Fluidized bed reactor and method for recovering active metals from lithium secondary batteries using the same

Abstract

A method for recovering active metals from lithium secondary batteries according to an embodiment of the present invention includes the steps of preparing a waste cathode active material mixture obtained from waste cathodes of lithium secondary batteries; reacting the waste cathode active material mixture with a reactant gas in a fluidized bed reactor to form a pre-precursor mixture; and selectively recovering a lithium precursor from the pre-precursor mixture, wherein the fluidized bed reactor includes a reactor body and a horizontal expansion tube, and the ratio of the diameter of the horizontal expansion tube to the diameter of the reactor body is 3 or greater, thereby improving the recovery efficiency of lithium secondary batteries.

Description

[Technical field]

[0001] The present invention relates to a method for recovering active metals from lithium secondary batteries, and more particularly to a method for recovering active metals from lithium secondary batteries using a fluidized bed reactor. [Background technology]

[0002] In recent years, secondary batteries have been widely applied and developed as power sources for portable electronic communication devices such as camcorders, mobile phones, and notebook computers, and for vehicles such as hybrid cars, electric cars, etc. As secondary batteries, lithium secondary batteries have been actively developed and applied because of their high operating voltage and energy density per unit weight, as well as their advantages in terms of charging speed and weight reduction.

[0003] The positive electrode active material of the lithium secondary battery may be a lithium metal oxide, which may further contain a transition metal such as nickel, cobalt, or manganese.

[0004] Since the positive electrode active material contains the above-mentioned expensive valuable metals, the production of the positive electrode material accounts for more than 20% of the production cost. In addition, in recent years, with the increasing interest in environmental protection, research into recycling methods for the positive electrode active material has been progressing.

[0005] Conventionally, a method has been used in which waste cathode active material is leached in a strong acid such as sulfuric acid to recover valuable metals, but the wet process is disadvantageous in terms of regeneration selectivity, regeneration time, etc., and can cause environmental pollution. Therefore, a method of recovering valuable metals using a dry-based reaction by contact with a reactive gas is being researched.

[0006] However, the size of the active material particles supplied for the dry reaction becomes smaller, which may cause non-uniform reaction due to aggregation, and the recovery rate of the active material may decrease due to local non-uniform supply of the reaction gas in the reactor.

[0007] For example, Korean Patent No. 10-0709268 discloses an apparatus and method for recycling waste manganese batteries and alkaline batteries, but does not provide a dry-based method for recovering valuable metals with high selectivity and high yield. Summary of the Invention [Problem to be solved by the invention]

[0008] An object of the present invention is to provide a method for recovering active metals from lithium secondary batteries with excellent recovery efficiency. [Means for solving the problem]

[0009] In a method for recovering active metals from a lithium secondary battery according to an embodiment of the present invention, a mixture of waste positive electrode active materials obtained from waste positive electrodes of lithium secondary batteries is prepared. The mixture of waste positive electrode active materials is reacted with a reaction gas in a fluidized bed reactor to form a preliminary precursor mixture. A lithium precursor is selectively recovered from the preliminary precursor mixture. In this case, the fluidized bed reactor may include a reactor body and a horizontal expansion bed, and a ratio of a diameter of the horizontal expansion bed to a diameter of the reactor body may be 3 or more.

[0010] In some embodiments, forming the pre-precursor mixture may include causing the waste cathode active material mixture or the pre-precursor mixture, which has risen from the reactor body to the horizontally expanding bed, to descend by the reactant gas and be collected in the reactor body.

[0011] In some embodiments, the ratio of the diameter of the horizontally expanding bed to the diameter of the reactor body may be 3-10.

[0012] In some embodiments, the fluidized bed reactor may further include a vertical expansion pipe connecting the reactor body and the horizontal expansion bed.

[0013] In some embodiments, the inclination angle of the vertical extension tube may be 45 to 80 degrees.

[0014] In some embodiments, the reactant gas may include hydrogen.

[0015] In some embodiments, the pre-precursor mixture can be washed with water to recover the lithium precursor.

[0016] A fluidized bed reactor according to an embodiment of the present invention may include a reactor body, a horizontal expansion bed communicating with the reactor body and having a diameter three or more times that of the reactor body, a vertical expansion pipe connecting the reactor body and the horizontal expansion bed, and a gas injection channel for injecting a reaction gas into the reactor body. Effect of the Invention

[0017] In the method for recovering active metals of a lithium secondary battery according to an exemplary embodiment, a fluidized bed reactor is used in which the ratio of the diameter of the horizontal expansion bed to the diameter of the reactor body is 3 or more, thereby preventing the pre-precursor mixture from leaking out or accumulating on the wall during the formation of the pre-precursor mixture. The injection rate of the reaction gas injected into the fluidized bed reactor can be increased to more easily form a fluidized bed, thereby improving the recovery efficiency of the lithium precursor.

[0018] In the method for recovering active metals of a lithium secondary battery according to an exemplary embodiment, a fluidized bed reactor including a vertical expansion tube having a specific inclination angle is used, thereby reducing the amount of a pre-precursor mixture flowing out to the outside, and the pre-precursor mixture is again introduced into the reactor body along the inclined surface of the vertical expansion tube, thereby improving the recovery efficiency of the lithium precursor. [Brief description of the drawings]

[0019] [Figure 1] FIG. 1 is a schematic diagram illustrating a fluidized bed reactor and a method for recovering active metals of a lithium secondary battery using the fluidized bed reactor according to an exemplary embodiment. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0020] An embodiment of the present invention provides a method for recovering active metals with high purity and high yield utilizing a fluidized bed reactor having a ratio of the diameter of the horizontally expanded bed to the diameter of the reactor body of 3 or more.

[0021] Hereinafter, embodiments of the present invention will be described in more detail with reference to the drawings. However, these embodiments are merely illustrative of the present invention and are not intended to limit the present invention.

[0022] As used herein, the term "precursor" is used to refer collectively to a compound containing a specific metal to provide the specific metal contained in the electrode active material.

[0023] As shown in FIG. 1, a waste positive electrode active material mixture can be prepared from a waste positive electrode of a lithium secondary battery (eg, step S10).

[0024] The lithium secondary battery may include an electrode assembly including a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode, and the positive electrode and the negative electrode may include a positive electrode active material layer and a negative electrode active material layer coated on a positive electrode current collector and a negative electrode current collector, respectively.

[0025] For example, the positive electrode active material included in the positive electrode active material layer may include an oxide containing lithium and a transition metal.

[0026] In some embodiments, the positive electrode active material may include a compound represented by Formula 1:

[0027] [Chemical formula 1] Li x M1 a M2 b M3 c O y

[0028] In Chemical Formula 1, M1, M2, and M3 may be a transition metal selected from Ni, Co, Mn, Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga, or B. <x≦1.1、2≦y≦2.02、0<a<1、0<b<1、0<c<1、0<a+b+c≦1であってもよい。

[0029] In some embodiments, the active cathode material may be an NCM-based lithium oxide containing nickel, cobalt, and manganese.

[0030] The positive electrode can be separated from the used lithium secondary battery to recover the used positive electrode. The used positive electrode includes a positive electrode current collector (e.g., aluminum (Al)) and a positive electrode active material layer as described above, and the positive electrode active material layer can include a conductive material and a binder in addition to the positive electrode active material.

[0031] The conductive material may include, for example, a carbon-based material such as graphite, carbon black, graphene, carbon nanotubes, etc. The binder may include, for example, a resin material such as vinylidene fluoride-hexafluoropropylene copolymer (PVDF-co-HFP), polyvinylidene fluoride (PVDF), polyacrylonitrile, polymethylmethacrylate, etc.

[0032] According to an exemplary embodiment, the recovered waste cathodes may be pulverized to generate a waste cathode active material mixture. Thus, the waste cathode active material mixture may be manufactured in a powder form. The waste cathode active material mixture may include a lithium-transition metal oxide powder as described above, for example, an NCM-based lithium oxide powder (e.g., Li(NCM)O 2 ).

[0033] The term "waste cathode active material mixture" as used herein may refer to a raw material input to a fluidized bed reaction process described below after the cathode current collector is substantially removed from the waste cathode. In one embodiment, the waste cathode active material mixture may include cathode active material particles such as the NCM-based lithium oxide. In one embodiment, the waste cathode active material mixture may also include a component derived from the binder or the conductive material. In one embodiment, the waste cathode active material mixture may be substantially composed of the cathode active material particles.

[0034] In some embodiments, the average particle size (D50) of the waste positive electrode active material mixture may be 5 to 100 μm. Within this range, the Li(NCM)O to be recovered is extracted from the positive electrode current collector, conductive material, and binder contained in the waste positive electrode active material mixture. 2 The lithium-transition metal oxides such as

[0035] In some embodiments, the waste cathode active material mixture may be heat-treated before being introduced into a fluidized bed reactor described below. The heat treatment may remove or reduce impurities, such as the conductive material and binder, contained in the waste cathode active material mixture, and the lithium-transition metal oxide may be introduced into the fluidized bed reactor with high purity.

[0036] The heat treatment temperature may be, for example, about 100 to 500° C., preferably about 350 to 450° C. Within this range, the impurities are substantially removed, and decomposition and damage of the lithium-transition metal oxide can be prevented.

[0037] For example, in step S20, the waste cathode active material mixture may be reacted with a reaction gas in a fluidized bed reactor 100 to form a pre-precursor mixture 80.

[0038] 1, the fluidized bed reactor 100 can be divided into a reactor body 110, a reactor lower portion 120, and a horizontal expansion bed 130. The reactor body 110 can include a heating means such as a heater or can be integrated with a heating means.

[0039] The reactor lower portion 120 can be defined as the lower portion of the distribution plate 50 in the reactor body 110 .

[0040] The waste cathode active material mixture may be supplied into the reactor body 110 through the supply passage 108a. The waste cathode active material mixture may be dropped through the supply passage 108a connected to the top of the reactor body 110. The waste cathode active material mixture may also be introduced through a supply passage (not shown) connected to the bottom of the reactor body 110.

[0041] A reactant gas for converting the waste cathode active material mixture into a pre-precursor may be supplied into the reactor body 110 through a gas passage 104 connected to the reactor lower portion 120. According to an exemplary embodiment, the reactant gas includes a reducing gas, for example, hydrogen (H 2 ) can be supplied.

[0042] The reaction gas may be injected into the reactor body 110 through the injection column 60 included in the dispersion plate. The reaction gas is supplied from the lower part of the fluidized bed reactor 100 and contacts the waste cathode active material mixture, so that the waste cathode active material mixture moves to the horizontal expansion bed 130 and reacts with the reaction gas to be converted into a pre-precursor mixture 80.

[0043] For example, the ratio of the diameter of the horizontal expansion bed 130 to the diameter of the reactor body 110 may be 3 or more. Preferably, the diameter ratio may be 3-10, more preferably 3-5.

[0044] The diameter can be measured based on the central axis of the fluidized bed reactor 100 and the inner wall of the fluidized bed reactor 100. In this case, the flow rate of the pre-precursor mixture 80 or the reaction gas moving from the reactor body 110 to the horizontal expansion bed 130 can be rapidly reduced. As a result, the moving speed of the pre-precursor mixture 80 reaches the terminal velocity (u t) and can effectively reduce the amount of the pre-precursor mixture 80 flowing out of the reactor body 110.

[0045] For example, the ratio of the diameter of the horizontal expansion bed 130 to the diameter of the reactor body 110 may be 3 to 10. For example, if the diameter ratio is less than 3, the diameter of the horizontal expansion bed 130 of the fluidized bed reactor 100 is not sufficiently expanded, making it difficult to expect a sufficient deceleration effect, and if it exceeds 10, the size of the horizontal expansion bed 130 of the fluidized bed reactor 100 becomes too large, which may reduce the overall process efficiency.

[0046] For example, the fluidized bed reactor 100 may further include a vertical expansion pipe 140 connecting the reactor body 110 and the horizontal expansion bed 130. The vertical expansion pipe 140 may refer to a region whose diameter gradually increases with a certain inclination angle (a) as the diameter of the horizontal expansion bed 130 becomes larger than the diameter of the reactor body 110. For example, the inclination angle (a) may be defined as the angle between the vertical extension line of the side of the reactor body 110 and the inclined surface of the vertical expansion pipe 140.

[0047] For example, the inclination angle (a) of the vertical extension pipe 140 may be about 45 to 80°. More preferably, the inclination angle (a) of the vertical extension pipe 140 may be about 60 to 80°. For example, when the inclination angle (a) satisfies the above range, an effective deceleration effect of the preliminary precursor mixture 80 can be expected within a range in which the area of ​​the horizontal expansion bed 130 included in the fluidized bed reactor 100 is not unnecessarily increased.

[0048] In addition, the pre-precursor mixture 80 descending at a reduced speed re-flows into the reactor body 110 along the inclined surface of the vertical expansion tube 140, thereby further improving the recovery efficiency of the lithium precursor.

[0049] In some exemplary embodiments, the fluidized bed reactor 100 may include gas injection passages 104 for injecting reactant gases into the reactor body 110 .

[0050] The reaction gas can be injected into the reactor body 110 by passing through the gas injection passage 104, the base plate 50 and the injection column 60 in sequence.

[0051] In some embodiments, the lithium-transition metal oxide is reduced by the hydrogen gas to, for example, lithium hydroxide (LiOH), lithium oxide (e.g., LiO 2 ), and a transition metal or transition metal oxide. For example, Ni, Co, NiO, CoO, and MnO can be produced by reduction reactions along with the reserve lithium precursor.

[0052] The reduction reaction in the reactor main body 110 can be carried out at about 400 to 700° C., preferably 450 to 550° C. Within this reaction temperature range, the reduction reaction can be promoted without inviting re-aggregation or recombination of the spare lithium precursor and the transition metal / transition metal oxide.

[0053] In some embodiments, a carrier gas can be supplied together with the reaction gas from the lower reactor portion 120. For example, the carrier gas can be supplied together with the reaction gas through the gas passage 104. For example, the carrier gas can be nitrogen (N 2 The carrier gas may include an inert gas such as nitrogen (N) or argon (Ar). The carrier gas may also be injected through the injection column 60 of the dispersion plate to promote the formation of a fluidized bed. For example, the carrier gas may promote the formation of a cyclone.

[0054] A preliminary precursor mixture 80 can be formed within the reactor body 110, including a preliminary lithium precursor and a preliminary transition metal precursor (e.g., the transition metal or transition metal oxide). The preliminary lithium precursor can include, for example, lithium hydroxide, lithium oxide, and / or lithium carbonate.

[0055] For example, the pre-precursor mixture 80 may be cooled, in which case the pre-precursor mixture 80 may be cooled using a refrigerant in a gaseous state or a refrigerant in a liquid state.

[0056] For example, the pre-precursor mixture 80 can be cooled to about 100° C. or less. More preferably, the pre-precursor mixture 80 can be cooled to about 50 to 100° C. For example, when the pre-precursor mixture 80 is cooled within the above temperature range, the recovery efficiency of the lithium precursor during the recovery of the lithium precursor, which will be described later, can be improved.

[0057] The lithium precursor can be selectively recovered from the cooled pre-precursor mixture 80 (eg, step S30).

[0058] In some embodiments, the cooled pre-precursor mixture 80 can be washed with water to recover the pre-lithium precursor. The pre-lithium precursor particles in the form of lithium hydroxide (LiOH) can be substantially dissolved in water and preferentially recovered separately from the transition metal precursor. A lithium precursor substantially composed of lithium hydroxide can be obtained, such as by a crystallization process of the lithium hydroxide dissolved in water.

[0059] In one embodiment, the reserve lithium precursor particles in the form of lithium oxide and lithium carbonate may be substantially removed by said water washing process, hi one embodiment, the reserve lithium precursor particles in the form of lithium oxide and lithium carbonate may be at least partially converted to lithium hydroxide by said water washing process.

[0060] In some embodiments, the reserve lithium precursor is a mixture of carbon monoxide (CO), carbon dioxide (CO 2 ) as a lithium precursor to produce lithium carbonate (e.g., Li 2 CO 3) can be obtained. By reacting with the carbon-containing gas, a crystallized lithium precursor can be obtained. For example, a carbon-containing gas can be co-injected during the water washing process and lithium carbonate can be collected.

[0061] In some embodiments, the transition metal precursor can be obtained from the collected preliminary transition metal precursor (eg, step S40).

[0062] For example, the preliminary lithium precursor can be collected via outlet 108b, and then the preliminary transition metal precursor can be recovered. The preliminary transition metal precursor can then be treated with an acid solution to form a precursor of each transition metal in the form of an acid salt.

[0063] In one embodiment, sulfuric acid can be used as the acid solution. In this case, NiSO can be used as the transition metal precursor. 4 , MnSO 4 , and CoSO 4 can be collected respectively.

[0064] As described above, after the lithium precursor is collected by the dry process, the transition metal precursor is selectively extracted using an acid solution, thereby improving the purity and selectivity of each metal precursor, reducing the rods of the wet process, and reducing the increase in wastewater and by-products.

[0065] In the following, preferred examples are presented to aid in understanding the present invention, but these examples are merely illustrative of the present invention and do not limit the scope of the appended claims. It is clear to those skilled in the art that various changes and modifications can be made to these examples within the scope of the scope and technical ideas of the present invention, and it is natural that these changes and modifications fall within the scope of the appended claims.

[0066] Example 1 100 kg of the positive electrode material separated from the waste lithium secondary battery was heat-treated at 450° C. for 1 hour. The heat-treated positive electrode material was cut into small units and pulverized by milling to obtain Li-Ni-Co-Mn oxide positive electrode active material samples.

[0067] 10 kg of the positive active material sample was loaded into a fluidized bed reactor having a ratio of the diameter of the horizontal expansion bed to the diameter of the reactor body of 4, and nitrogen gas was injected from the bottom of the reactor at a flow rate of 100 L / min. The temperature inside the reactor was maintained at 450°C.

[0068] The amount of the positive electrode active material that flowed out of the reactor was measured, and the amount flowed out per hour was calculated. The results are shown in Table 1 below.

[0069] Examples 2 to 3 and Comparative Example 1 The amount of the positive electrode active material that flowed out of the reactor was measured in the same manner as in Example 1, except that the ratio of the diameter of the horizontal expansion bed to the diameter of the reactor body was adjusted as shown in Table 1 below, and the outflow amount per hour was calculated and shown.

[0070] [Table 1]

[0071] As shown in Table 1, when the ratio of the diameter of the horizontal expansion bed to the diameter of the reactor body was 3 or more, the amount of the positive electrode active material flowing out of the reactor was reduced. [Explanation of symbols]

[0072] 50: Base plate 60: Jet column 80: Pre-precursor mixture 100: Fluidized bed reactor 104: Gas flow path 110: Reactor body 120: Lower part of reactor 130: Horizontal expansion bed 140: Vertical expansion tube a: Inclination angle

Claims

1. Preparing a waste positive electrode active material mixture obtained from a waste positive electrode of a lithium secondary battery; reacting the waste cathode active material mixture with a reactant gas in a fluidized bed reactor to form a pre-precursor mixture; and selectively recovering a lithium precursor from the preliminary precursor mixture. the fluidized bed reactor comprises a reactor body, a vertical expansion tube connected to an upper portion of the reactor body, and a horizontal expansion bed communicating with the upper portion via the vertical expansion tube, and a ratio of a diameter of the horizontal expansion bed to a diameter of the reactor body is 3 or more.

2. 2. The method for recovering active metals of lithium secondary batteries according to claim 1, wherein the step of forming the preliminary precursor mixture further comprises the step of descending the waste cathode active material mixture or the preliminary precursor mixture, which has risen from the reactor body to the horizontally expanding bed by the reaction gas, and collecting it in the reactor body.

3. 2. The method for recovering active metals from lithium secondary batteries according to claim 1, wherein the ratio of the diameter of the horizontally expanded bed to the diameter of the reactor body is 3-10.

4. 2. The method for recovering active metals from lithium secondary batteries according to claim 1, wherein the inclination angle of the vertical expansion tube is 45 to 80 degrees.

5. The method for recovering active metals from a lithium secondary battery according to claim 1 , wherein the reaction gas contains hydrogen.

6. 2. The method for recovering active metals of a lithium secondary battery according to claim 1, wherein the step of recovering the lithium precursor comprises a step of washing the preliminary precursor mixture with water.

7. A reactor body; a horizontal expansion bed communicating with the reactor body and having a diameter three times or more the diameter of the reactor body; a vertical expansion pipe connecting the reactor body and the horizontal expansion bed; a gas injection passage for injecting a reaction gas into the reactor body; The vertical expansion pipe is connected to the upper part of the reactor body, The horizontal expansion bed communicates with the vertical expansion pipe above the upper portion, The inclination angle of the vertical expansion pipe is 45 to 80 degrees.

Images