Pouch containing a film having a layered structure and method for manufacturing the same
Patent Information
- Application Number
- JP2026022175
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2025-07-24
- Filing Date
- 2026-02-13
- Publication Date
- 2026-09-01
Smart Images

Figure 2026139599000001_ABST
Abstract
Description
[Technical Field]
[0001] The present invention relates to a container for holding products such as liquid foods. The present invention also relates to a method for manufacturing a film, the film of which can be used to manufacture a container for holding products. Furthermore, the present invention relates to a method for manufacturing a container for holding products. Furthermore, the present invention relates to the use of a film for manufacturing a container for holding products, and to the use of a container for holding products such as liquid foods. [Background technology]
[0002] Containers for holding products such as liquid foods are well known in the art. An example of such a container is a pouch (e.g., a spouted pouch), often also called a stand-up pouch. Examples of such pouches are disclosed in Patent Documents 1 and 2, and Patent Document 3 discloses a laminate that can be used to manufacture pouches. Conventional containers have several limitations, including insufficient puncture resistance, impact resistance upon dropping, and gas barrier properties. These containers are generally difficult to recycle. [Prior art documents] [Patent Documents]
[0003] [Patent Document 1] U.S. Patent Application No. 2019 / 0224952 [Patent Document 2] U.S. Patent Application No. 2011 / 0252745 [Patent Document 3] U.S. Patent Application No. 2020 / 0122439 [Overview of the Initiative] [Problems that the invention aims to solve]
[0004] The object of the present invention is to overcome at least one of the drawbacks encountered in the prior art, at least partially.
[0005] A further object of the present invention is to provide a container for holding liquid products, preferably liquid foods and the like.
[0006] A further object of the present invention is to provide a container for containing a product that has improved puncture resistance.
[0007] A further object of the present invention is to provide a container for containing a product that has improved resistance to damage when dropped, and more preferably a container that has improved resistance to damage when at least partially filled.
[0008] A further object of the present invention is to provide a container for housing a product, which has improved heat damage resistance.
[0009] A further object of the present invention is to provide a container for containing a product that can be sealed at a lower temperature.
[0010] A further object of the present invention is to provide a container for containing a product that has greater rigidity.
[0011] A further object of the present invention is to provide a container for containing a product, which has improved gas barrier properties.
[0012] A further object of the present invention is to provide a container for holding products that is more easily recyclable.
[0013] A further object of the present invention is to provide a film that can be used to manufacture containers for holding liquid products, preferably liquid foods and the like.
[0014] A further object of the present invention is to provide a film with improved puncture resistance.
[0015] A further object of the present invention is to provide a film with improved strength.
[0016] A further object of the present invention is to provide a film having an outer layer with improved heat damage resistance.
[0017] A further object of the present invention is to provide a film having an outer layer that can be sealed at a lower temperature.
[0018] A further object of the present invention is to provide a film with higher rigidity.
[0019] A further object of the present invention is to provide a film with improved gas barrier properties.
[0020] A further objective of the present invention is to provide a film that is easier to recycle.
[0021] A further object of the present invention is to provide a method for manufacturing a film having improved properties (for example, improved puncture resistance, improved strength, improved heat damage resistance, lower sealing temperature, improved rigidity, improved gas barrier properties, and easier recyclability).
[0022] A further object of the present invention is to provide a method for manufacturing a container having improved properties (for example, improved puncture resistance, improved strength, improved drop damage resistance, improved heat damage resistance, lower sealing temperature, improved rigidity, improved gas barrier properties, and easier recyclability). [Means for solving the problem]
[0023] (Preferred embodiment of the present invention) Any embodiment of the present invention contributes to satisfying at least one of the above-mentioned objectives, at least partially.
[0024] A first embodiment of the present invention is a container for containing a product, wherein the container is a. An internal volume adapted and arranged to accommodate the aforementioned product, b. A first side wall, wherein the first side wall is i. The first edge and, ii. A first surface and a further surface opposite to the first surface, the further surface facing the internal volume, the first surface and the further surface, iii. Film, A. The film comprises at least 30%, preferably at least 50%, more preferably at least 70%, and even more preferably at least 90% of the thickness of the first side wall. B. The film comprises a film having a layered structure, more preferably a film having a layered structure, c. A further side wall opposite to the first side wall, the further side wall having a first edge connected to the first edge of the first side wall, Equipped with, The cross-sectional portion of the layered structure comprises at least five layers, and these at least five layers are A.] Layered substructure A, which includes at least two layers. B.] Layered substructure B, which includes at least one layer. C.] Layered substructure C, including at least two layers. They are arranged as follows: I. The layered substructure B is positioned between the layered substructure A and the layered substructure C. II. The layered substructure C is positioned closer to the internal volume of the container compared to the layered substructure A. The first side wall comprises less than 20% by weight, preferably less than 15% by weight, more preferably less than 10% by weight, and even more preferably less than 5% by weight of paper, cardboard, or both.
[0025] In a preferred embodiment of the first embodiment, the container is a flexible container. In a preferred embodiment of the first embodiment, the product is a liquid product. In a preferred embodiment of the first embodiment, the product is a food, more preferably a liquid food. In a preferred embodiment of the first embodiment, the film comprises at least seven layers, more preferably at least nine layers. In a preferred embodiment of the first embodiment, the film consists of seven or nine layers. In a preferred embodiment of the first embodiment, the film and / or layered structure are more preferably both unoriented. In a preferred embodiment of the first embodiment, at least one of layered substructure A, layered substructure B, and layered substructure C, more preferably all, are unoriented.
[0026] In a preferred embodiment of the first embodiment, the film constitutes at least 95%, more preferably at least 99%, of the thickness of the first sidewall. In a preferred embodiment of the first embodiment, the film forms the first sidewall. In a preferred embodiment of the first embodiment, the thickness of the layered structure constitutes at least 30%, more preferably at least 50%, even more preferably at least 70%, and even more preferably at least 90%, of the thickness of the film. In a preferred embodiment of the first embodiment, the thickness of the layered structure constitutes at least 95%, more preferably at least 99%, of the thickness of the film. In a preferred embodiment of the first embodiment, the thickness of the layered structure constitutes at least 30%, more preferably at least 50%, even more preferably at least 70%, and even more preferably at least 90%, of the thickness of the first sidewall. In a preferred embodiment of the first embodiment, the thickness of the layered structure constitutes at least 95%, more preferably at least 99%, of the thickness of the first sidewall.
[0027] In a preferred embodiment of the first embodiment, the container contains less than 20% by weight, more preferably less than 15% by weight, even more preferably less than 10% by weight, and even more preferably less than 5% by weight of paper, cardboard, or both. In a preferred embodiment of the first embodiment, the first side walls, at least one or all of the containers, more preferably all of them, are substantially free of paper, cardboard, or both.
[0028] In one preferred embodiment of the first embodiment, the layered substructure A consists of two layers. In another preferred embodiment of the first embodiment, the layered substructure A includes at least three layers. In yet another preferred embodiment of the first embodiment, the layered substructure A consists of three layers. In a preferred embodiment of the first embodiment, the layered substructure B includes at least two layers, more preferably at least three layers. In a preferred embodiment of the first embodiment, the layered substructure B consists of three layers. In a preferred embodiment of the first embodiment, the layered substructure B includes at least one layer, more preferably one layer (e.g., B2), which is adapted and arranged to function as a gas barrier. In a preferred embodiment of the first embodiment, the layered substructure B consists of three layers, one of the three layers (e.g., B2) is adapted and arranged to function as a gas barrier, and preferably two of the three layers (e.g., B1, B3) are adapted and arranged to function as adhesive layers. In a preferred embodiment of the first embodiment, the layered substructure C consists of two layers. In another preferred embodiment of the first embodiment, the layered substructure C includes at least three layers. In yet another aforementioned embodiment of the first embodiment, the layered substructure C consists of three layers.
[0029] Many of the embodiments and / or preferred embodiments in this disclosure have preferred embodiments X and / or preferred embodiments Y, such as embodiments 2 to 67 (preferred). A.] A preferred embodiment X of any of the embodiments is preferably applied to a layered structure comprising at least nine layers, more preferably nine layers. A preferred embodiment X of any of the embodiments is preferably applied to a layered structure comprising layers A1, A2, and A3, more preferably a layered substructure A comprising those layers. A preferred embodiment X of any of the embodiments is preferably applied to a layered structure comprising layers C1, C2, and C3, more preferably a layered substructure C comprising those layers. B.] A preferred embodiment Y of any of the embodiments is preferably applied to a layered structure comprising at least seven layers, more preferably seven layers. A preferred embodiment Y of any of the embodiments is preferably applied to a layered structure having a layered substructure A that does not include layer A3. A preferred embodiment Y of any of the embodiments is preferably applied to a layered structure having a layered substructure A that includes layers A1 and A2, more preferably those layers. A preferred embodiment Y of any of the embodiments is preferably applied to a layered structure having a layered substructure C that does not include layer C2. A preferred embodiment Y of any of the embodiments is preferably applied to a layered structure having a layered substructure C that includes layers C1 and C3, more preferably those layers.
[0030] In a preferred embodiment of the container for housing the product, at least one or all of the following apply: a. The layered substructure A comprises at least one polyolefin, preferably at least one polyethylene, more preferably at least one HDPE, at least one LDPE, at least one LLDPE, at least one mLLDPE, or at least one polyethylene selected from the group consisting of at least two of these. b. The layered substructure B comprises at least one or all of the following: polyamide, ethylene / vinyl alcohol copolymer (EVOH), polyvinyl alcohol (PVOH), and polyvinylidene chloride (PVDC), wherein EVOH and PVOH are preferred over PVDC, and EVOH is preferred over PVOH. c. The layered substructure C comprises at least one polyolefin, preferably at least one polyethylene, more preferably at least one HDPE, at least one LDPE, at least one LLDPE, at least one mLLDPE, or at least one polyethylene selected from the group consisting of at least two of these. This preferred embodiment is a second embodiment of the present invention, and more preferably depends on the first embodiment of the present invention.
[0031] In aspects of the second embodiment, all possible combinations of features a. to c. constitute preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In preferred embodiments of the second embodiment, if layered substructure A and / or layered substructure C include “at least two of them”, at least two components can be combinations such as blends. Additionally or alternatively, at least two components may be arranged in separate layers of the layered substructure. In preferred embodiments of the second embodiment, layered substructure A includes at least one HDPE and at least one LDPE, more preferably at least one HDPE and at least one LLDPE. In preferred embodiments of the second embodiment, layered substructure C includes at least one HDPE and at least one LDPE, more preferably at least one HDPE and at least one LLDPE, or at least one HDPE and at least one mLLDPE.
[0032] A third aspect of the present invention is a method for manufacturing a film, I. A step of obtaining a film having a layered structure by extruding at least five layers simultaneously, at least partially, wherein in a cross-section of the film, the at least five layers are the following layered substructures of the layered structure: A. A layered substructure A comprising at least two layers A1 and A2, and optionally layer A3, i. Layer A1 has a density of 0.940 g / cm³ 3 Preferably 0.950 g / cm³ 3 More preferably 0.955 g / cm³ 3 More preferably 0.960 g / cm³ 3 The above-mentioned polyolefins, preferably polyethylene, more preferably HDPE, ii. Layer A2 has a density of 940 g / cm³ 3 Less than 0.935 g / cm³, preferably 0.935 g / cm³ 3 More preferably, 0.930 g / cm³ 3 More preferably, 0.925 g / cm³ 3comprising the following polyolefin, preferably polyethylene, more preferably LDPE, even more preferably LLDPE, iii. Layer A3, if present, has a density of 0.940 g / cm 3 or more, preferably 0.950 g / cm 3 or more, more preferably 0.955 g / cm 3 or more, even more preferably 0.960 g / cm 3 or more, the layered sub-structure A comprising polyolefin, preferably polyethylene, more preferably HDPE, and B. a layered sub-structure B comprising at least one layer, wherein the layered sub-structure B comprises at least one or all of polyamide, ethylene / vinyl alcohol copolymer (EVOH), polyvinyl alcohol (PVOH) and polyvinylidene chloride (PVDC), EVOH and PVOH are more preferred than PVDC, and EVOH is more preferred than PVOH, and the layered sub-structure B, and C. a layered sub-structure C comprising at least two layers C1 and C3, and optionally a layer C2, wherein i. Layer C1 has a density of 0.940 g / cm 3 or more, preferably 0.950 g / cm 3 or more, more preferably 0.955 g / cm 3 or more, even more preferably 0.960 g / cm 3 or more, comprising polyolefin, preferably polyethylene, more preferably HDPE, ii. Layer C2, if present, has a density of less than 940 g / cm 3 , preferably 0.935 g / cm 3 or less, more preferably 0.930 g / cm 3 or less, even more preferably 0.925 g / cm 3 or less, comprising the following polyolefin, preferably polyethylene, more preferably LDPE, even more preferably LLDPE, iii. Layer C3 preferably has a density of less than 940 g / cm 3 , preferably 0.935 g / cm 3 or less, more preferably 0.930 g / cm 3 or less, even more preferably 0.925 g / cm 3The following polyolefins, preferably polyethylene, more preferably LDPE, and even more preferably LLDPE, comprise a layered substructure C, They are arranged in this order, The layered substructure B is positioned between the layered substructure A and the layered substructure C.
[0033] In the third embodiment, the layers in the layered substructure A are arranged in the order A1, A2, and A3 (if present). In the third embodiment, the layers in the layered substructure C are arranged in the order C1, C2 (if present), and C3.
[0034] In a preferred embodiment of the third embodiment, at least seven layers are extruded at least partially simultaneously, more preferably simultaneously, for example, by co-extrusion. In another preferred embodiment of the third embodiment, at least nine layers are extruded at least partially simultaneously, more preferably simultaneously, for example, by co-extrusion. In yet another preferred embodiment of the third embodiment, seven or nine layers are extruded at least partially simultaneously, more preferably simultaneously, for example, by co-extrusion.
[0035] In a preferred embodiment of the third embodiment, the layered structure, more preferably the film, is manufactured by co-extrusion. In a preferred embodiment of the third embodiment, the layered structure, more preferably the film, is manufactured by inflation film extrusion and / or cast film extrusion, and even more preferably by inflation film extrusion. In a preferred embodiment of the third embodiment, at least five layers are extruded simultaneously, for example, by co-extrusion.
[0036] In a preferred embodiment of the third embodiment, the polyolefin of layer A1 is the first polyolefin. In a preferred embodiment of the third embodiment, the polyolefin of layer A2 is the third polyolefin. In a preferred embodiment of the third embodiment, the polyolefin in layer A3 (if present) is the first polyolefin.
[0037] In a preferred embodiment of the third embodiment, the layered substructure B comprises at least two layers, more preferably at least three layers. In a preferred embodiment of the third embodiment, the layered substructure B comprises three layers. In a preferred embodiment of the third embodiment, the layered substructure B comprises a layer (e.g., B2) comprising at least one or all of polyamide, ethylene / vinyl alcohol copolymer (EVOH), polyvinyl alcohol (PVOH), and polyvinylidene chloride (PVDC), wherein EVOH and PVOH are preferred over PVDC, and EVOH is preferred over PVOH. In a preferred embodiment of the third embodiment, the layered substructure B consists of three layers, one of the three layers (e.g., B2) is adapted and arranged to function as a gas barrier, and preferably two of the three layers (e.g., B1, B3) are adapted and arranged to function as adhesive layers.
[0038] In a preferred embodiment of the third embodiment, the polyolefin in layer C1 is the first polyolefin. In a preferred embodiment of the third embodiment, the polyolefin in layer C2 (if present) is the third polyolefin. In a preferred embodiment of the third embodiment, the polyolefin in layer C3 is the fourth polyolefin.
[0039] In a preferred embodiment of the third embodiment, the film and / or the layered structure are, more preferably both, unoriented. In a preferred embodiment of the third embodiment, at least one of the layered substructures A, B, and C, more preferably all, are unoriented. In a preferred embodiment of the third embodiment, the method does not include a step of subjecting the film to a stretching step (for example, the film is not subjected to a stretching step in either the mechanical or transverse direction). In a preferred embodiment of the third embodiment, the method does not include a step of subjecting the layered structure to a stretching step. In a preferred embodiment of the third embodiment, the method does not include a step of subjecting at least one layered substructure to a stretching step.
[0040] In preferred embodiments of the method for manufacturing the film, at least one or all of the following apply: a. The polyolefin in layer A1 has a density of 0.940-0.995 g / cm³. 3 Preferably 0.950~0.985 g / cm³ 3 , more preferably 0.955~0.980 g / cm³ 3 More preferably 0.960~0.975 g / cm³ 3 Being within the range, b. The polyolefin in layer A2 has a density of 0.900-0.940 g / cm³. 3 Less than 0.903 to 0.937 g / cm³ 3 , more preferably 0.908~0.934 g / cm³ 3 More preferably 0.913 to 0.932 g / cm³ 3 Being within the range, c. The polyolefin in layer A3 has a density of 0.940-0.995 g / cm³. 3 Preferably 0.950~0.985 g / cm³ 3 , more preferably 0.955~0.980 g / cm³ 3 More preferably 0.960~0.975 g / cm³ 3 Being within the range. This preferred embodiment is a fourth embodiment of the present invention, and more preferably depends on the third embodiment of the present invention.
[0041] In the embodiment of the fourth embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0042] In preferred embodiments of the method for manufacturing the film, at least one or all of the following apply: a. The polyolefin in layer C1 has a density of 0.940-0.995 g / cm³. 3 Preferably 0.950~0.985 g / cm³ 3 , more preferably 0.955~0.980 g / cm³ 3 More preferably 0.960~0.975 g / cm³ 3 Being within the range, b. The polyolefin in layer C2 has a density of 0.900-0.940 g / cm³ 3 Less than 0.903-0.935 g / cm³ 3 , more preferably 0.908 to 0.930 g / cm³ 3 More preferably 0.913 to 0.925 g / cm³ 3 Being within the range, c. The polyolefin in layer C3 has a density of 0.869 to 0.940 g / cm³. 3 Preferably 0.879~0.935 g / cm³ 3 , more preferably 0.886~0.930 g / cm³ 3 More preferably 0.892~0.925 g / cm³ 3 Being within the range. This preferred embodiment is a fifth embodiment of the present invention, and preferably depends on any of the third to fourth embodiments of the present invention.
[0043] In the fifth embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In preferred embodiment X of the fifth embodiment, feature c., the polyolefin in layer C3 has a density of 0.875 to 0.940 g / cm³.3 Less than 0.885-0.935 g / cm³ 3 , more preferably 0.892~0.930 g / cm³ 3 More preferably 0.898~0.925 g / cm³ 3 It is within the range. In preferred embodiment Y of the fifth embodiment, feature c, the polyolefin in layer C3 has a density of 0.869 to 0.936 g / cm³. 3 Preferably 0.879~0.931 g / cm³ 3 , more preferably 0.886~0.926 g / cm³ 3 More preferably 0.892 to 0.921 g / cm³ 3 It is within the range.
[0044] In a preferred embodiment of the film manufacturing method, at least five layers are extruded at a temperature in the range of 170-250°C, preferably 180-240°C, more preferably 180-220°C, and even more preferably 190-210°C. This preferred embodiment is a sixth embodiment of the present invention, and preferably depends on any of the third to fifth embodiments of the present invention.
[0045] In a preferred embodiment of the method for manufacturing the film, the method further includes the step of cooling the film at a rate in the range of 60 to 430°C / min, preferably 90 to 400°C / min, and more preferably 120 to 370°C / min. This preferred embodiment is a seventh embodiment of the present invention, and preferably depends on any of the third to sixth embodiments of the present invention.
[0046] In embodiments 8 through 54, the phrase "in a preferred embodiment of the method for manufacturing a container and / or film" should be understood to mean that these embodiments are independent, separate, and preferred embodiments of a container for containing a product according to any of embodiments 1 through 2, and a method for manufacturing a film according to any of embodiments 3 through 7.
[0047] In a preferred embodiment of the method for manufacturing a container and / or film, the thickness A of the layered substructure A is less than or equal to the thickness C of the layered substructure C, and preferably less than or equal to that. This preferred embodiment is an eighth embodiment of the present invention, and preferably depends on any of the first to seventh embodiments of the present invention.
[0048] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The thickness B of the layered substructure B is less than the thickness A. b. The thickness B of the layered substructure B is less than the thickness C. This preferred embodiment is the ninth embodiment of the present invention, and preferably depends on any of the first to eighth embodiments of the present invention.
[0049] In the ninth embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0050] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The ratio of thickness C to thickness A is 0.5 to 2.9, preferably 0.8 to 2.4, more preferably 1.0 to 2.2, and even more preferably in the range of 1.20 to 2.05. b. The ratio of thickness A to thickness B is 0.6 to 2.9, preferably 0.9 to 2.4, more preferably 1.1 to 2.2, and even more preferably in the range of 1.35 to 2.10. c. The ratio of thickness C to thickness B is 1.3 to 4.5, preferably 1.5 to 4.2, more preferably 1.7 to 4, and even more preferably in the range of 1.90 to 3.85. This preferred embodiment is a tenth embodiment of the present invention, and preferably depends on any of the first to ninth embodiments of the present invention.
[0051] In the embodiment of the tenth embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0052] In a preferred embodiment X of the tenth embodiment, at least one or all of the following apply: a. The ratio of thickness C to thickness A is in the range of 1.1 to 2.9, preferably 1.4 to 2.4, more preferably 1.6 to 2.2, and even more preferably 1.75 to 2.05. b. The ratio of thickness A to thickness B is in the range of 1.1 to 2.9, preferably 1.4 to 2.4, more preferably 1.6 to 2.2, and even more preferably 1.8 to 2.1. The ratio of thickness C to thickness B is 3.0 to 4.5, preferably 3.2 to 4.2, more preferably 3.4 to 4, and even more preferably in the range of 3.60 to 3.85. In preferred embodiment X of the tenth embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0053] In a preferred embodiment Y of the tenth embodiment, at least one or all of the following apply: a. The ratio of thickness C to thickness A is 0.5 to 2.4, preferably 0.8 to 1.9, more preferably 1.0 to 1.7, and even more preferably in the range of 1.20 to 1.50. b. The ratio of thickness A to thickness B is in the range of 0.6 to 2.5, preferably 0.9 to 2.0, more preferably 1.1 to 1.8, and even more preferably 1.35 to 1.65. c. The ratio of thickness C to thickness B is in the range of 1.3 to 2.8, preferably 1.5 to 2.5, more preferably 1.7 to 2.3, and even more preferably 1.90 to 2.18. In preferred embodiment Y of the tenth embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0054] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Thickness A is in the range of 23-51 μm, preferably 26-48 μm, more preferably 29-45 μm, and even more preferably 32-42 μm. b. Thickness B is in the range of 10 to 34 μm, preferably 12 to 32 μm, more preferably 14 to 30 μm, and even more preferably 16 to 28 μm. c. The thickness C is in the range of 41 to 79 μm, preferably 44 to 76 μm, more preferably 47 to 73 μm, and even more preferably 50 to 70 μm. This preferred embodiment is the 11th embodiment of the present invention, and preferably depends on any of the 1st to 10th embodiments of the present invention.
[0055] In the eleventh embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0056] In a preferred embodiment X of the eleventh embodiment, at least one or all of the following apply: a. The thickness A is in the range of 23 to 47 μm, preferably 26 to 44 μm, more preferably 29 to 41 μm, and even more preferably 32 to 38 μm. b. The thickness B is in the range of 10 to 26 μm, preferably 12 to 24 μm, more preferably 14 to 22 μm, and even more preferably 16 to 20 μm. c. / Thickness C is in the range of 55 to 79 μm, preferably 58 to 76 μm, more preferably 61 to 73 μm, and even more preferably 64 to 70 μm. In preferred embodiment X of the eleventh embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0057] In a preferred embodiment Y of the eleventh embodiment, at least one or all of the following apply: a. The thickness A is in the range of 27-51 μm, preferably 30-48 μm, more preferably 33-45 μm, and even more preferably 36-42 μm. b. The thickness B is in the range of 18-34 μm, preferably 20-32 μm, more preferably 22-30 μm, and even more preferably 24-28 μm. c. / Thickness C is in the range of 41 to 65 μm, preferably 44 to 62 μm, more preferably 47 to 59 μm, and even more preferably 50 to 56 μm. In preferred embodiment Y of the eleventh embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0058] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Thickness A is in the range of 17-45%, preferably 20-42%, more preferably 23-39%, and even more preferably 26-36% of the thickness of the layered structure. b. Thickness B is in the range of 7-30%, preferably 9-28%, more preferably 11-26%, and even more preferably 13-24% of the thickness of the layered structure. c. The thickness C is in the range of 33-68%, preferably 36-65%, more preferably 39-62%, and even more preferably 42-59% of the thickness of the layered structure. However, this must be subject to the constraint that the sum of thicknesses A, B, and C does not exceed 100%. This preferred embodiment is a twelfth embodiment of the present invention, and preferably depends on any of the first to eleventh embodiments of the present invention.
[0059] In the twelfth embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In the twelfth embodiment, the sum of thickness A, thickness B, and thickness C may be less than 100%.
[0060] In a preferred embodiment X of the twelfth embodiment, at least one or all of the following apply: a. Thickness A is in the range of 17-41%, preferably 20-38%, more preferably 23-35%, and even more preferably 26-32% of the thickness of the layered structure. b. The thickness B is in the range of 7-23%, preferably 9-21%, more preferably 11-19%, and even more preferably 13-17% of the thickness of the layered structure. c. / Thickness C is in the range of 44-68%, preferably 47-65%, more preferably 50-62%, and even more preferably 53-59% of the thickness of the layered structure. However, this must be subject to the constraint that the sum of thicknesses A, B, and C does not exceed 100%. In preferred embodiment X of the twelfth embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / . In preferred embodiment X of the twelfth embodiment, the sum of thickness A, thickness B, and thickness C may be less than 100%.
[0061] In a preferred embodiment Y of the twelfth embodiment, at least one or all of the following apply: a. Thickness A is in the range of 21-45%, preferably 24-42%, more preferably 27-39%, and even more preferably 30-36% of the thickness of the layered structure. b. The thickness B is in the range of 14-30%, preferably 16-28%, more preferably 18-26%, and even more preferably 20-24% of the thickness of the layered structure. c. / Thickness C is in the range of 33-57%, preferably 36-54%, more preferably 39-51%, and even more preferably 42-49% of the thickness of the layered structure. However, this must be subject to the constraint that the sum of thicknesses A, B, and C does not exceed 100%. In preferred embodiment Y of the 12th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / . In preferred embodiment Y of the 12th embodiment, the sum of thickness A, thickness B, and thickness C may be less than 100%.
[0062] In preferred embodiments of the method for manufacturing the container and / or film, the following applies: a. The layered substructure A includes at least two layers with different densities. b. The layered substructure C includes at least two layers with different densities. This preferred embodiment is a thirteenth embodiment of the present invention, and preferably depends on any of the first to twelfth embodiments of the present invention.
[0063] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. At least two layers of the layered substructure A, which have different densities, are arranged to be in contact with each other. b. At least two layers of the layered substructure C, which have different densities, are arranged in contact with each other. This preferred embodiment is a 14th embodiment of the present invention, and more preferably depends on a 13th embodiment of the present invention.
[0064] In the 14th embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b. An example of feature a. of the 14th embodiment is as follows: Layered substructure A comprises two layers A1 and A2, the layers having different densities, and the layers of different densities are arranged to be in contact with each other. For example, layers A1 and A2 have different densities and are arranged to be in contact with each other. An example of feature a. of the 14th embodiment is as follows: Layered substructure A comprises three layers A1, A2, and A3, at least two of these layers having different densities, and the layers of different densities are arranged to be in contact with each other. For example, layers A1 and A2 have different densities and are arranged to be in contact with each other. An example of feature b. of the 14th embodiment is as follows: Layered substructure C comprises two layers C1 and C3, the layers having different densities, and the layers of different densities are arranged to be in contact with each other. For example, layers C1 and C3 have different densities and are arranged in contact with each other. An example of the 14th embodiment, feature b., is as follows: the layered substructure C comprises three layers C1, C2, and C3, at least two of which have different densities, and the layers of different densities are arranged in contact with each other. For example, layers C1 and C2 have different densities and are arranged in contact with each other.
[0065] In a preferred embodiment of the method for manufacturing a container and / or film, the density of at least one of the at least two layers of the layered substructure A is different from the density of at least one of the at least two layers of the layered substructure C. This preferred embodiment is the 15th embodiment of the present invention, which preferably depends on any of the 1st to 14th embodiments of the present invention, and more preferably on any of the 13th to 14th embodiments of the present invention.
[0066] An example of the 15th embodiment is as follows: Layered substructure A includes layers A1, A2, and optionally A3, and layered substructure C includes layers C1, optionally C2, and C3, wherein the density of at least one of layers A1, A2, and A3 is different from the density of at least one of layers C1, C2, and C3. For example, the density of layer A1 is different from the density of layer C3.
[0067] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The density of at least one of the at least two layers of layered substructure A is greater than the density of at least one of the at least two layers of layered substructure C. b. The density of at least one of the at least two layers of layered substructure A is less than the density of at least one of the at least two layers of layered substructure C. This preferred embodiment is the 16th embodiment of the present invention, which preferably depends on any of the 1st to 15th embodiments of the present invention, and more preferably on any of the 13th to 15th embodiments of the present invention.
[0068] In the sixteenth embodiment, all possible combinations of features a. and b. constitute preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b. An example of feature a. of the sixteenth embodiment is as follows: Layered substructure A includes layers A1, A2 and optionally A3, and layered substructure C includes layers C1, optionally C2 and C3, where the density of at least one of layers A1, A2 and A3 is greater than the density of at least one of layers C1, C2 and C3. For example, the density of layer A1 is greater than the density of layer C3. An example of feature b. of the sixteenth embodiment is as follows: Layered substructure A includes layers A1, A2 and optionally A3, and layered substructure C includes layers C1, optionally C2 and C3, where the density of at least one of layers A1, A2 and A3 is less than the density of at least one of layers C1, C2 and C3. For example, the density of layer A2 is less than the density of layer C1.
[0069] In a preferred embodiment of the method for manufacturing the container and / or film, the thickness of the layered structure is in the range of 50 to 200 μm, preferably 70 to 170 μm, more preferably 90 to 150 μm, and even more preferably 105 to 135 μm. This preferred embodiment is the 17th embodiment of the present invention, and preferably depends on any of the 1st to 16th embodiments of the present invention.
[0070] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The layers of the layered substructure A form the first surface of the layered structure, more preferably the first surface of the film, and even more preferably the first surface of the container. b. The layers of the layered substructure C form a further surface of the layered structure, more preferably a further surface of the film, and even more preferably a further surface of the container. This preferred embodiment is the 18th embodiment of the present invention, and preferably depends on any of the 1st to 17th embodiments of the present invention.
[0071] In aspects of the 18th embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b. In an alternative to feature a. in the 18th embodiment, the layers of the layered substructure A form a first surface of the layered structure, more preferably a first surface of the film, and the first surface is at least partially coated with a lacquer layer, a printed layer, or both. In one aspect of the 18th embodiment, the first surface and further surfaces of the layered structure face each other. In one aspect of the 18th embodiment, the first surface and further surfaces of the film face each other.
[0072] In a preferred embodiment of the method for manufacturing a container and / or film, the layers of the layered structure are asymmetrical when viewed in a cross-sectional view of the layered structure. This preferred embodiment is the 19th embodiment of the present invention, and preferably depends on any of the 1st to 18th embodiments of the present invention.
[0073] In a preferred embodiment of the 19th embodiment, the cross-sectional cutting is performed perpendicular to the layers of the layered structure.
[0074] In preferred embodiments of the method for manufacturing a container and / or film, the asymmetry relates to at least one or all of the following: the thickness of the layer, the density of the layer, and the chemical composition of the layer. This preferred embodiment is a 20th embodiment of the present invention, and more preferably depends on the 19th embodiment of the present invention.
[0075] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Two consecutive layers of at least two layers of the layered substructure A have different densities. b. Any two consecutive layers of at least two layers of the layered substructure A have different densities. This preferred embodiment is the 21st embodiment of the present invention, and preferably depends on any of the 1st to 20th embodiments of the present invention.
[0076] In the 21st embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0077] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Two of the two consecutive layers of the layered substructure C have different densities. b. Any two consecutive layers of at least two layers of the layered substructure C have different densities. This preferred embodiment is a 22nd embodiment of the present invention, and preferably depends on any of the 1st to 21st embodiments of the present invention.
[0078] In the 22nd embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0079] In a preferred embodiment of the method for manufacturing a container and / or film, the layered structure has a density of 0.94 g / cm³. 3 The above polyolefins are included in an amount of 17-50% by weight, preferably 22-45% by weight, more preferably 29-41% by weight, and even more preferably 29-38% by weight. This preferred embodiment is the 23rd embodiment of the present invention, and preferably depends on any of the 1st to 22nd embodiments of the present invention.
[0080] In a preferred embodiment of the 23rd embodiment, the polyolefin is polyethylene, more preferably HDPE. In a preferred embodiment X of the 23rd embodiment, the layered structure has a density of 0.94 g / cm³ 3 The above polyolefins are included in an amount of 20-50% by weight, preferably 25-45% by weight, more preferably 29-41% by weight, and more preferably 32-38% by weight. In preferred embodiment Y of the 23rd embodiment, the layered structure has a density of 0.94 g / cm³. 3 The above polyolefins are included in an amount of 17.5 to 47.5% by weight, preferably 22.5 to 42.5% by weight, more preferably 26.5 to 38.5% by weight, and even more preferably 29.5 to 35.5% by weight.
[0081] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layered substructure A is in contact with layered substructure B. b. Layered substructure C is in contact with layered substructure B. This preferred embodiment is the 24th embodiment of the present invention, and preferably depends on any of the 1st to 23rd embodiments of the present invention.
[0082] In the 24th embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0083] In a preferred embodiment of the method for manufacturing a container and / or film, the cross-sectional portion of the layered substructure A includes layers A1, A2, and preferably A3 arranged in this order. I. Layer A1 has a thickness A1 and / or density A1, II. Layer A2 has a thickness A2 and / or density A2, III. If layer A3 exists, it has a thickness of A3 and / or density of A3. IV. Layer A1 is located further away from the layered substructure B compared to layer A2. This preferred embodiment is the 25th embodiment of the present invention, and preferably depends on any of the 1st to 24th embodiments of the present invention.
[0084] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Thickness A1 is in the range of 28-67%, preferably 31-64%, more preferably 34-61%, and even more preferably 37-58% of thickness A. b. Thickness A2 is in the range of 22-57%, preferably 25-54%, more preferably 28-51%, and even more preferably 31-49% of thickness A. c. Thickness A3 is in the range of 13-38%, preferably 16-35%, more preferably 19-32%, and even more preferably 22-29% of thickness A. However, this is subject to the constraint that the sum of thickness A1, thickness A2, and thickness A3 (if any) does not exceed 100%. This preferred embodiment is the 26th embodiment of the present invention, and more preferably depends on the 25th embodiment of the present invention.
[0085] In the 26th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In preferred embodiment X of the 26th embodiment, the sum of thickness A1, thickness A2, and thickness A3 (if present) does not have to exceed 100%.
[0086] In preferred embodiment X of the 26th embodiment, at least one or all of the following apply: a. The thickness A1 is in the range of 28-52%, preferably 31-49%, more preferably 34-46%, and even more preferably 37-43% of the thickness A. b. The thickness A2 is in the range of 22-46%, preferably 25-43%, more preferably 28-40%, and even more preferably 31-37% of the thickness A. c. / Thickness A3 is in the range of 13-38% of thickness A, preferably 16-35%, more preferably 19-32%, and even more preferably 22-29%. However, this is subject to the constraint that the sum of thickness A1, thickness A2, and thickness A3 (if any) does not exceed 100%. In preferred embodiment X of the 26th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / . In preferred embodiment X of the 26th embodiment, the sum of thickness A1, thickness A2, and thickness A3 (if present) does not have to exceed 100%.
[0087] In a preferred embodiment Y of the 26th embodiment, at least one or all of the following apply: a. The thickness A1 is in the range of 42.5 to 66.5% of the thickness A, preferably 45.5 to 63.5%, more preferably 48.5 to 60.5%, and even more preferably 51.5 to 57.5%. b. The thickness A2 is in the range of 33-57%, preferably 36-54%, more preferably 39-51%, and even more preferably 42.5-48.5% of the thickness A. However, this must comply with the constraint that the sum of thickness A1 and thickness A2 does not exceed 100%. In preferred embodiment Y of the 26th embodiment, all possible combinations of features a. / and b. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;a. / +b. / . In preferred embodiment Y of the 26th embodiment, the sum of thickness A1 and thickness A2 may be less than 100%.
[0088] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Thickness A1 is in the range of 5-25%, preferably 7-23%, more preferably 9-21%, and even more preferably 10-20% of the thickness of the layered structure. b. Thickness A2 is in the range of 3-24%, preferably 5-20%, more preferably 7-18%, and even more preferably 8.5-16.5% of the thickness of the layered structure. c. Thickness A3 is in the range of 3 to 15%, preferably 4 to 13%, more preferably 5 to 11%, and even more preferably 6 to 9% of the thickness of the layered structure. This preferred embodiment is the 27th embodiment of the present invention, and preferably depends on any of the 25th to 26th embodiments of the present invention.
[0089] In the embodiment of the 27th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0090] In preferred embodiment X of the 27th embodiment, at least one or all of the following apply: a. The thickness A1 is in the range of 5-19%, preferably 7-17%, more preferably 9-15%, and even more preferably 10-13% of the thickness of the layered structure. b. The thickness A2 is in the range of 3 to 19%, preferably 5 to 15%, more preferably 7 to 13%, and even more preferably 8.5 to 11.5% of the thickness of the layered structure. c. The thickness A3 is in the range of 3 to 15%, preferably 4 to 13%, more preferably 5 to 11%, and even more preferably 6 to 9% of the thickness of the layered structure. In preferred embodiment Y of the 27th embodiment, at least one or all of the following apply: combinations of these are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0091] In a preferred embodiment Y of the 27th embodiment, at least one or all of the following apply: a. The thickness A1 is in the range of 11-25%, preferably 13-23%, more preferably 15-21%, and even more preferably 16.5-19.5% of the thickness of the layered structure. b. The thickness A2 is in the range of 8 to 24%, preferably 10 to 20%, more preferably 12 to 18%, and even more preferably 13.5 to 16.5% of the thickness of the layered structure. In preferred embodiment Y of the 27th embodiment, all possible combinations of features a. / and b. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;a. / +b. / .
[0092] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The thickness A1 is in the range of 6 to 31 μm, preferably 9 to 27 μm, more preferably 11 to 24 μm, and even more preferably 12.5 to 23 μm. b. The thickness A2 is in the range of 5 to 28 μm, preferably 7 to 24 μm, more preferably 9 to 21 μm, and even more preferably 10.5 to 19.5 μm. c. The thickness A3 is in the range of 2 to 19 μm, preferably 4.5 to 15 μm, more preferably 6 to 12 μm, and even more preferably 7.5 to 10.5 μm. This preferred embodiment is the 28th embodiment of the present invention, and preferably depends on any of the 25th to 27th embodiments of the present invention.
[0093] In the 28th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0094] In preferred embodiment X of the 28th embodiment, at least one or all of the following apply: a. The thickness A1 is in the range of 6 to 24 μm, preferably 9 to 20 μm, more preferably 11 to 17 μm, and even more preferably 12.5 to 15.5 μm. b. The thickness A2 is in the range of 5 to 22 μm, preferably 7 to 18 μm, more preferably 9 to 15 μm, and even more preferably 10.5 to 13.5 μm. c. The thickness A3 is in the range of 2 to 19 μm, preferably 4.5 to 15 μm, more preferably 6 to 12 μm, and even more preferably 7.5 to 10.5 μm. In preferred embodiment X of the 28th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0095] In a preferred embodiment Y of the 28th embodiment, at least one or all of the following apply: a. The thickness A1 is in the range of 13 to 31 μm, preferably 16 to 27 μm, more preferably 18 to 24 μm, and even more preferably 19.5 to 22.5 μm. b. The thickness A2 is in the range of 11 to 28 μm, preferably 13 to 24 μm, more preferably 15 to 21 μm, and even more preferably 16.3 to 19.5 μm. In preferred embodiment Y of the 28th embodiment, all possible combinations of features a. / and b. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;a. / +b. / .
[0096] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer A1 contains a first polyolefin, preferably a second polyolefin. b. Layer A2 contains a third polyolefin. c. Layer A3 contains a first polyolefin. This preferred embodiment is the 29th embodiment of the present invention, and preferably depends on any of the 25th to 28th embodiments of the present invention.
[0097] In the embodiment of the 29th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0098] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer A1 contains at least 70% by weight, preferably at least 75% by weight, more preferably at least 80% by weight, and even more preferably at least 85% by weight of the first polyolefin. b. Layer A2 contains at least 70% by weight, preferably at least 80% by weight, more preferably at least 90% by weight, and even more preferably at least 95% by weight of a third polyolefin. c. Layer A3 contains at least 70% by weight, preferably at least 80% by weight, more preferably at least 90% by weight, and even more preferably at least 95% by weight of the first polyolefin. The weight percentage should be based on the total weight of each layer. This preferred embodiment is the 30th embodiment of the present invention, and preferably depends on any of the 25th to 29th embodiments of the present invention.
[0099] In the 30th embodiment, all possible combinations of features a. to c. constitute preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In preferred embodiment X of the 30th embodiment, feature a., layer A1 contains a first polyolefin in the range of 70-100% by weight, more preferably 80-95% by weight, and even more preferably 85-92% by weight. In preferred embodiment Y of the 30th embodiment, feature a., layer A1 contains at least 90% by weight, more preferably at least 94% by weight, and even more preferably at least 97% by weight. In preferred embodiment b of the 30th embodiment, layer A2 contains at least 97% by weight, more preferably at least 98% by weight of a third polyolefin. In preferred embodiment c of the 30th embodiment, layer A3 contains at least 97% by weight, more preferably at least 98% by weight of a first polyolefin.
[0100] In a preferred embodiment of the method for manufacturing a container and / or film, layer A1 comprises a second polyolefin in a weight percentage based on the total weight of layer A1, ranging from 0 to 30% by weight, preferably 2.5 to 20% by weight, more preferably 5 to 16% by weight, and even more preferably 7.5 to 12.5% by weight, wherein the remaining weight percentage of layer A1 is preferably composed of a first polyolefin. This preferred embodiment is the 31st embodiment of the present invention, and preferably depends on any of the 25th to 30th embodiments of the present invention.
[0101] In a preferred embodiment of the 31st embodiment, the layered structure preferably comprises at least nine layers, more preferably consisting of nine layers. In a preferred embodiment of the 31st embodiment, the layered substructure A preferably comprises layers A1, A2, and A3, more preferably consisting of these layers.
[0102] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer A1 is in contact with layer A2. b. Layer A2 is in contact with layer A3. This preferred embodiment is the 32nd embodiment of the present invention, and preferably depends on any of the 25th to 31st embodiments of the present invention.
[0103] In the 32nd embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0104] In a preferred embodiment of the method for manufacturing a container and / or film, the cross-sectional portion of the layered substructure B preferably includes layers B1, B2, and B3 arranged in this order. I. If layer B1 exists, it has a thickness B1 and / or density B1. II. Layer B2 has a thickness B2 and / or density B2, III. Layer B3, if present, has a thickness B3 and / or density B3. IV. Layer B1 is located closer to layered substructure A compared to layer B2. This preferred embodiment is the 33rd embodiment of the present invention, and preferably depends on any of the 1st to 32nd embodiments of the present invention.
[0105] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Thickness B1 is in the range of 20-40%, preferably 22-38%, more preferably 24-36%, and even more preferably 25.5-34.5% of thickness B. b. Thickness B2 is in the range of 26-52%, preferably 28-50%, more preferably 30-48%, and even more preferably 31.5-46.8% of thickness B. c. Thickness B3 is in the range of 20-40%, preferably 22-38%, more preferably 24-36%, and even more preferably 25.5-34.5% of thickness B. However, the constraint is that the sum of thickness B1 (if present), thickness B2, and thickness B3 (if present) does not exceed 100%. This preferred embodiment is the 34th embodiment of the present invention, and more preferably depends on the 33rd embodiment of the present invention.
[0106] In the 34th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In the 34th embodiment, the sum of thickness B1 (if present), thickness B2, and thickness B3 (if present) may be less than 100%.
[0107] In preferred embodiment X of the 34th embodiment, at least one or all of the following apply: a. The thickness B1 is in the range of 26-40%, preferably 28-38%, more preferably 30-36%, and even more preferably 31.5-34.5% of the thickness B. b. The thickness B2 is in the range of 26-40%, preferably 28-38%, more preferably 30-36%, and even more preferably 31.5-34.5% of the thickness B. c. / Thickness B3 is in the range of 26-40% of thickness B, preferably 28-38%, more preferably 30-36%, and even more preferably 31.5-34.5%. However, the constraint is that the sum of thickness B1 (if present), thickness B2, and thickness B3 (if present) does not exceed 100%. In preferred embodiment X of the 34th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0108] In a preferred embodiment Y of the 34th embodiment, at least one or all of the following apply: a. The thickness B1 is in the range of 20-34%, preferably 22-32%, more preferably 24-30%, and even more preferably 25.5-28.5% of the thickness B. b. The thickness B2 is in the range of 38-52%, preferably 40-50%, more preferably 42-48%, and even more preferably 43.5-46.8% of the thickness B. c. / Thickness B3 is in the range of 20-34%, preferably 22-32%, more preferably 24-30%, and even more preferably 25.5-28.5% of thickness B. However, the constraint is that the sum of thickness B1 (if present), thickness B2, and thickness B3 (if present) does not exceed 100%. In preferred embodiment Y of the 34th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0109] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The thickness B1 is in the range of 0.5 to 10.5%, preferably 1.5 to 9.5%, more preferably 2.5 to 8.5%, and even more preferably 3.5 to 7.3% of the thickness of the layered structure. b. The thickness B2 is in the range of 0.5 to 14.5%, preferably 1.5 to 13.5%, more preferably 2.5 to 12.5%, and even more preferably 3.5 to 11.5% of the thickness of the layered structure. c. The thickness B3 is in the range of 0.5 to 10.5%, preferably 1.5 to 9.5%, more preferably 2.5 to 8.5%, and even more preferably 3.5 to 7.3% of the thickness of the layered structure. This preferred embodiment is the 35th embodiment of the present invention, and preferably depends on any of the 33rd to 34th embodiments of the present invention.
[0110] In the 35th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0111] In preferred embodiment X of the 35th embodiment, at least one or all of the following apply: a. The thickness B1 is in the range of 0.5 to 9.5%, preferably 1.5 to 8.5%, more preferably 2.5 to 7.5%, and even more preferably 3.7 to 6.3% of the thickness of the layered structure. b. The thickness B2 is in the range of 0.5 to 9.5%, preferably 1.5 to 8.5%, more preferably 2.5 to 7.5%, and even more preferably 3.7 to 6.3% of the thickness of the layered structure. c. The thickness B3 is in the range of 0.5 to 9.5%, preferably 1.5 to 8.5%, more preferably 2.5 to 7.5%, and even more preferably 3.7 to 6.3% of the thickness of the layered structure. In preferred embodiment X of the 35th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0112] In a preferred embodiment Y of the 35th embodiment, at least one or all of the following apply: a. The thickness B1 is in the range of 1.5 to 10.5%, preferably 2.5 to 9.5%, more preferably 3.5 to 8.5%, and even more preferably 4.7 to 7.3% of the thickness of the layered structure. b. The thickness B2 is in the range of 5.5 to 14.5%, preferably 6.5 to 13.5%, more preferably 7.5 to 12.5%, and even more preferably 8.7 to 11.3% of the thickness of the layered structure. c. The thickness B3 is in the range of 1.5 to 10.5%, preferably 2.5 to 9.5%, more preferably 3.5 to 8.5%, and even more preferably 4.7 to 7.3% of the thickness of the layered structure. In preferred embodiment Y of the 35th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0113] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The thickness B1 is in the range of 0.7 to 13.6 μm, preferably 1.5 to 11.6 μm, more preferably 3.5 to 9.6 μm, and even more preferably 4.5 to 8.6 μm. b. The thickness B2 is in the range of 0.7 to 18.3 μm, preferably 1.5 to 16.3 μm, more preferably 3.5 to 14.3 μm, and even more preferably 4.5 to 13.3 μm. c. The thickness B3 is in the range of 0.7 to 13.6 μm, preferably 1.5 to 11.6 μm, more preferably 3.5 to 9.6 μm, and even more preferably 4.5 to 8.6 μm. This preferred embodiment is the 36th embodiment of the present invention, and preferably depends on any of the 33rd to 35th embodiments of the present invention.
[0114] In the 36th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0115] In a preferred embodiment X of the 36th embodiment, at least one or all of the following apply: a. The thickness B1 is in the range of 0.7 to 12.5 μm, preferably 1.5 to 10.5 μm, more preferably 3.5 to 8.5 μm, and even more preferably 4.5 to 7.5 μm. b. The thickness B2 is in the range of 0.7 to 12.5 μm, preferably 1.5 to 10.5 μm, more preferably 3.5 to 8.5 μm, and even more preferably 4.5 to 7.5 μm. c. The thickness B3 is in the range of 0.7 to 12.5 μm, preferably 1.5 to 10.5 μm, more preferably 3.5 to 8.5 μm, and even more preferably 4.5 to 7.5 μm. In preferred embodiment X of the 36th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0116] In a preferred embodiment Y of the 36th embodiment, at least one or all of the following apply: a. The thickness B1 is in the range of 1.8 to 13.6 μm, preferably 2.6 to 11.6 μm, more preferably 4.6 to 9.6 μm, and even more preferably 5.6 to 8.6 μm. b. The thickness B2 is in the range of 6.5 to 18.3 μm, preferably 7.3 to 16.3 μm, more preferably 9.3 to 14.3 μm, and even more preferably 10.3 to 13.3 μm. c. The thickness B3 is 1.8 to 13.6 μm, preferably 2.6 to 11.6 μm, more preferably 4.6 to 9.6 μm, and even more preferably in the range of 5.6 to 8.6 μm. In preferred embodiment Y of the 36th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0117] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer B1 shall be fitted and positioned to function as an adhesive layer. b. Layer B2 shall be adapted and positioned to function as a gas barrier layer. c. Layer B3 shall be fitted and positioned to function as an adhesive layer. This preferred embodiment is the 37th embodiment of the present invention, and preferably depends on any of the 33rd to 36th embodiments of the present invention.
[0118] In the 37th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0119] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The ethylene content of layer B2 is in the range of 22 to 40 mol%, preferably 24 to 38 mol%, more preferably 25.5 to 36 mol%, and even more preferably 27 to 34 mol%. b. Layer B2 contains at least one or all of the following: polyamide, ethylene / vinyl alcohol copolymer (EVOH), polyvinyl alcohol (PVOH), and polyvinylidene chloride (PVDC), wherein EVOH and PVOH are preferred over PVDC, and EVOH is preferred over PVOH. c. Layer B2 has a melting point in the range of 175 to 200°C, preferably 181 to 194°C, and more preferably 185 to 191°C. This preferred embodiment is the 38th embodiment of the present invention, and preferably depends on any of the 33rd to 37th embodiments of the present invention.
[0120] In the 38th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0121] In feature a. of the 38th preferred embodiment X, the ethylene content of layer B2 is in the range of 24 to 38 mol%, more preferably 25.5 to 34.0 mol%, and even more preferably 27 to 31 mol%.
[0122] In the 38th preferred embodiment Y, feature a, the ethylene content of layer B2 is in the range of 25 to 38 mol%, more preferably 28 to 36 mol%, and even more preferably 30 to 34 mol%.
[0123] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer B1 contains at least one or all of the following: carboxylic acid, preferably maleic acid; carboxylic anhydride, preferably maleic anhydride; modified polyolefin, preferably modified polyethylene. b. Layer B3 contains at least one or all of the following: carboxylic acid, preferably maleic acid; carboxylic acid anhydride, preferably maleic anhydride; modified polyolefin, preferably modified polyethylene. This preferred embodiment is the 39th embodiment of the present invention, and preferably depends on any of the 33rd to 38th embodiments of the present invention.
[0124] In the 39th embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0125] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer B1 is in contact with layer B2. b. Layer B2 is in contact with layer B3. This preferred embodiment is the 40th embodiment of the present invention, and preferably depends on any of the 33rd to 39th embodiments of the present invention.
[0126] In the 40th embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0127] In a preferred embodiment of the method for manufacturing a container and / or film, the cross-sectional portion of the layered substructure C includes layers C1, preferably layer C2, and layer C3 arranged in that order. I. Layer C1 has a thickness C1 and / or density C1. II. If layer C2 exists, it shall have a thickness C2 and / or density C2. III. Layer C3 has a thickness C3 and / or density C3. IV. Layer C1 is located closer to layered substructure B compared to layer C3. This preferred embodiment is the 41st embodiment of the present invention, and preferably depends on any of the 1st to 40th embodiments of the present invention.
[0128] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Thickness C1 is in the range of 20-43%, preferably 24-40%, more preferably 27-36%, and even more preferably 28.5-35.0% of thickness C. b. The thickness C2 is in the range of 17-37%, preferably 21-34%, more preferably 24-30%, and even more preferably 25.5-28.5% of the thickness C. c. Thickness C3 is in the range of 32-78% of thickness C, preferably 36-75%, more preferably 39-71%, and even more preferably 41-69%. However, the constraint is that the sum of thickness C1, thickness C2 (if present), and thickness C3 does not exceed 100%. This preferred embodiment is the 42nd embodiment of the present invention, and more preferably depends on the 41st embodiment of the present invention.
[0129] In the 42nd embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In the 42nd embodiment, the sum of thickness C1, thickness C2 (if present), and thickness C3 may be less than 100%.
[0130] In a preferred embodiment X of the 42nd embodiment, at least one or all of the following apply: a. The thickness C1 is in the range of 20-40%, preferably 24-37%, more preferably 27-33%, and even more preferably 28.5-31.5% of the thickness C. b. The thickness C2 is in the range of 17-37%, preferably 21-34%, more preferably 24-30%, and even more preferably 25.5-28.5% of the thickness C. c. / Thickness C3 is in the range of 32-55% of thickness C, preferably 36-50%, more preferably 39-47%, and even more preferably 41-45%. However, the constraint is that the sum of thickness C1, thickness C2 (if present), and thickness C3 must not exceed 100%. In preferred embodiment X of the 42nd embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / . In preferred embodiment X of the 42nd embodiment, the sum of thickness C1, thickness C2 (if present), and thickness C3 may be less than 100%.
[0131] In a preferred embodiment Y of the 42nd embodiment, at least one or all of the following apply: a. The thickness C1 is in the range of 23-43%, preferably 27-40%, more preferably 30-36%, and even more preferably 31.7-35.0% of the thickness C. b. The thickness C3 is in the range of 57-77% of the thickness C, preferably 61-74%, more preferably 64-70%, and even more preferably 65.2-68.5%. However, this must comply with the constraint that the sum of thicknesses C1 and C3 must not exceed 100%. In preferred embodiment Y of the 42nd embodiment, all possible combinations of features a. / and b. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;a. / +b. / . In preferred embodiment Y of the 42nd embodiment, the sum of thicknesses C1 and C3 may be less than 100%.
[0132] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The thickness C1 is in the range of 6-25%, preferably 9-22%, more preferably 11.5-19.5%, and even more preferably 13.5-18.0% of the thickness of the layered structure. b. The thickness C2 is in the range of 6.5 to 23.0% of the thickness of the layered structure, preferably 9.5 to 20.5%, more preferably 12 to 18%, and even more preferably 13.5 to 16.5%. c. The thickness C3 is in the range of 15.5 to 38.0% of the thickness of the layered structure, preferably 18.5 to 35.5%, more preferably 21 to 33%, and even more preferably 22.5 to 31.5%. This preferred embodiment is the 43rd embodiment of the present invention, and preferably depends on any of the 41st to 42nd embodiments of the present invention.
[0133] In the 43rd embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0134] In a preferred embodiment X of the 43rd embodiment, at least one or all of the following apply: a. The thickness C1 is in the range of 8-25%, preferably 11-22%, more preferably 13.5-19.5%, and even more preferably 15-18% of the thickness of the layered structure. b. The thickness C2 is in the range of 6.5 to 23.0% of the thickness of the layered structure, preferably 9.5 to 20.5%, more preferably 12.0 to 18.0%, and even more preferably 13.5 to 16.5%. c. / The thickness C3 is in the range of 15.5 to 32.5% of the thickness of the layered structure, preferably 18.5 to 29.5%, more preferably 21.0 to 27.0%, and even more preferably 22.5 to 25.5%. In preferred embodiment X of the 43rd embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0135] In a preferred embodiment Y of the 43rd embodiment, at least one or all of the following apply: a. The thickness C1 is in the range of 6-23%, preferably 9-20%, more preferably 11.5-20.0%, and even more preferably 13.5-16.5% of the thickness of the layered structure. b. The thickness C3 is in the range of 21.5 to 38.0% of the thickness of the layered structure, preferably 24.5 to 35.5%, more preferably 27.0 to 33.0%, and even more preferably 28.5 to 31.5%. In preferred embodiment Y of the 43rd embodiment, all possible combinations of features a. / and b. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;a. / +b. / .
[0136] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The thickness C1 is in the range of 7 to 30 μm, preferably 10 to 27 μm, more preferably 13 to 24 μm, and even more preferably 15 to 22 μm. b. The thickness C2 is in the range of 8 to 28 μm, preferably 11 to 25 μm, more preferably 14 to 22 μm, and even more preferably 16 to 20 μm. c. The thickness C3 is in the range of 19 to 46 μm, preferably 22 to 43 μm, more preferably 25 to 40 μm, and even more preferably 27 to 38 μm. This preferred embodiment is the 44th embodiment of the present invention, and preferably depends on any of the 41st to 43rd embodiments of the present invention.
[0137] In the 44th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0138] In a preferred embodiment X of the 44th embodiment, at least one or all of the following apply: a. The thickness C1 is in the range of 10 to 30 μm, preferably 13 to 27 μm, more preferably 16 to 24 μm, and even more preferably 18 to 22 μm. b. The thickness C2 is in the range of 8 to 28 μm, preferably 11 to 25 μm, more preferably 14 to 22 μm, and even more preferably 16 to 20 μm. c. The thickness C3 is in the range of 19 to 39 μm, preferably 22 to 36 μm, more preferably 25 to 33 μm, and even more preferably 27 to 31 μm. In preferred embodiment X of the 44th embodiment, all possible combinations of features a. / ~c. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;c. / ;a. / +b. / ;a. / +c. / ;b. / +c. / ;a. / +b. / +c. / .
[0139] In a preferred embodiment Y of the 44th embodiment, at least one or all of the following apply: a. The thickness C1 is in the range of 7.7 to 27.7 μm, preferably 10.7 to 24.7 μm, more preferably 13.7 to 21.7 μm, and even more preferably 15.7 to 19.7 μm. b. The thickness C3 is in the range of 25.4 to 45.4 μm, preferably 28.4 to 42.4 μm, more preferably 31.4 to 39.4 μm, and even more preferably 33.4 to 37.4 μm. In preferred embodiment Y of the 44th embodiment, all possible combinations of features a. / and b. / are preferred embodiments of the embodiment. These combinations are, for example, a. / ;b. / ;a. / +b. / .
[0140] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer C1 contains a first polyolefin. b. Layer C2 contains a third polyolefin. c. Layer C3 contains a fourth polyolefin, preferably at least one or all of the second polyolefin, the third polyolefin, and the fifth polyolefin. This preferred embodiment is the 45th embodiment of the present invention, and preferably depends on any of the 41st to 44th embodiments of the present invention.
[0141] In the 45th embodiment, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0142] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer C1 contains at least 70% by weight, preferably at least 80% by weight, more preferably at least 90% by weight, and even more preferably at least 95% by weight of the first polyolefin. b. Layer C2 contains at least 70% by weight, preferably at least 80% by weight, more preferably at least 90% by weight, and even more preferably at least 95% by weight of a third polyolefin. c. Layer C3 contains at least 30% by weight, preferably at least 45% by weight, more preferably at least 40% by weight, and even more preferably at least 45% by weight of a fourth polyolefin. Here, the weight percentage is based on the total weight of each layer. This preferred embodiment is the 46th embodiment of the present invention, and preferably depends on any of the 41st to 45th embodiments of the present invention.
[0143] In the 46th embodiment, all possible combinations of features a. to c. constitute preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In the 46th preferred embodiment, feature a., layer C1 comprises at least 97% by weight, more preferably at least 98% by weight, of a first polyolefin. In the 46th preferred embodiment, feature b., layer C2 comprises at least 97% by weight, more preferably at least 98% by weight, of a third polyolefin. In the 46th preferred embodiment X, feature c., layer C3 comprises 30-60% by weight, more preferably 40-55% by weight, and even more preferably 44-52% by weight, of a fourth polyolefin. In the 46th preferred embodiment Y, feature c., layer C3 comprises 37-68% by weight, more preferably 47-63% by weight, and even more preferably 51-60% by weight, of a fourth polyolefin.
[0144] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer C3 contains a second polyolefin in an amount ranging from 12 to 24% by weight, preferably 14 to 22% by weight, and more preferably 16 to 20% by weight. b. Layer C3 contains a third polyolefin in the range of 18-38% by weight, preferably 21-35% by weight, more preferably 24-32% by weight, and even more preferably 26-30% by weight. c. Layer C3 contains a fourth polyolefin in the range of 30-100% by weight, preferably 35-85% by weight, more preferably 40-65% by weight, and even more preferably 43-55% by weight. Here, the weight percentage is based on the total weight of layer C3, and if layer C3 contains two or more of the components of features a. to c., the weight percentage does not need to be increased up to 100 weight%. This preferred embodiment is the 47th embodiment of the present invention, and preferably depends on any of the 41st to 46th embodiments of the present invention.
[0145] In the 47th embodiment, all possible combinations of features a. to c. constitute preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In the 47th embodiment, the layered structure comprises at least nine layers, more preferably nine layers. In the 47th embodiment, the layered substructure C comprises layers C1, C2, and C3, more preferably those layers.
[0146] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. Layer C3 contains a fourth polyolefin in the range of 30-100% by weight, preferably 35-80% by weight, more preferably 45-65% by weight, and even more preferably 50-60% by weight. b. Layer C3 contains a fifth polyolefin in the range of 22-63% by weight, preferably 27-58% by weight, more preferably 32-53% by weight, and even more preferably 37-48% by weight. Here, the weight percentage is based on the total weight of layer C3, and if layer C3 contains both components of features a. and b., the weight percentage does not need to be added up to 100 weight%. This preferred embodiment is the 48th embodiment of the present invention, and preferably depends on any of the 41st to 46th embodiments of the present invention.
[0147] In the 48th embodiment, all possible combinations of features a. and b. constitute preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b. In the 48th embodiment, the layered structure comprises at least seven layers, more preferably seven layers. In the 48th embodiment, the layered structure has a layered substructure C that does not include layer C2. In the 48th embodiment, the layered structure comprises layers C1 and C3, more preferably a layered substructure C consisting of those layers.
[0148] In a preferred embodiment of the method for manufacturing a container and / or film, the layered substructure C includes layers C1 and C3, and one of the following applies: a. Layer C1 is in contact with layer C3; or b. Layer C2 is positioned between layers C1 and C3 (for example, layers C1 and C3 do not come into contact). This preferred embodiment is the 49th embodiment of the present invention, and preferably depends on any of the 41st to 48th embodiments of the present invention.
[0149] In a preferred embodiment of the method for manufacturing a container and / or film, the layered substructure C includes layers C1, C2, and C3, and at least one or all of the following apply: a. Layer C1 is in contact with layer C2. b. Layer C2 is in contact with layer C3. This preferred embodiment is the 50th embodiment of the present invention, and preferably depends on any of the 41st to 49th embodiments of the present invention.
[0150] In the 50th embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0151] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The first polyolefin is polyethylene, preferably HDPE. b. The second polyolefin is polyethylene, preferably LDPE, more preferably LLDPE. c. The third polyolefin is polyethylene, preferably LDPE, more preferably LLDPE. This preferred embodiment is the 51st embodiment of the present invention, and preferably depends on any of the 29th to 50th embodiments of the present invention.
[0152] In an aspect of the 51st embodiment, all possible combinations of features a. to c. are preferred aspects of the embodiment. These combinations are, for example, a; b; c; a+b; a+c; b+c; a+b+c.
[0153] In a preferred embodiment of the method for producing a container and / or a film, at least one or all of the following apply: a. the first polyolefin has a density of 0.940 to 0.995 g / cm 3 , preferably 0.950 to 0.985 g / cm 3 , more preferably 0.955 to 0.980 g / cm 3 , still more preferably 0.960 to 0.975 g / cm 3 , b. the second polyolefin has a density of less than 0.900 to 0.940 g / cm 3 , preferably 0.908 to 0.936 g / cm 3 , more preferably 0.913 to 0.933 g / cm 3 , still more preferably 0.918 to 0.928 g / cm 3 , c. the third polyolefin has a density of less than 0.900 to 0.940 g / cm 3 , preferably 0.903 to 0.935 g / cm 3 , more preferably 0.908 to 0.932 g / cm 3 , still more preferably 0.913 to 0.930 g / cm 3 . This preferred embodiment is the 52nd embodiment of the present invention, and preferably depends on any one of the 29th to 51st embodiments of the present invention.
[0154] In an aspect of the 52nd embodiment, all possible combinations of features a. to c. are preferred aspects of the embodiment. These combinations are, for example, a; b; c; a+b; a+c; b+c; a+b+c. In a preferred aspect X of the 52nd embodiment, the third polyolefin has a density of 0.900 to 0.940 g / cm 3 less than, preferably 0.903 to 0.935 g / cm 3, more preferably 0.908 to 0.930 g / cm³ 3 More preferably 0.913 to 0.925 g / cm³ 3 It is within the range. In preferred embodiment Y of the 52nd embodiment, the third polyolefin has a density of 0.900 to 0.940 g / cm³. 3 Less than 0.910-0.937 g / cm³ 3 , more preferably 0.915~0.934 g / cm³ 3 More preferably 0.920~0.932 g / cm³ 3 It is within the range.
[0155] In preferred embodiments of the method for manufacturing containers and / or films, at least one or all of the following apply: a. The fourth polyolefin is polyethylene, preferably LDPE, VLDPE, or plastomer, more preferably LLDPE. b. The fourth polyolefin has a density of 0.869–0.935 g / cm³ 3 Preferably 0.879~0.925 g / cm³ 3 , more preferably 0.886~0.918 g / cm³ 3 More preferably 0.892 to 0.912 g / cm³ 3 Being within the range. This preferred embodiment is the 53rd embodiment of the present invention, and preferably depends on any of the 45th to 52nd embodiments of the present invention.
[0156] In the 53rd embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b. In preferred embodiment X of the 53rd embodiment, the fourth polyolefin has a density of 0.875 to 0.935 g / cm³. 3 Preferably 0.885~0.925 g / cm³ 3 , more preferably 0.892~0.918 g / cm³ 3 More preferably 0.898 to 0.912 g / cm³ 3within the range. In preferred embodiment Y of the fifty-third embodiment, the fourth polyolefin has a density of 0.869 to 0.929 g / cm 3 , preferably 0.879 to 0.919 g / cm 3 , more preferably 0.886 to 0.912 g / cm 3 , still more preferably 0.892 to 0.906 g / cm 3 within the range.
[0157] In a preferred embodiment of the method for producing a container and / or a film, at least one or all of the following apply: a. the fifth polyolefin is polyethylene, preferably LDPE, VLDPE or a plastomer, more preferably LLDPE, even more preferably mLLDPE, b. the fifth polyolefin has a density of 0.896 to 0.936 g / cm 3 , preferably 0.899 to 0.931 g / cm 3 , more preferably 0.904 to 0.926 g / cm3, still more preferably 0.909 to 0.921 g / cm 3 within the range. This preferred embodiment is the fifty-fourth embodiment of the present invention, and preferably depends on any one of the forty-fifth to fifty-third embodiments of the present invention.
[0158] In a preferred embodiment of the container, the further side wall is a. a first surface and a further surface opposite the first surface, wherein the further surface faces the internal volume; and b. a film, wherein i. the film constitutes at least 30%, preferably at least 50%, more preferably at least 70%, still more preferably at least 90% of the thickness of the further side wall; and comprises the above. This preferred embodiment is the fifty-fifth embodiment of the present invention, and preferably depends on any one of the first to second and eighth to fifty-fourth embodiments of the present invention.
[0159] In a preferred embodiment of the 55th embodiment, the film constitutes at least 95%, more preferably at least 99%, of the thickness of the further sidewall. In a preferred embodiment of the 55th embodiment, the thickness of the layered structure constitutes at least 30%, more preferably at least 50%, even more preferably at least 70%, and even more preferably at least 90%, of the thickness of the further sidewall. In a preferred embodiment of the 55th embodiment, the thickness of the layered structure constitutes at least 95%, more preferably at least 99%, of the thickness of the further sidewall. In a preferred embodiment of the 55th embodiment, the film forms the further sidewall. In a preferred embodiment of the 55th embodiment, the further sidewall includes less than 20% by weight, more preferably less than 15% by weight, even more preferably less than 10% by weight, and even more preferably less than 5% by weight of paper, cardboard, or both. In a preferred embodiment of the 55th embodiment, the further sidewall is substantially free of paper, cardboard, or both.
[0160] A 56th embodiment of the present invention is a method for manufacturing a container for holding a product, and this method is I. / A film obtained according to the method of the present invention for manufacturing a film, preferably a film obtained by a method according to any of the third to fifty-fourth embodiments of the present invention, II. A step of using a film to generate at least a first side wall of a container, and preferably a further side wall of the container, wherein the further side wall is on the opposite side of the first side wall, and Includes. In a preferred embodiment of the 56th embodiment, the product is a liquid product. In a preferred embodiment of the 56th embodiment, the product is a food, more preferably a liquid food.
[0161] In a preferred embodiment of the method for manufacturing a container, the step of using a film to create at least a first side wall of the container is: A. / The step of manipulating the film, preferably by folding it, to form a first side wall and a further side wall opposite the first side wall, which at least partially encloses the internal volume, i. The first side wall and the further side wall are, respectively a) The first edge and, b) A first surface and a further surface opposite to the first surface, the further surface facing the internal volume, the first surface and the further surface, c) comprising a film, ii. With respect to the first side wall and each of the further side walls, the layered substructure C is positioned closer to the internal volume compared to the layered substructure A, and includes substeps. B. / A substep of connecting the first edge of the first side wall to the first edge of a further side wall, Includes. This preferred embodiment is the 57th embodiment of the present invention, and more preferably depends on the 56th embodiment of the present invention.
[0162] In a preferred embodiment of the method for manufacturing a container, the method further includes the step of filling the container with the product. This preferred embodiment is the 58th embodiment of the present invention, and preferably depends on any of the 56th to 57th embodiments of the present invention.
[0163] In a preferred embodiment of the 58th embodiment, the product is a food product or a liquid product. In a preferred embodiment of the 58th embodiment, the product is a food product, more preferably a liquid food product. In a preferred embodiment of the present invention, a container according to any of the 1st to 2nd and 8th to 55th embodiments is manufactured using a method according to any of the 56th to 58th embodiments.
[0164] The 59th embodiment of the present invention is a container that can be obtained by a method of the present invention for manufacturing a container for containing a product, preferably by a method according to any of the 56th to 58th embodiments.
[0165] The 60th embodiment of the present invention is a container according to the present invention, preferably a container according to any of the 1st to 2nd, 8th to 55th and 59th embodiments of the present invention, wherein the container is at least partially housed within a receptacle.
[0166] In a preferred aspect of the 60th embodiment, the receptacle comprises at least 50% by weight, more preferably at least 65% by weight, even more preferably at least 80% by weight, still more preferably at least 95% by weight of paper, cardboard, or both. In a preferred aspect of the 60th embodiment, the receptacle is semi-rigid. In another preferred aspect of the 60th embodiment, the receptacle is rigid. In another preferred aspect of the 60th embodiment, the receptacle is cubic or cuboid (i.e., has a three-dimensional rectangular shape). An example of a container accommodated in the receptacle is a bag-in-box.
[0167] A sixty-first embodiment of the present invention is a container according to the present invention, preferably a container according to any one of the first to second, eighth to fifty-fifth, and fifty-ninth to sixtieth embodiments of the present invention, wherein the container is at least partially filled with a product. In a preferred aspect of the 61st embodiment, the product is a liquid food product. In a preferred aspect of the 61st embodiment, the product is a food product, more preferably a liquid food product.
[0168] In a preferred embodiment of the container, the first side wall, preferably the further side wall, has at least one or all of the following properties: a. the dart drop impact is in the range of 160 to 290 g, preferably 180 to 270 g, more preferably 200 to 250 g, b. the average puncture elongation is in the range of 35 to 65 mm, preferably 40 to 59 mm, more preferably 44 to 55 mm, c. the average puncture force is in the range of 95 to 150 N, preferably 105 to 140 N, more preferably 115 to 130 N, d. the Young's modulus in MD is in the range of 600 to 1150 MPa, preferably 750 to 1050 MPa, more preferably 850 to 950 MPa, e. the Young's modulus in TD is in the range of 600 to 1300 MPa, preferably 850 to 1150 MPa, more preferably 950 to 1050 MPa. This preferred embodiment is the 62nd embodiment of the present invention, and preferably depends on any of the 1st to 2nd, 8th to 55th, and 59th to 61st embodiments of the present invention.
[0169] In the embodiment of the 62nd embodiment, all possible combinations of features a. to e. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;d;e;a+b;a+c;a+d;a+e;b+c;b+d;b+e;c+d;c+e;d+e;a+b+c;a+b+d;a+b+e;a+c+d;a+c+e;a+d+e;b+c+e;b+d+e;c+d+e;a+b+c+d;a+b+c+e;a+b+c+e;b+c+d+e;a+b+c+d+e.
[0170] In a preferred embodiment of the container, the first side wall, and preferably further side walls, have at least one or all of the following characteristics: a. The maximum tensile strength MD is in the range of 35-75 N / 15 mm, preferably 45-65 N / 15 mm, and more preferably 50-60 N / 15 mm. b. The maximum tensile strength TD is in the range of 30-70 N / 15 mm, preferably 40-60 N / 15 mm, and more preferably 45-55 N / 15 mm. c. The elongation MD at the breaking point is in the range of 650 to 1150%, preferably 750 to 1050%, and more preferably 850 to 950%. d. The elongation at the breaking point (TD) is in the range of 650 to 1150%, preferably 750 to 1050%, and more preferably 850 to 950%. e. The seal strength measured at 130℃ is in the range of 20-56 N / 15 mm, preferably 28-49 N / 15 mm, and more preferably 32-45 N / 15 mm. f. The oxygen permeability (OTR) is less than 1.5, preferably less than 1.1, and more preferably less than 0.6. This preferred embodiment is the 63rd embodiment of the present invention, and preferably depends on any of the 1st to 2nd, 8th to 55th, and 59th to 62nd embodiments of the present invention.
[0171] In the 63rd embodiment, all possible combinations of features a. to f. are preferred embodiments of the embodiment. These combinations include, for example, a;b;c;d;e;f;a+b;a+c;a+d;a+e;a+f;b+c;b+d;b+e;b+f;c+d;c+e;c+f;d+e;d+f;e+f;a+b+c;a+b+d;a+b+e;a+b+f;a+c+d;a+c+e;a+d+f;a+e+f;b+c+e;b+d+f;b+e+f;c+d+e;c+e+f;d +e+f;a+b+c+d;a+b+c+e;a+b+c+f;a+b+d+e;a+b+d+f;a+b+e+f;a+c+d+e;a+c+d+f;a+c+e+f;a+d+e+f;b+c+d+e;b+c+d+f ;b+c+e+f;b+d+e+f;c+d+e+f;a+b+c+d+e;a+b+c+d+f;a+b+c+e+f;a+b+d+e+f;a+c+d+e+f;b+c+d+e+f;a+b+c+d+e+f. In a preferred embodiment of the 63rd embodiment, the OTR is in the range of 0.15 to 0.55, more preferably 0.20 to 0.50, and even more preferably 0.25 to 0.45.
[0172] In a preferred embodiment of the container, the first side wall, and preferably a further side wall, have at least one or all of the following characteristics: a. COF In-In is less than 0.5, preferably less than 0.4, and more preferably less than 0.3. b. COF Out-Out is less than 0.5, preferably less than 0.4, and more preferably less than 0.3. This preferred embodiment is the 64th embodiment of the present invention, which preferably depends on any of the 1st to 2nd, 8th to 55th, and 59th to 63rd embodiments of the present invention.
[0173] In the 64th embodiment, all possible combinations of features a. and b. are preferred embodiments of the embodiment. These combinations are, for example, a;b;a+b.
[0174] The 65th embodiment of the present invention is a film obtained by a method of the present invention for manufacturing a film, preferably by a method according to any of the 3rd to 54th embodiments of the present invention.
[0175] A 66th embodiment of the present invention is the use of a film according to the present invention, preferably a film according to the 65th embodiment of the present invention, for manufacturing a container for holding a product.
[0176] In a preferred embodiment of the 66th embodiment, the film comprises, and more preferably comprises, a layered structure according to any of the 1st to 55th embodiments of the present invention. In a preferred embodiment of the 66th embodiment, the product is a liquid product. In a preferred embodiment of the 66th embodiment, the product is a food, more preferably a liquid food.
[0177] The 67th embodiment of the present invention is the use of a container according to the present invention for containing a product, preferably a container according to any of the 1st to 2nd, 8th to 55th, and 59th to 64th embodiments of the present invention.
[0178] In a preferred embodiment of the 67th embodiment, the product is a liquid product. In a preferred embodiment of the 67th embodiment, the product is a food, more preferably a liquid food.
[0179] (Detailed description of the present invention) Throughout this specification, a disclosure of a range should preferably be understood to include both endpoints of that range. Furthermore, each disclosure of a range in this specification should preferably be understood to also disclose a preferred sub-range from which one or both endpoints are excluded. For example, a disclosure of the range X1-X2 should be understood to disclose a range that includes both endpoints X1 and X2. Furthermore, it should be understood to also disclose a range that includes endpoint X1 but not endpoint X2, a range that does not include endpoint X1 but includes endpoint X2, and a range that does not include either endpoint X1 or X2.
[0180] Some preferred embodiments and preferred forms have various combinations of features as alternatives. When these various combinations are disclosed, the combinations are separated by semicolons (";"). For example, the list of feature combinations in a preferred embodiment "a; a+b; a+c+d" discloses a preferred embodiment containing feature "a", a preferred embodiment containing features "a" and "b", and a preferred embodiment containing features "a", "c", and "d".
[0181] In this specification, the use of letters and / or numbers to indicate features is for distinguishing labels that might otherwise be similar or identical, such as "Layer C1" and "Layer C3," and does not imply priority, importance, the presence of other features, or other attributes unless otherwise stated. For example, a layered substructure C containing Layer C3 should not necessarily be understood to mean that the layered substructure C also contains Layer C2 (i.e., a layered substructure C containing Layer C3 may or may not contain Layer C2).
[0182] In this specification, the following abbreviations are used: PE: polyethylene; HDPE: high-density polyethylene; LDPE: low-density polyethylene; LLDPE: linear low-density polyethylene; mLLDPE: metallocene LLDPE; VLDPE: very low-density polyethylene; COF: coefficient of friction; MD: mechanical direction; TD: transverse direction.
[0183] (Preferred embodiments X and Y) Preferred embodiment X is applied to a layered structure having a layered substructure A comprising, preferably, three layers. Preferred embodiment X is applied to a layered structure having a layered substructure A comprising, preferably, layers A1, A2, and A3. Preferred embodiment X is applied to a layered structure having a layered substructure C comprising, preferably, three layers. Preferred embodiment X is applied to a layered structure having a layered substructure C comprising, preferably, layers C1, C2, and C3.
[0184] Preferred embodiment Y is applied to a layered structure having a layered substructure A that preferably includes two layers, more preferably consisting of two layers. Preferred embodiment Y is applied to a layered structure having a layered substructure A that preferably does not include layer A3. Preferred embodiment Y is applied to a layered structure having a layered substructure A that preferably includes layers A1 and A2, more preferably consisting of those layers. Preferred embodiment Y is applied to a layered structure having a layered substructure C that preferably includes two layers, more preferably consisting of two layers. Preferred embodiment Y is applied to a layered structure having a layered substructure C that preferably does not include layer C2. Preferred embodiment Y is applied to a layered structure having a layered substructure C that preferably includes layers C1 and C3, more preferably consisting of those layers.
[0185] Preferred embodiment X is preferably applied to a layered structure comprising at least nine layers, more preferably nine layers. Preferred embodiment Y is preferably applied to a layered structure comprising at least seven layers, more preferably seven layers. Preferred embodiments X and / or Y are also preferably applied to a layered structure comprising at least eight layers, more preferably eight layers. For example, preferred embodiment X is preferably applied to a layered substructure A of a layered structure comprising eight layers. For example, preferred embodiment Y is preferably applied to a layered substructure C of a layered structure comprising eight layers.
[0186] It should be noted that Preferred Embodiment X may be applied to any layered structure according to the present invention, for example, a layered structure containing or consisting of seven layers. However, Preferred Embodiment X is more preferable to a layered structure containing nine layers than to a layered structure consisting of seven layers. It should also be noted that Preferred Embodiment Y may be applied to any layered structure according to the present invention, for example, a layered structure containing or consisting of nine layers. However, Preferred Embodiment Y is more preferable to a layered structure containing seven layers, more preferably a layered structure consisting of seven layers, than to a layered structure containing or consisting of nine layers.
[0187] Preferred embodiment X can be applied separately and independently to any container, any method for manufacturing a film according to the present invention (if the method is according to the present invention), any method for manufacturing a container (if the method is according to the present invention), any film according to the present invention, any use of the film (if the use is according to the present invention), and any use of the container (if the use is according to the present invention). Preferred embodiment Y can be applied separately and independently to any container, any method for manufacturing a film according to the present invention (if the method is according to the present invention), any method for manufacturing a container (if the method is according to the present invention), any film according to the present invention, any use of the film (if the use is according to the present invention), and any use of the container (if the use is according to the present invention).
[0188] (container) A preferred container is flexible. Here, the term “flexible” should preferably be understood as used in the packaging industry. A flexible container should preferably be understood as a non-rigid container. A preferred flexible container is fitted and positioned so that it can be deformed at least partially without damaging the container. The term “rigid” should preferably be understood as used in the packaging industry.
[0189] A preferred container contains at least 65% by weight, more preferably at least 75% by weight, and even more preferably at least 85% by weight of the film according to the present invention, where weight percentage is based on the total weight of the container. The film according to the present invention includes, more preferably consists of, a layered structure according to the present invention.
[0190] In a preferred embodiment of the present invention, the first side wall, further side walls, and at least one or all, more preferably all, of the containers contain less than 3% by weight of paper. In a preferred embodiment of the present invention, the first side wall, further side walls, and at least one or all, more preferably all, of the containers contain less than 1% by weight of paper. In a preferred embodiment of the present invention, the first side wall, further side walls, and at least one or all, more preferably all, of the containers contain less than 3% by weight of cardboard. In a preferred embodiment of the present invention, at least one or all, more preferably all, of the following contain less than 1% by weight of cardboard. In a preferred embodiment of the present invention, the first side wall, further side walls, and at least one or all, more preferably all, of the containers are substantially free of paper. In a preferred embodiment of the present invention, the first side wall, further side walls, and at least one or all, more preferably all, of the containers are substantially free of cardboard.
[0191] The “first surface” of the container should preferably be understood as the surface of the container that is intended to come into contact with the environment in which the container is placed. An example of the first surface is the outer surface of the container. The “further surfaces” of the container should preferably be understood as the surface of the container that is intended to come into contact with the product, preferably food, contained within the internal volume of the container. An example of the further surfaces is the inner surface of the container.
[0192] The container preferably comprises a lacquer layer superimposed on the first surface. The container may also include a printed layer superimposed on the first surface. Here, “superimposed” should not necessarily be understood to mean that the lacquer layer and / or printed layer are in direct contact with the first surface. This may be the case, but there may also be one or more other layers positioned between the lacquer layer and / or printed layer and the first surface.
[0193] A preferred container is a pouch, and more preferably a spouted pouch. Examples of spouted pouches include CloverCap pouches and CleanClic Connect pouches, both of which are commercially available from SIG Group AG.
[0194] (Opening) In a preferred embodiment, the container is adapted and arranged to be opened by at least partially damaging the container, preferably by at least partially damaging the first side wall, the further side wall, or both. Examples of damaging the container include puncturing the container, and at least partially separating at least two sections of the container, preferably at least two sections of the first side wall, the further side wall, or both. Examples of at least partial separation of at least two sections include cutting and tearing the container.
[0195] Unless otherwise stated, the term "opening" as used herein should be understood as an opening adapted and arranged to discharge a product contained in the internal volume of the container. In another preferred embodiment, the container comprises an opening. A preferred opening has a cross-sectional area of 7.2 cm 2 or less, more preferably 5.2 cm 2 or less, still more preferably 3.2 cm 2 or less, even more preferably 2 cm 2 or less.
[0196] Unless otherwise stated, "discharging means" should be understood as means for discharging a product contained in the internal volume of the container. In a preferred embodiment, the container comprises a discharging means. The discharging means may for example be formed from a polymer or a blend of polymers. The discharging means preferably comprises a polyolefin, more preferably polyethylene, and even more preferably MDPE. The discharging means may for example be attached to said first surface of the container, or may be integrated into the container. Examples of discharging means include spouts, nozzles, straws (such as drinking straws), and the like.
[0197] In a preferred embodiment, the container is fitted and arranged to be closable, where closable is preferably understood to mean that the container can be opened and closed at least once. In a preferred embodiment, the container includes an opening and / or discharge means fitted and arranged to be closable. A container fitted and arranged to be closable preferably includes at least one closure means. Examples of closure means for a container fitted and arranged to be opened by at least partially damaging the container include a section of adhesive and a press seal. Examples of closure means for a container with an opening and / or discharge means include a lid and a cap. The closure means preferably include polyolefin, more preferably polyethylene, and even more preferably HDPE.
[0198] In another preferred embodiment of the present invention, the container includes an opening, such as an overcoated hole, that is fitted and positioned to be non-closable. For example, the opening is covered with a seal that is not fitted and positioned to be closable once broken (e.g., using a straw).
[0199] (product) Examples of “products” as used herein include, but are not limited to, household products, food products, and cosmetics. A preferred product is food products.
[0200] Preferred products are liquid products. The term “liquid products” as used herein should be understood to also include semi-liquid products (e.g., pastes, creams, purees, gels). Preferred liquid products are liquid foods.
[0201] The term "household products" should be understood to include any products suitable for use in a household, and preferably commonly used in a household. Examples of household products include cleaning agents (detergents, laundry powders, dishwashing solutions, soaps, etc.), adhesives (glues, etc.), and wood products (wood oils, varnishes, etc.). Preferred household products are cleaning agents.
[0202] The term "liquid household products" should be understood to include semi-liquid household products (e.g., pastes, creams, gels). Examples of liquid household products include liquid cleaning products such as detergents and dish soaps.
[0203] The term “food” should be understood to include all kinds of food and beverages that are known to those skilled in the art and / or that are consumed by humans and / or animals. Examples include cereals, milk and juices.
[0204] The term "liquid foods" should be understood to include semi-liquid foods (e.g., pastes, creams, purees, gels). Preferred liquid foods are those that are non-solid above 5°C. Examples of liquid foods include milk, honey, yogurt, tomato sauce, soup, and tomato paste.
[0205] The term "cosmetics" should preferably be understood as products suitable for application to the body of humans and / or animals for the purpose of improving the appearance of the body. Examples of cosmetics include night creams and blushes.
[0206] The term "liquid cosmetics" should be understood to include semi-liquid cosmetics (e.g., pastes, creams, gels). Examples of liquid cosmetics include beauty creams.
[0207] (Layered structure) The preferred film and / or preferred layered structure is unoriented. In preferred embodiments of the present invention, both the film and the layered structure are unoriented. Unoriented is sometimes also called non-oriented. The terms “oriented” and “unoriented” should be understood as used in the packaging industry. A film can be oriented by subjecting the film to one or more stretching steps, the stretching steps can be performed in the machine direction, transverse direction, or both. The one or more stretching steps are usually performed after the film has been manufactured. A layered structure can be oriented by subjecting the layered structure to one or more stretching steps, the stretching steps can be performed in the machine direction, transverse direction, or both. The one or more stretching steps are usually performed after the layered structure has been manufactured. In preferred embodiments of the present invention, neither the film nor the layered structure, more preferably both, is subjected to stretching steps.
[0208] A particularly preferred layered structure comprises at least seven layers. Here, a layered structure comprising seven, eight, or nine layers is preferred, and more preferably, a layered structure comprising such layers is preferred. Here, a layered structure comprising seven or nine layers is preferred over a layered structure comprising eight layers.
[0209] In a preferred embodiment of the present invention, the layered structure comprises at least nine layers, more preferably nine layers. The layered structure comprising at least nine layers, more preferably nine layers, preferably has a layered substructure A comprising three layers, more preferably three layers. The layered structure comprising at least nine layers, more preferably nine layers, preferably comprises layers A1, A2, and A3, more preferably a layered substructure A comprising those layers. The layered structure comprising at least nine layers, more preferably nine layers, preferably has a layered substructure C comprising three layers, more preferably three layers. The layered structure comprising at least nine layers, more preferably nine layers, preferably comprises layers C1, C2, and C3, more preferably a layered substructure C comprising those layers.
[0210] In a preferred embodiment of the present invention, the layered structure comprises at least eight layers, more preferably eight layers. The layered structure comprising at least eight layers, more preferably eight layers, preferably has a layered substructure A comprising three layers, more preferably three layers. The layered structure comprising at least eight layers, more preferably eight layers, preferably comprises layers A1, A2, and A3, more preferably a layered substructure A comprising those layers. The layered structure comprising at least eight layers, more preferably eight layers, preferably has a layered substructure C comprising two layers, more preferably two layers. The layered structure comprising at least eight layers, more preferably eight layers, preferably has a layered substructure C that does not include layer C2. The layered structure comprising at least eight layers, more preferably eight layers, preferably comprises layers C1 and C3, more preferably a layered substructure C comprising those layers.
[0211] In another preferred embodiment of the present invention, the layered structure comprises at least seven layers, more preferably seven layers. The layered structure comprising at least seven layers, more preferably seven layers, preferably has a layered substructure A comprising two layers, more preferably two layers. The layered structure comprising at least seven layers, more preferably seven layers, preferably has a layered substructure A that does not include layer A3. The layered structure comprising at least seven layers, more preferably seven layers, preferably includes layers A1 and A2, more preferably a layered substructure A comprising them. The layered structure comprising at least seven layers, more preferably seven layers, preferably has a layered substructure C comprising two layers, more preferably two layers. The layered structure comprising at least seven layers, more preferably seven layers, preferably has a layered substructure C that does not include layer C2. The layered structure comprising at least seven layers, more preferably seven layers, preferably includes layers C1 and C3, more preferably a layered substructure C comprising them.
[0212] A layered structure consisting of eight layers is less preferable than a layered structure consisting of seven layers and a layered structure consisting of at least nine layers (for example, nine layers).
[0213] (Layered substructure and layers) The term "layered substructure" is a supplementary conceptual structure used herein to characterize layered structures.
[0214] A preferred layered substructure comprises one or more polymers and / or one or more polymer blends, more preferably one or more polyolefins and / or one or more polyolefin blends. For example, the layered substructure may comprise two layers Z1 and Z2, where layer Z1 comprises a first polymer and layer Z2 comprises a blend of the first polymer and the second polymer. The layered substructure may also comprise further components. These further components are preferably components that do not adversely affect the behavior of the layered substructure. These further components may be, for example, inorganic compounds such as metal salts, or further plastics such as further thermoplastics.
[0215] A preferred layer comprises one or more polymers and / or one or more polymer blends, more preferably one or more polyolefins and / or one or more polyolefin blends. The layer may also contain further components. These further components are preferably components that do not adversely affect the behavior of the layer. These further components may be, for example, inorganic compounds such as metal salts, or further plastics such as further thermoplastics.
[0216] Any two "continuous layers" of a layered substructure should be understood as any two layers of a layered substructure arranged in contact with each other.
[0217] In a particularly preferred embodiment of the present invention, layered substructure A and layered substructure B are not laminated to each other. In another particularly preferred embodiment of the present invention, layered substructure B and layered substructure C are not laminated to each other. An example of lamination is to manufacture layered substructures A and B separately, bring layered substructures A and B into contact with each other, and bond layered substructures A and B to each other by adhesive, heat, pressure, or a combination thereof.
[0218] In a preferred embodiment of the present invention, the layered structure comprises four or fewer layers, more preferably three or fewer, and even more preferably two or fewer. In a particularly preferred embodiment of the present invention, the layered structure does not comprise any layers. An example of lamination is to manufacture two layers X and Y separately, bring layers X and Y into contact with each other, and bond layers X and Y together by adhesive, heat, pressure, or a combination thereof.
[0219] A preferred layered substructure is not oriented. The layered substructure can be oriented by subjecting it to one or more stretching steps, which can be performed in the mechanical direction, the transverse direction, or both. The one or more stretching steps are usually performed after the layered substructure has been manufactured. In a preferred embodiment of the present invention, at least one layered substructure, more preferably all of the layered substructures, are not subjected to the stretching steps.
[0220] (Layered substructure A) The layered substructure A has a thickness A and / or density A. In one preferred embodiment of the present invention, the layered substructure A consists of two layers (e.g., layers A1 and A2). In another preferred embodiment of the present invention, the layered substructure A includes at least three layers (e.g., layers A1, A2, and A3). In yet another preferred embodiment of the present invention, the layered substructure A consists of three layers (e.g., layers A1, A2, and A3).
[0221] A preferred layered substructure A is considered by those skilled in the art to impart to the layered structure, more preferably the film, at least one or all of the following properties: rigidity, toughness, function as a moisture barrier, heat resistance, or at least two combinations thereof.
[0222] The layered substructure A, more preferably one or more layers of the layered substructure A, may contain at least one or all of the following: an antiblocking agent, a slip agent, an antistatic agent, and a processing aid.
[0223] If layered substructure A includes layers A1 and A2, layer A1 is positioned further away from layered substructure B than layer A2. If layered substructure A includes layers A1, A2, and A3, layer A1 is positioned further away from layered substructure B than layer A2, and layer A2 is positioned further away from layered substructure B than layer A3.
[0224] Layer A1 of the layered substructure A has a thickness A1 and / or density A1. Layer A2 of the layered substructure A has a thickness A2 and / or density A2. Layer A3 of the layered substructure A has a thickness A3 and / or density A3.
[0225] In a preferred embodiment R1 of the present invention, the cross-sectional portion of the layered substructure A includes layers A1 and A2 arranged in this order, and the difference between the thicknesses A1 and A2 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less.
[0226] In a preferred embodiment R2 of the present invention, the cross-sectional section of the layered substructure A includes layers A1, A2, and A3 arranged in this order, and at least one or all of the following apply: a. The difference between thickness A1 and thickness A2 is 10% or more, preferably 12% or more, more preferably 14% or more, and even more preferably 16% or more, and preferably the difference between thickness A1 and thickness A2 is in the range of 10-20%, more preferably 12-18%. b. The difference between thickness A1 and thickness A3 is 25% or more, preferably 30% or more, more preferably 40% or more, and even more preferably 50% or more, and preferably the difference between thickness A1 and thickness A3 is in the range of 25-70%, more preferably in the range of 30-60%. c. The difference between thickness A2 and thickness A3 is 10% or more, preferably 14% or more, more preferably 18% or more, and even more preferably 22% or more, and preferably the difference between thickness A2 and thickness A3 is in the range of 10 to 35%, more preferably in the range of 20 to 30%. In an embodiment of Embodiment R2, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In a preferred embodiment of Embodiment R2, thickness A1 > thickness A2. In a preferred embodiment of Embodiment R2, thickness A2 > thickness A3. In a preferred embodiment of Embodiment R2, thickness A1 > thickness A2 > thickness A3.
[0227] In a preferred embodiment R3 of the present invention, the cross-sectional section of the layered substructure A includes layers A1, A2, and A3 arranged in this order, and at least one or all of the following apply: a. The difference between thickness A1 and thickness A2 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less. b. The difference between thickness A1 and thickness A3 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less. c. The difference between thickness A2 and thickness A3 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less. In the embodiment of Embodiment R3, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0228] Embodiment R2 is preferred over Embodiment R3.
[0229] In a preferred embodiment R4 of the present invention, the cross-sectional portion of the layered substructure A includes, more preferably consists of, layers A1 and A2 arranged in this order, and the difference between the thicknesses A1 and A2 is 10% or more, preferably 12% or more, more preferably 14% or more, and even more preferably 16% or more, and preferably the difference between the thicknesses A1 and A2 is in the range of 10 to 30%, more preferably 14 to 22%. In embodiment R4, thickness A1 > thickness A2.
[0230] Preferred embodiments R1, R2, and R3 are preferably layered structures comprising at least nine layers, and more preferably nine layers. Preferred embodiments R1 and R4 are preferably layered structures comprising at least seven layers, and more preferably seven layers.
[0231] In a preferred embodiment of the present invention, the layered substructure A comprises two consecutive layers with different densities. For example, the layered substructure A has layers A1, A2, and optionally A3, where layers A1 and A2 are arranged in contact with each other, and layers A2 and A3 (if present) are arranged in contact with each other, and at least one or all of the following apply: density A1 is different from density A2, and / or density A2 is different from density A3 (if present).
[0232] In a preferred embodiment of the present invention, any two consecutive layers of the layered substructure A have different densities. For example, the layered substructure A has layers A1, A2, and optionally A3, where layers A1 and A2 are arranged in contact with each other, and layers A2 and A3 (if present) are arranged in contact with each other, and density A1 is different from density A2, and density A2 is different from density A3 (if present).
[0233] In a preferred embodiment of the present invention, the layered substructure A comprises two continuous layers comprising polyethylene of different densities, each layer comprising at least 60% by weight, more preferably at least 70% by weight, and even more preferably at least 80% by weight of each respective polyethylene. For example, the layered substructure A comprises layers A1, A2, and optionally A3, where layers A1 and A2 are arranged in contact with each other, and layers A2 and A3 (if present) are arranged in contact with each other, and at least one or all of the following apply: layer A1 comprises at least 80% by weight of HDPE, layer A2 comprises at least 80% by weight of LDPE (preferably LLDPE), layer A3 (if present) comprises at least 80% by weight of HDPE.
[0234] In a preferred embodiment of the present invention, any two consecutive layers of the layered substructure A contain polyethylene of different densities, and each layer contains at least 60% by weight, more preferably at least 70% by weight, and even more preferably at least 80% by weight of each respective polyethylene. For example, the layered substructure A has layers A1, A2, and A3, where layers A1 and A2 are arranged in contact with each other, and layers A2 and A3 are arranged in contact with each other, and at least one or all of the following apply: layer A1 contains at least 80% by weight of HDPE, layer A2 contains at least 80% by weight of LDPE (preferably LLDPE), layer A3 contains at least 80% by weight of HDPE.
[0235] The preferred layered substructure A is not oriented.
[0236] (Layered substructure C) The layered substructure C has a thickness C and / or density C. In one preferred embodiment of the present invention, the layered substructure C consists of two layers (e.g., layers C1 and C3). In another preferred embodiment of the present invention, the layered substructure C includes at least three layers (e.g., layers C1, C2, and C3). In yet another preferred embodiment of the present invention, the layered substructure C consists of three layers (e.g., layers C1, C2, and C3).
[0237] A preferred layered substructure C is considered by those skilled in the art to impart to the layered structure, more preferably the film, at least one or all of the following properties: rigidity, toughness, sealing ability, processability, or at least two combinations thereof.
[0238] The layered substructure C, more preferably one or more layers of the layered substructure C (e.g., layer C3), may contain at least one or all of the following: an antiblocking agent, a slip agent, an antistatic agent, and a processing aid.
[0239] In one preferred embodiment of the present invention, the layered substructure C contains less than 1% by weight, more preferably less than 0.5% by weight, and even more preferably less than 0.3% by weight of an antistatic agent, based on the total weight of the layered substructure C. In another preferred embodiment of the present invention, the layered substructure C does not contain an antistatic agent.
[0240] If the layered substructure C includes layers C1 and C3, layer C1 is positioned closer to the layered substructure B than layer C3. If the layered substructure C includes layers C1, C2, and C3, layer C1 is positioned closer to the layered substructure B than layer C2, and layer C2 is positioned closer to the layered substructure B than layer C3.
[0241] Layer C1 of the layered substructure C has a thickness C1 and / or density C1. Layer C2 of the layered substructure C has a thickness C2 and / or density C2. Layer C3 of the layered substructure C has a thickness C3 and / or density C3.
[0242] In a preferred embodiment T1 of the present invention, the cross-sectional portion of the layered substructure C includes layers C1 and C2 arranged in this order, and the difference between the thickness C1 and the thickness C2 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less.
[0243] In a preferred embodiment T2 of the present invention, the cross-sectional section of the layered substructure C includes layers C1, C2, and C3 arranged in this order, and at least one or all of the following apply: a. The difference between thickness C1 and thickness C2 is 18% or less, more preferably 16% or less, even more preferably 14% or less, and even more preferably 12% or less. Preferably, the difference between thickness C1 and thickness C2 is in the range of 6-18%, more preferably 8-14%. b. The difference between thickness C1 and thickness C3 is 20% or more, preferably 30% or more, more preferably 35% or more, and even more preferably 40% or more, and preferably the difference between thickness C1 and thickness C3 is in the range of 25-60%, more preferably in the range of 40-50%. c. The difference between thickness C2 and thickness C3 is 30% or less, preferably 40% or less, more preferably 55% or less, and even more preferably 55% or less, and preferably the difference between thickness C2 and thickness C3 is in the range of 30 to 70%, more preferably 35 to 65%. In an embodiment of Embodiment T2, all possible combinations of features a. to c. are preferred embodiments of the embodiment. These combinations are, for example, a;b;c;a+b;a+c;b+c;a+b+c. In a preferred embodiment of Embodiment T2, thickness C3 > thickness C1. In a preferred embodiment of Embodiment T2, thickness C3 > thickness C2.
[0244] In a preferred embodiment T3 of the present invention, the cross-sectional section of the layered substructure C includes layers C1, C2, and C3 arranged in this order, and at least one or all of the following apply: a. The difference between thickness C1 and thickness C2 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less. b. The difference between thickness C1 and thickness C3 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less. c. The difference between thickness C2 and thickness C3 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less. All possible combinations of features a. to c. represent preferred embodiments of the model. These combinations include, for example, a;b;c;a+b;a+c;b+c;a+b+c.
[0245] Embodiment T2 is preferred over Embodiment T3.
[0246] In a preferred embodiment T4 of the present invention, the cross-sectional portion of the layered substructure C includes layers C1 and C3 arranged in this order, and the difference between the thickness C1 and the thickness C3 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less.
[0247] In a preferred embodiment T5 of the present invention, the cross-sectional portion of the layered substructure C includes layers C1 and C3 arranged in this order, the difference between the thickness C1 and the thickness C3 is 20% or more, more preferably 40% or more, and even more preferably 80% or more, and the difference between the thickness C1 and the thickness C3 is in the range of 20 to 200%, more preferably 40 to 120%. In embodiment T5, thickness C1 < thickness C3.
[0248] Preferred embodiments T1, T2, and T3 are for a layered structure preferably comprising at least nine layers, and more preferably comprising nine layers. Preferred embodiments T4 and T5 are for a layered structure preferably comprising at least seven layers, and more preferably comprising seven layers.
[0249] In a preferred embodiment of the present invention, the layered substructure C comprises two consecutive layers with different densities. For example, the layered substructure C has layers C1 and C3, where layers C1 and C3 are arranged in contact with each other, and density C1 is different from density C3. For example, the layered substructure C has layers C1, C2, and C3, where layers C1 and C2 are arranged in contact with each other, and layers C2 and C3 are arranged in contact with each other, and at least one or all of the following apply: density C1 is different from density C2, and / or density C2 is different from density C3. In a preferred embodiment of this embodiment, density C1 is different from density C2, if present. In a preferred embodiment of this embodiment, density C1 is different from density C3, if present.
[0250] In a preferred embodiment of the present invention, any two consecutive layers of the layered substructure C have different densities. For example, the layered substructure C has layers C1, C2, and C3, where layers C1 and C2 are arranged in contact with each other, layers C2 and C3 are arranged in contact with each other, and density C1 is different from density C2, and density C2 is different from density C3.
[0251] In a preferred embodiment of the present invention, the layered substructure C comprises two consecutive layers containing polyethylene of different densities, each layer containing at least 60% by weight, more preferably at least 70% by weight, and even more preferably at least 80% by weight of each polyethylene. For example, the layered substructure C has layers C1 and C3, where layers C1 and C3 are arranged in contact with each other, layer C1 contains at least 80% by weight of HDPE, and layer C3 contains at least 80% by weight of LDPE (preferably LLDPE). For example, the layered substructure C has layers C1, C2, and C3, where layers C1 and C2 are arranged in contact with each other, and layers C2 and C3 are arranged in contact with each other, layer C1 contains at least 80% by weight of HDPE, and layer C2 contains at least 80% by weight of LDPE (preferably LLDPE).
[0252] The preferred layered substructure C is not oriented.
[0253] (Layered substructure B) The layered substructure B has a thickness B and / or density B. In one preferred embodiment of the present invention, the layered substructure comprises at least two layers (e.g., layers B1 and B2). In another preferred embodiment of the present invention, the layered substructure B consists of two layers (e.g., layers B1 and B2). In yet another preferred embodiment of the present invention, the layered substructure B comprises at least three layers (e.g., layers B1, B2, and B3). In yet another preferred embodiment of the present invention, the layered substructure B consists of three layers (e.g., layers B1, B2, and B3).
[0254] A preferred layered substructure B is considered by those skilled in the art to impart to the layered structure, more preferably the film, at least one or all of the following properties: function as a gas barrier, function as an adhesive, or a combination thereof.
[0255] A preferred layered substructure B includes at least one layer (referred to herein as the gas barrier layer) that is adapted and arranged to function as a gas barrier. The layer B2 is preferably the gas barrier layer.
[0256] A preferred layered substructure B includes at least one layer (referred to herein as an adhesive layer) adapted and arranged to function as an adhesive, more preferably between layered substructure A and layered substructure B, and even more preferably between the gas barrier layer and layered substructure A. A preferred layered substructure B includes at least one layer (referred to herein as an adhesive layer) adapted and arranged to function as an adhesive, more preferably between layered substructure C and layered substructure B, and even more preferably between the gas barrier layer and layered substructure C. It is preferable that at least one or all of B1, B3, or both B1 and B3 are adhesive layers.
[0257] In one preferred embodiment of the present invention, layer B2 is adapted and arranged to function as a gas barrier layer and an adhesive layer. In a preferred aspect of this embodiment, the thickness B2 of layer B2 constitutes at least 90%, more preferably at least 95%, and even more preferably at least 99% of the thickness B of the layered substructure B.
[0258] If layered substructure B includes layers B1 and B2, layer B1 is positioned closer to layered substructure A than layer B2. If layered substructure B includes layers B1, B2, and B3, layer B1 is positioned closer to layered substructure A than layer B2, and layer B2 is positioned closer to layered substructure A than layer B3.
[0259] Layer B1 of the layered substructure B has a thickness B1 and / or density B1. Layer B2 of the layered substructure B has a thickness B2 and / or density B2. Layer B3 of the layered substructure B has a thickness B3 and / or density B3.
[0260] A preferred layered substructure B includes at least one or all of the following: polyamide (PA), polyester, ethylene vinyl alcohol copolymer (EVOH), polyvinyl alcohol (PVOH), polyvinylidene chloride (PVDC), polyethylene terephthalate (PET), polyvinyl chloride, acrylate polymer, methacrylate polymer, polyurethane (PU), polyalkylimine, acid-modified polyolefin, polyether ester-amide block copolymer, or at least two combinations thereof, and more preferably includes at least one layer (e.g., layer B2) made of these materials.
[0261] A preferred layered substructure B includes at least one layer (e.g., layer B2) containing 50% by weight or more, more preferably 60% by weight or more, even more preferably 70% by weight or more, even more preferably 80% by weight or more, even more preferably 90% by weight or more, and even more preferably 95% by weight or more of EVOH, based on the total weight of the at least one layer. A preferred layered substructure B includes at least one layer (e.g., layer B2) consisting of EVOH.
[0262] In a preferred embodiment of the present invention, the layered substructure B includes layers B1, B2, and B3 arranged in this order, and the difference between the thicknesses of B1 and B3 is 10% or less, more preferably 7% or less, even more preferably 4% or less, and even more preferably 2% or less.
[0263] The preferred layered substructure B is not oriented.
[0264] (Gas barrier layer) A preferred gas barrier layer is a gas barrier for oxygen, nitrogen, carbon dioxide, or at least one or all of at least two of these. A preferred gas barrier layer has an oxygen permeability (OTR) of less than 1.5, more preferably less than 1.2, even more preferably less than 0.9, and even more preferably less than 0.6. A preferred gas barrier layer has an OTR in the range of 0.15 to 0.55, more preferably in the range of 0.20 to 0.50, and even more preferably in the range of 0.25 to 0.45.
[0265] Suitable gas barrier layers for the present invention are well known to those skilled in the art. Examples of gas barrier layers include EVOH layers, which are commercially available under trade names such as Evasin™ (e.g., Evasin EV2951F) from SK functional polymers and Eval™ (e.g., EVAL Y171B) from Kuraray Ltd. and / or EVAL Europe NV.
[0266] (adhesive layer) The adhesive layer should preferably be understood as a layer that improves adhesion between layers adjacent to the adhesive layer. A preferred adhesive layer provides adhesion of at least 0.5 N / 15 mm, more preferably at least 0.7 N / 15 mm, and even more preferably at least 0.8 N / 15 mm to adjacent layers. The adhesive preferably comprises at least one polymer, more preferably at least one polymer resin.
[0267] Examples of adhesive layers include bonding layers and adhesion promoter layers. Suitable adhesive layers are well known to those skilled in the art and include, for example, products sold under the trade names Bynel® (e.g., Bynel 41E1353B) available from The Dow Chemical Company, Plexar® (e.g., Plexar PX3060, Plexar PX3236) available from LyondellBasell Industries, and Escor® available from Exxon Mobil Chemical.
[0268] (polymer) The preferred polymer is a thermoplastic polymer, and more preferably a polyolefin. The preferred polymer is easy to process because it exhibits good extrusion behavior. The preferred polymer is obtained by chain polymerization and is particularly polyolefin, with cyclic olefin copolymers (COCs), polycyclic olefin copolymers (POCs), polyethylene and polypropylene being particularly preferred, and polyethylene being exceptionally preferred.
[0269] Preferred polymers have a melt flow index in the range of 0.1 to 20 g / 10 min, more preferably 0.3 to 10 g / 10 min, and even more preferably 0.5 to 5 g / 10 min. Preferred polymers have a melting temperature in the range of 80 to 155°C, more preferably 90 to 145°C, and even more preferably 95 to 135°C.
[0270] The plastomer should preferably be understood as a polymer that combines the qualities of both an elastomer and a plastic, for example, a polymer that combines the rubber-like properties of an elastomer with the processability of a plastic.
[0271] (Polyolefin) Preferred polyolefins are polyethylene (PE), polypropylene (PP), or both. PE is preferred over PP. Preferred polyethylene is selected from the group consisting of LDPE, LLDPE, mLLDPE, HDPE, or at least two combinations thereof. HDPE preferably has a density of 0.940 g / cm³. 3 It should be understood that the above applies. LDPE, LLDPE, and mLLDPE preferably have a density of 0.940 g / cm³. 3 It should be understood that the density is less than 0.950 g / cm³. Preferred HDPE has a density of at least 0.950 g / cm³. 3 That's all.
[0272] LLDPE may be produced using a Ziegler-Natta catalyst. mLLDPE may be produced using a metallocene catalyst.
[0273] Preferred polyethylene has a melt flow index in the range of 0.1 to 10 g / 10 min, more preferably 0.2 to 6 g / 10 min, and even more preferably 0.5 to 3 g / 10 min.
[0274] Suitable commercially available polyolefins for the present invention are well known to those skilled in the art. Examples include Lumicene® (e.g., Lumicene M 6012 AP) available from TotalEnergies SE, Elite® (e.g., Elite 5960g1) and Affinity® (e.g., Affinity PL1860G, Affinity PL1880G) available from The Dow Chemical Company; Exceed® (e.g., Exceed XP 8318ML) and LDPE LD (e.g., LDPE LD 150BW) available from ExxonMobil Chemical; Superer® (e.g., Superer 7118NE) and Cohere® (e.g., Cohere 8102) available from SABIC; Queo® (e.g., Queo 0201FX) available from Borealis AG; and Lupolen® (e.g., Lupolen) available from LyondellBasell Industries. It contains polyolefin sold under the product name 2420F.
[0275] (First polyolefin) The first polyolefin has a melt flow index preferably in the range of 0.3 to 2.0 g / 10 min, more preferably 0.6 to 1.8 g / 10 min, even more preferably 0.8 to 1.6 g / 10 min, and even more preferably 1.0 to 1.4 g / 10 min. The melt flow index of the first polyolefin is measured according to standard ASTM D1238-10.
[0276] The first polyolefin has a secant modulus MD preferably in the range of 600 to 1500 MPa, more preferably 900 to 1200 MPa, even more preferably 1030 to 1150 MPa, and still more preferably 1060 to 1120 MPa. The first polyolefin has a secant modulus TD preferably in the range of 600 to 1700 MPa, more preferably 1410 to 1630 MPa, even more preferably 1460 to 1580 MPa, and still more preferably 1490 to 1550 MPa. Here, the secant modulus should be understood as the 2% secant modulus. The secant modulus (both MD and TD) of the first polyolefin is measured according to standard ASTM D882-18.
[0277] The first polyolefin has an Elmendorf tear strength (MD) in the range of preferably 18-42 g, more preferably 23-37 g, and even more preferably 27-33 g. The first polyolefin has an Elmendorf tear strength (TD) in the range of preferably 38-62 g, more preferably 43-57 g, and even more preferably 47-53 g. The Elmendorf tear strength (both MD and TD) of the first polyolefin is measured according to standard ASTM D1922-15(2020).
[0278] The density of the first polyolefin is measured according to the standard ASTM D792-20.
[0279] (Second polyolefin) The second polyolefin preferably has a melt flow index in the range of 0.1 to 4.0 g / 10 min, more preferably 0.3 to 3.0 g / 10 min, even more preferably 0.5 to 2.5 g / 10 min, and even more preferably 0.65 to 2.00 g / 10 min. The second polyolefin preferably has a melt flow index in the range of 0.3 to 1.2 g / 10 min, more preferably 0.5 to 1.0 g / 10 min, and even more preferably 0.65 to 0.85 g / 10 min. The melt flow index of the second polyolefin is measured according to standard ASTM D1238-10.
[0280] The second polyolefin has a tensile strength MD preferably in the range of 17 to 36 MPa, more preferably 20 to 33 MPa, and even more preferably 23 to 29 MPa. The second polyolefin has a tensile strength TD preferably in the range of 15 to 33 MPa, more preferably 18 to 30 MPa, and even more preferably 21 to 27 MPa. The tensile strength (both MD and TD) of the second polyolefin is measured according to standard ISO 527-1, -3:2018.
[0281] The second polyolefin has a tensile fracture strain MD preferably in the range of 220-380%, more preferably 250-350%, and even more preferably 280-320%. The second polyolefin has a tensile fracture strain TD preferably in the range of 520-680%, more preferably 550-650%, and even more preferably 580-620%. The tensile fracture strain (also known as elongation at break) (both MD and TD) of the second polyolefin is measured according to standard ISO 527-1, -3:2018.
[0282] The second polyolefin has a dart drop impact in the range of preferably 50 to 250 g, more preferably 100 to 200 g, and even more preferably 125 to 175 g. The dart drop impact of the second polyolefin is measured according to standard ASTM D1709-01, method A.
[0283] The second polyolefin has a fracture energy in the range of preferably 2 to 9 J / mm, more preferably 3.5 to 7.5 J / mm, and even more preferably 4.5 to 6.5 J / mm. The fracture energy of the second polyolefin is measured according to standard DIN 53373:1970-09.
[0284] The density of the second polyolefin is measured according to the standard ISO 1183-1:2019.
[0285] (Third polyolefin) The third polyolefin has a melt flow index in the range of preferably 0.1 to 1.3 g / 10 min, more preferably 0.3 to 1.2 g / 10 min, even more preferably 0.6 to 1.1 g / 10 min, and even more preferably 0.75 to 0.95 g / 10 min. The melt flow index of the third polyolefin is measured according to standard ASTM D1238-10.
[0286] The third polyolefin has a secant modulus MD preferably in the range of 150 to 390 MPa, more preferably 170 to 370 MPa, and even more preferably 185 to 355 MPa. The third polyolefin has a secant modulus TD preferably in the range of 185 to 435 MPa, more preferably 205 to 415 MPa, and even more preferably 220 to 400 MPa. Here, the secant modulus should be understood as the 2% secant modulus. The secant modulus (both MD and TD) of the third polyolefin is measured according to standard ASTM D882-18. A.] In preferred embodiment X, the third polyolefin has a secant modulus MD in the range of 150 to 240 MPa, more preferably 170 to 220 MPa, and even more preferably 185 to 205 MPa. In preferred embodiment X, the third polyolefin has a secant modulus TD in the range of 185 to 275 MPa, more preferably 205 to 255 MPa, and even more preferably 220 to 240 MPa. Here, the secant modulus should be understood as the 2% secant modulus. B.] In preferred embodiment Y, the third polyolefin has a secant modulus MD in the range of 300 to 390 MPa, more preferably 320 to 370 MPa, and even more preferably 335 to 355 MPa. In preferred embodiment Y, the third polyolefin has a secant modulus TD in the range of 340 to 435 MPa, more preferably 360 to 415 MPa, and even more preferably 375 to 400 MPa. Here, the secant modulus should be understood as the 2% secant modulus.
[0287] The third polyolefin has a yield tensile strength (MD) preferably in the range of 7.5 to 17.5 MPa, more preferably 8.8 to 16.2 MPa, and even more preferably 9.5 to 15.6 MPa. The third polyolefin has a yield tensile strength (TD) preferably in the range of 8.2 to 17.5 MPa, more preferably 9.5 to 16.2 MPa, and even more preferably 10.2 to 15.6 MPa. The yield tensile strength (both MD and TD) of the third polyolefin is measured according to standard ASTM D882-18. A.] In preferred embodiment X, the third polyolefin has a yield tensile strength (MD) in the range of 7.5 to 12.5 MPa, more preferably 8.8 to 11.2 MPa, and even more preferably 9.5 to 10.6 MPa. In preferred embodiment X, the third polyolefin has a yield tensile strength (TD) in the range of 8.2 to 13.2 MPa, more preferably 9.5 to 11.9 MPa, and even more preferably 10.2 to 11.4 MPa. B.] In preferred embodiment Y, the third polyolefin has a yield tensile strength (MD) in the range of 12.5 to 17.5 MPa, more preferably 13.8 to 16.2 MPa, and even more preferably 14.4 to 15.6 MPa. In preferred embodiment Y, the third polyolefin has a yield tensile strength (TD) in the range of 12.5 to 17.5 MPa, more preferably 13.8 to 16.2 MPa, and even more preferably 14.4 to 15.6 MPa.
[0288] The third polyolefin has a tensile elongation at break (MD) preferably in the range of 350-690%, more preferably 410-640%, and even more preferably 450-590%. The third polyolefin has a tensile elongation at break (TD) preferably in the range of 420-780%, more preferably 480-730%, and even more preferably 520-680%. The tensile elongation at break (both MD and TD) of the third polyolefin is measured according to standard ASTM D882-18. A.] In preferred embodiment X, the third polyolefin has a tensile elongation at break (MD) in the range of 450 to 690%, more preferably 510 to 640%, and even more preferably 550 to 590%. In preferred embodiment X, the third polyolefin has a tensile elongation at break (TD) in the range of 540 to 780%, more preferably 600 to 730%, and even more preferably 640 to 680%. B.] In preferred embodiment Y, the third polyolefin has a tensile elongation at break (MD) in the range of 350 to 590%, more preferably 410 to 540%, and even more preferably 450 to 490%. In preferred embodiment Y, the third polyolefin has a tensile elongation at break (TD) in the range of 420 to 660%, more preferably 480 to 610%, and even more preferably 520 to 560%.
[0289] The third polyolefin is preferably 1 to 35 J / cm³. 3 More preferably 5-30 J / cm² 3 More preferably 9-26 J / cm² 3 The film has puncture resistance within the specified range. A. In preferred embodiment X, the third polyolefin is 10-35 J / cm³. 3 More preferably 15-30 J / cm² 3 More preferably 19-26 J / cm² 3 The film has puncture resistance within the specified range. B.] In preferred embodiment Y, the third polyolefin is 1 to 25 J / cm³. 3 More preferably 5-20 J / cm² 3 More preferably 9-16 J / cm² 3 The film has puncture resistance within the specified range.
[0290] The third polyolefin has a film puncture force preferably in the range of 48 to 140 N, preferably 63 to 125 N, and more preferably 73 to 115 N. A.] In preferred embodiment X, the third polyolefin has a film puncture force in the range of 70 to 140 N, preferably 85 to 125 N, and more preferably 95 to 115 N. B.] In preferred embodiment Y, the third polyolefin has a film puncture force in the range of 48 to 118 N, preferably 63 to 103 N, and more preferably 73 to 93 N.
[0291] The third polyolefin has a dart drop impact in the range of preferably 1300 to 2700 g, more preferably 1600 to 2400 g, and even more preferably 1800 to 2200 g. The dart drop impact of the third polyolefin is measured according to standard ASTM D1709-01, method A. A.] In preferred embodiment X, the third polyolefin has a dart drop impact in the range of 1300 to 2500 g, more preferably 1600 to 2200 g, and even more preferably 1800 to 2000 g. B.] In preferred embodiment Y, the third polyolefin has a dart drop impact in the range of 1500 to 2700 g, more preferably 1800 to 2400 g, and even more preferably 2000 to 2200 g.
[0292] The density of the third polyolefin is measured according to the standard ASTM D792-20.
[0293] (The fourth polyolefin) The fourth polyolefin has a melt flow index in the range of preferably 0.3 to 2.0 g / 10 min, more preferably 0.5 to 1.6 g / 10 min, and even more preferably 0.7 to 1.2 g / 10 min. The melt flow index of the fourth polyolefin is measured according to standard ASTM D1238-10. A.] In preferred embodiment X, the fourth polyolefin has a melt flow index in the range of 0.35 to 1.25 g / 10 min, more preferably 0.55 to 1.05 g / 10 min, and even more preferably 0.70 to 0.90 g / 10 min. B.] In preferred embodiment Y, the fourth polyolefin has a melt flow index in the range of 0.50 to 1.50 g / 10 min, more preferably 0.70 to 1.30 g / 10 min, and even more preferably 0.85 to 1.15 g / 10 min.
[0294] The fourth polyolefin has a secant modulus (MD) preferably in the range of 33 to 100 MPa, more preferably 40 to 93 MPa, and even more preferably 46 to 87 MPa. The fourth polyolefin has a secant modulus (TD) preferably in the range of 37 to 100 MPa, more preferably 44 to 93 MPa, and even more preferably 50 to 87 MPa. Here, the secant modulus should be understood as the 2% secant modulus. The secant modulus (both MD and TD) of the fourth polyolefin is measured according to standard ASTM D882-18. A.] In preferred embodiment X, the fourth polyolefin has a secant modulus (MD) in the range of 65 to 100 MPa, more preferably 72 to 93 MPa, and even more preferably 78 to 87 MPa. In preferred embodiment X, the fourth polyolefin has a secant modulus (TD) in the range of 65 to 100 MPa, more preferably 72 to 93 MPa, and even more preferably 78 to 87 MPa. Here, the secant modulus should be understood as the 2% secant modulus. B.] In preferred embodiment Y, the fourth polyolefin has a secant modulus (MD) in the range of 33 to 69 MPa, more preferably 40 to 62 MPa, and even more preferably 46 to 56 MPa. In preferred embodiment Y, the fourth polyolefin has a secant modulus (TD) in the range of 37 to 73 MPa, more preferably 44 to 66 MPa, and even more preferably 50 to 60 MPa. Here, the secant modulus should be understood as the 2% secant modulus.
[0295] The fourth polyolefin has a yield strength (MD) preferably in the range of 4.0 to 8.2 MPa, more preferably 5.0 to 7.2 MPa, and even more preferably 5.5 to 6.4 MPa. The fourth polyolefin has a yield strength (TD) preferably in the range of 3.7 to 8.6 MPa, more preferably 4.7 to 7.6 MPa, and even more preferably 5.2 to 6.8 MPa. The yield strength (both MD and TD) of the fourth polyolefin is measured according to standard ASTM D882-18. A.] In preferred embodiment X, the fourth polyolefin has a yield tensile strength (MD) in the range of 4.0 to 8.0 MPa, more preferably 5.0 to 7.0 MPa, and even more preferably 5.5 to 6.2 MPa. In preferred embodiment X, the fourth polyolefin has a yield tensile strength (TD) in the range of 3.7 to 7.7 MPa, more preferably 4.7 to 6.7 MPa, and even more preferably 5.2 to 5.9 MPa. B.] In preferred embodiment Y, the fourth polyolefin has a yield tensile strength (MD) in the range of 4.1 to 8.2 MPa, more preferably 5.1 to 7.2 MPa, and even more preferably 5.6 to 6.4 MPa. In preferred embodiment Y, the fourth polyolefin has a yield tensile strength (TD) in the range of 4.6 to 8.6 MPa, more preferably 5.6 to 7.6 MPa, and even more preferably 6.1 to 6.8 MPa.
[0296] The fourth polyolefin has a tensile elongation at break (MD) preferably in the range of 280-660%, more preferably 320-620%, and even more preferably 370-570%. The fourth polyolefin has a tensile elongation at break (TD) preferably in the range of 350-750%, more preferably 420-680%, and even more preferably 470-630%. The tensile elongation at break (both MD and TD) of the fourth polyolefin is measured according to standard ASTM D882-18. A.] In preferred embodiment X, the fourth polyolefin has a tensile elongation at break (MD) in the range of 280 to 500%, more preferably 320 to 460%, and even more preferably 370 to 410%. In preferred embodiment X, the fourth polyolefin has a tensile elongation at break (TD) in the range of 350 to 650%, more preferably 420 to 580%, and even more preferably 470 to 530%. B.] In preferred embodiment Y, the fourth polyolefin has a tensile elongation at break (MD) in the range of 440 to 660%, more preferably 480 to 620%, and even more preferably 530 to 570%. In preferred embodiment Y, the fourth polyolefin has a tensile elongation at break (TD) in the range of 450 to 750%, more preferably 520 to 680%, and even more preferably 570 to 630%.
[0297] The fourth polyolefin preferably has a film puncture resistance of 1 to 45 J / cm³, more preferably 5 to 40 J / cm³, and even more preferably 7 to 35 J / cm³. A.] In preferred embodiment X, the fourth polyolefin is 15-45 J / cm³, more preferably 20-40 J / cm³ 3 More preferably 25-35 J / cm 3 The film has puncture resistance within the specified range. B.] In preferred embodiment Y, the fourth polyolefin is 1 to 25 J / cm³. 3 , more preferably 5 to 18 J / cm² 3 More preferably 7-13 J / cm 3 The film has puncture resistance within the specified range.
[0298] The fourth polyolefin has a film puncture force preferably in the range of 48 to 140 N, preferably 63 to 125 N, and more preferably 73 to 115 N. A.] In preferred embodiment X, the fourth polyolefin has a film puncture force in the range of 30 to 85 N, preferably 45 to 70 N, and more preferably 52 to 63 N. B.] In preferred embodiment Y, the fourth polyolefin has a film puncture force in the range of 21 to 76 N, preferably 36 to 61 N, and more preferably 43 to 54 N.
[0299] The fourth polyolefin has a dart drop impact in the range of preferably 400 to 1200 g, more preferably 550 to 1050 g, and even more preferably 700 to 900 g. The dart drop impact of the fourth polyolefin is measured according to standard ASTM D1709-01, method B.
[0300] The density of the fourth polyolefin is measured according to the standard ASTM D792-20.
[0301] (The fifth polyolefin) The fifth polyolefin has a melt flow index preferably in the range of 0.3 to 2.0 g / 10 min, more preferably 0.5 to 1.6 g / 10 min, and even more preferably 0.7 to 1.3 g / 10 min. The melt flow index of the fifth polyolefin is measured according to standard ASTM D1238-10.
[0302] The density of the fifth polyolefin is measured according to the standard ASTM D792-20.
[0303] (Antiblocking agents, slip agents, antistatic agents, coloring agents) Suitable antiblocking agents for the present invention are well known to those skilled in the art. Suitable antiblocking agents may include organic materials such as amide waxes, stearates, silicones, polytetrafluoroethylenes, and erucamides. Suitable antiblocking agents may also include inorganic materials such as talc, calcium carbonate, natural silica, and synthetic silica.
[0304] Suitable slip agents for the present invention are well known to those skilled in the art. Suitable slip agents may include, for example, one or more amides (such as erucamide) and / or one or more siloxanes (such as polydimethylsiloxane) and / or one or more oleamides.
[0305] Suitable antistatic agents for the present invention are well known to those skilled in the art. Suitable antistatic agents may include, for example, long-chain aliphatic amines (optionally ethoxylated) and amides, quaternary ammonium salts (e.g., behentrimonium chloride or cocamidopropyl betaine), phosphate esters, polyethylene glycol esters, polyols, long-chain alkylphenols, ethoxylated amines, glycerol fatty acid esters (such as glyceryl monostearate), and at least two combinations thereof.
[0306] One or more coloring means may be added to one or more layers of the layered structure. Suitable coloring means for the present invention are well known to those skilled in the art. Preferred coloring means include pigments. Suitable pigments are well known to those skilled in the art. For example, titanium dioxide may be used to obtain white, carbon black to obtain black, and ultramarine blue to obtain blue. An example of a coloring means is a color masterbatch. When the layered structure contains at least one coloring means, the density is 0.940 g / cm³. 3 It is preferable to add the coloring means to one or more layers containing at least 75% by weight of one or more polyolefins, which is less than 100%. For example, the coloring means is added to one or more layers containing at least 75% by weight of LDPE, more preferably LLDPE. For example, the coloring means is added to layer A2, C2, or both A2 and C2.
[0307] (Preferred embodiment) Embodiment E1 of the present invention is a container for containing a product, wherein the container is a. An internal volume adapted and arranged to accommodate the aforementioned product, b. A first side wall, wherein the first side wall is i. The first edge and, ii. A first surface and a further surface opposite to the first surface, the further surface facing the internal volume, the first surface and the further surface, iii. Film, A. The film comprises at least 30%, preferably at least 50%, more preferably at least 70%, and even more preferably at least 90% of the thickness of the first side wall. B. The film comprises a film having a layered structure, The first side wall and, c. A further side wall opposite to the first side wall, the further side wall having a first edge connected to the first edge of the first side wall, Equipped with, The cross-sectional portion of the layered structure comprises at least five layers, and these at least five layers are A.] Layered substructure A, which includes at least two layers. B.] Layered substructure B, which includes at least one layer. C.] A layered substructure C, comprising at least two layers, is arranged as follows: Here I. The layered substructure B is positioned between the layered substructure A and the layered substructure C. II. The layered substructure C is positioned closer to the internal volume of the container compared to the layered substructure A. The first side wall comprises less than 20% by weight, preferably less than 15% by weight, more preferably less than 10% by weight, and even more preferably less than 5% by weight of paper, cardboard, or both. The thickness A of the layered substructure A is less than or equal to the thickness C of the layered substructure C, and preferably less than the thickness C.
[0308] In a preferred embodiment of Embodiment E1, the film comprises at least seven layers, more preferably at least nine layers. In another preferred embodiment of Embodiment E1, the film consists of seven or nine layers.
[0309] Embodiment E2 of the present invention is a container for containing a product, wherein the container is a. An internal volume adapted and arranged to accommodate the aforementioned product, b. A first side wall, wherein the first side wall is i. The first edge and, ii. A first surface and a further surface opposite to the first surface, the further surface facing the internal volume, the first surface and the further surface, iii. Film, A. The film comprises at least 30%, preferably at least 50%, more preferably at least 70%, and even more preferably at least 90% of the thickness of the first side wall. B. The film has a layered structure, A first side wall comprising, c. A further side wall opposite to the first side wall, the further side wall having a first edge connected to the first edge of the first side wall, Equipped with, The cross-sectional portion of the layered structure comprises at least five layers, and these at least five layers are A.] Layered substructure A, which includes at least two layers with different densities. B.] Layered substructure B, which includes at least one layer. C.] A layered substructure C, comprising at least two layers with different densities, is arranged as follows: I. The layered substructure B is positioned between the layered substructure A and the layered substructure C. II. The layered substructure C is positioned closer to the internal volume of the container compared to the layered substructure A. The first side wall comprises less than 20% by weight, preferably less than 15% by weight, more preferably less than 10% by weight, and even more preferably less than 5% by weight of paper, cardboard, or both.
[0310] In a preferred embodiment of Embodiment E2, the film comprises at least seven layers, more preferably at least nine layers. In another preferred embodiment of Embodiment E2, the film consists of seven or nine layers.
[0311] Embodiments 1 to 55, as well as their preferred embodiments, are preferred embodiments and preferred embodiments of Embodiments E1 and E2.
[0312] (Manufacturing of layered structures) The layered structures and / or films according to the present invention can be manufactured using any means deemed suitable by those skilled in the art. This includes extrusion, lamination, and combinations thereof. The layered structures and / or films according to the present invention are preferably manufactured using an extrusion method, more preferably a co-extrusion method. In one particularly preferred embodiment of the present invention, the layered structures and / or films according to the present invention are manufactured using a method that does not include a lamination step. Suitable extrusion methods and apparatus for manufacturing the layered structures and / or films according to the present invention are well known to those skilled in the art. Therefore, any extrusion method and apparatus deemed suitable for the present invention by those skilled in the art can be used. For example, the layered structures and / or films can be manufactured using inflation film extrusion and / or cast film extrusion. Apparatus suitable for extrusion is commercially available from, for example, Windmoeller & Hoelscher KG (e.g., VAREX II 9-layer co-extrusion line), Reifenhaeuser GmbH & Co. KG, and Hosokawa Alpine AG.
[0313] (Test method) The following test methods were used within the context of the present invention. Unless otherwise specified, measurements were performed at an ambient temperature of 23°C, an ambient air pressure of 100 kPa (0.986 atm), and a relative air humidity of 50%. When measuring the properties of a film (or layered structure), the sample was taken from an area of the film (or layered structure) that was groove-free and unfolded.
[0314] (composition) The layered structure and the chemical composition of the film are determined as follows: A 1 cm × 1 cm sample of the film (or layered structure) is cut perpendicular to the layers of the film (or layered structure). The sample is then prepared using a Tegramin-25 polishing machine, commercially available from Struers. The polishing step removes irregularities and deformations from the surface of the sample. After polishing, the sample is irradiated with infrared light using a Spotlight 400 FT-IR imaging system, commercially available from Perkin Elmer Inc. The transmittance of each layer of the film (or layered structure) is measured as a function of wavenumber (i.e., a graph showing the transmittance as a function of wavenumber is created). The graph reaches 1377 cm⁻¹. -1 If a peak is observed, polyethylene (HDPE, LLDPE, LDPE) is present. -1 range and / or 3300~3500cm -1 If a peak is observed within this range, EVOH is present. 1462cm -1 The peak indicates the presence of polypropylene.
[0315] (density) Unless otherwise specified, density shall be measured according to standard D792-20.
[0316] (layer thickness) The thickness of each layer, layered structure, and film is measured perpendicular to the respective layer, layered structure, and film.
[0317] 0.5cm 2A sample of a film (or layered structure) having a certain area is provided. A cross-sectional section is then made through the sample using a Leica Microtome 3050S. Before cross-sectional cutting, the sample is rapidly frozen in liquid nitrogen and stabilized at -30°C using a commercially available temperature control system from Linkam Scientific Instruments Ltd. The thickness of each individual layer of the sample is then measured using an Olympus BX51 optical microscope. The microscope generates a cross-sectional image, which is then analyzed using software provided with the microscope. Layer boundaries are marked in the image, and the software determines the thickness of the layer.
[0318] (Parameter ratio) The ratio of parameter P1 to parameter P2 is determined as follows: =P1 / P2. Here, parameters P1 and P2 can be, for example, the thicknesses of two layered substructures.
[0319] (Meltflow Index) Unless otherwise specified, the melt flow index (also known as the melt flow rate or melt index) is measured according to the standard ASTM D1238-10.
[0320] (Melting temperature) The melting temperature of the layers is determined according to the standard DIN EN ISO 11357-3:2011(E), which refers to the DSC method. The DSC method used is described below.
[0321] (Differential Scanning Calorimetry (DSC)) DSC measurement is performed as follows:
[0322] Sample preparation for differential scanning calorimetry (DSC): At least 1.0 mg of the sample is weighed using a Kern 770 precision balance from Kern & Sohn GmbH (Balingen, Germany). For this purpose, an empty DSC pan is tare-weighted on the balance, followed by the weighing of the sample. The pan is then sealed with a lid using a press. The lid should have small holes to prevent deformation of the pan during DSC measurement. The sample and crucible must not be deformed during DSC measurement. Care must be taken not to touch the sample or crucible with bare hands during sample preparation.
[0323] (Differential Scanning Calorimetry (DSC)): Differential scanning calorimetry is performed according to the standard DIN EN ISO 11357-1 (version 11357-1:2010-03). The following details are applied in addition to or in deviation from the standard. The calorimeter is a PerkinElmer Inc. DSC 8000. In the DSC method, heat flow is measured as a function of temperature. Therefore, the graph of the measurement is shown with heat flow (dQ / dt) as a function of the vertical axis and temperature (T) as a function of the horizontal axis. The endothermic direction is always upward, as noted in Note 2 of Section 3.1 of DIN EN ISO 11357-1:2010-03. Differential calorimetry of heat flow is performed according to Section 4.2 of the standard DIN EN ISO 11357-1:2010-03. In this case, the reference crucible is always empty, and the reference position is always used for temperature, in accordance with Section 3.10 of DIN EN ISO 11357-1:2010-03. Nevertheless, the reference crucible must always be used. The flushing gas used (Sections 5.5 and 9.1.2 of DIN EN ISO 11357-1:2010-03) is nitrogen. Before each measurement, the DSC instrument is calibrated using indium and zinc (according to Annex C of DIN EN ISO 11357-1:2010-03), which are the calibrating materials (Sections 3.2 and 5.4 of DIN EN ISO 11357-1:2010-03), in accordance with Sections 8.2 to 8.4 of DIN EN ISO 11357-1:2010-03. As recommended in DIN EN ISO11357-1:2010-03, 8.4.2, thermal calibration is performed using indium as the calibrator. The crucible is supplied to the calorimeter via an autosampler. Details about the sample (name, weight, measurement method, position on the autosampler, storage location (memory location)) are entered via an editor. The measurement is performed in dynamic mode (DIN EN ISO11357-1:2010-03, 3.9.5). In this case, the sample is first pre-treated by heating from 35°C to 160°C at a rate of 20°C / min and maintaining the temperature for 1 minute. The sample is then cooled to 35°C at a rate of 2°C / min. The measurement process is then carried out to 160°C at a heating rate of 20°C / min.
[0324] (evaluation:) For the evaluation of the measurement, only the second heating curve described above is used. The curve can be selected under the menu "curves," and then under "heat flow." The selected curve is colored blue, and the rest of the data is red and can be removed via "remove curve." The melting temperature can then be determined from the data by selecting "peak area" in the "calc" menu. The peaks are marked and then automatically evaluated. The sample has exactly the same number of melting temperatures as the number of endothermic peaks in its second heating curve. If the sample has multiple peaks, i.e., multiple melting temperatures, when a single melting temperature is referred to herein, it means the one with the lowest temperature.
[0325] (Oxygen transmission rate (OTR)) The OTR of the film is determined according to the standard ASTM D3985-05 (2010). The film sample to be tested is taken from a groove-free, unfolded area of the film. The sample area is 50 cm². 2 The measurement is performed at an ambient temperature of 23°C and an ambient air pressure of 100 kPa (0.986 atm). The test equipment is the Ox-Tran 2 / 22, commercially available from Amatek Mocon. The measurement is performed without compressed air correction. A sample at ambient temperature is used for the measurement. One side of the sample (the first outer surface) is set to 0% oxygen and 90% relative humidity, while the opposite side of the sample (the further outer surface) is set to 100% oxygen and 50% relative humidity. Further settings and factors affecting the measurement (in particular, the remaining ones listed in point 16 of standard ASTM D3985-05 (2010)) are defined by the equipment used and the proper use and maintenance of the equipment in accordance with the manufacturer's handbook.
[0326] The layered structure, layered substructure, and layer OTR are determined for the film as described above.
[0327] (Tensile strength and elongation at fracture) Unless otherwise specified, tensile strength (both MD and TD) shall be measured according to standard ISO 527-1,-3:2018. Unless otherwise specified, elongation at break (also known as tensile fracture strain or tensile fracture elongation) (both MD and TD) shall be measured according to standard ISO 527-1,-3:2018.
[0328] (Drop test) To test a specific layered structure, 100 pouches are provided, each having a first sidewall, a further sidewall, and a bottom made from a layered structure (i.e., the sidewall and bottom are made from a film, which is then made from a layered structure). Each pouch is then filled with a liquid product of its nominal capacity. The pouches are then dropped from a height of 1.2 m. 50 pouches are dropped so that they land bottom-first. The remaining 50 pouches are dropped so that they land either on the first sidewall or the further sidewall. A pouch fails the drop test if any damage, such as a tear, is observed in the sidewall or bottom. The number of undamaged pouches indicates a pass in the drop test.
[0329] In the above, the nominal capacity is defined as the capacity for which the pouch is designed. For example, if a pouch is designed to hold 100 ml of liquid or paste, then 100 ml is defined as the nominal capacity of the pouch.
[0330] (Film puncture strength) Unless otherwise specified, film puncture force (also known as average puncture force) is measured according to the standard ASTM D5748-95:2019.
[0331] (Impact of darts falling) Unless otherwise specified, the impact of a dart drop shall be measured according to standard ASTM D1709-01, method A.
[0332] Herein, the present invention will be described by non-limiting examples and exemplary embodiments. [Brief explanation of the drawing]
[0333] The drawings serve to illustrate the present invention and should not be considered to limit it. The drawings are not drawn to scale.
[0334] [Figure 1A] This is a schematic diagram showing a cross-sectional view of a first embodiment of the layered structure according to the present invention. [Figure 1B] This is a schematic diagram showing a cross-sectional view of a second embodiment of the layered structure according to the present invention. [Figure 2A] This is a schematic diagram of a cross-section of the container according to the present invention, viewed from the side. [Figure 2B] This is a schematic diagram of the container according to the present invention, viewed from the front. [Figure 3] This is a flowchart of the method according to the present invention for manufacturing the film according to the present invention. [Figure 4] This is a flowchart of the method according to the present invention for manufacturing a container according to the present invention. [Modes for carrying out the invention]
[0335] (Drawing description) The drawings will be explained in more detail below.
[0336] (Figure 1A) Figure 1A is a schematic diagram showing a cross-sectional view of a first embodiment of the layered structure 100a according to the present invention. The cross-sectional view is taken perpendicular to the layers of the layered structure. As can be seen in Figure 1A, the layered structure has nine layers 101a to 109a.
[0337] Layer 101a contains at least 88% by weight of HDPE (e.g., a first polyolefin). Optionally, layer 101a may also contain 10% by weight or less of LLDPE (e.g., a second polyolefin). Layer 102a is placed in contact with layer 101a and is made from LLDPE (e.g., a third polyolefin). Layer 103a is placed in contact with layer 102a and is made from HDPE (e.g., a first polyolefin).
[0338] Both layers 104a and 106a contain maleic anhydride-modified PE. Layers 104a and 106a are fitted and positioned to function as adhesive layers (e.g., bonding layers). Layer 105a is positioned between layers 104a and 106a. Layer 105a is made from ethylene vinyl alcohol copolymer (EVOH). Layer 105a is positioned in contact with layers 104a and 106a. Layer 104a is positioned in contact with layer 103a, and layer 106a is positioned in contact with layer 107a.
[0339] Layer 107a is made from HDPE (e.g., a first polyolefin). Layer 108a is placed in contact with layer 107a and is made from LLDPE (e.g., a third polyolefin). Layer 109a, placed in contact with layer 108a, contains a blend of LLDPE (e.g., a blend of a second polyolefin, a third polyolefin, and a fourth polyolefin). The LLDPE blend constitutes at least 90% by weight of layer 109a. Layer 109a may further contain additives such as an antiblocking masterbatch and a slip masterbatch.
[0340] The layered structure 100a may include a color masterbatch added to one or more of the layers of the layered structure 100a. For example, the color masterbatch may be added to layer 102a, layer 108a, or both layers 102a and 108a.
[0341] Layers 101a, 102a, and 103a form part of the layered substructure A110a. Layer 101a is an example of layer A1, layer 102a is an example of layer A2, and layer 103a is an example of layer A3. Layers 104a, 105a, and 106a form part of the layered substructure B111a. Layer 104a is an example of layer B1, layer 105a is an example of layer B2, and layer 106a is an example of layer B3. Layers 107a, 108a, and 109a form part of the layered substructure C112a. Layer 107a is an example of layer C1, layer 108a is an example of layer C2, and layer 109a is an example of layer C3.
[0342] Figure 1A also shows that the layered substructure A110a has a thickness A smaller than the thickness C of the layered substructure C112a. This is preferable but not required. Both thickness A and thickness C are greater than the thickness B of the layered substructure B111a. This is preferable but not required.
[0343] In one preferred embodiment, layer 102a has a thickness greater than the thickness of layer 101a and / or layer 103a, more preferably greater than the thickness of both layers 101a and 103a. In one preferred embodiment, layer 109a has a thickness greater than the thickness of layer 107a and / or layer 108a, more preferably greater than the thickness of both layers 107a and 108a. In one preferred embodiment, the thickness of layer 107a and / or layer 108a, preferably the thickness of both layers 107a and 108a, is greater than the thickness of layer 101a. In one preferred embodiment, the thickness of layer 107a and / or layer 108a, preferably the thickness of both layers 107a and 108a, is greater than the thickness of layer 102a. In one preferred embodiment, the thickness of layer 107a and / or layer 108a, preferably the thickness of both layers 107a and 108a, is greater than the thickness of layer 103a. In one preferred embodiment, the thicknesses of layers 107a and 108a are greater than the thicknesses of layers 101a, 102a, and 103a. The difference in thickness between layers 104a and 106a is preferably less than 10%.
[0344] The layered structure 100a has a first surface 113a formed by the surface of layer 101a and a further surface 114a formed by the surface of layer 109a. The layered structure 100a is also asymmetric, for example, with respect to layer 105a. For example, the layer arrangement when moving from layer 105a toward the first surface 113a is different from the layer arrangement when moving from layer 105a toward the further surface 114a. This asymmetry is in the composition of layers 101a to 109a. This asymmetry is also preferable in terms of the thickness of layers 101a to 109a.
[0345] (Figure 1B) Figure 1B is a schematic diagram showing a cross-sectional view of a second embodiment of the layered structure 100b according to the present invention. The cross-sectional view is taken perpendicular to the layers of the layered structure. As can be seen in Figure 1B, the layered structure has seven layers 101b, 102b, 104b, 105b, 106b, 107b, and 109b.
[0346] Layer 101b comprises at least 95% by weight of HDPE (e.g., a first polyolefin). Layer 102b is disposed in contact with layer 101b and comprises at least 98% by weight of LLDPE (e.g., a third polyolefin).
[0347] Both layers 104b and 106b contain maleic anhydride-modified PE. Layers 104b and 106b are also fitted and positioned to function as adhesive layers (e.g., bonding layers). Layer 105b is positioned between layers 104b and 106b. Layer 105b is made from ethylene vinyl alcohol copolymer (EVOH). Layer 105b is positioned in contact with layers 104b and 106b. Additionally, layer 104b is positioned in contact with layer 102b, and layer 106b is positioned in contact with layer 107b.
[0348] Layer 107b comprises at least 98 wt% HDPE (e.g., a first polyolefin). Layer 109b, positioned in contact with layer 107b, comprises a blend of LLDPE (e.g., a blend of a third polyolefin and a fifth polyolefin). The LLDPE blend constitutes at least 97 wt% of layer 109b. Layer 109b may further contain additives such as an antiblocking masterbatch and a slip masterbatch.
[0349] The layered structure 100b may include a color masterbatch added to one or more of the layers of the layered structure 100b. For example, a color masterbatch may be added to layer 102b.
[0350] Layers 101b and 102b form part of the layered substructure A110b. Layer 101b is an example of layer A1, and layer 102b is an example of layer A2. Layers 104b, 105b, and 106b form part of the layered substructure B111b. Layer 104b is an example of layer B1, layer 105b is an example of layer B2, and layer 106b is an example of layer B3. Layers 107b and 109b form part of the layered substructure C112b. Layer 107b is an example of layer C1, and layer 109b is an example of layer C3.
[0351] Figure 1B also shows that the layered substructure A110b has a thickness A smaller than the thickness C of the layered substructure C112b. This is preferable but not required. Both thickness A and thickness C are greater than the thickness B of the layered substructure B111b. This is preferable but not required.
[0352] In a preferred embodiment, layer 102b has a thickness less than the thickness of layer 101b. In a preferred embodiment, layer 109b has a thickness greater than the thickness of layer 107b. In a preferred embodiment, the thickness of layer 107b is less than the thickness of layer 101b. In a preferred embodiment, the difference in thickness between layers 102b and 107b is less than 10%. Preferably, the difference in thickness between layers 104b and 106b is less than 10%.
[0353] The layered structure 100b has a first surface 113b formed by the surface of layer 101b and a further surface 114b formed by the surface of layer 109b. The layered structure 100b is also asymmetric, for example, with respect to layer 105b. For example, the layer arrangement when moving from layer 105b toward the first surface 113b is different from the layer arrangement when moving from layer 105b toward the further surface 114b. This asymmetry is in the composition of layers 101b to 109b. This asymmetry is also preferable in terms of the thickness of layers 101b to 109b.
[0354] (Figures 2A and 2B) Figure 2A is a schematic cross-sectional view of the container 200 according to the present invention, viewed from the side. The container 200 has an internal volume 201, which is formed between a first side wall 204, a further side wall 207 (side walls 204 and 207 partially enclose the internal volume 201), and a bottom 210. The container 200 also has a spout 202 (discharge means) for discharging the contents of the container 200. The discharge means 202 can be closed by a closing means 203, such as a screw cap. Taking the first side wall 204 as an example, the first side wall 204 has a first surface 205 and a further surface 206 (opposite the first surface 205). The further surface 206 faces the internal volume 201.
[0355] The first side wall 204 and the further side wall 207 are made from a film having a layered structure 100a or a layered structure 100b, as shown in Figures 1A and 1B, respectively. Layers 109a / 109b of the layered structure 100a / 100b are positioned closer to the internal volume 201 compared to layers 101a / 101b. Further surfaces 114a / 114b of the layered structure 100a / 100b form further surfaces 206 of the container 200 (i.e., layers 109a / 109b form further surfaces 206). The first surfaces 113a / 113b of the layered structure 100a / 100b may form the first surface 205 of the container 200 (i.e., layers 101a / 101b form the first surface 205), but the container 200 may also have a coating layer, for example, containing lacquer, and a printing layer containing ink, superimposed on the first surface 113a / 113b of the layered structure 100a / 100b. In the latter embodiment, either the surface of the printing layer or the coating layer may form the first surface 205 of the container 200.
[0356] The above films will be described using the layered structures 100a and 100b shown in Figures 1A and 1B, respectively. Please note that the layered structures 100a and 100b are examples of layered structures according to the present invention. Other layered structures according to the present invention can also be used in films.
[0357] Figure 2B is a schematic diagram of the container 200 according to the present invention as seen from the front. The first side wall 204 and further side walls are connected by the first edge 208 and further edge 209 to form the interior of the container 200.
[0358] (Figures 3 and 4) Figure 3 is a flowchart of method 300 according to the present invention for producing a film according to the present invention. In step 301, at least seven layers are simultaneously extruded using inflation film extrusion to obtain a film comprising at least seven layers. The at least seven layers have the following layered substructure: A. A layered substructure A comprising at least two layers A1 and A2, and optionally layer A3, i. Layer A1 has a density of 0.940 g / cm³ 3 Including the above HDPE, ii. Layer A2 has a density of 0.940 g / cm³ 3 Contains less than LLDPE, iii. If layer A3 is present, its density is 0.940 g / cm³. 3 Layered substructure A containing the above HDPE, B. A layered substructure B comprising layers B1, B2, and B3, i. Layers B1 and B3 are adhesive layers (also known as bonding layers), ii. Layer B2 is a layered substructure B containing EVOH, C. A layered substructure C comprising at least two layers C1 and C3, and optionally layer C2, i. Layer C1 has a density of 0.940 g / cm³ 3 Including the above HDPE, ii. If layer C2 is present, its density is 0.940 g / cm³. 3 Contains less than LLDPE, iii. Layer C3 has a density of 0.940 g / cm³ 3 A layered substructure C containing at least one LLDPE less than, They are placed. Layered substructure B is positioned between layered substructure A and layered substructure C.
[0359] Figure 4 is a flowchart of method 400 according to the present invention for similarly manufacturing a container according to the present invention. In step 401, a film according to the present invention is provided. The film can be obtained using the method described above with respect to Figure 3. In step 402, the film is folded to generate a first side wall and further side walls of a container, the side walls at least partially defining (e.g., enclosing) the internal volume of the container. At least one edge of the first side wall (e.g., the first edge) is connected to at least one edge of the further side wall. In an optional step 403, a discharge means such as a spout is incorporated into the container. [Examples]
[0360] The present invention will be further described by examples. The present invention is not limited to these examples.
[0361] In the following examples, spouted pouches (containers) with side walls made from films having different layered structures were investigated. The same layered structure is used for both the first and further side walls of each pouch, as well as for the bottom of each pouch. The films consist of a layered structure, and each film constitutes at least 97% of the thickness of the side walls and bottom of each pouch.
[0362] Layers C1-C3 are positioned closer to the internal volume of each container compared to layers A1-A3. Layers B1 and B3 are adhesive layers (binding layers) made of maleic anhydride-modified polyethylene. Layer B2 is made of EVOH.
[0363] (Example 1) Table 1 shows the different layered structures used in Example 1 and their effects on the spouted pouch. Unless otherwise stated, each layer contains 100% by weight of the components shown in Table 1. Where indicated, additives in the form of slip agents, antiblocking agents, and coloring pigments constitute approximately 6.5% by weight of the layer. The thickness of layer A1 varies by less than 5% among the examples in Table 1. This also applies to layers A2-C3.
[0364] Examples 1.1 to 1.5 are particularly preferred embodiments of the present invention.
[0365] The technical effects in Table 1 are as follows: • Puncture resistance: The pouch's resistance to punctures by sharp objects. "+" indicates high puncture resistance, and "-" indicates low puncture resistance. Improving puncture resistance is desirable. • Drop test: The pouch's resistance to damage when dropped or when pressure is applied to the pouch. "+" indicates high resistance to damage, and "-" indicates low resistance to damage. Improving resistance to damage is desirable. • Heat resistance: The pouch's resistance to damage when heat is applied, especially to its outer surface. "+" indicates high resistance, and "-" indicates low resistance. Increased resistance to heat damage is desirable. • Sealing temperature: The temperature required to seal the pouch by connecting the sections on the inner surface of the pouch and applying heat and pressure to those sections. "+" indicates that a lower temperature is required, and "-" indicates that a higher temperature is required. Furthermore, "++++" indicates a lower temperature compared to, for example, "+", and "----" indicates a higher temperature compared to "-". It is desirable to reduce the temperature required for sealing. • Stiffness: The rigidity of the pouch. A "+" indicates high stiffness, while a "-" indicates low stiffness. Generally, increasing stiffness is desirable. • OTR: Oxygen permeability rate through the sidewall of the pouch. "+" indicates a low OTR, and "-" indicates a high OTR. Furthermore, "++++" indicates a lower OTR compared to, for example, "+", and "----" indicates a higher OTR compared to "-". Reducing OTR is desirable. [Table 1(1)] [Table 1(2)]
[0366] (Example 2) Example 2 provides a pouch having a layered structure according to Example 1.4. In this example, the thicknesses of layered substructures A and C are varied as shown in Table 2. Layered substructure A has a thickness A, and layered substructure C has a thickness C. The thickness of the layered structure varies by less than 5% between Examples 2.1 to 2.3. Furthermore, the thickness of layered substructure B also varies by 8% between Examples 2.1 to 2.3. [Table 2]
[0367] The technical effects in Table 2 are the same as those given in Table 1 above.
[0368] By repeating the steps in Examples 2.1 to 2.3 using a pouch having a layered structure as described in any of Examples 1.1 to 1.3 and 1.5 to 1.10, similar results to those shown in Table 2 can be obtained. [Explanation of Symbols]
[0369] 100a,b Layered structure 101a,b Layer A1 102a,b Layer A2 103a, layer A3 104a,b Layer B1 105a,b Layer B2 106a,b Layer B3 107a,b Layer C1 108a, layer C2 109a,b Layer C3 110a,b Layered substructure A 111a,b Layered substructure B 112a,b Layered substructure C 113a,b First surface of the layered structure 114a,b Further surface of the layered structure 200 containers 201 Internal volume 202 Spout 203 Cap 204 First side wall 205 First side wall / first surface of container 206 Further surface of the first side wall / container 207 Further side walls 208 First edge 209 Further edges 210 Bottom
Claims
1. A container (200) for containing the product, wherein the container (200) is a. An internal volume (201) adapted and arranged to accommodate the said product, b. A first side wall (204), wherein the first side wall (204) is i. The first edge (208) and, ii. A first surface (205) and a further surface (206) opposite to the first surface (205), wherein the further surface (206) faces the internal volume (201), the first surface (205) and the further surface (206), iii. It is a film, A. The film constitutes at least 30% of the thickness of the first side wall (204), B. The film comprises a film having a layered structure (100a, b), A first side wall (204) and c. A further side wall (207) opposite to the first side wall (204), the further side wall (207) having a first edge connected to the first edge (208) of the first side wall (204), Equipped with, The cross-sectional portion of the layered structure (100a, b) comprises at least five layers, and the at least five layers are A. Layered substructure A (110a, b) comprising at least two layers (101a, b; 102a, b), B. Layered substructure B (111a, b) including at least one layer (105a, b), C. Layered substructure C(112a, b) comprising at least two layers (107a, b; 109a, b) They are arranged as follows: I. The layered substructure B (111a, b) is positioned between the layered substructure A (110a, b) and the layered substructure C. II. The layered substructure C (112a, b) is positioned closer to the internal volume (201) of the container (200) compared to the layered substructure A (110a, b), The first side wall (204) comprises less than 20% by weight of paper, cardboard, or both. A container (200) in which the thickness A of the layered substructure A (110a, b) is less than or equal to the thickness C of the layered substructure C (112a, b).
2. a. The layered substructure A (110a, b) contains at least one polyolefin. b. The layered substructure B (111a, b) contains at least one or all of the following: polyamide, ethylene / vinyl alcohol copolymer (EVOH), polyvinyl alcohol (PVOH), and polyvinylidene chloride (PVDC). c. The layered substructure C (112a, b) contains at least one polyolefin. The container (200) according to claim 1, wherein at least one or all of the following apply.
3. a. The ratio of thickness C to thickness A is in the range of 0.5 to 2.
9. b. The ratio of the thickness A to the thickness B of the layered substructure B (111a, b) is in the range of 0.6 to 2.
9. c. The ratio of the thickness C of the layered substructure B (111a, b) to the thickness B is in the range of 1.3 to 4.
5. A container (200) according to claim 1 or 2, wherein at least one or all of the following apply.
4. a. The thickness A is in the range of 23 to 51 μm. b. The thickness B is in the range of 10 to 34 μm. c. The thickness C is in the range of 41 to 79 μm. A container (200) according to any one of claims 1 to 3, wherein at least one or all of the above apply.
5. a. The thickness A is in the range of 17 to 45% of the thickness of the layered structure (100a, b). b. The thickness B is in the range of 7 to 30% of the thickness of the layered structure (100a, b). c. The thickness C is in the range of 33 to 68% of the thickness of the layered structure (100a, b). At least one or all of the following apply: However, the container (200) according to any one of claims 1 to 4, subject to the constraint that the sum of the thickness A, the thickness B, and the thickness C does not exceed 100%.
6. a. The layered substructure A (110a, b) is composed of at least two layers (101a, b; 102a, b) with different densities. b. The layered substructure C (112a, b) is composed of at least two layers (107a, b; 109a, b) with different densities. A container (200) according to any one of claims 1 to 5, to which the provisions apply.
7. a. The density of at least one of the at least two layers (101a, b) of the layered substructure A (110a, b) is greater than the density of at least one of the at least two layers (109a, b) of the layered substructure C (112a, b). b. The density of at least one of the at least two layers (102a, b) of the layered substructure A (110a, b) is less than the density of at least one of the at least two layers (107a, b) of the layered substructure C (112a, b). A container (200) according to any one of claims 1 to 6, wherein at least one or all of the above apply.
8. A method for manufacturing a film, I. A step of obtaining a film having a layered structure (100a, b) by extruding at least five layers simultaneously, at least partially, wherein in the cross-sectional portion of the film, the at least five layers are the following layered substructures of the layered structure: A. A layered substructure A(110a,b) comprising at least two layers A1(101a,b) and A2(102a,b), i. The layer A1 (101a, b) has a density of 0.940 g / cm³. 3 The above polyolefins are included, ii. The layer A2 (102a, b) has a density of 0.940 g / cm³. 3 A layered substructure A (110a, b) containing a polyolefin of less than 1, B. A layered substructure B (111a, b) comprising at least one layer (105a, b), wherein the layered substructure B (111a, b) comprises at least one or all of the following: polyamide, ethylene / vinyl alcohol copolymer, polyvinyl alcohol, and polyvinylidene chloride. C. A layered substructure C(112a,b) comprising at least two layers C1(107a,b) and C3(109a,b), i. The layer C1 (107a, b) has a density of 0.940 g / cm³. 3 The above polyolefins are included, ii. The layer C3 (109a,b) has a density of 0.940 g / cm³ 3 A layered substructure C (112a,b) containing a polyolefin of less than 1, However, the steps are arranged in this order. Includes, The method wherein the layered substructure B (111a, b) is placed between the layered substructure A (110a, b) and the layered substructure C (112a, b).
9. A method for manufacturing a container for holding a product, I. The step of providing the film obtained according to claim 8, II. / A step of manufacturing at least a first side wall of the container using the film, Methods that include...
10. A container obtained by the method described in claim 9.
11. The container according to any one of claims 1 to 7 and 10, wherein the container is at least partially housed within a receptacle.
12. The container according to any one of claims 1 to 7 and 10 to 11, wherein the container is at least partially filled with the product.
13. A film obtained according to claim 8.
14. Use of the film according to claim 13 for manufacturing a container for housing a product.
15. Use of a container according to any one of claims 1 to 7, 10 to 11 for containing a product.
Citation Information
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