the alkyl and / or acyl groups of these compounds containing from 6 to 30 carbon atoms, in particular from 12 to 28, even better from 14 to 24, or even from 16 to 22, carbon atoms carbon; the aryl group preferably designating a phenyl or benzyl group; these compounds may be polyoxyalkylenated, in particular polyoxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units. Also useful are C5-C8 alkyl monoesters of polyglycoside polycarboxylic acids such as C5-C8 alkyl polyglycoside citrates, C1-C12 alkyl polyglycoside tartrates, and C1-C14 alkyl polyglycoside sulfosuccinates and their salts. Preferably, the carboxylate anionic surfactants are chosen from, alone or in a mixture: - acylglutamates, particularly Cs-Cz4, or even C;2-Ca, such as stearoyl-glutamates, and in particular disodium stearoylglutamate; - acylsarcosinates, particularly Cs-C24, or even C,2-Cx, such as palmitoylsarcosinates, and in particular sodium palmitoylsarcosinate; -acyllactylates, particularly C,2-Czs, or even C,4-C24, such as behenoyllactylates, and in particular sodium behenoyllactylate; - Cs-Cz4 acylglycinates, especially C,2-C30; -alkyl(Cs-Cz4)ethercarboxylates, and in particular alkyl(C12-C20)ethercarboxylates; - polyoxyalkylenated alkyl(Cs-Cz4) (amido) ether carboxylic acids, in particular those containing 2 to 50 ethylene oxide groups; in particular in the form of salts of alkali or alkaline earth metals, ammonium, or amino alcohol. Sarcosinate-type surfactants may in particular be chosen from alkyl(C 6-Czp)sarcosinates of the following formula (I): RC(O)-N(CH;)-CH;-C(O)-OX (D with - X denoting a hydrogen atom, an ammonium ion, an ion derived from an alkali or alkaline earth metal or an ion derived from an organic amine, preferably a hydrogen atom, and - R denoting a linear or branched alkyl group, with 5 to 29 carbon atoms. R preferably denotes a linear or branched alkyl group, with 8 to 24 carbon atoms, preferably with 12 to 20 carbon atoms. Among the alkyl(Cs-Cz9)sarcosinates of formula (I) which can be used in the present composition, mention may be made of palmitoylsarcosinates, stearoylsarcosinates, myristoylsarcosinates, lauroylsarcosinates, and cocoylsarcosinates, in acid form or in salified form. The anionic surfactant(s) of sarcosinate type are advantageously chosen among sodium lauroyl sarcosinate, stearoyl sarcosine, myristoyl sarcosine, and mixtures thereof, preferably among stearoyl sarcosine, myristoyl sarcosine, and mixtures thereof. Among the above carboxylic surfactants, mention may also be made of polyoxyalkylenated alkyl(amido)ether carboxylic acids and their salts, in particular those comprising from 2 to 50 alkylene oxide groups, in particular ethylene oxide, such as the compounds offered by the company KAO under the names AKYPO. The polyoxyalkylenated alkyl(amido)ether carboxylic acids that may be used are preferably chosen from those of formula (II): R1-(OC,H,),-OCH,COOA (ID in which: - RI represents a linear or branched C1-C24 alkyl or alkenyl radical, an alkyl(C1-C2)phenyl radical, an R.CONH-CH,-CH, radical; - with R2 denoting a linear or branched C1-C7 alkyl or alkenyl radical; preferably RI is a Cz-Czp, preferably Cz-Cys, alkyl radical, and aryl preferably denotes phenyl, - is an integer or decimal number (average value) ranging from 2 to 24, preferably from 2 to 10, - A denotes H, ammonium, Na, K, Li, Mg or a monoethanolamine or triethanolamine residue. Mixtures of compounds of formula (II) may also be used, in particular mixtures of compounds having different R1 groups. The preferred polyoxyalkylenated alkyl(amido)ether carboxylic acids are those of formula (II) in which: - R1 denotes a C,2-C;4 alkyl radical, Cocoyl, oleyl, nonylphenyl or octylphenyl, - A denotes a hydrogen or sodium atom, and - n varies from 2 to 20, preferably 2 to 10. More preferably still, R1 denotes a C2 alkyl radical, A denotes a hydrogen or sodium atom and n varies from 2 to 10. The anionic sulfonate surfactants that can be used contain at least one sulfonate function (-SO4H or -SO4). The anionic surfactants sullonates may be chosen from the following compounds: alkylsulfonates, alkylamidesulfonates, alkylarylsulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamidesulfosuccinates, alkylsulfoacetates, N-acyltaurates, acylisethionates, alkylsulfolaurates, as well as the salts of these compounds; the alkyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 12 to 28, even better from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; these compounds can be polyoxyalkylenated, in particular polyoxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units. Preferably, the anionic sulfonate surfactants are chosen from, alone or in a mixture: - Cs-C24 alkylsulfosuccinates, especially C;>-C2y, especially laurylsulfosuccinates. - Ce-Cz4 alkyl ether sulfosuccinates, in particular C,2-C»0; - N-acyltaurates in C5-C24, notably in C,>-C2 - (Cs-C»4)acylisethionates, preferably (C,,-C;3) acylisethionates, in particular in the form of salts of alkali or alkaline earth metals, ammonium, or amino alcohol. Preferably, the anionic surfactant(s) of sulfonate type are chosen from Cs-Cz N-acyltaurates, in particular C,2-Cz, and in particular N-acyl N-methyltaurates, Cs-C24 acylisethionates, in particular Cy2-C;s, as well as their salts and their mixtures. More preferably, the anionic surfactant(s) of sulfonate type are chosen from Cs-Cu, in particular C,>-C, acylisethionates, as well as their salts and their mixtures. The anionic sulfate surfactants that can be used contain at least one sulfate function (-OSO-4H or -0S04). The anionic sulfate surfactants can be chosen from the following compounds: alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates; as well as the salts of these compounds; the alkyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 8 to 28, even better from 10 to 24, or even from 12 to 22, carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; these compounds may be (poly)oxyalkylenated, in particular (poly)oxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 1 to 10 ethylene oxide units. Preferably, the anionic sulfate surfactants are chosen from, alone or in a mixture: - alkyl sulfates, particularly Cy0-C24, or even C,2-Cz2, - alkyl ether sulfates, in particular C,0-Cz4, or even C,2-C22, preferably comprising from 1 to 20 ethylene oxide units; in particular in the form of salts of alkali or alkaline earth metals, ammonium, or amino alcohol. When the anionic surfactant is in salt form, said salt may be chosen from alkali metal salts such as the sodium or potassium salt, ammonium salts, amine salts and in particular amino alcohol salts, and alkaline earth metal salts such as the magnesium salt. Examples of amino alcohol salts include mono-, di- and triethanolamine salts, mono-, di- or triisopropanolamine salts, 2-amino 2-methyl 1-propanol, 2-amino 2-methyl 1,3-propanediol and tris(hydroxymethyl)amino methane salts. Preferably, salts of alkali or alkaline earth metals are used, and in particular sodium or magnesium salts. Advantageously, the anionic surfactant(s) are chosen from sulfate anionic surfactants, carboxylate anionic surfactants, and mixtures of these two types of surfactants. Preferably, the composition according to the invention comprises at least one anionic carboxylate surfactant, more preferably chosen from: acylglycinates, acyllactylates, acylsarcosinates, acylglutamates; alkyl-D-galactoside-uronic acids, alkyl ether carboxylic acids, alkyl (C5-Cao aryl) ether carboxylic acids, alkyl amido ether carboxylic acids; as well as the salts of these compounds; and mixtures thereof; the alkyl and / or acyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 12 to 28, even better from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; these compounds may be polyoxyalkylenated, in particular polyoxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 2 to 10 ethylene oxide units. In a particularly preferred manner, the composition comprises at least one anionic carboxylate surfactant chosen from alkyl(C1-C10)ethercarboxylic acids, and in particular alkyl(C1-C10)ethercarboxylic acids. Advantageously, the composition according to the invention comprises at least one anionic sulfate surfactant, preferably chosen from alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, salts of these compounds, and mixtures thereof; the alkyl groups of these compounds preferably comprising from 6 to 30 carbon atoms, in particular from 8 to 28, even better from 10 to 24, or even from 12 to 22, carbon atoms; the aryl group preferably denoting a phenyl or benzyl group; these compounds may be (poly)oxyalkylenated, in particular (poly)oxyethylenated and then preferably comprising from 1 to 50 ethylene oxide units, better still from 1 to 10 ethylene oxide units. More preferably, the anionic surfactant(s) are chosen from: - Cs-C3p alkyl sulfates, better still C;-C,, even better still C,9-C74, or even C,2 - C» - Cs-Cz4, better still Cyo-C24, or even C,2-Cz2 alkyl ether sulfates, preferably comprising from 1 to 20 ethylene oxide units, - the salts of these compounds and their mixtures; in particular in the form of salts of alkali or alkaline earth metals, ammonium, or amino alcohol. More preferably still, the anionic surfactant(s) are chosen from C5-Cz0, better still C1-C4, even better still C10-Cy, or even C12-C7 alkyl sulfates. In a particularly preferred manner, the composition according to the invention comprises at least one carboxylate anionic surfactant and at least one sulfate anionic surfactant as described above. Preferably, the total content of anionic surfactant(s) ranges from 1 to 25% by weight, more preferably from 2 to 20% by weight, more preferably still from 5 to 18% by weight, better still from 10 to 18% by weight, relative to the total weight of the composition. Preferably, the total content of carboxylate anionic surfactant(s) present in the composition ranges from 0.5 to 10% by weight, more preferably from 1 to 5% by weight, relative to the total weight of the composition. More preferably, the total content of anionic carboxylate surfactant(s) chosen from alkyl(Cs-C,4)ethercarboxylic acids, and in particular alkyl(C;>-C;o)ethercarboxylic acids ranges from 0.5 to 10% by weight, more preferably from 1 to 5% by weight, relative to the total weight of the composition. Preferably, the total content of anionic surfactant(s) sulfate(s) present in the composition ranges from 1 to 20% by weight, more preferably from 5 to 18% by weight, better still from 10 to 15% by weight, relative to the total weight of the composition. Preferably, the total content of anionic surfactant(s) sulfate(s) chosen from Cs-Cy alkyl sulfates and Cs-C:4 alkyl ether sulfates ranges from 1 to 20% by weight, more preferably from 5 to 18% by weight, better still from 10 to 15% by weight, relative to the total weight of the composition. Amphoteric surfactants The composition according to the present invention comprises one or more amphoteric or zwitterionic surfactants. In particular, the amphoteric or zwitterionic surfactant(s), preferably non-silicone, used in the composition according to the present invention, may in particular be derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the aliphatic group is a linear or branched chain comprising from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group. In particular, mention may be made of alkyl(C;-Czo)betaines, alkyl(Ca-Cop)sulfobetaines, alkyl(C;-Cp)amidoalkyl(C,-C;)betaines, alkyl(C;-Czo)-amidalky(C;-C4)sulfobetaines, and mixtures thereof. Among the derivatives of secondary or tertiary aliphatic amines, optionally quaternized, which can be used, as defined above, we may also cite the compounds of the following respective structures (III) and (IV): R,-CONHCH,CH.-N''{(R,(R.)-CH,COO-, M+, formula (IID), in which: - R, represents a Cyp to Ca alkyl or alkenyl group derived from an acid R,COOH, preferably present in hydrolyzed coconut oil, preferably R, represents a heptyl, nonyl or undecyl group; - R, represents a beta-hydroxyethyl group; - R. represents a carboxymethyl group; - M* represents a cationic counterion derived from an alkali metal, alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; and - X represents an organic or inorganic anionic counterion, such as that chosen from halides, acetates, phosphates, nitrates, alkyl(C,-C4)sulfates, alkyl(C,-C4)- or alkyl(C,-C,)aryl-sulfonates, in particular methylsulfate and ethylsulfate; or else M* and X- are absent; R, -CONHCH,CH--N(B)(B') IV) formula (IV), in which: - B represents the group -CH,CH,OX; - B' represents the group -(CH),YŸ', with z=l1ou2; - X represents the group -CH,COOHF, -CH,-COOZ”, -CH,CH,COOH, CH2CF - COOZ', or a hydrogen atom; - Y' represents the group -COOH, -COOZ”, -CH,CH(OH)SO3H or the group CH, CH(OH)SO--Z; - Z' represents a cationic counterion derived from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - R, represents a C0 to Czy alkyl or alkenyl group of an acid R,°-COOH preferably present in coconut oil or in hydrolyzed linseed oil, preferably R;' an alkyl group, in particular C,7 and its iso form, an unsaturated C7 group. These compounds are classified in the CTFA dictionary, 5th edition, 1993, under the names disodium cocoamphodiacetate, disodium lauroamphodiacetate, disodium caprylamphodiacetate, disodium capryloamphodiacetate, disodium cocoampho- dipropionate, disodium lauroamphodipropionate, disodium caprylamphodi- propionate, disodium capryloamphodipropionate, lauroamphodi- propionic acid, coccamphodipropionic acid. For example, we can cite cocoamphodiacetate marketed by the company RHODIA under the trade name MIRANOL® C2M concentrate. Compounds of formula (V) can also be used: R,'-NHCH(Y'')-(CH,) CONH(CH,),-N(R,(R.) (V) formula (V), in which: - Y” represents the group -COOH, -COOZ”", -CH,-CH(OH)SO;H or the group CH; CH(OH)SO--Z”; - R; and R,, independently of one another, represent a C, to C4, alkyl or hydroxyalkyl radical; - Z'' represents a cationic counterion derived from an alkali or alkaline earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - R,' represents a Cp to Cp alkyl or alkenyl group of an acid R,°”-COOH preferably present in coconut oil or in hydrolyzed linseed oil; and - net n°, independently of each other, designates an integer ranging from 1 to 3. Among the compounds of formula (V) we can cite the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoaspartamide and marketed by the company CHIMEX under the name CHIMEXANE HB. These compounds can be used alone or in mixtures. Among the amphoteric or zwitterionic surfactants mentioned above, alkyl(C;-C»y)betaines, such as cocobetaine, alkyl(C;-C29)amidoalkyl(C;-C;)betaines, such as cocamidopropylbetaine, alkyl(C;-C» Jamphoacetates, alkyl(C;-C>p)amphodiacetates and mixtures thereof, are advantageously used. More preferably, the amphoteric or zwitterionic surfactant(s) are chosen from alkyl(C;-C»p)betaines, alkyl(C;-C,p)amidoalkyl(C;-C;)betaines and mixtures thereof; even more preferably from cocobetaine, cocamidopropylbetaine, and mixtures thereof. Even better, the amphoteric or zwitterionic surfactant(s) are chosen from alkyl(C;-C )betaines, and in particular coco-betaine. Preferably, the total content of anphoteric or zwitterionic surfactant(s) present in the composition ranges from 0.1 to 15% by weight, more preferably from 0.5 to 10% by weight, even more preferably from 1 to 5% by weight, relative to the total weight of the composition. Preferably, the total content of alkyl(C1-C2)betaine(s) and alkyl(C3-C4) )amidoalkyl(C;-C;)betaine(s) present in the composition ranges from 0.1 to 15% by weight, more preferably from 0.5 to 10% by weight, even more preferably from 1 to 5% by weight, relative to the total weight of the composition. More preferably, the total content of alkyl(Cz-Czo)betaine(s) present in the composition ranges from 0.1 to 15% by weight, more preferably from 0.5 to 10% by weight, even more preferably from 1 to 5% by weight, relative to the total weight of the composition. Advantageously, the total content of anionic surfactant(s) and amphoteric and zwitterionic surfactant(s) present in the composition is greater than or equal to 5% by weight, more preferably greater than or equal to 10% by weight, better still greater than or equal to 15% by weight relative to the total weight of the composition. Preferably, the total content of anionic surfactant(s) and amphoteric and zwitterionic surfactant(s) present in the composition ranges from 5 to 40% by weight, more preferably from 10 to 25% by weight, even more preferably from 15 to 20% by weight, relative to the total weight of the composition. Cross-linked ionic vi The composition according to the invention comprises one or more crosslinked anionic copolymers. The copolymer(s) used in the composition according to the invention are derived from one or more monomers A chosen from vinyl carboxylic acids, one or more monomers B having at least one œ,B-ethylenic unsaturation and one or more crosslinking agents. The monomers A are preferably chosen from acrylic acid, methacrylic acid, itaconic acid, fumaric acid, crotonic acid, maleic acid and mixtures thereof, more preferably from acrylic acid and methacrylic acid, and better still methacrylic acid. The monomers B having at least one α,β-ethylenic unsaturation are chosen from the monomers of formulas: bl) CH;=CXY with X denotes hydrogen and Y denotes a group selected from -COOR, -CsH4R", CN, -CONH,, -NHCOCH,, -CONHC(CH;),, and -CON(CH-),, or X denotes CH; and Y denotes a group selected from -COOR, -C5H4R", -CN or - CH=CH, R denoting a C1-C8 alkyl group or a C1-C2 hydroxyalkyl group, preferably a C1-C3 alkyl group, or a C2-C4 hydroxyalkyl group, R' denoting hydrogen, a C1-C8 alkyl group or a C1-C4 hydroxyalkyl group: b2) CH-=CH(OCOR") with R' denotes a C1-C4 alkyl group, preferably C1-C4. b3) CH,=CH2 or CH =CHCH, Preferably, R denotes a C1-C4 alkyl group or a Ca-Cr hydroxyalkyl group. The monomer B having at least one α,β-ethylenic unsaturation is preferably a monomer of formula bl). Among these monomers B, mention may be made of methyl acrylate, ethyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, styrene, vinyl acetates, acrylamide, N,N-dimethylacrylamide, tert-butylacrylamide, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, 2-ethylhexyl methacrylate, 2-hydroxyethyl methacrylate. The monomer B having at least one œ,B -ethylenic unsaturation is preferably a monomer of formula b1) in which X denotes hydrogen and Y denotes - COOR with R denoting a C;-C; alkyl group, better C,-C, or a C--C; hydroxyalkyl group, better C;-C, More preferably, monomer B is chosen from methyl acrylate, ethyl acrylate and butyl acrylate and more particularly ethyl acrylate. The monomer A is preferably present in amounts ranging from 20 to 80% by weight and more particularly from 25 to 70% by weight and even more particularly from 35 to 60% by weight relative to the total weight of the copolymer. Monomer B is preferably present in amounts ranging from 15 to 80% by weight and more particularly from 25 to 75% by weight and even more particularly from 40 to 65% by weight relative to the total weight of the copolymer. This copolymer is partially or completely crosslinked by at least one conventional crosslinking agent. The crosslinking agents are in particular polyunsaturated compounds, in particular ethylenically polyunsaturated ones. These compounds are in particular polyalkenyl ethers of sucrose or polyols, diallylphthalates, divinylbenzene, allyl (meth)acrylate, ethylene glycol di(meth)acrylate, methylene bis-acrylamide, trimethylol propane tri(meth)acrylate, diallyl itaconate, diallyl fumarate, diallyl maleate, zinc (meth)acrylate, castor oil derivatives or polyols made from unsaturated carboxylic acids. The crosslinking agent may also be chosen from unsaturated monomeric compounds comprising a reactive group capable of reacting with an unsaturation to form a crosslinked copolymer. The content of crosslinking agent generally varies from 0.01 to 5% by weight and preferably from 0.03 to 3% by weight and even more particularly from 0.05 to 1% by weight relative to the total weight of the copolymer. Preferably, the crosslinked anionic copolymer is chosen from crosslinked copolymers of methacrylic acid and C-C alkyl acrylate, crosslinked copolymers of acrylic acid and C1-C3 alkyl acrylate, and more preferably crosslinked copolymers of methacrylic acid and ethyl acrylate. The crosslinked anionic copolymer may be in particular in the form of a dispersion in water. The number-average size of the copolymer particles in the dispersion is generally between 10 and 500 nm and preferably between 20 and 200 nm and more preferably from 50 to 150 nm. These copolymers are described in particular in application WO01 / 76552. More particularly, a crosslinked copolymer of methacrylic acid and ethyl acrylate in the form of a 30% aqueous dispersion manufactured and sold under the name CARBOPOL AQUA SF-1 by the company NOVEON or a crosslinked copolymer of (meth)acrylic acid and C1-C4 alkyl acrylate sold under the name ACULYN 33 by the company ROHM&HAAS may be used. Preferably, the total content of crosslinked anionic copolymer(s) according to the invention ranges from 0.05 to 10% by weight, more preferably from 0.1 to 5% by weight, even more preferably from 0.5 to 3% by weight, and better still from 1 to 2% by weight, relative to the total weight of the composition. Preferably, the total content of copolymers comprising one or more monomers A chosen from acrylic acid and methacrylic acid, one or more monomers of formula b1) as defined above and one or more crosslinking agents ranges from 0.05 to 10% by weight, more preferably from 0.1 to 5% by weight, even more preferably from 0.5 to 3% by weight, and better still from 1 to 2% by weight, relative to the total weight of the composition. Preferably, the total content of copolymers chosen from crosslinked copolymers of methacrylic acid and C1-C2 alkyl acrylate, and crosslinked copolymers of acrylic acid and C1-C2 alkyl acrylate, preferably crosslinked copolymers of methacrylic acid and ethyl acrylate, ranges from 0.05 to 10% by weight, more preferably from 0.1 to 5% by weight, even more preferably from 0.5 to 3% by weight, and better still from 1 to 2% by weight, relative to the total weight of the composition. Non-ionic ioactives The composition according to the present invention may further comprise one or more non-ionic surfactants. For example, non-ionic surfactants can be chosen from: - alcohols, alpha-diols and alkyl(C,-Czp)phenols, these compounds being polyethoxylated and / or polypropoxylated and / or polyglycerolated, the number of ethylene oxide and / or propylene oxide groups being able to range from 1 to 100, and the number of glycerol groups being able to range from 2 to 30; or these compounds comprising at least one fatty chain comprising from 8 to 40 carbon atoms, in particular from 16 to 30 carbon atoms; in particular alcohols comprising at least one C to C alkyl chain, saturated or unsaturated, linear or branched, oxyethylenated comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles of ethylene oxide and comprising one or two fatty chains; - condensates of ethylene oxide and propylene oxide on fatty alcohols; - polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1.5 to 4; - ethoxylated sorbitan fatty acid esters preferably having from 2 to 40 ethylene oxide units; - sucrose fatty acid esters; - polyoxyalkylenated, preferably polyoxyethylenated, fatty acid esters having from 2 to 150 moles of ethylene oxide, including oxyethylenated vegetable oils; - N-(C1-C4 alkyl)glucamine derivatives, - amine oxides such as (C,0-C,4 alkyl)amine oxides or N-(C,0-C,4 acyl)aminopropylmorpholine oxides; - and their mixtures. When present, the total content of the non-ionic surfactant(s) ranges from 0.5 to 25% by weight, more preferably from 1 to 20% by weight, better still from 5 to 15% by weight, relative to the total weight of the composition. Cationic polymers Preferably, the composition according to the present invention further comprises one or more cationic polymers. For the purposes of the present invention, the expression "cationic polymer" designates any non-silicone polymer (not comprising a silicon atom) containing cationic groups and / or groups ionizable into cationic groups, and not containing anionic groups and / or groups ionizable into anionic groups. Cationic polymers are not siliconized (do not include a Si-O unit). Cationic polymers can be associative or non-associative. Preferably, the cationic polymer(s) are chosen from non-associative cationic polymers. The cationic polymers that can be used preferably have a weight-average molar mass (Mw) of between approximately 500 and 5.105, preferably of between approximately 100 and 3.105. Among the cationic polymers, we can cite more particularly: (1) homopolymers or copolymers derived from acrylic or methacrylic esters or amides and comprising at least one of the units of the following formula: Ra E my brother is R where Oo oO A o ç 3 È XX À ; %X ES A E N RoCNt—R, t 4 R, Re R R4 Ba , me CA pee Ge m0 CH Grome ik se Os6 DC NH NH += AA REe— N ee R Ra R, A AN R, F formulas in which: - R3, identical or different, denote a hydrogen atom or a CH3 radical; - A, identical or different, represent a divalent alkyl group, linear or branched, of 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group of 1 to 4 carbon atoms; - Ru, Rs and Rs, identical or different, represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical; preferably an alkyl group having from 1 to 6 carbon atoms; - R, and Ra, identical or different, represent a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms, preferably methyl or ethyl; and - X denotes an anion derived from a mineral or organic acid such as a methosulfate anion or a halide such as chloride or bromide. The copolymers of family (1) may also contain one or more units derived from comonomers which may be chosen from the family of acrylamides, methacrylamides, diacetone acrylamides, acrylamides and methacrylamides substituted on the nitrogen by lower alkyls (C,-Cz), acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters. Among these copolymers of family (1), we can cite: - copolymers of acrylamide and dimethylaminoethyl methacrylate quaternized with dimethyl sulfate or with a dimethyl halide, such as that sold under the name HERCOFLOC by the company HERCULES, - copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride, such as those sold under the name BINA QUAT P 100 by the company CIBA GEIGY, - the copolymer of acrylamide and methacryloyloxyethyltrimethylammonium methosulfate, such as that sold under the name RETEN by the company HERCULES, - vinylpyrrolidone / dialkylaminoalkyl acrylate or methacrylate copolymers, quaternized or not, such as the products sold under the name "GAFQUAT" by the company ISP such as for example "GAFQUAT 734" or "GAFQUAT 755" or the products called "COPOLYMER 845, 958 and 937", These polymers are described in detail in French patents 2,077,143 and 2,393,573, - dimethylaminoethyl methacrylate / vinylcaprolactam / vinylpyrrolidone terpolymers, such as the product sold under the name GAFFIX VC 713 by the company ISP, - vinylpyrrolidone / methacrylamidopropyldimethylamine copolymers, such as those marketed under the name STYLEZE CC 10 by ISP; - vinylpyrrolidone / quaternized dimethylaminopropyl methacrylamide copolymers, such as the product sold under the name "GAFQUAT HS 100" by the company ISP, - polymers, preferably crosslinked, of methacryloyloxyalkyl(C1-C4)trialkyl(C1-C1)ammonium salts such as polymers obtained by homopolymerization of dimethylaminoethylmethacrylate quaternized with methyl chloride, or by copolymerization of acrylamide with dimethylaminoethylmethacrylate quaternized with methyl chloride, the homo- or copolymerization being followed by crosslinking with an olefinically unsaturated compound, in particular methylene bisacrylamide. It is more particularly possible to use a crosslinked acrylamide / methacryloyloxyethyl trimethylammonium chloride copolymer (20 / 80 by weight) in the form of a dispersion comprising 50% by weight of said copolymer in mineral oil. This dispersion is marketed under the name "SALCARE® SC 92" by the company CIBA.It is also possible to use a crosslinked homopolymer of methacryloyloxyethyl trimethylammonium chloride comprising approximately 50% by weight of the homopolymer in mineral oil or in a liquid ester. These dispersions are marketed under the names "SALCARE® SC 95" and "SALCARE® SC 96" by the company CIBA. (2) Cationic polysaccharides, including celluloses and ga- Cationic lactomannans. Among the cationic polysaccharides, mention may be made more particularly of cellulose ether derivatives containing quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer and cationic galactomannan gums. Cellulose ether derivatives containing quaternary ammonium groups are described in particular in FR1492597, and mention may be made of the polymers marketed under the name "UCARE POLYMER JR" (JR 400 LT, JR 125, JR 30M) or "LR" (LR 400, LR 30M) by the company AMERCHOL. These polymers are also defined in the CTFA dictionary as quaternary ammoniums of hydroxyethylcellulose having reacted with an epoxide substituted by a trimethylammonium group, such as for example polyquaternium-10. Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer are described in particular in patent US4131576, and mention may be made of hydroxyalkylcelluloses, such as hydroxymethyl-, hydroxyethyl- or hydroxypropyl celluloses grafted in particular with a salt of methacryloylethyl trimethylammonium, methacrylamidopropyl trimethylammonium, dimethyl-diallylammonium, such as for example polyquaternium-4. The marketed products meeting this definition are more particularly the products sold under the name "Celquat L 200" and "Celquat H 100" by the National Starch Company. Among the cationic cellulose derivatives, it is also possible to use cationic associative celluloses, which can be chosen from quaternized cellulose derivatives, and in particular quaternized celluloses modified by groups comprising at least one fatty chain, such as linear or branched alkyl, linear or branched arylalkyl, linear or branched alkylaryl, preferably linear or branched alkyl, these groups comprising at least 8 carbon atoms, in particular from 8 to 30 carbon atoms, better still from 10 to 24, or even from 10 to 14, carbon atoms; or mixtures thereof. Preferably, mention may be made of quaternized hydroxyethylcelluloses modified by groups comprising at least one fatty chain, such as linear or branched alkyl, linear or branched arylalkyl, linear or branched alkylaryl, preferably linear or branched alkyl, these groups comprising at least 8 carbon atoms, in particular from 8 to 30 carbon atoms, better still from 10 to 24, or even from 10 to 14, carbon atoms; or mixtures thereof. Preferably, we can cite hydroxyethylcelluloses of formula (Ib): OH { da F z R DFE S + HO A has amevrrees 1 db; ed -enpnotg-i-Ehs in which: - R represents an ammonium group RaRbRcN+-, Q' in which Ra, Rb, Rc, identical or different, represent a hydrogen atom or an alkyl, linear or branched, C, to C3o, preferably an alkyl, and Q represents an anionic counterion such as a halide like a chloride or bromide; - R° represents an ammonium group R'aR'bR'eN+-, Q” in which R'a, R°b, R'c, identical or different, represent a hydrogen atom or a linear or branched alkyl, C; to Cao, preferably an alkyl, and Q” represents an anionic counterion such as a halide like a chloride or bromide; it being understood that at least one of the radicals Ra, Rb, Rc, R'a, R'b, R'c represents a linear or branched alkyl, C; to Ca; -n, x and y, identical or different, represent an integer between | and 10,000. Preferably, in formula (Ib), at least one of the radicals Ra, Rb, Rc, R'a, R°b, R°c represents a linear or branched alkyl, C; to C3; better still C;0 to C4, or even C0 to C,4; In particular, mention may be made of the dodecyl radical (C;:). Preferably, the other radical(s) represent a linear or branched alkyl, C, to C4, in particular methyl. Preferably, in formula (Ib), only one of the radicals Ra, Rb, Rc, R'a, R'b, R'c represents a linear or branched alkyl of C; to C3, ; better still of C;9 to C4, or even of C,0 to C4; Mention may in particular be made of the dodecyl radical (C,z). Preferably, the other radicals represent a linear or branched alkyl of C, to C4, in particular methyl. Even better, R may be a group chosen from -N*(CHz)3, Q” and —N*(C;2H2s)(CH3)», Q”, preferably a group —N(CH3)s, Q. Even better still, R' may be a group —-N*(C,2H>s)(CH;)», Q”. Aryl radicals preferably denote phenyl, benzyl, naphthyl or anthryl groups. We can notably cite the polymers with INCI names: - Polyquaternium-24, such as the product QUATRISOFT LM 2008, marketed by the company AMERCHOL / DOW CHEMICAL: - PG-Hydroxyethylcellulose Cocodimonium Chloride, such as the product CRODACEL QME; - PG-Hydroxyethylcellulose Lauryldimonium Chloride (C;2 alkyl), such as the product CRODACEL QL® and - PG-Hydroxyethylcellulose Stearyldimonium Chloride (Cys alkyl) such as the product CRODACEL QS®, marketed by the company CRODA. Mention may also be made of hydroxyethylcelluloses of formula (Ib) in which R represents trimethylammonium halide and R° represents dimethyldodecylammonium halide, preferably R represents trimethylammonium chloride CI,(CH,);N*- and R' represents dimethyldodecylammonium chloride CI,(CH,)(C,2H.s)N+-. This type of polymer is known under the INCI name Polyquaternium-67; as commercial products, mention may be made of SOFTCAT POLYMER SL® polymers such as SL-100, SL-60, SL-30 and SL-5 from the company AMERCHOL / DOW CHEMICAL. More particularly, the polymers of formula (Ib) are, for example, those whose viscosity is inclusively between 2000 and 3000 cPs, preferably between 2700 and 2800 cPs. Typically, SOFTCAT POLYMER SL-S has a viscosity of 2500 cPs, SOFTCAT POLYMER SL-30 has a viscosity of 2700 cPs, SOFITCAT POLYMER SL-60 has a viscosity of 2700 cPs and SOFTCAT POLYMER SL-100 has a viscosity of 2800 cPs. SOFTCAT POLYMER SX-1300X with a viscosity of between 1000 and 2000 cPs can also be used. Cationic galactomannan gums are described more particularly in patents US3589578 and US4031307, and guar gums comprising cationic trialkylammonium groups may be mentioned. For example, guar gums modified with a salt (for example a chloride) of 2,3-epoxypropyltrimethylammonium are used. Such products are marketed in particular under the names JAGUAR C13 S, JAGUAR C 15, JAGUAR C 17 or JAGUAR C162 or JAGUAR EXCEL by the company RHODIA. Such compounds have the INCI names guar hydroxypropyltrimonium chloride or hydroxypropyl guar hydroxypropyltrimonium chloride. (3) polymers consisting of piperazinyl units and divalent alkylene or hydroxyalkylene radicals with linear or branched chains, optionally interrupted by oxygen, sulfur, nitrogen atoms or by aromatic or heterocyclic rings, as well as the oxidation and / or quaternization products of these polymers. (4) water-soluble polyaminoamides, prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides may be crosslinked by an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halide or by an oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis- azetidinium, a bis-haloacyldiamine, an alkyl bis-halide, an epihalohydrin, a diepoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mole per amine group of the polyaminoamide; these polyaminoamides can be alkylated or, if they contain one or more tertiary amine functions, quaternized. (5) polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation by bifunctional agents. Examples that may be mentioned are adipic acid-diacoylaminohydroxyalkyldialoylene triamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes methyl, ethyl, propyl. Among these derivatives, mention may be made more particularly of adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz. (6) polymers obtained by reacting a polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with a dicarboxylic acid chosen from diglycolic acid and saturated aliphatic dicarboxylic acids having from 3 to 8 carbon atoms; the molar ratio between the polyalkylene polyamine and the dicarboxylic acid preferably being between 0.8:1 and 1.4:1; the resulting polyaminoamide being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide preferably between 0.5:1 and 1.8:1. Polymers of this type are in particular marketed under the name "Hercosett 57" by the company Hercules Inc. or under the name "PD 170" or “Delsette 101" by the company Hercules in the case of the adipic acid copolymer / epoxypropyl / / diethylene-triamine. (7) cyclopolymers of alkyl diallyl amine or dialkyl diallyl ammonium such as homopolymers or copolymers comprising as the main constituent of the chain units corresponding to the formulas (VI) or (VID): CH)K CHIK 150 Rd {CHJE —— CRy CIR,2}CH7 <CH,}+ — CR, c RC CH, H,C CH, HG _CH- x st FI; R. sas CCE Res formulas (VI) and (VII), in which: - kett are equal to A or 1, the sum k + t being equal to 1; - R, denotes a hydrogen atom or a methyl radical; - R10 and R11, independently of each other, denote an alkyl group having from 1 to 6 carbon atoms, a hydroxyalkyl group in which the alkyl group has from 1 to 5 carbon atoms, a C1 to C4 amidoalkyl group; or R11 and R12 may denote, together with the nitrogen atom to which they are attached, heterocyclic groups, such as piperidinyl or morpholinyl; R11 and R12, independently of each other, preferably denote an alkyl group having from 1 to 4 carbon atoms; and - Ÿ- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate. Mention may be made more particularly of the homopolymer of salts (for example chloride) of dimethyldiallylammonium, for example sold under the name "MERQUAT 100" by the company NALCO (and their counterparts with low weight-average molar masses) and the copolymers of salts (for example chloride) of diallyldimethylammonium and acrylamide sold in particular under the name "MERQUAT 550" or "MERQUAT 7SPR". (8) quaternary diammonium polymers comprising recurring units of formula: was was (WORM —N+-A,CN—B, - Ru XR,* formula (VIID), in which: = Ris, Ry4, Ry5 and Ry6, which may be identical or different, represent aliphatic, alicyclic or arylaliphatic radicals comprising from 1 to 20 carbon atoms or lower hydroxyalkylaliphatic radicals (preferably C, to Cç), or else R;3, Ris, Rys and Ry6, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles optionally comprising a second heteroatom other than nitrogen or else R;3, R14, Ry5 and Ry5 represent a linear or branched C, to C5 alkyl radical substituted by a nitrile, ester, acyl, amide or -CO-OR 17-D or -CO-NH-R,--D group where Ry, is an alkylene and D a quaternary ammonium group; - A and B represent divalent polymethylene groups comprising from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and which may contain, linked to or intercalated in the main chain, one or more aromatic rings, or one or more oxygen or sulfur atoms or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and - X- denotes an anion derived from a mineral or organic acid; it being understood that A,, R;3 and Rys can form with the two nitrogen atoms to which they are attached a piperazine ring; furthermore if A denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B can also denote a group (CH,),-CO-D-OC-(CH,) .- in which D denotes: a) a glycol residue of formula -OZO-, where Z denotes a linear or branched hydrocarbon radical or a group corresponding to one of the following formulae: -(CH> - CH,-O),-CH;-CH;- and -[CH,-CH(CH;)-O],-CH,-CH(CH)- where x and y denote an integer from 1 to 4, representing a defined and unique degree of polymerization or any number from | to 4 representing an average degree of polymerization; b) a bis-secondary diamine residue such as a piperazine derivative; (c) a bis-primary diamine residue of formula: -NH-Y-NH-, where Y denotes a linear or branched hydrocarbon radical, or the divalent radical -CH,-CH>-SS-CH;-CH--; or d) a ureylene group of formula; -NH-CO-NH-. Preferably, X- is an anion such as chloride or bromide. These polymers have a number average molar mass (Mn) generally between 1000 and 100000. We can cite more particularly polymers which are made up of recurring units corresponding to the formula: R, R —N'COH NEC x 1) XX R* KR formula (IX) in which R;, R2, R3 and R4, identical or different, denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms approximately, n and p are whole numbers varying from 2 to 20 approximately and, X- is an anion derived from a mineral or organic acid. A particularly preferred compound of formula (IX) is that for which R,, R>, R3 and R, represent a methyl radical, n=3, p=6 and X = CI, called Hexadimethrine chloride according to the INCI nomenclature (CTFA). (9) quaternary polyammonium polymers comprising units of formula 0: bi Ras x fre —(CH7,-NH-CO-(CR3, CO -NH (CH, N-+ —TA— Rs Ras æ Mr. formula (X), in which: - Ris, Rio, Racët Ra1, identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, B-hydroxyethyl, B-hydroxypropyl or -CH,CH; (OCH:CH2),OH radical, where p is equal to O or to an integer between 1 and 6, provided that Rys, R19, Rap and Ra; do not simultaneously represent a hydrogen atom, -rets, identical or different, are whole numbers between 1 and 6, - q is equal to 0 or to an entire number between | and 34, - X- denotes an anion such as a halide, and - A denotes a radical of a dihalide or preferably represents -CH,-CH,-O-CH, -CH-. Examples include the products "Mirapol® À 15", "Mirapol® ADI", "Mirapol® AZ 1" and "Mirapol® 175" sold by the company Miranol. (10) Quaternary polymers of vinylpyrrolidone and vinylimidazole such as, for example, the products marketed under the names Luviquat® FC 905, FC 550 and FC 370 by BASF (11) Polyamines such as Polyquart® H sold by COGNIS, referenced under the name “POLYETHYLENEGLYCOL (15) TALLOW POLYAMINE” in the CTFA dictionary. (12) polymers comprising in their structure: (a) one or more patterns corresponding to the following formula (A): —CH—CH— N #4 (A) (b) optionally one or more units corresponding to the following formula (B): —CH:—CHR— tm (B) NH—C—H oO In other words, these polymers can be chosen in particular from homo- or copolymers comprising one or more units derived from vinylamine and possibly one or more units derived from vinylformamide. Preferably, these cationic polymers are chosen from polymers comprising, in their structure, from 5 to 100 mol% of units corresponding to the formula (A) and from 0 to 95 mol% of units corresponding to formula (B), preferably from 10 to 100 mol% of units corresponding to formula (A) and from 0 to 90 mol% of units corresponding to formula (B). These polymers can be obtained, for example, by partial hydrolysis of polyvinylformamide. This hydrolysis can be carried out in an acidic or basic medium. The weight-average molecular mass of said polymer, measured by light diffraction, may preferably vary from 1,000 to 3,000,000 g / mol, more preferably from 10,000 to 1,000,000 and more particularly still from 100,000 to 500,000 g / mol. The cationic charge density of these polymers can preferably vary from 2 meq / g to 20 meg / g, more preferably from 2.5 to 15 and more particularly from 3.5 to 10 med / g. Polymers comprising units of formula (A) and possibly units of formula (B) are sold in particular under the name LUPAMIN by the company BASF, such as, for example, and in a non-limiting manner, the products offered under the names LUPAMIN 9095, LUPAMIN 5095, LUPAMIN 1095, LUPAMIN 9030 (or LUVIQUAT 9030) and LUPAMIN 9010. (13) and their mixtures. Preferably, the cationic polymer(s) are chosen from cationic polysaccharides, in particular associative or non-associative cationic polysaccharides; more preferably non-associative cationic polysaccharides. More preferably, the cationic polymer(s) are chosen from cellulose ether derivatives comprising quaternary ammonium groups, cationic cellulose copolymers, cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, cationic galactomannan gums, and mixtures thereof. More preferably still, the cationic polymer(s) are chosen from cellulose ether derivatives comprising quaternary ammonium groups, and more preferably still the composition according to the invention contains polyquaternium-10. Preferably, when they are present in the composition, the total content of cationic polymer(s) ranges from 0.01 to 10% by weight, more preferably from 0.05 to 5% by weight, more preferably still from 0.1 to 3% by weight, even better still from 0.1 to 1% by weight, relative to the total weight of the composition. Preferably, when they are present in the composition, the total content of cationic polysaccharide(s) ranges from 0.01 to 10% by weight, more preferably from 0.05 to 5% by weight, more preferably still from 0.1 to 3% by weight, even better still from 0.1 to 1% by weight, relative to the total weight of the composition. Preferably, when present in the composition, the total content of cellulose ether derivatives comprising quaternary ammonium groups, preferably polyquaternium-10, ranges from 0.01 to 10% by weight, more preferably from 0.05 to 5% by weight, even more preferably from 0.1 to 3% by weight, even better from 0.2 to 1% by weight, relative to the total weight of the composition. Preferably, the composition according to the invention further comprises at least one inorganic salt, and more preferably sodium chloride. For the purposes of the present application, the inorganic salt(s) are different from the anionic surfactants (i) and the amphoteric or zwitterionic surfactants (ii), the particles, and more particularly from all the ingredients described above. Preferably, the total content of inorganic salt(s) present in the composition according to the invention ranges from 0.01 to 5% by weight, more preferably from 0.05 to 3% by weight, and even more preferably from 0.1 to 2% by weight, relative to the total weight of the composition. Preferably, the composition according to the invention comprises water, that is to say that the medium of the composition is aqueous or hydroalcoholic. More preferably, the total water content of the composition according to the invention is between 20 and 98% by weight, more preferably between 50% and 96% by weight, more preferably still between 60 and 95% by weight, even better between 65 and 90% by weight, relative to the total weight of the composition. The composition according to the invention may further comprise at least one organic solvent. It is understood within the meaning of the invention that the organic solvents are liquid at 25°C and at atmospheric pressure. Examples of organic solvents that may be used include those that are water-soluble, such as C1-C3 alcohols, and especially C1-C7 aliphatic or aromatic monoalcohols, C3-C4 polyols, and C1-C3 polyol ethers, which may be used alone or mixed with water. Advantageously, the organic solvent(s) may be chosen from ethanol, isopropanol, propylene glycol, hexylene glycol, glycerol and mixtures thereof. Preferably, the composition according to the invention comprises at least one C; - C; polyol; more preferably C--C; and even more preferably glycerol. Preferably, when the organic solvent(s) are present in the composition according to the invention, the total content of C"-C; organic solvent(s) is between 0.5 and 10% by weight, more preferably between 1 and 5% by weight, relative to the total weight of the composition. Preferably, when the composition according to the invention comprises water, the pH of the composition is between 3.0 and 9.0, more preferably between 3.5 and 8.0, more preferably between 4.0 and 7.0, even better between 4.5 and 6.5. The pH of the composition according to the invention can be adjusted to the desired value by means of alkalizing agents (such as monoethanolamine) and / or acidifying agents (such as citric acid). The composition according to the invention may optionally also contain one or more additives used in cosmetics, such as perfumes, thickeners other than the polymers previously described, and colorants. These additives may be present in the composition according to the invention in an amount ranging from 0 to 20% by weight relative to the total weight of the composition. A person skilled in the art will take care to choose these possible additives and their quantities so that they do not harm the properties of the compositions of the present invention. The composition according to the invention can advantageously be presented in the form of a shampoo. The viscosity of the composition according to the invention can be determined using a viscometer such as a Rheomat RM100 device from the company Lamy Rheology (measurement at 25°C, 30 seconds, rotation speed 200 rpm, spindle 4). Preferably, the viscosity of the composition ranges from 2000 to 10000 mPa.s, preferably from 4000 to 9500 mPa.s, better still from 5000 to 9000 mPa.s, better still from 5500 to 8500 mPa.s, even better still from 6000 to 8300 mPa.s. The invention also relates to a method for treating, in particular cosmetically, keratin materials, in particular human keratin materials such as hair and scalp, comprising at least one step of applying to said materials a composition as defined above. Preferably, the method according to the invention is a method for washing and / or conditioning human keratin materials, more particularly a method for washing the hair and scalp, comprising at least one step of applying to the keratin materials a composition as defined above, followed by a step of rubbing said materials using the composition. According to a preferred embodiment of the invention, a step of rinsing the keratin fibers is then carried out. A step of drying the keratin fibers may also be provided in the method according to the invention, in particular using a heating means such as a hair dryer, a straightening iron, a steam iron or a heating hood; the heating means being able to heat to a temperature ranging from 35°C to 230°C, preferably from 50°C to 120°C. The invention finally relates to the use of the composition as described above for the treatment of keratin materials, preferably for washing. hair and scalp. The following example serves to illustrate the invention without, however, being limiting. Example Compositions A and B were prepared from the ingredients indicated in the table below, the quantities of which are expressed in % by weight of active ingredient (AI). [Tables 1] [Ingredients a CB Sodium laurcth sulfate 10.8 “|i08 Sodium lauryl sulfate 3.4 3.4 Salicylic acid 1.8 1.8 Coco betaine 1.8 1.8 Laureth-5 carboxylic acid 1.8 1.8 Cocamide MEA la 2 Crosslinked copolymer of methacrylic acid |1,5| and ethyl acrylate (1) Crosslinked homopolymer of acrylic acid |- Juice @) Cocamide MIPA 1.0 1.0 Apricot kernel powder (3) 0.5 0.5 Argan nut shell powder (4) 0.5 0.5 Sodium chloride 04 04 Polyquaternium-10 0.3 0.3 Isopropyl myristate 0.3 0.3 Polyols 2,8 2,8 PEG-55 propylene glycol oleate + + Preservatives, pH agents, perfume qs - qs Water Qsp 100 Qsp 100 1. INCI name Acrylates Copolymer, CARBOPOL AQUA SF-1 marketed by the company NOVEON 2 INCI name Carbomer, CARBOPOL 980 marketed by the company Lubrizol 8 INCI Name Prunus Armeniaca Seed Powder (average diameter in number between 300 and 400 um) 4 INCI name Argania Spinosa Shell Powder (average diameter in number between 410 and 800 um) Composition A is in accordance with the invention, composition B is comparative. Both compositions were prepared by homogeneously mixing the ingredients at room temperature (25°C). The stability of both compositions was then evaluated by placing them for two months in an oven maintained at a temperature of 45°C and in the dark. After one month of storage, the appearance of composition A has not changed; it appears as a visually homogeneous suspension of solid particles in a clear fluid. For composition B, however, the beginning of a phase shift is observed: there are no longer any particles on the surface of the composition, an upper layer of composition devoid of particles has formed and the fluid is cloudy. After two months of storage at 45°C, the appearance of composition A has still not changed: it appears as a visually homogeneous suspension of solid particles in a clear fluid and no phase shift phenomenon is visible. As for composition B, the phase shift has increased, the thickness of the upper layer of composition without particles has increased and the fluid is cloudy. It therefore appears that composition A according to the invention has better stability over time than comparative composition B.

Claims

Claims

1. Cosmetic composition comprising: (1) salicylic acid and / or at least one salicylic acid salt in a total content of at least 1.5% by weight, relative to the total weight of the composition, (ii) solid particles having a number average size su- greater than or equal to 300 um, with a total content of at least 0.2% in weight relative to the total weight of the composition, (iii) at least one anionic surfactant, (iv) at least one amphoteric or zwitterionic surfactant, and (v) at least one crosslinked anionic copolymer of at least one monomer Selected from vinyl carboxylic acids and at least one monomer B having at least one chosen α,β-ethylenic unsaturation among the monomers of the following formulas: bl) CH=CXY with X denoting hydrogen and Y denoting a group chosen from COOR, -C;H4R", -CN, -CONH,, -NHCOCH,, -CONHC(CH;),, and - CON(CH;),, or X denotes CH; and Ÿ denotes a group selected from -COOR, -CsHR", CN or -CH=CH,, R denoting a C,-C alkyl group; or a C hydroxyalkyl group 2-Cz, preferably a C1-C3 alkyl group, or a hy- group C1-C4 droxyalkyl R' denoting hydrogen, a C,-C alkyl group; or a hy- group C;-Cz droxyalkyl. b2) CH-=CH(OCOR!) with R! denotes a C1-C4 alkyl group, preferably C1-C4. b3) CH-=CH;, or CH,=CHCHz.

2. Composition according to the preceding claim, characterized in that that it comprises salicylic acid and / or at least one acid salt salicylic acid in a total content ranging from 1.5% to 8% by weight, preferably 1.8 to 6% by weight, and more preferably 2 to 5% by weight per relative to the total weight of the composition.

3. A composition according to any preceding claim, ca- characterized in that the number average size of the particles is in the range of 300 to 1500 um, preferably 350 at 1000 um, better from 400 to 800 um.

4. A composition according to any preceding claim, ca- characterized in that solid particles are chosen from particles organic and more preferably among the fragments of one or several plants.

5. A composition according to any preceding claim, ca- characterized in that it comprises at least one powder of materials vegetable, preferably chosen from kernel powders such as apricot kernel powder, plum kernel powder, powder olive kernels; nut shell powders such as powder of argan nut shells (INCI name Argania spinosa shell powder), the nut shell powder; seed powders such as coffee beans, cocoa bean powder; seed powders such as than kiwi seed powder; as well as mixtures of these powders; preferably the composition comprises a core powder and a powder of walnut shells; better a powder of kernels apricot and argan nut shell powder.

6. A composition according to any preceding claim, ca- characterized in that it comprises said solid particles in a total content ranging from 0.2 to 10% by weight, preferably from 0.5 to 5% by weight weight, better from 0.7 to 2% by weight, and better still from 0.8 to 1.5% by weight, relative to the total weight of the composition.

7. A composition according to any preceding claim, ca- characterized in that it comprises at least one anionic surfactant car- boxylate, preferably chosen from: acylglycinates, acyl- lactylates, acylsarcosinates, acylglutamates; alkyl- D-galactoside-uronic acids, alkyl ether carboxylic acids, acids alkyl(aryl Cs-Czo)ethercarboxylic acids, alkylamidoethercar- carboxylic; as well as the salts of these compounds; and their mixtures; the alkyl and / or acyl groups of these compounds comprising from 6 to 30 carbon atoms, especially from 12 to 28, even better from 14 to 24, or even from 16 to 22 carbon atoms; the aryl group designating preferably a phenyl or benzyl group; these compounds being able to be polyoxyalkylenated, in particular polyoxye- thylene and then preferably comprising from 1 to 50 oxide units ethylene, better from 2 to 10 ethylene oxide units; and more preferably chosen from alkyl acids (Ce-C24 )ethercarboxylic acids, and better still alkyl acids (C;2-Cz0 )ethercarboxylic acids.

8. A composition according to any preceding claim, ca- characterized in that it comprises at least one anionic surfactant sulfate, preferably chosen from alkyl sulfates, alkyl ether- sulfates, alkylamidoether sulfates, alkylarylpolyether sulfates, monoglyceride sulfates, salts of these compounds, and mixtures thereof; the alkyl groups of these compounds preferably comprising from 6 to 30 carbon atoms, especially from 8 to 28, even better from 10 to 24, or even from 12 to 22 carbon atoms; the aryl group designating preferably a phenyl or benzyl group; these compounds may be (poly)oxyalkylenated, in particular (poly)oxyethylenated and then preferably comprising from 1 to 50 units ethylene oxide, preferably 1 to 10 ethylene oxide units; and more preferably chosen from: - alkyl sulfates in Ce-Cap, Better in Cz-C24, even better in C10-C24, - Cs-Cz24, better C,0-C24, alkyl ether sulfates, comprising preferably from 1 to 20 ethylene oxide units, - the salts of these compounds and their mixtures

9. A composition according to any preceding claim, ca- characterized in that the total content of anionic surfactant(s) ranges from 1 at 25% by weight, preferably from 2 to 20% by weight, more preferably- primarily from 5 to 18% by weight, and better still from 10 to 18% by weight, by relative to the total weight of the composition.

10. A composition according to any preceding claim, ca- characterized in that the amphoteric or zwitterionic surfactants are chosen from alkyl(C;-C-0)betaines, alkyl(C;-C»,)amidoalkyl(C; - Cs)betaines, alkyl(C;-C-,)amphoacetates, alkyl1(C;-Cao J)amphodiacetates and mixtures thereof; preferably among the alkyl1(C;-C 20)betaines, alkyl(Cz-C,0)amidoalkyl(C;-C;)betaines and their mixtures; more preferably still among cocobetaine, coca- midopropyl betaine, and mixtures thereof.

11. A composition according to any preceding claim, ca- characterized in that the total content of amphoteric surfactant(s) or zwillerionic(s) ranges from 0.1 to 15% by weight, preferably from 0.5 to 10% by weight, more preferably from 1 to 5% by weight, relative to the total weight of the composition.

12. A composition according to any preceding claim, ca- characterized in that the crosslinked anionic copolymer is derived from at least a monomer A chosen from acrylic acid, methacrylic acid, itaconic acid, fumaric acid, crotonic acid, maleic acid and mixtures thereof; and at least one monomer B of formula bl).

13. Composition according to any one of the preceding claims, ca- characterized in that the crosslinked anionic copolymer is chosen from crosslinked copolymers of methacrylic acid and alkyl acrylate C,-C, crosslinked copolymers of acrylic acid and alkyl acrylate C,-C,, and preferably crosslinked copolymers of metha- erylic and ethyl acrylate.

14. A composition according to any preceding claim, ca- characterized in that the total content of anionic copolymer(s) crosslinked ranges from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight weight, more preferably from 0.5 to 3% by weight, and better still from 1 to 2% by weight, relative to the total weight of the composition.

15. Process for treating keratin materials, preferably for washing and / or conditioning of keratin materials, including at at least one step of applying a composition to said materials as defined in any one of claims 1 to 14.