Molded articles based on organic materials

Abstract

The presently claimed invention relates to a molded article based on organic material, comprising a compound of formula (1) and at least one anti-scratch agent. Furthermore, the molded article based on organic material is an interior or exterior material for an automobile.

Description

Technical Field

[0001] The present invention claimed herein relates to a molded article based on an organic material, comprising a compound of formula (1) and at least one anti-scratch agent. The present invention claimed herein further relates to a molded article based on an organic material, which is an interior or exterior material of an automobile.

Background Art

[0002] Organic materials such as polyolefins, polyethylene, polypropylene, i.e., synthetic polymers, are widely used because they can be easily used in the manufacture of various extruded and molded articles. However, these articles often face common stability problems when repeatedly exposed to UV light. Furthermore, current stabilization systems, i.e., anti-scratch agent-improved organic materials, show blooming / exudation when these molded articles are repeatedly exposed to UV light when used to prepare automotive articles. Blooming / exudation is undesirable because it can destroy the aesthetic surface properties of articles made from the blooming polymer. Blooming in articles where transparency is desired is particularly undesirable. Blooming is also undesirable because it reduces the ability to securely bond an article made from the blooming polymer to other articles by an adhesive. Blooming has been recognized as a serious problem in some applications, and effective means to mitigate it have been sought for many years.

[0003] Therefore, it is highly desirable to retain properties such as the stability of the polymer when exposed to UV light and reduce the tendency of the polymer to bloom.

Summary of the Invention

Problems to be Solved by the Invention

[0004] Therefore, an object of the present invention is to provide a molded article based on an organic material that is susceptible to oxidative, thermal or photo-induced decomposition.

[0005] Another object of the present invention is to provide an organic material-based molded article having a non-sticky surface and not exhibiting blooming / seepage from the organic material article. [Means for solving the problem]

[0006] Surprisingly, molded articles based on the organic material according to the claimed invention have been found to be susceptible to oxidative, thermal, or photo-induced decomposition. Molded articles based on the organic material according to the claimed invention have a non-sticky surface and a surface that does not exhibit blooming / seepage from the organic material article.

[0007] Therefore, in one aspect, the present invention claimed herein is i. Equation (1) [ka] The compound and ii. At least one type of anti-scratch agent and This relates to molded articles based on organic materials, including [specific material]. [Modes for carrying out the invention]

[0008] Before describing the compositions and formulations of the present invention, it should be understood that, since such compositions and formulations can naturally vary, the present invention is not limited to the specific compositions and formulations described. It should also be understood that, since the scope of the present invention as claimed herein is limited only by the appended claims, the terms used herein are not intended to be limiting.

[0009] Hereinafter, when a group is defined as including at least a certain number of embodiments, this preferably also means that the group consists only of these embodiments. Furthermore, terms such as “first,” “second,” “third,” or “(a),” “(b),” “(c),” and “(d)” in this specification and the claims are used to distinguish similar components and do not necessarily indicate a continuous or chronological order. Thus, it should be understood that the terms used in this manner are interchangeable under appropriate circumstances, and that the embodiments described herein can be implemented in an order other than that described or illustrated herein. Where terms such as “first,” “second,” “third,” or “(A),” “(B),” “(C),” or “(a),” “(b),” “(c),” “(d),” “i,” “ii” relate to a method, use, or step of an assay, unless otherwise specified in this application, there may be no time interval between these steps or the time intervals may be inconsistent, as described or described herein, i.e., these steps may be performed simultaneously or there may be time intervals of a few seconds, a few minutes, a few hours, a few days, a few months, a few weeks, or even a few years between such steps.

[0010] The following text provides more detailed definitions of different aspects of the present invention. Each of these defined aspects may be combined with any other aspect unless otherwise explicitly stated. In particular, any feature indicated as preferred or advantageous may be combined with any other feature indicated as preferred or advantageous.

[0011] In this specification, the phrase "one embodiment" or "preferred embodiment" means that certain features, structures, or characteristics described in relation to an embodiment are included in at least one embodiment of the claimed invention. Therefore, expressions such as "in one embodiment," "in a preferred embodiment," or "in another embodiment" appearing in various places in this specification do not necessarily all refer to the same embodiment, but may all refer to the same embodiment. Furthermore, certain features, structures, or characteristics may be combined in any suitable manner in one or more embodiments, as will be apparent to those skilled in the art from this disclosure. Furthermore, while some embodiments described herein include some, but other, features included in other embodiments, combinations of features from different embodiments mean that they fall within the scope of the invention and form different embodiments as will be understood by those skilled in the art. For example, any combination of any of the claimed embodiments may be used in the appended claims.

[0012] Furthermore, the ranges defined herein include the extreme values; that is, the range 1 to 10 means that both 1 and 10 are included within that range. To avoid any doubt, the applicant reserves the right to obtain any equivalents in accordance with applicable law.

[0013] To facilitate understanding of this disclosure, certain terms are defined first. Unless otherwise defined, all technical and scientific terms used herein have the same meaning as those generally understood by those skilled in the art in the field to which embodiments of the present invention relate.

[0014] In one embodiment, the present invention claimed herein is: i. Equation (1) [ka] The compound and ii. At least one type of anti-scratch agent and This relates to molded articles based on organic materials, including [specific material].

[0015] Examples of organic materials that can be stabilized are as follows:

[0016] 1. Polymers of monoolefins and diolefins, e.g., polypropylene, polyisobutylene, polybuta-1-ene, poly-4-methylpenta-1-ene, polyvinylcyclohexane, polyisoprene, or polybutadiene; polymers of cycloolefins, e.g., polymers of cyclopentene or norbornene; polyethylene (optionally crosslinkable), e.g., high-density polyethylene (HDPE), high-density and high-molecular-weight polyethylene (HDPE-HMW), high-density and ultra-high-molecular-weight polyethylene (HDPE-UHMW), medium-density polyethylene (MDPE), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), (VLDPE), and (ULDPE).

[0017] Polyolefins, i.e., the monoolefin polymers exemplified in the previous section, preferably polyethylene and polypropylene, can be prepared by various methods, particularly the following: a) Radical polymerization (usually under high pressure and high temperature). b) Catalytic polymerization using a catalyst usually containing one or more metals from Group IVb, Vb, VIb or VIII of the periodic table. These metals usually have one or more ligands, typically oxides, halides, alcoholates, esters, ethers, amines, alkyls, alkenyls and / or aryls, which can be either π- or σ-coordinated. These metal complexes can be in free form or immobilized on a substrate, typically activated magnesium chloride, titanium(III) chloride, alumina or silicon oxide. These catalysts can be soluble or insoluble in the polymerization medium. The catalyst can be used alone in the polymerization or a further activator can be used, typically a metal alkyl, metal hydride, metal alkyl halide, metal alkyloxide or metal alkyloxane, and the said metal is an element belonging to Group Ia, IIa and / or IIIa of the periodic table. The activator can be conveniently modified with a further ester group, ether group, amine group or silyl ether group. These catalyst systems are usually called Phillips, Standard Oil Indiana, Ziegler(-Natta), TNZ (DuPont), metallocene or single-site catalysts (SSC).

[0018] Mixtures of the polymers described in 2.1), for example mixtures of polypropylene and polyisobutylene, mixtures of polypropylene and polyethylene (e.g., PP / HDPE, PP / LDPE) and mixtures of different types of polyethylene (e.g., LDPE / HDPE).

[0019] 3. Copolymers of monoolefins and diolefins with each other or with other vinyl monomers, such as ethylene / propylene copolymers, linear low density polyethylene (LLDPE) and mixtures thereof with low density polyethylene (LDPE), propylene / but-1-ene copolymers, propylene / isobutylene copolymers, ethylene / but-1-ene copolymers, ethylene / hexene copolymers, ethylene / methylpentene copolymers, ethylene / heptene copolymers, ethylene / octene copolymers, ethylene / vinylcyclohexane copolymers, ethylene / cycloolefin copolymers (e.g., ethylene / norbornene, COC, etc.), ethylene / 1-olefin copolymers (the 1-olefin being generated in situ), propylene / butadiene copolymers, isobutylene / isoprene copolymers, ethylene / vinylcyclohexane copolymers, ethylene / alkyl acrylate copolymers, ethylene / alkyl methacrylate copolymers, ethylene / vinyl acetate copolymers, ethylene / acrylic acid copolymers and their salts (ionomers) and terpolymers of ethylene with dienes such as propylene and hexadiene, dicyclopentadiene or ethylidene norbornene and mixtures of such copolymers with each other and with the polymers of 1) above, such as polypropylene / ethylene-propylene copolymer, LDPE / ethylene-vinyl acetate copolymer (EVA), LDPE / ethylene-acrylic acid copolymer (EAA), LLDPE / EVA, LLDPE / EAA and alternating or random polyalkylene / carbon monoxide copolymers and their mixtures with other polymers, such as polyamides.

[0020] 4. Hydrocarbon resins (e.g., C5 - C9), such as hydrogenated modifications (e.g., tackifiers) and mixtures of polyalkylenes and starch.

[0021] 1.) - 4.) The homopolymers and copolymers may have any stereostructure including syndiotactic, isotactic, hemiisotactic or atactic, with atactic polymers being preferred. Stereoblock polymers are also included.

[0022] 5. Polystyrene, poly(p-methylstyrene), poly(α-methylstyrene).

[0023] 6. Aromatic homopolymers and copolymers derived from vinyl aromatic monomers, including all isomers of styrene, α-methylstyrene, and vinyltoluene, particularly p-vinyltoluene, all isomers of ethylstyrene, propylstyrene, vinyl biphenyl, vinylnaphthalene, and vinylanthracene, and mixtures thereof. The homopolymers and copolymers may have any stereostructure, including syndiotactic, isotactic, hemiisotactic, or atactic, with atactic polymers being preferred. Stereoblock polymers are also included.

[0024] 6a. Copolymers comprising the aforementioned vinyl aromatic monomers and comonomers selected from ethylene, propylene, diene, nitrile, acid, maleic anhydride, maleimide, vinyl acetate and vinyl chloride or acrylic derivatives and mixtures thereof. For example, styrene / butadiene, styrene / acrylonitrile, styrene / ethylene (interpolymer), styrene / alkyl methacrylate, styrene / butadiene / alkyl acrylate, styrene / butadiene / alkyl methacrylate, styrene / maleic anhydride, styrene / acrylonitrile / methyl acrylate; high impact strength mixtures of styrene copolymers with other polymers, such as polyacrylates, diene polymers, ethylene / propylene / diene interpolymers; and styrene block copolymers such as styrene / butadiene / styrene, styrene / isoprene / styrene, styrene / ethylene / butylene / styrene or styrene / ethylene / propylene / styrene.

[0025] Examples include hydrogenated aromatic polymers derived from the hydrogenation of polymers described in 6b.6, particularly polycyclohexylethylene (PCHE) prepared by the hydrogenation of atactic polystyrene, which is often called polycyclohexane (PVCH).

[0026] Hydrogenated aromatic polymers derived from the hydrogenation of polymers described in 6c.6a.).

[0027] Homopolymers and copolymers may have any stereostructure, including syndiotactic, isotactic, hemiisotactic, or atactic, with atactic polymers being preferred. Stereoblock polymers are also included.

[0028] 7. Graft copolymers of vinyl aromatic monomers such as styrene or α-methylstyrene, e.g., styrene on polybutadiene, styrene on polybutadiene-styrene, or polybutadiene-acrylonitrile copolymers; styrene and acrylonitrile (or methacrylonitrile) on polybutadiene; styrene, acrylonitrile, and methyl methacrylate on polybutadiene; styrene and maleic anhydride on polybutadiene; styrene, acrylonitrile, and maleic anhydride or maleimide on polybutadiene; styrene and maleimide on polybutadiene; styrene and alkyl acrylate or methacrylate on polybutadiene; styrene and acrylonitrile on ethylene / propylene / diene polymers; styrene and acrylonitrile on polyalkyl acrylate or polyalkyl methacrylate, styrene and acrylonitrile on acrylate / butadiene copolymers, and mixtures thereof with the copolymers described in 6), e.g., copolymer mixtures known as ABS, MBS, ASA, or AES polymers.

[0029] 8. Halogen-containing polymers, such as polychloroprene, chlorinated rubber, isobutylene-isoprene chlorinated and brominated copolymers (halobutyl rubber), chlorinated or sulfochlorinated polyethylene, copolymers of ethylene and chlorinated ethylene, epichlorohydrin homopolymers and copolymers, and especially polymers of halogen-containing vinyl compounds, such as polyvinyl chloride, polyvinylidene chloride, polyvinyl fluoride, polyvinylidene fluoride and their copolymers, such as vinyl chloride / vinylidene chloride, vinyl chloride / vinyl acetate, and vinyl chloride / vinyl acetate copolymers.

[0030] 9. Polymers obtained from α,β-unsaturated acids and their derivatives, such as polyacrylates, polymethacrylates, polymethyl methacrylates, polyacrylamides, and polyacrylonitriles, which are impact-modified with butyl acrylate.

[0031] Copolymers of monomers described in 10.9) with each other or with other unsaturated monomers, for example, acrylonitrile / butadiene copolymer, acrylonitrile / alkyl acrylate copolymer, acrylonitrile / alkoxyalkyl acrylate or acrylonitrile / halogenated vinyl copolymer or acrylonitrile / alkyl methacrylate / butadiene copolymer.

[0032] 11. Polymers derived from unsaturated alcohols and amines, or their acyl derivatives or acetals, such as polyvinyl alcohol, polyvinyl acetate, vinyl polystearate, polyvinyl polybenzoate, vinyl polymaleate, polybutyral, polyallyl phthalate, or polyallylmelamine, and copolymers thereof with the olefins of 1) above.

[0033] 12. Homopolymers and copolymers of cyclic ethers such as polyalkylene glycols, polyethylene oxides, and polypropylene oxides, or copolymers thereof with bisglycidyl ethers.

[0034] 13. Polyacetals such as polyoxymethylene and polyoxymethylene containing ethylene oxide as a comonomer; polyacetals modified with thermoplastic polyurethane, acrylate or MBS.

[0035] 14. Polyphenylene oxides and sulfides, and mixtures of polyphenylene oxide with styrene polymers or polyamides.

[0036] 15. Polyurethanes derived from hydroxyl-terminated polyethers, polyesters, or polybutadienes on the one hand, and from aliphatic or aromatic polyisocyanates on the other hand, and precursors thereof.

[0037] 16. Polyamides and copolyamides derived from diamines and dicarboxylic acids and / or aminocarboxylic acids or corresponding lactams, e.g., polyamide 4, polyamide 6, polyamide 6 / 6, 6 / 10, 6 / 9, 6 / 12, 4 / 6, 12 / 12, polyamide 11, polyamide 12, aromatic polyamides starting from m-xylylenediamine and adipic acid; polyamides prepared from hexamethylenediamine and isophthalic acid or / and terephthalic acid, with or without elastomers as modifiers, e.g., poly-2,4,4,-t Rimethylhexamethylene terephthalamide or poly-m-phenylene isophthalamide; and block copolymers of the aforementioned polyamides with polyolefins, olefin copolymers, ionomers, or chemically bonded or grafted elastomers; or block copolymers with polyethers, such as polyethylene glycol, polypropylene glycol, or polytetramethylene glycol; and polyamides or copolyamides modified with EPDM or ABS; and polyamides condensed during processing (RIM polyamide systems).

[0038] 17. Polyureas, polyimides, polyamide-imides, polyetherimides, polyesterimides, polyhydantoins, and polybenzimidazoles.

[0039] 18. Polyesters derived from dicarboxylic acids and diols and / or hydroxycarboxylic acids or corresponding lactones or lactides, such as polyethylene terephthalate, polybutylene terephthalate, poly-1,4-dimethylolcyclohexane terephthalate, polyalkylene naphthalate and polyhydroxybenzoate, and copolyether esters derived from hydroxyl-terminated polyethers, as well as polycarbonates and polyesters modified with MBS. Copolyesters include, for example, but are not limited to, polybutylene succinate / terephthalate, polybutylene adipate / terephthalate, polytetramethylene adipate / terephthalate, polybutylene succinate / adipate, polybutylene succinate / carbonate, poly-3-hydroxybutyrate / octanoate copolymer, and poly-3-hydroxybutyrate / hexanoate / decanoate copolymer. Furthermore, aliphatic polyesters may include, for example, but are not limited to, the class of poly(hydroxyalkanoates), particularly poly(propiolactone), poly(butyrolactone), poly(pivalolactone), poly(valerolactone), and poly(caprolactone), polyethylene succinate, polypropylene succinate, polybutylene succinate, polyhexamethylene succinate, polyethylene adipate, polypropylene adipate, polybutylene adipate, polyhexamethylene adipate, polyethylene oxalate, polypropylene oxalate, polybutylene oxalate, polyhexamethylene oxalate, polyethylene sebacate, polypropylene sebacate, polybutylene sebacate, and polylactic acid (PLA), as well as corresponding polyesters modified with polycarbonate or MBS.The term "polylactic acid (PLA)" preferably means homopolymers of poly-L-lactide and any blends or alloys with other polymers; copolymers of lactic acid or lactide with other monomers, e.g., hydroxycarboxylic acids, e.g., glycolic acid, 3-hydroxybutyric acid, 4-hydroxybutyric acid, 4-hydroxyvaleric acid, 5-hydroxyvaleric acid, 6-hydroxycaproic acid and their cyclic products; the term "lactic acid" or "lactide" includes L-lactic acid, D-lactic acid, mixtures thereof and dimers, i.e., L-lactide, D-lactide, D-lactide, D-lactide, D-lactide, D-lactide, i.e., L-lactide, D-lactide, meso-lactide and any mixtures thereof.

[0040] 19. Polycarbonate and polyester carbonate.

[0041] 20. Polyketones.

[0042] 21. Polysulfones, polyethersulfones, and polyetherketones.

[0043] 22. Crosslinked polymers derived from aldehydes on the one hand and phenol, urea, and melamine on the other, such as phenol / formaldehyde resins, urea / formaldehyde resins, and melamine / formaldehyde resins.

[0044] 23. Dry and non-dry alkyd resins.

[0045] 24. Unsaturated polyester resins derived from saturated and unsaturated dicarboxylic acids and individual polyesters using polyhydric alcohols and vinyl compounds as crosslinking agents, and halogen-containing modified products thereof, which have low flammability.

[0046] 25. Crosslinkable acrylic resins derived from substituted acrylates, such as epoxy acrylate, urethane acrylate, or polyester acrylate.

[0047] 26. Alkyd resins, polyester resins, and acrylate resins crosslinked with melamine resin, urea resin, isocyanate, isocyanurate, polyisocyanate, or epoxy resin.

[0048] 27. Products of diglycidyl ethers of bisphenol A and bisphenol F crosslinked with or without an accelerator using a crosslinked epoxy resin derived from aliphatic, alicyclic, heterocyclic, or aromatic glycidyl compounds, for example, with conventional curing agents such as anhydrides or amines.

[0049] 28. Natural polymers, such as cellulose, rubber, gelatin and chemically modified derivatives thereof, such as cellulose acetate, cellulose propionate and cellulose butyrate or cellulose ethers such as methylcellulose, as well as rosin and its derivatives.

[0050] 29. Blends of the aforementioned polymers (polyblends), such as PP / EPDM, polyamide / EPDM or ABS, PVC / EVA, PVC / ABS, PVC / MBS, PC / ABS, PBTP / ABS, PC / ASA, PC / PBT, PVC / CPE, PVC / acrylate, POM / thermoplastic PUR, PC / thermoplastic PUR, POM / acrylate, POM / MBS, PPO / HIPS, PPO / PA6.6 and copolymers, PA / HDPE, PA / PP, PA / PPO, PBT / PC / ABS or PBT / PET / PC.

[0051] 30. Natural and synthetic organic materials that are pure monomer compounds or mixtures thereof, such as mineral oils, animal and vegetable oils and waxes or oils and waxes based on synthetic esters (e.g., phthalates, adipates, phosphates or trimellites), as well as mixtures of synthetic esters and mineral oils in any weight ratio, typically used as spinning compositions, and aqueous emulsions of such materials.

[0052] 31. Aqueous emulsions of natural or synthetic rubber, e.g., natural latex or carboxylated styrene / butadiene copolymer latex.

[0053] Polyolefins, acrylonitrile / butadiene / styrene, polyvinyl chloride, polymethyl methacrylate, polyamides, or polyoxymethylenes are of particular interest.

[0054] In a preferred embodiment, the organic material is a thermoplastic elastomer.

[0055] Examples of thermoplastic elastomers include polyolefin thermoplastic elastomers and block copolymer type polystyrene thermoplastic elastomers. Polyolefin thermoplastic elastomers contain polyolefin resins such as polypropylene and polyethylene as hard segments and rubber compositions such as ethylene-propylene-diene-elastomer (EPDM) as soft segments. Block copolymer type polystyrene thermoplastic elastomers contain polystyrene as hard segments and polydienes such as polybutadiene or polyisoprene as soft segments.

[0056] Alternatively, a blend of polyolefin elastomer and polystyrene elastomer may also be used as the thermoplastic elastomer of the present invention. Methods for combining soft and hard segments in thermoplastic elastomers can be broadly classified into simple blends, copolymerization, and dynamic crosslinking. Combinations of segments in polystyrene thermoplastic elastomers include styrene-butadiene-styrene block copolymer (SBS), styrene-isoprene-styrene block copolymer (SIS), styrene-ethylenebutylene-styrene block copolymer (SEBS), styrene-ethylenepropylene-styrene block copolymer (SEPS), a hydrogenated polymer of any one of the four copolymers, a hydrogenated polymer of random SBR (HSBR), polypropylene, and blends with one or more members selected from these polymers (SBR = styrene-butadiene rubber).

[0057] Of particular interest are thermoplastic polyolefins, especially polyethylene or polypropylene containing a rubber phase based on ethylene and / or propylene.

[0058] In one embodiment, the anti-scratch agent is selected from the group consisting of unsaturated or saturated fatty acid amides, poly(organo)siloxanes, and mixtures thereof.

[0059] In preferred embodiments, the anti-scratch agent is selected from the group consisting of erucamide, oleamide, stearamide, and mixtures thereof.

[0060] In a more preferred embodiment, the anti-scratch agent is selected from erucamide, stearamide, or a mixture thereof.

[0061] The anti-scratch additive of the present invention is known to those skilled in the art.

[0062] They can be prepared in the same way as known methods. Most of them are commercially available.

[0063] Preferred commercially available poly(organo)siloxane anti-scratch additives are as follows: TEGOMER (registered trademark) AntiScratch 100, TEGOMER(registered trademark) M-Si 2650, TEGOPREN (registered trademark) 6846 TEGOMER (registered trademark) H-Si 6440 P, TEGOMER (registered trademark) AntiScratch 200, GENIOPLAST(registered trademark)S GENIOPLAST® Pellet P, and GENIOPLAST (registered trademark) Pellet P plus.

[0064] Preferred poly(organo)siloxane anti-scratch additives relate to mixtures of silicon and silicone polymers (e.g., 0-50% by weight, preferably 30% by weight of fumed silica and 50-0% by weight, preferably 70% by weight of silicone polymer).

[0065] A more preferred poly(organo)siloxane anti-scratch additive is, formula [ka] (In the formula, R is an alkyl, polyester residue, acrylate residue, epoxy, hydroxyalkyl, aminoalkyl, etc.) It is a compound of [the compound].

[0066] Another preferred anti-scratch additive is IRGASURF® SR 100.

[0067] In one embodiment, the weight ratio of the compound of formula (1) to at least one anti-scratch agent is in the range of 1:70 to 30:99.

[0068] In a preferred embodiment, the weight ratio of the compound of formula (1) to at least one anti-scratch agent is 1:98, or 2:98, or 2:97, or 3:97, or 4:96, or 4:95, or 5:95, or 5:94, or 6:94, or 6:93, or 7:93, or 7:92, or 6:92, or 6:91, or 5:91, or 5:90, or 6:90, or 6:89, or 7:89, or 7:88, or 8:88, or 8:87, or 9:87, or 9:86, or 10:86, or 10:85, or 11:85, or 11:84, or 12:84, or 12:83, or 13 :83, or 13:82, or 14:82, or 14:81, or 15:81, or 15:80, or 16:80, or 16:79, or 17:79, or 17:78, or 18:78, or 18:77, or 19:77, or 19:76, or 20:76, ​​or 20:75, or 21:75, or 21:76, or 22:76, or 22:75, or 23:75, or 23:74, or 24:74, or 24:73, or 25:73, or 25:72, or 26:72, or 26:71, or 27:71, or 27:70, or 28:70, or 29:70, or 30:70.

[0069] In a more preferred embodiment, the weight ratio of the compound of formula (1) to at least one anti-scratch agent is 5:91, or 5:90, or 6:90, or 6:89, or 7:89, or 7:88, or 8:88, or 8:87, or 9:87, or 9:86, or 10:86, or 10:85, or 11:85, or 11:84, or 12:84, or 12:83, or 13:83, or 13:82, or 14:82, or 14:81, or 15:81, or 15:80.

[0070] In the most preferred embodiment, the weight ratio of the compound of formula (1) to at least one anti-scratch agent is 10:86, or 10:85, or 11:85, or 11:84, or 12:84, or 12:83, or 13:83, or 13:82, or 14:82, or 14:81, or 15:81, or 15:80.

[0071] In one embodiment, the weight ratio of the organic material to the compound of formula (1) is in the range of 99.99:0.01 to 99.0:1.0.

[0072] In one embodiment, the weight ratio of the organic material to at least one anti-scratch agent is in the range of 99.99:0.01 to 98:2.

[0073] The compound of formula (1) and the anti-scratch agent can be added to the polymer material, for example, before, during, or after the polymerization or crosslinking of the material. Furthermore, they can be incorporated into the polymer material in their pure form or encapsulated in wax, oil, or polymer.

[0074] In general, the compound of formula (1) and the anti-scratch agent can be incorporated into organic materials together or individually by various processes, such as dry mixing in powder form, wet mixing in solution or suspension form, or in the form of a masterbatch containing the compound of formula (I) and / or the anti-scratch additive at a concentration of 0.01 to 70% by weight, preferably 0.01 to 50% by weight, and particularly 0.01 to 25% by weight. In such operations, the polymer can be used in the form of powder, granules, solution, suspension, or latex.

[0075] Examples of processing the compound of formula (1) and the scratch inhibitor together or individually into the organic material according to the present invention include: injection blow molding, extrusion molding, blow molding, rotational molding, in-mold decoration (back injection), slush molding, injection molding, co-injection molding, molding, compression molding, pressing, film extrusion (cast film; blow film), spinning (woven fabric, nonwoven fabric), stretching (uniaxial, biaxial), annealing, deep drawing, calendering, mechanical transformation, sintering, co Extrusion, coating, lamination, crosslinking (radiation, peroxide, silane), vapor deposition, welding, adhesives, vulcanization, thermoforming, pipe extrusion, profile extrusion, sheet extrusion; sheet casting, spin coating, strapping, foaming, recycling / rework, extrusion coating, screw breaking (peroxide, heat), fiber meltblown, spunbond, surface treatment (corona discharge, flame, plasma), sterilization (gamma ray, electron beam), gel coating, tape extrusion, SMC process or Plastisol.

[0076] The compound of formula (I) and the anti-scratch agent in combination or individually in organic materials according to the present invention can be advantageously used in the preparation of various molded articles. For example, the following:

[0077] I-1) Floating devices, marine applications, pontoons, buoys, plastic sheets for decks, piers, boats, kayaks, oars, and beach reinforcements.

[0078] I-2) Automotive applications, particularly bumpers, dashboards, batteries, rear and front linings, molded parts under the hood, hat shelves, trunk linings, interior linings, airbag covers, electronically molded parts for fittings (lights), panels for dashboards, headlamp glass, instrument panels, exterior linings, interiors, automotive lights, headlights, parking lights, taillights, stoplights, interior and exterior trim; door panels; gasoline tanks; front side glass; rear windows; seat backs, exterior panels, wire insulation, profile extrusions for sealing, cladding, pillar covers, chassis components, exhaust systems, fuel filters / fillers, fuel pumps, fuel tanks, body side molded parts, convertible tops, exterior mirrors, exterior trim, fasteners / fixtures, front end modules, glass, hinges, locking systems, luggage / roof racks, pressed / stamped parts, seals, side impact protection, soundproofing / insulation and sunroofs.

[0079] I-3) Road traffic devices, especially guideposts, road marking posts, car accessories, warning triangles, medical cases, helmets, and tires.

[0080] I-4) Devices for airplanes, trains, and automobiles (cars, motorcycles), including furnishings.

[0081] I-5) Devices for space applications, especially rockets and satellites, such as re-entry shields.

[0082] I-6) Devices for architecture and design, mining, acoustic equipment, street shelters and shelters.

[0083] II-1) Cases and covers for electrical appliances, general-purpose and electrical / electronic devices (personal computers, telephones, mobile phones, printers, televisions, audio and video devices), flower pots, satellite receivers and panel devices.

[0084] II-2) Jackets made of steel and other materials such as fibers.

[0085] II-3) Electronic industrial devices, especially plugs, especially insulating materials for computer plugs, cases for electrical and electronic components, printed circuit boards and chips, and materials for electronic data storage such as check cards or credit cards.

[0086] II-4) Electrical appliances, especially washing machines, tumblers, ovens (microwave ovens), dishwashers, mixers and irons.

[0087] II-5) Covers for lighting (e.g., streetlights, lampshades).

[0088] II-6) Applications in electric wires and cables (semiconductors, insulators, and cable jackets).

[0089] II-7) Foils for condensers, refrigerators, heating devices, air conditioners, sealing of electronic equipment, semiconductors, coffee makers, and vacuum cleaners.

[0090] III-1) Technical products such as gears, sliding fittings, spacers, screws, bolts, handles, and knobs.

[0091] III-2) Rotary blades, ventilation systems and wind turbine blades, solar cell systems, swimming pools, pool covers, pool liners, pond liners, closets, wardrobes, partition walls, slat walls, folding walls, roofs, shutters (e.g., roller shutters), fittings, connections between pipes, sleeves and conveyor belts.

[0092] III-3) Sanitary items, especially shower rooms, toilet seats, covers and sinks.

[0093] III-4) Sanitary products, especially diapers (for infants and adult incontinence), feminine hygiene products, shower curtains, brushes, mats, bathtubs, portable toilets, toothbrushes and bedpans.

[0094] III-5) Pipes for water, drainage and chemicals (whether cross-linked or not), pipes for protecting electric wires and cables, pipes for gas, oil and sewage, rain gutters, downpipes and drainage systems.

[0095] III-6) Profiles (window panes) and siding of any shape.

[0096] III-7) Glass substitutes, especially extruded plates, building glazing (monolithic, twin or multi-wall), aircraft, schools, extruded sheets, window films for building glazing, trains, transport and sanitary supplies.

[0097] III-8) Plates (walls, cutting boards), extruded coatings (photographic paper, Tetra Pak and pipe coatings), silos, wood substitutes, plastic sheets, wood composites, walls, surfaces, furniture, decorative foils, flooring (interior and exterior), flooring, duckboard and tiles.

[0098] III-9) Intake and exhaust manifold.

[0099] III-10) Cement, concrete, composites and covers, siding and cladding, handrails, banisters, kitchen worktops, roofing, roofing sheets, tiles and tarpaulins.

[0100] IV-1) Plates (walls and cutting boards), trays, artificial turf, AstroTurf, artificial coverings for athletic rings, artificial flooring and tape for athletic rings.

[0101] IV-2) Continuous and short fiber fabrics, textiles (carpets / sanitary products / geotextiles / monofilaments / filters / wipes / curtains (shades) / medical use), bulk fibers (for use in gowns / protective clothing, etc.), nets, ropes, cables, strings, cords, threads, safety seat belts, clothing, underwear, gloves; boots, rubber boots, innerwear, clothing, swimwear, sportswear, umbrellas (parasols, sunshades), parachutes, paragliders, sails, "balloon silk", camping equipment, tents, air beds, sunbeds, bulk bags and bags.

[0102] IV-3) Roofs, tunnels, dumps, pond membranes, insulation, covers, seals, dumps, wall roofing membranes, geomembranes, pools, curtains (sunshades), awnings, canopies, wallpaper, food packaging and packing (flexible and solid), medical packaging (flexible and solid), airbags / seat belts, armrests and headrests, carpets, center consoles, dashboards, cockpits, doors, overhead console modules, door trims, headliners, interior lighting, interior mirrors, parcel shelves, rear luggage covers, seats, steering columns, steering wheels, textiles and trunk trims.

[0103] V-1) Films (packaging, dump, lamination, bale wrap, pool, garbage bags, wallpaper, stretch film, raffia, desalination film, batteries and connectors).

[0104] V-2) Agricultural films (greenhouse covers, tunnels, mulches, silage, bale wraps), especially when concentrated pesticide application is involved.

[0105] VI-1) Food packaging and packing (flexible and solid), BOPP, BOPET, bottles.

[0106] VI-2) Storage systems for boxes (crates), luggage, chests, household boxes, pallets, shelves, trucks, screw boxes, packs and cans, etc.

[0107] VI-3) Cartridges, syringes, medical applications, transport containers, garbage baskets and trash cans, garbage bags, trash cans, dustbins, bin liners, wheeled trash cans, containers in general, tanks for water / used water / chemicals / gas / oil / gasoline / diesel; tank liners, boxes, wooden crates, battery cases, troughs, medical devices such as pistons, ophthalmic applications, diagnostic devices and pharmaceutical blister packaging.

[0108] VII-1) Extrusion coatings (photographic paper, Tetra Pak, pipe coatings), all kinds of household goods (e.g., electrical appliances, thermos bottles / clothes hangers), fastening systems, e.g., plugs, wire and cable clamps, zippers, closures, locks and snap closures.

[0109] VII-2) Support devices, leisure items, e.g., sports and fitness devices, gymnastics mats, ski boots, inline skates, skis, Bigfoot, sports surfaces (e.g., tennis courts), screw tops, bottle and can tops and stoppers.

[0110] VII-3) All types of furniture, foam products (cushions, shock absorbers), foam, sponges, dish towels, mats, garden chairs, stadium seats, tables, sofas, toys, assembly kits (boards / figures / balls), playhouses, slides and toy cars.

[0111] VII-4) Materials for optical and magnetic data storage.

[0112] VII-5) Kitchenware (eating, cooking, storage).

[0113] VII-6) Cases for CDs, cassettes and videotapes; DVD electronic articles, all kinds of office supplies (ballpoint pens, stamps and ink pads, mice, shelves, trucks), bottles of all capacities and contents (beverages, detergents, perfumes and other cosmetics) and adhesive tapes.

[0114] VII-7) Footwear (shoes / soles), insoles, leggings, adhesives, structural adhesives, food boxes (fruits, vegetables, meat, fish), synthetic paper, bottle labels, benches, artificial joints (human), printing plates (flexographic), printed circuit boards and display technologies.

[0115] VII-8) Devices filled with polymers (talc, chalk, Chinese clay (kaolin), wollastonite, pigments, carbon black, TiO2, mica, nanocomposites, dolomite, silicate, glass, asbestos).

[0116] Automotive interior and exterior trim materials manufactured using the compound of formula (1) and an anti-scratch agent together or individually in an organic material according to the present invention are preferred. Particularly preferred molded articles are those listed in I-2 above. Surface materials for roofs, seats, or dashboards are also of interest.

[0117] If necessary, one or more conventional additives for synthetic polymers, such as antioxidants, UV absorbers, nickel stabilizers, slip additives, pigments, fillers, plasticizers, corrosion inhibitors, and metal deactivators, may be added to the organic material containing the compound of formula (I).

[0118] Examples of conventional additives include the following:

[0119] 1. Antioxidant 1.1. Alkylated monophenols, e.g., 2,6-di-tert-butyl-4-methylphenol, 2-tert-butyl-4,6-dimethylphenol, 2,6-di-tert-butyl-4-ethylphenol, 2,6-di-tert-butyl-4-n-butylphenol, 2,6-di-tert-butyl-4-isobutylphenol, 2,6-dicyclopentyl-4-methylphenol, 2-(α-methylcyclohexyl)-4,6-dimethylphenol, 2,6-dioctadecyl-4-methylphenol, 2,4,6-tri Cyclohexylphenol, 2,6-di-tert-butyl-4-methoxymethylphenol, nonylphenols with linear or branched side chains, such as 2,6-dinonyl-4-methylphenol, 2,4-dimethyl-6-(1'-methylundeca-1'-yl)phenol, 2,4-dimethyl-6-(1'-methylheptadeca-1'-yl)phenol, 2,4-dimethyl-6-(1'-methylpentadeca-1'-yl)phenol, 2,4-dimethyl-6-(1'-methyltrideca-1'-yl)phenol, and mixtures thereof.

[0120] 1.2. Alkylthiomethylphenols, for example, 2,4-dioctylthiomethyl-6-tert-butylphenol, 2,4-dioctylthiomethyl-6-methylphenol, 2,4-dioctylthiomethyl-6-ethylphenol, 2,6-di-dodecylthiomethyl-4-nonylphenol.

[0121] 1.3. Hydroquinones and alkylated hydroquinones, e.g., 2,6-di-tert-butyl-4-methoxyphenol, 2,5-di-tert-butylhydroquinone, 2,5-di-tert-amylhydroquinone, 2,6-diphenyl-4-octadecyloxyphenol, 2,6-di-tert-butylhydroquinone, 2,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxyphenyl stearate, bis(3,5-di-tert-butyl-4-hydroxyphenyl) adipate.

[0122] 1.4. Tocopherols, such as α-tocopherol, β-tocopherol, γ-tocopherol, δ-tocopherol, and mixtures thereof (vitamin E).

[0123] 1.5. Hydroxylated thiodiphenyl ethers, e.g., 2,2'-thiobis(6-tert-butyl-4-methylphenol), 2,2'-thiobis(4-octylphenol), 4,4'-thiobis(6-tert-butyl-3-methylphenol), 4,4'-thiobis(6-tert-butyl-2-methylphenol), 4,4'-thiobis(3,6-di-sec-amylphenol), 4,4'-bis(2,6-dimethyl-4-hydroxyphenyl) disulfide.

[0124] 1.6. Alkylidenebisphenols, e.g., 2,2'-methylenebis(6-tert-butyl-4-methylphenol), 2,2'-methylenebis(6-tert-butyl-4-ethylphenol), 2,2'-methylenebis[4-methyl-6-(α-methylcyclohexyl)phenol], 2,2'-methylenebis(4-methyl-6-cyclohexylphenol), 2,2'-methylenebis(6-nonyl-4-methylphenol), 2,2'-methylenebis(4,6-di-tert-butylphenol), 2,2'-ethylidenebis( 4,6-di-tert-butylphenol), 2,2'-ethylidenebis(6-tert-butyl-4-isobutylphenol), 2,2'-methylenebis[6-(α-methylbenzyl)-4-nonylphenol], 2,2'-methylenebis[6-(α,α-dimethylbenzyl)-4-nonylphenol], 4,4'-methylenebis(2,6-di-tert-butylphenol), 4,4'-methylenebis(6-tert-butyl-2-methylphenol), 1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl) Butane, 2,6-bis(3-tert-butyl-5-methyl-2-hydroxybenzyl)-4-methylphenol, 1,1,3-tris(5-tert-butyl-4-hydroxy-2-methylphenyl)butane, 1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)-3-n-dodecylmercaptobutane, ethylene glycol bis[3,3-bis(3'-tert-butyl-4'-hydroxyphenyl)butyrate], bis(3-tert-butyl-4-hydroxy-5-methylphenyl)dicyclopentadi En, bis[2-(3'-tert-butyl-2'-hydroxy-5'-methylbenzyl)-6-tert-butyl-4-methylphenyl]terephthalate, 1,1-bis-(3,5-dimethyl-2-hydroxyphenyl)butane, 2,2-bis(3,5-di-tert-butyl-4-hydroxyphenyl)propane, 2,2-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)-4-n-dodecylmercaptobutane, 1,1,5,5-tetra-(5-tert-butyl-4-hydroxy-2-methylphenyl)pentane.

[0125] 1.7. O-, N-, and S-benzyl compounds, e.g., 3,5,3',5'-tetra-tert-butyl-4,4'-dihydroxydibenzyl ether, octadecyl-4-hydroxy-3,5-dimethylbenzyl mercaptoacetate, tridecyl-4-hydroxy-3,5-di-tert-butylbenzyl mercaptoacetate, tris(3,5-di-tert-butyl-4-hydroxybenzyl)amine, bis(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)dithioterephthalate, bis(3,5-di-tert-butyl-4-hydroxybenzyl)sulfide, isooctyl-3,5-di-tert-butyl-4-hydroxybenzyl mercaptoacetate.

[0126] 1.8. Hydroxybenzylated malonates, e.g., dioctadecyl-2,2-bis(3,5-di-tert-butyl-2-hydroxybenzyl)malonate, dioctadecyl-2-(3-tert-butyl-4-hydroxy-5-methylbenzyl)malonate, didodecylmercaptoethyl-2,2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)malonate, bis[4-(1,1,3,3-tetramethylbutyl)phenyl]-2,2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)malonate.

[0127] 1.9. Aromatic hydroxybenzyl compounds, e.g., 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, 1,4-bis(3,5-di-tert-butyl-4-hydroxybenzyl)-2,3,5,6-tetramethylbenzene, 2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)phenol.

[0128] 1.10. Triazine compounds, e.g., 2,4-bis(octylmercapto)-6-(3,5-di-tert-butyl-4-hydroxyanilino)-1,3,5-triazine, 2-octylmercapto-4,6-bis(3,5-di-tert-butyl-4-hydroxyanilino)-1,3,5-triazine, 2-octylmercapto-4,6-bis(3,5-di-tert-butyl-4-hydroxyphenoxy)-1,3,5-triazine, 2,4,6-tris(3,5-di-tert-butyl-4-hydroxyphenoxy)-1,2,3-triazine, 1,3, 5-Tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate, 1,3,5-Tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) isocyanurate, 2,4,6-Tris(3,5-di-tert-butyl-4-hydroxyphenylethyl)-1,3,5-triazine, 1,3,5-Tris(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)-hexahydro-1,3,5-triazine, 1,3,5-Tris(3,5-dicyclohexyl-4-hydroxybenzyl) isocyanurate.

[0129] 1.11. Benzyl phosphonates, such as dimethyl-2,5-di-tert-butyl-4-hydroxybenzylphosphonate, diethyl-3,5-di-tert-butyl-4-hydroxybenzylphosphonate, dioctadecyl-3,5-di-tert-butyl-4-hydroxybenzylphosphonate, dioctadecyl-5-tert-butyl-4-hydroxy-3-methylbenzylphosphonate, and calcium salts of monoethyl esters of 3,5-di-tert-butyl-4-hydroxybenzylphosphonic acid.

[0130] 1.12. Acylaminophenols, e.g., 4-hydroxylauranilide, 4-hydroxystearanilide, octyl N-(3,5-di-tert-butyl-4-hydroxyphenyl)carbamate.

[0131] 1.13. Esters of β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid with monohydric or polyhydric alcohols, such as methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, and 4-hydroxymethyl-1-phosphine-2,6,7-trioxabicyclo[2.2.2]octane.

[0132] 1.14. Esters of β-(5-tert-butyl-4-hydroxy-3-methylphenyl)propionic acid with monohydric or polyhydric alcohols, e.g., methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)iso Esters with cyanurate, N,N'-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane; and 3,9-bis[2-{3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy}-1,1-dimethylethyl]-2,4,8,10-tetraoxaspiro[5.5]undecane.

[0133] 1.15. Esters of β-(3,5-dicyclohexyl-4-hydroxyphenyl)propionic acid with monohydric or polyhydric alcohols, such as methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, and 4-hydroxymethyl-1-phosphine-2,6,7-trioxabicyclo[2.2.2]octane.

[0134] 1.16.3,5-di-tert-butyl-4-hydroxyphenylacetic acid esters with monohydric or polyhydric alcohols, such as methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, and 4-hydroxymethyl-1-phosphine-2,6,7-trioxabicyclo[2.2.2]octane.

[0135] 1.17. Amides of β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid, e.g., N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hexamethylenediamide, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)trimethylenediamide, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hydrazide, N,N'-bis[2-(3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyloxy)ethyl]oxamide (Naugard® XL-1 supplied by Uniroyal).

[0136] 1.18. Ascorbic acid (Vitamin C).

[0137] 1.19. Amine-based antioxidants, e.g., N,N'-di-isopropyl-p-phenylenediamine, N,N'-di-sec-butyl-p-phenylenediamine, N,N'-bis(1,4-dimethylpentyl)-p-phenylenediamine, N,N'-bis(1-ethyl-3-methylpentyl)-p-phenylenediamine, N,N'-bis(1-methylheptyl)-p-phenylenediamine, N,N'-dicyclohexyl-p-phenylenediamine, N,N'-diphenyl-p-phenyl Diendiamine, N,N'-bis(2-naphthyl)-p-phenylenediamine, N-isopropyl-N'-phenyl-p-phenylenediamine, N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine, N-(1-methylheptyl)-N'-phenyl-p-phenylenediamine, N-cyclohexyl-N'-phenyl-p-phenylenediamine, 4-(p-triensulfamoyl)diphenylamine, N,N'-dimethyl-N,N'-di-sec-butyl-p - Phenylenediamine, diphenylamine, N-allyldiphenylamine, 4-isopropoxydiphenylamine, N-phenyl-1-naphthylamine, N-(4-tert-octylphenyl)-1-naphthylamine, N-phenyl-2-naphthylamine, octylated diphenylamine, e.g., p,p'-di-tert-octyldiphenylamine, 4-n-butylaminophenol, 4-butyrylaminophenol, 4-nonanoylaminophenol, 4-dodecanoylamine Nophenol, 4-octadecanoylaminophenol, bis(4-methoxyphenyl)amine, 2,6-di-tert-butyl-4-dimethylaminomethylphenol, 2,4'-diaminodiphenylmethane, 4,4'-diaminodiphenylmethane, N,N,N',N'-tetramethyl-4,4'-diaminodiphenylmethane, 1,2-bis[(2-methylphenyl)amino]ethane, 1,2-bis(phenylamino)propane, (o-tolyl)biguanide, bis[4-(1',[3'-dimethylbutyl)phenyl]amine, tert-octylated N-phenyl-1-naphthylamine, mixtures of mono and dialkylated tert-butyl / tert-octyldiphenylamine, mixtures of mono and dialkylated nonyldiphenylamine, mixtures of mono and dialkylated dodecyldiphenylamine, mixtures of mono and dialkylated isopropyl / isohexyldiphenylamine, mixtures of mono and dialkylated tert-butyldiphenylamine, 2,3-dihydro-3,3-dimethyl-4H-1,4-benzothiazine, phenothiazine, mixtures of mono and dialkylated tert-butyl / tert-octylphenothiazine, mixtures of mono and dialkylated tert-octylphenothiazine, N-allylphenothiazine, N,N,N',N'-tetraphenyl-1,4-diaminobuto-2-ene.

[0138] 2. UV absorbers and light stabilizers 2.1.2-(2'-hydroxyphenyl)benzotriazole, e.g., 2-(2'-hydroxy-5'-methylphenyl)-benzotriazole, 2-(3',5'-di-tert-butyl-2'-hydroxyphenyl)benzotriazole, 2-(5'-tert-butyl-2'-hydroxyphenyl)benzotriazole, 2-(2'-hydroxy-5'-(1,1,3,3-tetramethylbutyl)phenyl)benzotriazole, 2-(3',5'-di-tert-butyl-2'-hydroxyphenyl)-5-chloro-benzotriazole, 2- (3'-tert-butyl-2'-hydroxy-5'-methylphenyl)-5-chlorobenzotriazole, 2-(3'-sec-butyl-5'-tert-butyl-2'-hydroxyphenyl)benzotriazole, 2-(2'-hydroxy-4'-octyloxyphenyl)benzotriazole, 2-(3',5'-di-tert-amyl-2'-hydroxyphenyl)benzotriazole, 2-(3',5'-bis-(α,α-dimethylbenzyl)-2'-hydroxyphenyl)benzotriazole, 2-(3'-tert-butyl-2'-hydroxyphenyl) Xy-5'-(2-octyloxycarbonylethyl)phenyl)-5-chloro-benzotriazole, 2-(3'-tert-butyl-5'-[2-(2-ethylhexyloxy)-carbonylethyl]-2'-hydroxyphenyl)-5-chloro-benzotriazole, 2-(3'-tert-butyl-2'-hydroxy-5'-(2-methoxycarbonylethyl)phenyl)-5-chloro-benzotriazole, 2-(3'-tert-butyl-2'-hydroxy-5'-(2-methoxycarbonylethyl)phenyl)benzotriazole, 2-(3 '-tert-butyl-2'-hydroxy-5'-(2-octyloxycarbonylethyl)phenyl)benzotriazole, 2-(3'-tert-butyl-5'-[2-(2-ethylhexyloxy)carbonylethyl]-2'-hydroxyphenyl)benzotriazole, 2-(3'-dodecyl-2'-hydroxy-5'-methylphenyl)benzotriazole, 2-(3'-tert-butyl-2'-hydroxy-5'-(2-isooctyloxycarbonylethyl)phenylbenzotriazole, 2,2'-methylene-bis[4-(1,1,3,[3-tetramethylbutyl)-6-benzotriazole-2-ylphenol]; transesterification product of 2-[3'-tert-butyl-5'-(2-methoxycarbonylethyl)-2'-hydroxyphenyl]-2H-benzotriazole and polyethylene glycol 300; [ka] (wherein R = 3'-tert-butyl-4'-hydroxy-5'-2H-benzotriazole-2-ylphenyl, 2-[2'-hydroxy-3'-(α,α-dimethylbenzyl)-5'-(1,1,3,3-tetramethylbutyl)phenyl]benzotriazole; and 2-[2'-hydroxy-3'-(1,1,3,3-tetramethylbutyl)-5'-(α,α-dimethylbenzyl)-phenyl]benzotriazole).

[0139] 2.2.2-Hydroxybenzophenone, for example, 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2',4'-trihydroxy and 2'-hydroxy-4,4'-dimethoxy derivatives.

[0140] 2.3. Substituted and unsubstituted benzoic acid esters, e.g., 4-tert-butyl-phenyl salicylate, phenyl salicylate, octylphenyl salicylate, dibenzoyl resorcinol, bis(4-tert-butylbenzoyl)resorcinol, benzoyl resorcinol, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate, hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, octadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, 2-methyl-4,6-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate.

[0141] 2.4. Acrylates, for example, ethyl α-cyano-β,β-diphenyl acrylate, isooctyl α-cyano-β,β-diphenyl acrylate, methyl α-carbomethoxy cinnamate, methyl α-cyano-β-methyl-p-methoxy cinnamate, butyl α-cyano-β-methyl-p-methoxy cinnamate, methyl α-carbomethoxy-p-methoxy cinnamate, N-(β-carbomethoxy-β-cyanovinyl)-2-methylindoline, neopentyltetra(α-cyano-β,β-diphenyl acrylate).

[0142] 2.5. Nickel compounds, e.g., nickel complexes of 2,2'-thio-bis[4-(1,1,3,3-tetramethylbutyl)phenol], e.g., 1:1 or 1:2 complexes (with or without additional ligands such as n-butylamine, triethanolamine, or N-cyclohexyldiethanolamine), nickel dibutyldithiocarbamate, nickel salts of monoalkyl esters, e.g., nickel salts of methyl or ethyl esters of 4-hydroxy-3,5-di-tert-butylbenzylphosphonic acid, nickel complexes of ketoximes, e.g., nickel complexes of 2-hydroxy-4-methylphenylundecylketoxime, nickel complexes of 1-phenyl-4-lauroyl-5-hydroxypyrazole (with or without additional ligands).

[0143] 2.6. Steriohind amines, e.g., 1,6-hexanediamine N,N'-bis(1-propyloxy-2,2,6,6-tetramethyl-4-piperidinyl)-N,N'-bis-2-[4,5-bis-(Nn-butyl-N'-1-propyloxy-2,2,6,6-tetramethyl-4-piperidinyl)-1,3,5-triazine], 1,6-hexanediamine N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-N,N'-bis-2-[4,5-bis-(Nn-butyl-N'-2,2,6,6-tetramethyl-4-piperidinyl] )-1,3,5-triazine], bis(1-undecyloxy-2,2,6,6-tetramethyl-4-piperidyl) carbonate ester, bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis(2,2,6,6-tetramethyl-4-piperidyl) succinate, reaction product of alkanoic acid (C=18,20,22,24, linear) consisting of 1,2,2,6,6-pentamethylpiperidine-4-yldocosanoate as the main component (80% or more) and 1,2,2,6,6-pentamethylpiperidine-4-ol, bis(1,2,2,6, 6-Pentamethyl-4-piperidyl) sebacate, bis(1-Undecanoxy-2,2,6,6-tetramethylpiperidine-4-yl) carbonate (CAS registry number [705257-84-7], bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-tert-butyl-4-hydroxybenzylmalonate, 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid Condensates with, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-tert-octylamino-2,6-dichloro-1,3,5-triazine, tris(2,2,6,6-tetramethyl-4-piperidyl)nitrilotriacetate, tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetracarboxylate, 1,1'-(1,2-ethanediyl)-bis(3,3,5,5-tetramethylpiperazinone), 4-benzoyl-2,2,6,6-Tetramethylpiperidine, 4-Stearyloxy-2,2,6,6-Tetramethylpiperidine, Bis(1,2,2,6,6-Pentamethylpiperidyl)-2-n-Butyl-2-(2-Hydroxy-3,5-Di-Tert-Butylbenzyl) Malonate, 3-n-Octyl-7,7,9,9-Tetramethyl-1,3,8-Triazaspiro[4.5]decane-2,4-Dione, Bis(1-Octyloxy-2,2,6,6-Tetramethylpiperidyl) Sebacate, Bis(1-Octyloxy-2,2,6,6-Tetramethylpiperidyl) Succinate, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5-triazine, condensates of 2-chloro-4,6-bis(4-n-butylamino-2,2,6,6-tetramethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, 2-chloro-4,6-di-(4-n-butylamino-1,2,2,6,6-pentamethylpiperidyl)-1,3,5-triazine and 1,2-bis Condensate with (3-aminopropylamino)ethane, 8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, 3-dodecyl-1-(2,2,6,6-tetramethyl-4-piperidyl)pyrrolidine-2,5-dione, 3-dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione, mixture of 4-hexadecyloxy- and 4-stearyloxy-2,2,6,6-tetramethylpiperidine, N,N'-bis(2,2,6, Condensate of 6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-cyclohexylamino-2,6-dichloro-1,3,5-triazine, condensate of 1,2-bis(3-aminopropylamino)ethane, 2,4,6-trichloro-1,3,5-triazine, and 4-butylamino-2,2,6,6-tetramethylpiperidine (CAS Registry No. [136504-96-6]); 1,6-hexanediamine and 2,4,6-trichloro-1,3,5-triazine, and N,N-dibutylamine and 4-butylamino-2,2,6,Condensate of 6-tetramethylpiperidine (CAS Registry No. [192268-64-7]); N-(2,2,6,6-tetramethyl-4-piperidyl)-n-dodecylsuccinimide, N-(1,2,2,6,6-pentamethyl-4-piperidyl)-n-dodecylsuccinimide, 2-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxospiro[4,5]decane, 7,7,9,9-tetramethyl-2-cyclo Reaction product of ndecyl-1-oxa-3,8-diaza-4-oxospiro-[4,5]decane with epichlorohydrin, 1,1-bis(1,2,2,6,6-pentamethyl-4-piperidyloxycarbonyl)-2-(4-methoxyphenyl)ethene, N,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine, 4-methoxymethylenemalonic acid and 1,2,2,6,6-pentamethyl Diester with -4-hydroxypiperidine, poly[methylpropyl-3-oxy-4-(2,2,6,6-tetramethyl-4-piperidyl)]siloxane, reaction product of maleic anhydride-α-olefin copolymer with 2,2,6,6-tetramethyl-4-aminopiperidine or 1,2,2,6,6-pentamethyl-4-aminopiperidine, 2,4-bis[N-(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidine-4- [Iyl)-N-butylamino]-6-(2-hydroxyethyl)amino-1,3,5-triazine, 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine, 5-(2-ethylhexanoyl)oxymethyl-3,3,5-trimethyl-2-morpholinone, Sanduvor (Clariant; CAS Registry No. 106917-31-1), amino ether HALS / Polymer Hostavin NOW Pills XP (Clariant; CAS Registry No. [942926-88-7], reaction product of 5-(2-ethylhexanoyl)oxymethyl-3,3,5-trimethyl-2-morpholinone, 2,4-bis[(1-cyclohexyloxy-2,2,6,6-piperidine-4-yl)butylamino]-6-chloro-s-triazine and N,N'-bis(3-aminopropyl)ethylenediamine), 1,3,5-Tris(N-cyclohexyl-N-(2,2,6,6-tetramethylpiperazine-3-on-4-yl)amino)-s-triazine, 1,3,5-Tris(N-cyclohexyl-N-(1,2,2,6,6-pentamethylpiperazine-3-on-4-yl)amino)-s-triazine, N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-N,N'-diformylhexamethylenediamine. [ka]

[0144] 2.7. Benzoxazinone derivatives, e.g., 2,2'-(1,4-phenylene)bis[4H-3,1-benzoxazin-4-one] (CAS number 018600-59-4).

[0145] 2.8. Oxamides, such as 4,4'-dioctyloxyoxanilide, 2,2'-diethoxyoxanilide, 2,2'-dioctyloxy-5,5'-ditert-butoxanilide, 2,2'-didodecyloxy-5,5'-ditert-butoxanilide, 2-ethoxy-2'-ethyloxanilide, N,N'-bis(3-dimethylaminopropyl)oxamide, 2-ethoxy-5-tert-butyl-2'-ethoxanilide and 2-ethoxy-2'-ethyl-5,4'-ditert-butoxanilide and mixtures thereof, mixtures of o- and p-methoxy-disubstituted oxanilides and mixtures of o- and p-ethoxy-disubstituted oxanilides.

[0146] 2.9.2-(2-hydroxyphenyl)-1,3,5-triazine, e.g., 2,4,6-tris(2-hydroxy-4-octyloxyphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2,4-dihydroxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2,4-bis(2-hydroxy-4-propyloxyphenyl)-6-(2,4-dimethylphenyl)-1,3,5-triazine , 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(4-methylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-dodecyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-tridecyloxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-butyloxypropoxy)phenyl]-4,6-bis(2,4-dimethyl)-1,3,5-triazine, 2 -[2-hydroxy-4-(2-hydroxy-3-octyloxypropyloxy)phenyl]-4,6-bis(2,4-dimethyl)-1,3,5-triazine, 2-[4-(dodecyloxy / tridecyloxy-2-hydroxypropoxy)-2-hydroxyphenyl]-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-dodecyloxypropoxy)phenyl]-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2-(2-hydroxy-4-hexyl Oxy)phenyl-4,6-diphenyl-1,3,5-triazine, 2-(2-hydroxy-4-methoxyphenyl)-4,6-diphenyl-1,3,5-triazine, 2,4,6-tris[2-hydroxy-4-(3-butoxy-2-hydroxypropoxy)phenyl]-1,3,5-triazine, 2-(2-hydroxyphenyl)-4-(4-methoxyphenyl)-6-phenyl-1,3,5-triazine, 2-{2-hydroxy-4-[3-(2-ethylhexyl-1-oxy)-2-hydroxypropyloxy]phenyl}-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine, 2,4-bis(4-[2-ethylhexyloxy]-2-hydroxyphenyl)-6-(4-methoxyphenyl)-1,3,5-triazine, 2-(4,6-bis-biphenylyl-4-yl-1,3,5-triazine-2-yl)-5-(2-ethyl-(n)-hexyloxy)phenol.

[0147] 3. Metal deactivators, such as N,N'-diphenyloxamide, N-salicyl-N'-salityroylhydrazine, N,N'-bis(salityroyl)hydrazine, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hydrazine, 3-salityroylamino-1,2,4-triazole, bis(benzylidene)oxalyl dihydrazide, oxanilide, isophthaloyl dihydrazide, sebacoylbisphenylhydrazide, N,N'-diacetyladipoyl dihydrazide, N,N'-bis(salityroyl)oxalyl dihydrazide, and N,N'-bis(salityroyl)thiopropionyl dihydrazide.

[0148] 3a. Formamidine, e.g., ethoxycarbonylphenyl)-N'-ethyl-N'-phenylformamidine.

[0149] 4. Phosphates and phosphonites, such as triphenyl phosphite, diphenylalkyl phosphite, phenyl dialkyl phosphite, tris(nonylphenyl) phosphite, trilauryl phosphite, trioctadecyl phosphite, distearyl pentaerythritol diphosphite, tris(2,4-di-tert-butylphenyl) phosphite, diisodecyl pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite, Bis(2,4-di-cumylphenyl)pentaerythritol diphosphite, bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythritol diphosphite, diisodecyloxypentaerythritol diphosphite, bis(2,4-di-tert-butyl-6-methylphenyl)pentaerythritol diphosphite, bis(2,4,6-tris(tert-butylphenyl)pentaerythritol diphosphite), tristearylsorbitol triphosphite, tetrakis(2,4-di (-tert-butylphenyl)4,4'-biphenylenediphosphonite, 6-isooctyloxy-2,4,8,10-tetra-tert-butyl-12H-dibenz[d,g]-1,3,2-dioxaphosphosine, bis(2,4-di-tert-butyl-6-methylphenyl)methylphosphite, bis(2,4-di-tert-butyl-6-methylphenyl)ethylphosphite, 6-fluoro-2,4,8,10-tetra-tert-butyl-12-methyldibenz[d,g]-1,3,2-dioxaphosphosine Hosine, 2,2',2''-nitrilo[triethyltris(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl)phosphite], 2-ethylhexyl(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl)phosphite, 5-butyl-5-ethyl-2-(2,4,6-tri-tert-butylphenoxy)-1,3,2-dioxaphosphyran, phosphoric acid, mixed 2,4-bis(1,1-dimethylpropyl)phenyl and 4-(1,1-Dimethylpropyl)phenyl triester (CAS: 939402-02-5), phosphoric acid, triphenyl ester, α-hydro-ω-hydroxypoly[oxy(methyl-1,2-ethanediyl)], C10-16-alkyl ester with polymer (CAS: 1227937-46-3).

[0150] The following phosphites are particularly preferred. Tris(2,4-di-tert-butylphenyl) phosphite, Tris(nonylphenyl) phosphite, [ka]

[0151] 5. Hydroxylamines, such as N,N-dibenzylhydroxylamine, N,N-diethylhydroxylamine, N,N-dioctylhydroxylamine, N,N-dilaurylhydroxylamine, N,N-ditetradecylhydroxylamine, N,N-dihexadecylhydroxylamine, N,N-dioctadecylhydroxylamine, N-hexadecyl-N-octadecylhydroxylamine, N-heptadecyl-N-octadecylhydroxylamine, and N,N-dialkylhydroxylamines derived from hydrogenated fat amines.

[0152] 6. Amine oxides, such as N,N-dibenzylhydroxylamine oxide, N,N-diethylhydroxylamine oxide, N,N-dioctylhydroxylamine oxide, N,N-dilaurylhydroxylamine oxide, N,N-ditetradecylhydroxylamine oxide, N,N-dihexadecylhydroxylamine oxide, N,N-dioctadecylhydroxylamine oxide, N-hexadecyl-N-octadecylhydroxylamine oxide, N-heptadecyl-N-octadecylhydroxylamine oxide, and N,N-dialkylhydroxylamine oxides derived from hydrogenated fat amines.

[0153] 7. Nitrones, such as N-benzyl-α-phenylnitrone, N-ethyl-α-methylnitrone, N-octyl-α-heptylnitrone, N-lauryl-α-undecylnitrone, N-tetradecyl-α-tridecylnitrone, N-hexadecyl-α-pentadecylnitrone, N-octadecyl-α-heptadecylnitrone, N-hexadecyl-α-heptadecylnitrone, N-octadecyl-α-pentadecylnitrone, N-heptadecyl-α-heptadecylnitrone, N-octadecyl-α-hexadecylnitrone, and nitrones derived from N,N-dialkylhydroxylamines derived from hydrogenated fat amines.

[0154] 8. Thio synergistic agents, such as dilauryl thiodipropionate, dimistrill thiodipropionate, distearyl thiodipropionate, pentaerythritol tetrakis[3-(dodecylthio)propionate], or distearyl disulfide.

[0155] 9. Peroxide scavengers, such as esters of β-thiodipropionic acid, such as lauryl, stearyl, myristyl or tridecyl esters, zinc salts of mercaptobenzimidazole or 2-mercaptobenzimidazole, zinc dibutyldithiocarbamate, dioctadecyl disulfide, pentaerythritol tetrakis(β-dodecylmecapto)propionate.

[0156] 10. Polyamide stabilizers, such as copper salts and divalent manganese salts combined with iodide and / or phosphorus compounds.

[0157] 11. Basic co-stabilizers, such as melamine, polyvinylpyrrolidone, dicyandiamide, triallyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polyurethanes, alkali metal salts and alkaline earth metal salts of higher fatty acids, such as calcium stearate, zinc stearate, magnesium behenate, magnesium stearate, sodium ricinoleate and potassium palmitate, antimony pyrocatecholate or zinc pyrocatecholate, zeolites, hydrotalcite, and hydrocalmite.

[0158] 12. Nucleating agents, such as inorganic substances, such as talcam; metal oxides, such as titanium dioxide or magnesium oxide; phosphates, carboxylates or sulfates, preferably alkaline earth metals; organic compounds, such as mono or polycarboxylic acids and their salts, such as 4-tert-butylbenzoic acid, adipic acid, diphenylacetic acid, sodium succinate or sodium benzoate; polymer compounds, such as ionic copolymers (ionomers). Particularly preferred are 1,3:2,4-bis(3',4'-dimethylbenzylidene)sorbitol, 1,3:2,4-di(paramethyldibenzylidene)sorbitol, and 1,3:2,4-di(benzylidene)sorbitol.

[0159] 13. Fillers and reinforcing agents, such as calcium carbonate, silicates, glass fibers, carbon fibers, glass beads, asbestos, talcan (preferably with a particle size of 0.01 to 20 μm), kaolin, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite, wood flour and other powders or fibers of natural products, and synthetic fibers.

[0160] 14. Other additives, such as plasticizers, lubricants, emulsifiers, pigments, rheological additives, catalysts, flow regulators, fluorescent whitening agents, flame retardants, antistatic agents, and foaming agents.

[0161] 15. Benzofuranones and indolinones, e.g., U.S. Patent No. 4,325,863; U.S. Patent No. 4,338,244; U.S. Patent No. 5,175,312; U.S. Patent No. 5,216,052; U.S. Patent No. 5,252,643; German Patent Application Publication No. A-4316611; German Patent Application Publication No. A-4316622; German Patent Application Publication No. A-43 Disclosed in Specification 16876; European Patent Application Publication A-0589839; European Patent Application Publication A-0591102; European Patent Application Publication A-1291384 or 3-[4-(2-acetoxyethoxy)phenyl]-5,7-di-tert-butylbenzofuran-2-one, 5,7-di-tert-butyl-3-[4-(2-stearoyloxyethoxy] )phenyl]benzofuran-2-one, 3,3'-bis[5,7-di-tert-butyl-3-(4-[2-hydroxyethoxy]phenyl)benzofuran-2-one], 5,7-di-tert-butyl-3-(4-ethoxyphenyl)benzofuran-2-one, 3-(4-acetoxy-3,5-dimethylphenyl)-5,7-di-tert-butylbenzofuran-2-one, 3-(3,5-dimethyl-4-pivaloyloxyphenyl)-5,7-di-tert-butylbenzofuran-2-one, 3-(3,4-dimethylphenyl)-5,7-di-tert-butylbenzofuran-2-one, 3-(2,3-dimethylphenyl)-5,7-di-tert-butylbenzofuran-2-one, 3-(2-acetyl-5-isooctylphenyl)-5-isooctylbenzofuran-2-one.

[0162] In preferred embodiments, the sterically hindered amine is selected from the group consisting of a condensate of 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, a condensate of 1,6-hexanediamine and 2,4,6-trichloro-1,3,5-triazine, and a condensate of N,N-dibutylamine and 4-butylamino-2,2,6,6-tetramethylpiperidine, 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine, N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-N,N'-diformylhexamethylenediamine and mixtures thereof.

[0163] In a more preferred embodiment, the sterically hindered amine is 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and / or N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-N,N'-diformylhexyl Methylene It is a diamine.

[0164] Phenolic antioxidants are preferred. Those listed in item 1 above are of particular interest. Phenolic antioxidants and process stabilizers, such as octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hexamethylenediamide, bis(1,2,2,6,6-pentamethylpiperidine-4-yl)-butyl(3,5-di-t-butyl-4-hydroxybenzyl)malonate, and tris[2,4-di-tert-butylphenyl]phosphite are of particular interest.

[0165] A more preferred additive is calcium stearate.

[0166] Pigments such as TiO2 and carbon black are even more preferable. Fillers such as talc are also of interest.

[0167] Preferred additives are also, in particular, the sterically hindered amine light stabilizers and / or UV absorbers listed in item 2 above.

[0168] Preferred amine light stabilizers that do not interfere with light are as follows: [ka] (In the formula, a1 is between 2 and 10.) [ka] (In the formula, b1 is a number between 2 and 20, preferably between 2 and 10.) [ka] (In the formula, a1 is between 2 and 10.) [ka] (In the formula, a1 is between 2 and 10.) [ka] (In the formula, X1, X2, X3, X4, X5, X6, X7 and X8 are base [ka] (is), [ka] (In the formula, Y1 is independently hydrogen or propoxy, preferably propoxy.) [ka] (In the formula, n is between 4 and 20.) [ka] (In the formula, n' is between 14 and 16).

[0169] The preferred UV absorber is a hydroxyphenyltriazine UV absorber. Hydroxyphenyltriazine UV absorbers are as follows: [ka] [ka] [ka]

[0170] Preferred UV absorbers are substituted and unsubstituted benzoic acid esters. The substituted and unsubstituted benzoic acid esters are selected from di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzoate and / or hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate.

[0171] The compound of formula (1) and the anti-scratch agent according to the present invention are preferably applied together with a phenolic antioxidant, a phosphite, preferably tris[2,4-di-tert-butylphenyl]phosphite, a sterically hindered amine light stabilizer, a UV absorber, an acid scavenger, preferably calcium stearate, and carbon black and talc.

[0172] The weight ratio of the compound of formula (1) and the anti-scratch agent to the conventional additive is, for example, 1:100 to 100:1, preferably 1:100 to 10:1, and particularly 1:10 to 10:1.

[0173] The present invention, as claimed herein, offers one or more of the following advantages: 1. Molded articles based on organic materials containing the compound of formula (1) and an anti-scratch agent are susceptible to oxidative, thermal, or photo-induced decomposition. 2. A molded article based on an organic material containing the compound of formula (1) and an anti-scratch agent has a surface that does not exhibit tackiness and does not show blooming / seepage from the molded article of the organic material.

[0174] The following describes specific embodiments of the present invention claimed herein.

[0175] 1.i. Equation (1) [ka] The compound and ii. At least one type of anti-scratch agent and Molded articles based on organic materials, including [the specified element].

[0176] 2. A molded article based on the organic material described in Embodiment 1, wherein the organic material is selected from the group consisting of polyolefins, acrylonitrile / butadiene / styrene, polyvinyl chloride, polymethyl methacrylate, polyamide, or polyoxymethylene and mixtures thereof.

[0177] 3. A molded article based on the organic material described in Embodiment 1 or 2, wherein the organic material is a thermoplastic polyolefin.

[0178] 4. A molded article based on an organic material as described in one or more embodiments 1 to 3, wherein the thermoplastic polyolefin is thermoplastic polyethylene or polypropylene.

[0179] 5. A molded article based on an organic material according to one or more embodiments 1 to 4, wherein the anti-scratch agent is selected from the group consisting of unsaturated or saturated fatty acid amides, poly(organo)siloxanes, and mixtures thereof.

[0180] 6. A molded article based on an organic material as described in one or more embodiments 1 to 5, wherein the anti-scratch agent is selected from the group consisting of erucamide, oleamide, stearamide, and mixtures thereof.

[0181] 7. The anti-scratch agent is selected from erucamide, stearamide, or a mixture thereof, in the molded article according to one or more embodiments 1 to 6.

[0182] 8. A molded article based on an organic material according to one or more of Embodiments 1 to 7, wherein the weight ratio of the compound of formula (1) to at least one anti-scratch agent is in the range of 1:70 to 30:99.

[0183] 9. A molded article based on an organic material as described in one or more of Embodiments 1 to 8, wherein the weight ratio of the organic material to the compound of formula (1) is in the range of 99.99:0.01 to 99.0:1.0.

[0184] 10. A molded article based on an organic material according to one or more of Embodiments 1 to 9, wherein the weight ratio of the organic material to at least one anti-scratch agent is in the range of 99.99:0.01 to 98:2.

[0185] 11. A molded article based on one or more of the organic materials described in Embodiments 1 to 10, further comprising a phenolic antioxidant and / or a phenolic phosphite.

[0186] 12. A molded article based on an organic material according to one or more of Embodiments 1 to 11, wherein the phenolic antioxidant is selected from the group consisting of octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hexamethylenediamide, bis(1,2,2,6,6-pentamethylpiperidine-4-yl)-butyl(3,5-di-t-butyl-4-hydroxybenzyl)malonate) and mixtures thereof.

[0187] 13. A molded article based on an organic material according to one or more of Embodiments 1 to 11, wherein the phenolic phosphite is tris[2,4-di-tert-butylphenyl]phosphite.

[0188] 14. A molded article based on one or more of the organic materials described in Embodiments 1 to 13, further comprising a sterically hindered amine light stabilizer and / or a UV absorber.

[0189] 15. Steriostatic amine light stabilizers include bis(1-undecyloxy-2,2,6,6-tetramethyl-4-piperidyl) carbonate, bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis(2,2,6,6-tetramethyl-4-piperidyl) succinate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate, and bis(1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-tert- Butyl-4-hydroxybenzylmalonate, condensate of 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, linear or cyclic condensate of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-tert-octylamino-2,6-dichloro-1,3,5-triazine, tris(2,2,6,6-tetramethyl-4-piperidyl)nitrilotriacetate, tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butantete Lacarboxylate, 1,1'-(1,2-ethanediyl)-bis(3,3,5,5-tetramethylpiperazinone), 4-benzoyl-2,2,6,6-tetramethylpiperidine, 4-stearyloxy-2,2,6,6-tetramethylpiperidine, bis(1,2,2,6,6-pentamethylpiperidyl)-2-n-butyl-2-(2-hydroxy-3,5-di-tert-butylbenzyl)malonate, 3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, bis(1-octyl) Xy-2,2,6,6-tetramethylpiperidyl) sebacate, bis(1-octyloxy-2,2,6,6-tetramethylpiperidyl) succinate, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5-triazine, condensates of 2-chloro-4,6-bis(4-n-butylamino-2,2,6,6-tetramethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, 2-chloro-4,Condensate of 6-di-(4-n-butylamino-1,2,2,6,6-pentamethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, 8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, 3-dodecyl-1-(2,2,6,6-tetramethyl-4-piperidyl)pyrrolidine-2,5-dione, 3-dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione, 4-hexadecyloxy- and A mixture of 4-stearyloxy-2,2,6,6-tetramethylpiperidine, a condensate of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-cyclohexylamino-2,6-dichloro-1,3,5-triazine, a condensate of 1,2-bis(3-aminopropylamino)ethane, 2,4,6-trichloro-1,3,5-triazine and 4-butylamino-2,2,6,6-tetramethylpiperidine; 1,6-hexanediamine and 2,4,6-trichloro-1,3,5-triazine and N,N-dibuty Reaction of lumine and 4-butylamino-2,2,6,6-tetramethylpiperidine condensate; N-(2,2,6,6-tetramethyl-4-piperidyl)-n-dodecylsuccinimide, N-(1,2,2,6,6-pentamethyl-4-piperidyl)-n-dodecylsuccinimide, 2-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxospiro[4,5]decane, 7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaza-4-oxospiro-[4,5]decane with epichlorohydrin Products, 1,1-bis(1,2,2,6,6-pentamethyl-4-piperidyloxycarbonyl)-2-(4-methoxyphenyl)ethene, N,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine, diester of 4-methoxymethylenemalonic acid and 1,2,2,6,6-pentamethyl-4-hydroxypiperidine, poly[methylpropyl-3-oxy-4-(2,2,6,6-tetramethyl-4-piperidyl)]siloxane, maleic anhydride-α-olefin copolymer and 2,2,6,Reaction products with 6-tetramethyl-4-aminopiperidine or 1,2,2,6,6-pentamethyl-4-aminopiperidine, 2,4-bis[N-(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidine-4-yl)-N-butylamino]-6-(2-hydroxyethyl)amino-1,3,5-triazine, 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine, 5-(2-ethylhexanoyl)oxymethyl-3,3,5-trimethyl-2-morpholinone, 5-(2-ethylhexanoyl)oxymethyl-3,3,5-trimethyl-2-morpholinone, 2,4-bis[(1-cyclohexyloxy-2,2, A molded article based on one or more organic materials according to Embodiments 1 to 14, selected from the group consisting of reaction products of 6,6-piperidine-4-yl)butylamino]-6-chloro-s-triazine and N,N'-bis(3-aminopropyl)ethylenediamine, 1,3,5-tris(N-cyclohexyl-N-(2,2,6,6-tetramethylpiperazine-3-on-4-yl)amino)-s-triazine, 1,3,5-tris(N-cyclohexyl-N-(1,2,2,6,6-pentamethylpiperazine-3-on-4-yl)amino)-s-triazine, N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-N,N'-diformylhexamethylenediamine and mixtures thereof.

[0190] 16. A molded article based on one or more organic materials according to Embodiments 1 to 14, wherein the UV absorber is selected from the group consisting of 2-(2'-hydroxyphenyl)benzotriazole, 2-hydroxybenzophenone, oxamide, substituted and unsubstituted benzoic acid esters, and 2-(2-hydroxyphenyl)-1,3,5-triazine.

[0191] 17. A molded article based on one or more of the organic materials described in Embodiments 1 to 16, further comprising a slip additive, a filler and / or a pigment.

[0192] 18. A molded article based on one or more of the organic materials described in Embodiments 1 to 17, which is an interior or exterior material for an automobile.

[0193] The following examples illustrate the present invention in more detail. All percentages and parts mentioned herein are by weight unless otherwise specified. [Examples]

[0194] Example 1: Stabilization of thermoplastic polypropylene Base formulation: 1.89.36% by weight of thermoplastic polypropylene (Daplen® EE013 AE of Borealis); melt flow rate: 11 g / 10 min (ISO 1133), density: 905 kg / m³ 3 (ISO 1183) 2.0.100% by weight, a blend of 80% tris(2,4-di-tert-butylphenyl)phosphite + 20% octadecyl-3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionate, 3.0.050% by weight of calcium stearate, 4.10% by weight of talc, 5.0.03% by weight of carbon black, and 6.0.400% by weight of ercamid.

[0195] Further additives, outlined below, are incorporated in the same manner as in the base formulation. In all cases, the weight percentage of thermoplastic polypropylene is adjusted so that the total of all components equals 100%.

[0196] Additive mixture: Compound A: 1,3,5-tri(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate, Compound B: Pentaerythritol tetrakis[3,5-di-tert-butyl-4-hydroxyphenylpropionate], Compound C: 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine Compound D: N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-N,N'-diformylhexamethylenediamine.

[0197] [Table 1]

[0198] Preparation of test specimens: The base formulation was pre-mixed in a Pappermaier® ESK-150 mixer. This mixture was combined with 0.60 wt% of the above additives in a Mixaco Lab CM12 high-speed mixer and compounded at 220°C in a Bersterff® ZE 25x32D twin-screw extruder. Subsequently, injection molding was performed at 240°C in an Engel HL65 injection molding machine.

[0199] Injection-molded plaques measuring 40mm x 60mm x 2mm or 25mm x 60mm x 2mm were exposed to artificial weathering according to international standards from Volkswagen (VW), PV 1303-Grayscale and Volkswagen, PV 1303-Delta E. The PV 1303 settings are as follows: VW PV 1303, DIN 75 202: Lamp: Xenon arc Lamp illumination: 1.2W / m 2 @420nm or 300-400nm at 60W / m 2 Lamp filter set: Borosilicate inside / Soda lime outside Black panel temperature BPT: 100±3℃ Dry valve temperature: 65±3℃ Chamber RH: 20±10% Weather cycle: Permanent light / no dark period, dry only / no rain

[0200] The parameters measured were color shifts on the Gray scale according to DIN EN ISO 105-A05 and the Delta E scale according to DIN 6174.

[0201] The results are shown in Tables 1 and 2.

[0202] [Table 2]

[0203] [Table 3]

[0204] Tables 1 and 2 clearly show that adding the additive of the present invention better preserves the properties of the tested thermoplastic polypropylene samples (i.e., there is no color change due to decomposition when exposed to artificial weathering).

[0205] Example 2: Stabilization of thermoplastic polypropylene Test specimens were prepared in the same manner as described in Example 1 and exposed to artificial weathering according to international standards from Volkswagen, PV 3930-Grayscale and Volkswagen, PV 3930-Delta E (PV3930 is also known as the "Florida Test").

[0206] The settings for PV 3930 are as follows: VW PV 3930: Lamp: Xenon arc Lamp illumination: 0.5W / m 2 @340nm Lamp filter set: Inner borosilicate / Outer borosilicate Black standard temperature BST: 65±3℃ Dry valve temperature: 40±3℃ Chamber RH: 70±10% Weather cycle: 108°C and dry / 18°C ​​and wet

[0207] The parameters measured were color shifts on the Gray scale according to DIN EN ISO 105-A05 and the Delta E scale according to DIN 6174.

[0208] The results are shown in Tables 3 and 4.

[0209] [Table 4]

[0210] [Table 5]

[0211] Tables 3 and 4 clearly show that adding the additive mixture of the present invention better preserves the properties of the tested thermoplastic polypropylene sample (i.e., there is no color change due to decomposition when exposed to artificial weathering).

[0212] Example 3: Stabilization of thermoplastic polypropylene In some combinations of polymers, fillers, colorants, stabilizers, and anti-scratch agents, some of the additives may migrate, and in unfortunate combination ratios, these additives may further bloom on the surface. These additives, decomposed upon exposure to sunlight, can therefore form a sticky layer. A stickiness test can record how this stickiness develops on the surface.

[0213] Test specimens were prepared in the same manner as described in Example 1, and their tackiness was evaluated according to the international standards PV 1306-GS and PV 1306-DE (PV1306 is an exposure test for determining the tackiness of polypropylene parts). The tackiness felt by the finger was evaluated according to a predetermined system and recorded over the aging time. The evaluation system shown below was used for this test.

[0214] [Table 6]

[0215] The results are shown in Table 5.

[0216] [Table 7]

[0217] Table 5 clearly shows that by adding the additive mixture, a surface can be obtained that does not exhibit tackiness to the thermoplastic polypropylene sample and does not show blooming / exudation from the thermoplastic polypropylene sample, or exhibits reduced blooming / exudation. The present invention includes, for example, the following embodiments. [Section 1] i. Equation (1) [ka] The compound and ii. At least one type of anti-scratch agent and Molded articles based on organic materials, including [the specified element]. [Section 2] A molded article based on the organic material described in item 1, wherein the organic material is selected from the group consisting of polyolefins, acrylonitrile / butadiene / styrene, polyvinyl chloride, polymethyl methacrylate, polyamide, or polyoxymethylene and mixtures thereof. [Section 3] A molded article based on the organic material described in item 1 or 2, wherein the organic material is a thermoplastic polyolefin. [Section 4] A molded article based on an organic material as described in any one of claims 1 to 3, wherein the thermoplastic polyolefin is thermoplastic polyethylene or polypropylene. [Section 5] The anti-scratch agent is selected from the group consisting of unsaturated or saturated fatty acid amides, poly(organo)siloxanes, and mixtures thereof, and is used to form a molded article based on an organic material as described in any one of claims 1 to 4. [Section 6] The anti-scratch agent is selected from the group consisting of erucamide, oleamide, stearamide, and mixtures thereof, and is used to form a molded article based on an organic material as described in any one of claims 1 to 5. [Section 7] The anti-scratch agent is selected from erucamide, stearamide, or a mixture thereof, and the molded article is based on an organic material as described in any one of claims 1 to 6. [Section 8] A molded article based on an organic material according to any one of claims 1 to 7, wherein the weight ratio of the compound of formula (1) to the at least one anti-scratch agent is in the range of 1:70 to 30:99. [Section 9] A molded article based on an organic material as described in any one of claims 1 to 8, wherein the weight ratio of the organic material to the compound of formula (1) is in the range of 99.99:0.01 to 99.0:1.0. [Section 10] A molded article based on the organic material according to any one of claims 1 to 9, wherein the weight ratio of the organic material to the at least one anti-scratch agent is in the range of 99.99:0.01 to 98:2. [Section 11] A molded article based on an organic material as described in any one of claims 1 to 10, further comprising a phenolic antioxidant and / or a phenolic phosphite. [Section 12] A molded article based on an organic material according to any one of claims 1 to 11, selected from the group consisting of the phenolic antioxidant, octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hexamethylenediamide, bis(1,2,2,6,6-pentamethylpiperidine-4-yl)-butyl(3,5-di-t-butyl-4-hydroxybenzyl)malonate, and mixtures thereof. [Section 13] The phenolic phosphite is tris[2,4-di-tert-butylphenyl]phosphite, in a molded article based on an organic material as described in any one of claims 1 to 11. [Section 14] A molded article based on an organic material as described in any one of claims 1 to 13, further comprising a sterically hindered amine light stabilizer and / or a UV absorber. [Section 15] The aforementioned sterically hindered amine light stabilizers are bis(1-undecyloxy-2,2,6,6-tetramethyl-4-piperidyl) carbonate, bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis(2,2,6,6-tetramethyl-4-piperidyl) succinate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate, and bis(1,2,2,6,6-pentamethyl-4-piperidyl) n-butyl-3,5-di-tert-butyl Tyl-4-hydroxybenzylmalonate, condensate of 1-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, linear or cyclic condensate of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-tert-octylamino-2,6-dichloro-1,3,5-triazine, tris(2,2,6,6-tetramethyl-4-piperidyl)nitrilotriacetate, tetrakis(2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butanetetra Carboxylate, 1,1'-(1,2-ethanediyl)-bis(3,3,5,5-tetramethylpiperazinone), 4-benzoyl-2,2,6,6-tetramethylpiperidine, 4-stearyloxy-2,2,6,6-tetramethylpiperidine, bis(1,2,2,6,6-pentamethylpiperidyl)-2-n-butyl-2-(2-hydroxy-3,5-di-tert-butylbenzyl)malonate, 3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, bis(1-octyloxy C-2,2,6,6-tetramethylpiperidyl) sebacate, bis(1-octyloxy-2,2,6,6-tetramethylpiperidyl) succinate, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5-triazine, condensate of 2-chloro-4,6-bis(4-n-butylamino-2,2,6,6-tetramethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, 2-chloro-4,Condensate of 6-di-(4-n-butylamino-1,2,2,6,6-pentamethylpiperidyl)-1,3,5-triazine and 1,2-bis(3-aminopropylamino)ethane, 8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione, 3-dodecyl-1-(2,2,6,6-tetramethyl-4-piperidyl)pyrrolidine-2,5-dione, 3-dodecyl-1-(1,2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione, 4-hexadecyloxy- and A mixture of 4-stearyloxy-2,2,6,6-tetramethylpiperidine, a condensate of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-cyclohexylamino-2,6-dichloro-1,3,5-triazine, a condensate of 1,2-bis(3-aminopropylamino)ethane, 2,4,6-trichloro-1,3,5-triazine and 4-butylamino-2,2,6,6-tetramethylpiperidine; 1,6-hexanediamine and 2,4,6-trichloro-1,3,5-triazine and N,N-dibuty Reaction of lumine and 4-butylamino-2,2,6,6-tetramethylpiperidine condensate; N-(2,2,6,6-tetramethyl-4-piperidyl)-n-dodecylsuccinimide, N-(1,2,2,6,6-pentamethyl-4-piperidyl)-n-dodecylsuccinimide, 2-undecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diaza-4-oxospiro[4,5]decane, 7,7,9,9-tetramethyl-2-cycloundecyl-1-oxa-3,8-diaza-4-oxospiro-[4,5]decane with epichlorohydrin Products, 1,1-bis(1,2,2,6,6-pentamethyl-4-piperidyloxycarbonyl)-2-(4-methoxyphenyl)ethene, N,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine, diester of 4-methoxymethylenemalonic acid and 1,2,2,6,6-pentamethyl-4-hydroxypiperidine, poly[methylpropyl-3-oxy-4-(2,2,6,6-tetramethyl-4-piperidyl)]siloxane, maleic anhydride-α-olefin copolymer and 2,2,6,Reaction products with 6-tetramethyl-4-aminopiperidine or 1,2,2,6,6-pentamethyl-4-aminopiperidine, 2,4-bis[N-(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidine-4-yl)-N-butylamino]-6-(2-hydroxyethyl)amino-1,3,5-triazine, 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine, 5-(2-ethylhexanoyl)oxymethyl-3,3,5-trimethyl-2-morpholinone, 5-(2-ethylhexanoyl)oxymethyl-3,3,5-trimethyl-2-morpholinone, 2,4-bis[(1-cyclohexyloxy-2,2, A molded article based on an organic material described in any one of claims 1 to 14, selected from the group consisting of reaction products of 6,6-piperidine-4-yl)butylamino]-6-chloro-s-triazine and N,N'-bis(3-aminopropyl)ethylenediamine, 1,3,5-tris(N-cyclohexyl-N-(2,2,6,6-tetramethylpiperazine-3-on-4-yl)amino)-s-triazine, 1,3,5-tris(N-cyclohexyl-N-(1,2,2,6,6-pentamethylpiperazine-3-on-4-yl)amino)-s-triazine, N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-N,N'-diformylhexamethylenediamine and mixtures thereof. [Section 16] The UV absorber is selected from the group consisting of 2-(2'-hydroxyphenyl)benzotriazole, 2-hydroxybenzophenone, oxamide, esters of substituted and unsubstituted benzoic acid, and 2-(2-hydroxyphenyl)-1,3,5-triazine, and is used to form a molded article based on an organic material as described in any one of claims 1 to 14. [Section 17] A molded article based on an organic material as described in any one of claims 1 to 16, further comprising a slip additive, filler and / or pigment. [Section 18] A molded article based on an organic material as described in any one of paragraphs 1 to 17, which is an interior or exterior material for an automobile.

Claims

1. i. Equation (1) 【Chemistry 1】 The compound and ii. At least one anti-scratch agent selected from the group consisting of unsaturated or saturated fatty acid amides, poly(organo)siloxanes and mixtures thereof, iii. 1-(2-hydroxy-2-methylpropoxy)-4-octadecanoyloxy-2,2,6,6-tetramethylpiperidine and / or N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)-N,N'-diformylhexamethylenediamine as sterically hindered amine light stabilizers A molded article based on an organic material, wherein the organic material is a thermoplastic polyolefin.

2. The molded article based on the organic material according to claim 1, wherein the thermoplastic polyolefin is thermoplastic polyethylene or polypropylene.

3. The molded article based on the organic material according to claim 1 or 2, wherein the anti-scratch agent is selected from the group consisting of erucamide, oleamide, stearamide, and mixtures thereof.

4. A molded article based on an organic material according to any one of claims 1 to 3, wherein the anti-scratch agent is selected from erucamide, stearamide, or a mixture thereof.

5. A molded article based on an organic material according to any one of claims 1 to 4, wherein the weight ratio of the compound of formula (1) to the at least one anti-scratch agent is in the range of 1:70 to 30:

99.

6. A molded article based on an organic material according to any one of claims 1 to 5, wherein the weight ratio of the organic material to the compound of formula (1) is in the range of 99.99:0.01 to 99.0:1.

0.

7. A molded article based on the organic material according to any one of claims 1 to 6, wherein the weight ratio of the organic material to the at least one anti-scratch agent is in the range of 99.99:0.01 to 98:

2.

8. A molded article based on an organic material according to any one of claims 1 to 7, further comprising a phenolic antioxidant and / or a phenolic phosphite.

9. The phenolic antioxidant is selected from the group consisting of octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl)hexamethylenediamide, bis(1,2,2,6,6-pentamethylpiperidine-4-yl)-butyl(3,5-di-t-butyl-4-hydroxybenzyl)malonate, and mixtures thereof, wherein the molded article is based on an organic material according to claim 8.

10. The molded article based on the organic material according to claim 8, wherein the phenolic phosphite is tris[2,4-di-tert-butylphenyl]phosphite.

11. A molded article based on the organic material according to any one of claims 1 to 10, further comprising a UV absorber.

12. The molded article based on the organic material according to claim 11, wherein the UV absorber is selected from the group consisting of 2-(2'-hydroxyphenyl)benzotriazole, 2-hydroxybenzophenone, oxamide, substituted and unsubstituted benzoic acid esters, and 2-(2-hydroxyphenyl)-1,3,5-triazine.

13. A molded article based on an organic material according to any one of claims 1 to 12, further comprising a slip additive, a filler and / or a pigment.

14. A molded article based on an organic material according to any one of claims 1 to 13, which is an interior or exterior material for an automobile.

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