Resin-impregnated decorative paper and resin-impregnated decorative board

Abstract

To provide a resin-impregnated decorative paper and resin-impregnated decorative board that have suppressed costs and furthermore are excellent in gloss matte expression and feeling to the touch.SOLUTION: A resin-impregnated decorative paper 2 is provided in which an impregnation resin 5 is impregnated in a decorative paper 4. The decorative paper 4 comprises a base paper 6, a pattern layer 7 provided on the surface 6a side of the base paper 6, a filling layer 8 provided on the surface 7a of the pattern layer 7, and a foamed resin layer 9 provided on the surface 8a of the filling layer 8. The filling layer 8 includes at least one of an epoxy-based resin, an acryl-based resin, an urethane-based resin, and a casein-based resin.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to a resin-impregnated decorative paper and a resin-impregnated decorative board. [Background technology]

[0002] A method for manufacturing a resin-impregnated decorative board has been proposed in the past, in which a metal plate is brought into contact with a laminate of a resin-impregnated decorative paper impregnated with a thermosetting resin and a substrate, and heat and pressure molding is performed to obtain a resin-impregnated decorative board in which the resin-impregnated decorative paper and the substrate are integrated (see, for example, Patent Document 1). In the method for manufacturing a resin-impregnated decorative board described in Patent Document 1, an embossed shape is provided on the metal plate, and an uneven pattern is imparted to the surface of the resin-impregnated decorative board, thereby imparting a tactile feel. In addition, the coarseness and density of the embossed shape can be adjusted to impart a glossy or matte appearance. However, in the manufacturing method of resin-impregnated decorative board described in Patent Document 1, it is necessary to prepare a metal plate for each concave-convex pattern to be imparted, which may increase costs. Therefore, it is considered to impart the concave-convex pattern by providing a foamed resin layer. However, foamed resin, which is compatible with impregnating resins such as melamine resin, tends to soak into the base paper, which may reduce the feel and gloss matte feel. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Publication No. 09-262956 Summary of the Invention [Problem to be solved by the invention]

[0004] The present invention has been made in consideration of the above-mentioned problems, and has an object to provide a resin-impregnated decorative paper and a resin-impregnated decorative board that have an excellent gloss and matte appearance and a good feel while keeping costs down. [Means for solving the problem]

[0005] A resin-impregnated decorative paper according to one embodiment of the present invention is a resin-impregnated decorative paper in which decorative paper is impregnated with an impregnating resin, the decorative paper comprising a base paper, a picture pattern layer provided on the surface side of the base paper, a filling layer provided on the surface of the picture pattern layer, and a foamed resin layer formed by a foaming agent on the surface of the filling layer, the filling layer containing at least one of an epoxy-based resin, an acrylic-based resin, a urethane-based resin, and a casein-based resin. A resin-impregnated decorative board according to another aspect of the present invention comprises a resin-impregnated decorative paper and a substrate integrated with the resin-impregnated decorative paper. Effect of the Invention

[0006] According to the present invention, the foaming agent can be foamed by heat and pressure molding, and a concave-convex pattern can be appropriately formed on the surface of the resin-impregnated decorative paper. Since there is no need to prepare a metal plate for each concave-convex pattern, it is possible to provide a resin-impregnated decorative paper and a resin-impregnated decorative board that are excellent in gloss matte expression and touch feeling while keeping costs down. In addition, since a sealing layer containing at least one of epoxy resin, acrylic resin, urethane resin, and casein resin is provided, it is possible to prevent the foamed resin that forms the foamed resin layer from seeping into the picture pattern layer or base paper. Therefore, it is possible to provide a resin-impregnated decorative paper and a resin-impregnated decorative board that are excellent in gloss matte expression and touch feeling. [Brief description of the drawings]

[0007] [Figure 1] FIG. 2 is a cross-sectional view showing the resin-impregnated decorative board after hot and pressure molding. [Diagram 2] FIG. 2 is a cross-sectional view showing a resin-impregnated decorative board before hot and pressure molding. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0008] The decorative paper, resin-impregnated decorative paper, and resin-impregnated decorative board according to the embodiments of the present invention will be described below with reference to the drawings. The present invention is not limited to the embodiments described below, and modifications such as design changes can be made based on the knowledge of those skilled in the art, and such modified embodiments are also included in the scope of the present invention. In addition, the drawings are appropriately exaggerated to make them easier to understand.

[0009] (composition) As shown in Figures 1 and 2, the resin-impregnated decorative board 1 according to the embodiment of the present invention is a decorative board formed by subjecting a laminate of a resin-impregnated decorative paper 2 and a substrate 3 to heat and pressure molding to integrate the resin-impregnated decorative paper 2 and the substrate 3. That is, the resin-impregnated decorative board 1 includes the substrate 3 and the resin-impregnated decorative paper 2 provided on the surface 3a side of the substrate 3. The resin-impregnated decorative board 1 according to the embodiment of the present invention is a resin-impregnated decorative board used for, for example, interior decoration of floors, walls, ceilings, etc. of buildings, surface decoration materials for furniture and various cabinets, surface decoration of fittings, vehicle interiors, etc. Figure 1 shows the resin-impregnated decorative board 1 after heat and pressure molding, and Figure 2 shows the resin-impregnated decorative board 1 before heat and pressure molding.

[0010] (base material) The type of the substrate 3 is not particularly limited, and any substrate can be used depending on the intended use of the resin-impregnated decorative board 1. For example, wood substrates such as wood veneer, plywood, laminated lumber, particle board, medium density fiberboard, and hard fiberboard, fibrous substrates such as paperboard, woven fabric, nonwoven fabric, resin-impregnated paper, and resin-impregnated cloth, inorganic substrates such as gypsum board, slate board, calcium silicate board, slag gypsum board, wood wool cement board, slag cement board, lightweight aerated concrete board, and glass fiber reinforced concrete board, metal substrates such as steel plate, brass plate, aluminum plate, duralumin plate, and stainless steel plate, synthetic resin substrates such as acrylic resin plate, styrene resin plate, ABS (Acrylonitrile butadiene styrene) resin plate, polycarbonate resin plate, nylon resin plate, polystyrene resin plate, polypropylene resin plate, polyester resin plate, and glass fiber reinforced plastic plate, or composites or laminates of two or more of these substrates can be used.

[0011] (Resin-impregnated decorative paper) Resin-impregnated decorative paper 2 according to an embodiment of the present invention is formed by impregnating the entirety of decorative paper 4 with impregnating resin 5 and then drying. Decorative paper 4 comprises base paper 6, a picture pattern layer 7, a filling layer 8, and a foamed resin layer 9. Picture pattern layer 7 is provided on surface 6a of base paper 6. Filler layer 8 is provided on surface 7a of picture pattern layer 7. Foamed resin layer 9 is provided on surface 8a of filling layer 8.

[0012] (base paper) The base paper 6 can be a fibrous sheet such as paper with good water absorption properties that can be impregnated with the impregnating resin 5. For example, thin paper, titanium paper, high-quality paper, bleached or unbleached kraft paper, etc. can be used. In particular, titanium paper is most suitable when both printability and resin impregnation suitability are taken into consideration. In addition, when making the most of the texture of the surface 3a of the substrate 3, it is preferable to use so-called transparent paper, which has the property of becoming transparent upon impregnation with the impregnating resin 5. The thickness of the base paper 6 is not particularly limited, but a basis weight of 20 g / m 2 More than 200g / m 2 The following ranges are preferred:

[0013] (Pattern layer) The picture pattern layer 7 is a layer for imparting design by a picture pattern to the resin-impregnated decorative paper 2. The picture pattern layer 7 is formed using a printing ink or the like obtained by dissolving or dispersing a colorant such as a dye or pigment together with an appropriate binder resin in a dilution solvent. The type of printing ink is not particularly limited, and may be an oil-based ink or a water-based ink. In other words, the printing ink may be a normal printing ink that does not have liquid repellency. In particular, water-based inks are most suitable in consideration of the impregnation suitability of the impregnating resin 5. Water-based inks have better compatibility with the aqueous solution of the impregnating resin than oil-based inks. Therefore, when water-based inks are used, the impregnating resin 5 can be rapidly and uniformly impregnated into the decorative paper 4 during the impregnation process in the manufacture of the resin-impregnated decorative board 1, and the integration with the impregnating resin 5 can provide excellent strength to the picture pattern layer 7. The type of water-based ink is not particularly limited, but it is preferable to use one that contains a binder resin whose main components are casein and emulsion resin.

[0014] Such binder resins have the property of becoming poorly water-soluble through a drying process after printing of the ink. Therefore, when a binder resin containing such a binder resin is used, the picture pattern layer 7 is unlikely to re-dissolve in the aqueous solution of the impregnating resin 5 during the resin impregnation process in the manufacture of the resin-impregnated decorative board 1, so that the picture pattern can be maintained and further contamination of the impregnating resin 5 can be prevented. Examples of the emulsion resin that can be used include acrylic, vinyl acetate, styrene, and urethane resins. In addition to casein and emulsion resins, the binder resin may also include water-soluble resins such as polyvinyl alcohol and polyacrylamide, and water-soluble polymers such as polysaccharides and cellulose derivatives in order to improve the stability of the ink.

[0015] The method for forming the picture pattern layer 7 is not particularly limited, and any printing method can be used, such as gravure printing, offset printing, screen printing, flexographic printing, letterpress printing, inkjet printing, etc. A solid ink layer for the purpose of base coloring may be provided between the picture pattern layer 7 and the base paper 6. When a solid ink layer is provided, in addition to the above-mentioned various printing methods, any coating method can be used, such as roll coating, gravure coating, rod coating, knife coating, air knife coating, spray coating, lip coating, die coating, etc., as the method for forming the solid ink layer. The type of pattern formed by the picture pattern layer 7 is not particularly limited, and any pattern can be used depending on the intended use of the resin-impregnated decorative board 1. For example, wood grain patterns, stone patterns, fabric patterns, abstract patterns, geometric figures, letters, symbols, solid colors, etc., or a combination of two or more selected from these can be used.

[0016] (Sealing layer) The filling layer 8 is a coating layer partially formed on the picture pattern layer 7, which prevents the foamed resin from penetrating into the base paper 6. As the resin constituting the filling layer 8, for example, a thermosetting resin having a urethane bond, such as a two-component curing urethane resin, or a curable resin, such as an ionizing radiation curable resin, can be used. As the curable resin, for example, a thermosetting resin, such as an epoxy resin, an acrylic resin, a urethane resin, a casein resin, a melamine resin, a urea resin, a phenol resin, an unsaturated polyester resin, a diallyl phthalate resin, a benzoguanamine resin, an aminoalkyd resin, or a silicone resin, or an ionizing radiation curable resin, such as a (meth)acrylate resin or an unsaturated polyester resin, can be used.

[0017] The printing method for the filling layer 8, like the picture pattern layer 7, is not particularly limited, and any printing method can be used, such as gravure printing, offset printing, screen printing, flexographic printing, letterpress printing, inkjet printing, etc. The position where the filling layer 8 is formed can be one that is in harmony with the design of the pattern (picture design) of the picture pattern layer 7. For example, the filling layer 8 is formed at a location in the pattern (picture design) of the picture pattern layer 7 where a matte or glossy texture is desired to be expressed. This can further improve the design of the resin-impregnated decorative board 1. The resin for forming the filling layer 8 may be colorless or colored.

[0018] The thickness of the filling layer 8 may be from 0.5 μm to 15 μm, and more preferably from 1 μm to 10 μm. If it is less than 0.5 μm, the foamed resin (thermoplastic resin) may seep into the base paper 6. If it is more than 15 μm, the designability is reduced. The filling layer 8 may be provided over a range of 100% or more of the surface area (coating area) of the foamed resin layer 9, but is more preferably provided over a range of 150% or less of the surface area of ​​the foamed resin layer 9. If it is less than 100% of the surface area of ​​the foamed resin layer 9, the foamed resin forming the foamed resin layer 9 may soak into the picture pattern layer or base paper. If it is more than 150% of the surface area of ​​the foamed resin layer 9, the designability is reduced. In addition, when the position of the foamed resin layer 9 is synchronized with the pattern formed by the picture pattern layer 7, it can be rephrased as follows. The filling layer 8 may be provided over a range of 100% or more of the area of ​​the pattern formed by the picture pattern layer 7, but is more preferably provided over a range of 150% or less of the area of ​​the pattern formed by the picture pattern layer 7.

[0019] (Foamed resin layer) The foamed resin layer 9 is a layer for imparting a glossy matte appearance and a tactile feel by the uneven pattern 10 on the surface of the resin-impregnated decorative paper 2. The type of foaming agent is not particularly limited, and any foaming agent can be used. For example, azo-based foaming agents such as azodicarbonamide and azobisformamide, hydrazide-based foaming agents such as oxybenzenesulfonylhydrazide and paratoluenesulfonylhydrazide, and other thermal decomposition-type chemical foaming agents, microcapsule foaming agents, and the like can be used. In particular, a microcapsule foaming agent is most suitable. The microcapsule foaming agent has a capsule and a volatile substance enclosed in the capsule. The microcapsule foaming agent is in a foamed state when the volatile substance evaporates and expands the capsule. For example, vinylidene chloride-acrylonitrile copolymer can be used as the material of the capsule. For example, aliphatic hydrocarbon can be used as the material of the volatile substance.

[0020] The foaming agent preferably has an average particle size before foaming of 2 / 3 to 50 times the thickness of the picture pattern layer 7. If the particle size is less than 2 / 3 times the thickness of the picture pattern layer 7, the gloss matte feel and the touch may be weakened. On the other hand, if the particle size is more than 50 times the thickness of the picture pattern layer 7, the foamed resin layer 9 after foaming may fall off from the decorative paper 4, and the scratch resistance may be weakened. Here, the average particle size is the average particle size observed by microscope. The average particle size observed by microscope can be obtained, for example, by observing the foaming agent under a microscope, measuring the particle size of 100 particles of the foaming agent observed under the microscope using image processing software, and averaging the measurement results by number. The particle size of the foaming agent can be the average value of the major axis diameter and minor axis diameter of the foaming agent particles.

[0021] The foaming agent preferably has an average particle size of 15 μm or more and 250 μm or less after foaming. If it is less than 15 μm, the gloss matte feeling and the touch may be weakened. On the other hand, if it is more than 250 μm, the foamed resin layer 9 after foaming may fall off from the decorative paper 4, and the scratch resistance may be weakened. More preferably, it is 30 μm or more and 200 μm or less. Here, the average particle size of the foaming agent after foaming is the average particle size observed by a microscope, like the average particle size of the foaming agent before foaming. In addition, the particle size of the foaming agent after foaming used to obtain the average particle size can be the average value of the major axis diameter and the minor axis diameter of the voids formed by the foaming of the foaming agent. The foaming start temperature of the foaming agent is preferably 100°C or higher and 220°C or lower. If the temperature is lower than 100°C, the timing of foaming start is early, so the time for which the foamed resin layer 9 is heated and pressurized after foaming is longer, and the foamed resin layer 9 is crushed after foaming, which may weaken the gloss matte feeling and the feel. On the other hand, if the temperature is higher than 220°C, the foamed resin layer 9 may not be sufficiently foamed during the heat and pressure molding performed by contacting a metal plate (mirror plate) during the production of the resin-impregnated decorative board 1, which may weaken the gloss matte feeling and the feel. A temperature of 120°C or higher and 200°C or lower is more preferable.

[0022] The type of the uneven pattern 10 formed by the foamed resin layer 9 after foaming is not particularly limited, and may be in harmony with the pattern formed by the picture pattern layer 7 or may be out of harmony. In particular, when considering obtaining a resin-impregnated decorative board 1 with excellent design, it is most preferable to have a pattern that is in harmony with the pattern formed by the picture pattern layer 7. When the pattern formed by the picture pattern layer 7 and the uneven pattern 10 are to be in harmony with each other in terms of design, the position of the foamed resin layer 9 is made to be in harmony with the pattern formed by the picture pattern layer 7. That is, the foamed resin layer 9 is placed on a part of the pattern formed by the picture pattern layer 7 where a matte texture is desired to be expressed. For example, the foamed resin layer 9 is placed on the surface of the picture pattern layer 7 so as to cover a dark color part that is relatively less bright than the other parts of the pattern formed by the picture pattern layer 7. The ratio of the area covered by the foamed resin layer 9 to the area of ​​the dark color part is preferably 70% or more. In particular, 90% or more is most preferable. When the design of the picture pattern layer 7 is a wood grain pattern, the foamed resin layer 9 is arranged in a vascular pattern that is in harmony with the wood grain pattern of the picture pattern layer 7. The color of the foamed resin layer 9 is not particularly limited, and may be colorless or colored.

[0023] When the foamed resin layer 9 is disposed in the picture pattern layer 7, the foamed resin layer 9 is disposed in the picture pattern layer 7 by being mixed in a dark color part that is relatively lighter than other parts of the picture formed by the picture pattern layer 7. The ratio of the volume of the foamed resin layer 9 to the total volume of the dark color part and the volume of the foamed resin layer 9 is preferably 70% or more. In particular, 90% or more is most preferable.

[0024] The method of arranging the foamed resin layer 9 is not particularly limited, and for example, a method of printing a printing ink obtained by dispersing the foamed resin layer 9 together with a suitable binder resin in a dilution solvent on the picture pattern layer 7 can be used. As the binder resin, for example, a thermosetting resin having a urethane bond such as a two-component curing urethane resin, a curable resin such as an ionizing radiation curable resin, or a resin mainly containing casein or emulsion resin can be used. As the thermosetting resin, for example, a melamine-based resin, an epoxy-based resin, a urea-based resin, a phenol-based resin, an unsaturated polyester-based resin, a diallyl phthalate-based resin, a benzoguanamine-based resin, a urethane-based resin, an aminoalkyd-based resin, a silicone-based resin, etc. can be used. Also, as the ionizing radiation curable resin, for example, a (meth)acrylate-based resin, an unsaturated polyester-based resin, etc. can be used.

[0025] In addition, the printing method of the printing ink for the foamed resin layer 9, like the picture pattern layer 7, is not particularly limited, and any printing method can be used, such as gravure printing, offset printing, screen printing, flexographic printing, letterpress printing, inkjet printing, etc. The foamed resin layer 9 contains a colored ink. As a vehicle for the colored ink, one or more of chlorinated polyolefins such as chlorinated polyethylene and chlorinated polypropylene, polyester, polyurethane made of isocyanate and polyol, polyacrylic, polyvinyl acetate, polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, cellulose resin, polyamide resin, etc. can be used, and a pigment, a solvent, various auxiliary agents, etc. can be added to the mixture to form an ink.

[0026] (Method of manufacturing resin-impregnated decorative panels) Next, a method for producing the resin-impregnated decorative board 1 according to an embodiment of the present invention will be described. First, a picture pattern layer 7 is provided on a surface 6a of a base paper 6, a filling layer 8 is provided on the surface 7a of the picture pattern layer 7, and a foamed resin layer 9 is provided on the surface 8a of the filling layer 8 to form the decorative paper 4. Then, the decorative paper 4 is immersed in an aqueous impregnation liquid in which an impregnation resin 5 is dissolved or dispersed in water, and the decorative paper 4 is impregnated with the impregnation resin 5.

[0027] The impregnating resin 5 may be a thermosetting resin used in the manufacture of a known resin-impregnated decorative board. For example, melamine-based resin, epoxy-based resin, diallyl phthalate-based resin, benzoguanamine-based resin, urethane-based resin, alkyd-based resin, unsaturated polyester-based resin, phenol-based resin, urea-based resin, etc. may be used. The impregnation with the impregnating resin 5 may be performed from the surface side of the decorative paper 4 on which the picture pattern layer 7 is formed, or from the opposite surface side. Also, each surface may be impregnated twice, or both surfaces may be impregnated simultaneously. The impregnation rate of the impregnating resin 5 (the ratio of the mass of the impregnating resin to the mass of the decorative paper 4 after impregnation) is preferably 20% or more and 80% or less. In particular, 40% or more and 70% or less is most suitable. In order to obtain a resin-impregnated decorative board 1 with excellent physical properties, it is important to impregnate the entire base paper 6 with the impregnating resin 5 uniformly.

[0028] Next, the decorative paper 4 impregnated with the impregnating resin 5 is dried to obtain the resin-impregnated decorative paper 2. Next, the resin-impregnated decorative paper 2 is placed on the substrate 3 (FIG. 2), and a metal plate (mirror plate) is placed on the surface of the resin-impregnated decorative paper 2 on which the foamed resin layer 9 is formed, and the laminate of the resin-impregnated decorative paper 2 and the substrate 3 is heated and pressurized to integrate the resin-impregnated decorative paper 2 and the substrate 3, thereby obtaining the resin-impregnated decorative board 1. At this time, the foaming agent is foamed by the heat during the heating and pressurizing, and the position where the foamed resin layer 9 is arranged rises, forming an uneven pattern 10 (FIG. 1). The formed uneven pattern 10 gives the resin-impregnated decorative board 1 a glossy matte feel and a tactile feel. Here, the case where foaming is performed after impregnation has been described, but this is not limited to this, and impregnation and foaming may be performed simultaneously.

[0029] In addition, an adhesive or the like may be interposed between the base material 3 and the resin-impregnated decorative paper 2, or an adhesive or the like may not be interposed. Also, if necessary, a core paper may be interposed in the same manner as in the method adopted for known melamine resin decorative boards. As the core paper, for example, a suitable base paper such as titanium paper, bleached or unbleached kraft paper, glass fiber nonwoven fabric, etc., impregnated with an uncured thermosetting resin can be used. In addition, as the thermosetting resin, any thermosetting resin can be used depending on the physical properties required for the intended resin-impregnated decorative board 1. For example, melamine-based resin, epoxy-based resin, diallyl phthalate-based resin, benzoguanamine-based resin, urethane-based resin, alkyd-based resin, unsaturated polyester-based resin, phenol-based resin, urea-based resin, etc. can be used. An example of the core paper is phenolic resin-impregnated kraft paper, which has been widely adopted as a core paper for melamine resin decorative boards.

[0030] As a heat and pressure molding method for bonding the resin-impregnated decorative paper 2 in a laminated state onto the base material 3, for example, a method of flat pressing with a metal plate in contact, a continuous lamination method using a circular pressure method, etc. can be used. In particular, a continuous lamination method using an endless metal belt is preferable. With the continuous lamination method, a high-quality resin-impregnated decorative board 1 that is densely cured and integrated without surface warping or waviness, with good interlayer adhesion, can be continuously produced at high speed. When the continuous lamination method is used, the surface shape of the resin-impregnated decorative board 1 is the same as that of the embossed sheet made of a metal plate, an endless metal belt, a curable resin, etc., used in the continuous lamination method. Therefore, by using an embossed sheet made of a metal plate, an endless metal belt, a curable resin, etc., with a surface polished to a mirror-like smoothness, it is possible to obtain a resin-impregnated decorative board 1 with excellent surface gloss and smoothness.

[0031] Of course, if necessary, it is also possible to obtain a resin-impregnated decorative board 1 with any desired surface finish state depending on the intended use of the resin-impregnated decorative board 1 by using any desired matte or textured metal plate, metal endless belt, embossed sheet made of curable resin, etc. The resin-impregnated decorative board 1 of the present invention is not limited to the embodiment described above in detail, and can be implemented with various modifications without departing from the spirit of the present invention.

[0032] As described above, the resin-impregnated decorative paper 2 according to the embodiment of the present invention is a decorative paper 4 impregnated with an impregnating resin 5, and the decorative paper 4 includes a base paper 6, a picture pattern layer 7, a filler layer 8, and a foamed resin layer 9. The picture pattern layer 7 is provided on the surface 6a side of the base paper 6. The filler layer 8 contains at least one of an epoxy resin, an acrylic resin, a urethane resin, and a casein resin, and the filler layer 8 is provided on the surface 7a of the picture pattern layer 7. The foamed resin layer 9 is provided on the surface 8a of the filler layer 8. This allows the foaming agent to be foamed by heat and pressure molding, and the uneven pattern can be appropriately formed on the surface of the resin-impregnated decorative paper. In addition, since there is no need to prepare a metal plate for each uneven pattern 10, it is possible to provide a resin-impregnated decorative paper 2 and a resin-impregnated decorative board 1 that are excellent in gloss matte expression and feel while keeping costs down. It is also possible to prevent the foamed resin forming the foamed resin layer 9 from seeping into the picture pattern layer 7 and the base paper 6. Therefore, it is possible to provide a resin-impregnated decorative paper 2 and a resin-impregnated decorative board 1 that have an even more excellent gloss and matte appearance and feel.

[0033] In addition, the thickness of the filling layer 8 is set to 0.5 μm or more and 15 μm or less, thereby preventing deterioration of the design and providing a resin-impregnated decorative paper 2 and a resin-impregnated decorative board 1 that are excellent in gloss and matte expression and feel. In addition, the thickness of the filling layer 8 is set to 1 μm or more and 10 μm or less, which effectively prevents the design from being deteriorated, and makes it possible to provide a resin-impregnated decorative paper 2 and a resin-impregnated decorative board 1 that are excellent in gloss and matte expression and feel. Furthermore, the filling layer 8 is provided over an area of ​​100% or more of the surface area of ​​the foamed resin layer 9. This makes it possible to provide a resin-impregnated decorative paper 2 and a resin-impregnated decorative board 1 that are excellent in gloss and matte appearance and feel. The filling layer 8 is provided in an area of ​​150% or less of the surface area of ​​the foamed resin layer 9. This makes it possible to provide a resin-impregnated decorative paper 2 and a resin-impregnated decorative board 1 that effectively prevent deterioration of the design.

[0034] Furthermore, colored ink is contained in the foamed resin layer 9. This makes it possible to provide a resin-impregnated decorative paper 2 and a resin-impregnated decorative board 1 that are suppressed from whitening the foamed resin layer 9 and have improved design properties. Furthermore, in the decorative paper 4 according to an embodiment of the present invention, the pattern formed by the picture pattern layer 7 is in harmony with the position of the foamed resin layer 9, so that a resin-impregnated decorative board 1 can be formed in which the pattern formed by the picture pattern layer 7 and the uneven pattern 10 on the surface of the resin-impregnated decorative board 1 are in harmony in design. Furthermore, the resin-impregnated decorative board 1 according to the embodiment of the present invention includes a resin-impregnated decorative paper 2 and a base material 3 integrated with the resin-impregnated decorative paper 2. Therefore, it is possible to provide a resin-impregnated decorative board 1 that has an excellent gloss matte appearance and a good feel while keeping costs down. EXAMPLES

[0035] Examples and comparative examples of the resin-impregnated decorative board 1 according to the present invention will be described below. Note that the present invention is not limited to the following examples. Example 1 First, titanium paper for decorative paper with good water absorption was prepared as the base paper 6. Next, a wood grain pattern was printed on the surface 6a of the base paper 6 with a water-based ink mainly composed of casein to form a picture pattern layer 7 with a layer thickness of 10 μm. The printing method used was gravure printing. Next, a vascular pattern that was in harmony with the wood grain pattern of the picture pattern layer 7 was printed in-line on the surface 7a of the picture pattern layer 7 with a water-based ink mainly composed of epoxy containing a foaming agent to provide a filling layer 8 in the shape of a vascular pattern. The printing method used was gravure printing, and an epoxy-based resin was used for the filling layer 8. The thickness of the filling layer 8 was 3 μm, and the area in which the filling layer 8 was provided was 100% of the surface area of ​​the foamed resin layer 9, that is, the area of ​​the picture formed by the picture pattern layer 7. There were multiple foamed resin layers 9, and in all of them, the filling layer 8 was provided in a range of 100% of the surface area.

[0036] Next, a foamed resin layer 9 was printed on the surface 8a of the sealing layer 8 to form the decorative paper 4. The printing method used was a direct gravure printing method. The foamed resin layer 9 had an average particle size of 100 μm (10 times the layer thickness of the picture pattern layer 7) before foaming, an average particle size of 120 μm after foaming, and a foaming start temperature of 180° C. Next, the decorative paper 4 was impregnated with the impregnating resin 5, and then dried in an oven to form the resin-impregnated decorative paper 2. As the impregnating resin 5, an aqueous melamine-based resin liquid was used. Next, the resin-impregnated decorative paper 2 was placed on the substrate 3. As the substrate 3, a particle board substrate was used. Next, a heat press was performed at about 160° C. on the surface of the resin-impregnated decorative paper 2 on which the foamed resin layer 9 was formed, and the laminate of the resin-impregnated decorative paper 2 and the substrate 3 was heated and pressurized to form the resin-impregnated decorative board 1 of Example 1 by integrating the resin-impregnated decorative paper 2 and the substrate 3. A flat plate was used for the heat pressing. In the resin-impregnated decorative board 1, the area of ​​the picture pattern layer 7 that does not have the foamed resin layer 9 has a gloss finish, and the area that has the foamed resin layer 9 has a matte finish.

[0037] Example 2 In Example 2, a casein-based resin was used as the filling layer 8. A resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1 except for the above. Example 3 In Example 3, an acrylic resin was used as the filling layer 8. Other than that, a resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1. Example 4 In Example 4, a urethane-based resin was used as the filling layer 8. Apart from that, a resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1.

[0038] Example 5 In Example 5, the thickness of the filling layer 8 was set to 0.5 μm. Except for that, the resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1. Example 6 In Example 6, the thickness of the filling layer 8 was set to 1 μm. Otherwise, a resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1. Example 7 In Example 7, the thickness of the filling layer 8 was set to 5 μm. Otherwise, a resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1.

[0039] Example 8 In Example 8, the thickness of the filling layer 8 was set to 7 μm. Otherwise, a resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1. Example 9 In Example 9, the thickness of the filling layer 8 was set to 10 μm. Otherwise, a resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1. Example 10 In Example 10, the thickness of the filling layer 8 was set to 15 μm. Otherwise, a resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1.

[0040] Example 11 In Example 11, the area of ​​the filling layer 8 was increased by 10% to 110% of the surface area of ​​the foamed resin layer 9, i.e., the area of ​​the pattern formed by the picture pattern layer 7. A resin-impregnated decorative board 1 was otherwise produced using the same materials and procedures as in Example 1. Example 12 In Example 12, the area of ​​the filling layer 8 was increased by 30% to 130% of the surface area of ​​the foamed resin layer 9, i.e., the area of ​​the pattern formed by the picture pattern layer 7. A resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1 except for the above. (Example 13) In Example 13, the area of ​​the filling layer 8 was increased by 50% to 150% of the surface area of ​​the foamed resin layer 9, i.e., the area of ​​the pattern formed by the picture pattern layer 7. A resin-impregnated decorative board 1 was otherwise produced using the same materials and procedures as in Example 1.

[0041] Example 14 In Example 14, a colored ink was added to the foamed resin layer 9. Apart from that, a resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1. Comparative Example 1 In Comparative Example 1, the filling layer 8 was omitted. A resin-impregnated decorative board 1 was produced using the same materials and procedures as in Example 1 except for the above.

[0042] (Performance evaluation) The resin-impregnated decorative boards 1 of Examples 1 to 14 and Comparative Example 1 were subjected to the performance evaluation shown below. (Cross-cut test) In the cross-cut test, a cutter is used to make cross-cuts in the resin-impregnated decorative board 1, and it is evaluated whether peeling occurs or not. When no significant peeling occurs during the cross-cut, it is marked as "○", and when significant peeling occurs, it is marked as "×". (Contamination test) In the staining test, the resin-impregnated decorative board 1 was covered with black crayon and red ink, and after one hour it was wiped off with alcohol and the degree of remaining ink was evaluated. A rating of "○" was given when the degree of remaining ink was less than 30%, "△" when the degree of remaining ink was 30% or more but less than 70%, and "×" when the degree of remaining ink was 70% or more.

[0043] (Tactile evaluation) The tactile evaluation was carried out as a sensory test by 10 examiners. If 7-10 people rated it as good, it was marked as "○", if 1-6 people rated it as good, it was marked as "△", and if 0 people rated it as good, it was marked as "×". (Design Evaluation) The design evaluation was conducted as a sensory test by 10 examiners. If 7-10 people rated it as good, it was marked as "○", if 1-6 people rated it as good, it was marked as "△", and if 0 people rated it as good, it was marked as "×".

[0044] (Long-term environmental testing) In the long-term environmental test, the resin-impregnated decorative board 1 was left in an environment with a temperature of 40°C and humidity of 90% for two months, after which a sensory test on the change in design was conducted by 10 testers. If 7 to 10 people rated it as good, it was marked as "○", if 1 to 6 people rated it as good, it was marked as "△", and if 0 people rated it as good, it was marked as "×". (Overall Judgment) The products were evaluated comprehensively based on the five items mentioned above: cross-cut test, stain test, tactile evaluation, design evaluation, and long-term environmental test. Products that were particularly excellent were marked with a "◎", those that were excellent were marked with a "○", those with few problems were marked with a "△", and those with problems were marked with an "×".

[0045] (Evaluation Results) The evaluation results are shown in Table 1.

[0046] [Table 1]

[0047] As shown in Table 1, in the cross-cut test, no peeling was observed in any of Examples 1 to 14 and Comparative Example 1, and there was no problem with adhesion. However, compared with Comparative Example 1 in which the filling layer 8 was omitted, Examples 1 to 14 in which the filling layer 8 was provided had improved tactile evaluation and design evaluation. In particular, as shown by the evaluation results of Examples 1 to 4, those in which an epoxy resin, an acrylic resin, a urethane resin, or a casein resin was used as the filling layer 8 were excellent in tactile evaluation and design evaluation, or had almost no problems. Also, as shown by the evaluation results of Examples 5 to 10, the thicker the filling layer 8 was, the lower the design tended to be. Also, as shown by the evaluation results of Examples 11 to 13, the larger the application area of ​​the filling layer 8 was, the lower the design tended to be. On the other hand, if the filling layer 8 is too thin (less than 0.5 μm), the foamed resin will seep in, resulting in a decrease in the touch feeling and gloss matte feeling, and also in a decrease in design. Furthermore, as shown by the evaluation results of Example 14, the freedom of design expression was improved by adding colored ink to the foamed resin layer 9, and the design was improved. In terms of overall judgment, the resin-impregnated decorative boards 1 of Examples 1, 6, 7, and 14 were particularly excellent. In Examples 5 to 14, an epoxy resin was used as the filling layer 8, but even if a casein resin, an acrylic resin, a urethane resin, or the like was used instead of the epoxy resin, there was no significant difference in the basic physical properties and approximately equivalent results were obtained.

[0048] Although the above description has been given with reference to a limited number of embodiments, the scope of the invention is not limited thereto, and modifications of the embodiments based on the above disclosure will be obvious to those skilled in the art. [Explanation of symbols]

[0049] 1...resin-impregnated decorative board, 2...resin-impregnated decorative paper, 3...base material, 3a...surface, 4...decorative paper, 5...impregnated resin, 6...base paper, 6a...surface, 7...picture pattern layer, 7a...surface, 8...filling layer, 8a...surface, 9...foamed resin layer, 10...uneven pattern

Claims

1. A resin-impregnated decorative paper in which a decorative paper is impregnated with an impregnating resin, The decorative paper is The original paper and A picture pattern layer provided on the surface side of the base paper; A filling layer provided on the surface of the picture pattern layer; A foamed resin layer formed by a foaming agent provided on a surface of the filling layer, The filling layer contains at least one of an epoxy resin, an acrylic resin, a urethane resin, and a casein resin, The filling layer has a thickness of 0.5 μm or more and 15 μm or less, The resin-impregnated decorative paper is characterized in that the foaming agent has an average particle size after foaming of 15 μm or more and 250 μm or less.

2. 2. The resin-impregnated decorative paper according to claim 1, wherein the filling layer has a thickness of 1 μm or more and 10 μm or less.

3. 3. The resin-impregnated decorative paper according to claim 1, wherein the filling layer is provided over an area of ​​100% or more of the surface area of ​​the foamed resin layer.

4. 4. The resin-impregnated decorative paper according to claim 3, wherein the filling layer is provided over an area of ​​150% or less of the surface area of ​​the foamed resin layer.

5. 5. The resin-impregnated decorative paper according to claim 1, wherein the foamed resin layer contains a colored ink.

6. 6. The resin-impregnated decorative paper according to claim 1, wherein the pattern formed by the picture design layer and the position of the foamed resin layer are in harmony with each other.

7. The resin-impregnated decorative paper according to any one of claims 1 to 6, A resin-impregnated decorative board comprising a substrate integrated with the resin-impregnated decorative paper.

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