Polymer compositions having excellent electrical and mechanical properties

Abstract

1. A composition comprising: a) a first ethylene / alpha-olefin / non-conjugated polyene interpolymer having a Mooney viscosity of ≧50; b) a second ethylene / alpha-olefin / non-conjugated polyene interpolymer having a Mooney viscosity of <50; and c) a calcined filler formed from a filler composition comprising kaolinite.

Description

[Background technology]

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS This application claims the benefit of priority to U.S. Patent Application No. 62 / 904,940, filed September 24, 2019, which is incorporated by reference in its entirety.

[0002] Stricter carbon emission regulations are driving automakers to reduce vehicle weight wherever possible. For example, in Europe, the emission target is set to "125g CO2 per kilometre" by 2020. 2 " to "95g CO per km 2 " in modern vehicles, to achieve significant weight reduction, steel door panels are being replaced by aluminum / magnesium (Al / Mg) alloys. However, the change from steel to Al / Mg alloys (or Al and Mg alone) has a significant impact on, for example, the rubber sealing profiles used to seal door and window panels to other surface components. Such profiles include those made of conventional profiles (approximately 10 6 Much higher electrical resistivity (≥10 Ω cm) compared to 8 Ω·cm) is required.

[0003] Conventional profiles formed from EPDM-based elastomer compositions have a high carbon black loading, which tends to condense to form conductive 3D networks in the final rubber formulation. Therefore, the amount of carbon black needs to be reduced to reduce the rubber's conductivity. Insulating white fillers can be used to replace some of the carbon black. However, the use of white fillers can adversely affect the rubber's mechanical properties, such as compression set and elasticity, and can increase porosity in the extruded profile. Increasing the white filler content and decreasing the carbon black content also affect the curing properties in a similar manner. There is a need for an elastomer composition that provides high volume resistivity and excellent mechanical properties, and can form extruded profiles with good integrity and minimal or no porosity.

[0004] V. Krmelova et al., Evaluation of Effect of White Fillers on Selected Properties of EPDM Blend, Procedia Engineering, 136 (2016), 336-340, discloses EPDM compositions containing various white fillers. These blends have relatively low volume resistivities (≦3.48×10 7 Ω·cm, see Table 4), which is in line with the currently required “≥ 10 8 The electrical resistance of the EPDM rubber is too low to meet the electrical resistance requirement of 1.0 Ω·cm. U.S. Patent No. 9,994,095 discloses weather stripping for automobiles. The weather stripping design uses non-conductive materials that help prevent the formation of electrical circuits caused by snow or water ingress (see Abstract). The patent generally discloses the use of rubber materials such as EPDM sponge or EPDM solid rubber materials. Carbon black can be used to adjust the electrical resistance of the EPDM rubber (see col. 6, lines 28-41).

[0005] The POLESTAR 200R Product Guide (The Application of Mineral Science, POLESTAR 200R in Rubber, 2017) discloses a cable formulation that contains, in part, VISTALON 4608 and POLESTAR 200R. The formulation has a relatively high volume resistivity (1.3×10 14 Ω·cm), but relatively low elongation at break (240%). See also POLESTAR 200R Product Guide (The Application of Mineral Science,Calcined Clay in EPDM Rubber,2018). H. Oggermuller, Gummi Fasern Kunststoffe,56,1,2003,31-37 (Abstract in English) discloses EPDM formulations containing reduced levels of carbon black and various inorganic fillers selected from silica, calcium carbonate, talc, and kaolin. This reference discloses that only the silica-reinforced EPDM formulations showed good extrusion properties as well as sufficient mechanical and electrical properties.

[0006] As discussed above, there remains a need for elastomeric compositions for automotive parts that provide high volume resistivity and excellent mechanical properties such as elongation and compression set, and provide good processability and cure characteristics. Such compositions should form good extruded profiles with minimal or no porosity. These needs are met by the following inventions. Summary of the Invention

[0007] 1. A composition comprising: a) a first ethylene / alpha-olefin / non-conjugated polyene interpolymer having a Mooney viscosity of ≧50; b) a second ethylene / alpha-olefin / non-conjugated polyene interpolymer having a Mooney viscosity of <50; and c) a calcined filler formed from a filler composition comprising kaolinite. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0008] Elastomeric compositions have been discovered that have excellent volume resistivity, excellent elongation, and compression set, as well as good rheological and curing properties. These compositions can be used to form extruded profiles with minimal or no porosity. As discussed above, the compositions include: a) a first ethylene / alpha-olefin / non-conjugated polyene interpolymer having a Mooney viscosity of ≧50; b) a second ethylene / alpha-olefin / non-conjugated polyene interpolymer having a Mooney viscosity of <50; and c) a calcined filler formed from a filler composition comprising kaolinite.

[0009] In one embodiment, or in a combination of two or more embodiments, each described herein: The filler composition further comprises silica.

[0010] In one embodiment, or a combination of two or more embodiments, each described herein, the fired filler is surface treated with a composition comprising a mercaptosilane, an alkylsilane, a vinylsilane, an epoxy, or an aminosilane.

[0011] In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of the sintered filler to the composition is ≧0.10, or ≧0.15, or ≧0.20, or ≧0.25. In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of the sintered filler to the composition is ≦0.50, or ≦0.45, or ≦0.40, or ≦0.35, or ≦0.30.

[0012] In one embodiment, or a combination of two or more embodiments, each of which is described herein, the weight ratio of the sintered filler to the sum of the first and second interpolymers is ≧0.80, or ≧0.85, or ≧0.90, or ≧0.95, or ≧1.00, or ≧1.05. In one embodiment, or a combination of two or more embodiments, each of which is described herein, the weight ratio of the sintered filler to the sum of the first and second interpolymers is ≦1.35, or ≦1.30, or ≦1.25, or ≦1.20, or ≦1.15, or ≦1.10.

[0013] In one embodiment, or a combination of two or more embodiments, each described herein, the composition further comprises carbon black. In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of carbon black to the composition is ≧0.05, or ≧0.10, or ≧0.15, or ≧0.20. In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of carbon black to the composition is ≦0.50, or ≦0.45, or ≦0.40, or ≦0.35, or ≦0.30, or ≦0.25.

[0014] In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of carbon black to the sum of the first and second interpolymers is ≧0.40, or ≧0.45, or ≧0.50, or ≧0.55, or ≧0.60, or ≧0.65, or ≧0.70, or ≧0.75. In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of carbon black to the sum of the first and second interpolymers is ≦1.10, or ≦1.05, or ≦1.00, or ≦0.95, or ≦0.90, or ≦0.85, or ≦0.80.

[0015] In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of carbon black to calcined filler is ≧0.40, or ≧0.45, or ≧0.50, or ≧0.55, or ≧0.60, or ≧0.65. In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of carbon black to calcined filler is ≦1.00, or ≦0.95, or ≦0.90, or ≦0.85, or ≦0.80, or ≦0.75, or ≦0.70.

[0016] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a Mooney viscosity (ML(1+4), 100° C.) of ≧20, or ≧25, or ≧30, or ≧35, or ≧40. In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a Mooney viscosity (ML(1+4), 100° C.) of ≦80, or ≦75, or ≦70, or ≦65, or ≦60, or ≦55, or ≦50.

[0017] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a Rheology Ratio (RR) of ≧40, or ≧45, or ≧50, or ≧55, or ≧60. In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a Rheology Ratio (RR) of ≦95, or ≦90, or ≦85, or ≦80, or ≦75.

[0018] In one embodiment, or a combination of two or more embodiments, each of which is described herein, the first interpolymer is a first EPDM. In one embodiment, or a combination of two or more embodiments, each of which is described herein, the non-conjugated polyene of the first interpolymer is ENB. In a further embodiment, the ENB content of the first interpolymer is ≧5.5 wt%, or ≧6.0 wt%, or ≧6.5 wt%, or ≧7.0 wt%. In one embodiment, or a combination of two or more embodiments, each of which is described herein, the ENB content of the first interpolymer is ≦9.5 wt%, or ≦9.0 wt%, or ≦8.5 wt%, or ≦8.0 wt%. Each weight percentage is based on the weight of the first interpolymer. It is understood that the ENB content is in polymerized form.

[0019] In one embodiment, or a combination of two or more embodiments, each of which is described herein, the second interpolymer is a second EPDM. In one embodiment, or a combination of two or more embodiments, each of which is described herein, the non-conjugated polyene of the second interpolymer is ENB. In a further embodiment, the ENB content of the second interpolymer is ≧3.0 wt%, or ≧3.5 wt%, or ≧4.0 wt%. In one embodiment, or a combination of two or more embodiments, each of which is described herein, the ENB content of the second interpolymer is ≦6.5 wt%, or ≦6.0 wt%, or ≦5.5 wt%, or ≦5.0 wt%. Each weight percentage is based on the weight of the second interpolymer. It is understood that the ENB content is in polymerized form.

[0020] In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a Mooney viscosity (ML1+4 @ 125° C.) of ≧52, or ≧54, or ≧56, or ≧58, or ≧60, or ≧62, or ≧64. In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a Mooney viscosity (ML1+4 @ 125° C.) of ≦100, or ≦95, or ≦90, or ≦85, or ≦80, or ≦75, or ≦70.

[0021] In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a Mooney viscosity (ML1+4 @ 125° C.) of ≧5.0, or ≧10, or ≧15, or ≧20, or ≧25. In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a Mooney viscosity (ML1+4 @ 125° C.) of ≦48, or ≦46, or ≦44, or ≦42, or ≦40, or ≦38, or ≦36, or ≦34, or ≦32, or ≦30.

[0022] In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of ≧28, or ≧29, or ≧30. In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of <50, or ≦48, or ≦46, or ≦44, or ≦42, or ≦40, or ≦38, or ≦36, or ≦34, or ≦32.

[0023] In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of 28 to <50, or 29 to <50, or 30 to <50.

[0024] In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of 28 to 45, or 28 to 40, or 28 to 35.

[0025] In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a number average molecular weight Mn of ≥ 50,000 g / mol, or ≥ 55,000 g / mol, or ≥ 60,000 g / mol, or ≥ 65,000 g / mol, or ≥ 70,000 g / mol. In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a number average molecular weight Mn of ≤ 95,000 g / mol, or ≤ 90,000 g / mol, or ≤ 85,000 g / mol, or ≤ 80,000 g / mol, or ≤ 75,000 g / mol.

[0026] In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a number average molecular weight Mn of ≥ 20,000 g / mol, or ≥ 25,000 g / mol, or ≥ 30,000 g / mol, or ≥ 35,000 g / mol. In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a number average molecular weight Mn of ≤ 70,000 g / mol, or ≤ 65,000 g / mol, or ≤ 60,000 g / mol, or ≤ 55,000 g / mol, or ≤ 50,000 g / mol, or ≤ 45,000 g / mol, or ≤ 40,000 g / mol.

[0027] In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a weight average molecular weight Mw of ≥ 180,000 g / mol, or ≥ 190,000 g / mol, or ≥ 200,000 g / mol, or ≥ 210,000 g / mol. In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a weight average molecular weight Mw of ≤ 250,000 g / mol, or ≤ 240,000 g / mol, or ≤ 230,000 g / mol, or ≤ 220,000 g / mol.

[0028] In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a weight average molecular weight Mw of ≥ 70,000 g / mol, or ≥ 80,000 g / mol, or ≥ 90,000 g / mol, or ≥ 100,000 g / mol, or ≥ 110,000 g / mol. In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a weight average molecular weight Mw of ≤ 150,000 g / mol, or ≤ 140,000 g / mol, or ≤ 130,000 g / mol, or ≤ 120,000 g / mol.

[0029] In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a molecular weight distribution MWD of ≥ 2.60, or ≥ 2.65, or ≥ 2.70, or ≥ 2.75, or ≥ 2.80, or ≥ 2.85, or ≥ 2.90. In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a molecular weight distribution MWD of ≤ 3.30, or ≤ 3.25, or ≤ 3.20, or ≤ 3.15, or ≤ 3.10, or ≤ 3.05, or ≤ 3.00.

[0030] In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a molecular weight distribution MWD of ≥ 2.80, or ≥ 2.85, or ≥ 2.90, or ≥ 2.95, or ≥ 3.00, or ≥ 3.05, or ≥ 3.10. In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a molecular weight distribution MWD of ≤ 3.50, or ≤ 3.45, or ≤ 3.40, or ≤ 3.35, or ≤ 3.30, or ≤ 3.25, or ≤ 3.20.

[0031] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a {[Mn] of ≧1.50, or ≧1.55, or ≧1.60, or ≧1.65, or ≧1.70, or ≧1.75, or ≧1.80, or ≧1.85, or ≧1.90. 第1のインターポリマー / [Mn] 第2のインターポリマー In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a {[Mn]} ratio of ≦2.15, or ≦2.10, or ≦2.05, or ≦2.00. 第1のインターポリマー / [Mn] 第2のインターポリマー} ratio.

[0032] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a {[Mw]} of ≧1.60, or ≧1.65, or ≧1.70, or ≧1.75. 第1のインターポリマー / [Mw] 第2のインターポリマー In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a {[Mw]} ratio of ≦1.95, or ≦1.90, or ≦1.85, or ≦1.80. 第1のインターポリマー / [Mw] 第2のインターポリマー} ratio.

[0033] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a {[MWD]} of ≧0.905, or ≧0.910, or ≧0.915, or ≧0.920. 第1のインターポリマー / [MWD] 第2のインターポリマー In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a {[MWD]} ratio of ≦0.945, or ≦0.940, or ≦0.935, or ≦0.930. 第1のインターポリマー / [MWD] 第2のインターポリマー} ratio.

[0034] In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a rheology ratio (RR) of ≧22, or ≧24, or ≧26, or ≧28, or ≧30. In one embodiment, or a combination of two or more embodiments, each described herein, the first interpolymer has a rheology ratio (RR) of ≦46, or ≦44, or ≦42, or ≦40, or ≦38, or ≦36.

[0035] In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a rheology ratio (RR) of ≧8, or ≧9, or ≧10, or ≧11, or ≧12. In one embodiment, or a combination of two or more embodiments, each described herein, the second interpolymer has a rheology ratio (RR) of ≦30, or ≦28, or ≦26, or ≦24, or ≦22, or ≦20, or ≦18, or ≦16, or ≦14.

[0036] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has an {[RR] 第1のインターポリマー / [RR] 第2のインターポリマーIn one embodiment, or a combination of two or more embodiments, each described herein, the composition has a {[RR]} ratio of ≦3.0, or ≦2.9, or ≦2.8, or ≦2.7, or ≦2.6. 第1のインターポリマー / [RR] 第2のインターポリマー} ratio.

[0037] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a {[MV] of ≧1.9, or ≧2.0, or ≧2.1, or ≧2.2, or ≧2.3, or ≧2.4, or ≧2.5, or ≧2.6. 第1のインターポリマー / [MV] 第2のインターポリマー In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a Mooney viscosity ratio of {[MV]}≦3.2, or ≦3.1, or ≦3.0, or ≦2.9, or ≦2.8, or ≦2.7. 第1のインターポリマー / [MV] 第2のインターポリマー} ratio.

[0038] In one embodiment, or a combination of two or more embodiments, each described herein, the first ethylene / alpha-olefin / non-conjugated polyene interpolymer or the second ethylene / alpha-olefin / non-conjugated polyene interpolymer each independently comprises 50% by weight or a majority of polymerized ethylene based on the weight of the respective interpolymer. In a further embodiment, each interpolymer is independently EPDM. In a further embodiment, each diene is ENB.

[0039] In one embodiment, or a combination of two or more embodiments, each described herein, the first ethylene / alpha-olefin / non-conjugated polyene interpolymer and the second ethylene / alpha-olefin / non-conjugated polyene interpolymer each independently contain 50% by weight or a majority of polymerized ethylene based on the weight of the respective interpolymer. In a further embodiment, each interpolymer is independently EPDM. In a further embodiment, each diene is ENB.

[0040] In one embodiment, or a combination of two or more embodiments, each described herein, the composition comprises ≧20.0 wt.%, or ≧22.0 wt.%, or ≧24.0 wt.%, or ≧26.0 wt.% of the first interpolymer and the second interpolymer, based on the weight of the composition. In one embodiment, or a combination of two or more embodiments, each described herein, the composition comprises ≦40.0 wt.%, or ≦38.0 wt.%, or ≦36.0 wt.%, or ≦34.0 wt.%, or ≦32.0 wt.%, or ≦30.0 wt.% of the first interpolymer and the second interpolymer, based on the weight of the composition.

[0041] In one embodiment, or a combination of two or more embodiments, each described herein, the composition further comprises an oil. In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of the oil to the composition is ≧0.10, or ≧0.12, or ≧0.14, or ≧0.16, or ≧0.18. In one embodiment, or a combination of two or more embodiments, each described herein, the weight ratio of the oil to the composition is ≦0.30, or ≦0.28, or ≦0.26, or ≦0.24, or ≦0.22, or ≦0.20.

[0042] In one embodiment, or a combination of two or more embodiments, each described herein, the composition further comprises a crosslinking agent. In a further embodiment, the crosslinking agent comprises sulfur, one or more activators, and / or one or more accelerators, and additional sulfur. In one embodiment, or a combination of two or more embodiments, each described herein, the crosslinking agent is present in an amount of 0.5 phr to 18 phr, or 5.0 phr to 18 phr, or 12 phr to 18 phr, based on 100 parts of the first interpolymer and the second interpolymer combined.

[0043] The present invention also provides crosslinked compositions formed from one embodiment, or a combination of two or more embodiments, each described herein.

[0044] In one embodiment, or a combination of two or more embodiments, each described herein, the composition comprises > 1 x 10 9 ohm cm, or ≥ 1×10ohm cm, or ≥ 1×10 11 In a further embodiment, the composition has a volume resistivity of ≦1×10 15 It has a volume resistivity of ohm·cm.

[0045] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has an elongation at break of ≧400%, or ≧420%, or ≧440%, or ≧460%, or ≧480%, or ≧500%, or ≧520%, or ≧540%, or ≧560%, or ≧580%.

[0046] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has an elongation at break of ≧600%, or ≧610%, or ≧620%, or ≧630%, or ≧640%, or ≧650%, or ≧660%, or ≧670%.

[0047] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a Shore A hardness of ≧57, or ≧58, or ≧59, or ≧60. In further embodiments, the composition has a Shore A hardness of ≦95.

[0048] In one embodiment, or a combination of two or more embodiments, each described herein, the composition has a tensile strength of ≧7.4 MPa, or ≧7.5 MPa, or ≧7.6 MPa, or ≧7.7 MPa. In further embodiments, the composition has a tensile strength of ≦16 MPa.

[0049] The present invention also provides an article comprising at least one component formed from the composition of an embodiment, or a combination of two or more embodiments, each of which is described herein. In an embodiment, or a combination of two or more embodiments, each of which is described herein, the article is an automobile part. In an embodiment, or a combination of two or more embodiments, each of which is described herein, the article is an extrusion article (e.g., an extrusion profile), an injection molded article, or a thermoformed article, as well as an extrusion article (e.g., an extrusion profile).

[0050] In one embodiment, or a combination of two or more embodiments, each described herein, the article is selected from a weatherstrip, a hose (e.g., an automotive hose), a belt (e.g., an automotive belt), a building material, a roofing membrane, a wire or cable jacket, a flooring material, a computer component, a gasket, or a tire.

[0051] The composition of the present invention may comprise a combination of two or more embodiments as described herein. The first ethylene / alpha-olefin / non-conjugated polyene interpolymer (first interpolymer) may comprise a combination of two or more embodiments as described herein. The second ethylene / alpha-olefin / non-conjugated polyene interpolymer (second interpolymer) may comprise a combination of two or more embodiments as described herein.

[0052] Ethylene / Alpha-Olefin / Non-Conjugated Polyene Interpolymer The first and second ethylene / alpha-olefin / non-conjugated polyene interpolymers each independently comprise, in polymerized form, ethylene, an alpha-olefin, and a non-conjugated polyene, as described herein. The alpha-olefins can be either aliphatic or aromatic. The alpha-olefins are preferably C3-C20 aliphatic, preferably C3-C16 aliphatic, more preferably C3-C10 aliphatic. Preferred C3-C10 aliphatic alpha-olefins include propylene, 1-butene, 1-hexene, 1-octene, and 1-decene, more preferably propylene. In one embodiment, or a combination of two or more embodiments, each described herein, each interpolymer is independently an ethylene / propylene / non-conjugated diene terpolymer. In a further embodiment, each diene is ENB.

[0053] Suitable examples of non-conjugated polyenes include C4-C40 non-conjugated dienes. Exemplary non-conjugated polyenes include linear acyclic dienes such as 1,4-hexadiene and 1,5-heptadiene; branched acyclic dienes such as 5-methyl-1,4-hexadiene, 2-methyl-1,5-hexadiene, 6-methyl-1,5-heptadiene, 7-methyl-1,6-octadiene, 3,7-dimethyl-1,6-octadiene, 3,7-dimethyl-1,7-octadiene, 5,7-dimethyl-1,7-octadiene, 1,9-decadiene, and mixed isomers of dihydromyrcene; monocyclic alicyclic dienes such as 1,4-cyclohexadiene, 1,5-cyclooctadiene. , and 1,5-cyclododecadiene; polycyclic alicyclic fused ring and bridged ring dienes, such as tetrahydroindene, methyltetrahydroindene; alkenyl, alkylidene, cycloalkenyl, and cycloalkylidene norbornenes, such as 5-methylene-2-norbornene (MNB), 5-ethylidene-2-norbornene (ENB), 5-vinyl-2-norbornene (VNB), 5-propenyl-2-norbornene, 5-isopropylidene-2-norbornene, 5-(4-cyclopentenyl)-2-norbornene, and 5-cyclohexylidene-2-norbornene. Preferably, the polyene is a non-conjugated polyene selected from the group consisting of ENB, VNB, dicyclopentadiene, 1,4-hexadiene, 7-methyl-1,6-octadiene, preferably ENB, VNB, dicyclopentadiene, and 1,4-hexadiene, more preferably ENB, VNB, and dicyclopentadiene, even more preferably ENB.

[0054] Crosslinkers, oils, and other additives Crosslinking agents include, but are not limited to, sulfur-containing compounds such as elemental sulfur, 4,4'-dithiodimorpholine, thiuram di- and polysulfides, alkylphenol disulfides, and 2-morpholino-dithiobenzothiazole; and peroxides such as di-tertiary butyl peroxide, tert-butyl cumyl peroxide, dicumyl peroxide, 2,5-dimethyl-2,5-di-(tertiary butyl peroxy)hexane, di-(tertiary butyl peroxy isopropyl)benzene, tertiary butyl peroxybenzoate, and 1,1-di-(tertiary butyl peroxy)-3,3,5-trimethylcyclohexane. The sulfur can be crystalline elemental sulfur or amorphous elemental sulfur, either type being in pure form or supported on an inert carrier. An example of supported sulfur is RHENOGRAN S-80 (80% S and 20% inert carrier) from Rhein Chemie. Sulfur-containing compounds are preferred crosslinking agents.

[0055] The oil includes, but is not limited to, paraffin oil, naphthenic oil, and polyalkylbenzene. In one embodiment, or a combination of two or more embodiments, each of which is described herein, the oil is selected from the group consisting of non-aromatic oil, paraffin oil, naphthenic oil, and combinations thereof. Suitable oils include, but are not limited to, SUNPAR 2280, PARALUX 6001, HYDROBRITE 550, and CALSOL 5550, preferably SUNPAR 2280.

[0056] The composition of the present invention may include one or more additional additives. Suitable additives include, but are not limited to, fillers, stabilizers (e.g., antioxidants, antiozonants, UV stabilizers), flame retardants, colorants or pigments, and combinations thereof. Fillers include, but are not limited to, calcined fillers (e.g., see Table 1 below); carbon black (e.g., SPHERON 6000A, SPHERON 5000A, SPHERON 6400A, and THERMAX N-990); silicates of aluminum, magnesium, calcium; titanium dioxide; natural fibers; synthetic fibers, and the like. The composition of the present invention preferably includes at least one calcined filler and carbon black. Antiozonants include, but are not limited to, hindered phenols, bisphenols, thiobisphenols, and substituted hydroquinones. Typically, one or more stabilizers in "ppm" amounts are added to the polymer or polymer composition. Calcium oxide may be used as a desiccant in an amount typically between 4 phr and 10 phr based on 100 parts of the polymeric component (e.g., the first and second interpolymers). Useful processing aids include fatty acids, Zn / Ca, and Zn-free fatty acids.

[0057] In one embodiment, or a combination of two or more embodiments, each of which is described herein, the composition of the present invention further comprises a thermoplastic polymer that is different from each of the first and second interpolymers independently in one or more characteristics, such as the type and / or amount of monomer, Mn, Mw, Mz, MWD, Mooney viscosity, V0.1, V100, RR, or any combination thereof. The polymer includes, but is not limited to, ethylene-based polymers, propylene-based polymers, and olefin multi-block interpolymers. Suitable ethylene-based polymers include, but are not limited to, high density polyethylene (HDPE), linear low density polyethylene (LLDPE), very low density polyethylene (VLDPE), very low density polyethylene (ULDPE), homogeneously branched linear ethylene-based polymers, and homogeneously branched substantially linear ethylene-based polymers (i.e., homogeneously branched long chain branched ethylene polymers). Suitable propylene-based polymers include, but are not limited to, polypropylene homopolymers and propylene / ethylene copolymers.

[0058] definition Unless stated to the contrary, implicit from the context, or customary in the art, all parts and percentages are by weight and all test methods are as of the filing date of this disclosure.

[0059] As used herein, the term "composition" means It includes mixtures of materials, including compositions and reaction products and decomposition products formed from the materials of the composition. Any reaction or decomposition products are typically present in trace or residual amounts.

[0060] As used herein, the term "polymer" means It refers to a polymeric compound prepared by polymerizing monomers, whether of the same type or different types.Thus, the general term polymer includes the term homopolymer (used to refer to a polymer prepared from only one type of monomer, with the understanding that trace amounts of impurities may be incorporated into the polymer structure), and the term interpolymer, as defined herein below.Trace amounts of impurities, such as catalyst residues, may be incorporated into and / or into the polymer.

[0061] As used herein, the term "interpolymer" refers to a polymer prepared by the polymerization of at least two different types of monomers. Thus, the term interpolymer includes the term copolymer (used to refer to a polymer prepared from two different types of monomers) and polymers prepared from more than two different types of monomers.

[0062] As used herein, the term "propylene-based polymer" refers to a polymer that, in polymerized form, contains a majority weight percent propylene (based on the weight of the polymer) and may optionally contain one or more comonomers.

[0063] As used herein, the term "ethylene-based polymer" refers to a polymer that, in polymerized form, contains at least 50 weight percent or majority weight percent ethylene (based on the weight of the polymer), and may optionally contain one or more comonomers.

[0064] As used herein, "ethylene / alpha-olefin / non-conjugated polyene interpolymer" refers to an interpolymer comprising, in polymerized form, ethylene, an alpha-olefin, and a non-conjugated polyene. In one embodiment, the "ethylene / alpha-olefin / non-conjugated polyene interpolymer" comprises, in polymerized form, 50% or a majority weight percent of ethylene (based on the weight of the interpolymer). As used herein, the term "ethylene / α-olefin / non-conjugated diene interpolymer" refers to an interpolymer comprising ethylene, an alpha-olefin, and a non-conjugated polyene. In one embodiment, the "ethylene / alpha-olefin / non-conjugated diene interpolymer" comprises, in polymerized form, 50% or a majority weight percent of ethylene (based on the weight of the interpolymer).

[0065] As used herein, the term "ethylene / alpha-olefin copolymer" refers to a copolymer that includes, in polymerized form, 50% by weight or a majority amount of ethylene monomer (based on the weight of the copolymer) and an alpha-olefin as the only two monomer types.

[0066] As used herein, the term "calcination," in relation to a filler, refers to a heat treatment of the filler; The treatment is carried out at temperatures ≧600° C., typically up to ≦1050° C. Such heat treatments can be carried out in a furnace. The filler may be heated to oxidize, remove moisture, and / or reduce to a loose state (calx), but not to melt. Typically, the calcination process removes the water of crystallization and crystallinity of the hydrous materials.

[0067] The terms "comprising," "including," "having," and their derivatives are not intended to exclude the presence of any additional component, step, or procedure, whether or not the same is specifically disclosed. For the avoidance of doubt, all compositions claimed through the use of the term "comprising" may include any additional additive, adjuvant, or compound, whether polymeric or not, unless stated to the contrary. In contrast, the term "consisting essentially of" excludes any other component, step, or procedure from the scope of any succeeding description, except those that are not essential to operability. The term "consisting of" excludes any component, step, or procedure not specifically defined or listed.

[0068] A list of some compositional features a) a composition comprising: a) a first ethylene / alpha-olefin / non-conjugated polyene interpolymer (first interpolymer) having a Mooney viscosity of ≧50; b) a second ethylene / alpha-olefin / non-conjugated polyene interpolymer (second interpolymer) having a Mooney viscosity of <50; and c) a calcined filler formed from a filler composition comprising kaolinite. b) The composition of a) above, wherein the filler composition further comprises silica. c) The composition of a) or b) above, wherein the fired filler is surface treated with a composition comprising a mercapto-silane, an alkylsilane, a vinylsilane, an epoxy, or an aminosilane. d) Any one of the compositions of a) to c) above, wherein the fired filler has a d50 of <4 microns, ≦0.5 wt. % and preferably ≦0.2 wt. % volatiles at 105° C., >6m 2 / g surface area, or combinations thereof. e) Any one of the compositions a) to d) above, wherein the weight ratio of the sintered filler to the composition is ≧0.10, or ≧0.15, or ≧0.20, or ≧0.25. f) Any one of the compositions a) to e) above, wherein the weight ratio of the sintered filler to the composition is ≦0.50, or ≦0.45, or ≦0.40, or ≦0.35, or ≦0.30. g) Any one of the compositions of a) to f) above, wherein the weight ratio of the sintered filler to the sum of the first and second interpolymers is ≧0.80, or ≧0.85, or ≧0.90, or ≧0.95, or ≧1.00, or ≧1.05. h) Any one of the compositions of a) to g) above, wherein the weight ratio of the sintered filler to the sum of the first and second interpolymers is ≦1.35, or ≦1.30, or ≦1.25, or ≦1.20, or ≦1.15, or ≦1.10. i) Any one of the compositions a) to h) above, wherein the composition further contains carbon black. j) The composition of i) above, wherein the weight ratio of carbon black to the composition is ≧0.05, or ≧0.10, or ≧0.15, or ≧0.20. k) The composition of i) or j) above, wherein the weight ratio of carbon black to the composition is ≦0.50, or ≦0.45, or ≦0.40, or ≦0.35, or ≦0.30, or ≦0.25. l) Any one of the compositions i) to k) above, wherein the weight ratio of carbon black to the sum of the first and second interpolymers is ≧0.40, or ≧0.45, or ≧0.50, or ≧0.55, or ≧0.60, or ≧0.65, or ≧0.70, or ≧0.75. m) Any one of the compositions i) to l) above, wherein the weight ratio of carbon black to the sum of the first and second interpolymers is ≦1.10, or ≦1.05, or ≦1.00, or ≦0.95, or ≦0.90, or ≦0.85, or ≦0.80. n) Any one of the compositions i) to m) above, wherein the weight ratio of carbon black to the sintered filler is ≧0.40, or ≧0.45, or ≧0.50, or ≧0.55, or ≧0.60, or ≧0.65. o) The composition according to any one of the above i) to n), wherein the weight ratio of carbon black to the sintered filler is ≦1.00, or ≦0.95, or ≦0.90, or ≦0.85, or ≦0.80, or ≦0.75, or ≦0.70. p) Any one of the compositions i) to o) above, wherein the carbon black has an oil amount (OAN) of <100 mL / 100 g, an oil amount (OAN) of <25 m 2 / g STSA surface area, an iodine value of ≦20 mg / g, or a combination thereof. q) Any one of the compositions of a) to p) above, wherein the composition has a viscosity of ≧1.00 g / cc, or ≧1.05 g / cc, or ≧1.10 g / cc, or ≧1.15 g / cc, or ≧1.20 g / cc (1 cc=1 cm 3 ) the composition. r) Any one of the compositions of a) to q) above, wherein the composition has a density of ≦1.50 g / cc, or ≦1.45 g / cc, or ≦1.40 g / cc, or ≦1.35 g / cc, or ≦1.30 g / cc. s) Any one of the compositions of a) to r) above, wherein the composition has a Mooney viscosity (ML(1+4), 100°C) of ≧20, or ≧25, or ≧30, or ≧35, or ≧40. t) Any one of the compositions of a) to s) above, wherein the composition has a Mooney viscosity (ML(1+4), 100°C) of ≦80, or ≦75, or ≦70, or ≦65, or ≦60, or ≦55, or ≦50. u) Any one of the compositions of a) to t) above, wherein the composition has a rheology ratio (RR) of ≧40, or ≧45, or ≧50, or ≧55, or ≧60. v) Any one of the compositions of a) to u) above, wherein the composition has a rheology ratio (RR) of ≦95, or ≦90, or ≦85, or ≦80, or ≦75. w) Any one of the compositions a) to v) above, wherein the composition has a V0.1(0.1 rad / s, 190°C) of ≥ 150,000 Pa·s, or ≥ 155,000 Pa·s, or ≥ 160,000 Pa·s, or ≥ 165,000 Pa·s, or ≥ 170,000 Pa·s, or ≥ 175,000 Pa·s. x) Any one of the compositions a) to w) above, wherein the composition has a V0.1(0.1 rad / s, 190°C) of ≦230,000 Pa·s, or ≦225,000 Pa·s, or ≦220,000 Pa·s, or ≦215,000 Pa·s, or ≦210,000 Pa·s, or ≦205,000 Pa·s, or ≦195,000 Pa·s. y) Any one of the compositions a) to x) above, wherein the composition has a V100(100 rad / s, 190°C) of ≥ 2,000 Pa·s, or ≥ 2,100 Pa·s, or ≥ 2,200 Pa·s, or ≥ 2,300 Pa·s, or ≥ 2,400 Pa·s, or ≥ 2,500 Pa·s, or ≥ 2,600 Pa·s. z) Any one of the compositions a) to y) above, wherein the composition has a V100(100 rad / s, 190°C) of ≦3,600 Pa·s, or ≦3,500 Pa·s, or ≦3,400 Pa·s, or ≦3,300 Pa·s, or ≦3,200 Pa·s, or ≦3,100 Pa·s, or ≦3,000 Pa·s, or ≦2,900 Pa·s. aa) Any one of the compositions of a) to z) above, wherein the composition comprises ≧12.0 wt.%, or ≧14.0 wt.%, or ≧16.0 wt.%, or ≧18.0 wt.% of the first ethylene / alpha-olefin / non-conjugated polyene interpolymer (first interpolymer), based on the weight of the composition. bb) Any one of the compositions of a) to aa) above, wherein the composition comprises ≦30.0 wt.%, or ≦28.0 wt.%, or ≦26.0 wt.%, or ≦24.0 wt.%, or ≦22.0 wt.%, or ≦20.0 wt.% of the first interpolymer, based on the weight of the composition. cc) Any one of the compositions of a) to bb) above, wherein the composition comprises ≧3.0 wt.%, or ≧4.0 wt.%, or ≧5.0 wt.%, or ≧6.0 wt.%, or ≧7.0 wt.% of a second ethylene / alpha-olefin / non-conjugated polyene interpolymer (second interpolymer), based on the weight of the composition. dd) Any one of the compositions of a) to cc) above, wherein the composition comprises ≦12.0 wt.%, or ≦11.0 wt.%, or ≦10.0 wt.%, or ≦9.0 wt.% of the second interpolymer, based on the weight of the composition. ee) Any one of the compositions a) to dd) above, wherein the first interpolymer is a first EPDM. ff) Any one of the compositions a) to ee) above, wherein the non-conjugated polyene of the first interpolymer is ENB. gg) The composition of ff) above, wherein the ENB content of the first interpolymer is ≧5.5 wt%, or ≧6.0 wt%, or ≧6.5 wt%, or ≧7.0 wt%. hh) The composition of ff) or gg) above, wherein the ENB content of the first interpolymer is ≦9.5 wt%, or ≦9.0 wt%, or ≦8.5 wt%, or ≦8.0 wt%, each weight percent being based on the weight of the first interpolymer. It is understood that the ENB content is in polymerized form. ii) Any one of the compositions of a) to hh) above, wherein the second interpolymer is a second EPDM. jj) Any one of the compositions a) to ii) above, wherein the non-conjugated polyene of the second interpolymer is ENB. kk) The composition of jj) above, wherein the ENB content of the second interpolymer is ≧3.0 wt%, or ≧3.5 wt%, or ≧4.0 wt%. ll) The composition of jj) or kk) above, wherein the ENB content of the second interpolymer is ≦6.5 wt%, or ≦6.0 wt%, or ≦5.5 wt%, or ≦5.0 wt%, each weight percent being based on the weight of the second interpolymer. It is understood that the ENB content is in polymerized form. mm) Any one of the compositions a) to ll) above, wherein the C2 (ethylene) content of the first interpolymer is ≧40.0 wt%, or ≧42.0 wt%, or ≧44.0 wt%, or ≧46.0 wt%, or ≧48.0 wt%. nn) Any one of the compositions of a) to mm) above, wherein the C2 (ethylene) content of the first interpolymer is ≦60.0 wt%, or ≦58.0 wt%, or ≦56.0 wt%, or ≦54.0 wt%, or ≦52.0 wt%, each weight percent being based on the weight of the first interpolymer. It is understood that the C2 (ethylene) content is in polymerized form. oo) Any one of the compositions a) to nn) above, wherein the C2 (ethylene) content of the second interpolymer is ≧60.0 wt%, or ≧62.0 wt%, or ≧64.0 wt%, or ≧66.0 wt%, or ≧68.0 wt%. pp) The composition of any one of a) to oo) above, wherein the C2 (ethylene) content of the second interpolymer is ≧84.0 wt%, or ≧82.0 wt%, or ≧80.0 wt%, or ≧78.0 wt%, or ≧76.0 wt%, or ≧74.0 wt%, each weight percentage being based on the weight of the second interpolymer. It is understood that the C2 (ethylene) content is in polymerized form. qq) Any one of the compositions of a) through pp) above, wherein the first interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of ≧52, or ≧54, or ≧56, or ≧58, or ≧60, or ≧62, or ≧64. rr) Any one of the compositions of a) through qq) above, wherein the first interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of ≦100, or ≦95, or ≦90, or ≦85, or ≦80, or ≦75, or ≦70. ss) The composition of any one of a) through rr) above, wherein the second interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of ≧5.0, or ≧10, or ≧15, or ≧20, or ≧25, or ≧30. tt) The composition of any one of a) through ss) above, wherein the second interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of ≦48, or ≦46, or ≦44, or ≦42, or ≦40, or ≦38, or ≦36. uu) Any one of a) through tt) above, wherein the second interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of ≧28, or ≧29, or ≧30. vv) Any one of a) through uu) above, wherein the second interpolymer has a Mooney viscosity (ML1+4 at 125° C.) of <50, or ≦48, or ≦46, or ≦44, or ≦42, or ≦40, or ≦38, or ≦36, or ≦34, or ≦32. ww) Any one of a) to vv) above, wherein the second interpolymer has a Mooney viscosity (ML1+4 at 125°C) of 28 to <50, 29 to <50, or 30 to <50. xx) Any one of the compositions of a) to ww) above, wherein the second interpolymer has a Mooney viscosity (ML1+4 at 125°C) of 28 to 45, or 28 to 40, or 28 to 35. yy) The composition of any one of a) through xx) above, wherein the first interpolymer has a number average molecular weight Mn of ≧50,000 g / mol, or ≧55,000 g / mol, or ≧60,000 g / mol, or ≧65,000 g / mol, or ≧70,000 g / mol. zz) Any one of the compositions of a) through yy) above, wherein the first interpolymer has a number average molecular weight Mn of ≦95,000 g / mol, or ≦90,000 g / mol, or ≦85,000 g / mol, or ≦80,000 g / mol, or ≦75,000 g / mol. a3) Any one of the compositions of a) to zz) above, wherein the second interpolymer has a number average molecular weight Mn of ≧20,000 g / mol, or ≧25,000 g / mol, or ≧30,000 g / mol, or ≧35,000 g / mol. b3) Any one of the compositions of a) to a3) above, wherein the second interpolymer has a number average molecular weight Mn of ≦70,000 g / mol, or ≦65,000 g / mol, or ≦60,000 g / mol, or ≦55,000 g / mol, or ≦50,000 g / mol, or ≦45,000 g / mol, or ≦40,000 g / mol. c3) Any one of the compositions of a) to b3) above, wherein the first interpolymer has a weight average molecular weight Mw of ≧180,000 g / mol, or ≧190,000 g / mol, or ≧200,000 g / mol, or ≧210,000 g / mol. d3) The composition of any one of a) through c3) above, wherein the first interpolymer has a weight average molecular weight Mw of ≦250,000 g / mol, or ≦240,000 g / mol, or ≦230,000 g / mol, or ≦220,000 g / mol. e3) The composition of any one of a) through d3) above, wherein the second interpolymer has a weight average molecular weight Mw of ≥ 70,000 g / mol, or ≥ 80,000 g / mol, or ≥ 90,000 g / mol, or ≥ 100,000 g / mol, or ≥ 110,000 g / mol. f3) The composition of any one of a) through e3) above, wherein the second interpolymer has a weight average molecular weight Mw of ≦150,000 g / mol, or ≦140,000 g / mol, or ≦130,000 g / mol, or ≦120,000 g / mol. g3) The composition of any one of a) to f3) above, wherein the first interpolymer has a molecular weight distribution MWD of ≧2.60, or ≧2.65, or ≧2.70, or ≧2.75, or ≧2.80, or ≧2.85, or ≧2.90. h3) The composition of any one of a) through g3) above, wherein the first interpolymer has a molecular weight distribution (MWD) of ≦3.30, or ≦3.25, or ≦3.20, or ≦3.15, or ≦3.10, or ≦3.05, or ≦3.00. i3) The composition of any one of a) through h3) above, wherein the second interpolymer has a molecular weight distribution (MWD) of ≧2.80, or ≧2.85, or ≧2.90, or ≧2.95, or ≧3.00, or ≧3.05, or ≧3.10. j3) Any one of the compositions of a) to i3) above, wherein the second interpolymer has a molecular weight distribution MWD of ≦3.50, or ≦3.45, or ≦3.40, or ≦3.35, or ≦3.30, or ≦3.25, or ≦3.20. k3) Any one of the compositions of a) to j3) above, wherein the composition has a {[Mn] of ≧1.75, or ≧1.80, or ≧1.85, or ≧1.90. 第1のインターポリマー / [Mn] 第2のインターポリマー} ratio. l3) Any one of the compositions of a) to k3) above, wherein the composition has a {[Mn] 第1のインターポリマー / [Mn] 第2のインターポリマー} ratio. m3) Any one of the compositions a) to l3) above, wherein the composition has a {[Mw] of ≧1.60, or ≧1.65, or ≧1.70, or ≧1.75. 第1のインターポリマー / [Mw] 第2のインターポリマー} ratio. n3) Any one of the compositions a) to m3) above, wherein the composition has a {[Mw] of ≦1.95, or ≦1.90, or ≦1.85, or ≦1.80. 第1のインターポリマー / [Mw] 第2のインターポリマー} ratio. o3) Any one of the compositions of a) to n3) above, wherein the composition has a {[MWD] of ≧0.905, or ≧0.910, or ≧0.915, or ≧0.920. 第1のインターポリマー / [MWD] 第2のインターポリマー The composition has a ratio of p3) Any one of the compositions a) to o3) above, wherein the composition has a {[MWD] of ≦0.945, or ≦0.940, or ≦0.935, or ≦0.930. 第1のインターポリマー / [MWD] 第2のインターポリマー} ratio. q3) Any one of the compositions of a) to p3) above, wherein the composition has a rheology ratio (RR) of ≧22, or ≧24, or ≧26, or ≧28, or ≧30. r3) Any one of the compositions of a) to q3) above, wherein the first interpolymer has a rheology ratio (RR) of ≦46, or ≦44, or ≦42, or ≦40, or ≦38, or ≦36. s3) Any one of the compositions of a) to r3) above, wherein the second interpolymer has a rheology ratio (RR) of ≧8, or ≧9, or ≧10, or ≧11, or ≧12. t3) Any one of the compositions of a) to s3) above, wherein the second interpolymer has a rheology ratio (RR) of ≦30, or ≦28, or ≦26, or ≦24, or ≦22, or ≦18, or ≦16, or ≦14. u3) Any one of the compositions of a) to t3) above, wherein the composition has an {[RR] of ≧2.0, or ≧2.1, or ≧2.2, or ≧2.3, or ≧2.4, or ≧2.5. 第1のインター Polymer / [RR] 第2のインター The composition has a ratio of 1:1 to 1:1. v3) Any one of the compositions of a) to u3) above, wherein the composition has an {[RR] of ≦3.0, or ≦2.9, or ≦2.8, or ≦2.7, or ≦2.6. 第1のインターポリマー / [RR] 第2のインターポリマー} ratio. w3) Any one of the compositions of a) to v3) above, wherein the composition has an {[MV] of ≧1.9, or ≧2.0, or ≧2.1, or ≧2.2, or ≧2.3, or ≧2.4, or ≧2.5, or ≧2.6. 第1のインターポリマー / [MV] 第2のインターポリマー} ratio. x3) ​​Any one of the compositions a) to w3) above, wherein the composition has an {[MV] of ≦3.2, or ≦3.1, or ≦3.0, or ≦2.9, or ≦2.8, or ≦2.7. 第1のインターポリマー / [MV] 第2のインターポリマー} ratio. y3) Any one of the compositions of a) through x3) above, wherein the first ethylene / alpha-olefin / non-conjugated polyene interpolymer or the second ethylene / alpha-olefin / non-conjugated polyene interpolymer each independently contains 50% by weight or a majority of polymerized ethylene, based on the weight of the respective interpolymer. z3) The composition of y3) above, wherein each interpolymer is independently EPDM and each diene is ENB. a4) Any one of the compositions a) through z3) above, wherein the first ethylene / alpha-olefin / non-conjugated polyene interpolymer and the second ethylene / alpha-olefin / non-conjugated polyene interpolymer each independently contain 50 weight percent or a majority of polymerized ethylene, based on the weight of the respective interpolymer. b4) The composition of a4) above, wherein each interpolymer is independently EPDM and each diene is ENB. c4) Any one of the compositions of a) to b4) above, wherein the composition comprises, based on the weight of the composition, the first interpolymer and the second interpolymer in a total amount of ≧20.0 wt%, or ≧22.0 wt%, or ≧24.0 wt%, or ≧26.0 wt%. d4) Any one of the compositions of a) to c4) above, wherein the composition comprises the first interpolymer and the second interpolymer in a total amount of ≦40.0 wt%, or ≦38.0 wt%, or ≦36.0 wt%, or ≦34.0 wt%, or ≦32.0 wt%, or ≦30.0 wt%, based on the weight of the composition. e4) Any one of the compositions a) to d4) above, wherein the composition further comprises an oil. f4) The composition of e4) above, wherein the weight ratio of oil to the composition is ≧0.10, or ≧0.12, or ≧0.14, or ≧0.16, or ≧0.18. g4) The composition of e4) or f4) above, wherein the weight ratio of oil to the composition is ≦0.30, or ≦0.28, or ≦0.26, or ≦0.24, or ≦0.22, or ≦0.20. h4) Any one of the compositions a) to g4) above, wherein the composition further comprises a crosslinker. i4) The composition of h4) above, wherein the crosslinking agent comprises sulfur, one or more activators, and / or one or more accelerators. j4) The composition of i4) above, wherein the crosslinking agent comprises sulfur. k4) The composition of any one of h4) to j4) above, wherein the crosslinker is present in an amount of 0.5 phr to 18 phr, or 5.0 phr to 18 phr, or 12 phr to 18 phr, based on 100 parts combined of the first interpolymer and the second interpolymer. A crosslinked composition formed from any one of the compositions a) to k4) above. m4) Any one of the compositions of a) to l4) above, wherein the composition has a molecular weight of ≧1×10 9 ohm cm, or ≥ 1×10ohm cm, or ≥ 1×10 11 A composition having a volume resistivity of ohm·cm. n4) Any one of the compositions of a) to m4) above, wherein the composition has an elongation at break of ≧400%, or ≧420%, or ≧440%, or ≧460%, or ≧480%, or ≧500%, or ≧520%, or ≧540%, or ≧560%, or ≧580%, or ≧600%, or ≧610%, or ≧620%, or ≧630%, or ≧640%, or ≧650%, or ≧660%, or ≧670%. o4) Any one of the compositions of a) to n4) above, wherein the composition has a compression set (22 hours / 23°C) of ≦13, or ≦12, or ≦11, or ≦10. p4) Any one of the compositions a) to o4) above, wherein the composition has a compression set (22 hours / 70°C) of ≦17, or ≦16, or ≦15, or ≦14. q4) Any one of the compositions of a) to p4) above, wherein the composition has a compression set (22 hours / 100°C) of ≦32, or ≦31, or ≦30, or ≦29. r4) Any one of the compositions of a) to q4) above, wherein the composition has a Shore A hardness of ≧57, or ≧58, or ≧59, or ≧60. s4) Any one of the compositions of a) to r4) above, wherein the composition has a trouser tear strength of ≧8 N / m, or ≧9 N / m, or ≧10 N / m, or ≧11 N / m, or ≧12 N / m. t4) Any one of the compositions of a) to s4) above, wherein the composition has a tensile strength of ≧7.4 MPa, or ≧7.5 MPa, or ≧7.6 MPa, or ≧7.7 MPa. u4) An article comprising at least one component formed from any one of the compositions a) to t4) above. v4) An article as described above in u4), which is an automobile part. w4) The article of u4) or v4), wherein the article is an extruded article (e.g., an extruded profile), an injection molded article, or a thermoformed article, further comprising an extruded article (e.g., an extruded profile). x4) Any one of the articles u4) through w4) above, wherein the article is selected from a weatherstrip, a hose (e.g., an automotive hose), a belt (e.g., an automotive belt), a building material, a roofing membrane, a wire or cable jacket, a flooring material, a computer part, a gasket, or a tire.

[0069] Test Method Gel Permeation Chromatography The chromatography system consisted of a PolymerChar GPC-IR (Valencia, Spain) high temperature GPC chromatograph equipped with an internal IR5 infrared detector (IR5). The autosampler oven compartment was set at 160 °C and the column compartment was set at 150 °C. The columns were four Agilent "Mixed A" 30 cm, 20 micron linear mixed bed columns, and a 20 micron precolumn. The chromatography solvent was 1,2,4-trichlorobenzene containing "200 ppm butylated hydroxytoluene (BHT)". The solvent source was sparged nitrogen. The injection volume was 200 microliters and the flow rate was 1.0 milliliters / min.

[0070] Calibration of the GPC column set was performed with "21 narrow molecular weight distribution polystyrene standards" with molecular weights ranging from 580 to 8,400,000 g / mol, prepared in six "cocktail" mixtures with at least 10-fold separation between individual molecular weights. Standards were purchased from Agilent Technologies. Polystyrene standards were prepared at 0.025 grams in 50 milliliters of solvent for molecular weights of 1,000,000 g / mol or greater, and 0.05 grams in 50 milliliters of solvent for molecular weights less than 1,000,000 g / mol. The polystyrene standards were dissolved at 80°C with gentle agitation for 30 minutes. The polystyrene standard peak molecular weights were converted to polyethylene molecular weights using the following formula (described in Williams and Ward, J. Polym. Sci., Polym. Let., 6, 621 (1968)): M ポリエチレン =A×(M ポリスチレン ) B (Equation 1), where M is the molecular weight, A has a value of 0.4315, and B is equal to 1.0.

[0071] A fifth order polynomial was used to fit each of the polyethylene equivalent calibration points. A small adjustment (approximately 0.375 to 0.445) was made to A to correct for column resolution and band broadening effects for a linear homopolymer polyethylene standard obtained at 120,000 Mw.

[0072] Total plate counts for the GPC column set were performed in decane (prepared at 0.04 g in 50 milliliters of TCB and dissolved for 20 minutes with gentle agitation). Plate counts (Equation 2) and symmetry (Equation 3) were measured with a "200 microliter injection" according to the following equations:

number

[0073] Samples were prepared semi-automatically with PolymerChar "Instru-ment Control" software, with a target weight of "2 mg / ml" and solvent (containing 200 ppm BHT) added via the PolymerChar high temperature autosampler to a septum-capped vial that had been pre-sparged with nitrogen. Samples were dissolved at 160°C for 2 hours under "slow" shaking. Calculations of Mn(GPC), Mw(GPC), and Mz(GPC) were based on GPC results using the internal IR5 detector (measurement channel) of the PolymerChar GPC-IR chromatograph according to Equations 4-6, and using PolymerChar GPCOne™ software, IR chromatograms with baseline subtraction at each equally spaced data collection point (i), and polyethylene equivalent molecular weights obtained from a narrow standard calibration curve of point (i) from Equation (1).

number

[0074] To monitor deviations over time, a flow marker (decane) was introduced into each sample via a micropump controlled by the PolymerChar GPC-IR system. This flow marker (FM) was used to linearly correct the pump flow rate (Flow (apparent)) of each sample by matching the RV of the respective decane peak in the sample (RV (FM sample)) with the RV of the decane peak in the narrow standard calibration (RV (FM calibrated)). Any change in the decane marker peak at that time was then assumed to be related to a linear shift in the flow rate (Flow (effective)) throughout the run. To facilitate the highest accuracy of the RV measurement of the flow marker peaks, the peaks of the flow marker concentration chromatogram were fitted to a quadratic equation using a least squares fitting routine. The first derivative of the quadratic equation was then used to determine the true peak position. After calibrating the system based on the flow marker peaks, the effective flow rate (relative to the narrow standard calibration) was calculated as in Equation 7. Processing of the flow marker peaks was performed by PolymerChar GPCOne™ software. An acceptable flow correction is that the effective flow should be within + / - 1% of the nominal flow: Flow (effective) = Flow (nominal) * (RV (FM calibrated) / RV (FM sample)) (Equation 7).

[0075] Dynamic mechanical spectroscopy (DMS) Small angle oscillatory shear was performed using a TA Instruments ARES equipped with 25 mm parallel plates under nitrogen purge. The time from sample loading to the start of testing was set to 5 min for all samples. Experiments were performed at 190 °C over a frequency range of 0.1-100 rad / s. Strain amplitude was adjusted from 1-3% based on the sample response. The stress response was analyzed in terms of amplitude and phase, from which the storage modulus (G'), loss modulus (G"), dynamic viscosity (η*), and loss tangent could be calculated. Specimens for dynamic mechanical spectroscopy were compression molded disks of 25 mm diameter x 3.3 mm thickness formed at 180 °C and 100 bar molding pressure for 5 min, then quenched (15-20 °C) between cooling platens for 2 min. Viscosity (V0.1, V100) and rheological ratio (V0.1 / V100 or RR) at 190 °C, respectively, were recorded.

[0076] Mooney Viscosity of Polymer Composition The Mooney viscosity (ML1+4) and Mooney stress relaxation (ML1+4+3) of each compounded polymer composition were recorded using an Alpha Technologies MV2000E viscometer according to ASTM D1646 at 100°C (large rotor). The preheat time was 1 minute and the rotor run time was 4 minutes. The viscosity of each compounded composition was measured using approximately 25 grams of uncured sheet (see Experimental Section).

[0077] Mooney Viscosity of Polymers Mooney Viscosity (ML1+4 at 125° C.) was measured according to ASTM 1646 with a 1 minute preheat time and a "4 minute" rotor run time. The instrument was an Alpha Technologies Mooney Viscometer 2000. Sample size was approximately 25 grams.

[0078] Curing kinetics - MDR Cure properties were measured at 180°C, 0.5 deg arc according to ASTM D5289 using an Alpha Technologies Moving Die Rheometer (MDR) 2000 E. Test time was 30 minutes. Samples (6-8 grams) were cut from each uncured sheet (see Experimental Section). Values ​​reported were ts2 (time to reach a "2 unit" increase in torque from ML), t90 (time to reach 90% of maximum cure), MH (maximum viscosity or maximum cure), and ML (minimum viscosity).

[0079] Mooney scorch was measured according to ASTM D-1646 using an Alpha Technologies Mooney Viscometer 2000. The Mooney Viscometer was set at 125°C and Mooney scorch values ​​were reported for a small rotor and indicated the time to increase "x Mooney units (or torque units)" above the minimum viscosity (torque) (e.g., t3 is the time required to increase the viscosity by "3 torque units"). The total test time was 30 minutes, including a 1 minute preheat time. The viscosity of each composition was measured from the respective uncured sheets cured in the viscometer so that scorch properties could be determined. Samples were conditioned at room temperature for 24 hours before testing.

[0080] Tensile strength Tensile properties were measured according to ASTM D412 using a Zwick Roell Z010 device. Each dumbbell specimen (type 5A) was cut from a compression molded (cured) plaque (t90+3 min, 180° C., 100 bar, ambient atmosphere, 2 mm thick plaque), see experimental section, where "t90" is the time for the specimen to reach 90% of its maximum cured value as measured by MDR. Tensile properties (tensile strength and elongation) were measured at room temperature in the machine direction according to method ASTM D-412, with a travel speed of 500 mm / min.

[0081] Trouser tear strength (or Die-T tear strength) Trouser tear strength was measured with a Zwick Roell Z010 device according to ASTM D624 Type-T (Trouser tear specimen) at a travel speed of 100 mm / min. Test specimens were cut from compression molded (cured) plaques (t90+3 min, 180° C., 100 bar, ambient atmosphere, 2 mm thick plaques). See experimental section.

[0082] Shore A hardness Shore A hardness was measured according to ASTM D2240 using 3-ply compression molded plaques (t90+3 min, 180° C., 100 bar, ambient atmosphere, (10 cm×10 cm×2 mm) plaques, total thickness 6 mm). See experimental section. Shore A hardness was measured on an INSTRON Shore A Durometer Model 2000 with a Durometer Stand Model 902. This method allows for hardness measurements based on initial indentation, indentation after a specific period of time, or both. Here, the indentation imprint was measured after a specified time of 3 seconds.

[0083] Optical microscope (porosity) Cross sections of the extruded profile samples (see Experimental Section) were examined with a ZEISS STEMI 2000-C Stereo Light Microscope operating with incident light. Digital images of the samples were acquired using a ZEISS AXIOCAM ICc 1 digital color camera. Each sample was prepared by sectioning using a razor blade.

[0084] Density of the cured polymer composition The density of each cured composition was determined according to Archimedes' law (ASTM B962-17). Each test specimen (approximately 10 grams) was cut from a compression molded (cured) plaque (t90+3 min, 180° C., 100 bar, ambient atmosphere, 2 mm thick plaque). See Experimental Section. Test specimens were immersed in isopropanol at room temperature, then dried and weighed.

[0085] Melt Index The melt index (I2) of ethylene-based polymers is measured according to ASTM D-1238, condition 190°C / 2.16 kg (melt index at 190°C / 5.0 kg (I5), melt index at 190°C / 10.0 kg (I10), high load melt index at 190°C / 21.0 kg (I21)). The melt flow rate (MFR) of propylene-based polymers is measured according to ASTM D-1238, condition 230°C / 2.16 kg.

[0086] Polymer Density Polymer density is measured according to ASTM D-297.

[0087] Volume resistivity The volume resistivity of compression molded sheets of each compounded composition (t90+3 min, 180° C., 100 bar, ambient atmosphere, 2 mm thick plaques, see experimental section) was measured according to DIN IEC 93. The sample dimensions were 10 cm×10 cm×2 mm. The measurements were performed after 1 min with an applied voltage of 10 V.

[0088] FTIR Method for EPDM Composition Analysis EPDM terpolymers containing ethylene, propylene, and 5-ethylidene-2-norbornene were analyzed using ASTM D3900 for ethylene content and ASTM D6047 for ethylidene-norbornene content.

[0089] Compression set Compression set was measured according to ASTM D395 at 23°C, 70°C, and 100°C for 22 hours. 29mm diameter, 2mm thick disks were punched from the compression molded plaques (180°C, 100 bar, t90+9min, ambient atmosphere, 2mm thick). See experimental section. Each button sample was inspected for notches, uneven thickness, and non-uniformity, and selected buttons (without these defects) were tested. Compression set was performed on two specimens of each sample at the specified temperature, and the average result of the two specimens was reported. The button samples were placed in a compression device that had two metal plates that could be pressed together and locked into place at 25% of the original height of the button sample. The compression device, along with the sample to be compressed, was then placed in an oven and allowed to equilibrate at the appropriate temperature for the specified time (22 hours at 23°C, 70°C, or 100°C). In this test, the stress is released at the test temperature and the thickness of the sample is measured after an equilibration time of 30 minutes at room temperature. Compression set is a measure of the recovery of the sample after compression and is calculated according to the formula CS=(H0-H2) / (H0-H1), where H0 is the original thickness of the sample, H1 is the thickness of the spacer bar used, and H2 is the final thickness of the sample after the compression force is removed.

[0090] experiment Film Polymers and Additives The polymers and additives used in this study were as follows: NORDEL EPDM 5565 having a Mooney viscosity of 65 (ML1+4, 125°C), a density of 0.86 g / cc, a weight percent of ethylene (C2) of 50% (ASTM D3900), and a weight percent of ENB of 7.5% (ASTM D6047). Available from the Dow Chemical Company. NORDEL EPDM 4725P having a Mooney viscosity of 25 (ML1+4, 125°C), a density of 0.88 g / cc, a weight percent ethylene (C2) of 70% (ASTM D3900), and a weight percent ENB of 4.9% (ASTM D6047). Available from The Dow Chemical Company. SPHERON 6000A carbon black available from Cabot Corporation. SUNPAR 2280-Plasticizer / Paraffinic Oil available from RE Carroll, Inc. RHENOGRAN ZnO-70-curing activator available from Rhein Chemie. Stearic Acid - Curing activator and processing aid available from Loxiol. RHENOGRAN CaO-80 - Desiccant available from RheinChemie. CARBOWAX PEG 4000-Processing aid (polyethylene glycol) available from The Dow Chemical Company. STRUKTOL W33-Dispersant available from Struktol. RHENOGRAN RETARDER E-80 - Curing retarder available from Rhein Chemie RHENOGRAN MBTS-70 - Curing accelerator available from Rhein Chemie RHENOGRAN ZBEC-70 - Curing accelerator available from Rhein Chemie. RHENOGRAN TP-50 - cure accelerator available from Rhein Chemie. RHENOGRAN CBS-80 - delayed action accelerator available from Rhein Chemie. RHENOGRAN CLD-80-sulfur donor available from Rhein Chemie. RHENOGRAN S-80-hardener available from Rhein Chemie. OMYA BSH-Coated Calcium Carbonate, available from Omya. POLESTAR 200R - White filler available from Imerys Kaolin. SILFIT Z91-white filler available from Hoffmann Mineral GmbH. SILLITIN Z86-white filler available from Hoffmann Mineral GmbH. AKTIFIT PF111-white filler available from Hoffmann Mineral GmbH. AKTISIL PF216-white filler available from Hoffmann Mineral GmbH. AKTISIL EM-white filler available from Hoffmann Mineral GmbH. AKTIFIT AM-white filler available from Hoffmann Mineral GmbH.

[0091] Table 1 below provides further description regarding the white filler, and Table 2 below provides further description regarding the polymer. [Table 1] [Table 2]

[0092] Polymer Composition The blended polymer compositions are listed in Table 3 below. [Table 3]

[0093] Each composition (see Table 3) was mixed in a HARBURG FREUDENBERGER internal mixer equipped with intermeshing rotors using the standard "upside-down" mixing procedure, with all additives added followed by the first interpolymer (EPDM) and the second interpolymer (EPDM). The "1.5 L net chamber" was filled to a 75% fill level. The rotor speed was kept constant at 45 RPM during the mix cycle. The feed temperature was 50°C, and the final composition was mixed for 200 seconds or until a drop temperature of 110°C was reached, whichever was earlier. The compositions were then homogenized on a two-roll mill (60°C) for 3 minutes and then sheeted to form green sheets (2 mm thick). The rheological properties of each compounded composition are shown in Table 4.

[0094] Garvey Die Extrusion - Extrusion Profiles Garvey die extrusion was carried out using a THERMO HAAKE POLYLAB system associated with a HAAKE RHEOMEX104. The barrel was heated to 80° C. and the extruder was operated at a rotation speed of 50 RPM. Each compounded polymer composition was extruded through an ASTM extrusion Garvey die according to ASTM D2230. The die temperature was set at 100° C. The extruded profiles were further cured in a hot air oven at 220° C. for 5 minutes.

[0095] Compression Molded Plaque The mechanical properties (hardness, tensile, tear, compression set) of the cured polymer compositions were measured from compression molded plaques. For each compounded composition, a sample of uncured sheet (see above) was compression molded using a PHI (100 ton press) according to ASTM D3182. The desired mold (10 cm x 10 cm x 2 mm) was placed on the platens. Samples (uncured sheets) were cut slightly smaller than the dimensions of the individual mold cavities. The mill orientation was marked and the sample was labeled. The sample was placed into the preheated mold, taking care to properly position the mill orientation. The platens were closed. The mold pressure was 100 bar, the temperature was 180°C, and ambient atmosphere. Cure times were specified, for example, as t90+3 minutes, where "t90" is the time it takes for the sample to reach 90% of maximum cure (MH) as determined by the MDR. At the end of the specified cure time, the bottom platen automatically opened. The samples were removed and immediately placed in water to stop the cure. Samples were conditioned at room temperature for 24 hours before testing.

[0096] Table 4 below shows the mechanical, curing, rheological, electrical and porosity properties for each composition. The compositions of the present invention were found to have high volume resistivity, low compression set, high elongation and virtually no porosity in extruded profiles. These compositions also had excellent curing properties and good overall mechanical properties. [Table 4]

Claims

1. 1. A composition comprising: a) 16.0 to 20.0 wt %, based on the weight of the composition, of a first ethylene / alpha-olefin / non-conjugated polyene interpolymer having a Mooney viscosity (ML1+4, 125° C.) of ≧50, as measured in accordance with ASTM D-1646; b) 7.0 to 9.0 wt. %, based on the weight of the composition, of a second ethylene / alpha-olefin / non-conjugated polyene interpolymer having a Mooney viscosity (ML1+4, 125° C.) of <50, as measured in accordance with ASTM D-1646; c) a calcined filler formed from a filler composition comprising kaolinite and silica; The weight ratio of said sintered filler to said composition is 0.25 to 0.

30.

2. The composition of claim 1 , wherein the composition further comprises carbon black.

3. 3. The composition of claim 2, wherein the weight ratio of said carbon black to said calcined filler is ≦1.

00.

4. 4. The composition according to claim 1, wherein the composition has a Rheology Ratio (RR) (V0.1(0.1 rad / s, 190° C.) / V100(100 rad / s, 190° C.)) of ≧40.

5. The composition of any one of claims 1 to 4, wherein the second ethylene / alpha-olefin / non-conjugated polyene interpolymer has a Mooney viscosity (ML1+4, 125°C) of 28 to <50, measured according to ASTM D-1646.

6. A crosslinked composition formed from the composition of any one of claims 1 to 5.

7. An article comprising at least one component formed from the composition of any one of claims 1-5.

8. The article of claim 7 , wherein the article is an extrusion molded, injection molded, or thermoformed article.

Images