Eyeglass lenses

Abstract

The present invention provides an eyeglass lens having an excellent brightening effect. This eyeglass lens comprises a lens substrate, and a resin layer disposed on the lens substrate. The resin layer contains a compound represented by formula (A), and a resin. The resin contains a repeating unit 1 derived from silsesquioxane having a polymerizable group, and a repeating unit 2 derived from a monofunctional monomer. The mass ratio of the repeating unit 1 to the repeating unit 2 is 60 / 40 to 95 / 5. The transmittance of the eyeglass lens is 65% to 80% at a wavelength of 556 nm.

Description

[Technical Field]

[0001] This disclosure relates to eyeglass lenses. [Background technology]

[0002] Patent Document 1 discloses a photochromic curable composition characterized by containing a silsesquioxane component (A1) having a radical polymerizable group and a bifunctional radical polymerizable monomer (A2) represented by general formula (1) as a radical polymerizable component (A), and further containing a photochromic compound (B). [Prior art documents] [Patent Documents]

[0003] [Patent Document 1] International Publication No. 2013 / 008825 [Overview of the project]

[0004] This disclosure relates to an eyeglass lens having a lens substrate and a resin layer disposed on the lens substrate, wherein the resin layer comprises a compound represented by formula (A) and a resin, the resin comprises repeating unit 1 derived from silsesquioxane having polymerizable groups and repeating unit 2 derived from a monofunctional monomer, the mass ratio of repeating unit 1 to repeating unit 2 is 60 / 40 to 95 / 5, and the transmittance of the eyeglass lens at a wavelength of 556 nm is 65 to 80%. [Brief explanation of the drawing]

[0005] [Figure 1] This is an example showing a cross-section of an eyeglass lens. [Modes for carrying out the invention]

[0006] The eyeglass lenses described herein will be described in detail below. The eyeglass lenses of this disclosure exhibit excellent brightening effects due to their transmittance at a wavelength of 556 nm being within a predetermined range. The brightening effect refers to at least one of the following effects: when a subject wears glasses having spectacle lenses, for example, in a room where the photosensitive light is not substantially irradiated, the observed object appears brighter and clearer (in particular, the vividness of red is not lost and red appears brighter), and white (for example, the white screen of a personal computer (especially an LED backlight)) appears whiter. In addition, the spectacle lens of the present disclosure has its color tone reduced by the irradiation of the photosensitive light and becomes closer to colorless.

[0007] In this specification, "~" means including the numerical values described before and after it as the lower limit value and the upper limit value. In this specification, "(meth)acrylic" is a concept including both acrylic and methacrylic, and "(meth)acryloyl group" is a concept including both acryloyl group and methacryloyl group. In this specification, ultraviolet light means light having a wavelength of 100 to 400 nm. Visible light means light having a wavelength of 380 to 780 nm. Infrared light means light having a wavelength of 780 nm to 1000 nm. In this specification, the transmittance can be measured, for example, using a spectrophotometer (U-4100, manufactured by Hitachi, Ltd.).

[0008] In this specification, the solid content is a component other than the solvent, and even if the property of the component is liquid at normal temperature and pressure (25°C, 101.3 kPa), it is calculated as the solid content. Also, the solid content may be a component that undergoes a chemical change during the curing process.

[0009] Figure 1 is a cross-sectional view of an embodiment of a spectacle lens. The spectacle lens 10 shown in Figure 1 has a lens substrate 12 and a resin layer 14 disposed on the lens substrate 12. In FIG. 1, the resin layer 14 is arranged to be in direct contact with the lens substrate 12, but this form is not limited, and other layers (for example, a primer layer or the like) may be arranged between the lens substrate 12 and the resin layer 14. That is, the resin layer 14 may be directly arranged on the lens substrate 12, or may be indirectly arranged on the lens substrate 12 via other layers. Also, in FIG. 1, the resin layer 14 is arranged on one side of the lens substrate 12, but the resin layer 14 may be arranged on both sides of the lens substrate 12.

[0010] [Eyeglass lens] It has a lens substrate and a resin layer arranged on the lens substrate. It is preferable that the transmittance of the eyeglass lens at a wavelength of 556 nm increases by irradiation with light (hereinafter also referred to as "specific light") to which the compound represented by formula (A) (hereinafter also referred to as "compound A") is sensitive. The compound A contained in the resin layer is a compound having a characteristic that it weakly exhibits red before irradiation with specific light and decolorizes or further weakly exhibits red after irradiation with specific light. Therefore, when specific light is irradiated to the eyeglass lens, the compound A decolorizes or further weakly exhibits red, so that the eyeglass lens also undergoes the same color change as the compound A, and as a result, the transmittance of the eyeglass lens at a wavelength of 556 nm can increase. In addition, when the eyeglass lens after irradiation with specific light is stored without irradiation with specific light, it gradually returns to the state before irradiation with specific light. That is, the color change of the eyeglass lens by specific light can occur reversibly.

[0011] The specific light is light to which the compound A is sensitive. The light to which the compound A is sensitive means light that causes a structural change in the compound A when irradiated to the compound A. Specifically, the compound A is a compound that can change its structure from a closed-ring form to an open-ring form by irradiation with specific light, and along with this structural change, it is a reverse photochromic compound whose color fades. The specific light is not particularly limited as long as it causes a change in the chemical structure of the compound A (for example, an open-ring reaction), and examples include ultraviolet light, visible light, and infrared light, with ultraviolet light being preferable. For example, when the specific light is ultraviolet light, the spectacle lens of the present disclosure can obtain a brightening effect indoors where the ultraviolet light is not substantially irradiated. On the other hand, outdoors where the ultraviolet light is irradiated, the spectacle lens can be used as a normal non-tinted spectacle lens because it fades.

[0012] The transmittance of the spectacle lens at a wavelength of 556 nm is 65 - 80%. The above transmittance is 65 - 80%, preferably 67 - 80%, and more preferably 68 - 79%. Note that the transmittance of the spectacle lens at a wavelength of 556 nm is measured using the spectacle lens after leaving it under a fluorescent lamp indoors for 30 minutes. In the above environment, the structural change of compound A from the cyclic form to the open-chain form does not proceed. That is, the transmittance of the spectacle lens at a wavelength of 556 nm means the transmittance in the state where compound A is in the cyclic form.

[0013] When the spectacle lens is irradiated with a halogen lamp at an illuminance of 90 W / cm 2 for 240 seconds, the difference (ΔT) in the average transmittance before and after irradiation in each wavelength range preferably satisfies at least one of the following formulas (1) to (4), and more preferably satisfies at least the relationship of formula (3). Hereinafter, the irradiation with the above halogen lamp at an illuminance of 90 W / cm 2 for 240 seconds is referred to as specific irradiation. ΔT1 = T 12 - T 11 Formula (1) ΔT2 = T 22 - T 21 Formula (2) [[ID=三十]]ΔT3 = T 32 - T 31 Formula (3) ΔT4 = T 42 - T 41 Formula (4)

[0014] The average transmittance in the wavelength range of 380 - 780 nm of the spectacle lens before specific irradiation is T 11(%) is used to express the average transmittance of eyeglass lenses in the wavelength range of 380-780 nm after specific irradiation as T 12 When expressed as (%), it is preferable that the eyeglass lens satisfies the relationship in equation (1). T 11 The percentage is preferably 70-90%, and more preferably 72-87%. 12 The percentage is preferably 80-90%, and more preferably 85-90%. ΔT1 is preferably 2.0 to 20.0%, and more preferably 2.0 to 18.0%. The average transmittance of the spectacle lens in the wavelength range of 380-780 nm before specific irradiation was measured using the spectacle lens after it had been left under fluorescent lighting indoors for 30 minutes, similar to the measurement of the transmittance of the spectacle lens at a wavelength of 556 nm mentioned above.

[0015] The average transmittance of eyeglass lenses in the wavelength range of 430-470 nm before specific irradiation is defined as T. 21 (%) is used to express the average transmittance of eyeglass lenses in the wavelength range of 430-470 nm after specific irradiation as T 22 When expressed as (%), it is preferable that the eyeglass lens satisfies the relationship in equation (2). T 21 The percentage is preferably 75-90%, and more preferably 84-90%. 22 The percentage is preferably 82-90%, and more preferably 85-90%. ΔT2 is preferably 0.0 to 6.0%, and more preferably 0.0 to 3.0%. The average transmittance of the spectacle lens in the wavelength range of 430-470 nm before specific irradiation was measured using the spectacle lens after it had been left under a fluorescent light in a room for 30 minutes, similar to the measurement of the transmittance of the spectacle lens at a wavelength of 556 nm mentioned above.

[0016] The average transmittance of eyeglass lenses in the wavelength range of 530-570 nm before specific irradiation is defined as T. 31 (%) is used to express the average transmittance of eyeglass lenses in the wavelength range of 530-570 nm after specific irradiation as T 32When expressed as (%), it is preferable that the eyeglass lens satisfies the relationship in equation (3). T 31 The percentage is preferably 70-90%, and more preferably 72-87%. 32 The percentage is preferably 80-90%, and more preferably 85-90%. ΔT3 is preferably 7.0 to 20.0%, and more preferably 7.0 to 18.0%. The average transmittance of the spectacle lens in the wavelength range of 530-570 nm before specific irradiation was measured using the spectacle lens after it had been left under fluorescent lighting indoors for 30 minutes, similar to the measurement of the transmittance of the spectacle lens at a wavelength of 556 nm mentioned above.

[0017] The average transmittance of eyeglass lenses in the wavelength range of 630-670 nm before specific irradiation is defined as T. 41 (%) is used to express the average transmittance of eyeglass lenses in the wavelength range of 630-670 nm after specific irradiation as T 42 When expressed as (%), it is preferable that the eyeglass lens satisfies the relationship in equation (4). T 41 The percentage is preferably 80-92%, and more preferably 85-92%. 42 The percentage is preferably 85-92%, and more preferably 87-92%. ΔT4 is preferably 0.0 to 7.0%, and more preferably 0.0 to 4.0%. The average transmittance of the spectacle lens in the wavelength range of 630-670 nm before specific irradiation was measured using the spectacle lens after it had been left under a fluorescent light indoors for 30 minutes, similar to the measurement of the transmittance of the spectacle lens at a wavelength of 556 nm mentioned above.

[0018] Methods for adjusting the above ΔT1 to ΔT4 values ​​include, for example, adjusting the content of compound A relative to the total mass of the resin layer and the thickness of the resin layer.

[0019] The following details the various components that may be included in eyeglass lenses.

[0020] <Lens substrate> Eyeglass lenses have a lens base material. Examples of lens substrates include those made from organic or inorganic materials, with lens substrates made from inorganic materials (e.g., glass substrates) being preferred. Examples of lens substrates include finished lenses in which both the convex and concave surfaces are optically finished and molded to the desired prescription, semi-finished lenses in which only the convex surface is finished as an optical surface (e.g., spherical, rotationally symmetric aspherical, and progressive surfaces), and semi-finished lenses in which the concave surface is processed and polished according to the wearer's prescription. Examples of organic materials include resins, specifically (meth)acrylic resins, thiourethane resins, allyl resins, episulfide resins, polycarbonate resins, polyurethane resins, polyester resins, polystyrene resins, polyethylene sulfone resins, poly-methylpentene-1 resins, and diethylene glycol bisallyl carbonate resins (CR-39). Examples of inorganic materials include silicon, ceramics, and glass, with glass being preferred.

[0021] For ease of handling, the thickness of the lens substrate is often between 1 and 30 mm.

[0022] The transmittance of the lens substrate at a wavelength of 556 nm is preferably 80% or higher, and more preferably 90% or higher. The upper limit may be less than 100%.

[0023] <Resin layer> Eyeglass lenses have a resin layer disposed on a lens substrate. The resin layer contains compound A and resin X, which will be described later.

[0024] (The compound represented by formula (A)) Compound A exhibits a weak red color before irradiation with a specific light, and either disappears or exhibits an even weaker red color after irradiation with that specific light. In other words, eyeglass lenses having a resin layer containing compound A exhibit a weak red color before irradiation with a specific light, and either disappears or exhibits an even weaker red color after irradiation with that specific light. Because it exhibits a weak red color before irradiation with that specific light, a brightening effect is easily obtained. The resin layer may also contain other dyes if it contains compound A.

[0025] [ka]

[0026] In formula (A), R represents a methyl group, a methoxy group, or a dialkylamino group. n represents an integer from 0 to 5. The alkyl group constituting the dialkylamino group may be linear, branched, or cyclic. The number of carbon atoms in the alkyl group is preferably 1 to 10. For n, an integer between 0 and 2 is preferred, and 0 is more preferred. If there are multiple Rs, they may be the same or different.

[0027] Compound A may be used alone or in combination of two or more compounds. The content of compound A is preferably 0.01 to 20% by mass, more preferably 0.05 to 10% by mass, and even more preferably 1 to 5% by mass, relative to the total mass of the resin layer.

[0028] (Resin X) The resin layer contains resin X. Resin X contains repeating unit 1 derived from silsesquioxane having polymerizable groups and repeating unit 2 derived from a monofunctional monomer, with the mass ratio of repeating unit 1 to repeating unit 2 being 60 / 40 to 95 / 5. The mass ratio of repeating unit 1 to repeating unit 2 (mass of repeating unit 1 / mass of repeating unit 2) is preferably 60 / 40 to 80 / 20, and more preferably 60 / 40 to 70 / 35. The content of repeating unit 1 is preferably 10 to 90% by mass, more preferably 30 to 80% by mass, and even more preferably 50 to 70% by mass, relative to the total repeating units of the resin. The content of repeating unit 2 is preferably 10 to 90% by mass, more preferably 20 to 70% by mass, and even more preferably 30 to 50% by mass, relative to the total repeating units of the resin.

[0029] Repeating unit 1 is a repeating unit derived from silsesquioxane having polymerizable groups. In other words, repeating unit 1 is a repeating unit obtained by polymerizing silsesquioxane having polymerizable groups. Examples of polymerizable groups include radical polymerizable groups and cationic polymerizable groups. Examples of radical polymerizable groups include (meth)acryloyl groups. Examples of cationic polymerizable groups include epoxy groups, alicyclic ether groups such as oxetanyl groups, cyclic acetal groups, cyclic lactone groups, cyclic thioether groups, spiroorthoester groups, and vinyloxy groups. As the polymerizable group, a radical polymerizable group is preferred, and a (meth)acryloyl group is more preferred. The number of polymerizable groups in silsesquioxane may be one or two or more.

[0030] Silsesquioxane is a silane compound obtained by hydrolyzing trifunctional silane compounds such as alkoxysilanes, chlorosilanes, and silanols. Examples of silsesquioxane structures include irregular forms such as random structures, ladder structures, cage-type (fully condensed cage) structures, and incomplete cage-type structures (partially cleaved cage-type structures in which some silicon atoms are missing from the cage-type structure, and structures in which some silicon-oxygen bonds in the cage-type structure are broken).

[0031] As a silsesquioxane having polymerizable groups, a silane compound having a basic skeleton represented by formula (Q) is preferred.

[0032] R Q -SiO3 / 2 (Q) In formula (Q), R Q R represents a monovalent organic group. Q At least one of these represents a polymerizable group. The polymerizable groups are as described above.

[0033] Examples of silsesquioxanes include the SQ series (e.g., AC-SQ series and MAC-SQ series, manufactured by Toagosei Co., Ltd.).

[0034] Repeating unit 1 may be used alone or in combination of two or more types.

[0035] Repeating unit 2 is a repeating unit derived from a monofunctional monomer. In other words, repeating unit 2 is a repeating unit obtained by polymerizing a monofunctional monomer. A monofunctional monomer is a monomer that has one polymerizable group. Examples of the polymerizable groups mentioned above include the groups exemplified above as polymerizable groups of silsesquioxane, with radical polymerizable groups being preferred and (meth)acryloyl groups being more preferred. Monofunctional monomers may have functional groups other than polymerizable groups. Examples of monofunctional monomers include ethylene glycol monoethyl ether methacrylate, (meth)acrylic acid, 2-(2-ethoxyethoxy)ethyl acrylate, methoxypolyethylene glycol monoacrylate, methoxypolyethylene glycol monomethacrylate, phenoxypolyethylene glycol acrylate, 2-acryloyloxyethyl succinate, 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, tetrahydrofurfuryl acrylate, 2-ethylhexyl carbitol acrylate, 3-methoxybutyl acrylate, benzyl acrylate, cyclohexyl acrylate, isoamyl acrylate, isobutyl acrylate, methoxytriethylene glycol acrylate, phenoxytetraethylene glycol acrylate, cetyl acrylate, isostearyl acrylate, stearyl acrylate, and styrene monomer. As the monofunctional monomer, monofunctional acrylate monomers are preferred.

[0036] Repeating unit 2 may be used alone or in combination of two or more types.

[0037] Resin X may be used alone or in combination of two or more types. The content of resin X is preferably 80 to 99.99% by mass, more preferably 85 to 99.95% by mass, and even more preferably 90 to 99% by mass, relative to the total mass of the resin layer.

[0038] The resin layer may contain other components besides compound A and resin X. Other components include, for example, pH adjusters, surfactants, viscosity modifiers, and leveling agents.

[0039] The thickness of the resin layer is preferably 1 to 150 μm, more preferably 2 to 40 μm, and even more preferably 5 to 25 μm.

[0040] <Other layers> Eyeglass lenses may have other layers besides the lens substrate and resin layer. Other layers include, for example, a primer layer and an anti-reflective layer.

[0041] (Primer layer) The primer layer is a layer that improves the adhesion of the resin layer to the lens substrate. The primer layer can be positioned, for example, between the lens substrate and the resin layer. Examples of materials that make up the primer layer include resins. Specifically, these include urethane resins, epoxy resins, phenolic resins, polyimide resins, polyester resins, bismaleimide resins, and polyolefin resins.

[0042] (Anti-reflection layer) The anti-reflective layer may have either a single-layer or multi-layer structure. An inorganic anti-reflective layer is preferred as the anti-reflective layer. An inorganic anti-reflective layer refers to an anti-reflective layer composed of an inorganic compound. The multilayer anti-reflective layer may have a structure in which low refractive index layers and high refractive index layers are alternately stacked. Examples of materials that make up the high refractive index layer include titanium, zircon, aluminum, niobium, tantalum, and lanthanum oxide. Examples of materials that make up the low refractive index layer include silica oxide.

[0043] [Manufacturing method for eyeglass lenses] Examples of methods for manufacturing eyeglass lenses include known manufacturing methods. Specifically, a method for manufacturing eyeglass lenses includes the step of applying a resin layer-forming composition onto a lens substrate and curing it. Examples of methods for applying resin layer-forming compositions include dip coating, roll coating, bar coating, spin coating, spray coating, die coating, and gravure coating.

[0044] One example of a curing method is exposure treatment. While there are no particular restrictions on the exposure light used in the exposure process, ultraviolet light is preferred. An example of an exposure light source is an electrodeless UV lamp.

[0045] The exposure treatment conditions can be selected based on the type of polymerization initiator used. The illuminance of the exposure light is 1 to 100 mW / cm². 2 It is preferable. The exposure time is preferably 5 to 60 seconds.

[0046] Furthermore, a drying process may be carried out, and heating may or may not be performed during the drying process. The heating time is preferably 10 to 180 minutes. The preferred heating temperature is 70 to 180°C.

[0047] <Composition for forming resin layer> A composition for forming a resin layer is a composition for forming a resin layer. The resin layer forming composition preferably contains compound A, a silsesquioxane having polymerizable groups, a monofunctional monomer, a polymerization initiator, and a solvent. Compound A, the polymerizable silsesquioxane, and the monofunctional monomer are as described in the section on the resin layer.

[0048] (Polymerization initiator) Examples of polymerization initiators include photopolymerization initiators and thermal polymerization initiators, and may also be radical polymerization initiators or photopolymerization initiators. Examples of polymerization initiators include Omnirad 127, 184, 907, 651, 1700, 1800, 819, 369 and TPO (manufactured by IGM Resins BV); DAROCUR 1173 (manufactured by Sigma-Aldrich); Ezacure KIP150 and TZT (manufactured by Nippon Siber Hegner Co., Ltd.); Kayacure BMS and Kayacure DMBI (manufactured by Nippon Kayaku Co., Ltd.); and Tinuvin 400, Tinuvin 405, Tinuvin 460, Tinuvin 477, Tinuvin 479 and Tinuvin 1577 (manufactured by BASF). Examples of cationic polymerization initiators include one or more cations selected from the group consisting of aromatic sulfonium, aromatic iodonium, aromatic diazonium, and pyridinium, and BF4 - , PF 6- SbF 6- AsF 6- CF3SO 3- , (CF3SO2)2N - and B(C6F5) 4- Examples include onium salts composed of one or more anions selected from the group consisting of; and thermal cationic polymerization initiators such as aluminum complexes like aluminum chloride. Polymerization initiators may be used individually or in combination of two or more. The polymerization initiator content is preferably 0.001 to 5% by mass, and more preferably 0.01 to 5% by mass, relative to the total solid content of the resin layer forming composition.

[0049] (solvent) Examples of solvents include alcohol-based solvents, ketone-based solvents, ether-based solvents, and ester-based solvents. Examples of ether-based solvents include diethyl ether, tetrahydrofuran, propylene glycol monobutyl ether, and propylene glycol monomethyl ether. An example of a ketone solvent is methyl ethyl ketone. An example of an ester solvent is butyl acetate. The solvent may be used alone or in combination of two or more types.

[0050] The resin layer forming composition may also contain other components that the resin layer may contain. [Examples]

[0051] The eyeglass lenses of this disclosure will be described in more detail below with reference to examples and comparative examples, but the eyeglass lenses of this disclosure are not limited in any way by these examples.

[0052] [Various ingredients] <Compound A> Compound A1 was synthesized according to the following scheme.

[0053] [ka]

[0054] First, we synthesized compounds A1-3, referring to Melmy et al., Photoswitching Using Visible Light: A New Class of Organic Photochromic Molecules, J. Am. Chem. Soc., 2014. Specifically, compound A1-2 (793 mg, 5.5 mmol) and water (40 mL) were mixed, and compound A1-1 (480 mg, 5 mmol) was added. The mixture was stirred at 75°C for 2 hours. After that, the resulting mixture was cooled to room temperature, filtered, and washed with cold water to obtain compound A1-3.

[0055] [ka]

[0056] Next, compound A1 was synthesized from compounds A1-3, referring to Hemmer et al, Tunable Visible and Near Infrared Photoswitches, J. Am. Chem. Soc., 2016. Specifically, the obtained compounds A1-3 (106 mg) and A1-4 (104 μL) were stirred at room temperature for 1 hour to obtain a mixture. The resulting mixture was filtered, the filtrate was washed with hexane, and then sonicated in tetrahydrofuran. After further dilution with diethyl ether and filtration again, compound A1 was obtained. Furthermore, the obtained compound A1 was diluted with tetrahydrofuran to the concentrations shown in the table below.

[0057] <Preparation of composition for resin layer formation> Various components shown in the table below were mixed to prepare each resin layer-forming composition. Note that "parts by mass" in "Compound A1" refers to parts by mass of the tetrohydrofuran solution containing Compound A1. Specifically, in Example 1, 10 parts by mass of a tetrohydrofuran solution containing 6% by mass of Compound A1 was used.

[0058] [Table 1]

[0059] MAC-SQ-HDM: A silsesquioxane with polymerizable groups, in a 50% by mass solution of propylene glycol monobutyl ether, manufactured by Toagosei Co., Ltd. EOEMA: Ethylene glycol monoethyl ether methacrylate AA: Acrylic acid • Compound A1: Compound A1 as described above • DAROCUR 1173: Manufactured by BASF

[0060] [Example 1] A plano-convex lens (Nikon-Essilor NL3-AS, 0.00D, refractive index 1.60) was used as the lens substrate 1. The resin layer-forming composition 1 was spin-coated onto the convex side of the lens substrate 1 at 200 rpm for 60 seconds, so that the thickness after drying was 5.7 μm. Next, the resulting coating was dried in an oven at 80°C for 20 minutes to obtain a sample. Furthermore, while the sample was being transported on a belt conveyor (transport speed 4 m / min), a FusionUV LightHammer 6 was used at 50% output (illuminance approximately 60 mW / cm²). 2 The coating film was exposed to light to produce the eyeglass lens of Example 1.

[0061] [Example 2, Comparative Examples 2-4] In Example 2 and Comparative Examples 2-4, the spectacle lenses were prepared using the same procedure as in Example 1, except that the resin layer forming composition was changed as shown in the table.

[0062] [Comparative Example 1] A spectacle lens of Comparative Example 1 was fabricated using the same procedure as in Example 1, except that a lens (Nikon-Essilor NL5-AS, refractive index 1.74) was used as the lens substrate 2, and resin layer forming composition 3 was used as the resin layer forming composition. Although the above lens was not curved, the shape of the lens did not affect the subsequent evaluation.

[0063] [evaluation] <Transmittance at a wavelength of 556nm> The transmittance of each obtained spectacle lens at a wavelength of 556 nm was measured using a spectrophotometer (U-4100, Hitachi). For the above measurement, the spectacle lenses were left under fluorescent lighting indoors for 30 minutes.

[0064] <Difference in transmittance (ΔT) before and after specific irradiation> First, the average transmittance of each spectacle lens in the wavelength ranges of 380-780 nm, 430-470 nm, 530-570 nm, and 630-670 nm was measured using a spectrophotometer (U-4100, Hitachi) before specific irradiation. For the above measurements, the spectacle lenses were left under fluorescent lighting indoors for 30 minutes. Next, using a slide projector (CABIN CS-15, manufactured by Iwasaki Electric Co., Ltd., using a halogen lamp), each spectacle lens was fixed 10 cm from the light source, and ultraviolet light was applied at 90 mW / cm². 2 The light was irradiated for 240 seconds. Subsequently, the average transmittance in each wavelength range after specific irradiation was measured using a spectrophotometer (U-4100, Hitachi), and the difference in average transmittance before and after specific irradiation in each wavelength range (ΔT1~ΔT4, the results are shown in the average ΔT column of the table) was determined.

[0065] <Brightening effect> Each of the obtained spectacle lenses was fitted into a frame, and a wear test was conducted with subjects aged 40 to 60, followed by a sensory evaluation. For the sensory evaluation, typical individuals aged 40-60 were selected as subjects, and in order to avoid preconceived notions, a blind test was conducted in which they wore eyeglasses using the lenses disclosed herein. A questionnaire was used to confirm whether colors appeared brighter and more vivid, and whether white appeared whiter. The brightening effect was evaluated according to the following evaluation criteria. Regarding whether colors appear brighter and more vivid, we surveyed participants about whether they perceived the white screen of their computer (especially when working with Excel files) as whiter. Regarding whether white appears whiter, subjects were asked to wear the above-mentioned glasses indoors and in dimly lit outdoor environments from evening to night, and to complete a questionnaire comparing their perceived brightness with that of untinted clear lenses. The untinted clear lenses are the lens substrates (lens substrate 1 or lens substrate 2) used in each of the eyeglass lenses in the examples and comparative examples. A: Unlike untinted clear lenses, there was at least one of the following effects: landscapes and objects (especially red) appeared vividly brighter in dimly lit environments, and the white screen of a computer appeared whiter. B: There was no difference compared to using undyed clear lenses; red appeared duller, and the white screen of the computer did not appear whiter.

[0066] The meaning of each entry in the table is explained below. The thickness of the resin layer was measured using a microspectrometer (USPM, manufactured by Olympus Corporation). The "X ratio" indicates the mass ratio of repeating unit 1 to repeating unit 2 (mass of repeating unit 1 / mass of repeating unit 2).

[0067] [Table 2]

[0068] As shown in Table 1, the spectacle lenses of this disclosure were confirmed to produce the desired effect. [Explanation of symbols]

[0069] 10 eyeglass lenses 12 Lens substrate 14 resin layer

Claims

1. Lens substrate and An eyeglass lens having a resin layer disposed on the lens substrate, The resin layer comprises a compound represented by formula (A) and a resin, The resin comprises repeating units 1 derived from silsesquioxane having polymerizable groups and repeating units 2 derived from monofunctional monomers. The mass ratio of repeating unit 1 to repeating unit 2 is 60 / 40 to 95 / 5. An eyeglass lens having a transmittance of 65-80% at a wavelength of 556 nm. 【Chemistry 1】 In formula (A), R represents a methyl group, a methoxy group, or a dialkylamino group. n represents an integer from 0 to 5.

2. The spectacle lens according to claim 1, wherein the transmittance at the aforementioned wavelength of 556 nm is 68 to 79%.

3. Using a halogen lamp, the illuminance is 90 W / cm². ２ The spectacle lens is irradiated for 240 seconds, and the average transmittance of the spectacle lens in the wavelength range of 530 to 570 nm before irradiation is measured to T ３１ (%), and the average transmittance of the spectacle lens in the wavelength range of 530 to 570 nm after irradiation is T ３２ When expressed as (%), ΔT is represented by equation (3). ３ The spectacle lens according to claim 1 or 2, wherein the content is 10-20%. ΔT ３ = T ３２ - T ３１ Equation (3)

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