Spectrometer device and spectrometer system
Patent Information
- Application Number
- JP2020532921
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Priority Date
- 2017-12-13
- Filing Date
- 2018-12-12
- Publication Date
- 2025-02-18
- Estimated Expiration
- 2038-12-12
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Abstract
Description
[Technical field]
[0001] The present invention relates to a spectrometer device, a spectrometer system including the spectrometer device, and various uses of the spectrometer device and the spectrometer system. Such devices and systems may be generally employed for surveillance or monitoring, particularly in the infrared (IR) spectral region, in particular the near infrared (NIR) and mid infrared (MidIR) spectral regions, and for heat, flame, fire or smoke detection. However, further types of applications are possible. [Background technology]
[0002] Various spectrometer devices and systems for the investigation of the infrared (IR) spectral region, in particular the near infrared (NIR) spectral region, are known. In particular, spectrometer devices have already been proposed that have a combination of a linear variable filter (LVF) and a detector array. Here, the LVF is assigned to separate the light captured from an object into a spectrum of constituent wavelength signals, while the detector array includes a plurality of pixels, each of which is arranged to receive at least a portion of the plurality of constituent wavelength signals providing an output measurement value for each of the constituent wavelengths. Usually, a baffle is used for this purpose in order to make the incident light strike the LVF in a manner perpendicular to the receiving surface of the LVF, but this generally results in a low light throughput and a low signal-to-noise ratio.
[0003] US 2014 / 131578 A1 discloses a mobile spectrometer device having an illumination source that directs light to a sample and delivers the light to an LVF at a second focal ratio lower than the first focal ratio, together with a tapered light pipe (TLP) that captures the light interacting with the sample at a first focal ratio. Preferably, the TLP is embedded in a protective boot with a lens at one end and a stepped inner wall. Furthermore, the gap between the TLP and the LVF is minimized to further improve resolution and robustness. It is emphasized here that the TLP disclosed herein can also be referred to as a "light collector", and that the light collector includes a conical shape that is operated in the opposite direction to spread the captured light and reduce the angular spread of the captured light.
[0004] However, concentrators including conical geometries suffer from low focusing efficiency, as described for example in S. Madala and RF Boehm, "Effect of Reflection Losses on Stationary Dielectric-Filled Nonimaging Concentrators," J. Photonics for Energy 6(4), 047002, 2016. As further explained by S. Madala et al., the effect of Fresnel reflection and total internal reflection (TIR) losses on the performance parameters of refractive nonimaging solar concentrators affects the performance parameters and thus the energy collection. To this end, S. Madala et al. performed a ray tracing analysis to illustrate the effect of Fresnel reflection and TIR losses on four different types of stationary dielectric-filled nonimaging concentrators, including conical concentrators (V-trough concentrators), compound parabolic concentrators (CPCs), compound elliptical concentrators (CECs), and compound hyperbolic concentrators (CHCs). They found that the refractive index (RI) of the dielectric fill material determines the acceptance angle of a solid non-imaging concentrator: a larger refractive index results in a larger acceptance angle and therefore greater energy collection, but also increases Fresnel reflection losses.
[0005] Lun J. and R. Winston et al., "Asymmetric design of compound elliptical concentrators (CECs) and its influence on geometric flux", Proc. SPIE, 9572, 2015, provides a theoretical paper on asymmetric compound elliptical concentrators (CECs) as a further non-imaging optical element. Here, they state that the traditional way of understanding an ideal concentrator is based on maximizing the concentration ratio based on a uniform acceptance angle. Although such an angle does not exist for CECs, the thermodynamic laws still apply, and to solve this general problem, by using the string method, the concentrator has been considered with the maximum concentration ratio allowed by it. The result is a group of ideal concentrators using the geometric flux field or flow line method.
[0006] No. 5,615,673 A discloses a compound parabolic concentrator (CPC) used to optically collect the Raman scattered light returning from a region of interest, where the CPC is a non-imaging optical element used in a conventional configuration that converts the light emitted over a full hemisphere into a narrow cone that can be collected by conventional optics such as optical fibers and lenses.
[0007] US 2016 / 151009 A1 discloses a sensor for the detection of gases, in particular for the detection of CO2, in which a numerical aperture converter (NA converter) is arranged in the path between a wavelength filter and a radiation source. Here, the NA converter is created as an aperture in a reflective or opaque material, having the shape of a compound parabolic or compound elliptical concentrator. Alternatively, a NA filter can be used, which corresponds to the NA converter except that it limits the angular spread of the light beam by absorbing high-angle rays instead of converting them.
[0008] US 2008 / 156969 A1 discloses an optical deflection element having a non-conical shape, a bandpass filter array, and a detector array, where the optical deflection element as an optical element spectrally shifts the effective bandpass curves of the bandpass filters of all filter groups except one, making the spectral positions of the effective bandpass curves of all bandpass filters different. As a result, the multiplication of filter channels can be realized using only a few different bandpass filters. Summary of the Invention [Problem to be solved by the invention]
[0009] The problem solved by the present invention is therefore to provide a spectrometer device and a spectrometer system which may be particularly suitable for investigations in the infrared (IR) spectral region, in particular the near infrared (NIR) spectral region, and which at least substantially avoids the disadvantages of known devices and systems of this type.
[0010] In particular, it would be desirable to provide an improved simple, cost-effective, and reliable spectrometer device having optical elements designed to capture light from an object and transmit the captured light to a linear variable filter with a higher concentration ratio than is currently possible. [Means for solving the problem]
[0011] This problem is solved by the invention with the features of the independent patent claims. Advantageous developments of the invention, which can be implemented individually or in combination, are set out in the dependent claims and / or in the following description and detailed embodiments.
[0012] As used herein, the terms "having," "comprising," and "including," as well as grammatical variations thereof, are used in a non-exclusive manner. Thus, the terms "A has B," as well as "A includes B" or "A comprises B," can refer both to the fact that A includes one or more further parts and / or configurations in addition to B, and to the case where there are no other parts, configurations, or elements in A other than B.
[0013] In a first aspect of the present invention, a spectrometer device is disclosed. Accordingly, the spectrometer device comprises: - an optical element designed to receive incident light from an object and transmit the incident light to a variable length filter, the optical element having a concentrator, the concentrator operating in a reverse direction, the concentrator comprising a non-conical shape; - a variable length filter assigned to separate the incident light into a spectrum of constituent wavelength signals; and - a detector array having a plurality of pixelated sensors, each pixelated sensor adapted to receive at least a portion of one of the constituent wavelength signals, each constituent wavelength signal related to an intensity of each constituent wavelength; has.
[0014] An "object" may generally be any object selected from living objects and non-living objects. Thus, by way of example, the at least one object may include one or more articles and / or one or more parts of an article, and the at least one article or at least one part thereof may include at least one configuration that may provide a spectrum suitable for interrogation. Additionally or alternatively, the object may be or include one or more living organisms and / or one or more parts thereof, e.g., a human being, such as a user, and / or one or more body parts of an animal.
[0015] The term "light" as used herein generally refers to a division of electromagnetic radiation, usually referred to as the "optical spectrum range", including one or more of the visible spectrum range, the ultraviolet spectrum range, and the infrared spectrum range. As used herein, the term "ultraviolet spectrum range" generally refers to electromagnetic radiation having wavelengths between 1 nm and 380 nm, preferably between 100 nm and 380 nm. Furthermore, in part in accordance with the standard ISO-21348 in its effective version as of the date of this document, the term "visible spectrum range" generally refers to the spectral range between 380 nm and 760 nm. The term "infrared spectrum range" (IR) generally refers to electromagnetic radiation between 760 nm and 1000 μm, with the range between 760 nm and 1.5 μm usually referred to as the "near infrared spectrum range" (NIR), the range between 1.5 μm and 15 μm usually denoted as the "mid infrared spectrum range" (MidIR), and the range between 15 μm and 1000 μm usually denoted as the "far infrared spectrum range" (FIR). Preferably, the light used for typical purposes of the present invention is light in the infrared (IR) spectral range, more preferably light in the near infrared (NIR) and mid-infrared spectral range (MidIR), in particular light having a wavelength between 1 μm and 5 μm, preferably between 1 μm and 3 μm.
[0016] The light leaving the object may originate from the object itself, but alternatively may have another source and may propagate from this source to the object and subsequently towards the spectrometer device. In the latter case, it may be influenced in particular by the at least one illumination source used. Thus, the light propagating from the object to the spectrometer device may be light that may be reflected by the object and / or by a reflecting device connected to the object. Alternatively or additionally, the light may be at least partially transmitted through the object.
[0017] The illumination source can be embodied in various ways. Thus, the illumination source can be, for example, part of the spectrometer device in the housing. Alternatively or additionally, however, the at least one illumination source can be configured outside the housing, for example as a separate light source. The illumination source can be arranged separately from the object and illuminate the object from a distance. As mentioned above, the illumination source can alternatively or additionally be connected to the object or be part of the object, for example the electromagnetic radiation leaving the object is directly generated by the illumination source. By way of example, the at least one illumination source can be arranged on and / or in the object and generate the electromagnetic radiation directly.
[0018] The illumination source can preferably include a type of illumination source known to provide sufficient radiation in the infrared (IR) spectral range, in particular in the near infrared (NIR) spectral range, in particular incandescent light. Alternatively or additionally, the illumination source can be selected from at least one of the following illumination sources: flame source; heat source; laser, in particular laser diode, although other types of lasers can also be used; light-emitting diode; organic light source, in particular organic light-emitting diode; neon light; structured light source. Alternatively or additionally, other illumination sources can also be used. It is particularly preferred here when the light emitted by the object and / or illumination source exhibits a spectral range that is closely related to the spectral sensitivity of the detector array, in a manner that ensures that the detector array that can be illuminated by the respective illumination source can provide a particularly high intensity detector signal, and therefore can be evaluated with a sufficient signal-to-noise ratio and at the same time with high resolution.
[0019] As commonly used, the term "spectrum" refers to a section of an optical spectral range, specifically the infrared (IR) spectral range, especially the near infrared (NIR) spectral range, where each part of the spectrum is constituted by an optical signal defined by a signal wavelength and a corresponding signal intensity. Furthermore, the term "spectrometer device" refers to a device capable of recording signal intensities for a section of the spectrum, such as a corresponding wavelength or wavelength interval of the spectrum, where the signal intensity can preferably be provided as an electrical signal that can be used for further evaluation. In the spectrometer device according to the invention, a variable length filter is used to decompose the incident light into a spectrum of constituent wavelength signals whose corresponding intensities are determined using a detector array as described in more detail below. Furthermore, an optical element is applied that receives the incident light from the object and transmits it to the variable length filter. As further used herein, a "spectrometer system" may therefore refer to a device that, in addition to the spectrometer device, comprises an evaluation unit that is assigned to determine information regarding the spectrum of the object by evaluating the detector signals provided by the spectrometer device as disclosed herein.
[0020] Thus, according to the invention, the spectrometer device comprises a variable length filter assigned to separate the incident light into a spectrum of constituent wavelength signals. As commonly used, the term "variable length filter" refers to an optical filter including a plurality of filters, preferably a plurality of interference filters, which may in particular be provided in a serial arrangement of filters. Here, each filter may form a bandpass with a variable center wavelength for each spatial position on the filter, preferably continuously along a single dimension, which is usually expressed in terms of "length" on the receiving surface of the variable length filter. In a preferred example, the variable center wavelength may be a linear function of the spatial position on the filter, in which case the variable length filter is usually referred to as a "linear variable filter" or its abbreviation "LVF". However, other types of functions may be applicable to the relationship between the variable center wavelength and the spatial position on the filter. Here, the filter may be arranged on a transparent substrate, which may in particular include at least one material capable of exhibiting a high degree of optical transparency in the infrared (IR) spectral range, in particular in the near infrared (NIR) spectral range as described in more detail below, thereby achieving a varying spectral characteristic of the filter along the length of the filter, in particular a continuously varying spectral characteristic. In particular, the variable length filter may be a wedge filter that may be adapted to carry at least one responsive coating on a transparent substrate, the responsive coating may exhibit spatially varying properties, in particular a spatially varying thickness. However, other types of variable length filters that may include other materials or exhibit additional spatially varying properties may also be feasible. At a normal incidence angle of the incident light beam, each filter included in the variable length filter may have a bandpass width that may amount to a fraction, typically a few percent, of the central wavelength of the particular filter. As an example, for a variable length filter with a wavelength range of 1400-1700 nm and a bandpass width of 1%, the bandpass width at normal incidence may vary from 14 nm to 17 nm. However, other examples may also be feasible.
[0021] As a result of this particular configuration of the variable length filter, only incident light having a wavelength equal to the central wavelength assigned to a particular spatial location on the filter, within the tolerance indicated by the bandpass width, can pass through the variable length filter at that particular spatial location. Thus, a "transmission wavelength", which may be equal to the central wavelength of the bandpass width ±1 / 2, may be defined for each spatial location on the variable length filter. In other words, all light that cannot pass through the variable length filter at the transmission wavelength may be absorbed or mostly reflected by the receiving surface of the variable length filter. As a result, the variable length filter has a varying transmittance and is therefore able to separate the incident light into a spectrum.
[0022] Thus, the light that can pass through the variable length filter at a particular spatial position on the variable length filter can then impinge on the detector array. In other words, the detector array can be preferably arranged in such a way that the light first impinges on the variable length filter, and only the portion of the light that can pass through a particular spatial position on the variable length filter can then impinge on the corresponding spatial position on the detector array. As a result, the variable length filter can thus be used to separate the incident light into at least one corresponding spatial position according to the associated wavelength or wavelengths, while a particular light sensor included in the detector array can thus be employed to measure the intensity of the light that impinges on the particular light sensor that can pass through the variable length filter at a corresponding spatial position according to its particular wavelength, and thus determine the intensity of the incident light at a particular wavelength. Thus, in a particularly preferred embodiment, the detector array can have a sequence of light sensors arranged one after the other in the form of a series of light sensors, which sequence of light sensors can be arranged in parallel with respect to the successive arrangement of the interference filters along the length of the variable length filter.
[0023] In a further preferred embodiment, the detector array can be preferably separated from the variable length filter through a transparent gap. Here, the transparent gap can be obtained by using an extended transparent body having two opposing faces, and a plurality of interference filters that can constitute the variable length filter can be arranged on the first face, and the optical sensor that constitutes the detector array can be arranged on the second face opposite to the first face. As a result, by selecting an appropriate width for the transparent gap, a more accurate adjustment of the detector array to the variable length filter can be achieved.
[0024] Thus, the detector array may have a series of light sensors arranged in a single line, preferably as a one-dimensional matrix along the length of the variable length filter, or in the form of a two-dimensional matrix, in several lines, in particular in two, three or four lines, in order to receive as much of the intensity of the incident light as possible. Thus, the number of pixels N in one direction may be high compared to the number of pixels M in the further direction, where M<10 and N≧10, preferably N≧20, more preferably N≧50, so that a one-dimensional 1×N matrix or a rectangular two-dimensional M×N matrix is obtained. Furthermore, the matrix used herein may be arranged in a staggered arrangement. Here, each light sensor used may have the same, or similar within a tolerance level, light sensitivity, in particular to facilitate the manufacture of the series of light sensors. Alternatively, each light sensor used in the series of light sensors may exhibit a light sensitivity that varies in response to the change in the transmittance characteristics of the variable length filter, for example by providing an increasing or decreasing change in light sensitivity to wavelength along the series of light sensors. However, other types of configurations may also be possible.
[0025] Specifically, to achieve a high resolution of the spectrometer device, each light sensor may therefore be adapted to receive incident light only at a small spatial angle. This configuration reflects in particular the configuration of a variable length filter designed to generate a desired spectrum depending on the spatial position of the impingement of the incident light along the length of the filter. This particular configuration is thus achieved according to the invention by a detector array comprising a plurality of pixelated sensors, where each pixelated sensor is adapted to receive at least a portion of one of the constituent wavelength signals provided by the variable length filter. As mentioned above, each of the constituent wavelength signals is thereby related to the intensity of each of the constituent wavelengths. As commonly used, the term "pixelated light sensor" or simply "pixelated sensor" refers to a light sensor comprising an arrangement (array) of individual pixel sensors, each of which has at least one photosensitive area adapted to generate an electrical signal depending on the intensity of the incident light, said electrical signal may in particular be provided to an external evaluation unit for further evaluation. Here, the photosensitive area included in each individual pixel sensor may in particular be a single uniform photosensitive area configured to receive the incident light impinging on the individual pixel sensor. However, other configurations of pixelated sensors may also be conceivable.
[0026] The pixelated sensors are designed to generate a signal, preferably an electronic signal, related to the intensity of incident light impinging on the individual pixelated sensor. The signal may be an analog signal and / or a digital signal. Thus, the electronic signals of adjacent pixelated sensors may be generated simultaneously or in a temporally consecutive manner. By way of example, during row or line scanning, it is possible to generate consecutive electronic signals corresponding to a series of individual pixel sensors arranged in a row. Furthermore, the individual pixel sensors may preferably be active pixel sensors adapted to amplify the electronic signal before providing it to an external evaluation unit. For this purpose, the pixelated sensors may include one or more signal processing devices, such as one or more filters and / or analog-to-digital converters for processing and / or pre-processing the electronic signal.
[0027] The pixelated sensor may be selected from any known pixel sensor, in particular from a pixelated organic camera element, preferably from a pixelated organic camera chip, or from a pixelated inorganic camera element, preferably from a pixelated inorganic camera chip, more preferably from a CCD chip or a CMOS chip, which are currently commonly used in various cameras. Alternatively, the pixelated sensor may be or include a photoconductor, in particular an inorganic photoconductor, in particular PbS, PbSe, Ge, InGaAs, ext.InGaAs, InSb or HgCdTe. As a further alternative, it may include a pyroelectric, bolometer or thermopile detector element. Thus, a camera chip with a matrix of 1×N pixels or M×N pixels may be used, where M<10 and N≧10, preferably N≧20, more preferably N≧50. Furthermore, a monochrome camera element, preferably a monochrome camera chip, may be used, where the monochrome camera element may be selected differently for each pixel sensor, in particular according to the varying wavelengths along the series of light sensors.
[0028] As a further alternative, the pixelated sensor can be based on the FiP sensor disclosed in WO 2012 / 110924 A1, WO 2014 / 097181 A1 or WO 2016 / 120392 A1, among other documents. In this specification, the term "FiP sensor" refers to a sensor in which, assuming the total power of the illumination is the same, the sensor signal depends on the geometry of the illumination of the photosensitive area, in particular on the beam cross section of the illumination on the photosensitive area, also called "spot size", according to the so-called "FiP effect". As a result, the observable property that the electrical properties of the photosensitive area depend on the extent of the illumination of the photosensitive area by the incident light is achieved, in particular that two incident light rays having the same total power but generating different spot sizes on the photosensitive area provide different values for the electrical properties of the photosensitive area and can therefore be distinguished from each other. Preferably, the photosensitive region of each FiP sensor may comprise a photoconductive material, in particular selected from PbS, PbSe, or HgCdTe, or a solid-state dye-sensitized solar cell (sDSC). Furthermore, WO 2014 / 198625 A1 discloses a particular embodiment of a detector array using an M×N matrix of FiP sensors. Alternatively, further types of pixelated sensors may also be feasible.
[0029] The detector array may therefore be adapted to provide a plurality of electrical signals that may be generated by the photosensitive areas of the pixelated sensors included in the detector array. The electrical signals provided by the detector array of the spectrometer device may be transmitted to an external evaluation unit, in particular an evaluation unit that may be included in a corresponding spectrometer system, which is described in more detail below. In this specification, the term "evaluation unit" refers in particular to a device assigned to determine information about the spectrum of an object, the spectrum of which is recorded, by using the spectrometer device described in this specification, in which the information is obtained by evaluating the detector signals provided by the detector array of the spectrometer device. The information may be provided, for example, electronically, visually, acoustically or any combination thereof. Furthermore, the information may be stored in a data storage device of the spectrometer device, preferably the spectrometer system, or in a separate storage device, and / or may be provided via at least one interface, such as a wireless interface and / or a wired interface.
[0030] According to the invention, the spectrometer device further comprises an optical element assigned to receive the incident light from the object and at the same time transmit the incident light to the variable length filter. For this purpose, the optical element comprises a concentrator operating in the reverse direction. As commonly used, the term "concentrator" refers to a non-imaging optical element having an input, also called "entrance pupil" or "entrance aperture", an output, represented by the term "exit pupil" or "exit aperture", located opposite the input, and a light guide structure located between the input and the output, which in its normal operating direction captures light with a large angular spread at the entrance, focuses the captured light in the light guide structure and emits the focused light at the output. By way of example, the concentrator may thus be used in concentrated photovoltaics to allow high solar concentration under possible large angles of incidence.
[0031] In contrast to this, the light collector according to the invention is used in the reverse direction, where the output of the aforementioned collector now serves as an input for receiving the incident light, and the light guide structure in the reverse direction preferably serves to spread the incident light, while the aforementioned input now serves as an output for emitting the diffused light. In a preferred embodiment of the invention, the entrance pupil of the working light collector preferably comprises an input angle of less than 90°, more preferably less than 70°, in particular less than 50°. Furthermore, in this preferred embodiment, the exit pupil of the conical reverse working light collector preferably comprises an output angle of less than 30°, more preferably less than 15°, in particular less than 10°. Thereby, the angular spread of the emitted light beam at the output can be simultaneously reduced compared to the incident light. As a result, applying a collector in the reverse direction makes it possible to capture incident light emitted or reflected by or passing through an object such that the light emitted at the output of the reverse-operating collector exhibits reduced angular spread, where the reduced angular spread may preferably be limited to an angular range of up to ±20°, preferably up to ±10°, most preferably up to ±5°.
[0032] Therefore, the light collector working in the reverse direction can be selected or configured so that the emitted light beam hits the variable length filter within a limited angular range and therefore mainly hits in a direction perpendicular to the receiving surface of the variable length filter, i.e. hits in a perpendicular manner to the receiving surface of the variable length filter. As already indicated above, each interference filter included in the variable length filter can have a bandpass width that only spans a part of the central wavelength of the particular interference filter at such a perpendicular angle of the incident light. As a result, the incident light can enter the variable length filter with a fairly high collection efficiency.
[0033] As mentioned above, various shapes of light collectors operating in a normal direction have been presented before. Apart from light collectors having a conical shape, which are known to have a low light collection efficiency, further possible light collectors can take on further shapes, in particular in the form of "compound parabolic concentrators" or "CPCs" or "compound elliptical concentrators" or "CECs", although "compound hyperbolic concentrators" or "CHCs" may not be very suitable for the purposes of the present invention. Here, as commonly used, a compound parabolic concentrator can be defined by two parabolic mirror segments, which may each comprise two different foci located on one of the parabolic mirror segments. Thereby, the surfaces of the two parabolic mirror segments can be arranged symmetrically with respect to reflection through the axis of the compound parabolic concentrator. Similarly, a compound elliptical concentrator can thus be defined by two elliptical mirror segments, the surfaces of which can be arranged symmetrically with respect to reflection through the axis of the compound elliptical concentrator.
[0034] As commonly used, the term "symmetric" or "symmetrical" refers in particular to a geometric property of an object, the shape of which or at least one of its elements may be invariant to the application of at least one operation, usually called "geometric transformation", which may include reflection, rotation, translation, and / or a combination thereof. In this case, however, the preferred geometric transformations may be reflection and rotation. In particular, an object or an element thereof may be considered to have reflection symmetry with respect to an axis and / or a mirror plane if the axis and / or mirror plane, respectively, allow the shape of the object or its element to be divided into two sections that are mirror images of each other. By way of example, an object may be considered to be symmetric if it comprises two parabolic mirror segments arranged with respect to a reflection axis that can be considered as a mirror image of each other. Similarly, an object may be considered to have rotational symmetry with respect to at least one fixed point or / and / or a mirror plane that includes an axis and / or a rotation axis of the object or its element if it can be rotated with respect to said fixed point or mirror plane, respectively, in a manner that does not change the shape of the object or its element. In contrast, the term "asymmetric" indicates that at least one of the geometric properties of the object under consideration may not be invariant to at least one of the geometric transformations that may be applied to this object.
[0035] More specifically, one of the following symmetry groups may be applicable to the optical element, in particular to the concentrator operating in the reverse direction: As commonly used, the term "symmetry group" describes a particular symmetry of an object or its elements by indicating what kind of geometric transformations can be applied to the object or its elements. For this consideration, a particular symmetry group can be described in particular using the so-called "Schönfrieder notation". Here, the following terms, defined as follows, are preferably applicable to the shape of the body of the element:
[0036] - C∞ refers to the symmetry of a truncated cone, in which the shape of the truncated cone is preserved under rotation around any angle with respect to a mirror plane that contains the axis of rotation of the truncated cone; - C4v refers to a square pyramidal trunk, the shape of which is preserved only under rotation at an angle of 360° / 4=90° with respect to a mirror plane containing the axis of rotation of the square pyramidal trunk; - C2v refers to a rectangular pyramid trunk that is distinct from a square pyramid trunk, and the shape of the rectangular pyramid trunk is preserved only under rotation at an angle of 360° / 2=180° with respect to a mirror plane that contains the axis of rotation of the rectangular pyramid trunk; - Cs refers to reflection symmetry only, in which the shape of an object or its elements is preserved only by reflection on a mirror surface; - C2 refers to only two-fold symmetry, in which the shape of the object or its elements is preserved only under rotation through an angle of 360° / 2=180° about a particular axis of rotation of the object or its elements; or - C1 indicates that there is no symmetry element.
[0037] For details of the Schoenfrieder notation, see, for example, Morton Hammermeshe, Group Theory and Its Applications to Physical Problems, Dover Publications, Mineola, NY 1989, pp. 32-67.
[0038] In particular with respect to the present invention, optical elements, in particular light collectors operating in the reverse direction, can thus be described as having an asymmetric shape if they have a less symmetric shape of the element, in particular at least one of the symmetry groups Cs, C2, C1, as described in the symmetry group C2v in the Schönfries notation. However, it can be emphasized that in order to consider the symmetry of an optical element, only the sections of the optical element that can affect the beam path of the incident light, in particular the optical guide structure located between the input and the output of the optical element, may be relevant. Other shapes of the optical element, in particular the external shape, may be excluded from consideration. Furthermore, manufacturing tolerances are taken into account to determine the symmetry of the optical element.
[0039] According to the invention, the optical element, in particular the inversely operated collector, more particularly the optical guide structure located between the input and the output of the optical element, comprises a non-conical shape. As a result, the light beam can be guided through the collector with increased efficiency at the output of the inversely operated collector. This effect is based in particular on the non-conical shape of the inversely operated collector, which makes it possible to guide the incident light in the form of a light beam through the non-conical shaped inversely operated collector in a manner that results in less light being absorbed by the side walls of the inversely operated collector, in contrast to the conical shaped inversely operated collector. As a result, more light beams can reach the variable length filter at a spatial position on the variable length filter that is configured to receive a light beam with a specific wavelength contained in the light beam. Furthermore, the transfer function of the non-conical shape shows a steeper onset of light transmission with respect to the angle of incidence on the inversely operated collector, thereby showing the theoretical maximum of the complete binary transition from no light transmission to a complete light transmission of the compound parabolic collector. Such a type of steepness in the transfer function can therefore be advantageous in minimizing the area of spectroscopic sampling for a given light throughput, thereby providing a sharp definition of the sampling spot and supporting homogenization of the response from the sampling spot.
[0040] More specifically, the term "conical" in relation to an optical element according to the state of the art refers to a shape of an optical element that can be described according to the Schönfries notation by a symmetry group equal to or greater than C2v, such as C2v, C4v or C∞, in particular a truncated cone or pyramidal trunk, where manufacturing tolerances are taken into account, as described above. In contrast, the term "non-conical" in relation to an optical element according to the invention refers to a shape of an optical element that can be described according to the Schönfries notation by a symmetry group equal to or less than C2v, such as Cs, C2 or C1, in accordance with the Schönfries notation, in particular where manufacturing tolerances are taken into account. In other words, the light guide structure located between the input and the output of the optical element according to the invention may preferably include a shape that may exhibit a diameter that, at half the distance between the input and the output of the optical element, deviates from the arithmetic mean of the first diameter of the input of the optical element and the second diameter of the output of the optical element by at least 10%, preferably at least 5%, most preferably at least 2%, in particular at least 1%.
[0041] In a particularly preferred embodiment, the non-conical shape of the collector working in the reverse direction is therefore preferably selected from a parabolic or elliptical shape, so that the collector may in particular be selected from the group comprising compound parabolic collectors and compound elliptical collectors, however, other types of collectors with non-conical shapes may also be feasible.
[0042] In particular, the parabolic shape of the optical element, and in particular the parabolic shape of the light guide structure located between the input and output of the optical element, is described, excluding manufacturing tolerances, by equation (1) as follows:
number
[0043] Here, the term x refers to a value along the optical axis of an optical element, in particular a light guide structure of a reverse acting light collector, while the term y refers to a value perpendicular to the optical axis, with y0 and a providing an opportunity to adjust the parabolic shape for the optical element. As commonly used, the term "optical axis" refers to an imaginary line of symmetry about which the optical element, and preferably other elements of the spectrometer device, may be invariant with respect to rotation of symmetric optical elements included in the spectrometer system.
[0044] Similarly, the elliptical shape of the optical elements, and in particular the elliptical shape of the light guide structures located between the input and output of the optical elements, is described, excluding manufacturing tolerances, by the following equation (2):
[0045]
number
[0046] Here, the term x refers to a value along the optical axis of the optical element, in particular of the light guide structure of the inversely acting light collector, while the term y refers to a value perpendicular to the optical axis, and a and b refer to the axes of the elliptical shape, again offering the opportunity to adjust the parabolic shape with respect to the optical element.
[0047] The use of a focusing device having such a shape can have the advantageous effect, as already indicated above, that more of the light beam can reach the variable length filter at the desired spatial position on the variable length filter, thereby in particular improving the efficiency of the spectrometer device described in this specification.
[0048] A reverse acting light concentrator having a non-conical shape may be or may include a solid body of optically transparent material, either completely or partially, or alternatively may be or may include a hollow body, preferably completely and / or uniformly filled with a gas and / or fluid and / or solid optically transparent material, and including at least two distinct side walls capable of assuming the desired non-conical shape. Here, at least one material that may exhibit a high degree of optical transparency within the infrared (IR) spectral range, in particular within the near infrared (NIR) and mid infrared (MidIR) spectral range, and may be selected for the solid body of the light collector, may preferably be selected from the group consisting of calcium fluoride (CaF2), fused silica, germanium, magnesium fluoride (MgF), potassium bromide (KBr), sapphire, silicon, sodium chloride (NaCl), zinc selenide (ZnSe), zinc sulfide (ZnS), borosilicate-crown glass, transparent conductive oxides (TCOs), and transparent organic polymers, where highly reflective silicon and germanium are particularly preferred as they can support total internal reflection that may occur at the sidewalls of the solid body. Alternatively, the gaseous optically transparent material that may be selected to fill a hollow body having at least two side walls exhibiting the desired non-conical shape may be selected from ambient air, nitrogen gas, or carbon dioxide, while the optically transparent fluid for this purpose may be selected from immersion oil or turpentine made from Canada balsam, i.e., the resin of the balsam fir tree, in particular Aviscosus balsamea. As a further alternative, a vacuum may be present in the hollow body.
[0049] In a further preferred embodiment, the efficiency of the spectrometer device can be further improved by applying a non-conically shaped inversely actuated collector with at least two distinct side walls adapted to reflect the incident light, the side walls of the collector being arranged at opposite lateral positions with respect to the longitudinal axis of the collector. In addition to the two opposite distinct side walls, the collector can further comprise a base plate and a cover plate, thereby providing a closed shape to the collector that can have a quasi-two-dimensional appearance. As a result, the shape of the collector can include at least one corner line at the intersection line between either one of the side walls of the collector and either the base plate or the cover plate. However, further corner lines may be conceivable. This embodiment is particularly in contrast to known non-conically shaped inversely actuated collectors that use non-reflective absorptive surfaces to avoid under all possible circumstances that the light beam may reach the variable length filter at a spatial position on the variable length filter that may not be configured to receive the light beam having the particular wavelength contained by the light beam. In contrast to this, as a result of this further preferred embodiment, the non-conical shaped inversely acting concentrator allows some light beams to be reflected and still be directed to the variable length filter, where the particular shape of the non-conical shaped inversely acting concentrator can ensure that only those light beams can reach the variable length filter at spatial positions configured to receive light beams having the particular wavelengths for which the spatial positions are specified.
[0050] In a further preferred embodiment, the efficiency of the spectrometer device can be further improved by applying a non-conical shaped inversely actuated collector comprising at least two individual side walls designed as rounded side walls, at least one of the rounded side walls advantageously comprising a profile that can be selected from a parabolic profile or an elliptical profile. In this specification, profile refers to the shape of the cross section of the side walls in a lateral position of the collector, which may in particular be or comprise a parabolic or elliptical shape, respectively. As mentioned above, the non-conical shaped inversely actuated collector can be or comprise a solid body having a non-conical shape. In this case, at least one of the side walls can preferably have a profile that can be configured to bulge from the surface of the collector. In an alternative further indicated above, the non-conical shaped inversely actuated collector can be or comprise a hollow body having at least two side walls that are non-conical, in this alternative, at least one of the side walls can preferably present a profile that can be configured to sink into the surface of the hollow body. As a result of this further preferred embodiment, the particular shape of the sidewall of the inversely acting light collector, which has a non-conical shape, further ensures that more of the light beam is guided so that it can reach the variable length filter at the desired spatial position on the variable length filter, thereby further improving the efficiency of the spectrometer device as described in this specification.
[0051] For example, as disclosed in US 2014 / 131578 A1, the optical elements, in particular the inverse-acting collector, together with the variable length filter, the detector array and optionally further optical elements of the spectrometer device, may be arranged symmetrically with respect to a common optical axis of the spectrometer device. As already defined above, the term "optical axis" refers to an imaginary line along which the configuration of the spectrometer device, in particular the inverse-acting collector, the variable length filter and the detector array, may be invariant with respect to the rotation of the symmetrical optical elements included in the spectrometer system. Thus, in this particular embodiment, each of the inverse-acting collector, the variable length filter, the detector array and the optional at least one further optical element of the spectrometer device may exhibit a symmetrical shape as further defined above and may further be arranged symmetrically with respect to each other. As a result of the symmetrical arrangement of the inverse-acting collector and the configuration of the variable length filter, which is described in more detail elsewhere, a symmetrical response of the spectrometer device may be expected for small wavelengths that may be detected on one side of the detector array and for long wavelengths that may be detected on the other side of the detector array.
[0052] In contrast to this, the spectrometer device according to the invention can in a further preferred embodiment comprise a reverse-acting collector with an asymmetric design. As shown in more detail in the following figures, a reverse-acting collector of this kind can be used, especially if it comprises side walls adapted to reflect the incident light. The spectrometer device can be designed to increase the efficiency of the spectrometer device by allowing additional light beams to still be directed to the variable length filter, where the asymmetric design of the non-conical shaped, inversely acting collector can ensure that only those light beams can reach the variable length filter at spatial locations configured to receive light beams having the particular wavelengths for which the spatial locations are designated.
[0053] A similar effect can alternatively or additionally be obtained by asymmetrically arranging the optical elements, in particular the non-conical reverse-acting collector, with respect to the optical axis of the spectrometer device, regardless of whether it has a symmetric or asymmetric design. As a result, the combination of the optical elements, the variable length filter, the detector array and optionally further optical elements of the spectrometer device may therefore exhibit a symmetry break that can be expressed in a similar manner to the above, in particular by using the corresponding Schönfrieder notation. For this purpose, the Schönfrieder notation provides in particular the symmetry group C4v, which refers to an arrangement in which a rotation of an angle of 360° / 4=90° with respect to the mirror plane containing the rotation axis is preserved. This kind of symmetry break may therefore result in a preferred configuration according to the invention. However, other kinds of asymmetric arrangements may also be feasible as a result of further symmetry breaks of the respective arrangements of the optical elements, the variable length filter, the detector array and optionally further optical elements of the spectrometer device.
[0054] Regardless of whether the non-conical inverse-actuated collector may have an asymmetric design or may be arranged asymmetrically with respect to the optical axis of the spectrometer device, the response of the spectrometer device can no longer be expected to be equal for short wavelengths detectable on one side of the detector array and long wavelengths detectable on the other side of the detector array. However, this observation may show certain advantages for the spectrometer device, especially when an incandescent lamp may be used as the illumination source. As commonly used, the term "incandescent lamp" refers to an electric lamp having a heatable element, such as a heated wire filament, that can be heated to a temperature at which it can emit light, especially infrared light. The radiation output of an incandescent lamp decreases with increasing wavelength, since the incandescent lamp can thus be considered a heat emitter in the infrared spectral range. Furthermore, typically, known materials that can be used for absorption in the infrared spectral range generally show a tendency for absorption to increase with increasing wavelength. Moreover, as already indicated above, the bandpass width of a variable length filter, especially a linear variable filter, can usually have a constant value, such as 1%, over the spectral range of the variable length filter, so that the resolution of the variable length filter, which is inversely proportional to the bandpass width, also decreases with increasing wavelength. Furthermore, the resolution of a variable length filter generally depends on the central wavelength of the variable length filter. Combining all the effects mentioned, in a symmetrical spectrometer device, the response of the spectrometer device decreases with increasing wavelength.
[0055] However, according to further preferred embodiments of the present invention, the use of a non-conical inverse-actuated collector with an asymmetric design, or alternatively or additionally, the use of a non-conical inverse-actuated collector arranged asymmetrically with respect to the optical axis of the spectrometer device, may allow the adjustment of the length of the path that the light beam may travel from the inlet of the inverse-actuated collector through the inverse-actuated collector to the outlet of the inverse-actuated collector. As a result, the asymmetry of the non-conical inverse-actuated collector, either in configuration or arrangement, may allow the light beam to have a shorter path for a light beam with a longer wavelength compared to a light beam with a shorter wavelength, and, additionally or alternatively, the light beam may impinge on the variable length filter with close to normal incidence, which may further increase the efficiency. As a result, further preferred embodiments may facilitate the provision of a spectrometer device that may be adapted to allow a higher efficiency, especially at longer wavelengths. Furthermore, although it may thus appear that the efficiency at shorter wavelengths is reduced, especially due to the longer path of the light beams with shorter wavelengths compared to light beams with longer wavelengths, this effect is generally outweighed in this type of arrangement by the higher radiant output of the incandescent lamp as shown above, and the lower bandpass width at shorter wavelengths. Thus, this type of arrangement may be used to give the spectrometer device an efficiency, especially in the infrared spectral range, which may be more evenly distributed over the wavelength range of the spectrometer device according to the invention, compared to known spectrometer devices.
[0056] Therefore, in this further preferred embodiment of the asymmetric arrangement according to the invention, the optical elements, in particular the non-conical inverse-acting collector, can be tilted with respect to a plane perpendicular to the receiving surface of said variable length filter. As commonly used, the term "tilt" refers to the tilt of the symmetry axis of the collector with respect to a plane perpendicular to the receiving surface of the variable length filter. As a result of the tilted arrangement of the optical elements, the entrance axis and the exit pupil axis of the non-conical inverse-acting collector can either be shifted and parallel to each other, shifted but not parallel, or not shifted and not parallel to each other. More preferably, the collector can be tilted with respect to this plane perpendicular to the receiving surface of the variable length filter in such a way that the light beam impinges on the variable length filter perpendicular to this plane at a spatial position on the variable length filter that is assigned to receive a specific wavelength of incident light. Alternatively, the light collector may be tilted relative to this plane in a further manner so that a further light beam impinges on a further spatial location on the variable length filter assigned to receive a further specific wavelength, where the further specific wavelength exceeds the wavelength of the incident light beam, i.e., the further specific wavelength represents a longer wavelength than the incident light that may be directed to impinge on the surface of the variable length filter.
[0057] Thus, although an incident light beam may pass through the variable length filter at a wavelength longer than the characteristic wavelength, due to the relative arrangement between the variable length filter and the detector array, separated by a gap as described in more detail elsewhere in this document, the incident light beam may still impinge on a particular light sensor provided to determine the intensity of the incident light at a particular wavelength of the incident light beam. As a result, not only the light beam impinging on the variable length filter perpendicular to the receiving surface of the variable length filter at a spatial position of the variable length filter designated for this purpose, but also the light beam impinging on the variable length filter at a further spatial position assigned to receive wavelengths longer than the wavelength of the incident light beam, but impinging on a particular light sensor designed to still receive a particular wavelength of the incident light beam, may contribute to the electrical signal generated by the photosensitive area of a particular individual pixel sensor. Thus, the efficiency of the spectrometer device can be further increased in this way.
[0058] In addition, the spectrometer device according to the invention may further comprise at least one transmission device, which may in particular be arranged between the inverse-acting collector and the variable length filter. Thus, most preferably, the light beam emerging from the object first passes through the inverse-acting collector, then through the variable length filter, and finally travels in or through the transmission device until it impinges on the detector array. As used herein, the term "transmission device" may thus refer to an optical element that may be configured to transmit the light beam emerging from the inverse-acting collector to the detector array. In certain embodiments, the transmission device may thus be designed to shape the light beam before it is guided to the variable length filter.
[0059] In particular, the transfer device may be selected from the group consisting of an optical lens, a curved mirror, a grating, and a diffractive optical element. More specifically, the optical lens may be selected from the group consisting of a biconvex lens, a plano-convex lens, a biconcave lens, a plano-concave lens, an aspheric lens, a cylindrical lens, and a meniscus lens. Thereby, the transfer device may comprise a material that may be at least partially transparent, preferably over the entire wavelength range of the variable length filter as described above. For this purpose, the same or similar optically transparent materials as mentioned in this point may also be used. However, further optical elements may also be feasible.
[0060] In a further aspect of the present invention, a spectrometer system is disclosed. Accordingly, the spectrometer system comprises: - a spectrometer apparatus as described in more detail above and / or below; and - an evaluation unit, which is assigned to determine information relating to the spectrum of the object by evaluating the detector signal provided by the spectrometer device; Includes.
[0061] Here, the components of the spectrometer system listed above may be separate components. Alternatively, two or more components of the spectrometer system may be integrated into a single integral component. Furthermore, the evaluation unit may be formed as a separate evaluation unit independent of the spectrometer device, but may preferably be connected to the detector array, in particular to receive the detector signals generated by the spectrometer device. Alternatively, at least one evaluation unit may be fully or partially integrated into at least one spectrometer device.
[0062] According to the invention, the spectrometer system comprises a spectrometer device and an evaluation unit. With regard to the spectrometer device, reference may be made to the description elsewhere in this document. As further used herein, the term "evaluation unit" generally refers to any device designed to generate a desired information item, i.e. at least one information item related to the spectrum of an object. By way of example, the evaluation unit may be or include one or more integrated circuits, such as one or more application specific integrated circuits (ASICs), and / or one or more data processing devices, such as one or more computers, digital signal processors (DSPs), field programmable gate arrays (FPGAs), preferably one or more microcomputers, and / or microcontrollers. Additional components may be included, such as one or more processing devices, and / or data acquisition devices for receiving and / or preprocessing the detector signals, such as one or more analog-to-digital converters, and / or one or more filters. As used herein, the detector signals are provided by the spectrometer device, in particular by the detector array of the spectrometer device. Furthermore, the evaluation unit may include one or more data storage devices. Furthermore, the evaluation unit may comprise one or more interfaces, such as one or more wireless interfaces and / or one or more wired interfaces.
[0063] The at least one evaluation unit may be adapted to execute at least one computer program, such as at least one computer program performing or supporting a step of generating an item of information. As an example, one or more algorithms may be implemented that can perform a predefined transformation to the position of the object by using the sensor signals as input variables. For this purpose, the evaluation unit may in particular comprise at least one data processing device, in particular an electronic data processing device designed to generate the items of information by evaluating the detector signals. The evaluation unit is thus designed to use the detector signals as input variables and to generate the items of information regarding the spectrum of the object by processing these input variables. The processing may be performed in parallel, sequentially or even in combination. The evaluation unit may use any process that generates these items of information, such as by calculation and / or by using at least one stored and / or known relationship. In addition to the detector signals, one or more further parameters and / or items of information, for example at least one item of information regarding the relative arrangement of the optical elements, the variable length filters and the detector array included in the spectrometer device, may affect the above relationship. The relationship may be determined or be determined empirically, analytically or semi-empirically. Particularly preferably, the relationship comprises at least one calibration curve, at least one set of calibration curves, at least one function, or a combination of the mentioned possibilities. One or more calibration curves can be stored, for example, in a data storage device and / or a table, for example, in the form of a set of values and their associated function values. However, alternatively or additionally, at least one calibration curve can also be stored, for example, in a parameterized form and / or as a function equation. Separate relationships for processing detector signals into information items can be used. Alternatively, at least one combined relationship for processing detector signals can be realized. Various possibilities are conceivable and can also be combined.
[0064] By way of example, the evaluation unit may be designed with respect to programming for the purpose of determining the item of information. The evaluation unit may in particular comprise at least one computer, for example at least one microcomputer. Furthermore, the evaluation unit may comprise one or more volatile or non-volatile data memories. As an alternative or in addition to a data processing device, in particular at least one computer, the evaluation unit may comprise one or more further electronic components designed for determining the item of information, for example an electronic table, in particular at least one look-up table and / or at least one application specific integrated circuit (ASIC).
[0065] Furthermore, the evaluation unit may be designed to fully or partially control or drive the spectrometer device or parts thereof, for example by means of an evaluation unit designed to control at least one illumination source and / or to control optical elements of the spectrometer device spectrometer and / or to control at least one modulation device of the detector. The evaluation unit may in particular be designed to perform at least one measurement cycle in which a plurality of detector signals are collected, in particular detector signals of individual pixelated sensors arranged successively along the length of the detector array and / or detector signals of different modulation frequencies of illumination. Here, the acquisition of the detector signals may be performed sequentially, in particular by using row and / or line scanning. However, other embodiments are also possible, for example in which specifically selected individual pixelated sensors are recorded simultaneously.
[0066] In a particular embodiment, the detector can therefore have at least one modulation device, preferably for periodic modulation, in particular a periodic beam interruption device, for modulating the illumination. As commonly used, modulation of the illumination includes a process in which the total power of the illumination is preferably varied periodically, in particular with one or more modulation frequencies. In particular, a periodic modulation can be performed between a maximum value and a minimum value of the total power of the illumination. The minimum value can be zero, but it can also be greater than zero, for example without the need to perform a complete modulation. The modulation can be performed, for example, in the beam path between the object and the detector array, for example by a modulation device arranged in said beam path. However, alternatively or additionally, the modulation can also be performed in the beam path between any illumination source for illuminating the object and the object, for example by a modulation device arranged in said beam path. A combination of these possibilities is also conceivable. By way of example, the modulation device can include a beam chopper or other type of periodic beam interruption device, for example at least one interruption blade or interruption wheel, which preferably rotates at a constant speed and thus can interrupt the illumination periodically. However, alternatively or additionally, one or more different types of modulation devices can also be used, for example modulation devices based on the electro-optical effect and / or the acousto-optical effect. Alternatively or additionally, any illumination source itself may also be designed to generate modulated illumination, for example by the illumination source itself having a modulated intensity and / or modulated total power, for example a periodically modulated total power, and / or by the illumination source itself embodied as a pulsed illumination source, for example a pulsed laser. Thus, by way of example, the modulation device may also be integrated in whole or in part into the illumination source. Various possibilities are conceivable. Thus, the detector array may be designed to detect at least two detector signals in the case of different modulations with different modulation frequencies. The evaluation device may be designed to generate information related to the spectrum from the two or more detector signals. By way of example, the detector may be designed to provide a modulation of the illumination of the object with a frequency between 0.05 Hz and 1 MHz, for example between 0.1 Hz and 10 kHz.
[0067] In a further aspect of the invention, the use of the spectrometer device and the spectrometer system according to the invention is disclosed. Therein, the use of the spectrometer device and the spectrometer system for determining information on the spectrum of an object is proposed. Here, the spectrometer device and the spectrometer system can preferably be used for a use selected from the group consisting of: infrared detection applications; heat detection applications; thermometer applications; heat seeking applications; flame detection applications; fire detection applications; smoke detection applications; temperature sensing applications; and spectroscopy applications. Furthermore, the spectrometer device and the spectrometer system according to the invention can preferably be used for exhaust gas monitoring, combustion process monitoring, pollution monitoring, industrial process monitoring, chemical process monitoring, food processing process monitoring, water quality evaluation, and / or air quality evaluation. Furthermore, the spectrometer device and the spectrometer system according to the invention can be used for quality control, temperature control, motion control, exhaust control, gas sensing, gas analysis, motion sensing, and / or chemical sensing. Further applications are possible.
[0068] The spectrometer device, the spectrometer system and the proposed uses described above have considerable advantages over the prior art. Thus, in general, a simple and yet efficient spectrometer device and spectrometer system can be provided for accurately determining information related to the spectrum of an object, where, as an example, an infrared spectrum of an object covering a section of the infrared spectral range can be obtained in a fast and efficient manner. Compared to devices known in the art, the spectrometer device and the spectrometer system proposed here offer a high degree of simplicity, in particular with regard to the optical structure of the spectrometer device. Here, the combination of specific optical elements, variable length filters and detector arrays included in the spectrometer device can be advantageous, in particular because the specific optical elements, including a collector having a non-conical shape and working in the opposite direction, are adapted to capture the incident light from the object and transmit the incident light to the variable length filter with a higher collection efficiency than those currently available. This high degree of simplicity, combined with the possibility of high resolution measurements, makes it particularly suitable for sensing, detection and / or monitoring applications in the infrared (IR) spectral region, especially in the near infrared (NIR) and mid infrared (MidIR) spectral range, in particular for heat, flame, fire or smoke sensing or detection, as well as for monitoring exhaust gases, combustion processes, pollution, industrial processes, chemical processes, food processing processes, water quality or air quality. Further applications are possible.
[0069] In summary, in the context of the present invention, the following embodiments are considered to be particularly preferred:
[0070] Embodiment 1: A spectrometer apparatus comprising: - an optical element designed to receive incident light from an object and transmit the incident light to a variable length filter, the optical element including a concentrator, the concentrator operating in a reverse direction, the concentrator including a non-conical shape; - a variable length filter assigned to separate the incident light into a spectrum of constituent wavelength signals; and - a detector array including a plurality of pixelated sensors, each pixelated sensor adapted to receive at least a portion of one of the constituent wavelength signals, each of the constituent wavelength signals related to an intensity of a respective constituent wavelength; 13. A spectrometer apparatus comprising:
[0071] Embodiment 2: A spectrometer device according to the preceding embodiment, in which the light collector operates in the opposite direction to broaden the incident light and at the same time reduce the angular spread of the light beam.
[0072] Embodiment 3: A spectrometer apparatus according to any one of the preceding embodiments, wherein the non-conical shape of the collector comprises a shape selected from a parabolic shape or an elliptical shape.
[0073] Embodiment 4: A spectrometer apparatus according to the preceding embodiment, wherein the collector is selected from the group comprising a compound parabolic collector and a compound elliptical collector.
[0074] Embodiment 5: A spectrometer device according to any one of the preceding embodiments, wherein the light collection device has an asymmetric design with respect to the optical axis of the spectrometer device.
[0075] Embodiment 6: A spectrometer device according to the preceding embodiment, wherein the concentrating device operating in the reverse direction comprises an entrance pupil and an exit pupil, and the entrance plane defined by the entrance pupil and the exit plane defined by the exit pupil are not parallel.
[0076] Embodiment 7: A spectrometer device according to any one of the two preceding embodiments, wherein the light collection device comprises only inversion symmetry and two-fold rotation axes.
[0077] Embodiment 8: A spectrometer device according to any one of the preceding three embodiments, wherein the light collection device does not exhibit rotational symmetry.
[0078] Embodiment 9: A spectrometer device according to any one of the preceding four embodiments, wherein the collector includes only a single mirror surface or no mirror surface.
[0079] Embodiment 10: A spectrometer device according to any one of the preceding embodiments, wherein the light collecting device is arranged asymmetrically with respect to the optical axis of the spectrometer device.
[0080] Embodiment 11: A spectrometer device according to the preceding embodiment, wherein the non-conical shape of the collector is asymmetrically positioned relative to the variable length filter.
[0081] Embodiment 12: A spectrometer device according to the preceding embodiment, wherein the respective arrangements of the collector and variable length filter operating in opposite directions include only a single mirror surface or no mirror surface.
[0082] Embodiment 13: A spectrometer device according to any one of the two preceding embodiments, wherein the respective arrangements of the collector and the variable length filter operating in opposite directions do not exhibit rotational symmetry.
[0083] Embodiment 14: A spectrometer device according to any one of the preceding three embodiments, wherein the light collecting device is inclined with respect to a plane perpendicular to the receiving surface of the variable length filter.
[0084] Embodiment 15: A spectrometer device according to the preceding embodiment, wherein the light collecting device is tilted with respect to a plane perpendicular to the receiving surface of the variable length filter so that incident light transmitted to the variable length filter impinges on the variable length filter perpendicular to the receiving surface of the variable length filter at a spatial position of the variable length filter designed to receive the wavelength of the incident light, and / or at a further spatial position of the variable length filter designed to receive further wavelengths beyond the wavelength of the incident light.
[0085] Embodiment 16: A spectrometer device according to any one of the preceding embodiments, wherein the light collection device may be or includes a solid body of optically transparent material.
[0086] Embodiment 17: A spectrometer apparatus according to the preceding embodiments, wherein the optically transparent material is selected from the group consisting of calcium fluoride (CaF2), fused silica, germanium, magnesium fluoride (MgF), potassium bromide (KBr), sapphire, silicon, sodium chloride (NaCl), zinc selenide (ZnSe), zinc sulfide (ZnS), borosilicate crown glass, transparent conductive oxides (TCOs), and transparent organic polymers.
[0087] Embodiment 18: A spectrometer device according to any one of the preceding embodiments, wherein the light collection device is or comprises a hollow body.
[0088] Embodiment 19: A spectrometer apparatus according to any one of the preceding embodiments, wherein a vacuum is present in the hollow body.
[0089] Embodiment 20: A spectrometer device according to the preceding embodiments, wherein the hollow body is filled with a gaseous and / or fluid optically transparent material.
[0090] Embodiment 21: A spectrometer device according to the preceding embodiments, wherein the hollow body is completely and / or uniformly filled with a gaseous and / or fluid optically transparent material.
[0091] Embodiment 22: A spectrometer apparatus according to any one of the preceding two embodiments, wherein the gaseous optically transparent material is selected from ambient air, nitrogen gas, or carbon dioxide.
[0092] Embodiment 23: A spectrometer apparatus according to any one of the preceding three embodiments, wherein the fluid optically transparent material is selected from immersion oil or Canada balsam.
[0093] Embodiment 24: A spectrometer device according to any one of the preceding embodiments, wherein the light collector has at least two distinct side walls.
[0094] Embodiment 25: A spectrometer device according to the preceding embodiment, wherein the sidewall is adapted to reflect incident light.
[0095] Embodiment 26: A spectrometer device according to any one of the preceding two embodiments, wherein the collector further comprises a base plate and a cover plate adapted to provide the collector with a closed shape.
[0096] Embodiment 27: A spectrometer device according to the preceding embodiment, wherein the closed shape includes at least four corner lines at the intersection between any one of the side walls of the collector and either the base plate or the cover plate.
[0097] Embodiment 28: A spectrometer device according to any one of the previous two embodiments, wherein at least one of the side walls of the collector is designed as a rounded side wall.
[0098] Embodiment 29: A spectrometer device according to the preceding embodiment, wherein at least one of the rounded sidewalls of the collector comprises a profile selected from a parabolic profile or an elliptical profile.
[0099] Embodiment 30: A spectrometer device according to any one of the two preceding embodiments, wherein at least one of the side walls assumes a profile protruding from a surface of the collector that is or contains a complete body of optically transparent material, or at least one of the side walls assumes a profile penetrating into a surface of the hollow body of the collector.
[0100] Embodiment 31: A spectrometer apparatus according to any one of the preceding embodiments, wherein the detector array is separated from the variable length filter via a transparent gap.
[0101] Embodiment 32: A spectrometer device according to the preceding embodiment, in which the transparent gap is obtained by an extended transparent body having two opposing sides, a plurality of interference filters constituting a variable length filter are arranged on a first side, and a pixelated sensor constituting a detector array is arranged on a second side opposite the first side.
[0102] Embodiment 33: A spectrometer device according to any one of the preceding embodiments, wherein the pixelated sensor is selected from at least one of: a pixelated organic camera element, preferably a pixelated organic camera chip; a photoconductor array, in particular an inorganic photoconductor array, in particular a PbS, PbSe, Ge, InGaAs, ext.InGaAs, InSb, or HgCdTe photoconductor array; a pyroelectric, bolometer, or thermopile array; a pixelated inorganic camera element, preferably a pixelated inorganic camera chip, more preferably a CCD chip or a CMOS chip; a monochrome camera element, preferably a monochrome camera chip; or an FiP sensor.
[0103] Embodiment 34: A spectrometer apparatus according to any one of the preceding embodiments, wherein the incident light comprises electromagnetic radiation between 760 nm and 1000 μm (infrared spectral range).
[0104] Embodiment 35: A spectrometer apparatus according to the preceding embodiment, wherein the incident light comprises electromagnetic radiation between 1 μm and 5 μm.
[0105] Embodiment 36: A spectrometer apparatus according to any preceding embodiment, wherein the incident light comprises electromagnetic radiation between 1 μm and 3 μm.
[0106] Embodiment 37: A spectrometer apparatus according to any one of the preceding embodiments, further comprising an illumination source adapted to illuminate the object.
[0107] Embodiment 38: A spectrometer device according to the preceding embodiment, wherein the illumination source is integrated or attached to the spectrometer device.
[0108] Embodiment 39: A spectrometer device according to any one of the two preceding embodiments, wherein the irradiation source is selected from: an irradiation source that is at least partially connected to the object and / or is at least partially identical to the object; an irradiation source designed to at least partially irradiate the object with primary radiation.
[0109] Embodiment 40: A spectrometer device according to the preceding embodiment, wherein the light beam is generated by reflection of the primary radiation on the object and / or by emission by the object itself stimulated by the primary radiation.
[0110] Embodiment 41: A spectrometer device according to the preceding embodiment, wherein the spectral sensitivity of the detector array is covered by the spectral range of the illumination source.
[0111] Embodiment 42: A spectrometer device according to any one of the preceding four embodiments, wherein the irradiation source is selected from at least one of: an incandescent lamp; a flame source; a heat source; a laser, in particular a laser diode; a light emitting diode; an organic light source, in particular an organic light emitting diode; a neon light; a structured light source.
[0112] Embodiment 43: A spectrometer device according to any one of the preceding embodiments, further comprising a transmitter.
[0113] Embodiment 44: A spectrometer device according to the preceding embodiment, wherein the transmitting device constitutes or has a converging optical element, the converging element being at least partially optically transparent for at least one portion of the wavelength range of the incident light.
[0114] Embodiment 45: A spectrometer apparatus according to the preceding embodiment, wherein the converging optical element is selected from the group consisting of a converging optical lens, a converging diffractive optical element, and a converging curved mirror.
[0115] Embodiment 46: A spectrometer device according to any one of the preceding three embodiments, wherein the transmission device is disposed between the collection device and the variable length filter.
[0116] Embodiment 47: A spectrometer system comprising: - a spectrometer apparatus according to any one of the preceding embodiments; and - an evaluation unit, which is assigned to determine information about the spectrum of the object by evaluating the detector signal provided by the spectrometer device; A spectrometer system comprising:
[0117] Embodiment 48: A spectrometer system according to the preceding embodiment, wherein the evaluation device is designed to generate information about the spectrum of the object from at least one predetermined relationship between the position of the pixelated sensor in the detector array, the wavelength of the incident light, and the signal of the pixelated sensor.
[0118] Embodiment 49: A spectrometer system according to the preceding embodiment, wherein the detector signal is generated by performing at least one current-voltage measurement and / or at least one voltage-current measurement.
[0119] Embodiment 50: A spectrometer system according to any one of the preceding embodiments relating to a spectrometer system, further comprising an illumination source adapted to illuminate the object.
[0120] Embodiment 51: A spectrometer system according to the preceding embodiment, wherein the irradiation source is selected from at least one of: a flame source; a heat source; a laser, in particular a laser diode; a light emitting diode; an organic light source, in particular an organic light emitting diode; a neon light; a structured light source.
[0121] Embodiment 52: Use of a spectrometer device or spectrometer system according to any one of the preceding embodiments in infrared detection applications; heat detection applications; thermometer applications; heat seeking applications; flame detection applications; fire detection applications; smoke detection applications; temperature sensing applications; spectroscopy applications; exhaust gas monitoring applications; combustion process monitoring applications; pollution monitoring applications; industrial process monitoring applications; chemical process monitoring applications; food processing process monitoring applications; water quality monitoring applications; air quality monitoring applications; quality control applications; temperature control applications; motion control applications; exhaust control applications; gas sensing applications; gas analysis applications; motion sensing applications; chemical sensing applications. [Brief description of the drawings]
[0122] Further optional details and features of the invention are evident from the following description of preferred exemplary embodiments in conjunction with the dependent claims. In this context, certain features may be realized alone or in combination with features. The scope of the invention is not limited to the exemplary embodiments. The exemplary embodiments are illustrated diagrammatically in the figures. The same reference numbers in the individual figures refer to the same elements or elements which correspond to each other in terms of their functionality.
[0123] Specifically, in the diagram: [Figure 1] 1 illustrates an exemplary embodiment of a spectrometer system including a spectrometer device according to the present invention; [Diagram 2] 1A-1C show top views of two exemplary embodiments of preferred non-conical shapes of light collectors. [Diagram 3] 1 shows a side view of an exemplary embodiment of a preferred profile for the sidewall of a light collector. [Figure 4] 1 shows a top view of a further exemplary embodiment of a spectrometer apparatus that uses a collector in an asymmetric arrangement; and [Diagram 5] The change in light transmittance for a symmetric (FIG. 5A) and asymmetric (FIG. 5B) configuration of the light collector is shown. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0124] Fig. 1 shows in a very schematic way an exemplary embodiment of a spectrometer system 110 comprising a spectrometer device 112 according to the invention. As commonly used, the spectrometer device 112 is a device capable of recording the signal intensity of the incident light 114 with respect to a corresponding wavelength or wavelength interval of the incident light 114 over a wavelength range expressed as a spectrum or a division thereof. According to the invention, the spectrometer device 112 can be adapted to record a spectrum in particular in the infrared (IR) spectral region, preferably in the near infrared (NIR) and mid-infrared (MidIR) spectral range, in particular where the wavelength of the incident light is between 1 μm and 5 μm, preferably between 1 μm and 3 μm, and thus can be applied to the detection of heat, flame, fire or smoke, further applications being feasible as well. Here, the incident light 114 can be generated by an object 116, which may be living or non-living, including one or more items and / or parts of one or more items, which may provide a spectrum that may be suitable for investigation in the IR, in particular NIR, spectral region.
[0125] 1 includes a linear variable filter 118 as a preferred example of a variable length filter, where the linear variable filter 118 is assigned to separate the incident light 114 into a spectrum of constituent wavelength signals, the detector array 120 is designed to determine the intensity of each of the received wavelength signals, and the optical element 122 is assigned to receive and transmit the incident light 114 from the object 116 to the linear variable filter 118.
[0126] According to the invention, the optical element 122 comprises a light collector 124, which operates in a reverse direction 126, the reverse-operating light collector 124 comprising a non-conical shape 128. Here, the reverse-operating light collector 124 comprises an input 130, a light guide structure 132 and an output 134. As a result, the incident light 114, which may be emitted or reflected by the object 116 or may pass through the object 116, enters the reverse-operating light collector 124 at the input 130 designed to receive the incident light 114. The incident light 114 captured by the input 130 then preferably passes through a light guide structure 132 designed to spread the incident light 114. Finally, the incident light 114 thus spread is emitted by an output 134 assigned for this purpose. Thus, the angular spread of the light beam emitted at the output 134 can at the same time be reduced compared to the angular spread of the incident light 114. As a result, the inverse-operating concentrator 124 makes it possible to modify the incident light 114 provided by the object 116 such that the light emitted at the output 134 of the inverse-operating concentrator 124 exhibits a reduced angular spread.
[0127] As a result, a major proportion of the light beam provided by the output 134 of the inversely actuated light collector 124 impinges on the linear variable filter 118 in parallel, and in particular perpendicularly on the receiving surface 136 of the linear variable filter 118. As used in this exemplary embodiment, the linear variable filter 118 is or includes an optical filter having a plurality of interference filters, preferably provided in a serial arrangement of interference filters, where each of the interference filters can form a bandpass with a variable center wavelength at each spatial location 138 on the receiving surface 136 of the linear variable filter 118 in such a way that the variable center wavelength can be a linear function of the spatial location 138. As exemplarily shown in FIG. 1, the linear variable filter 118 can thus be arranged along one dimension, typically along the "length" of the linear variable filter 118, preferably continuously. By way of example, the linear variable filter 118 can be a wedge filter carrying at least one responsive coating 140 on a transparent substrate 142, which responsive coating 140 can exhibit spatially variable properties, in particular a spatially variable thickness (not shown here). Here, the transparent substrate 142 may include at least one material that can exhibit a high degree of optical transparency in the IR spectral range, which may preferably be selected from the group consisting of calcium fluoride (CaF2), fused silica, germanium, magnesium fluoride (MgF), potassium bromide (KBr), sapphire, silicon, sodium chloride (NaCl), zinc selenide (ZnSe), zinc sulfide (ZnS), borosilicate-crown glass, transparent conductive oxide (TCO), and transparent organic polymer, where CaF2, fused silica, MgF, KBr, sapphire, NaCl, ZnSe, ZnS, borosilicate-crown glass, transparent conductive oxide, and selected transparent organic polymer may be particularly applicable to the NIR spectral range. However, other embodiments of the linear variable filter 118 may also be feasible. However, other types of variable length filters may also be feasible for the purposes of the present invention.
[0128] The linear variable filter 118 is assigned to separate the incident light 114 into a spectrum of constituent wavelength signals. For this purpose, the incident light 114 can preferably pass through the linear variable filter 118 at a specific spatial location 138 related to the wavelength of the incident light 114. After passing through the linear variable filter 118 at a specific spatial location 138 related to the wavelength of the incident light 114, the incident light 114 subsequently impinges on the detector array 120, specifically on one of a plurality of pixelated sensors 144 included in the detector array 120. Each of the pixelated sensors 144 thus receives at least a portion of one of the constituent wavelength signals provided by the incident light 114 after passing through the linear variable filter 118 as described above. Furthermore, each pixelated sensor 144 is adapted to provide a detector signal related to the intensity of each constituent wavelength. In other words, the spectrometer device 112 is thus assigned to generate a plurality of detector signals based on the constituent wavelength signals, each detector signal being related to the intensity of each constituent wavelength of the spectrum.
[0129] 1, the detector array 120 can be preferably separated from the linear variable filter 118 by a transparent gap 146, which can be obtained, for example, by using a transparent substrate 142. As a result, by selecting an appropriate width for the transparent gap 146, a more precise adjustment of the detector array 120 with respect to the linear variable filter 118 can be realized. As will be shown in more detail below, adjusting the transparent gap 146 can make it possible to further increase the efficiency of the spectrometer device 112.
[0130] The multiple detector signals may be transmitted via signal leads 148 to an evaluation unit 150, which may be included in the spectrometer system 110 in addition to the spectrometer device 112, as shown diagrammatically in Fig. 1. Here, the evaluation unit 150 is generally assigned to determine information regarding the spectrum of the object 116 by evaluating the multiple detector signals provided by the detector array 120 of the spectrometer device 112. For this purpose, the evaluation unit 150 may include one or more electronic devices and / or one or more software components, symbolically indicated by a signal evaluation unit 152, for evaluating the multiple detector signals. Here, the evaluation unit 150 may be adapted to determine at least one item of information regarding the spectrum of the object 116 by comparing two or more detector signals.
[0131] The incident light 114 received by the optical element 122 of the spectrometer device 112 may be generated by a light-emitting object 116. Alternatively or additionally, the incident light 114 may be generated by a separate illumination source 154, which may include an ambient light source and / or an artificial light source, in particular an incandescent lamp 156, which may be assigned to illuminate the object 116 such that the incident light 114 is configured to be received by the optical element 122, in such a way that at least a part of the light generated by the illumination source 154 passes through the object 116 (not shown here) and / or in such a way that the object 116 may reflect at least a part of the light generated by the illumination source 154. Here, the illumination source 154 may be or include a continuously emitting light source and / or a modulated light source. As further shown in FIG. 1, the illumination source 154 may be controlled by at least one illumination control unit 158, which may be adapted to provide modulated light as required. Here, the illumination control unit 158 can further provide information regarding the illumination to the signal evaluation unit 152 and / or can be controlled by the signal evaluation unit 152, which is symbolically indicated by a connection between the illumination control unit 158 and the signal evaluation unit 152 in Fig. 1. Alternatively or additionally, the control of the illumination of the object 116 may take place in the beam path between the illumination source 154 and the object 116 and / or between the object 116 and the optical element 122. Further possibilities are conceivable.
[0132] In general, the evaluation unit 150 may be part of and / or comprise one or more data processing devices 160. The evaluation unit 150 may be fully or partially integrated in a housing 162 with at least the spectrometer device 112 and / or may be fully or partially embodied as a separate device that may be electrically connected to the spectrometer device 112 wirelessly or by wire. The evaluation unit 150 may further include one or more additional components, such as one or more electronic hardware components and / or one or more software components, such as one or more measurement units and / or one or more evaluation units and / or one or more control units (not shown here).
[0133] 1, the spectrometer device 112 includes an optical element 122, a linear variable filter 118, and a detector array 120, which in this particular embodiment are arranged along an optical axis 164 of the spectrometer device 112. In particular, the optical axis 164 may be an axis of symmetry and / or a rotation axis of the configuration of at least one of the optical element 122, the linear variable filter 118, and the detector array 120. In particular, the optical axis 164 may thus be parallel to a plane perpendicular to the receiving surface 136 of the linear variable filter 118. Furthermore, the optical element 122, the linear variable filter 118, and the detector array 120 may preferably be arranged within a housing 162 having at least the spectrometer device 112.
[0134] In further embodiments, at least one transmission device (not shown here), in particular a refractive lens, may furthermore be arranged between the optical element 122 and the linear variable filter 118. However, since in the particular embodiment of Fig. 1 the optical element 122 is implemented in the form of a reverse-acting concentrator 124 with a conical shape 128, the use of a transmission device, in particular a refractive lens, seems unnecessary, since this implementation of the optical element 122 can simultaneously take over the function of the transmission device, in particular a refractive lens, in particular with regard to providing the main proportion of parallel light beams that can impinge perpendicularly on the linear variable filter 118 perpendicular to the receiving face 136 of the linear variable filter 118.
[0135] 2A and 2B show top views of two exemplary embodiments of a preferred non-conical shape 128 of the concentrator 124 with reverse actuation. Figure 2A illustrates generally a compound parabolic concentrator 166 in which the non-conical shape 128 of the concentrator 124 includes a parabolic shape 168, and Figure 2B illustrates generally a compound elliptical concentrator 170 in which the non-conical shape 128 of the concentrator 124 includes an elliptical shape 172. However, the concentrator 124 with reverse actuation may take on additional shapes that are non-conical.
[0136] Here, the reverse-acting light concentrator 124 may be provided in the form of a solid body (not shown here) of transparent optical material having high light transmittance in the IR spectral range in order to increase the reflectivity of the light concentrator 124 . In particular, the inversely operating light collector 124 may be preferably provided in a solid body of at least partially optically transparent material having a high degree of optical transparency in the IR spectral range, which may be selected from the group consisting of calcium fluoride (CaF2), fused silica, germanium, magnesium fluoride (MgF), potassium bromide (KBr), sapphire, silicon, sodium chloride (NaCl), zinc selenide (ZnSe), zinc sulfide (ZnS), borosilicate crown glass, transparent conductive oxides (TCOs), and transparent organic polymers, where CaF2, fused silica, MgF, KBr, sapphire, NaCl, ZnSe, ZnS, borosilicate-crown glass, transparent conductive oxides, and selected transparent organic polymers are particularly applicable in the NIR spectral range, and silicon and germanium, which have a high refractive index, are particularly preferred as they can support total internal reflection that may occur at the sidewalls of the solid body.
[0137] However, as further shown in Figures 2A and 2B, the reverse actuation light collector 124 may alternatively be provided in the form of a hollow body 174 having two opposing separate side walls 176 that may be disposed transversely relative to the longitudinal axis of the light collector 124 to define a desired non-conical shape, in particular the parabolic shape 168 of Figure 2A or the elliptical shape 172 of Figure 2B. In addition to the two opposing separate side walls 176 disposed in a transverse position, the light collector 124 may further include a base plate and a cover plate (both not shown here) to provide the light collector 124 with a closed shape. As a result, the shape of the light collector 124 includes at least four corner lines at the intersection lines between any one of the side walls 176 and any one of the base plate or cover plate of the light collector 124. Again, the reverse actuation light collector 124 may assume different shapes, so long as the different shapes are non-conical. For this purpose, the hollow body 174 having a base plate, a cover plate and two separate side walls 176 exhibiting the desired non-conical shape 128 may contain a vacuum or be filled, preferably completely and / or uniformly, with a gaseous and / or fluid optically transparent material, in particular with a gaseous and / or fluid optically transparent material selected from ambient air, nitrogen gas, carbon dioxide, immersion oil, or Canada balsam, in order to enable its application as a light collector 124 operating in the reverse direction 126.
[0138] In various embodiments, at least one of the side walls 176 of the hollow body 174 constituting the inverse-actuating light collector 124 may be designed as a side wall (not shown here) adapted to absorb those wavelengths of the incident light 114 that may deviate highly from a path that can guide the incident light mainly in parallel to ultimately impinge on the linear variable filter 118. However, such a kind of side wall of the hollow body 174 may reduce the efficiency of the spectrometer device 112, since an absorbed share of the incident light 114 may be prevented from passing through the linear variable filter 118 and ultimately reaching the detector array 120, and thus may not contribute to the detector signal.
[0139] Thus, in a particularly preferred embodiment as shown in Figures 2A and 2B, at least one of the side walls 176 of the hollow body 165 constituting the inversely actuated light collector 124 may be assigned as a reflective side wall 178 adapted to reflect the incident light 114. As a result, the reflective side wall 178 may thus increase the efficiency of the spectrometer device 112 by allowing additional light beams 180 to be guided by reflection at the reflective side wall 178 to the linear variable filter 118 and subsequently to the detector array 120 where they may further contribute to the detector signal. As a result, by providing a reflective side wall 178 that may define the hollow body 174 implementing the inversely actuated light collector 124, the efficiency of the spectrometer device 112 may thus be further increased, in particular by reducing the signal-to-noise ratio.
[0140] 3A to 3D further show side views of exemplary embodiments of preferred profiles 182 of the individual side walls 176 arranged in a transverse position relative to the longitudinal axis of the inversely actuated light collector 124 according to the present invention. As shown therein, the individual side walls 176, in particular the reflective side walls 176, are rounded side walls in order to further improve the efficiency of the spectrometer device 112. Thereby, the profile 183 of each of the individual side walls 166 can be preferably selected from a parabolic profile 184 as shown in FIGS. 3A and 3C, or from an elliptical profile as shown in FIGS. 3B and 3D. Here, the rounded side walls can present a immersion profile 188 that can be immersed in the surface of the hollow body 174 that can constitute the inversely actuated light collector 124, as shown in FIGS. 3A and 3B. As an alternative, as shown diagrammatically in Figures 3C and 3D, the rounded sidewalls may present a bulging profile 190 that may bulge out from the surface of the light collector 124 when the light collector 124 may be or include a solid body 192 of optically transparent material, as described in more detail elsewhere. However, further alternatives, as shown in Figures 3A to 3D, are also applicable to the sidewalls 176 of the light collector 124 of reverse operation according to the present invention. Here, the sidewalls 176 of the light collector 124 may be of uniform shape or may include different types of shapes at different locations. In particular, opposing sidewalls of the light collector 124 may be implemented in the same manner or alternatively in different manners. As an example, one of the sidewalls 176 of the light collector 124 may include a first type of profile, while the opposing sidewall 176 of the light collector 124 may include a second type of profile that is different from the first type of profile.
[0141] 4A further illustrates a schematic top view of a further exemplary embodiment of a spectrometer device 112 according to the present invention. In contrast to the exemplary embodiment of the spectrometer device 112 of FIG. 1, which assumes a symmetrical arrangement of the optical elements 122, the linear variable filter 118, and the detector array 120 along the optical axis 164 of the spectrometer device 112, the optical elements 122 of the spectrometer device 112 illustrated in FIG. 4A exhibit an asymmetrical arrangement 200.
[0142] Furthermore, a transfer device (not shown here), which may in particular be an optical lens, a curved mirror, a grating, or a diffractive optical element, may be arranged between the inversely acting light collector 124 and the linearly variable length filter 118. Preferably, the optical lens may in particular be selected from the group consisting of a biconvex lens, a plano-convex lens, a biconcave lens, a plano-concave lens, an aspheric lens, a cylindrical lens, and a meniscus lens. However, other types of transfer devices may also be feasible.
[0143] Thus, according to the invention, the axis of symmetry 202 of the optical element 122, provided in the form of a collector 124 arranged in the reverse direction 126 and having a non-conical shape 128, is inclined by an angle α with respect to the optical axis 164 of the spectrometer device 112, which is parallel to a plane perpendicular to the receiving face 136 of the linear variable filter 118, as described above. Here, the angle α is selected taking into account not only the incident light 114 transmitted to the linear variable filter 118, impinging on the linear variable filter 118 at a spatial position 138 of the linear variable filter 118 designed to receive the wavelength of the incident light 114, perpendicular to the receiving face 136 of the linear variable filter 118, but also the incident light 114 transmitted to the linear variable filter 118, impinging on the linear variable filter 118 at a further spatial position 138' of the linear variable filter 118 designed to receive further wavelengths beyond the wavelength of the incident light 114.
[0144] Thus, although the light beam 180 may pass through the linear variable filter 118 at a longer wavelength compared to the inherent wavelength, due to the relative arrangement between the linear variable filter 118 and the detector array 120, which are separated by a transparent gap 146 as described in more detail elsewhere in this document, the light beam 180 may still impinge on a particular pixelated sensor 144 provided for determining the intensity of the incident light at the particular wavelength of the incident light beam 114. As a result, not only the light beam 180 impinging on the linear variable filter 118 perpendicular to the receiving surface 136 of the linear variable filter 118 at a spatial location 138 on the linear variable filter 118 assigned for this purpose, but also the light beam 180' impinging on the linear variable filter 118 at a further spatial location 138' assigned to receive a longer wavelength compared to the wavelength of the incident light 114 will still impinge on the same particular pixelated sensor 144 designed to receive the particular wavelength of the incident light 114. As a result, the light beam 180 ′ may also therefore contribute to the electrical signal generated by a particular individual pixelated sensor 144 , thereby further increasing the efficiency of the spectrometer apparatus 112 .
[0145] As shown diagrammatically in the top view of FIG. 4B, the asymmetric arrangement 200 of the optical elements 122 in the spectrometer device 112 as shown in FIG. 4A may provide a further advantage. As shown here, each of the three different light beams 180, 180', 180" having three different wavelengths may generate a detector signal 204, 204', 204" at the corresponding pixelated sensor 144 of the detector array 120 having the same intensity regardless of wavelength within a defined tolerance level. This advantage may be achieved even when using an incandescent lamp 156 as the illumination source 158, which may be considered a thermal emitter in the IR spectral range and therefore exhibits a radiant output that decreases with increasing wavelength. However, this effect may be surpassed by the asymmetric arrangement 200 of the optical elements 122, in which a longer path may be provided for the light beam 180 having a shorter wavelength compared to the light beam 180" having a longer wavelength.
[0146] Furthermore, further effects that may affect the intensity of the light beam 180, 180', 180" at the pixelated sensor 144 may thus be overcome. In particular, known IR absorbing materials exhibit a tendency for absorption to increase with increasing wavelength. Furthermore, since the bandpass width of the linear variable filter 118 typically assumes a constant value, such as 1%, over the spectral range of the linear variable filter 118, the resolution of the linear variable filter 118, which is inversely proportional to the bandpass width, decreases with increasing wavelength. Furthermore, the resolution of the linear variable filter 118 generally depends on the central wavelength of the linear variable filter. However, while the higher radiant output of the incandescent lamp 156 and the lower bandpass width at shorter wavelengths may result in the efficiency of the spectrometer device 112 being more evenly distributed over the wavelength range, the asymmetric arrangement 200 of the optical elements 122 helps the spectrometer device 112 to be more receptive to longer wavelengths.
[0147] The efficiency of the spectrometer device 112 can be further increased if at least one of the side walls 176 of the inversely operating light collector is a reflective side wall 178. As shown diagrammatically in FIG. 4B, the reflective side wall 178 reflects an additional light beam 180. * 4A and 4B may be implemented with absorbing sidewalls (not shown here).
[0148] 5A and 5B each show a schematic variation of the transmittance, which may be defined by the relative intensity I / I0 of a transmission peak 206 as a function of the wavelength λ [nm] of the corresponding transmission peak 206 after transmission of the incident light 114 through the linear variable filter 118 of the spectrometer device 112, by respective simulations. Here, for example, a symmetrical arrangement 208 of the light collector 124 with respect to the optical axis 164 of the spectrometer device 112, as shown in FIGS. 1, 2A and 2B, was selected to determine the transmission peak 206 of FIG. 5A, while an asymmetrical arrangement 200 of the light collector 124, as shown in FIGS. 4A and 4B, was used to obtain the transmission peak 206 shown in FIG. 5B.
[0149] As a result of the asymmetric arrangement 200 of the light collectors 124, a shift of the maximum of the relative intensity I / I0 of the transmission peaks 206, and of their focal angles α, towards longer wavelengths can be observed. Furthermore, the transmission peaks 206 appear to have smaller peak widths 210, particularly at half maximum, in the asymmetric arrangement 200 of FIG. 5B, compared to the peak width at half maximum 210' in the symmetric arrangement 208 of FIG. 5A, resulting in a reduction in the bandpass width in the asymmetric arrangement 200. By way of example, the peak width at half maximum 210, and therefore the bandpass width, can be reduced by about 5% for the transmission peak 212 having the longest wavelength. Furthermore, the spectrum that can be fully acquired with each spectrometer arrangement 112 can therefore be estimated to increase slightly from a first spectral range 214 of 1270 nm to 2340 nm in the symmetric arrangement 208 as used in FIG. 5A to a second spectral range 216 of 1230 nm to 2390 nm in the asymmetric arrangement 200 as used in FIG. 5B.
[0150] In summary, the transmittance increases more strongly towards longer wavelengths and decreases more strongly towards smaller wavelengths in the asymmetric arrangement 200 compared to the symmetric arrangement 208 of the concentrator 124, thus facilitating the spectrometer device 112 to exhibit a higher reception for longer wavelengths. However, as mentioned above, this effect can be easily overcome by using an incandescent lamp 156 with a higher radiant output, which in turn can provide a spectrometer device 112 with an efficiency that can be more evenly distributed across its wavelength range. [Explanation of symbols]
[0151] 110 Spectrometer System 112 Spectrometer equipment 114 Incident light 116 Object 118 Linear variable filters as a preferred example of variable length filters 120 Detector Array 122 Optical elements 124 Reverse-acting light-collecting device 126 Reverse direction 128 Non-conical shape 130 Input 132 Guide structure 134 Output 136 Receiving surface 138,138' spatial position 140 Response Coating 142 Transparent Substrate 144 pixelated sensor 146 Transparent Gap 148 Signal Lead 150 evaluation units 152 Signal Evaluation Unit 154 Irradiation source 156 Incandescent lamp 158 Irradiation Control Unit 160 Data Acquisition Device 162 Housing 164 Optical axis 166 Compound Parabolic Concentrator 168 Parabolic Shape 170 Compound Elliptical Concentrator 172 Oval 174 Hollow body 176 individual side walls 178 Reflective sidewalls 180,180',180'',180 * Light beam 182 Profiles 184 Parabolic Profile 186 Oval Profile 188 Intrusion Profiles 190 protruding profile 192 Solid Body 200 Asymmetrical Arrangement 202 Axis of Symmetry 204 Detector Signal 206 Transmission Peak 208 Symmetrical Arrangement 210,210' Peak width (half value) 212 Transmission peak with the longest wavelength 214 First Spectral Range 216 Second Spectral Range
Claims
1. A spectrometer apparatus (112) comprising: an optical element (122) designed to receive incident light (114) from an object (116) and transmit said incident light (114) to a variable length filter (118) having a succession of bandpasses with variable center wavelengths, said optical element (122) comprising a light collector (124), said light collector (124) comprising a non-conical shape (128); said variable length filter (118) assigned to separate said incoming light (114) into a spectrum of constituent wavelength signals; and a detector array (120) including a plurality of pixelated sensors (144), each pixelated sensor (144) configured to receive at least a portion of one of the constituent wavelength signals, each constituent wavelength signal related to an intensity of a respective constituent wavelength; The focusing device (124) spreads the incident light (114) and simultaneously focuses the light beam (180, 180', 180'', 180 * ) in a direction opposite to the collecting direction (126) to reduce the diffusion of each of the A spectrometer arrangement (112), wherein the non-conical shape (128) of the light collector is asymmetrically positioned with respect to the variable length filter (118).
2. The apparatus (112) of claim 1, wherein the non-conical shape (128) of the light concentrator (124) comprises a shape selected from a parabolic shape (168) or an elliptical shape (172).
3. The apparatus (112) of claim 2, wherein the concentrator (124) is selected from the group consisting of a compound parabolic concentrator (166) and a compound elliptical concentrator (170).
4. The apparatus (112) of any one of claims 1 to 3, wherein the light collecting device (124) is inclined with respect to a plane perpendicular to a receiving surface (136) of the variable length filter (118).
5. The apparatus (112) of claim 4, wherein the light concentrator (124) is inclined with respect to a plane perpendicular to the receiving surface (136) of the variable length filter (118) so that the incident light (114) transmitted to the variable length filter (118) impinges on the variable length filter (118) perpendicular to the receiving surface (136) of the variable length filter (118) at a spatial position (138) of the variable length filter (118) designed to receive the wavelength of the incident light, and / or at a further spatial position (138') of the variable length filter (118) designed to receive a further wavelength beyond the wavelength of the incident light (114).
6. The apparatus (112) of any one of claims 1 to 5, wherein the light collecting device (124) has at least two distinct side walls (176) adapted to reflect the incident light (114).
7. The device (112) of claim 6, wherein at least one of the side walls (176) of the light collector (124) is designed as a rounded side wall.
8. 8. The apparatus (112) of claim 7, wherein at least one of the rounded sidewalls of the light concentrator (124) includes a profile (182) selected from a parabolic profile (184) or an elliptical profile (186).
9. The apparatus (112) of any one of claims 1 to 8, wherein the detector array (120) is separated from the variable length filter (118) by a transparent gap (146).
10. The apparatus (112) of any one of the preceding claims, further comprising an illumination source (154) adapted to illuminate the object (116).
11. The apparatus (112) of claim 10, wherein the illumination source (154) comprises an incandescent lamp (156).
12. A spectrometer system (110), comprising: a spectrometer device (112) according to any one of claims 1 to 11; and an evaluation unit (150) assigned to determine information about the spectrum of the object (116) by evaluating the detector signals (204, 204', 204'') provided by said spectrometer device (112); A spectrometer system (110).
13. The system (110) of claim 12, further comprising an illumination source adapted to illuminate the object (116).
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