High-strength titanium alloys

Abstract

To provide high-strength titanium alloys excellent in workability.SOLUTION: A non-limiting embodiment of a titanium alloy comprises, in weight percentages based on the total alloy weight: 2.0 to 5.0 aluminum; 3.0 to 8.0 tin; 1.0 to 5.0 zirconium; 0 to a total of 16.0 of one or more elements selected from the group consisting of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen and carbon; titanium; and impurities. A non-limiting embodiment of the titanium alloy comprises an intentional addition of tin and zirconium in conjunction with certain other alloying additions such as aluminum, oxygen, vanadium, molybdenum, niobium and iron, to stabilize the α phase and increase the volume fraction of the α phase without the risk of forming embrittling phases, which has been observed as increased room temperature tensile strength with maintained ductility.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present disclosure relates to high strength titanium alloys. [Background technology]

[0002] Titanium alloys typically exhibit high strength-to-weight ratios, are corrosion resistant, and are creep resistant at moderate to high temperatures. For these reasons, titanium alloys are used in aerospace applications, including, for example, landing gear components, engine frames, and other critical structural components. For example, Ti-10V-2Fe-3Al titanium alloy (also referred to as "Ti 10-2-3 alloy" and having a composition designated in UNS 56410) and Ti-5Al-5Mo-5V-3Cr titanium alloy (also referred to as "Ti 5553 alloy"; no UNS number) are commercially available alloys used in landing gear applications and other large components. These alloys exhibit ultimate tensile strengths in the range of 170-180 ksi and are heat treatable in thick sections. However, these alloys tend to have limited ductility at room temperature in the high strength state. This ductility limit is typically due to the fact that Ti 3 This is caused by embrittling phases such as Al, TiAl, or omega phases.

[0003] Also, Ti-10V-2Fe-3Al titanium alloy can be difficult to machine. The alloy must be rapidly cooled, such as by water quenching or air quenching, after solution treatment in order to achieve the desired mechanical properties of the product, which can limit the alloy's use to section thicknesses of less than 3 inches (7.62 cm). Ti-5Al-5Mo-5V-3Cr titanium alloy can be air cooled from the solution temperature and therefore can be used in section thicknesses up to 6 inches (15.24 cm). However, the strength and ductility of this alloy are lower than Ti-10V-2Fe-3Al titanium alloy. Current alloys also exhibit limited ductility, e.g., less than 6%, in the high strength state due to the precipitation of embrittling secondary metastable phases.

[0004] Thus, a need has arisen for titanium alloys that have an ultimate tensile strength greater than about 170 ksi at room temperature while still providing thick section hardenability and / or improved ductility. Summary of the Invention

[0005] According to a non-limiting embodiment of the present disclosure, the titanium alloy comprises, in weight percentages based on the total weight of the alloy: 2.0-5.0 aluminum; 3.0-8.0 tin; 1.0-5.0 zirconium; 0 to a total of 16.0 of one or more elements selected from the group consisting of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon; titanium; and impurities.

[0006] According to another non-limiting embodiment of the present disclosure, the titanium alloy comprises, in weight percentages based on the total weight of the alloy: one or more elements selected from the group consisting of vanadium and niobium from 8.6 to 11.4; tin from 4.6 to 7.4; aluminum from 2.0 to 3.9; molybdenum from 1.0 to 3.0; zirconium from 1.6 to 3.4; chromium from 0 to 0.5; iron from 0 to 0.4; oxygen from 0 to 0.25; nitrogen from 0 to 0.05; carbon from 0 to 0.05; titanium; and impurities.

[0007] According to yet another non-limiting embodiment of the present disclosure, the titanium alloy consists essentially of, in weight percentages based on the total weight of the alloy: 2.0 to 5.0 aluminum; 3.0 to 8.0 tin; 1.0 to 5.0 zirconium; 0 to a total of 16.0 of one or more elements selected from the group consisting of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon; titanium; and impurities.

[0008] The features and advantages of the alloys, articles, and methods described herein can be better understood by reference to the accompanying drawings, in which: [Brief description of the drawings]

[0009] [Figure 1]1 is a plot illustrating a non-limiting embodiment of a method for processing a titanium alloy according to the present disclosure; and [Diagram 2] 1 is a graph plotting the ultimate tensile strength (UTS) and elongation of non-limiting embodiments of titanium alloys according to the present disclosure compared to conventional titanium alloys.

[0010] The reader will understand these details, and others, by considering the following detailed description of certain non-limiting embodiments according to the present disclosure. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0011] In this description of non-limiting embodiments, except in the operating examples or unless otherwise stated, all numbers expressing quantities or properties should be modified in all instances by the term "about". Thus, unless otherwise indicated, any numerical parameters set forth in the following description are approximations that may vary depending on the desired properties sought to be obtained by the materials and methods according to the present disclosure. Rather than attempting to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques, even if only to a minor extent. All ranges set forth herein are inclusive of the recited endpoints unless otherwise stated.

[0012] Any patent, literature, or other disclosure material referred to as being incorporated by reference herein, in whole or in part, is incorporated herein only to the extent that it does not conflict with existing definitions, statements, or other disclosure material described in this disclosure.As such, to the extent necessary, the disclosure as described herein takes precedence over any conflicting material incorporated by reference herein.Any material, or a portion thereof, referred to as being incorporated by reference herein, but which conflicts with existing definitions, statements, or other disclosure material described in this disclosure, is incorporated only to the extent that it does not conflict between the incorporated material and the existing disclosure material.

[0013] As used herein, the term "ductility" or "ductility limit" refers to the limit or maximum amount of reduction or plastic deformation that a metallic material can withstand without rupturing or cracking. This definition is consistent with the meaning given, for example, in the ASM Materials Engineering Dictionary, J.R. Davis, ed., ASM International (1992), p.131.

[0014] References herein to titanium alloys "comprising" a particular composition are intended to encompass alloys "consisting essentially of" or "consisting of" the stated composition. Of course, titanium alloy compositions described herein that "comprise," "consist," or "consist essentially of" a particular composition may also include impurities.

[0015] The present disclosure relates, in part, to alloys that address certain limitations of conventional titanium alloys. One non-limiting embodiment of a titanium alloy according to the present disclosure may comprise or consist essentially of, in weight percentages based on the total weight of the alloy: 2.0-5.0 aluminum; 3.0-8.0 tin; 1.0-5.0 zirconium; 0 to a total of 16.0 of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon. and impurities. Certain embodiments of the titanium alloy may further comprise or consist essentially of, in weight percentages based on the total weight of the alloy: 6.0 to 12.0, and in some embodiments 6.0 to 10.0, of one or more elements selected from the group consisting of vanadium and niobium; 0.1 to 5.0 molybdenum; 0.01 to 0.40 iron; 0.005 to 0.3 oxygen; 0.001 to 0.07 carbon; and 0.001 to 0.03 nitrogen. Another non-limiting embodiment of a titanium alloy according to the present disclosure can comprise or consist essentially of, in weight percentages based on the total weight of the alloy: one or more elements selected from the group consisting of vanadium and niobium from 8.6 to 11.4; tin from 4.6 to 7.4; aluminum from 2.0 to 3.9; molybdenum from 1.0 to 3.0; zirconium from 1.6 to 3.4; chromium from 0 to 0.5; iron from 0 to 0.4; oxygen from 0 to 0.25; nitrogen from 0 to 0.05; carbon from 0 to 0.05; titanium; and impurities.

[0016] In non-limiting embodiments of alloys according to the present disclosure, incidental elements and impurities in the alloy composition may include or consist essentially of one or more of hydrogen, tungsten, tantalum, manganese, nickel, hafnium, gallium, antimony, silicon, sulfur, potassium, and cobalt. Certain non-limiting embodiments of titanium alloys according to the present disclosure may include, in weight percentages based on the total weight of the alloy, 0 to 0.015 hydrogen, and 0 to up to 0.1 each of tungsten, tantalum, manganese, nickel, hafnium, gallium, antimony, silicon, sulfur, potassium, and cobalt.

[0017] In certain non-limiting embodiments of the titanium alloy of the present invention, the titanium alloy has an aluminum equivalent value of 6.0-9.0 and a molybdenum equivalent value of 5.0-10.0, which the inventors have observed to avoid undesirable phases during processing, accelerate precipitation rates, and promote martensitic transformation while improving ductility with ultimate tensile strengths in excess of about 170 ksi at room temperature. As used herein, "aluminum equivalent value" or "aluminum equivalent" (Al eq ) can be determined as follows (where all element concentrations are weight percentages as indicated): Al eq =Al (wt.%) + [(1 / 6) × Zr (wt.%) ]+[(1 / 3)×Sn (wt.%) ]+[10×O (wt.%) As used herein, "molybdenum equivalent value" or "molybdenum equivalent" (Mo eq ) can be determined as follows (where all element concentrations are weight percentages as indicated): Mo eq =Mo (wt.%) + [(1 / 5) × Ta (wt.%) ]+[(1 / 3.6)×Nb (wt.%) ]+[(1 / 2.5)×W (wt.%) ]+[(1 / 1.5)×V (wt.%) ]+[1.25×Cr (wt.%) ]+[1.25×Ni (wt.%) ]+[1.7×Mn (wt.%) ]+[1.7×Co (wt.%) ]+[2.5×Fe (wt.%) ].

[0018] In certain non-limiting embodiments of the titanium alloy of the present invention, the titanium alloy has a relatively low aluminum content, 3 Titanium has two allotropic forms: the beta ("β") phase, which has a body-centered cubic ("bcc") crystal structure; and the alpha ("α") phase, which has a hexagonal close-packed ("hcp") crystal structure. Most α-β titanium alloys contain about 6% aluminum, which dissolves into Ti during heat treatment.3 Al, which may have a detrimental effect on ductility. Accordingly, certain embodiments of titanium alloys according to the present disclosure include about 2.0% to about 5.0% aluminum by weight. In certain other embodiments of titanium alloys according to the present disclosure, the aluminum content is about 2.0% to about 3.4% by weight. In further embodiments, the aluminum content of titanium alloys according to the present disclosure may be about 3.0% to about 3.9% by weight.

[0019] In certain non-limiting embodiments of the titanium alloys of the present invention, the titanium alloys contain intentionally added tin and zirconium in combination with certain other alloying additions, such as aluminum. The aluminum, tin, and zirconium content includes, along with aluminum, oxygen, vanadium, molybdenum, niobium, and iron. Without wishing to be bound by any theory, it is believed that the intentional addition of tin and zirconium stabilizes the alpha phase and increases the volume fraction of the alpha phase without the risk of forming embrittled phases. It has been observed that the intentional addition of tin and zirconium increases room temperature tensile strength while maintaining ductility. The addition of tin and zirconium also provides solid solution strengthening in both the alpha and beta phases. In certain embodiments of titanium alloys according to the present disclosure, the sum of the aluminum, tin, and zirconium content is between 8% and 15% by weight, based on the total alloy weight.

[0020] In certain non-limiting embodiments according to the present disclosure, the titanium alloys disclosed herein include one or more β-stabilizing elements selected from vanadium, molybdenum, niobium, iron, and chromium to slow the precipitation and growth of the α-phase during cooling of the material from the β-phase field and to achieve the desired hardenability in thickness sections. Certain embodiments of titanium alloys according to the present disclosure include from about 6.0% to about 12.0% by weight of one or more elements selected from the group consisting of vanadium and niobium. In further embodiments, the combined vanadium and niobium content in the titanium alloys according to the present disclosure may be from about 8.6% to about 11.4%, from about 8.6% to about 9.4%, or from about 10.6% to about 11.4%, all values ​​being weight percentages based on the total weight of the titanium alloy.

[0021] A first non-limiting titanium alloy according to the present disclosure comprises or consists essentially of, in weight percentages based on the total weight of the alloy: 2.0-5.0 aluminum; 3.0-8.0 tin; 1.0-5.0 zirconium; 0 to a total of 16.0 of one or more elements selected from the group consisting of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon; titanium; and impurities.

[0022] In a first embodiment, aluminum may be included to stabilize and strengthen the alpha phase. In a first embodiment, aluminum may be present in any concentration in the range of 2.0 to 5.0 weight percent based on the total weight of the alloy.

[0023] In a first embodiment, tin may be included to solid solution strengthen the alloy and stabilize the α phase. In a first embodiment, tin can be present in any concentration in the range of 3.0 to 8.0 wt. % based on the total weight of the alloy.

[0024] In a first embodiment, zirconium may be included to solid solution strengthen the alloy and stabilize the alpha phase. In a first embodiment, zirconium may be present in any concentration in the range of 1.0 to 5.0 weight percent based on the total weight of the alloy.

[0025] In a first embodiment, molybdenum, when present, may be included to solid solution strengthen the alloy and stabilize the β phase. In a first embodiment, molybdenum may be present in any of the following concentration ranges by weight based on the total weight of the alloy: 0-5.0; 1.0-5.0; 1.0-3.0; 1.0-2.0; and 2.0-3.0.

[0026] In a first embodiment, iron, when present, may be included to solid solution strengthen the alloy and stabilize the β phase. In a first embodiment, iron may be present in any of the following concentration ranges by weight based on the total weight of the alloy: 0 to 0.4; and 0.01 to 0.4.

[0027] In a first embodiment, chromium, if present, may be included to solid solution strengthen the alloy and stabilize the β phase. In a first embodiment, chromium may be present in any concentration ranging from 0 to 0.5 weight percent based on the total weight of the alloy.

[0028] A second non-limiting titanium alloy according to the present disclosure comprises or consists essentially of, in weight percentages based on the total weight of the alloy: one or more elements selected from the group consisting of vanadium and niobium from 8.6 to 11.4; tin from 4.6 to 7.4; aluminum from 2.0 to 3.9; molybdenum from 1.0 to 3.0; zirconium from 1.6 to 3.4; chromium from 0 to 0.5; iron from 0 to 0.4; oxygen from 0 to 0.25; nitrogen from 0 to 0.05; carbon from 0 to 0.05; titanium; and impurities.

[0029] In a second embodiment, vanadium and / or niobium may be included to solid solution strengthen the alloy and stabilize the β phase. In the second embodiment, the total combined vanadium, niobium and aluminum content can be any concentration in the range of 8.6 to 11.4 weight percent based on the total weight of the alloy.

[0030] Without wishing to be bound by any theory, it is believed that higher aluminum equivalent values ​​may stabilize the alpha phase of the alloys herein, while higher molybdenum equivalent values ​​may stabilize the beta phase. In certain embodiments of titanium alloys according to the present disclosure, the ratio of aluminum equivalent value to molybdenum equivalent value (i.e., the aluminum equivalent value / the molybdenum equivalent value) is between 0.6 and 1.3 to strengthen the alloy, thereby reducing the risk of forming embrittled phases and allowing for good forgeability and the formation of an ultrafine microstructure, which results in good high cycle fatigue properties.

[0031] Typical manufacturing methods for high strength titanium alloys according to the present disclosure are typical of cast and forged titanium and titanium alloys and will be familiar to those skilled in the art. The general process for manufacturing the alloys is shown in FIG. 1 and described below. It should be noted that this description is not intended to limit the manufacturing of the alloys to cast and forged. The alloys according to the present disclosure can also be manufactured, for example, by powder-to-part production methods, which may include consolidation and / or additional manufacturing methods.

[0032] In certain non-limiting embodiments according to the present disclosure, the raw materials to be used in the production of the alloy are prepared. According to certain non-limiting embodiments, the raw materials can include, but are not limited to, titanium sponge or powder, elemental additives, master alloys, titanium dioxide, and recycled materials. The recycled materials, also known as revert materials or scrap, can consist of or include titanium and titanium alloy turnings or chips, small and / or large solids, powders, and other forms of titanium or titanium alloys that have been previously produced and reprocessed for reuse. The shape, size, and form of the raw materials to be used can depend on the method used to melt the alloy. According to certain non-limiting embodiments, the material is in granular form and can be loosely introduced into the melting furnace. According to other embodiments, some or all of the raw materials can be compressed into small or large briquettes. Depending on the requirements or preferences of the particular melting method, the raw materials can be assembled into consumable electrodes for melting or can be fed to the melting furnace as particles. The raw materials processed by the casting and forging process can be melted one or more times into the final ingot product. According to certain non-limiting embodiments, the ingot may be cylindrical, however, in other embodiments, the ingot may take any geometric shape, including, but not limited to, ingots having a square or other cross-section.

[0033] According to certain non-limiting embodiments, melting methods for alloy production via the casting and forging route can include plasma cold hearth (PAM) or electron beam cold hearth (EB) melting, vacuum arc remelting (VAR), electroslag remelting (ESR or ESRR), and / or skull melting. Non-limiting examples of powder production methods include induction melting. / Gas atomization, plasma atomization, plasma rotating electrode, electrode-induced gas atomization, or TiO 2 or TiCl 4 One of the direct reduction techniques is from.

[0034] According to certain non-limiting embodiments, the raw material is melted to form one or more first melting electrode(s). The electrode(s) are prepared and remelted one or more times, typically by VAR, to produce a final melting ingot. For example, the raw material can be plasma arc cold hearth melted (PAM) to form a 26 inch diameter cylindrical electrode. The PAM electrode can then be prepared and subsequently vacuum arc remelted (VAR) to a 30 inch diameter final melting ingot, typically weighing about 20,000 lb. The final melting ingot of the alloy is then converted into the desired product by wrought processing means. The product can be, for example, wire, bar, billet, sheet, plate, and other shaped products. The product can be produced in a final shape using the present alloy, or an intermediate shape that can be further processed by one or more techniques to produce a final element. The one or more techniques can include, for example, wrought, rolling, drawing, extrusion, heat treating, machining, and welding.

[0035] According to certain non-limiting embodiments, the wrought conversion of titanium and titanium alloy ingots typically involves an initial hot forging cycle using an open die press. This stage of the process is designed to allow the ingot to assume an as-cast internal grain structure that is finer in size, which can better exhibit the desired alloy properties. The ingot can be heated to an elevated temperature, for example, above the beta transformation point of the alloy, and held at that temperature for a period of time. The temperature and time are established to allow the alloy to reach the desired temperature throughout, and can be extended for a longer period of time to homogenize the alloy's chemical structure. The alloy can then be forged to a smaller size by a combination of upsetting and / or drawing operations. The material can be subsequently forged and reheated, where the reheating cycle includes, for example, one or more heating steps above and / or below the beta transformation point. Subsequent forging cycles can be performed in an open die press, a rotary forging device, a rolling mill, and / or other similar devices used to transform alloys at elevated temperatures to desired dimensions and shapes. Those skilled in the art will be familiar with the various sequences of forging steps and temperature cycles to obtain the desired alloy size, shape, and internal grain structure. For example, one such processing method is presented in U.S. Patent No. 7,611,592, which is incorporated herein by reference in its entirety.

[0036] Non-limiting embodiments of methods for making titanium alloys according to the present disclosure include final forging in either the α-β or β phase field, followed by heat treatment by quenching, solution treatment and quenching, solution treatment and aging (STA), direct aging, or a combination of thermal cycles to obtain a desired balance of mechanical properties. In certain possible non-limiting embodiments, titanium alloys according to the present disclosure exhibit improved workability at a given temperature compared to other conventional high strength alloys. This feature allows the alloy to be processed by hot working in both the α-β and β phase fields with less cracking or other deleterious effects, thereby improving yields and reducing manufacturing costs.

[0037] As used herein, "solution treatment and aging" or "STA" treatment refers to a heat treatment process applied to a titanium alloy, which includes solution treating the titanium alloy at a solution treatment temperature below the β transformation temperature of the titanium alloy. In a non-limiting embodiment, the solution treatment temperature is at a temperature in the range of about 760°C to 840°C. In other embodiments, the solution treatment temperature varies with the β transformation temperature. For example, the solution treatment temperature can be at a temperature in the range of β transformation temperature -10°C to β transformation temperature -100°C, or β transformation temperature -15°C to β transformation temperature -70°C. In a non-limiting embodiment, the solution treatment time is in the range of about 30 minutes to about 4 hours. In certain non-limiting embodiments, the solution treatment time is in the range of about 30 minutes to about 4 hours. It is recognized that the time period may be less than 10 minutes or more than 4 hours, generally depending on the size and cross-sectional area of ​​the titanium alloy. In certain embodiments according to the present disclosure, the titanium alloy is water quenched to ambient temperature upon completion of the solution treatment. In certain embodiments according to the present disclosure, the titanium alloy is cooled to ambient temperature at a rate dependent on the cross-sectional thickness of the titanium alloy.

[0038] The solution-treated alloy is subsequently aged by heating to an aging temperature for a period of time. The aging temperature, also referred to herein as the "age hardening temperature", is in the α+β two-phase field, below the β transformation temperature of the titanium alloy, and below the solution treatment temperature of the titanium alloy. As used herein, terms such as "heated to" or "heating to", when referring to a temperature, temperature range, or minimum temperature, mean that the alloy is heated until at least a desired portion of the alloy has a temperature that is at least equal to or within the referenced or minimum temperature throughout the range of the portion. In a non-limiting embodiment, the aging temperature is in the range of about 482°C to about 593°C. In certain non-limiting embodiments, the aging time can range from about 30 minutes to about 16 hours. It is recognized that in certain non-limiting embodiments, the aging time may be less than 30 minutes or more than 16 hours, and generally depends on the size and cross-sectional area of ​​the titanium alloy product shape. The general techniques used in solution and aging (STA) processes for titanium alloys are known to those skilled in the art, and therefore will not be further described herein.

[0039] FIG. 2 is a graph depicting a useful combination of ultimate tensile strength (UTS) and ductility exhibited by the alloy when processed using the STA process. As can be seen from FIG. 2, the lower boundary of the plot containing useful combinations of UTS and ductility can be approximated by the linear equation x+7.5y=260.5, where "x" is UTS in ksi and "y" is ductility in % elongation. Data contained in Example 1 presented herein below demonstrates that embodiments of titanium alloys according to the present disclosure provide combinations of UTS and ductility that exceed those achieved with certain prior art alloys. While it is recognized that the mechanical properties of titanium alloys are generally affected by the size of the specimen tested, in a non-limiting embodiment according to the present disclosure, the titanium alloy exhibits a UTS of at least 170 ksi and a ductility according to the following equation (1): (7.5 × elongation (%)) + (UTS (ksi)) ≥ 260.5 (1)

[0040] In certain non-limiting embodiments of the present titanium alloys, the titanium alloys exhibit a UTS of at least 170 ksi and an elongation of at least 6% at room temperature. In other non-limiting embodiments according to the present disclosure, the titanium alloys have an aluminum equivalent value in the range of 6.0-9.0, or in certain embodiments, 7.0-8.0, and a molybdenum equivalent value in the range of 5.0-10.0, or in certain embodiments, 6.0-7.0, and exhibit a UTS of at least 170 ksi and an elongation of at least 6% at room temperature. In yet other non-limiting embodiments, the titanium alloys according to the present disclosure have an aluminum equivalent value in the range of 6.0-9.0, or in certain embodiments, 7.0-8.0, and a molybdenum equivalent value in the range of 5.0-10.0, or in certain embodiments, 6.0-7.0, and exhibit a UTS of at least 180 ksi and an elongation of at least 6% at room temperature.

[0041] The following examples are intended to further illustrate non-limiting embodiments according to the present disclosure without limiting the scope of the invention. Those skilled in the art will recognize that variations of the following examples are possible within the scope of the invention, which is defined only by the claims. EXAMPLES

[0042] Example 1 Table 1 shows the elemental composition, Al, and Fe for certain non-limiting embodiments of titanium alloys according to the present disclosure ("Ti Alloy Example 1" and "Ti Alloy Example 2"), as well as certain conventional titanium alloy embodiments. eq , and Mo eq This is a summary of the above. [Table 1]

[0043] The plasma arc melting (PAM) heat of titanium alloy example 1 and titanium alloy example 2 listed in Table 1 was generated using a plasma arc furnace to produce 9-inch diameter electrodes weighing approximately 400-800 lbs. The electrodes were remelted in a vacuum arc remelting (VAR) furnace. The 10 inch diameter ingots were produced by hot pressing each ingot into a 3 inch diameter billet. After a β forging process to 7 inch diameter, an α+β prestrain forging process to 5 inch diameter, and a β final forging process to 3 inch diameter, the ends of each billet were trimmed off to remove suck-ins and end cracks, and the billets were cut into multiple pieces. The top of each billet and the bottom of the bottommost billet at the 7 inch diameter stage were taken for chemistry and β transformation temperature samples. Based on the intermediate billet chemistry results, 2 inch long samples were cut from the billets and forged into "pancakes" in a press. The pancake specimens were heat treated using the following heat treatment profile: This profile applies to the solution and aging conditions: solution treat the titanium alloy at a temperature of 1400°F (760°C) for two hours; air cool the titanium alloy to ambient temperature; age the titanium alloy at about 482°C to about 593°C for eight hours; and air cool the titanium alloy.

[0044] Test blanks were cut from the STA processed pancake specimens for room and tensile testing and microstructural analysis. Final chemical structure analysis was performed on fracture toughness specimens after testing to ensure that the correlation between chemical structure and mechanical properties was accurate. Testing on the final 3 inch diameter billet revealed a microstructure of fine alpha lath in a beta matrix distributed uniformly throughout the billet from the surface to the center.

[0045] Referring to FIG. 2, the mechanical properties of titanium alloy Example 1 listed in Table 1 (labeled "B5N71" in FIG. 2) and titanium alloy Example 2 listed in Table 1 (labeled "B5N72" in FIG. 2) were measured and compared to conventional Ti 5553 alloy (without UNS number) and Ti10-2-3 alloy (having a composition designated UNS 56410). Tensile testing was performed in accordance with American Society for Testing and Materials (ASTM) standard method E8 / E8M-09 ("Standard Test Methods for Tension Testing of Metallic Materials", ASTM International, 2009). As shown by the experimental results in Table 2, titanium alloy Example 1 and titanium alloy Example 2 exhibited a significantly superior combination of ultimate tensile strength, yield strength, and ductility (reported in % elongation) compared to conventional Ti 5553 and Ti10-2-3 titanium alloys (which had no intentional additions of tin and zirconium). [Table 2]

[0046] There are many potential applications for alloys according to the present disclosure. As explained and demonstrated above, the titanium alloys described herein are advantageously used in a variety of applications where a combination of high strength and ductility is important. Products in which titanium alloys according to the present disclosure may be particularly advantageous include certain aerospace applications, including, for example, landing gear members, engine frames, and other critical structural components. Those skilled in the art will be able to manufacture the above equipment, components, or other products from alloys according to the present disclosure without the need for further explanation herein. The above descriptions of possible applications of alloys according to the present disclosure are provided by way of example only and are not intended to be comprehensive of all applications in which the product forms of the alloys may be applicable. Those skilled in the art will be able to readily identify additional applications for alloys as disclosed herein upon reading this disclosure.

[0047] Various non-exhaustive, non-limiting aspects of the novel alloys according to the present disclosure may be useful alone or in combination with one or more other aspects described herein. Without limiting the above, in a first non-limiting aspect of the present disclosure, the titanium alloy comprises, in weight percentages based on the total weight of the alloy: 2.0-5.0 aluminum; 3.0-8.0 tin; 1.0-5.0 zirconium; 0-16.0 total of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon. one or more selected elements; titanium; and impurities.

[0048] According to a second non-limiting embodiment of the present disclosure that can be used in conjunction with the first embodiment, the titanium alloy includes one or more elements selected from the group consisting of vanadium and niobium, in weight percentages between 6.0 and 12.0 based on the total weight of the alloy.

[0049] According to a third non-limiting embodiment of the present disclosure, which can be used in conjunction with any one or more of the embodiments above, the titanium alloy comprises, by weight percentage based on the total weight of the alloy, 0.1 to 5.0 molybdenum.

[0050] According to a fourth non-limiting embodiment of the present disclosure, which can be used in conjunction with any one or more of the embodiments above, the titanium alloy has an aluminum equivalent value of 6.0 to 9.0.

[0051] According to a fifth non-limiting embodiment of the present disclosure, which can be used in conjunction with any one or more of the embodiments above, the titanium alloy has a molybdenum equivalent value of 5.0 to 10.0.

[0052] According to a sixth non-limiting embodiment of the present disclosure, which can be used in conjunction with any one or more of the embodiments above, the titanium alloy has an aluminum equivalent value of 6.0 to 9.0 and a molybdenum equivalent value of 5.0 to 10.0.

[0053] According to a seventh non-limiting aspect of the present disclosure, which can be used in combination with any one or more of the aspects above, the titanium alloy comprises, in weight percentages based on the total weight of the alloy: 6.0 to 12.0, or in some embodiments 6.0 to 10.0, of one or more elements selected from the group consisting of vanadium and niobium; 0.1 to 5.0 molybdenum; 0.01 to 0.40 iron; 0.005 to 0.3 oxygen; 0.001 to 0.07 carbon; and 0.001 to 0.03 nitrogen.

[0054] According to an eighth non-limiting embodiment of the present disclosure, which may be used in conjunction with any one or more of the above embodiments, the sum of the aluminum, tin, and zirconium contents is 8 to 15, in weight percentages based on the total weight of the alloy.

[0055] According to a ninth non-limiting embodiment of the present disclosure, which can be used in conjunction with any one or more of the embodiments above, the ratio of the aluminum equivalent value to the molybdenum equivalent value is 0.6 to 1.3.

[0056] According to a tenth non-limiting embodiment of the present disclosure, a method of making a titanium alloy includes: solution treating the titanium alloy at 760°C-840°C for 1-4 hours; air cooling the titanium alloy to ambient temperature; aging the titanium alloy at 482°C-593°C for 8-16 hours; and air cooling the titanium alloy, wherein the titanium alloy has a composition as set forth in any one or more of the embodiments above.

[0057] According to an eleventh non-limiting embodiment of the present disclosure, which can be used in combination with any one or more of the embodiments above, the titanium alloy exhibits an ultimate tensile strength (UTS) of at least 170 ksi at room temperature, and the ultimate tensile strength and elongation of the titanium alloy satisfy the following equation: (7.5×elongation (%))+UTS≧260.5.

[0058] In accordance with a twelfth non-limiting aspect of the present disclosure, the present disclosure also provides a titanium alloy comprising, in weight percentages based on the total weight of the alloy: one or more elements selected from the group consisting of vanadium and niobium from 8.6 to 11.4; tin from 4.6 to 7.4; aluminum from 2.0 to 3.9; molybdenum from 1.0 to 3.0; zirconium from 1.6 to 3.4; chromium from 0 to 0.5; iron from 0 to 0.4; oxygen from 0 to 0.25; and nitrogen from 0 to 0.05. ;0~0.05 Carbon; Titanium; and impurities.

[0059] According to a thirteenth non-limiting embodiment of the present disclosure that can be used in conjunction with any one or more of the above embodiments, the titanium alloy comprises one or more elements selected from the group consisting of vanadium and niobium, in weight percentages between 8.6 and 9.4 based on the total weight of the alloy.

[0060] According to a fourteenth non-limiting embodiment of the present disclosure that can be used in conjunction with any one or more of the above embodiments, the titanium alloy comprises one or more elements selected from the group consisting of vanadium and niobium, in weight percentages between 10.6 and 11.4 based on the total weight of the alloy.

[0061] According to a fifteenth non-limiting embodiment of the present disclosure that can be used in combination with any one or more of the embodiments above, the titanium alloy further comprises 2.0 to 3.0 molybdenum, by weight percentage based on the total weight of the alloy.

[0062] According to a sixteenth non-limiting embodiment of the present disclosure that can be used in conjunction with any one or more of the embodiments above, the titanium alloy includes, by weight percentage based on the total weight of the alloy, 1.0 to 2.0 molybdenum.

[0063] According to a seventeenth non-limiting embodiment of the present disclosure that can be used with any one or more of the embodiments above, the titanium alloy has an aluminum equivalent value of 7.0 to 8.0.

[0064] According to an eighteenth non-limiting embodiment of the present disclosure that can be used with any one or more of the embodiments above, the titanium alloy has a molybdenum equivalent value of 6.0 to 7.0.

[0065] According to a nineteenth non-limiting embodiment of the present disclosure, which can be used in conjunction with any one or more of the embodiments above, the titanium alloy has an aluminum equivalent value of 7.0 to 8.0 and a molybdenum equivalent value of 6.0 to 7.0.

[0066] According to a twentieth non-limiting embodiment of the present disclosure, which can be used in combination with any one or more of the embodiments above, the titanium alloy includes, in weight percentages based on the total weight of the alloy, the following: one or more elements selected from the group consisting of vanadium and niobium from 8.6 to 9.4; tin from 4.6 to 5.4; aluminum from 3.0 to 3.9; molybdenum from 2.0 to 3.0; and zirconium from 2.6 to 3.4.

[0067] According to a twenty-first non-limiting embodiment of the present disclosure, which can be used in combination with any one or more of the embodiments above, the titanium alloy includes, in weight percentages based on the total weight of the alloy, the following: one or more elements selected from the group consisting of vanadium and niobium from 10.6 to 11.4; tin from 6.6 to 7.4; aluminum from 2.0 to 3.4; molybdenum from 1.0 to 2.0; and zirconium from 1.6 to 2.4.

[0068] According to a twenty-second non-limiting embodiment of the present disclosure, a method of making a titanium alloy includes: solution treating the titanium alloy at 760°C-840°C for 2-4 hours; air cooling the titanium alloy to ambient temperature; aging the titanium alloy at 482°C-593°C for 8-16 hours; and air cooling the titanium alloy, wherein the titanium alloy has a composition as set forth in any one or more of the embodiments above.

[0069] According to a twenty-third non-limiting embodiment of the present disclosure that may be used in conjunction with any one or more of the embodiments above, the titanium alloy has an ultimate tensile strength (UTS) of at least 170 ksi at room temperature. and the ultimate tensile strength and elongation of the titanium alloy satisfy the following equation: (7.5×elongation(%))+UTS≧260.5.

[0070] According to a twenty-fourth non-limiting aspect of the present disclosure, the present disclosure also provides a titanium alloy consisting essentially of, in weight percentages based on the total weight of the alloy: 2.0 to 5.0 aluminum; 3.0 to 8.0 tin; 1.0 to 5.0 zirconium; 0 to a total of 16.0 of one or more elements selected from the group consisting of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon; titanium; and impurities.

[0071] According to a twenty-fifth non-limiting embodiment of the present disclosure, which can be used in conjunction with any one or more of the embodiments above, the total vanadium and niobium content in the alloy is, in weight percentage based on the total weight of the alloy, from 6.0 to 12, or from 6.0 to 10.0.

[0072] According to a twenty-sixth non-limiting embodiment of the present disclosure, which can be used in combination with any one or more of the embodiments above, the molybdenum content in the alloy is, in weight percentage based on the total weight of the alloy, 0.1 to 5.0.

[0073] According to a twenty-seventh non-limiting embodiment of the present disclosure that can be used in conjunction with any one or more of the embodiments above, the titanium alloy has an aluminum equivalent value of 6.0 to 9.0.

[0074] According to a twenty-eighth non-limiting embodiment of the present disclosure that can be used in conjunction with any one or more of the embodiments above, the molybdenum equivalent value of the titanium alloy is 5.0 to 10.0.

[0075] According to a twenty-ninth non-limiting embodiment of the present disclosure that can be used in combination with any one or more of the embodiments above, the aluminum equivalent value of the titanium alloy is 6.0 to 9.0, and the molybdenum equivalent value of the titanium alloy is 5.0 to 10.0.

[0076] According to a 30th non-limiting embodiment of the present disclosure, which can be used in combination with any one or more of the embodiments above, in the titanium alloy: the sum of the vanadium and niobium content is 6.0 to 12.0, or 6.0 to 10.0; the molybdenum content is 0.1 to 5.0; the iron content is 0.01 to 0.30; the oxygen content is 0.005 to 0.3; the carbon content is 0.001 to 0.07; and the nitrogen content is 0.001 to 0.03, all in weight percentages based on the total weight of the titanium alloy.

[0077] According to a thirty-first non-limiting embodiment of the present disclosure, which can be used in combination with any one or more of the embodiments above, the sum of the aluminum, tin, and zirconium contents is 8 to 15, in weight percentages based on the total weight of the alloy.

[0078] According to a thirty-second non-limiting embodiment of the present disclosure that can be used with any one or more of the embodiments above, the ratio of aluminum equivalent value to molybdenum equivalent value of the titanium alloy is 0.6 to 1.3.

[0079] According to a thirty-third non-limiting embodiment of the present disclosure, a method of making a titanium alloy includes: solution treating the titanium alloy at 760°C-840°C for 2-4 hours; air cooling the titanium alloy to ambient temperature; aging the titanium alloy at 482°C-593°C for 8-16 hours; and air cooling the titanium alloy, wherein the titanium alloy has a composition as set forth in any one or more of the embodiments above.

[0080] According to a thirty-fourth, non-limiting embodiment of the present disclosure that may be used in conjunction with any one or more of the embodiments above, the titanium alloy has an ultimate tensile strength (UTS) of at least 170 ksi at room temperature. and the ultimate tensile strength and elongation of the titanium alloy satisfy the following equation: (7.5×elongation(%))+UTS≧260.5.

[0081] According to a thirty-fifth non-limiting embodiment of the present disclosure, a method of making a titanium alloy includes: solution treating the titanium alloy at a temperature range of the alloy's β transformation temperature −10° C. to the β transformation temperature −100° C. for 2 to 4 hours; air cooling or blast cooling the titanium alloy to ambient temperature; aging the titanium alloy at 482° C. to 593° C. for 8 to 16 hours; and air cooling the titanium alloy, wherein the titanium alloy has a composition as set forth in any one or more of the embodiments above.

[0082] It is understood that the present description illustrates these aspects of the invention in the context of a clear understanding of the invention. Certain aspects that would be obvious to one skilled in the art and would therefore not facilitate a better understanding of the invention have not been presented for the purposes of brevity of the description. Although only a limited number of embodiments of the invention need be described herein, those skilled in the art will appreciate upon reviewing the above description that the invention is susceptible to many modifications and variations. All such modifications and variations of the invention are intended to be encompassed within the scope of the above description and the following claims.

[0083] [Mode of the invention] [1] Titanium alloys having the following weight percentages based on the total weight of the alloy: 2.0~5.0 Aluminum; 3.0-8.0 tin; Zirconium 1.0-5.0; one or more elements selected from the group consisting of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon, ranging from 0 to a total of 16.0; Titanium; and impurities The titanium alloy comprising: [2] The following, as percentages by weight based on the total weight of the alloy: 6.0 to 12.0, one or more elements selected from the group consisting of vanadium and niobium 2. The titanium alloy of claim 1, [3] The following, as percentages by weight based on the total weight of the alloy: 0.1~5.0 Molybdenum 2. The titanium alloy of claim 1, [4] 2. The titanium alloy according to claim 1, wherein the titanium alloy has an aluminum equivalent value of 6.0 to 9.0. [5] 2. The titanium alloy according to claim 1, wherein the titanium alloy has a molybdenum equivalent value of 5.0 to 10.0. [6] 2. The titanium alloy according to claim 1, wherein the titanium alloy has an aluminum equivalent value of 6.0 to 9.0 and a molybdenum equivalent value of 5.0 to 10.0. [7] The titanium alloy comprises, by weight percentage based on the total weight of the alloy, the following: 6.0 to 12.0, one or more selected from the group consisting of vanadium and niobium element; Molybdenum from 0.1 to 5.0; Iron from 0.01 to 0.40; Oxygen from 0.005 to 0.3; 0.001 to 0.07 carbon; and 0.001 to 0.03 Nitrogen 7. The titanium alloy of claim 6, [8] 8. The titanium alloy of claim 7, wherein the sum of the aluminum, tin, and zirconium contents is 8 to 15, expressed as weight percentages based on the total weight of the alloy. [9] 8. The titanium alloy according to claim 7, wherein the ratio of the aluminum equivalent value to the molybdenum equivalent value is 0.6 to 1.3.

[10] 1. A method for producing a titanium alloy, comprising: The titanium alloy is solution-treated at 760°C to 840°C for 1 to 4 hours; air cooling the titanium alloy to ambient temperature; Aging the titanium alloy at 482°C to 593°C for 8 to 16 hours; and cooling the titanium alloy in air; 1, wherein the titanium alloy has the composition described in 1. The above-mentioned production method.

[11] The titanium alloy exhibits an ultimate tensile strength (UTS) of at least 170 ksi at room temperature, and the ultimate tensile strength and elongation of the titanium alloy are determined according to the following equations: (7.5 x elongation (%)) + UTS ≥ 260.5 1. A titanium alloy as described in 1, which satisfies the above.

[12] Titanium alloys having the following weight percentages based on the total weight of the alloy: 8.6 to 11.4, one or more elements selected from the group consisting of vanadium and niobium; 4.6-7.4 tin; 2.0~3.9 Aluminum; Molybdenum 1.0-3.0; Zirconium 1.6-3.4; 0-0.5 Cr; Iron from 0 to 0.4; 0-0.25 oxygen; Nitrogen from 0 to 0.05; 0-0.05 carbon; Titanium; and impurities The titanium alloy.

[13] The following, as percentages by weight based on the total weight of the alloy: One or more elements selected from the group consisting of vanadium and niobium, 8.6 to 9.4 13. The titanium alloy of claim 12, comprising:

[14] The following, as percentages by weight based on the total weight of the alloy: 10.6 to 11.4, one or more selected from the group consisting of vanadium and niobium Elements 13. The titanium alloy of claim 12, comprising:

[15] The following, as percentages by weight based on the total weight of the alloy: 2.0~3.0 Molybdenum 13. The titanium alloy of claim 12, comprising:

[16] The following, as percentages by weight based on the total weight of the alloy: 1.0~2.0 Molybdenum 13. The titanium alloy of claim 12, comprising:

[17] 13. The titanium alloy according to claim 12, wherein the titanium alloy has an aluminum equivalent value of 7.0 to 8.0.

[18] 13. The titanium alloy according to claim 12, wherein the titanium alloy has a molybdenum equivalent value of 6.0 to 7.0.

[19] 13. The titanium alloy according to claim 12, wherein the titanium alloy has an aluminum equivalent value of 7.0 to 8.0 and a molybdenum equivalent value of 6.0 to 7.0.

[20] The titanium alloy comprises, by weight percentage based on the total weight of the alloy, the following: 8.6 to 9.4, one or more elements selected from the group consisting of vanadium and niobium; 4.6-5.4 tin; 3.0~3.9 Aluminum; 2.0 to 3.0 molybdenum; and Zirconium 2.6~3.4 20. The titanium alloy of claim 19, comprising: [twenty one] The titanium alloy comprises, by weight percentage based on the total weight of the alloy, the following: 10.6 to 11.4, one or more elements selected from the group consisting of vanadium and niobium; 6.6-7.4 tin; 2.0~3.4 aluminum; 1.0 to 2.0 molybdenum; and Zirconium 1.6~2.4 20. The titanium alloy of claim 19, comprising: [twenty two] 1. A method for producing a titanium alloy, comprising: The titanium alloy is solution-treated at 760°C to 840°C for 2 to 4 hours; air cooling the titanium alloy to ambient temperature; Aging the titanium alloy at 482°C to 593°C for 8 to 16 hours; and cooling the titanium alloy in air; 12, wherein the titanium alloy has a composition as set forth in claim 12. The above-mentioned production method. [twenty three] The titanium alloy exhibits an ultimate tensile strength (UTS) of at least 170 ksi at room temperature, and the ultimate tensile strength and elongation of the titanium alloy are determined according to the following equations: (7.5 x elongation (%)) + UTS ≥ 260.5 13. The titanium alloy according to claim 12, [twenty four] Titanium alloys having the following weight percentages based on the total weight of the alloy: 2.0~5.0 Aluminum; 3.0-8.0 tin; Zirconium 1.0-5.0; one or more elements selected from the group consisting of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon, ranging from 0 to a total of 16.0; Titanium; and impurities The titanium alloy consisting essentially of. [twenty five] 25. The titanium alloy of claim 24, wherein the sum of the vanadium and niobium contents in the alloy is 6.0 to 12.0, expressed as a weight percentage based on the total weight of the alloy.

[26] 25. The titanium alloy according to claim 24, wherein the molybdenum content in the alloy is, in weight percentage based on the total weight of the alloy, 0.1-5.0.

[27] 25. The titanium alloy according to claim 24, wherein the aluminum equivalent value of the titanium alloy is 6.0 to 9.0.

[28] 25. The titanium alloy according to 24, wherein the molybdenum equivalent value of the titanium alloy is 5.0 to 10.0.

[29] 25. The titanium alloy according to claim 24, wherein the aluminum equivalent value of the titanium alloy is 6.0 to 9.0, and the molybdenum equivalent value of the titanium alloy is 5.0 to 10.0.

[30] In the titanium alloy: The sum of the vanadium and niobium contents is 6.0 to 12.0; The molybdenum content is 0.1-5.0; The iron content is 0.01-0.30; The oxygen content is 0.005 to 0.3; The carbon content is 0.001 to 0.07; and The nitrogen content is 0.001 to 0.03; All of these are weight percentages based on the total weight of the titanium alloy. 29. A titanium alloy as described in 29.

[31] 31. The titanium alloy of claim 30, wherein the sum of the aluminum, tin, and zirconium contents is 8 to 15, in weight percentages based on the total weight of the alloy.

[32] 31. The titanium alloy according to claim 30, wherein the ratio of the aluminum equivalent value to the molybdenum equivalent value of the titanium alloy is 0.6 to 1.3.

[33] 1. A method for producing a titanium alloy, comprising: The titanium alloy is solution-treated at 760°C to 840°C for 2 to 4 hours; air cooling the titanium alloy to ambient temperature; Aging the titanium alloy at 482°C to 593°C for 8 to 16 hours; and cooling the titanium alloy in air; 24, wherein the titanium alloy has a composition as set forth in The above-mentioned production method.

[34] The titanium alloy exhibits an ultimate tensile strength (UTS) of at least 170 ksi at room temperature, and the ultimate tensile strength and elongation of the titanium alloy are determined according to the following equations: (7.5 x elongation (%)) + UTS ≥ 260.5 25. A titanium alloy as described in 24, which satisfies the above.

[35] 1. A method for producing a titanium alloy, comprising: The titanium alloy is solution-treated at a temperature range of β transformation point -10℃ to β transformation point -100℃ for 2 to 4 hours; air or blast cooling the titanium alloy to ambient temperature; Aging the titanium alloy at 482°C to 593°C for 8 to 16 hours; and cooling the titanium alloy in air; 24, wherein the titanium alloy has a composition as set forth in The above-mentioned production method.

Claims

1. 1. A titanium alloy comprising, in weight percentages based on the total weight of the alloy: Vanadium from 6.0 to 12.0; 3.0 to 8.0 tin; Aluminum from 2.0 to 5.0; Zirconium 1.0 to 5.0 1.0 to 5.0 molybdenum; 0-0.25 oxygen; iron from 0 to 0.40; 0-0.50 chromium; 0-0.05 carbon; Nitrogen from 0 to 0.05; Optionally, one or more of niobium and copper Titanium; and impurities Titanium alloy.

2. The following, as weight percentages based on the total weight of the alloy: Vanadium 8.6-11.4; 4.6-7.4 tin; Aluminum from 2.0 to 3.9; Zirconium 1.6 to 3.4 1.0 to 3.0 molybdenum; 0.005 to 0.25 oxygen; iron from 0 to 0.40; 0-0.50 chromium; 0-0.05 carbon; Nitrogen from 0 to 0.05; Optionally, one or more of niobium and copper Titanium; and impurities 2. The titanium alloy of claim 1, consisting essentially of

3. 2. The titanium alloy of claim 1, wherein the total amount of vanadium and niobium in the titanium alloy is 6.0 to 12.0 weight percent.

4. 2. The titanium alloy of claim 1, wherein the total amount of vanadium and niobium in the titanium alloy is 6.0 to 10.0 weight percent.

5. 2. The titanium alloy of claim 1, wherein the total amount of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon in said titanium alloy is less than or equal to 16.0 wt.%.

6. 2. The titanium alloy of claim 1, wherein the total amount of aluminum, tin, and zirconium in the titanium alloy is 8 to 15 wt.%.

7. 10. The titanium alloy of claim 1, wherein the titanium alloy has an aluminum equivalent value of 6.0 to 9.0 and a molybdenum equivalent value of 5.0 to 10.

0.

8. 8. The titanium alloy of claim 7, wherein the ratio of said aluminum equivalent value to said molybdenum equivalent value is 0.6 to 1.

3.

9. 1. A titanium alloy comprising, in weight percentages based on the total weight of the alloy: Vanadium 8.6-11.4; 4.6-7.4 tin; 2.0-3.9 aluminum; Zirconium from 1.6 to 3.4; 1.0 to 3.0 molybdenum; Oxygen from 0.005 to 0.30; Titanium; and impurities Titanium alloys, including:

10. 10. The titanium alloy of claim 9 comprising, by weight percentage based on the total weight of the alloy, 8.6 to 9.4 vanadium.

11. 10. The titanium alloy of claim 9 comprising tin in a weight percentage of from 4.6 to 7.0 based on the total weight of the alloy.

12. 10. The titanium alloy of claim 9, comprising 3.0 to 3.9 weight percentages of aluminum based on the total weight of the alloy.

13. 10. The titanium alloy of claim 9, comprising 2.0 to 3.4 weight percentages of zirconium based on the total weight of the alloy.

14. 10. The titanium alloy of claim 9 comprising 2.0 to 3.0 weight percentages of molybdenum based on the total weight of the alloy.

15. 10. The titanium alloy of claim 9, comprising 0.005 to 0.25 weight percent oxygen based on the total weight of the alloy.

16. 10. The titanium alloy of claim 9, exhibiting an ultimate tensile strength of at least 170 ksi and an elongation of at least 6% at room temperature.

17. 10. The titanium alloy of claim 9, exhibiting an ultimate tensile strength of at least 180 ksi and an elongation of at least 6% at room temperature.

18. 1. A titanium alloy comprising, in weight percentages based on the total weight of the alloy: Vanadium 8.6-9.4; 4.6-7.0 tin; 3.0-3.9 aluminum; Zirconium from 2.0 to 3.4; 2.0 to 3.0 molybdenum; 0.005 to 0.25 oxygen; 0-0.05 carbon; Nitrogen from 0 to 0.05; iron from 0 to 0.40; 0-0.50 chromium; Optionally, one or more of niobium and copper Titanium; and impurities Titanium alloy.

19. 19. The titanium alloy of claim 18, wherein the combined amount of vanadium and niobium in the titanium alloy is 8.6 to 11.4 weight percent.

20. 20. The titanium alloy of claim 18, wherein the total amount of oxygen, vanadium, molybdenum, niobium, chromium, iron, copper, nitrogen, and carbon in the titanium alloy is less than or equal to 16.0 wt.%.

Images