特定の微細孔体積を有するUiO-66の製造方法

Abstract

The present application provides a method for producing MOF UiO-66, comprising: reacting zirconium oxychloride with terephthalic acid or a derivative thereof and acetic acid in a solvent to provide a reaction solution; diluting the reaction solution with water, heating the diluted reaction solution, and lowering the reaction temperature of the reaction mixture to provide MOF UiO-66 having a micropore volume of 0.45 cc / g or more and a crystal size of about 20 nm to about 1000 nm. Also provided is a method for producing MOF UiO-66, comprising reacting zirconium hydroxide acetate and zirconium hydroxide with a carboxylic acid or a derivative thereof and acetic acid in a solvent to produce a metal-organic framework MOF UiO-66 having a micropore volume of at least about 0.35 cc / gram.

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