Method for controlling sanitary pests using condensed heterocyclic compounds

Abstract

This provides a simple and effective method for controlling sanitary pests. [Solution] Formula (I): TIFF2026153010000011.tif3168 [in the formula, R 1 R represents a C1-C3 haloalkoxy group, a C1-C3 haloalkylthio group, a C1-C3 haloalkylsulfinyl group, or a C1-C3 haloalkylsulfonyl group, and R 2 A sanitary pest control agent containing at least one compound selected from the group consisting of compounds represented by ], their N oxides, and their salts as an active ingredient, is provided in 1m 2 A method for controlling sanitary pests, comprising treating areas where sanitary pests may pass through, areas where sanitary pests may live, or both, so that the amount of active ingredient per area is 5 to 1000 mg.

Description

[Technical Field]

[0001] This patent application claims priority and interest under the Paris Convention based on Japanese Patent Application No. 2021-071590 (filed on April 21, 2021), and by reference herein the entire contents of the said application are incorporated herein by reference.

[0002] The present invention relates to a method for controlling sanitary pests containing a certain condensed heterocyclic compound. [Background technology]

[0003] Patent documents 1 to 4 disclose condensed heterocyclic compounds that have insecticidal activity. [Prior art documents] [Patent Documents]

[0004] [Patent Document 1] International Publication No. 2017 / 146226 [Patent Document 2] International Publication No. 2020 / 175491 [Patent Document 3] Japanese Patent Publication No. 2014-5263 [Patent Document 4] Japanese Patent Publication No. 2016-506360 [Overview of the Initiative] [Problems that the invention aims to solve]

[0005] The present invention aims to provide a simple and effective method for controlling sanitary pests using condensed heterocyclic compounds. [Means for solving the problem]

[0006] The present invention includes, but is not limited to, the following embodiments. [1] Equation (I): [ka] [During the ceremony, R 1 This represents a C1-C3 haloalkoxy group, a C1-C3 haloalkylthio group, a C1-C3 haloalkylsulfinyl group, or a C1-C3 haloalkylsulfonyl group, and R 2 [This represents a hydrogen atom or a cyano group.] A sanitary pest control agent (hereinafter referred to as "this sanitary pest control agent") containing at least one compound selected from the group consisting of a compound represented by (hereinafter referred to as "compound (I)"), its N oxide, and its salts, as an active ingredient, is prepared in 1 m 2 A method for controlling sanitary pests, comprising treating areas where sanitary pests may pass through, areas where sanitary pests may live, or both, so that the amount of active ingredient per unit is 5 to 1000 mg. (Hereinafter referred to as "the present invention's control method.") [2] 1m 2 The method for controlling sanitary pests described in the preceding paragraph [1], wherein the amount of active ingredient per unit is 5 to 300 mg. [3] In equation (I), R 1 is a trifluoromethylsulfinyl group or a trifluoromethylsulfonyl group, and R 2 The method for controlling sanitary pests described in the preceding paragraph [1] or [2], wherein is a hydrogen atom. [4] A method for controlling sanitary pests according to any one of the preceding paragraphs [1] to [3], wherein the place where sanitary pests can pass through or live, or both, consists of a surface constituting an indoor or outdoor structure, or a surface surrounding said structure. [5] The method for controlling sanitary pests according to paragraph [4], wherein the treatment of the sanitary pest control agent includes supporting the compound of formula (I) on any of the surfaces. [6] The method for controlling sanitary pests according to any one of the preceding paragraphs [1] to [5], wherein the sanitary pest control agent further contains at least one active ingredient. [7] The method for controlling sanitary pests according to the previous item [6], wherein the active ingredient is at least one selected from the group consisting of cypermethrin, alpha-cypermethrin, bifenthrin, cyfluthrin, beta-cyfluthrin, lambda-cyhalothrin, deltamethrin, esfenvalerate, etofenprox, prallethrin, permethrin, pyrethrin, chlorfenapyr, abamectin, acetamiprid, clothianidin, dinotefuran, resmethrin, imidacloprid, thiamethoxam, thiacloprid, indoxacarb, broflanilide, fenitrothion, cyphenothrin, pyriproxyfen, fipronil, phenothrin, sulfoxaflor, broflanilide, pirimiphos-methyl, bendiocarb, piperonyl butoxide, and N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide. [8] The method for controlling sanitary pests according to any one of items [1] to [7], wherein the sanitary pest is at least one sanitary pest selected from the group consisting of sanitary pests of Blattodea, Hymenoptera, Diptera, Siphonaptera, Acarina, Lepidoptera and Coleoptera. [9] The method for controlling sanitary pests according to any one of items [1] to [8], which comprises diluting the sanitary pest control agent with water and spraying the same for treatment.

[10] The method for controlling sanitary pests according to any one of items [1] to [9], wherein the sanitary pest control agent is an oil solution, an emulsifiable concentrate, a wettable powder, a wettable granule, a flowable formulation, or a microcapsule formulation. Effects of the Invention

[0007] According to the present invention, sanitary pests can be easily controlled. Mode for Carrying Out the Invention

[0008] The present compound used in the method for controlling sanitary pests of the present invention (hereinafter referred to as "the control method of the present invention") is described below. The substituent R of the compound of formula (I) 1 will be described first. Examples of C1-C3 haloalkoxy groups include trifluoromethyl, difluoromethyl, 2,2,2-trifluoroethyl, 1,1,2,2-tetrafluoroethyl, pentafluoroethyl, heptafluoropropyl, and 2,2,3,3,3-pentafluoropropyl. Examples of C1-C3 haloalkylthio groups include trifluoromethylthio group, difluoromethylthio group, 2,2,2-trifluoroethylthio group, 1,1,2,2-tetrafluoroethylthio group, pentafluoroethylthio group, heptafluoropropylthio group, and 2,2,3,3,3-pentafluoropropylthio group. Examples of C1-C3 haloalkylsulfinyl groups include trifluoromethylsulfinyl group, difluoromethylsulfinyl group, 2,2,2-trifluoroethylsulfinyl group, 1,1,2,2-tetrafluoroethylsulfinyl group, pentafluoroethylsulfinyl group, heptafluoropropylsulfinyl group, and 2,2,3,3,3-pentafluoropropylsulfinyl group. Examples of C1-C3 haloalkylsulfonyl groups include trifluoromethylsulfonyl group, difluoromethylsulfonyl group, 2,2,2-trifluoroethylsulfonyl group, 1,1,2,2-tetrafluoroethylsulfonyl group, pentafluoroethylsulfonyl group, heptafluoropropylsulfonyl group, and 2,2,3,3,3-pentafluoropropylsulfonyl group.

[0009] The N oxide of compound (I) is the compound represented by formula (II) (hereinafter referred to as "compound (II)"). Formula (II) [ka] [In the formula, the symbols have the same meaning as above.]

[0010] Compound (I) and Compound (II) may have one or more stereoisomers. Examples of stereoisomers include enantiomers and diastereomers. The present compound encompasses each individual stereoisomer and mixtures of stereoisomers in any ratio.

[0011] Compound (I) and Compound (II) may form acid addition salts. Examples of acids that form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid and p-toluenesulfonic acid. An acid addition salt can be obtained by mixing the present compound with an acid.

[0012] Examples of Compound (I) and Compound (II) are given below, but the compounds are not limited to these.

[0013] [1] R 1 is a C1-C3 haloalkylsulfinyl group or a C1-C3 haloalkylsulfonyl group, and R 2 is a hydrogen atom. [2] R 1 is a C1-C3 haloalkylsulfinyl group, and R 2 is a hydrogen atom. [3] R 1 is a C1-C3 haloalkylsulfonyl group, and R 2 is a hydrogen atom. [4] R 1 is a trifluoromethylsulfinyl group or a trifluoromethylsulfonyl group, and R 2 is a hydrogen atom. [5] R 1 is a trifluoromethylsulfinyl group, and R 2 is a hydrogen atom. [6] R 1 is a trifluoromethylsulfonyl group, and R 2 is a hydrogen atom.

[0014] Next, the methods for producing compound (I) and compound (II) will be described.

[0015] Compound (I) can be prepared, for example, by the methods described in WO2016 / 121997, WO2017 / 146226, and WO2020 / 117487. (Manufacturing method 1) Compound (II) can be produced by reacting compound (I) with an oxidizing agent, as shown in the scheme below. [ka] [In the formula, the symbols have the same meaning as above.] The reaction is usually carried out in the presence of a solvent. Examples of solvents used in the reaction include halogenated hydrocarbons such as dichloromethane and chloroform (hereinafter referred to as halogenated hydrocarbons); nitriles such as acetonitrile (hereinafter referred to as nitriles); acetic acid; water; and mixtures of two or more of these. Examples of oxidizing agents used in the reaction include sodium periodate, m-chloroperbenzoic acid, and hydrogen peroxide. When using hydrogen peroxide as an oxidizing agent, a base or catalyst may be added as needed. Sodium carbonate is an example of a base used in the reaction. When a base is used in the reaction, it is usually used in a ratio of 0.01 to 1 mole of base per mole of compound (I). Examples of catalysts used in the reaction include sodium tungstate. When a catalyst is used in the reaction, it is usually used in a ratio of 0.01 to 0.5 moles of catalyst per mole of compound (I). In the reaction, an oxidizing agent is typically used in a ratio of 1 to 2 moles per mole of compound (I). The reaction temperature is typically in the range of -20 to 120°C. The reaction time is typically in the range of 0.1 to 12 hours. After the reaction is complete, water is added to the reaction mixture, and it is extracted with an organic solvent. The organic layer is then washed with an aqueous solution of a reducing agent (e.g., sodium sulfite, sodium thiosulfate) and an aqueous solution of a base (e.g., sodium bicarbonate) as needed. Compound (II) can be obtained by drying and concentrating this organic layer.

[0016] Examples of the compound produced according to any of the manufacturing methods described herein are shown below.

[0017] In compound (I), R 1 and R 2 However, the compounds are any combination of substituents listed in [Table S1] and [Table S2] (hereinafter referred to as compound group SX1). In compound (II), R 1 and R 2 However, the compounds are those with any combination of substituents listed in [Table S1] and [Table S2] (hereinafter referred to as compound group SX2). [Table 1]

[0018] In this embodiment, when using this compound, it is usually mixed with a suitable solid or liquid carrier, and optionally, surfactants, thickeners, protective colloids, antifreeze, defoaming agents, antifungal agents, preservatives / bactericides, antioxidants, light stabilizers, pH adjusters, binders, adhesives / spreaders, lubricants / smoothing agents, anticaking agents, fragrances, coating agents, inclusion agents, etc. are added to form a liquid concentrate, oil, emulsifiable concentrate, wettable powder, water-soluble powder, water-dispersible granule, water-based suspension concentrate, oil-based suspension concentrate, emulsion in water, suspoemulsion, microemulsion, microcapsule, or dustable powder. The product can be used in any dosage form, such as powder, granules, tablets, or emulsifiable gels. Furthermore, from the viewpoint of labor saving and improved safety, the product can also be supplied in any dosage form enclosed in water-soluble packaging such as water-soluble capsules or water-soluble film bags. Among these, emulsions, wettable powders, aqueous soluble powders, granular wettable powders, aqueous suspensions, emulsions, suspend emulsions, microemulsions, and microcapsules are particularly preferred in terms of ease of handling.

[0019] The inert carrier that can be used in the composition according to this embodiment may be a solid or a liquid.

[0020] Examples of solid carriers include: inorganic materials: minerals (natural silicates, marble, pumice, limestone, rare earth minerals, cryolite, activated clay, lime, activated carbon, talc, attapulgite, sodium montmorillonite, calcium montmorillonite, kaolinite, calcite, dolomite, diatomite, bentonite, zeolite, sepiolite, pyrophyllite, vermiculite, crystalline silica, amorphous silica, etc.), silicon dioxide, calcium sulfate, magnesium sulfate, barium sulfate, magnesium oxide, aluminum oxide, ammonium sulfate, ammonium phosphate, ammonium nitrate, calcium phosphate, sulfur, calcium carbonate, sodium bicarbonate, sodium carbonate, synthetic silicates, and their pulverized products; organic materials: grain powders (rice bran, rice flour, corn flour) Examples of solid carriers include: powders (wheat flour, etc.), sugars (cellulose, starch, lactose, glucose, fructose, sucrose, etc.), plant-derived powders (nut shell powder (coconut, walnut, peanut, etc.), tree-derived powders (bark powder, sawdust, etc.), other plant powders (tobacco stems, soybeans, cottonseed husks, etc.)), lignin, wax, seashells, urea, polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resins, melamine resins, and epoxy resins. Furthermore, the above solid carriers can also be used as adsorbent carriers.

[0021] Examples of liquid carriers include water, aliphatic hydrocarbons (hexane, 1-hexene, cyclohexane, octane, isooctane, 1-heptene, d-limonene, pinene, hexadecane, etc.), aromatic hydrocarbons (alkylbenzenes (toluene, xylene, isopropylbenzene, p-diethylbenzene, etc.), alkylbenzene derivatives, alkylnaphthalenes, alkylnaphthalene derivatives, tetrahydronaphthalene, etc.), chlorinated hydrocarbons (monochloroethylene, dichloroethylene, trichloroethylene, tetrachloroethylene, Dichloromethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane, 1,2-dichloropropane, etc.), ketones (cyclohexanone, acetone, 2-heptanone, isophorone, mesityl oxide, methyl isoamyl ketone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone, diacetone alcohol, methylcyclohexanone, etc.), esters (fatty acid esters (ethyl acetate, butyl acetate, amyl acetate, isoamyl acetate, isobornyl acetate, hexyl acetate, heptyl acetate, octyl acetate, Isopropyl myristate, methyl octanoate, methyl oleate, methyl laurate, dibutyl adipate, tributyl citrate, and dibutyl phthalate, etc.), lactate esters (ethyl lactate, propyl lactate, etc.), carbonate esters (ethylene carbonate, propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate, etc.), esterified polyols (glycerol acetate, glycol acetate, glycerin monoacetate, glycerin diacetate, glycerin triacetate, diethylene glycol abietate, di Propylene glycol dibenzoate, dipropylene glycol monomethyl ester, etc.), lactones (γ-butyllactone, etc.), ethers (1,4-dioxane, tetrahydrofuran, dipropylene glycol methyl ether, ethylene glycol methyl ether, propylene glycol methyl ether, etc.), amides (N-octyl-caprolactam, N-dodecyl-caprolactam, N,N-dimethylformamide, fatty acid dimethylamides (N,N-dimethylacetamide, N,N-dimethyldecanamide, N,N-dimethyloctanamide, alkylpyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone, N-dodecylpyrrolidone, etc.), lactams (α-lactam, β-lactam, γ-lactam, δ-lactam, etc.), amines (octylamine, octylamine acetate, oleylamine, diethanolamine, laurylamine, etc.), alcohols (methanol, ethanol, butanol, propanol, isopropanol, butanol, amyl alcohol, hexanol, heptanol, octanol, 2-ethylhexanol, etc.), hexylene glycol, cyclohexanol, phenol, benzyl alcohol, methoxypropanol (1-methoxy-2-propanol), tetrahydrofurfuryl alcohol, furfuryl alcohol, polyethylene glycol, ethylene glycol, diethylene glycol, hexylene glycol, ethylene glycol methyl ether, diethylene glycoside Examples include methyl ether, diethylene glycol butyl ether, triethylene glycol, propylene glycol methyl ether, dipropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol ether, dipropylene glycol monomethyl ether, glycerin, etc.), mineral oils (naphtha, petroleum ether, kerosene, diesel oil, paraffin, olefins, etc.), animal and vegetable-derived oils, plant-derived oils (palm oil, rapeseed oil, castor oil, coconut oil, soybean oil and their derivatives, etc.), animal-derived oils (sardine oil, saury oil, whale oil and their derivatives, etc.), dimethyl sulfoxide, silicone oil, acetonitrile, propanenitrile, acid anhydrides (acetic anhydride, etc.), triethyl phosphate, oleic acid, propionic acid, lactic acid, and xylene sulfonic acid.

[0022] These solid and liquid carriers may be used individually or in combination of two or more types.

[0023] Examples of surfactants include anionic surfactants, cationic surfactants, amphoteric surfactants, and nonionic surfactants.

[0024] Examples of anionic surfactants include carboxylic acids, sulfonic acids, sulfate esters, and phosphate esters, and specifically, the following are listed below. Carboxylic acids: Fatty acid salts (octanoate, decanoate, laurate, myristicate, palmitate, stearate, behenate, oleate, polyoxyethylene alkyl ether carboxylates (laureth-3-carboxylate, α-(carboxymethyl)-ω-(dodecyloxy)poly(oxyethylene) salt, etc.), N-acyl sarcosine salts (N-lauroyl sarcosine salt, etc.), N-acyl glutamate salts (N-lauroyl glutamate, etc.), polycarboxylates (polyacrylates, polyvinyl acetates, comb-type polymers of polysates, and their derivatives, etc.), Sulfonic acids: Alkyl sulfonic acids and their salts (dodecyl sulfonate, etc.), alpha-olefin sulfonates (alkene (C14-18) hydroxysulfonate, alkapoliene (C12-20) hydroxysulfonate, alkene (C14-18) hydroxysulfonate, alkene (C12-20) hydroxysulfonate, tetradecene-1-sulfonate, α-olefin (C14-16) sulfonate, etc.), alkylbenzene sulfonates (decylbenzene sulfonate, dodecylbenzene sulfonate, tridecylbenzene sulfonate, diphenyl sulfonate, etc.), alkylnaphthalene sulfonates (naphthalene sulfonate, 6-methyl (e.g., 2-2-naphthalene sulfonate, dibutylnaphthalene sulfonate, 2,2'-dinaphthylmethane-6,6'-disulfonate, diisopropylnaphthalene sulfonate, triisopropylnaphthalene sulfonate, 1-isopropyl-2-naphthalene sulfonate, etc.), sulfosuccinic acid, monoalkyl sulfosuccinate, dialkyl sulfosuccinate, (e.g., di(2-ethylhexyl) sulfosuccinate), N-methyl-N-acyl taurate salt (e.g., oleoylmethyl taurate), lignin sulfonate, alkylphenol sulfonate, naphthalene sulfonate-formaldehyde condensate, benzimidazole sulfonate and its derivatives, Sulfate esters: Alkyl sulfates (hexyl sulfate, heptyl sulfate, octyl sulfate, lauryl sulfate, lauryl sulfate diethanolate, hexadecyl sulfate, octadecyl sulfate, etc.), polyoxyethylene alkyl ether sulfates and their salts (laureth-3 sulfate, polyoxyethylene monotridecyl ether sulfate, α-sulfo-ω-hydroxyalkyl(C6-10) ether poly(oxyethylene) salt, etc.), polyoxyethylene alkylphenyl ether sulfates (poly(oxyethylene)2-decylphenyl ether sulfate, poly(oxyethylene)3-decylphenyl ether sulfate, α-sulfo-ω-[2,4-bis(1,1,3,3-tetramethylbutyl)phenoxy]poly(oxyethylene) salt, etc.), polyoxypropylene alkyl ether sulfates, lignosulfite wastewater, and derivatives thereof; Phosphate esters: Alkyl phosphates (propyl phosphate, hexadecyl phosphate, lauryl phosphate, dioctyl phosphate, etc.), polyoxyethylene alkyl ether phosphates (polyoxyethylene decyl phosphate, α-phosphono-ω-butoxypoly(oxyethylene), etc.), polyoxyethylene alkylphenyl ether phosphates (α-(dinonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(dodecylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(nonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, etc.), polyoxypropylene alkyl ether phosphates, and derivatives thereof.

[0025] Examples of cationic surfactants include amine salts and quaternary ammonium salts, specifically the following: Amine salts: Alkylamine salts (monomethylamine salts, dimethylamine salts, trimethylamine salts, etc.), fatty acid amide amine salts (stearamidopropyldimethylamine, behenamidopropyldimethylamine, etc.), polyamine salts (polyvinylamine, polyethyleneimine, etc.), and their derivatives; Quaternary ammonium salts: lauryltrimethylammonium salt, cetyltrimethylammonium salt, dodecyltrimethylammonium salt, stearyltrimethylammonium salt, penzalkonium chloride, benzethonium chloride, and benzylbis(2-chloroethyl)ethylammonium bromide salt.

[0026] Examples of amphoteric surfactants include betaine, alkylbetaine, alkyldimethylbetaine, imidazoline, taurine, alkyltaurine, dodecyldimethylammonium acetate, 4-carboxy-N,N,N-trimethyl-1-butanaminonium, 1-carboxy-N,N,N-2-2-tetramethyl-1-propanaminonium, N-alkyl (or alkenyl)(C12-18)glycine and its salts, N-dodecylglycine and its salts, and derivatives thereof.

[0027] Examples of nonionic surfactants include alcohols, amides, amines, esters, ethers, ether esters, and carboxylic acids, and specifically, the following are listed below. Alcohols: Aromatic alcohols (alkylphenols (allylphenol, octylphenol, nonylphenol, octyl cresol, etc.), acylphenols, etc.), aliphatic alcohols (isotridecyl alcohol, oleyl alcohol, cetyl alcohol, etc.), polyhydric alcohols (polysaccharides, starch, starch derivatives, sucrose, alkyl polyglucosides, sorbitan, ethoxylated sorbitan, cellulose derivatives, gum arabic, etc.), synthetic polymers (polyvinyl alcohol, polyethylene glycol, etc.); Amides: Alkanolamides (fatty acid alkanolamides (e.g., lauric acid diethanolamide), fatty acid glucamides (e.g., alkoxylated propylene oxide fatty acid glucamide), alkoxylated amides (e.g., polyoxyethylene oleamide, polyoxyethylene stearate amide), synthetic polymers (e.g., polyvinylpyrrolidone), Amines: Alkoxylated amines (polyoxyethylene oleylamine, α,α'-[(9-octadecenylimino)di2,1-ethandyl]bis(ω-hydroxy)polyoxyethylene, etc.); Esters: Fatty acid esters (fatty acid esters of polyols, monoglycerides, phospholipids, etc.), sugar-derived esters (sucrose fatty acid esters (sucrose stearate diester, etc.), sorbitan fatty acid esters (sorbitan oleic acid monoester, etc.), glucose esters, cellulose esters, etc.), synthetic polymers (vinyl acetate copolymers, polymethacrylic acid, copolymers of methacrylic acid and methacrylic acid esters, etc.); Ethers: Alcohol ethoxylates (aliphatic alcohol ethoxylates (tridecyl alcohol ethoxylate, isooctyl alcohol ethoxylate, lauryl alcohol ethoxylate, hexadecyl alcohol ethoxylate, stearyl alcohol ethoxylate, etc.)), alkylphenol ethoxylates (nonylphenol ethoxylate, tristyrylphenol ethoxylate, tributylphenol ethoxylate, octylphenol ethoxylate, etc.), arylalkylphenol ethoxylates, arylphenol ethoxylates (monobenzyl biphenol alcohol ethoxylate, etc.), alcohol propoxylates (aliphatic alcohol propoxylates, alkylphenol propoxylates, arylalkylphenol propoxylates, etc.), block polymers (polyethylene oxide and polypropylene oxide block polymers, polyethylene oxide block polymers, polypropylene oxide block polymers, alkanol and polyethylene oxide and polypropylene oxide block polymers, etc.); Ether esters: Polyoxyethylene fatty acid esters (polyoxyethylene castor oil ester, polyoxyethylene stearate ester, polyoxyethylene beef tallow fatty acid ester, etc.), polyoxyethylene sorbitan fatty acid esters (polyoxyethylene sorbitan monooleate ester, polyoxyethylene sorbitan trioleate ester, polyoxyethylene sorbitan monolaurate ester, polyoxyethylene sorbitan stearate ester, etc.), polyoxyethylene fatty acid amine esters, polyoxyethylene rosin esters, polyoxypropylene fatty acid esters (polyoxypropylene castor oil ester, etc.), polyoxypropylene fatty acid amine esters; Carboxylic acids: Undecafluorohexanoic acid.

[0028] The content of these surfactants is not particularly limited, but it is generally preferable to have a range of 0.05 to 20 parts by weight per 100 parts by weight of the formulation. Furthermore, these surfactants may be used individually or in combination of two or more types.

[0029] Examples of thickening agents include polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose and their salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tyrose, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay, etc.), minerals (bentonite, attapulgite, silica, silicates, etc.), and synthetic polymers (polycarboxylates, polyacrylic acid derivatives, polyvinylpyrrolidone, polyvinyl alcohol, etc.). These thickening agents may be used individually or in combination of two or more.

[0030] Examples of protective colloidal agents include water-soluble celluloses such as methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, and carboxymethylcellulose; polyalkylene glycols such as polyethylene glycol and polypropylene glycol; polyvinyl alcohol; polyvinylpyrrolidone; guar gum; gum arabic; gelatin; polyacrylates; and alginates. These protective colloidal agents may be used individually or in combination of two or more.

[0031] Examples of antifreeze agents include alcohols (ethylene glycol, propylene glycol, dipropylene glycol, triethylene glycol, ethylene glycol methyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, ethylene glycol butyl ether, glycerin, polyethylene glycol, etc.), esters (dipropylene glycol dibenzoate, glycerol acetate, glycerol diacetate, glycerol triacetate, gamma butyrolactone, etc.), ethers (1,4-dioxane, etc.), and urea. These antifreeze agents may be used individually or in combination of two or more.

[0032] Examples of defoaming agents include silicones (polysiloxane, diblock ethoxysiloxane, triblock ethoxysiloxane, etc.), alkyl sulfosuccinates, higher alcohols, higher alcohol derivatives, fatty acid salts, and fatty acid derivatives. These defoaming agents may be used individually or in combination of two or more.

[0033] Examples of antifungal agents include benzothiazole derivatives, sorbic acid, potassium sorbate, and butyl p-oxybenzoate. These antifungal agents may be used individually or in combination of two or more.

[0034] Examples of preservatives and disinfectants include phenols (orthophenylphenol, thymol, 3,5-dimethyl-4-chlorophenol, 2-isopropyl-5-methylphenol, 3-methyl-4-isopropylphenol), isothiazolinone derivatives (alkylisothiazolinones (5-chloro-2-methylisothiazolinone, 2-methylisothiazolinone, N-octylisothiazolinone), benzisothiazolinones (1,2-benzisothiazolinone, N-butylbenzoisothiazolinone), bronopol derivatives (bronopol benzyl alcohol hemifomal), parabens (methylparaben, ethylparaben, propylparaben, isopropylparaben, butylparaben, isobutylparaben, heptylparaben, benzylparaben), and imidazoles (thiabendazole). , 2-(4-thiazolyl)benzimidazole), 2-benzimidazolylcarbamate methyl, benzalkonium chloride, didecyldimethylammonium chloride, glyceryl caprylate, glyceryl caprate, glycerin fatty acid ester, sodium dehydroacetate, hinokitiol, silver zeolite, silver salt, methylene bisthiocyanate, 2-bromo-2-nitropropane-1,3-diol, glutaraldehyde, iodopropynyl butylcarbamate, 1,2-dibromo-2,4-dicyanobutane, chlorhexidine gluconate, polyhexamethylene biguanide, parachlorometaxylenol, parachlorometacresol, polylysine, tetrachloroisophthalonitrile, diiodomethyl paratolylsulfone, parachlorophenyl-3-iodopropagylformal, 2,3,5,Examples include 6-tetrachloro-4-(methylsulfonyl)pyridine, lanthanum chloride, and rare earth salts (scandium salts, yttrium salts, lanthanum salts, cerium salts, praseodymium salts, neodymium salts, samarium salts, europium salts, gadolinium salts, terbium salts, dysprosium salts, holmium salts, erbium salts, thulium salts, ytterbium salts, and lutetium salts). Counterions include chloride salts, sulfate salts, nitrates, bromides, and iodides. Examples of preservatives and fungicides include carbonates, phosphates, organic acid salts, hydroxides, etc. Examples of organic acid salts include monovalent or divalent carboxylic acids and hydroxy acids. Specifically, examples of hydroxy acids include lactic acid, gluconic acid, tartaric acid, citric acid, malic acid, salicylic acid, etc., and examples of monovalent or divalent carboxylic acids include acetic acid, propionic acid, malonic acid, succinic acid, glutaric acid, adipic acid, azelaic acid, sorbic acid, benzoic acid, etc., as well as phosphoric acid and their salts. These preservatives and fungicides may be used alone or in combination of two or more.

[0035] Examples of antioxidants include phenols (2,6-di-t-butyl-p-cresol, 2,2'-methylenebis(4-methyl-6-t-butylphenol), etc.), amines (p,p'-dioctyldiphenylamine, N,N'-diphenyl-p-phenylenediamine, etc.), dibutylhydroxytoluene, butylhydroxyanisole, sodium erythorbate, sodium sulfite, potassium sulfite, potassium pyrosulfite, catechin, propyl gallate, sulfurs (didodecyl thiodipropionate, etc.), phosphoric acids (trisnonylphenyl phosphite, etc.), and vitamins (alpha-tocopherol, L-ascorbic acid, sodium ascorbate, ascorbyl palmitate, etc.). These antioxidants may be used individually or in combination of two or more.

[0036] Examples of light stabilizers include titanium dioxide, zinc oxide, activated carbon, carbon black, ethylhexyl methoxycinnamate, tert-butyl methoxydibenzoylmethane, hindered amines, ferulic acid, phenyl hydroxybenzoate, ethyl para-aminobenzoate, octyl salicylate, t-butylphenyl salicylate, 4-tert-octylphenyl salicylate, 2-cyano-3,3-diphenylpropane-2-enoic acid-2-ethylhexyl ester (octocrylene), drometrizole trisiloxane, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine (octyltriazone, TEAT), and 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol](MBP). Examples include 2-ethylhexyl paradimethylaminobenzoate (EDB), homomenthyl salicylate (HS), phenylbenzimidazole sulfonic acid (PBS), hydroxymethoxybenzophenone sulfonic acid (oxybenzone 4, OXB4), sodium hydroxymethoxybenzophenone sulfonate (oxybenzone 5, OXB5), sodium dihydroxydimethoxybenzophenone disulfonate (oxybenzone 9, OXB9), tetrahydroxybenzophenone, dihydroxybenzophenone, dihydroxydimethoxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-ethylhexyl dimethoxybenzylidene dioxoimidazolidinepropionate, 2,4-dihydroxybenzophenone, and bis(2-methoxy-4-hydroxy-5-benzoylphenyl)methane. These light stabilizers may be used alone or in combination of two or more.

[0037] Examples of pH adjusting agents include sulfuric acid, nitric acid, hydrochloric acid, acetic acid, carbonic acid, oxalic acid, lactic acid, succinic acid, gluconic acid, citric acid, phosphoric acid, sorbic acid, and their salts, sodium bicarbonate, sodium hydroxide, potassium hydroxide, calcium hydroxide, aluminum hydroxide, copper hydroxide, and magnesium hydroxide. These pH adjusting agents may be used individually or in combination of two or more.

[0038] Examples of binders include polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay), minerals (bentonite), synthetic polymers (polycarboxylic acid or its salts, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salts), and waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefins, etc.). These binders may be used alone or in combination of two or more.

[0039] Examples of adhesives and spreading agents include the surfactants and liquid carriers mentioned above (esters (alkyl fatty acid esters, sorbitan fatty acid esters, ethoxylated fatty acid esters, ethoxysorbitan fatty acids, etc.), alcohols (ethoxylated aliphatic alcohols, ethoxysorbitan aliphatic alcohols, etc.), waxes (vegetable oils, animal oils, and their derivatives, paraffin, olefins, etc.), vegetable oils (alkylated vegetable oils, etc.), mineral oils (mineral oil, etc.), silicone emulsions, synthetic polymers (styrene-butadiene copolymer, methyl methacrylate-butadiene copolymer, polyacrylic acid or its salts, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), and natural polymers (xanthan gum, cellulose ester, cellulose ether, carboxymethylcellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tyrose, etc.). These adhesives and spreading agents may be used alone or in combination of two or more.

[0040] Examples of lubricants and lubricants include the alcohols, fatty acid esters, sucrose fatty acid esters, glycerin fatty acid esters, hydrocarbons, paraffin, ethylene wax, aliphatic amides, erucic acid amide, stearic acid amide, oleic acid amide, methylenebisstearate amide, ethylenebisstearate amide, metal soaps, lead stearate, zinc stearate, calcium stearate, magnesium stearate, mineral oil, vegetable oil, kerosene, diesel oil, etc. These lubricants and lubricants may be used individually or in combination of two or more.

[0041] Examples of anticaking agents include the solid and liquid carriers described above, calcium phosphate, sodium phosphate, sodium carbonate, sodium silicate, calcium silicate, magnesium silicate, potassium aluminum silicate, silicon dioxide, talc, sodium aluminosilicate, calcium aluminosilicate, bentonite, stearic acid, dimethylpolysiloxane, powdered cellulose, and the like. These anticaking agents may be used individually or in combination of two or more.

[0042] Examples of fragrances include hydrocarbons, α-limonene, β-caryophyllene, alcohols, cis-3-hexenol, linalool, farnesol, β-phenylethyl alcohol, aldehydes, 2,6-nonagenal, citral, α-hexyl cinnamic aldehyde, ketones, β-ionone, L-carbone, cyclopentadecanone, esters, linalyl acetate, benzyl benzoate, lactones, γ-undecalactone, phenols, eugenol, oxides, rose oxide, acetals, phenylacetaldehyde dimethyl acetal, α-pinene, β-pinene, etc. These fragrances may be used individually or in combination of two or more.

[0043] Examples of coating agents include natural rubber, synthetic rubber, resins (styrene-butadiene copolymer, polyacrylonitrile, polyester, polyamide, polyurethane, polyurea, polyether, rosin, melamine, etc.), waxes (vegetable oils, animal oils, and their derivatives, paraffin, olefin, etc.), polysaccharides (xanthan gum, cellulose ester, cellulose ether, carboxymethylcellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tyrose, starch xanthate, carrageenan, etc.), and proteins (gelatin, etc.). These coating agents may be used individually or in combination of two or more.

[0044] Examples of inclusion agents include cyclodextrins, α-cyclodextrin, β-cyclodextrin, and γ-cyclodextrin. These inclusion agents may be used individually or in combination of two or more.

[0045] Furthermore, the pest control agent according to this embodiment may contain, in addition to the present compound, one or more other generally known insecticidal compounds and synergists. Examples of combinations of the present compound with other insecticidal compounds and synergists are described below. For example, alanicarb + SX means a combination of alanicarb and SX. The abbreviation SX refers to one of the compounds selected from compound groups SX1 and SX2. Furthermore, the other insecticidal compounds, repellents, and synergists described below are all known components and can be obtained from commercially available formulations or manufactured by known methods.

[0046] Combinations of this compound with other insecticidal compounds: Abamectin + SX, Acephate + SX, Acequinocyl + SX, Acetamiprid + SX, Acetoprole + SX, Acrinathrin + SX, Acynonapyr + SX, Afidopyropen + SX, Afoxolaner + SX, Alanicarb + SX, Aldicarb + SX, Allethrin + SX, Alpha-cypermethrin + SX, Alpha-endosulfan + SX, Aluminum phosphide + SX, Amitraz + SX, Azadirachtin + SX, Azamethiphos + SX, Azinphos-ethyl + SX, Azinphos-methyl + SX, Azocyclotin + SX, Bark of Celastrus angulatus + SX, Bendiocarb + SX, Benfluthrin + SX, Benfuracarb + SX, Bensultap + SX, Benzoximate + SX, Benzpyrimoxan + SX, Beta-cyfluthrin + SX, Beta-cypermethrin + SX, Bifenazate + SX, Bifenthrin + SX, Bioallethrin + SX, Bioresmethrin + SX,Bistrifluron + SX, Borax + SX, Boric acid + SX, Broflanilide + SX, Bromopropylate + SX, Buprofezin + SX, Butocarboxim + SX, Butoxycarboxim + SX, Cadusafos + SX, Calcium phosphide + SX, Carbaryl + SX, Carbofuran + SX, Carbosulfan + SX, Cartap hydrochloride + SX, Cartap + SX, Chinomethionate + SX, Chlorantraniliprole + SX, Chlordane + SX, Chlorethoxyfos + SX, Chlorfenapyr + SX, Chlorfenvinphos + SX, Chlorfluazuron + SX, Chlormephos + SX, Chloropicrin + SX, Chlorpyrifos + SX, Chlorpyrifos-methyl + SX, Chromafenozide + SX, Clofentezine + SX, Clothianidin + SX, Concanamycin A + SX, Coumaphos + SX, Cryolite + SX, Cyanophos + SX, Cyantraniliprole + SX, Cyclaniliprole + SX,Cyclobrifluram + SX, Cycloprothrin + SX, Cycloxaprid + SX, Cyenopyrafen + SX, Cyetpyrafen + SX, Cyflumetofen + SX, Cyfluthrin + SX, Cyhalodiamide + SX, Cyhalothrin + SX, Cyhexatin + SX, Cypermethrin + SX, Cyphenothrin + SX, Cyproflanilide + SX, Cyromazine + SX, Dazomet + SX, Deltamethrin + SX, Demeton-S-methyl + SX, Diafenthiuron + SX, Diazinon + SX, Dichlorvos + SX, Dichloromezotiaz + SX, Dicofol + SX, Diclotophos + SX, Diflovidazin + SX, Diflubenzuron + SX, Dimefluthrin + SX, Dimethoate + SX, Dimethylvinphos + SX, Dimpropyridaz + SX, Dinotefuran + SX, Disodium octaborate + SX, Disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, Doramectin + SX,Dried leaves of Dryopteris filix-mas + SX, emamectin-benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, ethiprole + SX, etoprophos + SX, etofenprox + SX, Ethoxazole + SX, Artemisia absinthium extract + SX, Azadirachta indica extract, Neem oil + SX, Cassia nigricans extract + SX, Clitoria ternatea extract + SX, Symphytum officinale extract + SX, Chenopodium ambrosioides extract (or simulated blend) + SX, Tansy extract + SX, Urtica dioica extract + SX, Viscum album extract + SX, Pyrethrum extract cinerariifolium)+ SX,Fanflu + SX, Fenamiphos + SX, Fenazaquin + SX, Fenbutatin oxide + SX, Fenitrothion + SX, Fenobucarb + SX, Fenoxycarb + SX, Fenpropathrin + SX, Fenpyroximate + SX, Fenthion + SX, Fenvalerate + SX, Fipronil + SX, Flometoquin + SX, Flonicamid + SX, Fluacrypyrim + SX, Fluazaindolizine + SX, Fluazuron + SX, Flubendiamide + SX, Flucycloxuron + SX, Flucythrinate + SX, Fluensulfone + SX, Flufenoprox + SX, Flufenoxuron + SX, Flufiprole + SX, Flumethrin + SX, Flupentiofenox + SX, Flupyradifurone + SX, Flupyrimin + SX, Fluralaner + SX, Fluvalinate + SX, Fluxametamide + SX, Formetanate + SX, Fosthiazate + SX, Furamethrin + SX, Furathiocarb + SX,Gamma-cyhalothrin + SX, GS-omega / kappa HXTX-Hv1a peptide + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, potassium salt of hop beta acid + SX, hydramethylnon + SX, hydroprene + SX, imicyaphos + SX, imidacloprid + SX, imidaclothiz + SX, imiprothrin + SX, Indoxacarb + SX, Isocycloseram + SX, Isofenphos + SX, Isoprocarb + SX, Isopropyl-O-(methoxyaminothiophosphoryl) salicylate + SX, Isoxathion + SX, Ivermectin + SX, Kadesrin + SX, Kappatefluthrin + SX, Kappa-bifenthrin + SX, Kinoprene + SX, Lambda-cyhalothrin + SX, Lenoremycin + SX, Lepimectin + SX, Lime sulfur + SX, Lotilaner + SX, Lufenuron + SX, Machine oil + SX, Malathion + SX, Mecarbam + SX, Meperfluthrin + SX, Metaflumizone + SX, Metam + SX, Methamidophos + SX, Methidathion + SX, Methiocarb + SX, Methomyl + SX, Methoprene + SX, Methoxychlor + SX, Methoxyfenozide + SX, Methyl bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX,Milbemectin + SX, Milbemycin oxime + SX, Momfluorothrin + SX, Monocrotophos + SX, Moxidectin + SX, Naled + SX, Nicofluprole + SX, Nicotine + SX, Nicotine sulfate + SX, Nitenpyram + SX, Novaluron + SX, Noviflumuron + SX, Oil of the seeds of Chenopodium anthelminticum + SX, Omethoate + SX, Oxamyl + SX, Oxazosulfyl + SX, oxydemeton-methyl + SX, parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, phosalone + SX, phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX, pirimicarb + SX, pirimiphos-methyl + SX, prallethrin + SX, profenofos + SX, Profluthrin + SX, Propargite + SX, Propetamphos + SX, Propoxur + SX,Propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX, pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spinetoram + SX, spinosad + SX, spirodiclofen + SX, spiromesifen + SX, spiropidion + SX, spirotetramat + SX, sulfuramide + SX, Sulfotep + SX, sulfoxaflor + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic + SX,Tau-fluvalinate + SX, Tebufenozide + SX, Tebufenpyrad + SX, Tebupirimfos + SX, Teflubenzuron + SX, Tefluthrin + SX, Temephos + SX, Terbufos + SX, Terpene constituents of the extract of chenopodium ambrosioides near ambrosioides + SX, Tetrachlorantraniliprole + SX, Tetrachlorvinphos + SX, Tetradifon + SX, Tetramethrin + SX, Tetramethylfluthrin + SX, Tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, thiometon + SX, thiosultap-disodium + SX, thiosultap-monosodium + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, triazamate + SX, Triazophos + SX, Trichlorfon + SX, Triflumezopyrim + SX,Triflumuron + SX, Trimethacarb + SX, Tyclopyrazoflor + SX, Vamidothion + SX, Wood extract of Quassia amara + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX, Xylylcarb + SX, Zeta-cypermethrin + SX, Zinc phosphide + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, 2-({2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2-trifluoroethyl)-1,3-thiazolidin-4-one (1445683-71-5) + SX, (2Z)-2-({2-fluoro-4-methyl-5-[(R)-(2,2,2-trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2-trifluoroethyl)-1,3-thiazolidin-4-one (2377084-09-6) + SX, (3R)-3-(2-chlorothiazol-5-yl)-8-methyl-7-oxo-6-phenyl-2,3-dihydrothiazolo[3,2-a]pyrimidin-4-ium-5-olate (2249718-27-0) + SX,N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, 11-(4-chloro-2,6-dimethylphenyl)-12-hydroxy-1,4-dioxa-9-azadispiro[4.2.4.2]tetradec-11-en-10-one (907187-07-9) + SX, 3-(4'-fluoro-2,4-dimethyl[1,1'-biphenyl]-3-yl)-4-hydroxy-8-oxa-1-azaspiro[4.5]dec-3-en-2-one (1031385-91-7) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, 1,4-dimethyl-2-[2-(3-pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX.,

[0047] Combination of a synergist and the present compound: 1-dodecyl-1H-imidazole + SX, N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide + SX, bucarpolate + SX, N,N-dibutyl-4-chlorobenzenesulfonamide + SX, dietholate + SX, diethylmaleate + SX, piperonyl butoxide + SX, piperonyl cyclonene + SX, piprotal + SX, Propyl isome + SX, safroxan + SX, sesamex + SX, sesamolin + SX, sulfoxide + SX, Verbutin + SX, DMC (1,1-bis(4-chlorophenyl)ethanol) + SX, FDMC (1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol) + SX, ETN (1,2-epoxy-1,2,3,4-tetrahydronaphthalene) + SX, ETP (1,1,1-trichloro-2,3-expoxypropane) + SX, PSCP (phenylsaligenin cyclic phosphate) + SX, TBPT (S,S,S-tributyl phosphorotrithioate) + SX, and TPP (triphenyl phosphate) + SX.

[0048] It is preferable to include one or more compounds selected from the group consisting of the following compounds, among the other insecticidal compounds and synergens that may be further contained as described above: cypermethrin, alpha-cypermethrin, bifensrin, cyfluthrin, beta-cyfluthrin, lambda-cyhalothrin, deltamethrin, esfenvalerate, etofenprox, prallethrin, permethrin, pyrethrin, chlorfenapyr, abamectin, acetamiprid Clothianidin, dinotefuran, resmethrin, imidacloprid, thiamethoxam, thiacloprid, indoxacarb, brofranilide, fenitrothion, cyphenothrin, pyriproxyfen, fipronil, phenothrin, sulfoxaflor, brofranilide, pirimiphosmethyl, benziocarb, piperonyl butoxide, N-(2-ethylhexyl)-8,9,10-trinorborn-5-en-2,3-dicarboximide.

[0049] The weight ratio of this compound to the total of other insecticidal compounds and synergists is typically 0.01 to 100 parts by weight, preferably 0.02 to 50 parts by weight, of the other insecticidal components per 1 part by weight of this compound.

[0050] Furthermore, the content of the compound in the pest control agent according to this embodiment is not limited, but is usually 0.1 to 99.9% by weight, preferably 1 to 90% by weight, and more preferably 3 to 80% by weight.

[0051] In the pest control method according to this embodiment, the control agent according to this embodiment may be used as is, or it may be used after being appropriately diluted with water or suspended. The amount used is usually preferably at a concentration of 0.0001 to 5000 ppm of the active ingredient, and more preferably at a concentration of 0.01 to 1000 ppm.

[0052] Furthermore, the control agent according to this embodiment may be mixed with other types of nematicides, fungicides, synergists, etc., during application as needed.

[0053] In this specification, places where sanitary pests may pass through or inhabit include houses, commercial facilities, hospitals, train stations, airports, factories, offices, schools, accommodation facilities, waste disposal facilities, livestock barns, warehouses, tents, vehicles, airplanes, ships, various products, the ground, forests, pastures, drainage ditches, etc. More specifically, this includes walls, ceilings, floors, underfloors, pillars, transoms, windows, doors, or materials containing cellulose components (wooden products, etc.) in the above-mentioned places where sanitary pests may pass through or inhabit.

[0054] Treatment of areas where sanitary pests may pass through or where sanitary pests may inhabit is carried out by spraying, coating and evaporating, or a combination of these methods with the control agent according to this embodiment.

[0055] Materials that can allow sanitary pests to pass through or inhabit include, but are not limited to, concrete (cement), brick, bamboo, wood, tile, ceramic, mud, metal, plastic, thatched roof, and corrugated iron.

[0056] By applying the control agent to the surface of areas where sanitary pests may pass through or where they may live, the active ingredient can be immobilized on the surface. The amount of active ingredient to be immobilized may be adjusted as appropriate depending on the timing of application, the location of application, the treatment method, etc. For example, 1 m 2 The amount of active ingredient per serving is typically 5 to 1000 mg, preferably 5 to 500 mg, and more preferably 5 to 300 mg.

[0057] When using this pest control agent to control pests that reach and damage buildings through the soil, it can be applied to the soil under the building's floor. In this case, treatment methods such as strip application, surface application, soil surface film formation, foam application, and soil surface sheet laying can be used.

[0058] Examples of sanitary pests that can be controlled by the control agent and sanitary pest control method according to this embodiment include arthropods and mollusks that harm humans and livestock, as well as arthropods and mollusks that are disliked due to their unpleasant shape or large outbreaks (also referred to as nuisance pests). Specifically, examples include the following:

[0059] Arthropods Order Blattodea: Includes species such as the German cockroach (Blattella germanica) and the family Ectobiidae; and species such as the American cockroach (Periplaneta fuliginosa), the Oriental cockroach (Periplaneta americana), the American cockroach (Periplaneta australasiae), the brown cockroach (Periplaneta brunnea), the Eastern cockroach (Blatta orientalis), the Turkestan cockroach (Blatta lateralis), and the brown-banded cockroach (Supella longipalpa) and others (Blattidae).Japanese termite (Reticulitermes speratus), Formosanus termite (Coptotermes formosanus), Gestor's termite (Coptotermes gestroi), American drywood termite (Incisitermes minor), Cryptotermes domesticus, Taiwanese termite (Odontotermes formosanus), Koshun termite (Neotermes koshunensis), Satsuma termite (Glyptotermes satsumensis), Nakajima termite (Glyptotermes nakajimai), Katan termite (Glyptotermes fuscus), Giant termite (Hodotermopsis sjostedti), Koshu termite (Coptotermes guangzhouensis), Amami termite (Reticulitermes Termites (Termitidae) include species such as amamianus, Reticulitermes miyatakei, Reticulitermes kanmonensis, Nasutitermes takasagoensis, Pericapritermes nitobei, Sinocapritermes mushae, Cornitermes cumulans, Reticulitermes flavipes, Cryptotermes brevis, Cryptotermes havilandi, Macrotermes gilvus, Schedorhinotermes medioobscurus, Microcerotermes crassus, Nasutitermes javanicus, Coptotermes kalshoveni, Nasutitermes corniger, Heterotermes tenuis, Coptotermes curvignathus, and Coptotermes acinaciformis. ; Order Siphonaptera: Includes the families Pulicidae (human fleas such as Pulex irritans, cat fleas such as Ctenocephalides felis, dog fleas such as Ctenocephalides canis, cheopsylla cheopis, and chicken fleas such as Echidnophaga gallinacea); the families Hectopsyllidae (sand fleas such as Tunga penetrans); and the families Ceratophyllidae (long-nosed fleas such as Nosopsyllus fasciatus). Order Psocodae: Family Trogiidae, including species like Trogium pulsatorium; Family Liposcelidae (or Liposcelididae), including species like Liposcelis corrodens, Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelis entomophila. Silverfish (Thysanura): Includes species such as the Japanese silverfish (Ctenolepisma villosa) and the European silverfish (Lepisma saccharina), belonging to the family Lepismatidae. Order Acari: Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysalis japonica, Haemaphysalis campanulata, Dermacentor variabilis, Dermacentor taiwanensis, Dermacentor andersoni, Dermacentor reticulatus, Ixodes ovatus, Ixodes persulcatus, Ixodes scapularis, Ixodes pacificus, Ixodes holocyclus, Ixodes ricinus, Lone Star tick (Amblyomma) Ixodidae ticks such as *Ixodidae americanum*, *Amblyomma maculatum*, *Rhipicephalus microplus*, *Rhipicephalus annulatus*, *Rhipicephalus sanguineus*, *Rhipicephalus appendiculatus*, and *Rhipicephalus decoloratus*; Argasidae ticks such as *Argas persicus*, *Ornithodoros hermsi*, and *Ornithodoros turicata*; Acaridae ticks such as *Tyrophagus putrescentiae* and *Tyrophagus similis*; Dermatophagoides farinae and Dermatophagoides Pyroglyphidae (family of dust mites), such as *Pteronyssinus*;Cheyletidae mites such as Cheyletus eruditus, Cheyletus malaccensis, Chelacaropsis moorei, and Cheyletiella yasguri; Psoroptidae mites such as Psoroptes ovis, Psoroptes equi, Knemidocoptes mutans, Otodectes cynotis, and Chorioptes spp.; Sarcoptidae mites such as Notoedres cati, Notoedres muris, and Sarcoptes scabiei; and Listrophorus Listrophoridae (e.g., gibbus); Dermanyssidae (e.g., Dermanyssus gallinae); Macronyssidae (e.g., Ornithonyssus sylviarum, Ornithonyssus bacoti); Varroidae (e.g., Varroa jacobsoni); Demodicidae (e.g., Demodex canis, Demodex cati); Leptotrombidium akamushi, Leptotrombidium pallidum, Leptotrombidium The family Trombiculidae, including species like *Trichoptera*. Hymenoptera: Genus Solenopsis (including red imported fire ants (Solenopsis invicta), red imported fire ants (Solenopsis geminata), Southern fire ants (Solenopsis xyloni), black imported fire ants (Solenopsis richteri), etc.), Genus Atta (including brown leaf-cutting ants (Atta capiguara), etc.), Genus Acromyrmex (Acromyrmex spp.), bullet ants (Paraponera clavata), blue ants (Ochetellus glaber), house ants (Monomorium pharaonis), Argentine ants (Linepithema humile), black garden ants (Formica japonica), reticulated ants (Pristomyrmex punctutus), large-headed ants (Pheidole noda), glossy large-headed ants (Pheidole This includes species such as *Camponotus megacephala*, *Camponotus japonicus*, *Camponotus obscuripes*, *Camponotus pennsylvanicus*, *Camponotus floridanus*, and *Camponotus modoc* (all belonging to the *Camponotus* spp.) (including *Camponotus megacephala*), *Camponotus japonicus*, *Camponotus obscuripes*, *Camponotus pennsylvanicus*, *Camponotus floridanus*, and *Camponotus modoc* (all belonging to the *Camponotus* spp.) (including *Pogonomyrmex sp.*, *Pogonomyrmex occidentalis*, and *Pogonomyrmex spp.*) (all belonging to the *Pogonomyrmex* spp.This includes species such as the Formicidae family (Formicidae), including the Odras house ant (Tapinoma sessile), pavement ant (Tetramorium caespitum), pyramid ant (Dorymyrmex insanus), European fire ant (Myrmica rubra), and long-legged ant (Anoplolepis gracilipes); the Vespidae family (Vespa mandarinia), hairy hornet (Vespa simillima), small hornet (Vespa analis), Asian hornet (Vespa velutina), and black-legged paper wasp (Polistes jokahamae); the Siricidae family (Siricidae), including the fir tree wasp (Urocerus gigas); and the Bethylidae family. Coleoptera: Weevils (Curculionidae), such as Sitophilus zeamais, Sitophilus oryzae, and Sitophilus granarius; Tenebrionidae, such as Tribolium castaneum, Tribolium confusum, and Alphitobius diaperinus; Bostrychidae, such as Lyctus brunneus and Rhizopertha dominica; Ptinidae; Longhorn beetles (Anoplophora malasiaca), Migdolus Cerambycidae family, including *fryanus* and *Aromia bungii*; *Melanotus okinawensis*, *Agriotes fuscicollis*, *Melanotus legatus*, *Anchastus* spp., *Conoderus* spp., *Ctenicera* spp., *Limonius* spp., and *Aeolus* spp.Elateridae (such as the green-leaved rove beetle); Staphylinidae (such as Paederus fuscipes); Dermestidae (such as Anthrenus verbasci, Dermestes maculates, and Trogoderma granarium); Anobiidae (such as Lasioderma serricorne and Stegobium paniceum); Laemophloeidae (such as Cryptolestes ferrugineus); and Oryzaephilus This includes species such as *Silvanidae* (e.g., *Silvanis surinamensis*) and *Nitidulidae* (e.g., *Brassicogethes aeneus*, the blossom beetle). Diptera: Drosophilidae (e.g., Drosophila suzukii, Drosophila melanogaster); Phoridae (e.g., Megaselia spiracularis); Psychodidae (e.g., Clogmia albipunctata); Sciaridae (e.g., Bradysia difformis); Culex pipiens pallens, Culex tritaeniorhynchus, Culex pipiens f. molestus, Culex quinquefasciatus, Culex pipiens Culicidae mosquitoes such as pipiens, Culex vishnui, Aedes albopictus, Aedes aegypti, Anopheles sinensis, Anopheles gambiae, Anopheles stephensi, Anopheles freeborni, Anopheles punctipennis, Anopheles quadrimaculatus, Anopheles coluzzii, Anopheles albimanus, Anopheles sundaicus, Anopheles arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus, etc.; Prosimulium yezoensis), clawed black fly (Simulium ornatum), black fly (Simulium spp.) and other gnats (Simulidae); horseflies (Tabanus trigonus), black houseflies (Tabanus atratus), striped houseflies (Tabanus lineola), deer flies (Chrysops sp.), and other flies (Tabanidae); houseflies (Musca domestica), giant houseflies (Muscina stabulans), stable flies (Stomoxys calcitrans), broad stable flies (Haematobia irritans), and other flies (Muscidae); blowflies (Lucilia sp., Calliphora sp.), and other flies (Calliphoridae); flesh flies (Sarcophaga sp., Wohlfahrtia sp.), and other flies (Sarcophagidae); midges (Leptoconops sp.), and other midges (Chironomus) Chironomidae (family Chironomidae), including species such as *Chironomus plumosus*, *Chironomus yoshimatsui*, and *Glyptotendipes tokunagai*; Fannidae (family Fannidae). Lepidoptera: Family Tineidae, which includes clothes moths (Tinea translucens), clothes moths (Tineola bisselliella), etc. Hemiptera: Bed bugs (Cimex lectularius), tropical bed bugs (Cimex hemipterus), and other species of the Cimicidae family; cicadas (Quesada gigas), and other species of the Cicadidae family; assassin bugs (Triatoma infestans), giant assassin bugs (Triatoma rubrofasciata), Triatoma dimidiata, nose bugs (Triatoma sanguisuga), kissing bugs (Triatoma protracta), Venezuelan assassin bugs (Rhodonius prolixus), and other species of the Reduviidae family. Order Araneae: Eutichuridae (e.g., Cheiracanthium japonicum); Theridiidae (e.g., Latrodectus hasseltii). Order Polydesmida: Family Paradoxosomatidae, which includes species such as the red millipede (Oxidus gracilis) and the red millipede (Nedyopus tambanus). Isopoda: Family Armadillidiidae, which includes the common pill bug (Armadillidium vulgare). Chilopoda: Scutigeridae (house centipedes such as Thereuonema hilgendorfi); Scolopendridae (centipedes such as Scolopendra subspinipes); Ethopolyidae (centipedes such as Bothropolys rugosus).

[0060] Mollusks Gastropoda: Limacidae (family Limacidae, including Limax marginatus and Limax flavus); Philomycidae (family Philomycidae, including Meghimatium bilineatum); Ampullariidae (family Pomacea canaliculata, etc.); Lymnaeidae (family Lymnaeidae, including Austropeplea ollula, etc.). [Examples]

[0061] The present invention will be described in more detail below with reference to examples such as formulations and test examples, but the present invention is not limited to these examples.

[0062] First, we will show some examples of formulations. Note that "parts" refers to parts by weight.

[0063] Formulation Example 1 A formulation is obtained by mixing 35 parts of a mixture of polyoxyethylene alkyl ether sulfate ammonium salt and silica (weight ratio 1:1), 10 parts of SX, and 55 parts of water, and then finely grinding the mixture using a wet grinding method.

[0064] Formulation Example 2 A formulation is obtained by grinding and mixing 50 parts of SX, 3 parts of calcium ligninsulfonate, 2 parts of sodium lauryl sulfate, and 45 parts of silica.

[0065] Formulation Example 3 A formulation is obtained by mixing 5 parts of SX, 9 parts of polyoxyethylene styrylphenyl ether, 5 parts of polyoxyethylene decyl ether (ethylene oxide addition number: 5), 6 parts of calcium dodecylbenzenesulfonate, and 75 parts of xylene.

[0066] Formulation Example 4 The formulation is obtained by grinding and mixing 2 parts SX, 1 part silica, 2 parts calcium ligninsulfonate, 30 parts bentonite, and 65 parts kaolin clay, adding an appropriate amount of water and kneading, granulating with a granulator, and then drying.

[0067] Formulation Example 5 Ten parts of SX are mixed with a mixture of eighteen parts of benzyl alcohol and nine parts of DMSO. To this mixture, six and a half parts of GERONOL® TE250, two and a half parts of Ethylan NS-500LQ®, and five and a half parts of solvent naphtha are added and mixed to obtain the formulation.

[0068] Formulation Example 6 A formulation is obtained by mixing 10 parts of SX, 5 parts of nonylphenol ethoxylate, and 85 parts of propylene glycol.

[0069] Formulation example 7 A formulation is obtained by mixing 10 parts of SX and 20 parts of xylene and dispersing the mixture in 68 parts of water containing 2 parts of polyvinyl alcohol.

[0070] Formulation example 8 The preparation is obtained by grinding and mixing 30 parts of SX, 3 parts of calcium ligninsulfonate, 2 parts of sodium lauryl sulfate, and 65 parts of kaolin clay, adding an appropriate amount of water and kneading, granulating with a granulator, and then drying.

[0071] Formulation example 9 A mixture of polyoxyethylene alkyl ether sulfate ammonium salt and white carbon (weight ratio 1:1) is mixed with 10 parts of SX and 55 parts of water. The mixture is then finely ground by a wet grinding method, and the resulting mixture is granulated using a fluidized bed granulator to obtain a formulation.

[0072] Formulation example 10 A formulation is obtained by mixing 20 parts of SX, 5 parts of polyoxyethylene nonylphenyl ether, 3 parts of carboxymethylcellulose, and 72 parts of water.

[0073] Formulation Example 11 Mix 10 parts of SX, 0.2 parts of hexamethylene diisocyanate, and 10 parts of xylene, and disperse in 75.8 parts of water containing 2 parts of polyvinyl alcohol. Add 2 parts of ethylenediamine and proceed with the encapsulation reaction while mixing to obtain the formulation.

[0074] Formulation Example 12 The formulation is obtained by grinding and mixing 2 parts SX, 88 parts kaolin clay, and 10 parts talc.

[0075] Formulation Example 13 Mix 60 parts of SX, 10 parts of special aromatic sodium sulfonate formalin condensate (product name: Demol SN-B, manufactured by Kao Corporation), 4 parts of sodium lauryl sulfate (product name: Emal 10 Powder, manufactured by Kao Corporation), and 26 parts of kaolin-based clay (product name: A Clay, manufactured by Katsumitsuyama Mining Co., Ltd.), then grind it with an air mill. Next, 11 parts of water are added to the pulverized material and thoroughly kneaded. The resulting mixture is then granulated using a small extruder with a 0.7 mm diameter screen, dried at 60°C for 10 minutes, and sized to obtain a granular wettable powder.

[0076] Formulation Example 14 Mix 50 parts of SX, 3.0 parts of sodium diisopropylnaphthalene sulfonate, 4.0 parts of sodium sulfomethylated lignin sulfonate, 0.25 parts of sodium cellulose carboxymethyl ether salt, 1.0 part of amorphous silica, and 41.75 parts of lactose, and grind them in an air mill. Next, 10 parts of water are added to the pulverized material and kneaded together. The resulting mixture is then granulated using a small extruder with a 1.0 mm diameter screen, dried at 60°C for 10 minutes, and sized to obtain a granular wettable powder.

[0077] Formulation Example 15 Mix 3.4 parts of SX4, 0.2 parts of a silicone-based antifoaming agent (product name: Xiameter ACP-1500 Antifoam compound, manufactured by Toray Dow Corning), 3.4 parts of polyoxyethylene tristyrylphenyl ether phosphate triethanolamine salt (product name: Soprofoll FL, manufactured by Solvey), 4.3 parts of propylene glycol, and 20.5 parts of deionized water, and wet grind them in a bead mill to obtain a suspension. Next, 0.3 parts of aluminum magnesium silicate (trade name: BeeGum®, manufactured by Vanderbilt Minerals, LLC), 0.2 parts of xanthan gum (trade name: Kelzan, manufactured by CP Kelco), and 0.2 parts of a preservative (containing 1,2-benzoisothiazolin-3-one as the active ingredient, trade name: Proxel GXL, manufactured by Lonza) are mixed, dissolved, and dispersed in 27.5 parts by weight of deionized water to prepare a thickening agent solution, which is then mixed with the above-mentioned suspension to obtain an aqueous suspension pesticide composition.

[0078] Formulation Example 16: Mix 40 parts of SX, 5 parts of sodium ligninsulfonate (product name: Reax 85A, manufactured by Ingevity, weight-average molecular weight 10000, degree of sulfonation 0.8), 0.5 parts of silicone-based antifoaming agent (product name: Xiameter ACP-1500 Antifoam compound, manufactured by Toray Dow Corning), 5 parts of propylene glycol, 1 part of silica (product name: Aerosil COK-84, manufactured by Evonik), and 48.3 parts of deionized water. Then, wet grinding is performed using a horizontal bead mill (product name: DYNO-MILL KDL, manufactured by WILLY A.BACHOFEN AG Maschinenfabrik) to obtain a suspension. To the obtained suspension, 0.2 parts of a preservative (containing 1,2-benzoisothiazolin-3-one as the active ingredient, trade name: Proxel GXL, manufactured by Lonza) are added and mixed to obtain the aqueous suspension composition of the present invention.

[0079] Next, the pest control effect of the present invention will be demonstrated in a test example.

[0080] Furthermore, this document specifically demonstrates that this compound has an effect in controlling sanitary pests. Note that Compound A, Compound B, and Comparative Compounds 1-4 are the compounds listed in Table 2. Comparative Compounds 1 and 2 are the compounds described in Patent Document 4, and Comparative Compounds 3 and 4 are the compounds described in Patent Document 3.

[0081] [Table 2]

[0082] The excellent pest control effect of this compound can be confirmed, for example, from the following test examples.

[0083] Test Example 1 A 0.2 mL acetone solution (with 0.09% surfactant added) containing predetermined weights of compound A, compound B, comparative compound 1, comparative compound 2, comparative compound 3, and comparative compound 4 was dropped into a 20 mL vial. The solution was uniformly coated on the inner wall of the vial and air-dried. Then, five German cockroaches were released into the vial and the lid was closed. After 6 hours, the number of dead and suffering German cockroaches was investigated, and the percentage of cockroaches dying from suffering was calculated using formula 1 below. A dead individual is defined as an individual that has completely stopped moving, and a suffering individual is defined as an individual that cannot get up when placed on its back and is unable to walk. The percentage of insects that died from bitterness obtained from the experiment is shown in Table 3. (Formula 1) The rate of insects dying from suffering (%) = {(number of dead individuals + number of individuals suffering) / number of individuals tested} × 100 The processing rates per unit area are 1000, 300, 150, 50, and 5 mg / m². 2 That's what I decided.

[0084] [Table 3]

[0085] Test Example 2 A 1.0 mL acetone solution (with 0.09% surfactant added) containing a predetermined weight of compound A, compound B, and comparative compounds 1, 2, 3, and 4 was dropped into a 250 mL vial, coated uniformly on the inner wall of the vial, and air-dried. Then, a predetermined number of adult female Anopheles gambier mosquitoes were released into the vial, the lid was closed, and the vial was exposed for 50 minutes. After 50 minutes of exposure, the mosquitoes were transferred to a new plastic cup, given sugar water, and the number of individuals suffering from distress and those that died was investigated after 4 days. The distress death rate (%) was calculated using Equation 2. A dead individual is defined as an individual that has completely ceased activity, and a distressed individual is defined as an individual that is unable to fly or walk. The percentage of insects that died from bitterness obtained from the experiment is shown in Table 4. (Formula 2) The rate of insects dying from suffering (%) = {(number of dead individuals + number of individuals suffering) / number of individuals tested} × 100 The processing rates per unit area are 300, 10, and 5 mg / m². 2 That's what I decided.

[0086] [Table 4]

[0087] Test Example 3 0.2 mL of an acetone solution (with 0.09% surfactant added) containing predetermined weights of compound A, compound B, comparative compound 1, comparative compound 2, comparative compound 3, and comparative compound 4 was dropped into a 20 mL vial. The solution was uniformly coated on the inner wall of the vial and air-dried. Then, house ant workers were released into the vial and the lid was closed. After 1 hour, the house ants in the vial were transferred to a new plastic cup and given 3% sucrose water. After 1 day, the number of dead and suffering individuals was investigated, and the rate of death due to suffering (%) was calculated using formula 3 below. A dead individual is defined as an individual that has completely stopped moving, and a suffering individual is defined as an individual that cannot get up when placed on its back and is unable to walk. The percentage of insects that died from bitterness obtained from the experiment is shown in Table 5. (Formula 3) The rate of insects dying from suffering (%) = {(number of dead individuals + number of individuals suffering) / number of individuals tested} × 100 The processing rates per unit area are 300, 100, and 5 mg / m². 2 That's what I decided.

[0088] [Table 5]

[0089] Test Example 4 A 0.6 mL acetone solution containing predetermined weights of compound A, compound B, and comparative compounds 1, 2, 3, and 4 was uniformly dropped onto 82 mm diameter filter paper and air-dried. The filter paper was then placed in a 90 mm diameter plastic petri dish with 1.4 mL of water, ensuring there were no gaps. Worker termites were released into the dish, the lid was closed, and the dish was exposed for 1 hour. After 1 hour of exposure, the termites were transferred to a new plastic cup with filter paper on the bottom, given water, and the number of distressed and dead individuals was investigated after 3 days. The distress death rate (%) was calculated using Equation 4. A dead individual is defined as an individual that has completely ceased activity, while a distressed individual is defined as an individual that is unable to fly or walk. The percentage of insects that died from bitterness obtained from the experiment is shown in Table 6. (Formula 4) The rate of insects dying from suffering (%) = {(number of dead individuals + number of individuals suffering) / number of individuals tested} × 100 The processing rates per unit area are 1000, 500, and 300 mg / m². 2 That's what I decided.

[0090] [Table 6] From this, it was found that compounds A and B have superior control effects against sanitary pests compared to comparative compounds 1-4. [Industrial applicability]

[0091] The pest control method of the present invention makes it possible to easily control sanitary pests.

Claims

1. Equation (I): 【Chemistry 1】 [During the ceremony, R １ This represents a C1-C3 haloalkoxy group, a C1-C3 haloalkylthio group, a C1-C3 haloalkylsulfinyl group, or a C1-C3 haloalkylsulfonyl group, and R ２ [This represents a hydrogen atom or a cyano group.] A sanitary pest control agent containing at least one compound selected from the group consisting of compounds represented by, their N oxides, and their salts as an active ingredient, is provided for 1 m ２ A method for controlling sanitary pests, comprising treating areas where sanitary pests may pass through, areas where sanitary pests may live, or both, such that the amount of active ingredient per area is 5 to 1000 mg.

2. 1m ２ The method for controlling sanitary pests according to claim 1, wherein the amount of active ingredient per dose is 5 to 300 mg.

3. In equation (I), R １ is a trifluoromethylsulfinyl group or a trifluoromethylsulfonyl group, and R ２ The method for controlling sanitary pests according to claim 1 or 2, wherein is a hydrogen atom.

4. A method for controlling sanitary pests according to any one of claims 1 to 3, wherein the place where sanitary pests can pass through or live, or both, is a surface constituting an indoor or outdoor structure, or a surface surrounding the structure.

5. The method for controlling sanitary pests according to claim 4, wherein the treatment of the sanitary pest control agent includes supporting the compound of formula (I) on any of the surfaces.

6. The method for controlling sanitary pests according to any one of claims 1 to 5, wherein the sanitary pest control agent further contains at least one active ingredient.

7. The method for controlling sanitary pests according to claim 6, wherein the active ingredient is at least one selected from the group consisting of cypermethrin, alpha-cypermethrin, bifensrin, cyfluthrin, beta-cyfluthrin, lambda-cyhalothrin, deltamethrin, esfenvalerate, etofenprox, prallethrin, permethrin, pyrethrin, chlorfenapyr, abamectin, acetamiprid, clothianidin, dinotefuran, resmethrin, imidacloprid, thiamethoxam, thiacloprid, indoxacarb, brofranilide, fenitrothion, cyphenothrin, pyriproxyfen, fipronil, phenothrin, sulfoxaflor, brofranilide, pirimiphosmethyl, benziocarb, piperonyl butoxide, and N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide.

8. A method for controlling sanitary pests according to any one of claims 1 to 7, wherein the sanitary pest is at least one type of sanitary pest selected from the group consisting of sanitary pests of the orders Blattodea, Hymenoptera, Diptera, Fleas, Acari, Lepidoptera and Coleoptera.

9. A method for controlling sanitary pests according to any one of claims 1 to 8, comprising diluting the aforementioned sanitary pest control agent with water and spraying it for treatment.

10. The method for controlling sanitary pests according to any one of claims 1 to 9, wherein the sanitary pest control agent is an oil formulation, emulsion, wettable powder, granular wettable powder, flowable formulation, or microcapsule formulation.

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