Fragrances and fragrance mixtures

Abstract

The present invention provides novel fragrances or fragrance mixtures that have the ability to improve the positive and advantageous olfactory aspects of a fragrance and / or (at the same time) reduce, suppress and / or mask the unpleasant olfactory aspects and sub-notes of a fragrance. [Solution] Fragrances according to formula (Ia) and / or formula (Ib). [Formula 1] JPEG2024540449000078.jpg4462

Description

Technical Field

[0001] The present invention belongs to the field of fragrance and relates to novel fragrances and fragrance mixtures, perfumes and their formulation and use in compositions for end consumers.

Background Art

[0002] In the perfume industry, there is always a demand for the creation of new scents. Creating new fragrances and perfumes involves a great many challenges. For example, in order to meet the specific needs of the market and provide a product that matches the specific profile required by customers, it is necessary to select specific compositions of several scents from a virtually infinite number of possible structures based on technical knowledge. In many cases, suitable scents exhibit very advantageous properties but are unpleasant and thus, when combined with unfavorable olfactory aspects, are difficult or even impossible to use for specific purposes.

[0003] A second important issue relates to the need to provide a fragrance composition that not only conforms to a specific olfactory profile but also offers so-called secondary advantageous properties. In fact, many fragrance compositions known in the market exhibit significant disadvantages in application, such as poor solubility and stability during storage, and also fail with regard to subjective issues such as richness, charisma, etc. Furthermore, many of the known fragrance compositions require high dosages to obtain the desired olfactory results. Another prerequisite for recent fragrances is high biodegradability and dermatological and toxicological safety, and preferably the use of renewable resources.

[0004] L-carbyl acetate (L-para-mentha-6,8-diene-2-yl acetate) was first described by S. Arctander in 1969 (Non-Patent Literature 1). Its trans isomer is considered a natural component of spearmint oil. It gives a fresh green mint scent with a slightly metallic accent. The same paper mentions L-carbyl propionic acid (L-para-mentha-6,8-diene-2-ylpropionate, No. 583), describing its scent as sweet, warm, minty, grassy, ​​and with smooth subnotes. No. 929 describes the scent of dihydrocarbyl acetate (para-mentha-8-(9)-en-2-yl acetate; 6-menthyl-3-isopropenyl-cyclohexanyl acetate) as sweet, slightly minty, floral, and rose-like with herbaceous subnotes.

[0005] Non-patent document 2 describes variations of Chinese Menthens essential oil containing carveols and carveol derivatives, but does not disclose specific isomers. A similar paper on the composition of calamintha is published in non-patent document 3, but this document also does not disclose specific carveol isomers.

[0006] Patent Document 1 discloses a mixture of esters of carveols such as formulas (1) and (2) and dihydrocarveols for masking unpleasant odors. [ka] [Prior art documents] [Patent Documents]

[0007] [Patent Document 1] International release 2017 / 041834A1 [Non-patent literature]

[0008] [Non-Patent Document 1] Perfume and Flavor Chemicals, Vol. I+II, Montclair, NJ, No. 582 [Non-Patent Document 2] Industrial Crops and products, Vol. 42, p. 251-260 (2013). [Non-Patent Document 3] J. Medicinal Food, Vol. 14(3), p. 297-303 (2011). [Overview of the project]

[0009] [Means for solving the problem]

[0010] The fundamental objective of the present invention is to provide a novel fragrance or fragrance mixture having the ability to enhance the positive and favorable olfactory aspects of a fragrance, and / or (simultaneously) reduce, suppress, and / or mask the unpleasant olfactory aspects and subnotes of a fragrance. More specifically, the novel fragrance (mixture) should be characterized by fresh, fruity, and rosewood notes, while simultaneously improving the stability, solubility, and overall performance of the fragrance, and reducing the required dosage. Finally, the mixture itself should exhibit excellent biodegradability, be safe for humans and the environment, and rely on renewable natural resources. [Modes for carrying out the invention]

[0011] The first object of the present invention relates to fragrances according to formula (Ia) and / or formula (Ib). [ka] Here, isomers Ia and Ib are preferably present in a weight ratio of about 1:99 to about 99:1, more preferably about 10:90 to 90:10, and most preferably about 25:75 to about 72:25.

[0012] Surprisingly, the component according to formula (I) exhibits the desired fragrance profile and has been found to exhibit notes of fresh, mushroom, rosewood, fruity, pear and violet. This new fragrance can also support, enhance and / or improve the olfactory properties of other fragrances, while at the same time reducing, suppressing and / or completely masking the negative and unpleasant sub-notes of these scents. This effect is significantly increased by using a blend of component (I) having a specific carveol and the dihydrocarveol ester forming component (II).

[0013] <Fragrance mixture> Another object of the present invention relates to a fragrance mixture, comprising or consisting only of the following. (a) at least one of compounds (Ia) and (Ib), and [Chemical formula] (b) at least one of compounds (IIa) and (IIb), and [Chemical formula] where R1 and R2 each represent a C1-C4 alkyl group, a methoxy group or an ethoxy group.

[0014] In a preferred embodiment, components (a) and (b) are present in a weight ratio of from about 1:99 to about 99:1, more preferably from about 10:90 to about 90:10, most preferably from about 25:75 to about 75:25.

[0015] The mixture may further comprise, as component (c), at least one compound of formula (III). [Chemical formula] Here, R3 represents a methyl group, an ethyl group, a methoxy group or an ethoxy group, and the dotted line means a single bond or a double bond. These ternary mixtures may consist of components (a + b) and component (c) in a weight ratio of from about 75:25 to about 99:1, preferably from about 80:20 to about 90:10.

[0016] <Synthesis> The present invention also encompasses a method for producing (5-isopropyl-2-methylene-cyclohexyl) acetate (= component I) comprising the following steps. (i) A step of providing 5-isopropyl-2-methylene-cyclohexanol, (ii) A step of providing acetyl acetate, and (iii) Reacting the 5-isopropyl-2-methylene-cyclohexanol with the acetyl acetate at a temperature in the range of from about 110 to about 130 °C, preferably from 115 to 125 °C, in the presence of an alkali source and an organic solvent.

[0017] Preferably, 5-isopropyl-2-methylene-cyclohexanol and acetyl acetate are reacted in a molar ratio of from about 1:1 to about 1:2, preferably from about 1:1.2 to about 1:1.7. A preferred alkali source is sodium carbonate and a preferred organic solvent is toluene.

[0018] <Perfume composition> As described, the novel fragrance according to formula (I) not only exhibits a fragrance of a desired profile, but in particular, when combined with components according to formula (II) and optionally (III), while increasing the pleasant notes of other fragrances, it is also possible to mask or even remove its unpleasant sub-notes. Thus, another object of the present invention is directed to such perfume compositions.

[0019] The fragrances forming the perfume composition (which are, of course, different from the components of formulas (I), (II), or (III)) can be used as single components or in the form of more or less complex mixtures. The species may be obtained from natural sources or prepared by organic synthesis.

[0020] <Natural fragrance> Natural fragrances include extracts from flowers (lily, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), fruit peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calamus), woods (pine wood, sandalwood, guaiac wood, cedarwood, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), needles and branches (spruce, fir, pine, dwarf pine), and resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax). Animal-derived ingredients such as civet and beaver may also be used.

[0021] <Synthetic fragrance> Typically, synthetic fragrances represent aldehydes, ketones, alcohols, ethers, esters, hydrocarbons, and mixtures thereof. Examples of these types of fragrances are listed below, but are not limited to them. • [(3,7-dimethyl-6-octenyl)-xy]-cetaldehyde · 1-(p-menten-6(2)-yl)-1-propanon • 1,2,3,4,5,6,7,8-Octahydro-8,8-dimethyl-2-naphthaldehyde · 10-Undesen-1-Al 10-Undesen-1-All 1-Decanal 1-Dodecanal • 1-Methyl-3-(4-methylpentyl)-3-cyclohexene-carboxyaldehyde • 1-Methyl-4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxyaldehyde 1-Nonanaar 1-Octanal 1-Octene-3-All • 1-p-menthen-q-carboxyaldehyde 1-Undekanal • 2-(2-(4-methyl-3-cyclohexen-1-yl)propyl)-cyclopentanone • 2,4,4,7-tetramethyl-octa-6-en-3-one • 2,4,6-trimethyl-3-cyclohexene-1-carboxyaldehyde • 2,4-dimethyl-3-cyclohexene-1-carboxyaldehyde 4-methoxybenzaldehyde • 2,4-dimethyl-3-cyclohexene-1-carboxyaldehyde • 2,6,10-trimethyl-5,9-undecadienal 2,6,10-trimethyl-9-undecenal,3-dodecene-1-al • 2,6-dimethyl-5-heptenal • 2,6-dimethylhept-5-en-1-al • 2,6-dimethylheptan-2-ol 2,6-nonadienal • 2-acetyl-3,3-dimethylnorbornane 2-Methyldecanal 2-Methyloctanal 2-Methylundecanal • 2-methyl-3-(4-tert-butyl)propanal • 2-Methyl-3-(isopropylphenyl)propanal • 2-methyl-3-(para-methoxyphenylpropanal) 2-methyl-3-phenyl-2-propene-1-al 2-Methyl-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-butenal • 2-methylbutanol • 2-methylpentanol 2-Phenoxyethanol 2-phenylpropane-1-al • 2-phenylpropanol • 2-tert-butylcyclohexanol • 3-(3,4-methylenedioxyphenyl)-2-methylpropane-1-al • 3-(3-isopropylphenyl)-butane-1-al • 3-(4-ethylphenyl)-2,2-dimethylpropane-1-al • 3-(4-ethylphenyl)-2,2-dimethylpropanal • 3-(4-isopropylphenyl)-2-methylpropane-1-al • 3-(4-methoxyphenyl)-2-methylpropanal 3-(4-tert-butylphenyl)-2-methylpropanal • 3-(4-tert-butylphenyl)-propanal • 3,4-Dimethoxybenzaldehyde • 3,4-Methylenedioxybenzaldehyde • 3,5,5-trimethylcyclohexanol • 3,5,5-trimethylhexanal • 3,5,6-trimethyl-3-cyclohexenecarboxyaldehyde 3,7-dimethyl-2-methylene-6-octenal • 3,7-dimethyl-6-octen-1-al • 3,7-dimethyloctane-1-al • 3-Ethoxy-4-hydroxybenzaldehyde 3-Hexanol • 3-Methoxy-4-hydroxy-benzaldehyde 3-methyl-5-phenyl-1-pentanal • 3-methyl-5-phenylpentanol • 3-octanol 3-phenyl-2-hexylpropa-2-enal 3-phenyl-2-pentylpropa-2-en-1-al • 3-phenyl-2-propenal 3-phenylpropane-2-en-1-al • 3-phenylpropanol • 3-Propyl-bicyclo[2.2.1]-hept-5-ene-2-carbaldehyde 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexanone • 4-(3)(4-methyl-3-pentenyl)-3-cyclohexene-carboxyaldehyde • 4-(4-hydroxy-3-methoxyphenyl)-2-butanone • 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxal-dehyde 4-(tricyclo[5.2.1.0(2,6)]-decylidene-8)-butanal. 4-Damaskol 4-heptenol • 4-Hydroxy-3-methoxybenzaldehyde • 4-Isopropylbenzylaldehyde • 4-Isopropylcyclohexanol • 4-Methoxybenzaldehyde 4-methylphenyl acetaldehyde • 4-tert-butylcyclohexanol • 5,9-dimethyl-4,8-decadienal • 5-Methoxyhexahydro-4,7-methanoindan-1-carboxyaldehyde • 5-Methoxyhexahydro-4,7-methanoindan-2-carboxyaldehyde • 6,10-dimethyl-3-oxa-5,9-undecadien-1-al • 6,6-dimethyl-2-norpinene-2-propionaldehyde • 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone • 6,8-dimethyl-2-nonanol, 6-nonen-1-ol • 6-Isopropyl-deca-hydro-2-naphthone • 6-Methoxyhexahydro-4,7-methanoindan-1-carboxyaldehyde • 6-Methoxyhexahydro-4,7-methanoindan-2-carboxyaldehyde • 7-Hydroxy-3,7-dimethyloctanal • 7-Methoxy-3,7-dimethyloctane-1-R 9-Decen-1-All 9-decenaral Acetophenone Adoxal • Allyl cyclohexylpropionate Alfa Ronen Ambroxane • Amyl salicylic acid Anethole • Anisaldehyde Benzaldehyde • Benzophenone Benzyl acetate Benzylacetone • Benzyl alcohol • Benzyl salicylate • Benzyl ethyl ether bourgeois • Buccoxim Butyl salicylate • Conference • Cantoxar · Carbon • Cachone Celery setton Chlorhydral • Thinner alcohol • cis- / trans-3,7-dimethyl-2,6-octadiene-1-al · SisJasmon • Citral or mixtures thereof • Citronellal • Citronellol • Citronellyl oxyacetaldehyde · Kumar • Cyclamenaldehyde • Cyclohexyl salicylate Simultaneous • Damarose • Damascene • Decanol Decyl aldehyde Delfon • Dihydrojasmone • Dihydromyrcenol • Dihydrodimaldehyde • Dihydro-β-ronone • Dimethylbenzylcarbinol • Dimethylbenzylcarbinyl acetate • Dimethylheptanol • Dimethyl octanol • Dimethyloctenone • Dulcinil Ethyl salicylate Ethyl vanillin • Ethylmethylphenylglycinate • Eugenol · Fenson • Furuuramon • Floral ozone • Flowmat Flow Hydral Gerson Geraniol • Hedione Helional Heliotropin Heptanol • Hexahydro-4,7-methanoindan-1-carboxyaldehyde Hexahydro-8,8-dimethyl-2-naphthaldehyde Hexalon • Hexyl salicylate • Hydroxycitronellal Isoborneol • Isodamascon Isoeugenol • Isojasmon Isoplegol Jasma McClatat Corebon • Laurinaldehyde • Listral • Lilial Citral • Lilial Limonene • Linalool Linalyl acetate • Ribcon Lilal m-cymene-7-carboxaldehyde Melonal · Melsat Menthol Menthon Methylacetophenone Methylcedrenyl ketone Methylcedrone Methylcedrone Methylcyclocitron Methyl dihydrojasmonate Methylheptenone Methyl lavender ketone Methyl dihydrojasmonate Methylnonylacetaldehyde Methyl-β-naphthylketone Mossus Indanone Muscon • Myrtenol n-dodecanal • Neobtenon Nerol n-hexanol Nonanol n-Undecanal Octahydro-4,7-methano-1H-indenecarboxyaldehyde. Octanal Octanol o-Methoxydimaldehyde · Oribon • p-ethyl-α,α-dimethylhydrodimaldehyde • Phenolic acid Phenoxyacetaldehyde. Phenoxyisobutyrate Phenylenacetaldehyde Phenyl salicylate Phenylate acetate Phenylate alcohol • p-hydroxyphenylbutanone • Pinen Pritone p-menthan-7-ol p-methoxyacetophenone • p-methylphenoxyacetaldehyde p-tert.-butinaru p-tert-butylcyclohexanone • p-tert-butyl cyclohexyl acetate p-Tolylacetaldehyde. Styryl propionate • Tetrahydrogeraniol Tetrahydrolinalool Tetramelan • Timor Tonalid / Moscus Plus • Trans-2-cis-6-nonadienol Trans-2-nonen-1-ol • Trans-2-octenol Trans-4-decenal Triple Undecanal Undecanol • Undecylenaldehyde Vanillin Velotone Verdon • α-methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde α-Damascon • α-methylbenzyl alcohol • α-methyl-4-(1-methylethyl)benzene-acetaldehyde • α-methylphenylacetaldehyde • α-n-amyl cinnamaldehyde • α-n-hexyl cinnamaldehyde • α-terpineol · β-Damascone β-ionone • β-terpineol • γ-methylionone, • δ-Damascone, and mixtures thereof.

[0022] Below is a list of some particularly favorite fragrances.

[0023] Woody fragrances are selected from the following group: [Table 1]

[0024] <Amber-scented fragrance> The amber-scented fragrance is selected from the following group: [Table 2]

[0025] <Fruity fragrance> Fruity fragrances are selected from the following group: [Table 3] JPEG0007896053000009.jpg8673

[0026] <Musk-scented fragrance> The musk-scented fragrance is selected from the following group: [Table 4]

[0027] The perfume composition according to the present invention may contain a fragrance according to formula (I) or a mixture according to formula (I), formula (II), and optionally formula (III) in an amount of about 0.001 to about 75% by weight, preferably about 0.01 to about 1% by weight, and most preferably about 0.02 to about 0.05% by weight.

[0028] <Cosmetic Compositions> Another object of the present invention relates to a cosmetic composition comprising, preferably in an amount of about 0.1 to about 5% by weight, more preferably about 0.2 to about 2% by weight, and most preferably about 0.5 to about 1% by weight, a fragrance according to formula (I), a mixture of fragrances according to formula (I), formula (II), and optionally formula (III), or a perfume composition containing the same. The composition may represent, for example, a cosmetic cream, lotion, spray, emulsion, ointment, gel, or mouth.

[0029] The formulations according to the present invention include anti-dandruff agents, anti-irritation agents, irritation inhibitors, antioxidants, astringents, sweat inhibitors, preservatives, antistatic agents, binders, buffers, carriers, chelating agents, cell stimulants, cleansing agents, care agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film-forming agents, fixing agents, foaming agents, foam stabilizers, anti-foaming agents, foam-enhancing agents, gelling agents, gel-forming agents, hair care agents, hair styling agents, hair straightening agents, moisture donors, humectants, moisturizers, bleaching agents, strengthening agents, stain removers, fluorescent whitening agents, impregnating agents, anti-fouling agents, friction reducers, lubricants, moisturizing creams, ointments, opacifiers, plasticizers, and covering agents. It may contain, as additional aids and additives, fatty acids, α-hydroxy acids, polyhydroxy fatty acids, liquefaction agents, dyes, color protectants, pigments, odorants, polyols, surfactants, electrolytes, organic solvents or silicone derivatives, etc., as additional aids and additives.

[0030] <Surfactants> Preferred additives and excipients are anionic surfactants and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants may also be present in the composition. Preferred examples are described in conjunction with the section dealing with emulsifiers.

[0031] Typical examples of anionic and zwitterionic surfactants include the following: Almondamidopropyl betaine, aminopropyl lauryl glutamine, C12-15 alkyl ammonium sulfate, C12-16 alkyl ammonium sulfate, capryleth sulfate ammonium, coco monoglyceride sulfate ammonium, coco sulfate ammonium, coco isethionate ammonium, cocoyl sarcosinate ammonium, C12-15 pareth sulfate ammonium, C9-10 perfluoroalkyl sulfonate ammonium, dinonyl sulfosuccinate ammonium, dodecylbenzenesulfonate ammonium, isostearate ammonium, laureth-6 carboxylate ammonium, laureth-8 carboxylate ammonium, laureth sulfate ammonium, laureth-5 sulfate ammonium, laureth-7 sulfate ammonium, laureth-9 sulfate ammonium, laureth-12 sulfate ammonium, lauroyl sarcosinate ammonium, lauryl sulfate ammonium, lauryl sulfosuccinate ammonium, myristyl sulfate ammonium, nonoxynol-4 sulfate ammonium, nonoxynol-30 sulfate ammonium, oleate ammonium, palm kernel sulfate ammonium, stearin Ammonium tarate, ammonium talate, AMPD-isostearoyl hydrolyzed collagen, AMPD-rosin hydrolyzed collagen, AMP-isostearoyl hydrolyzed collagen, AMP-isostearoyl hydrolyzed keratin, AMP-isostearoyl hydrolyzed soy protein, AMP-isostearoyl hydrolyzed wheat protein, apricotamidopropyl betaine, arachidic acid, hexyldecyl arginine phosphate, avocadoamidopropyl betaine, avocado oil glycereth-8 ester, babassu acid, babassuamidopropylamine oxide, babassu Midopropyl betaine, beeswax acid, behemidopropyl betaine, behenamine oxide, beheneth-25, beheneth-30, behenic acid, behenyl betaine, bis-butyldimethicone polyglyceryl-3, butoxynol-5 carboxylic acid, butoxynol-19 carboxylic acid, butyldimonium hydroxypropyl butyl glucoside chloride, isopropyl lauryl glucoside chloride, butyl glucoside, butyl glucoside caprate, butyl glucoside hydroxypropyltrimonium chloride, butyl octanoic acid, C18-36 acid, C20-40 acid,C30-50 acid, C16-22 acid amide MEA, calcium dodecylbenzenesulfonate, calcium lauroyl taurate, C9-16 alkane / cycloalkane, C10-14 alkylbenzenesulfonic acid, C12-14 alkyldiaminoethylglycine HCl, C9-15 alkyl phosphate, Candida bombicola / glucose / methyl rapeseed ferment, canolamidopropyl betaine, capric acid, caproic acid, caproyl ethyl glucoside, capryl / capramidopropyl betaine, capryleth-4 carboxylic acid, capryleth-6 carboxylic acid, capryleth- 9 Carboxylic Acid, Caprylic Acid, Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Caprylyl / Capryl Glucoside, Wheat Bran / Straw Glycoside, Caprylyl Glucoside, Caprylyl Glyceryl Ether, Caprylylpyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-3 3, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 carboxylic acid, Ceteareth-2 phosphate, Ceteareth-4 phosphate, Ceteareth-5 phosphate, Ceteareth-10 phosphate, Ceteareth-20, Ceteareth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 phosphate, Ceteth-10 phosphate, Ceteth-20 phosphate, Ceteth-22 phosphate, Ceteth-24, Ceteth-25, Ce-toleth- 30, Cetyl Betaine, Chrysanthemum Extract, C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropylamine Oxide, Cocamidopropyl Betaine Amidoamide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hydroxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid, Coceth-7 Carboxylic Acid, Coceth-4 Glucoside, Cocoamphodipropionic Acid, Cocobetaine Amidoamphopropionate, Cocobetaine,Cocodimonium hydroxypropyl hydrolyzed soy protein, cocodimonium hydroxypropyl hydrolyzed wheat protein, cocoglucoside, cocoglucoside hydroxypropyltrimonium chloride, cocohydroxysaltaine e, Co-co-morpholine oxide, coconut acid, coconut oil glycereth-8 ester, coco / oleamidopropyl betaine, cocosultaine, coco / sunflower amidopropyl betaine, cocoyl choline meth sulfate, cocoyl glutamate, cocoyl hydrolyzed collagen, cocoyl hydrolyzed keratin, cocoyl Hydrolyzed oat protein, cocoyl hydrolyzed rice protein, cocoyl hydrolyzed silk, cocoyl hydrolyzed soy protein, cocoyl hydrolyzed wheat protein, cocoyl sarcosine, corn acid, cottonseed acid, cottonseed oil glycereth-8 ester, C10-16 pareth-1, C10-16 pareth-2, C11-13 pareth-6, C11-13 pareth-9, C11-13 pareth-10, C11-15 pareth-30, C11-15 pareth-40, C12-13 pareth-1, C12-13 pareth-23, C12-14 pareth-5, C12-14 pareth-9, C13-1 5 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 carboxylic acid, C9-11 Pareth-8 carboxylic acid, C11-15 Pareth-7 carboxylic acid, C12-13 Pareth-5 carboxylic acid, C12-13 Pareth-7 carboxylic acid, C12-13 Pareth-8 carboxylic acid, C12-13 Pareth-12 carboxylic acid, C12-15 Pareth-7 carboxylic acid, C12-15 Pareth-8 carboxylic acid, C12-15 Pareth -12 carboxylic acid, C14-15 pareth-8 carboxylic acid, C6-10 pareth-4 phosphate, C12-13 pareth-2 phosphate, C12-13 pareth-10 phosphate, C12-15 pareth-6 phosphate, C12-15 pareth-8 phosphate, C12-15 pareth-10 phosphate, C12-16 pareth-6 phosphate, C4-18 perfluoroalkylethylthiohydroxypropyltrimonium chloride, cupuacuamidopropyl betaine, DEA-C12-13 alkyl sulfate, DEA-C12-15 alkyl sulfate, DEA-ceteareth-2 phosphate, DEA-cetyl sulfate,DEA-Cocoamphodipropionate, DEA-C12-13 Pareth-3 Sulfate, DEA-Cyclocarboxypropiolate, DEA-Do-Decylbenzenesulfonate, DEA-Isostearate, DEA-Laureth Sulfate, DEA-Lauryl Sulfate, DEA-Linoleate, DEA-Methyl Myristate Sulfonate, DEA-Myreth Sulfate, DEA-Myristate Sulfate, DEA-Myristyl Sulfate, DEA-Oleth-5 Phosphate, DEA-Oleth-20 Phosphate, DEA-PG-Oleic Acid, Deceth-7 Carboxylic Acid, Deceth-7 Glucoside, Deceth-9 Phosphate, Decylamine Oxide, Decylbetaine, Decyl Glucoside, Decyltetradeceth-30, Decyltetradecylamine Oxides, diammonium lauramide-MEA sulfosuccinate, diammonium lauryl sulfosuccinate, diammonium oleamide PEG-2 sulfosuccinate, dibutoxymethane, di-CI2-15 pareth-2 phosphate, di-CI2-15 pareth-4 phosphate, di-CI2-15 pareth-6 phosphate, di-C12-15 pareth-8 phosphate, di-CI2-15 pareth-10 phosphate, didodecyl butanetetracarboxylate, diethylamine laureth sulfate, diethylhexyl sulfosuccinate, dihydroxyethyl C8-10 alkoxypropylamine oxide, dihydroxyethyl C9-11 alkoxypropylamine oxide, dihydroxyethyl C12-15 alkoxypropylamine oxide, dihydroxyethyl cocamine oxide, dihydroxyethyl lauramine Oxide, dihydroxyethyl stearamine oxide, dihydroxyethyl tearamine oxide, dimethicone PEG-7 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone / polyglycerin-3 crosspolymer, dimethicone propyl PG-betaine, dimyristyl phosphate, dioleoylamide ethyl hydroxyethylmonium meth sulfate, DIPA-hydrogenated cocoate, DIPA-lanolate, DIPA-myristic acid, dipotassium capryloyl glutamate, dipotassium lauryl sulfosuccinate, desylenoyl glutamate, babassuamide MEA-disodium sulfosuccinate, disodium caproamphodipropionate, disodium capryloamphodiacetate,Disodium capryloamphodipropionate, disodium capryloyl glutamate, disodium cetearyl sulfosuccinate, disodium cetylphenyl ether disulfonate, cetyl sulfosuccinate, disodium cocamide MEA-sulfosuccinate, disodium cocamide MIPA PEG-4 sulfosuccinate, disodium cocamide MIPA-sulfosuccinate, disodium cocamide PEG-3 sulfosuccinate, disodium coceth-3 sulfosuccinate, disodium cocoamphocarboxyethyl hydroxypropyl sulfonate, cocoa Disodium phosphate disodium, disodium cocoamphodipropionate, disodium cocoglucoside sulfosuccinate, disodium cocosulfosuccinate, disodium cocoyl butylgluceth-10 sulfosuccinate, disodium cocoyl glutamate, disodium C12-14 pareth-1 sulfosuccinate, disodium C12-14 pareth-2 sulfosuccinate, disodium C12-15 pareth sulfosuccinate, C12-14 Sec-pareth-3 sulfosuccinate, disodium C12-14 Sec-pareth-5 sulfosuccinate, disodium C1 2-14Sec-Pareth-7 sulfosuccinate, disodium C12-14Sec-Pareth-9 sulfosuccinate, disodium C12-14Sec-Pareth-12 sulfosuccinate, disodium deceth-5 sulfosuccinate, disodium deceth-6 sulfosuccinate, disodium decylphenyl ether disulfonic acid, disodium dihydroxyethyl sulfosuccinyl undecylenate, ethylene dicoamide PEG-15 disulfate, disodium hydrogenated cottonseed glyceride sulfosuccinate, disodium hydrogenated tallow glutamate, hydroxydecyl sorbate Disodium tol citrate, disodium isodecyl sulfosuccinate, disodium isostearic acid amide MEA-sulfosuccinate, disodium isostearamid MIPA-sulfonyl disodium oxidate, disodium isostearoamphodiacetate, disodium isostearoamphodipropionate, disodium isostearyl sulfosuccinate, disodium lanes-5 sulfosuccinate, disodium lauramide MEA sulfosuccinate, disodium lauramide MIPA glycol sulfosuccinate, disodium lauramide PEG-2 sulfosuccinate,Lauramide disodium PEG-5 sulfosuccinate, laureth-5 carboxyamphodiacetate disodium, laureth-7 citrate disodium, laureth-sulfosuccinate disodium, laureth-6 sulfosuccinate disodium, laureth-9 sulfosuccinate disodium, laureth-12 sulfosuccinate disodium, lauriminobishydroxypropyl sulfo, Disodium lauryl sulfate, disodium lauriminodiacetate, disodium lauriminodipropionate, disodium lauriminodipropionate tocopheryl phosphate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium N-lauroyl aspartate, disodium lauroyl glutamate-mate, disodium laurylphenyl ether disulfonate, disodium lauryl sulfosuccinate, myristamide MEA-sulfosuccinate disodium, nonoxynol-10 sulfosuccinate disodium, oleamide M EA-Disodium Sulfosuccinate, Oleamide MIPA-Disodium Sulfosuccinate, Oleamide PEG-2 Disodium Sulfosuccinate, Oleoamphodipropionate Disodium, Oleth-3 Disodium Sulfosuccinate, Oleyl Phosphate Disodium, Oleyl Sulfosuccinate Disodium, Palmitoamide PEG-2 Disodium Sulfosuccinate, Palmitoamide PEG-2 Disodium Sulfosuccinate, PEG-4 Cocamide MIPA-Disodium Sulfosuccinate, PEG-12 Dimethicone Disodium Sulfosuccinate, PEG -8 Palm glyceride disodium sulfosuccinate, PPG-2-isodeceth-7 carboxyamphodiacetate disodium, ricinolamide MEA disodium sulfosuccinate, sitostereth-14 disodium sulfosuccinate, soybean disodium diacetate, stearamide MEA disodium sulfosuccinate, steariminodipropionate disodium, stearo disodium amphodiacetate, stearoylgluconide disodium tamaic acid, stearyl sulfosuccinate disodium, stearyl sulfosuccinate disodium, 2-sulfolaurin Disodium tallow acid, disodium 2-sulfopalmitate, disodium tarouamide MEA-sulfosuccinate, disodium tarouamide MEA-sulfosuccinate, disodium tarouamphodiacetate, disodium tarouiminodipropionate, disodium animal fat sulfosuccinate, disodium tridecyl sulfosuccinate, disodium undecylenamide MEA-sulfosuccinate, disodium undecylnaminamide PEG-2 sulfosuccinate, disodium glutamate undecylenoyl, disodium wheat germamide MEA-sulfosuccinate,Disodium wheat germamide PEG-2 sulfosuccinate, disodium wheat germanhodiacetate, di-TEA-cocamide diacetate, di-TEA-oleamide PEG-2 sulfosuccinate, di-TEA-palmitoyl aspartate, ditridecyl sodisulfosuccinate, dodecylbenzenesulfonic acid, ercamidopropyl hydroxysultaine, ethylhexet-3 carboxylic acid, ethyl PEG-15 cocamine sulfate, glyceryl capryl ether, hexyldecanoic acid, hydrogenated coconut acid, hydrogenated lenth-25, hydrogenated menhardic acid, palm acid, hydrogenated palm kernel Amine oxide, hydrogenated tallow acid, hydrogenated tallow amine oxide, hydrogenated tallow betaine, hydrogenated tallow-25, hydrogenated tallow glutamic acid, hydrolyzed Candida bombicola extract, hydroxyceteth-60, hydroxyethylacetomonium PG-dimethicone, hydroxyethyl-butylamine laureth sulfate, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethylyl C12-15 alkoxypropylamine oxide, hydroxylauryl / hydroxymyristyl betaine, hydroxystearic acid, hydroxysuccinimidyl C10 -40 Isoalkylate, Hydroxysuccinimidyl C21-22 Isoalkylate, Hydroxysultaine, IPDI / PEG-15 Soy Oxide Copolymer, IPDI / PEG-15 Soethonium Ethosulfate Copolymer, IPDI / PEG-15 Soy Glycinate Copolymer, Isoceteth-30, Isolaureth-4 Phosphate, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethiconol, Isopropanolamine Lanolate, Isopropylamine Dodecylbenzenesulfonic Acid, Isostearamidopropylamine Oxide, Isostea Lamidopropyl betaine, Iarmidopropyl morpholine oxide, Isosteareth-8, Isosteareth-16, Isosteareth-22, Isosteareth-25, Isosteareth-50, Isostearic acid, Isostearoyl hydrolyzed collagen, Jojoba oil PEG-150 ester, Jojoba wax PEG-80 ester, Jojoba wax PEG-120 ester, Lane-20, Lane-25, Lane-40, Lane-50, Lane-60, Lane-75, Lanolinic acid, Lauramidopropylamine oxide, Lauramidopropyl betaine,Lauramidopropyl hydroxysultaine, lauramine oxide, lauraaminopropionic acid, laurdimonium hydroxypropyl decyl glucoside chloride, laurdimonium hydroxypropyl lauryl glucoside chloride, laureth-16, laureth-20, laureth-21, laureth-23, -25, laureth-30, laureth-38, laureth-40, laureth-3 carboxylic acid, laureth-4 carboxylic acid, laureth-5 carboxylic acid, laureth-6 carboxylic acid, laureth-8 carboxylic acid, laureth-10 carboxylic acid, laureth-11 carboxylic acid Acids, Laureth-12 carboxylic acid, Laureth-13 carboxylic acid, Laureth-14 carboxylic acid, Laureth-17 carboxylic acid, Laureth-6 citric acid, Laureth-7 citric acid, Laureth-1 phosphate, Laureth-2 phosphate, Laureth-3 phosphate, Laureth-4 phosphate, Laureth-7 phosphate, Laureth-8 phosphate, Laureth-7 tartrate, Lauric acid, Lauriminobispropanediol, Lauriminodipropionic acid, Lauroyl beta-alanine, Lauroyl collagen amino acids, Lauroyl ethyltrimonium meth sulfate, Lauroyl hydrolyzed collagen, Lauroyl Hydrolyzed elastin, lauroyl methylglucamide, cosine, lauroyl silk amino acids, lauryl betaine, lauryl dimethicone / polyglycerin-3 crosspolymer, lauryldimonium hydroxypropyl cocoglucoside chloride, lauryl glucoside, lauryl glucoside hydroxypropyltrimonium chloride, lauryl glycol hydroxypropyl ether, lauryl hydroxysaltaine, lauryl maramide, lauryl methylglucamide, lauryl / myristyl glycol hydroxypropyl ether, lauryl / myristyl Wheat bran / straw glycosides, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, laurylpyrrolidone, lauryl sultaine, linoleic acid, linolenic acid, flaxseed acid, lysine cocoate, macadamia seed oil glycereth-8 ester, magnesium coceth sulfate, magnesium coco sulfate, magnesium isododecylbenzenesulfonate, magnesium laureth-11 carboxylate, magnesium laureth sulfate, magnesium laureth-5 sulfate, magnesium laureth-8 sulfate, magnesium laureth-16 sulfate, magnesium laureth-3 sulfosuccinate,Magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium cocoyl methyl taurate, magnesium myreth sulfate, magnesium oleth sulfate, magnesium / TEA-coco sulfate, manicouagan clay, MEA-coco acid, MEA-laureth-6 carboxylic acid, MEA-laureth sulfate, MEA-lauryl sulfate, MEA-PPG-6 laureth-7 carboxylate, MEA-PPG-8-steareth-7 carboxylate, MEA-undecylenic acid, meloxapol 108, meloxapol 174, meloxapol 178, Meloxapol 254, Meloxapol 255, Meloxapol 258, Meloxapol 314, MethoxyPEG-450 Amidoglutaloylsuccinimide, MethoxyPEG-450 Amidohydroxysuccinimidylsuccinamate, MethoxyPEG-450 Maleimide, Methylmorpholine Oxide, Myamidopropylamine Oxide, Myamidopropyl Betaine, Mincamidopropylamine Oxide, Mincamidopropyl Betaine, MIPAC 12-15 Pareth Sulfate, MIPA-Dodecylbenzenesulfonic Acid, MIPA-Laureth Sulfate, MIPA-Lauryl Sulfate, Mixed Isopropanolamine Lanolate, Mixed Isopropanolamine Lauryl Sulfate, Mixed Isopropanolamine Myristic Acid, Morpholine Oleate, Morpholine Stearate, Myreth-3 Carboxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamine Oxide, Myristamine Taminopropionic acid, myristic acid, myristoyl ethyltrimonium methosulfate, myristoyl glutamic acid, myristoyl hydro-lysed collagen, myristoyl sarcosine, myristyl betaine, myristyl / cetylamine oxide, myristyldimonium hydroxypropyl coco-glucoside chloride, myristyl glucoside, myristyl phosphate, nonoxynol-20, nonoxynol-23, nonoxynol-25, nonoxynol-30, nonoxynol-35, nonoxynol-40, nonoxynol-44, nonoxynol-50,Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 carboxylic acid, Nonoxynol-8 carboxylic acid, Nonoxynol-10 carboxylic acid, Nonoxynol-3 phosphate, Nonoxynol-4 phosphate, Nonoxynol-6 phosphate, Nonoxynol-9 phosphate, Nonoxynol-10 phosphate, Nonylnonoxynol-30, Nonylnonoxynol-49, Nonylnonoxynol-100, Nonylnonoxynol-150, Nonylnonoxynol-7 phosphate, Nonylnonoxynol-8 phosphate, Nonylnonoxynol-9 phosphate, Nonyl Nonoxynol-10 phosphate, Nonylnonoxynol-11 phosphate, Nonylnonoxynol-15 phosphate, Nonylnonoxynol-24 phosphate, Oatamidopropyl betaine, Octoxynol-16, Octoxynol-25, Octoxynol-30, Octoxynol-33, Octoxynol-40, Octoxynol-70, Octoxynol-20 carboxylic acid, Octyldodeceth-20, Octyldodeceth-25, Oc-Tyldodeceth-30, Oleamidopropylamine oxide, Oleamidopropyl betaine, Oleamidopropyl Droxysultaine, oleamine oxide, oleic acid, oleoyl hydrolyzed collagen, oleoyl sarcosine, oleth-20, oleth-23, oleth-24, oleth-25, oleth-30, oleth-35, oleth-40, oleth-44, oleth-50, oleth-3 carboxylic acid, oleth-6 carboxylic acid, oleth-10 carboxylic acid, oleyl betaine, olibamidopropylamine oxide, olibamidopropyl betaine, olivary acid, oliboyl hydrolyzed wheat protein, ophiopogon extract stearate, ozonated oleth-10, ozonated ole PEG-10 oleate, PEG-14 ozonated oleate, ozonated polysorbate 80, palm acid, palmamidopropyl betaine, palmes-2 phosphate, palmitamidopropylamine oxide, palmitamidopropyl betaine, palmitamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoyl glycine, palmitoyl hydrolyzed collagen, palmitoyl hydrolyzed milk protein, palmitoyl hydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptide, palmitoyl silk amino acids, palm nucleic acid,Palm kernel amidopropyl betaine, peach kernel oil glycereth-8 ester, peanut acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil, PEG-60 castor oil, PEG-80 castor oil, PEG-100 castor oil, PEG-200 castor oil, PEG-11 cocamide, PEG, -6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibehenate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Diolic Acid, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl cocoate, PEG-80 glyceryl cocoate, PEG-30 glyceryl isostearate, PEG-40 glyceryl isostearate, PEG-50 glyceryl isostearate, PEG-60 glyceryl isostearate, PEG-90 glyceryl isostearate, PEG-23 glyceryl laurate, PEG-30 glyceryl laurate, PEG-25 glyceryl oleate, PEG-30 glyceryl oleate, PEG-30 glyceryl soybean, PEG-25 glyceryl stearate, PEG-30 glyceryl stearate, PEG-40 glyceryl Glyceryl stearate, PEG-120 glyceryl stearate, PEG-200 glyceryl stearate, PEG-28 tallow glyceryl, PEG-80 tallow glyceryl, PEG-82 tallow glyceryl, PEG-130 tallow glyceryl, PEG-200 tallow glyceryl, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-54 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-30 hydrogenated lanolin, PEG-70 hydrogenated lanolin Nolin, PEG-50 Hydrogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Isostearate, Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin,PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lauramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70 Mango Glyceride Laurate, PEG-20 Mannitane Laurate, PEG-8 Methyl Ether Dimethicone Cone, PEG-120 methyl glucose dioleate, PEG-80 methyl glucose laurate, PEG-120 methyl glucose trioleate, PEG-4 montanic acid, PEG-30 oleic acid, PEG-20 oleic acid, PEG-23 oleic acid, PEG-32 oleic acid, PEG-36 oleic acid, PEG-75 oleic acid, PEG-150 oleic acid, PEG-20 palmitic acid, PEG-150 polyglyceryl-2 tristearate, PEG / PPG-28 / 21 dimethicone acetate, PEG / PPG-24 / 18 butyl ether dimethicone Thicone, PEG / PPG-3 / 17 copolymer, PEG / PPG-5 / 35 copolymer, PEG / PPG-8 / 55 copolymer, PEG / PPG-10 / 30 copolymer, PEG / PPG-10 / 65 copolymer, PEG / PPG-12 / 35 copolymer, PEG / PPG-16 / 17 copolymer, PEG / PPG-20 / 9 copolymer, PEG / PPG-20 / 20 copolymer, PEG / PPG-20 / 60 copolymer, PEG / PPG-20 / 65 copolymer, PEG / PPG-22 / 25 copolymer, PEG / PPG-28 / 30 copolymer - PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer, PEG / PPG-20 / 22 methyl ether dimethicone, PEG-26-PPG-30 phosphate, PEG / PPG-4 / 2 propylheptyl ether,PEG / PPG-6 / 2 propylheptyl ether, PEG-7 / PPG-2 propylheptyl ether, PEG / PPG-8 / 2 propylheptyl ether, PEG / PPG-10 / 2 propylheptyl ether, PEG / PPG-14 / 2 propylheptyl ether, PEG / PPG-40 / 2 propylheptyl ether, PEG / PPG-10 / 2 ricinoleate, PEG / PPG-32 / 3 ricinoleate, PEG-55 propylene glycol oleate, PEG-25 propylene glycol stearate, PEG-75 propylene glycol stearate Coal, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterols, PEG-10 Rapeseed Sterols, PEG-40 Ricinolamide, PEG-75 Shea Butter Glycerides, PEG-75 Shorea Butter Glycerides, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Lauric Acid, PEG-40 Sorbitan Lauric Acid, PEG-44 Sorbitan Lauric Acid, PEG-75 Sorbitan Lauric Acid, PEG- 80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soybean Sterols, PEG-2 Stearamide Carboxylic Acid, PEG-9 Stearamide Carboxylic Acid, PEG-20 Stearic Acid, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, Stear PEG-40 phosphate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 talate, PEG-50 tallow amide, PEG-2 tar-low amide DEA, PEG-20 tallow, PEG-66 trihydroxystearin, PEG-200 trihydroxystearin, PEG-60 glyceride tallowate, pelargonic acid,Pentadoxynol-200, Fenes-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Poloxamine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether - Polyglyceryl sesquioxane, Polyglyceryl-6 caprate, Polyglyceryl-10 dilaurate, Polyglyceryl-20 heptacaprylate, Polyglyceryl-20 hexacaprylate, Polyglyceryl-2 lauryl ether, Polyglyceryl-10 lauryl ether, Polyglyceryl-20 octaisononanoate, Polyglyceryl-6 pentacaacrylate, Polyglyceryl-10 pentacaacrylate, Polyglyceryl-3 polydimethylsiloxyethyl dimethicone, Polyglyceryl-6 tetracaprylate, Polyglyceryl-10 tetralaurate, Polyglyceryl Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82, Pomadelis Cumera Flower / Leaf Extract, Polyaca Palm Extract, Abietoyl Hydrolyzed Collagen Potassium, Babassuate Potassium, Behenate Potassium, C9-15 Alkyl Phosphate Potassium, C11-15 Alkyl Phosphate Potassium, C12-13 Alkyl Phosphate Potassium, C12-14 Alkyl Phosphate Potassium, Caprylic Acid Potassium capryloyl glutamate, potassium capryloyl hydrolyzed rice protein, potassium causticate, potassium coconutate, potassium cocoyl glutamate, potassium cocoyl glycinate, potassium cocoyl hydrolyzed caseinate, potassium cocoyl hydrolyzed collagen, potassium cocoyl hydrolyzed corn protein, potassium cocoyl hydrolyzed keratin, potassium cocoyl hydrolyzed oat protein, potassium cocoyl hydrolyzed potato protein, potassium cocoyl hydrolyzed rice bran protein, potassium cocoyl hydrolyzed rice protein,Potassium cocoyl hydrolyzed silk, potassium cocoyl hydrolyzed soy protein, potassium cocoyl hydrolyzed wheat protein, potassium cocoyl hydrolyzed yeast protein, potassium cocoyl PCA, potassium cocoyl sarcosinate, potassium cocoyl taurate, potassium cornate, potassium cyclocarboxypropylophosphate, dihydroxyethyl cocamine potassium oxidized phosphate, dimethicone PEG-7 phosphate potassium, potassium dodecylbenzenesulfonate, potassium hemp seed acid, hydrogenated potassium coconutate, hydrogenated potassium palmitate, hydrogenated potassium tallowate, potassium hydroxystearate, potassium isostearate, potassium lanolate, potassium laurate, potassium laureth-3 carboxylate, potassium laureth-4 carboxylate, potassium laureth-5 carboxylate, potassium laureth-6 carboxylate, potassium laureth-10 carboxylate, potassium laureth phosphate, potassium lauroyl collagen amino acid, potassium lauroyl glutamate, potassium lauroyl hydrolyzed collagen, hydrolyzed lauroyl potassium pea protein, potassium lauroyl potassium hydrolyzed soy protein, potassium lauroyl potassium PCA A, Lauroyl pea amino acid potassium, Lauroyl sarcosinate potassium, Lauroyl silk amino acid potassium, Lauroyl wheat amino acid potassium, Lauryl phosphate potassium, Lauryl sulfate potassium, Linoleate potassium, Metaphosphate potassium, Methyl cocoyl taurate potassium, Myristate potassium, Myristoyl glutamate potassium, Myristoyl hydrolyzed collagen potassium, Octoxynol-12 phosphate potassium, Oleate potassium, Oleoyl hydrolyzed collagen potassium, Oliveate potassium, Oliboyl hydrolyzed wheat protein potassium, Oliboyl / lauroyl wheat protein potassium, Oliboyl potassium PCA, Palmitate potassium, Palmitate potassium, Palmitoyl hydrolyzed corn protein potassium, Palmitoyl hydrolyzed oat protein potassium, Palmitoyl hydrolyzed rice protein potassium, Palmitoyl hydrolyzed sweet almond protein potassium, Palmitoyl hydrolyzed wheat protein potassium, Palm cereal acid potassium, Peanut acid potassium, Rapeseed acid potassium, Ricinoleate potassium, Safflower acid potassium, Soybean acid potassium, Stearate potassium,Potassium stearoyl hydrolyzed collagen, potassium talate, potassium talurate, potassium taurate, potassium taurine laurate, potassium trideceth-3 carboxylate, potassium trideceth-4 carboxylate, potassium trideceth-7 carboxylate, potassium trideceth-15 carboxylate, potassium trideceth-19 carboxylate, potassium trideceth-6 phosphate, Potassium trideceth-7 phosphate, potassium tetrate, potassium undecylenate, potassium undecylenoyl potassium hydrolyzed collagen, potassium undecylenoyl potassium hydrolyzed rice protein, PPG-30-buteth-30, PPG-36-buteth-36, PPG-38-buteth-37, PPG-30-capryleth-4 phosphate, PPG-10 cetyl ether phosphate, PPG-2C9-11 pareth-8, PPG-1-deceth-5, PPG-3-deceth-2 carboxylic acid, PPG-30 ethylhexeth-4 phosphate, PPG-20-glycereth-30, PPG- 2-Hydroxyethyl Coco-Isostearamide, PPG-2-Isodeceth-8, PPG-2-Isodeceth-10, PPG-2-Isodeceth-18, PPG-2-Isodeceth-25, PPG-4-Isodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Acid, Rice Bran Acid, Rice Oil Glycereth-8 Ester, Ricinolamidopropyl Betaine, Ricinoleic Acid, Ricinoleth-40, Safflower Acid, Sapinaria Sapindus Fruit Extract, Saponaria Officinalis Root Powder, Saponin, Soap-K, Soap-Sodium / K, Soap Soap, Soap Soap-K, Sesame Oil Glycereth-8 Ester, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butter Theamidopropyl Betaine, Shea Butter Glycereth-8 Ester, Sodium Arachidate, Sodium Arganamphoacetate, Sodium Astrocaryum Murumurate, Sodium Avocadoate, Sodium Babassuamphoacetate, Sodium Babassuate, Sodium Babassu Sulfate, Sodium Behenate, Sodium Bisglycol Ricinosulfosuccinate, Bishydroxyethyl Sodium lysinate cocoglucoside crosspolymer, bishydroxyethyl sodium glycinate lauryl glucoside crosspolymer, borage amidopropyl PG-dimonium chloride sodium phosphate, butoxynol-12 sodium sulfate, butyl glucoside sodium, hydroxypropyl phosphate, C13-17 sodium alkanesulfonate, C14-18 sodium alkanesulfonate, C12-15 alkoxypropyl iminodipropionate sodium, C10-16 alkyl sulfate sodium, C11-15 alkyl sulfate sodium,C12 sodium-13 alkyl sulfate, C12-15 alkyl sulfate sodium, C12-18 alkyl sulfate sodium, C16-20 alkyl sulfate sodium, C9-22 alkyl sec sulfonate sodium, C14-17 alkyl sec sulfonate sodium, caprate sodium, caproamphoacetate sodium, caproamphohydroxypropyl sulfonate sodium, caproamphopropionate sodium, caproyl methyltaurate sodium, caprylate sodium, capryleth-2 carboxylate sodium, capryleth-9 carboxylate sodium Thorium, sodium capryloamphoacetate, sodium capryloamphohydroxypropyl sulfonate, sodium capryloamphopropionate, sodium capryloyl glutamate, capryloyldium hydrolyzed wheat protein, sodium caprylyl PG-sulfonate, sodium caprylyl sulfonate, sodium castrate, sodium ceteareth-13 carboxylate, sodium cetearyl sulfate, sodium ceteth-13 carboxylate, sodium cetyl sulfate, cocamidopropyl PG-chloride sodium phosphate, sodium cocaminopropionate, Sodium coceth sulfate, sodium coceth-30 sulfate, sodium cocoa butter amphoacetate, sodium cocoa butterate, sodium cocoamphoacetate, sodium cocoamphohydroxypropyl sulfonate propionate, sodium cocoate, sodium coco / babassu / andiroba sulfate, sodium coco / babassu sulfate, sodium cocoglucoside hydroxypropyl phosphate, sodium cocoglucoside hydroxypropyl sulfonate, sodium cocoglucoside tartrate, sodium cocoglyceryl ether sulfonate, cocoglyceryl ether sulfonate Sodium cocoate, sodium cocoglucoside hydroxypropyl phosphate, sodium cocoglucoside hydroxypropyl sulfonate, sodium cocoiminodiacetate, sodium cocomonoglyceride sulfate, sodium cocomonoglyceride sulfonate, sodium cocoPG-dimonium chloride phosphate, sodium cocosulfate, sodium cocosulfoacetate, sodium cocoyl alaninate, sodium cocoyl amino acid, sodium cocoyl collagen amino acid, sodium cocoyl glutamate, sodium cocoyl glutamate, sodium cocoyl glycinate,Sodium cocoyl / glutamate hydride, sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed rice protein, sodium cocoyl hydrolyzed silk, sodium cocoyl hydrolyzed soy protein, sodium cocoyl hydrolyzed sweet almond protein, sodium cocoyl hydrolyzed wheat protein, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl isethionate, sodium cocoyl methylaminopropionate, sodium cocoyl oat amino acid, sodium cocoyl / palmoyl / sunflower oil glutamate, sodium cocoyl proline, sodium cocoyl sarcosinate, sodium cocoyl tau phosphate, sodium cocoyl sodium threonine, sodium cocoyl wheat amino acid, sodium C12-14 olefin sulfonate, sodium C14-16 olefin sulfonate, sodium C14-18 olefin sulfonate, sodium C16-18 olefin sulfonate, sodium cornum phosphonate, sodium cottonseed danphoacetate, sodium C13-15 pareth-8 butyl phosphate Thorium, C9-11 Pareth-6 carboxylate sodium, C11-15 Pareth-7 carboxylate sodium, C12-13 Pareth-5 carboxylate sodium, C12-13 Pareth-8 carboxylate sodium, C12 sodium-13 Pareth-12 carboxylic acid, sodium C12-15 Pareth-6 carboxylic acid, sodium C12-15 Pareth-7 carboxylic acid, sodium C12-15 Pareth-8 carboxylic acid, sodium C14-15 Pareth-8 carboxylic acid, sodium C12-14 Sec-Pareth-8 carboxylate sodium, C14-15 Pareth-P Sodium G sulfonate, C12-13 pareth-2 sodium phosphate, C13-15 pareth-8 sodium phosphate, C9-15 pareth-3 sodium sulfate, C10-15 pareth sulfate sodium, C10-16 pareth-2 sulfate, sodium C12-13 pareth sulfate, sodium C12-15 pareth sulfate, sodium C12-15 pareth-3 sulfate, sodium C13-15 pareth-3 sulfate, sodium C12-14 Sec-pareth-3 sulfate, C12-15 pareth-3 sodium sulfonate, C12-15 pareth-7 sodium sulfonate,Sodium C12-15 Pareth-15 Sulfonate, Sodium Deceth-2 Carboxylate, Sodium Deceth Sulfate, Sodium Decylbenzenesulfonate, Sodium Decyl Glucoside Hydroxypropyl Phosphate, Sodium Decyl Glucoside Hydroxypropyl Sulfonate, Sodium Dilaureth-7 Citrate, Sodium Dilaureth-10 Phosphate, Dilinolamidopropyl PG-Dimonium Chloride Phosphate, Sodium Dilinoleate, Sodium Dioleth-8 Phosphate, Sodium Do-Decylbenzenesulfonate, Sodium Ethyl 2-Sulfolaurate, Sodium Glyceryl Oleate Phosphate, Sodium Grapeseed Amidopropyl PG-Dimonium Chloride Phosphate, Sodium Grapeseed Danphoacetate, Sodium Grapeseed Acidate, Sodium Hempseeed Danphoacetate, Sodium Hexeth-4 Carboxylate, Sodium Hydrogenated Cocoate, Sodium Hydrogenated Cocoyl Methionate-Iseshionate, Sodium Hydrogenated Palmitate, Sodium Hydrogenated Fat Acidate, Sodium Hydrogenated Fat Glutamate, Sodium Hydroxyl Lauryl Dimonium Ethyl Phosphate, Hydroxypropyl Palm Kernelate Sulfate Sodium phosphate, sodium hydroxypropyl phosphate decyl glucoside crosspolymer, sodium lauryl glucoside crosspolymer, sodium hydroxypropyl sulfonate coco glucoside crosspolymer, sodium hydroxypropyl sulfonate decyl glucoside crosspolymer, sodium hydroxypropyl sulfonate, lauryl glucoside crosspolymer, sodium hydroxystearate, sodium isostearate, sodium isosteareth-6 carboxylate, sodium isosteareth-11 carboxylate, sodium isostearoamphoacetate, sodium isostearoamphopropionate, sodium N-isostearoyl methyltaurate, sodium laureth sulfate, sodium lanolate, sodium lardoate, sodium lauramide diacetate, sodium lauraminopropionate, lauric acid, sodium laureth-3 carboxylate, sodium laureth-4 carboxylate, sodium laureth-5 carboxylate, sodium laureth-6 carboxylate, sodium laureth-8 carboxylate, sodium laureth-11 carboxylate, sodium laureth-12 carboxylate,Sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, sodium laureth-16 carboxylate, sodium laureth-17 carboxylate, sodium laureth sulfate, sodium laureth-5 sulfate, sodium laureth-7 sulfate, sodium laureth-8 sulfate, sodium laureth-12 sulfate, sodium laureth-40 sulfate, sodium laureth-7 tartrate, sodium lauriminodipropionate, sodium lauroamphoacetate, sodium lauroamphohydroxypropyl sulfonate, sodium lauroamphoPG acetate phosphate, sodium lauroamphopropionate, sodium lauroyl aspartate, sodium lauroyl collagen amino acid, sodium lauroyl glycine propionate, lauroyl hydrolyzed collagen, sodium lauroyl hydrolyzed silk, sodium lauroyl hydroxypropyl sulfonate, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl methyl isethionate, sodium lauroyl kibi amino acid, sodium lauroyl / myristoyl aspartate, lauroyl o Sodium wheat amino acids, uroyl sarcosinate, sodium lauroyl silk amino acids, sodium lauroyl taurate, sodium lauroyl wheat amino acids, sodium lauryl diethylenediaminoglycinate, sodium lauryl glucose carboxylate, sodium lauryl glucoside hydroxypropyl phosphate, sodium lauryl glucoside hydroxypropyl sulfonate, sodium lauryl glycol carboxylate, sodium lauryl hydroxyacetamide sulfate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium linoleate, sodium macadamia seed acid, sodium mango amphoacetate, sodium mango seed acid, sodium laureth-2 sulfosuccinate / MEA, sodium methoxyPPG-2 acetate, sodium cocoyl methyl taurate, sodium methyl lauroyl taurate, sodium methylmyristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearoyl taurate, sodium methyl 2-sulfolaurate, sodium methyl 2-sulfopalmitate,Sodium methyl taurate isopalmitamide, sodium cocoyl methyl taurate, sodium myris sulfate, sodium myristate, sodium myristoamphoacetate, sodium myristoyl glutamate, sodium myristoyl hydrolyzed collagen, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium myristyl sulfate, nonoki, Sodium cinol-6 phosphate, sodium nonoxynol-9 phosphate, sodium nonoxynol-1 sulfate, sodium nonoxynol-3 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 sulfate, sodium nonoxynol-8 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-25 sulfate, sodium octooxynol-2 ethanesulfonate, sodium octooxynol-2 sulfate, sodium octooxynol-6 sulfate, sodium octooxynol-9 sulfate, sodium oleate, oleoamphovinegar Sodium oleopropyl sulfate, sodium oleoamphohydroxypropyl sulfonate, sodium oleoamphopropionate, sodium oleoyl hydrolyzed collagen, sodium oleoyl isethionate, sodium oleeth sulfate, sodium oleyl methyl isethionate, sodium oleyl sulfate, sodium olivanoacetate, sodium olivoyl glutamate, sodium palmanphoacetate, sodium palmitate, sodium palm glyceride sulfonate, sodium palmitate, sodium palmitoyl hydrolyzed collagen, sodium palmitoyl hydrolyzed wheat protein, sodium palmitoyl sarcosinate, sodium palm nucleotide, sodium palm kernelyl isethionate, sodium palmoyl glutamate, sodium passionflower seed, sodium peanut sulfate, sodium PEG-6 cocamide carboxylate, sodium PEG-8 cocamide carboxylate, sodium PEG-4 cocamide sulfate, sodium PEG-3 lauramide carboxylate, sodium PEG-4 lauramide carboxylate, sodium PEG-8 palm glyceride carboxylate Um, Pentaerythritylhydroxypropyliminodiacetate sodium, Dendrimer, Sodium propoxy PPG-2 acetate, Sodium rapeseed, Rice bran phoacetate sodium, Sodium ricinoleate, Rice hypsam phoacetate sodium, Sodium rosinate, Sodium safflower phosphate, Safflower oil hydrolyzed soy protein sodium, Sesame seed phosphate sodium, Sesanphoacetate sodium, Sciabutoteran phoacetate sodium, Soybean phosphate sodium, Soybean hydrolyzed collagen sodium, Sodium stearate,Sodium stearoamphoacetate, sodium stearoamphohydroxypropyl sulfonate, sodium stearoamphopropionate, sodium stearoyl caseinate, sodium stearoyl glutamate, sodium stearoyl hyaluronate, hydrolyzed stearoyl sodium zet collagen, sodium stearoyl hydrolyzed corn protein, sodium stearoyl hydrolyzed silk, sodium stearoyl hydrolyzed soy protein, sodium stearoyl hydrolyzed wheat protein, sodium stearoyl lactalbumin, sodium stearoyl methyl isethionate, sodium stearoyl oat protein, sodium stearoyl pea protein, sodium stearoyl soy protein, sodium stearyldimethylglycine, sodium stearyl sulfate, sodium sunflower seed danphoacetate, sodium surfactin, sodium sweet almond amphoacetate, sodium sweet almondate, sodium talum phopropionate, sodium talate, sodium tallow amphoacetate, sodium tallow sulfate, sodium tallow sulfate, tamanu Sodium septate, sodium taurate, sodium taurine cocoyl methyl taurate, sodium taurine laurate, sodium lauroyl collagen / TEA amino acids, sodium / TEA-lauroyl hydrolyzed collagen, sodium / TEA-lauroyl hydrolyzed keratin, sodium / TEA-lauroyl keratin amino acids, sodium / TEA-undecylenoyl collagen amino acids, sodium / TEA-undecylenoyl hydrolyzed collagen, sodium / TEA-undecylenoyl hydrolyzed corn protein, sodium / TEA-undecylenoyl hydrolyzed soy protein, sodium / TEA-undecylenoyl hydrolyzed wheat protein, sodium theobroma grandiflorum septate, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate,Sodium tridecylbenzenesulfonate, sodium tridecyl sulfate, trimethyltyrolpropane hydroxypropyl iminodiacetate dendrimer, sodium undeceth-5 carboxylate, sodium undecylenate, sodium undecylenoamphoacetate, sodium undecylenoamphopropionate, sodium undecylenoyl glutamate, sodium wheat germanphoacetate, sorbeth-160 tristearate, soybean acid, soybean amidopropylamine oxide, soybean amidopropyl betaine, soybean oil glycereth-8 ester, ylamine Stearamide, stearamidopropyl betaine, stearamine oxide, steareth-15, steareth-16, steareth-20, steareth-21, steareth-25, steareth-27, steareth-30, steareth-40, steareth-50, steareth-80, steareth-100, steareth-2 phosphate, steareth-3 phosphate, stearic acid, stearoxypropyltrimonium chloride, stearoyl glutamic acid, stearoyl sarcosine, stearyl betaine, stearyldimonium hydroxypropyl butyl glucoside chloride, ste Allyldimonium hydroxypropyl decyl glucoside chloride, stearyldimonium hydroxypropyl lauryl glucoside chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower amide MEA, sunflower seed acid, sunflower-LCDamidopropyl chloride hydroxyethyldimonium, sunflower seed oil glycereth-8 ester, tall oil acid, animal fat acid, tar-low amidopropylamine oxide, tar amidopropyl betaine, tar amidopropyl hydroxysultaine, tar Loamine oxide, taloupe betaine, taloupe dihydroxyethyl betaine, taloupe oil ethyl glucoside, TEA-avietoyl hydrolyzed collagen, TEA-C12-14 alkyl phosphate, TEA-C10-15 alkyl sulfate, TEA-C11-15 alkyl sulfate, TEA-C12-13 alkyl sulfate, TEA-C12-14 sulfate, TEA-C12-15 alkyl sulfate, TEA-AC14-17 alkyl sec sulfonate, TEA-canolate, TEA-cocamide diacetate, TEA-cocoic acid, TEA-cocoic acid sulfate, TEA-cocoyl alaninate,TEA-Cocoyl Glutamate, TEA-Cocoyl Glutamate, TEA-Cocoyl Glycine, TEA-Cocoyl Hydrolyzed Collagen, TEA-Cocoyl Hydrolyzed Soy Protein, TEA-Cocoyl Sarcosine, TEA-Dimethicone PEG-7 Phosphate, TEA-Dodecylbenzenesulfonate, TEA-Hydrogenated Cocoate, TEA-Hydrogenated Taroyl Glutamate, TEA-Isostearate, TEA-Isostearoyl Hydrolyzed Collagen, TEA-Lauraaminopropionate, TEA-Laurate, TEA-Laurate / Myristic Salts, TEA-Laureth Sulfate, TEA-Lauroyl Collagen Amino Acids, TEA-Lauroyl Glutamic Acid, TEA-Lauroyl Hydrolyzed Collagen, TEA-Lauroyl Keratin Amino Acids, TEA-Lauroyl Methylaminopropionate, TEA-Lauroyl / Myristoyl Aspartate, TEA-Lauroyl Sarcosinate, TEA-Lauryl Phosphate, TEA-Lauryl Sulfate, TEA-Myristoyl Aminopropionate, TEA-Myristic Acid, TEA-Myristoyl Hydrolyzed Collagen, TEA-Oleic Acid, TEA-Oleyl Hydrolyzed Collagen Lagen, TEA-Oleoyl Sarcosinate, TEA-Oleyl Sulfate, TEA-Palmitic Acid, TEA-Pine Kernel Sarcosinate, TEA-PEG-3 Cocamide Sulfate, TEA-Rosinate, TEA-Stearate, TEA-Thalate, TEA-Tridecylbenzenesulfonate, TEA-Undecylenate, TEA-Undecylenol Hydrolyzed Collagen, Tetramethyldecinediol, Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinate, TIPA-Laureth Sulfate, TIPA-Lauryl Sulfate, TIPA-Myristic Acid, TI PA-Stearic Acid, Tocopherol Phosphate, Trehalose Undecylenic Acid, TM-C12-15 Pareth-2 Phosphate, TM-C12-15 Pareth-6 Phosphate, TM-C12-15 Pareth-8 Phosphate, TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecylbenzenesulfonic Acid, Trilaureth-9 Citric Acid,Trimethylolpropane hydroxypropyl bis-hydroxyethylamine dendrimer, lauroampho-PG trisodium chloride phosphate, undecanoic acid, undeceth-5 carboxylic acid, undecylenamidopropylamine oxide, undecylenamidopropyl betaine, undecylenic acid, undecylenoyl collagen amino acids, undecylenoyl glycine, undecylenoyl hydrolyzed collagen, undecylenoyl wheat amino acids, undecyl glucoside, wheat germic acid, wheat germamidopropylamine oxide, wheat germamidopropyl betaine, Yucca schidigera leaf / root / stem extract, Yucca schidigera stem extract, zinc coceth sulfate, zinc coco sulfate.

[0032] One or more compounds selected from the group consisting of sodium laureth sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, cocoglucoside, and ammonium lauryl sulfosuccinate are preferred.

[0033] The surfactant content in the compound may be 0.1 to 10% by weight, preferably 0.5 to 5% by weight, based on the compound.

[0034] <Oil Body> Suitable oil bodies for forming the components of the O / W emulsion include, for example, gelbet alcohols based on fatty alcohols having 6-18, preferably 8-10 carbon atoms, esters of linear C6-C22-fatty acids with linear or branched C6-C22-fatty alcohols, or esters of branched C6-C13-carboxylic acids with linear or branched C6-C22-fatty alcohols. For example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, iso These are isostearyl stearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl myristate, oleyl palmitate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate, and erucate.Also, esters of linear C6-C22 fatty acids with branched alcohols, especially 2-ethylhexanol; esters of C18-C38 alkylhydroxycarboxylic acids with linear or branched C6-C22 fatty alcohols, especially dioctyl malate; linear and / or branched fatty acids with polyhydric alcohols (e.g., propylene glycol, dimergol or trimeltriol) and / or Guerbet alcohols; C6-C10 fatty acid-based triglycerides; liquid mono- / di- / triglyceride mixture-based C6-C18 fatty acids; C6-C22 fatty alcohols and / or Guerbet alcohols with aromatic carboxylic acids. In particular, benzoic acid, esters of C2-C12 dicarboxylic acids with linear or branched alcohols having 1-22 carbon atoms, or polyols having 2-10 carbon atoms and 2-6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C6-C22 fatty alcohol carbonates, such as dicaprylyl carbonate (Cetiol (registered trademark) CC), Guerbet carbonates based on aliphatic alcohols having 6-18, preferably 8-10 carbon atoms, and esters of benzoic acid with linear and / or branched C6-C22 alcohols (e.g., C6-C22). Finsolv (registered trademark) TN), linear or branched symmetric or asymmetric dialkyl ethers having 6-22 carbon atoms per alkyl group, such as dicaprylyl ether (Cetiol (registered trademark) OE), ring-opening products of epoxidized fatty acid esters and polyols, silicone oils (cyclomethicone, silicone methicone grade, etc.) and / or aliphatic or naphthenic hydrocarbons, such as squalane, squalene, or dialkylcyclohexane are preferred.

[0035] <Emulsifier> Other nonionic or cationic surfactants can also be added to the preparation, for example, as emulsifiers. Examples include:

[0036] Products obtained by adding 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear C8-22 fatty alcohols, C12-22 fatty acids, and alkylphenols containing 8-15 carbon atoms in the alkyl group; C12 / 18 fatty acid monoesters and diesters of addition products of 1 to 30 mol of ethylene oxide to glycerol; Glycerol mono and diesters, sorbitan mono and diesters, and ethylene oxide adducts thereof of saturated and unsaturated fatty acids having 6 to 22 carbon atoms; • Addition product of 15 to 60 moles of ethylene oxide to castor oil and / or hydrogenated castor oil; Polyol esters, especially polyglycerol esters, such as polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate, or polyglycerol dimerate isostearate. Mixtures of these class compounds are also suitable; • Addition product of 2 to 15 moles of ethylene oxide to castor oil and / or hydrogenated castor oil; • Linear, branched, unsaturated or saturated C6 / 22 fatty acids, ricinoleic acid, 12-hydroxystearic acid, glycerol, polyglycerol, partial esters based on pentaerythritol, dipentaerythritol, sugar alcohols (e.g., sorbitol), alkyl glucosides (e.g., methyl glucoside, butyl glucoside, lauryl glucoside), and polyglucosides (e.g., cellulose); Mono-, di-, and trialkyl phosphates, as well as mono-, di-, and / or tri-PEG-alkyl phosphates and their salts; Wool wax alcohol; • Polysiloxane / polyalkyl polyether copolymers and their corresponding derivatives; • Mixed esters of pentaerythritol, fatty acids, citric acid, and fatty alcohols, and / or mixed esters of C6-22 fatty acids, methyl glucose, and polyols, preferably glycerol or polyglycerol; • Polyalkylene glycols; and Glycerol carbonate.

[0037] Addition products of ethylene oxide and / or propylene oxide to fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters, sorbitan mono- and diesters, or castor oil are known commercially. These are homologous mixtures, and their average degree of alkoxylation corresponds to the ratio of the amount of substrate that undergoes the addition reaction with ethylene oxide and / or propylene oxide. C12 / 18 fatty acid monoesters and diesters of addition products of ethylene oxide to glycerol are known as lipid layer enhancers for cosmetic formulations. Preferred emulsifiers are described in detail below.

[0038] Partial glycerides. Typical examples of suitable partial glycerides include monoglycerides hydroxystearate, diglycerides hydroxystearate, monoglycerides isostearate, diglycerides isostearate, monoglycerides oleate, diglycerides oleate, monoglycerides ricinoleate, diglycerides ricinoleate, monoglycerides linoleate, diglycerides linoleate, monoglycerides linolenic acid, diglycerides linolenic acid, monoglycerides erucate, diglycerides erucate, monoglycerides tartaric acid, diglycerides tartaric acid, monoglycerides citrate, diglycerides citrate, monoglycerides malic acid, diglycerides malic acid, and technical mixtures thereof, which may still contain small amounts of triglycerides generated during the manufacturing process. It is also preferable to add 1 to 30 mol, preferably 5 to 10 mol, of ethylene oxide to the above-mentioned partial glyceride.

[0039] Sorbitan ester. Suitable sorbitan esters include sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoacetate, sorbitan sesquiacetate, sorbitan diacetate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate. Sorbitan monocitrate, sorbitan sesquitinate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimalate, and technical mixtures thereof. Addition products of 1 to 30 mol, preferably 5 to 10 mol, of ethylene oxide to the above-mentioned sorbitan esters are also suitable.

[0040] Polyglycerol ester. Typical examples of suitable polyglycerol esters include polyglyceryl-2 dipolyhydroxystearate (DEHYMULS (registered trademark) PGPH), polyglycerin-3-diisostearate (LAMEFORM (registered trademark) TGI), polyglyceryl-4 isostearate (ISOLAN (registered trademark) GI34), polyglyceryl-3 oleate, polyglyceryl-3 diisostearoyl diisostearate (ISOLAN (registered trademark) PDI), polyglyceryl-3 methylglucose distearate (TEGO CARE (registered trademark) 450), polyglyceryl-3 beeswax (CERA BELLINA (registered trademark)), and polyglyceryl-4 caprate (POLYGLYCEROL CAPRATE). (T2010 / 90), polyglyceryl-3 cetyl ether (CHIMEXANE (registered trademark) NL), polyglyceryl-3 distearate (CREMOPHOR (registered trademark) GS32), and polyglyceryl polyricinoleate (ADMUL (registered trademark) WOL1403), dimethylpolyglyceryl isostearate, and mixtures thereof. Other suitable examples of polyolesters include mono-, di-, and triesters of trimethylolpropane or pentaerythritol with lauric acid, coco fatty acids, animal fat fatty acids, palmitic acid, stearic acid, oleic acid, behenic acid, etc., optionally reacted with 1-30 mol of ethylene oxide.

[0041] Tetraalkylammonium salt. Cationic surfactants contain hydrophobic polymeric groups that dissociate in aqueous solution and are necessary for the surfactant activity of the cation. An important representative example of a cationic surfactant is a tetraalkylammonium salt of the general formula: (R1R2R3R4N+)X-, where R1 represents a C1-C8 alkyl(alkenyl) group, and R2, R3, and R4 independently represent alkyl(alkenyl) radicals having 1-22 carbon atoms. X is a counterion, preferably selected from the group of halides, alkyl sulfates, and alkyl carbonates. Cationic surfactants in which the nitrogen group is substituted with two long acyl groups and two short alkyl(alkenyl) groups are particularly preferred.

[0042] Estherquat. A further class of cationic surfactants particularly useful as co-surfactants for the present invention is represented by so-called ester quats. Ester quats are generally understood to be quaternized fatty acid triethanolamine ester salts. These are known compounds that can be obtained by relevant methods of preparative organic chemistry. In this regard, refer to International Patent Publication WO91 / 01295A1, which describes how triethanolamine is partially esterified with a fatty acid in the presence of hypophosphorous acid, air is passed through the reaction mixture, and then the whole is quaternized with dimethyl sulfate or ethylene oxide. Furthermore, German Patent DE 4308794C1 describes a method for producing solid ester quats in which the quaternization of the triethanolamine ester is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0043] Typical examples of ester quats suitable for use according to the present invention are products in which the acyl component is derived from a monocarboxylic acid corresponding to the formula RCOOH, where RCO is an acyl group containing 6-10 carbon atoms, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid, and technical mixtures thereof such as so-called head-fractionated fatty acids. Ester quats derived from monocarboxylic acids in which the acyl component contains 8-10 carbon atoms are preferably used. Other ester quats are those in which the acyl component is derived from dicarboxylic acids such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, ester quats derived from a mixture of monocarboxylic acids containing 6-22 carbon atoms and adipic acid are preferably used. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final ester quat may be in the range of 1:99 to 99:1, preferably in the range of 50:50 to 90:10, and more particularly in the range of 70:30 to 80:20. Besides quaternized fatty acid triethanolamine ester salts, other suitable ester quats are quaternized ester salts of mono- / dicarboxylic acid mixtures with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. Ester quats can be obtained from fatty acids as well as from corresponding triglycerides mixed with the corresponding dicarboxylic acid. A representative example of the relevant prior art is proposed in European Patent EP0750606B1, which describes such a method. To produce quaternized esters, mixtures of mono- and dicarboxylic acids and triethanolamine—based on available carboxyl functional groups—can be used in molar ratios of 1.1:1 to 3:1. Considering the performance characteristics of ester quats, ratios of 1.2:1–2.2:1, preferably 1.5:1–1.9:1, have proven particularly advantageous. Preferred ester quats are technical mixtures of mono-, di-, and triesters with an average degree of esterification of 1.5 to 1.9.

[0044] <Superfat-reducing agents and consistency factors> Superfatting agents can be selected from substances such as lanolin and lecithin, as well as polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides, and fatty acid alkanolamides, with fatty acid alkanolamides also functioning as foam stabilizers.

[0045] The coherence factors primarily used are fatty alcohols or hydroxyfatty alcohols containing 12 to 22, preferably 16 to 18, carbon atoms, as well as partial glycerides, fatty acids, or hydroxyfatty acids. These substances are preferably used in combination with alkyl oligoglucosides and / or fatty acid N-methylglucamides and / or polyglycerol poly-12-hydroxystearates of the same chain length.

[0046] <Thickeners and rheological additives> Suitable thickeners include polymer thickeners such as Aerosil® type (hydrophilic silica), polysaccharides, particularly xanthan gum, guar guar, agar, alginates and tyrose, carboxymethylcellulose and hydroxyethylcellulose, as well as relatively high molecular weight polyethylene glycol monoesters and fatty acid diesters, polyacrylates (e.g., Carbopols® [Goodrich] or Synthalens® [Sigma]), polyacrylamide, polyvinyl alcohol and polyvinylpyrrolidone, surfactants, such as ethoxylated fatty acid glycerides, esters of fatty acids and polyols, such as pentaerythritol or trimethylolpropane, narrow-range fatty alcohol ethoxylates and electrolytes, such as sodium chloride and ammonium chloride.

[0047] <polymer> Suitable cationic polymers include, for example, cationic cellulose derivatives such as quaternized hydroxyethylcellulose available from Amerchol under the name Polymer JR 400 (registered trademark), cationic starch, copolymers of diallylammonium salts and acrylamide, quaternized vinylpyrrolidone / vinylimidazole polymers such as Luviquat (registered trademark) (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat (registered trademark) L, Grunau), quaternized wheat polypeptides, polyethyleneimines, cationic silicone polymers such as amodym-silicone, copolymers of adipic acid and dimethylaminohydroxypropyl diethylenetriamine (Cartaretine (registered trademark) Sandoz), and copolymers of acrylic acid and dimethyldiallylammonium chloride (Merqua These include polyaminopolyamides and their crosslinked water-soluble polymers, cationic chitin derivatives such as quaternary chitosan (optionally in microcrystalline form), dihaloalkyls such as dibromobutane and bis-dialkylamines such as bis-dimethylamino-1,3-propane, cationized guar gums such as Celanese's Jaguar(registered trademark) CBS, Jaguar(registered trademark) C-17, Jaguar(registered trademark) C-16, quaternary ammonium salt polymers such as Mirapol(registered trademark) A-15, Mirapol(registered trademark) AD-1, Mirapol(registered trademark) AZ-1, and various polyquaternium types (e.g., 6, 7, 32, or 37) commercially available under the trade names Rheocare(registered trademark) CC or Ultragel(registered trademark) 300.

[0048] Suitable anionic, zwitterionic, amphoteric, and nonionic polymers include, for example, vinyl acetate / crotonic acid copolymer, vinylpyrrolidone / vinyl acrylate copolymer, vinyl acetate / butyl maleate / isobornyl acrylate copolymer, methyl vinyl ether / maleic anhydride copolymer and its esters, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamidopropyltrimethylammonium chloride / acrylate copolymer, octylacrylamide / methyl methacrylate / tert.-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymer, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, vinylpyrrolidone / dimethylaminoethyl methacrylate / vinyl caprolactam terpolymer, and optionally derivatized cellulose ethers and silicones.

[0049] <Pearlescent wax> Suitable pearlescent waxes include, for example, alkylene glycol esters, particularly ethylene glycol distearate; fatty acid alkanolamides, particularly coco-fatty acid diethanolamide; partially glycerides, particularly monoglyceride stearate; polybasic, optionally hydroxysubstituted carboxylic acids and fatty alcohols having 6-22 carbon atoms, particularly long-chain esters of tartaric acid; fatty compounds, such as fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates containing at least 24 carbon atoms in total, particularly laurone and distearyl ethers; fatty acids, such as stearic acid, hydroxystearic acid or behenic acid; ring-opening products of olefin epoxides containing 12-22 carbon atoms and fatty alcohols containing 12-22 carbon atoms and / or polyols containing 2-15 carbon atoms and 2-10 hydroxyl groups; and mixtures thereof.

[0050] <Silicone> A suitable silicone can be selected from the following group: Acrylate / Behenyl, Acrylate / Dimethicone Methacrylate Copolymer, Acrylate / Behenyl Methacrylate / Dimethicone Methacrylate Copolymer, Acrylate / Bis-Hydroxypropyl Dimethicone Crosspolymer, Acrylate / Dimethicone Copolymer, Acrylate / Behenyl, Acrylate / Dimethicone Methacrylate Copolymer, s / Dimethicone Methacrylate / Ethylhexyl Acrylate Copolymer, Acrylate / Dimethiconol Acrylate Copolymer, Acrylate / Ethylhexyl Acrylate / Methacrylic Acid Dimethicone copolymer, acrylate / octylacrylamide / diphenylamodimethicone copolymer, acrylate / polytrimethylsiloxymethacrylate copolymer, acrylate / propyltrimethicone methacrylate copolymer, aryl acrylate / dimethicone methacrylate copolymer, acrylate / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate copolymer, acrylate / trifluoropropyl methacrylate / polytrimethylsiloxymethacrylate copolymer, A Minobispropyl dimethicone, aminoethylaminopropyl dimethicone, aminopropyl dimethicone, aminopropyl phenyl trimethicone, aminopropyl triethoxysilane, dimethicone PEG-7 ammonium sulfate, amodimethicone, amodimethicone hydroxystearate, amodimethicone / silsesquioxane copolymer, ascorbyl carboxydecyltrisiloxane, ascorbyl methylsilanol pectinate, behenoxydimethicone, behentrimonium dimethicone PEG-8 phthalate, behenyl dimethicone, bisaminop EG / PPG-41 / 3 Aminoethylpropyl Dimethicone, Bis-Aminopropyl / Ethoxyaminopropyl Dimethicone, Bis-(Butylbenzoic Acid) Diaminotriazine Aminopropyl Trisiloxane, Bis-Butyl Dimethicone Polyglyceryl-3, Bis-Butyloxyamodimethicone / PEG-60 Copolymer, Bis-(C13-15 Alkoxy) Hydroxybutamide Modimethicone, Bis-(C13-15 Alkoxy) PG-Methicone, Bis-(C1-8 Alkyl Lauroyl Lysine Decyl Carboxamide) Dimethicone, Bis-Cetyl Cetyl Dimethicone,Bis-Cetyl / PEG-8 Cetyl PEG-8 Dimethicone, Bis-Diphenylethyl Disiloxane, Bis-Ethyl Ethyl Methicone, Bis-Gluconamide Ethylaminopropyl Dimethicone, Bis-Hydrogen Dimethicone, Bis-Hydroxyethoxypropyl Dimethicone, Bis-Hydroxyl Lauryl, Dimethicone / IPDI Copolymer, Bis-Hydroxy / Methoxyamodimethicone, Bis-Hydroxypropyl Dimethicone Behenate, Bis-Hydroxypropyl Dimethicone / SMDI Copolymer, Bis-Isobutyl PEG-14 / Amodimethicone Copolymer, bis-isobutyl PEG-15 / amodimethicone copolymer, bis-isobutyl PEG / PPG-20 / 35 / amodimethicone copolymer, bis-isobutyl PEG / PPG-10 / 7 / dimethicone copolymer, bis-isobutyl PEG-24 / PPG-7 / dimethicone copolymer, bis-PEG-1 dimethicone, bis-PEG-4 dimethicone, bis-PEG-8 dimethicone, bis-PEG-12 dimethicone, bis-PEG-20 dimethicone, bis-PEG-12 dimethicone beeswax, bis-PEG-12 dimethicone candelaire Bis-PEG-15 Dimethicone / IPDI Copolymer, Bis-PEG-15 Methyl Ether Dimethicone, Bis-PEG-18 Methyl Ether Dimethyl Silane, Bis-PEG / PPG-14 / 14 Dimethicone, Bis-PEG / PPG-15 / 5 Dimethicone, Bis-PEG / PPG-18 / 6 Dimethicone, Bis-PEG / PPG-20 / 20 Dimethicone, Bis-PEG / PPG-16 / 16 Dimethicone, Bis-PEG / PPG-20 / 5 Dimethicone, Bis-phenylhexamethicone, Bis-phenyl Phenylpropyl dimethicone, bis-polyethylene dimethicone, bis-(polyglyceryl-3 oxyphenylpropyl) dimethicone, bis-(polyglyceryl-7 oxyphenylpropyl) dimethicone, bis-PPG-15 dimethicone / IPDI copolymer, bis-(PPG-7 undecent-21) dimethicone, bis-stearyl dimethicone, bis-trimethoxysilylethyltetramethyldisiloxyethyl dimethicone, bis-vinyl dimethicone, bis-vinyl dimethicone / dimethicone copolymer, Borage seed oil PEG-7 dimethicone ester,Butyl acrylate / C6-14 perfluoroalkylethyl acrylate / mercaptopropyl dimethicone copolymer, Butyl acrylate / hydroxypropyl dimethicone acrylate copolymer, Butyl dimethicone acrylate / cyclohexyl methacrylate / ethylhexyl acrylate copolymer, Butyl dimethicone methacrylate / methyl methacrylate crosspolymer, t-butyldimethylsilyl grape seed extract, Butyl polydimethylsiloxyethylene / propylene / vinyl obornene copolymer, C6-8 alkyl C3-6 alkyl glucoside dimethicone C20-24 alkyl dimethicone, C24-28 alkyl dimethicone, C26-28 alkyl dimethicone, C30-45 alkyl dimethicone, C30-60 alkyl dimethicone, C32 alkyl dimethicone, C30-45 alkyl dimethicone / polycyclohexene oxide crosspolymer, C26-28 alkyldimethylsilyl polypropylene silsesquioxane, C30-45 alkyldimethylsilyl polypropylene silsesquioxane, C20-24 alkyl methicone, C24-28 alkyl methicone, C26-28 alkyl methicone, C30- 45-Alkyl Methicone, C20-28 Perfluorodecyl Ethoxy Dimethicone, C26-54 Alkyl Tetradecyl Dimethicone, Caprylyl Dimethicone, Caprylyl Dimethicone Ethoxyglucoside, Caprylyl Methicone, Caprylyl Trimethicone, Carboxydecyl Trisiloxane, Castor Oil Bis-Hydroxypropyl Dimethicone Ester Celotyl Dimethicone, Cetearyl Dimethicone Crosspolymer, Cetearyl Dimethicone / V-Inyl Dimethicone Crosspolymer, Cetearyl Methicone, Cetrimonium Carboxydecyl PEG-8 Dimethicone, Cetrimonium Di Methicone PEG-7 phthalate, cetyl behenyl dimethicone, cetyl dimethicone, cetyl dimethicone / bisvinyl dimethicone crosspolymer, cetyl hexacosyl dimethicone, cetyl oxydimethicone, cetyl PEG-8 dimethicone, cetyl PEG / PPG-15 / 15 butyl ether dimethicone, cetyl PEG / PPG-7 / 3 dimethicone, cetyl PEG / PPG-10 / 1 dimethicone, cetyltriethylmonium dimethicone PEG-8 phthalate, cetyltriethylmonium dimethicone PEG-8 succinate, copper methylsilanol acetyltyrosinate,Copper PCA methylsilanol, C4-14 perfluoroalkyl ethoxydimethicone, ICON, cycloheptasiloxane, cyclohexasiloxane, cyclomethicone, cyclopentasiloxane, cyclophenylmethicone, cyclotetrasiloxane, m-cyclovinylmethicone, cystine bis-PG-propylsilanetriol, DEA propyl PEG / PPG-18 / 21 dimethicone, diisostearoyl trimethylolpropanesiloxysilicate, dilauroyl trimethylolpropanesiloxysilicate, dilinolamidopropyl dimethylamine Dimethicone PEG-7 Phosphate, Dimethicone, Dimethicone Crosspolymer, Dimethicone Crosspolymer-3, Dimethicone / Divinyldimethicone / Silsesquioxane Crosspolymer, Dimethicone Ethoxyglucoside, Icon Hydroxypropyltrimonium Chloride, Dimethicone / Mercaptopropyl Methicone Copolymer, Dimethicone PEG-15 Acetate, Dimethicone PEG-8 Adipic Acid, Dimethicone PEG-7 Avocado Acid, Dimethicone PEG-8 Avocado Acid, Dimethicone PEG-8 Beeswax, Dimethicone PEG-8 Benzoic Acid, Dimethicone Dimethicone PEG-8 Boradic Acid, Dimethicone PEG-7 Cocoate, Dimethicone / PEG-10 Crosspolymer, Dimethicone / PEG-10 / 15 Crosspolymer, Dimethicone / PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG-8 Lanolate, Dimethicone PEG-8 Laurate, Dimethicone PEG-8 Meadowfoamate, Dimethicone PEG-7 Octyldodecyl Citrate, Dimethicone PEG-7 Oliveate, Dimethicone PEG-8 Olive Dimethicone PEG-7 phosphate, dimethicone PEG-8 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG-7 phthalate, dimethicone PEG-8 phthalate, dimethicone PEG-8 polyacrylate, dimethicone PEG / PPG-20 / 23 benzoate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone PEG-7 succinate, dimethicone PEG-8 succinate, dimethicone PEG-7 sulfate, dimethicone PEG-7 undecylenate, dimethicone PG-diethylmonium chloride,Dimethicone / phenylvinyl dimethicone crosspolymer, dimethicone / polyglycerin-3 crosspolymer, dimethicone / PPG-20 crosspolymer, dimethicone propyl ethylenediamine behenate, dimethicone propyl PG-betaine, dimethicone / silsesquioxane copolymer, dimethicone silylate, dimethicone / vinyl dimethicone crosspolymer, dimethicone / vinyl trimethylsiloxysilicate crosspolymer, dimethiconol, dimethiconol arginine, dimethiconol beeswax, dimethiconol behenate, dimethiconol Borazite, Dimethiconol Cantharlic Acid, Dimethiconol Carnabit, Dimethiconol Cysteine, Dimethiconol Fluoroalcohol Phosphate, Dimethiconol Hydroxylate, Dimethiconol Butterate Dimethiconol, Dimethiconol Bacteria, Dimethiconol, Dimethiconol Bacteria, Dimethiconol Lactate Ethiconol, Dimethiconol Meadowfoamate, Dimethiconol Methionine, Dimethiconol / Methylsilanol / Silicate Crosspolymer, Dimethiconol Mowa Butterate, Dimethiconol Panthenol, Dimethiconol Rusal butterate, dimethiconol / silica crosspolymer, dimethiconol / silsesquioxane copolymer, dimethiconol stearate, dimethiconol / stearyl, methicone / phenyl trimethicone copolymer, dimethoxysilylethylenediaminopropyl dimethicone, aminopropylamide PCA dimethicone, dimethyloxobenzodioxasilane, dimethylsilanol hyaluronate, dioleyl tocopheryl methylsilanol, diphenylamodimethicone, diphenyldimethicone, diphenyldimethicone crosspolymer diphenyl Dimethicone / Vinyldiphenyldimethicone / Silsesquioxane Crosspolymer, Diphenylethylbenzyloxydylsiloxane, Diphenylisopropyldimethicone, Diphenylsiloxyphenyl / Propyltrimethicone, DiphenylsiloxyphenyltrimethiconeDisiloxane, AmodimethiconeDisuccinamidDisodium, PEG-12DimethiconeSulfosuccinateDisodium, PEG-8LaurylDimethiconeSulfosuccinateDisodium, Divinyldimethicone / Dimethicone Copolymer, Divinyldimethicone / Dimethicone Crosspolymer,Drometrizole trisiloxane, ethylhexyl acrylate / VP / dimethicone methacrylate copolymer, ethyl methicone, ethyl trisiloxane, fluoro C2-8 alkyl dimethicone, gluconamidopropyl aminopropyl dimethicone, 4-(2-β-glucopyranosiloxy)propoxy-2-hydroxybenzophenone, glyceryl undecyl dimethicone, glycidoxy dimethicone, hexade, Silmethicone, Hexyl Dimethicone, Hexyl Methicone, Hexyl Trimethoxysilane, Hydrogen Dimethicone, Hydrogen Dimethicone / Octyl Silsesquioxane Copolymer, Hydrolyzed Collagen PG-Propyl Dimethiconol, Hydrolyzed Collagen PG-Propyl Methylsilanediol, Hydrolyzed Collagen PG-Propyl Silanetriol, Hydrolyzed Keratin PG-Propyl Methylsilanediol, Hydrolyzed Sesame Protein PG-Propyl Methylsilanediol, Hydrolyzed Silk PG-Propyl Methylsilanediol, Hydrolyzed Silk PG-propylmethylsilanediol crosspolymer, hydrolyzed soy protein / dimethicone PEG-7 acetate, hydrolyzed soy protein PG-propylmethylsilanediol, hydrolyzed vegetable protein PG-propylsilanetriol, hydrolyzed wheat protein / cystine bis-PG-propylsilanetriol copolymer, hydrolyzed wheat protein / dimethicone PEG-7 acetate, hydrolyzed wheat protein / dimethicone-7 phosphate copolymer, hydrolyzed wheat protein PG-propylmethylsilanediol, hydrolyzed wheat protein Protein PG-propylsilanetriol, hydroxyethylacetonium PG-dimethicone, hydroxypropyl dimethicone, hydroxypropyl dimethicone behenate, hydroxypropyl dimethicone isostearate, hydroxypropyl dimethicone stearate, isobutyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, isobutyl methacrylate / trifluoroethyl methacrylate / bis-hydroxypropyl dimethicone acrylate copolymer, isopentyl trimethoxycinnamate trisiloxane, Isopolyglyceryl-3 dimethicone, Isopolyglyceryl-3 dimethiconol, Isopropyl titanium triisostearate / triethoxysilylethyl, Polydimethylsiloxyethyl dimethicone crosspolymer, Isostearyl carboxydecyl PEG-8 dimethicone, Lactoyl methylsilanol elastinate, Lauryl dimethicone, Lauryl dimethicone PEG-15 crosspolymer, Lauryl dimethicone PEG-10 phosphate, Lauryl dimethicone / polyglycerin-3 crosspolymer, Lauryl methicone, Lauryl PEG-8 dimethicone,Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG / PPG-18 / 18 Methicone, Lauryl Phenylenisopropyl Methicone, Lauryl Phenylenpropyl Methicone, Lauryl Polydimethylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Trimethicone, Linoleamidopropyl PG-Dimethicone Chloride Phosphate, Methacryloylpropyl Trimethoxysilane, Methicone, Methoxya Modimethicone / silsesquioxane copolymer, methoxycinnamidopropyl propyl silsesquioxane, methoxycinnamoylpropyl silsesquioxane silicate, methoxyPEG-13 ethyl polysilsesquioxane, methoxyPEG / PPG-7 / 3 aminopropyl dimethicone, methoxyPEG / PPG-25 / 4 dimethicone, methoxyPEG-10 propyl trimethoxysilane, methyl eugenyl PEG-8 dimethicone, methylpolysiloxane emulsion, methylsilanol acetylmethionate, methylsilanol acetyl tyrosine Methylsilanol ascorbate, anol carboxymethyl theophylline, methylsilanol carboxymethyl theophylline alginate, methylsilanol elastate, methylsilanol glycyrrhizinate, methylsilanol hydroxyproline, methylsilanol hydroxyproline aspartate, methylsilanol mannuronate, methylsilanol PCA, methylsilanol PEG-7 glyceryl cocoate, methylsilanol / silicate crosspolymer, methylsilanol spirulinate, methylsilanol tri-PEG-8 Lyceryl cocoate, methyl trimethicone, methyltrimethoxysilane, myristylamidopropyl dimethylamine dimethicone PEG-7 phosphate, myristyl methicone, myristyl trisiloxane, nylon 611 / dimethicone copolymer, PCA dimethicone, PEG-7 amodimethicone, PEG-8 amodimethicone, PEG-8 cetyl dimethicone, PEG-3 dimethicone, PEG-6 dimethicone, PEG-7 dimethicone, PEG-8 dimethicone, PEG-9 dimethicone, PEG-10 dimethicone, PEG-12 dimethicone, PEG-14 dimethicone,PEG-17 Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimethicone / Dimer Dilinoleate Copolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-8 Disteammonium Chloride PG-Dimethicone, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, PEG-8 Methicone, PE G-6 Methicone Acetate, PEG-6 Methyl Ether Dimethicone, PEG-7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG-9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dimethicone, PEG-32 Methyl Ether Dimethicone, PEG-8 Methyl Ether Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, EG-4 PEG-12 Dimethicone, PEG-8 PG-Coco Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone PEG / PPG-20 / 22 Butyl Ether Dimethicone, PEG / PPG-22 / 22 Butyl Ether Dimethicone, PEG / PPG-23 / 23 Butyl Ether Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-27 / 9 Butyl Ether Dimethicone, PEG / PPG-3 / 10 Dimethicone, PEG / PPG-4 / 12 Dimethicone, PEG / PPG-6 / 4 Dimethicone, PEG / PPG-6 / 11 Dimethicone, PEG / PPG-8 / 14 Dimethicone, PEG / PPG-8 / 26 Dimethicone, PEG / PPG-10 / 2 Dimethicone, PEG / PPG-12 / 16 Dimethicone, PEG / PPG-12 / 18 Dimethicone, PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone,PEG / PPG-20 / 15 Dimethicone, PEG / PPG-20 / 20 Dimethicone, PEG / PPG-20 / 23 Dimethicone, PEG / PPG-20 / 29 Dimethicone, PEG / PPG-22 / 23 Dimethicone, PEG / PPG-22 / 24 Dimethicone, PEG / PPG-23 / 6 Dimethicone, PEG / PPG-25 / 25 Dimethicone, PEG / PPG-27 / 27 Dimethicone, PEG / PPG-30 / 10 Dimethicone, PEG / PPG-25 / 25 Dimethicone / Acrylate Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PE G / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dimethicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylylethoxysilyl Ethyl Methicone, Perfluorononyl Dimethicone, Perfluorononyl Dimethicone / Methicone / Amodimethicone Crosspolymer, Perfluoro Orononylethyl carboxydecylbehenyl dimethicone, perfluorononylethyl carboxydecylhexacosyl dimethicone, perfluorononylethyl carboxydecyl lauryl / behenyl dimethicone, perfluorononylethyl carboxydecyl lauryl dimethicone, perfluorononylethyl carboxydecyl PEG-8 dimethicone, perfluorononylethyl carboxydecyl PEG-10 dimethicone, perfluorononylethyl dimethicone / methicone copolymer, perfluorononylethyl PEG-8 dimethicone, perfluorononylethyl Lustearyl dimethicone, perfluorooctyl ethyl / diphenyl dimethicone copolymer, perfluorooctyl ethyl triethoxysilane, perfluorooctyl ethyl trimethoxysilane, perfluorooctyl ethyl trisyloxane, perfluorooctyl triethoxysilane, PG-amodimethicone, phenethyl dimethicone, phenethyl disiloxane, phenyl dimethicone, phenylisopropyl dimethicone, phenyl methicone, phenyl methiconol, phenylpropyl dimethylsiloxysilicate, phenylpropyl ethyl methicone,Phenylpropyl Trimethicone, Phenylpropyl Trimethicone / Diphenyl Methicone, Phenyl Trimethicone, Platinum Il Disiloxane, Polyacrylate-6, Polydiethylsiloxane, Polydimethylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Polydimethylsiloxyethyl Dimethicone / Methicone Copolymer, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-3 Disiloxane Dimethicone, Il- 3 / Lauryl polydimethylsiloxyethyl dimethicone crosspolymer, polyglyceryl-3 polydimethylsiloxyethyl dimethicone, poly(glycol adipate) / bis-hydroxyethoxypropyl dimethicone copolymer, polymethylsilsesquioxane, polymethylsilsesquioxane / trimethylsiloxysilicate, polyphenylsilsesquioxane, polypropylene silsesquioxane, polysilicone-1, polysilicone-2, polysilicone-4, polysilicone-5, polysilicone-6, polysilicone-7, polysilicone Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone-12, Polysilicone-13, Polysilicone-14, Polysilicone-15, Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Polysilicone-18 Cetyl Phosphate, Polysilicone-1 Crosspolymer, Polysilicone-18 Stearate, Polyurethane-10, Dimethicone Potassium PEG-7 Panthenyl Phosphate, Potassium Dimethicone PEG-7 Phosphate Acids, PPG-12 butyl ether dimethicone, PPG-2 dimethicone, PPG-12 dimethicone, PPG-27 dimethicone, PPG-4 oleth-10 dimethicone, propoxytetramethylpiperidinyl dimethicone, propyl trimethicone, quaternium-80, retinoxytrimethylsilane, silanediol salicylate, silanetriol, silanetriol alginate, silanetriol glutamate, silanetriol lysine, silanetriol melaninate, silanetriol trehalose ether, silica, silica dimethicone silylate,Silica dimethyl silylate, silica silylate, silicon carbide, silicone-1, silicone quaternium-2, silicone quaternium-2 panthenol succinate, silicone quaternium-3, silicone quaternium-4, silicone quaternium-5, silicone quaternium-6, silicone quaternium-7, silicone qua, Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, Silicone Quaternium-16, Silicone Quaternium-16 / Glycidoxydimethicone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium-18, Silicone Quaternium-19, Silicone Quaternium-20, Silicone Quaternium-21, Silicone Quaternium-22, Silicone Quaternium-24, Silicone Quaternium-25, Argy Siloxanetriol phytic acid, siloxanetriol phytic acid, simethicone, carboxydecyl PEG-8 dimethicone sodium, dimethicone PEG-7 acetylmethyltaurate sodium, dimethylsilanol hyaluronate sodium, methylsilanol lactate sodium, methylsilanol mannuronate sodium, PCA methylsilanol sodium, PG-propyl dimethicone thiosodium sulfate copolymer, PG-sodium thiosulfate propyl dimethicone, propoxyhydroxypropyl thiosulfate silica sodium, sorbitylsilanediol Soybean triethoxysilylpropyldimonium chloride, stearalkonium dimethicone PEG-8 phthalate, stearamidopropyl dimethicone, steardimonium hydroxypropyl panthenyl PEG-7 phosphate dimethicone, steardimonium hydroxypropyl PEG-7 phosphate dimethicone, stearoxydimethicone, stearoxymethicone / dimethicone copolymer, stearoxytrimethylsilane, stearylaminopropyl methicone, stearyldimethicone, Stearyl / lauryl methacrylate crosspolymer, stearyl meth Cone, stearyltriethoxysilane, stearyltrimethicone, styrene / acrylate / dimethicone acrylate crosspolymer, styrene / acrylate / dimethicone copolymer, TEA-dimethicone PEG-7 phosphate, tetrabutoxypropyltrisiloxane, tetramethylhexaphenyltetrasiloxane, tetramethyltetraphenyltrisiloxane, copheryloxypropyltrisiloxane, trideceth-9PG-amodimethicone, triethoxycaprylylsilane, triethoxysilylethyldimethicone / methicone copolymer,Triethoxysilylethyl polydimethylsiloxyethyl dimethicone, triethoxysilylethyl polydimethylsiloxyethyl hexyl dimethicone, triethoxysilylpropyl carbamoylethoxypropyl butyl dimethicone, trifluoromethyl C1-4 yl dimethicone, trifluoropropyl cyclopentasiloxane, trifluoropropyl cyclotetrasiloxane, trifluoropropyl dimethicone, trifluoropropyl dimethicone / PEG-10 crosspolymer, trifluoropropyl dimethicone / trifluoropropyl divinyl dimethicone Crosspolymer, Trifluoropropyl Dimethicone / Vinyl Trifluoropropyl, Dimethicone / Silsesquioxane Crosspolymer, Propyl Dimethiconol, Trifluoropropyl Dimethyl / Trimethylsiloxysilicate, Trifluoropropyl Methicone, Trimethoxycaprylylsilane, Trimethoxysilyl Dimethicone, Trimethylpentaphenyl Trisiloxane, Trimethylsiloxyamodimethicone, Trimethylsiloxyphenyl Dimethicone, Trimethylsiloxysilicate, Trimethylsiloxysilicate / Dimethicone Crosspolymer - Trimethylsiloxysilicate / Dimethiconol Crosspolymer, Trimethylsiloxysilyl Carbamoyl Pullulan, Trimethylsilyl Hydrolyzed Conchiolin Protein PG-Propylmethylsilanediol Crosspolymer, Trimethylsilyl Hydrolyzed Silk PG-Propylmethylsilanediol Crosspolymer, Trimethylsilyl Hydrolyzed Wheat Protein PG-Propylmethylsilanediol Crosspolymer, Trimethylsilyl Pullulan, Trimethylsilyl Trimethylsiloxyglycolate, Trimethylsilyl Trimethylsiloxylactate, Methylsilyl salicylic acid, triphenyl trimethicone, trisiloxane, tritribitoxysiloxymethylsilane, undecyl chloride dimethicone, vinyl dimethicone, vinyl dimethicone / lauryl dimethicone crosspolymer, vinyl dimethicone / methicone silsesquioxane crosspolymer, vinyl dimethyl / trimethylsiloxysilicate stearyl dimethicone crosspolymer, VP / dimethiconyl acrylate / polycarbamyl / polyglycol ester, zinc carboxydecyltrisiloxane and zinc dimethicone PEG-8 succinate,and mixtures thereof.

[0051] More preferably, the silicones to be included in the mixture according to the present invention are dimethicone, cyclomethicone, phenyltrimethicone, cyclohexasiloxane, and cyclopentasiloxane. A detailed overview of suitable volatile silicones is disclosed in TODD ET AL. IN COSM. TOIL. 91, 27 (1976).

[0052] <Wax and stabilizer> In addition to the natural oils used, waxes may also be present in the formulation. Natural waxes, in particular, include, for example, candelilla wax, carnauba wax, japonica wax, espartograss wax, cork wax, guarma wax, rice oil wax, sugarcane wax, uricury wax, montan wax, beeswax, shellac wax, spermaseth, lanolin (wool wax), uropiggy fat, ceresin, ozocerite (earth wax), petrolatum, paraffin wax, and microwax. Chemically modified waxes (hard waxes) include, for example, montan ester wax, sazole wax, hydrogenated jojoba wax, and synthetic waxes such as polyalkylene wax and polyethylene glycol wax.

[0053] As stabilizers, for example, metal salts of fatty acids such as magnesium, aluminum, and / or zinc stearate or ricinoleate can be used.

[0054] <Primary sun protection filter> The primary sun protection filter referred to in this invention is, for example, an organic substance (light filter) that is liquid or crystalline at room temperature, absorbs ultraviolet light, and releases the absorbed energy in the form of long-wave radiation, such as heat.

[0055] The formulation according to the present invention advantageously contains at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic pigment. The formulation according to the present invention preferably contains at least one UV-B filter or a broadband filter, and more preferably contains at least one UV-A filter and at least one UV-B filter.

[0056] The UV filters cited below, which can be used in the specification of this invention, are preferred but not limited. The UV filters that are preferred are selected from the group consisting of 1, 2, 3, 4, 5 or more types below. [Table 5]

[0057] In a preferred embodiment, the sunscreen filter forming component (ii) represents a blend of UV-A and UV-B filters selected from the group consisting of homosalate, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylmethane, ethylhexyl salicylate, and mixtures thereof. Particularly preferred is a blend of all these filters commercially available under the registered trademark NeoHeliopan® Flat (SYMRISE), as related to International Publication WO2020 / 088778A1.

[0058] Suitable pigments include oxides of titanium (TiO2), zinc (ZnO), iron (FE2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g., MnO), aluminum (Al2O3), cerium (e.g., Ce2O3), and / or mixtures thereof.

[0059] In a further preferred embodiment, the formulation according to the present invention contains a total amount of sunscreen, i.e., particularly UV filters and / or inorganic pigments (UV filter pigments), such that the formulation according to the present invention has a photoprotection coefficient of 5 to 50. Such formulation according to the present invention is particularly suitable for the protection of skin and hair.

[0060] <Secondary sun protection filter> In addition to the primary sun protection factors mentioned above, antioxidant-type secondary sun protection factors can also be used. Antioxidant-type secondary sun protection factors block the photochemical reaction chain that is initiated when ultraviolet rays penetrate the skin. Typical examples include amino acids (e.g., glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g., urocanic acid) and their derivatives, peptides (e.g., D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g., anserine)), carotenoids, carotenes (α-carotene, β-carotene, lycopene, etc.) and their derivatives, chlorogenic acid and its derivatives, liponic acid and its derivatives (e.g., dihydroliponic acid), aurothioglucose, propylthiouracil and other thiols (e.g., thioredoxin, glutathione, cysteine, cystine, cystamine and glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, α-linoleyl, cholesteryl and glyceryl esters) and their salts. Dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts), sulfoximine compounds (e.g., butionine sulfoximine, homocysteine ​​sulfoximine, butionine sulfone), butionine sulfone, penta-, hexa- and hepta-thionine sulfoximine) in very small, suitable doses, as well as (metal) chelating agents (e.g., α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acid, bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and its derivatives, unsaturated fatty acids and their derivatives (e.g., linoleic acid, oleic acid), folic acid and its derivatives, Bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (linoleic acid, oleic acid, etc.), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (ascorbyl palmitate, etc.)These include magnesium ascorbyl phosphate (ascorbyl acetate), tocopherol and its derivatives (such as vitamin E acetate), vitamin A and its derivatives (such as vitamin A palmitate), coniferyl benzoate, rutic acid and its derivatives, glycosylrutin, ferulic acid, furfridenglucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguayaretinic acid, nordihydroguayaretinic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (such as dispersions in ethanol), zinc and its derivatives (such as ZnO and ZnSO4), selenium and its derivatives (e.g., selenium methionine), stilbene and its derivatives (e.g., stilbene oxide, trans-stilbene oxide), and derivatives of these active substances (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides, and lipids) suitable for the purposes of the present invention.

[0061] Advantageous inorganic secondary photoprotective pigments are finely dispersed metal oxides and metal salts, which are also described in International Publication WO2005 / 123101A1. The total amount of inorganic pigments, particularly hydrophobic inorganic micropigments, in the finished cosmetic formulation according to the present invention is advantageously 0.1 to 30% by weight, preferably 0.5 to 10.0% by weight, in any case, based on the total weight of the formulation.

[0062] Also preferred is the use of particulate UV filters or optionally hydrophobizable inorganic pigments, such as oxides and / or mixtures thereof of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g., MnO), aluminum (Al2O3), cerium (e.g., Ce2O3).

[0063] <Biogenic substances and antioxidants> Examples of bioactive substances include tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy)ribonucleic acid and its fragmentation products, β-glucan, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts, such as Prunus extract, Bambaranus extract, and vitamin complexes.

[0064] Antioxidants inhibit the chain of photochemical reactions that occur when ultraviolet light penetrates the skin. Typical examples include amino acids (glycine, histidine, tyrosine, tryptophan, etc.) and their derivatives, imidazoles (urocanic acid, etc.) and their derivatives, peptides such as D,L-carnosine, D-carnosine, and L-carnosine and their derivatives (anserine, etc.), carotenoids, carotenes (-carotene, lycopene, etc.) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives, and others. The following substances have very low tolerance levels (e.g., pmol to mol / kg): anserine, carotenoids, carotenes (-carotene, lycopene, etc.) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (dihydrophosphate, etc.), aurothioglucose, propylthiouracil, other thiols (e.g., thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, linoleyl, cholesteryl and glyceryl esters) and their salts: dilauryl thiodipropionate, ditearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts), and sulfoximine compounds (e.g., butionine sulfoximine, homocysteine ​​sulfoximine), butionine sulfone, penta-, hexa-, hepta-thionine sulfoximine, etc.).Furthermore, (metal) chelating agents (e.g., hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), hydroxy acids (e.g., citric acid, lactic acid, malic acid), humic acid, gallic acid, bile extract, bilirubin, biliverdin, EDTA, EGTA and their derivatives), unsaturated fatty acids and their derivatives (e.g., linolenic acid, linoleic acid, oleic acid, etc.), folic acid and its derivatives, ubiquinone, ubiquinol and its derivatives, vitamin C and its derivatives (e.g., ascorbyl palmitate, magnesium-ascorbyl phosphate, ascorbyl acetate, etc.), tocopherol and its derivatives (e.g., vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate), and benzoin resin from coniferous trees. These include benzoates, rutinic acid and its derivatives, glycosylrutin, ferulic acid, furfridenglucitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiarecate, nordihydroguaiaretinic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (e.g., ZnO, ZnSO4, etc.), selenium and its derivatives (e.g., selenium-methionine), stilbene and its derivatives (e.g., styrene oxide, trans-stilbene oxide), and derivatives of these named active substances suitable for the present invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides, and lipids).

[0065] <Active substances that regulate hair pigmentation> Preferred active ingredients for lightening hair are selected from the following group: Kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinol and 4-(1-phenylethyl)1,3-dihydroxybenzene (phenylethyl resorcinol), cyclohexylcarbamate (preferably one or more cyclohexylcarbamates disclosed in International Publications WO2010 / 122178 and WO2010 / 097480), sulfur-containing molecule, preferably glutathione or cysteine, α-hydroxy acid (preferably cysteine Econic acid, lactic acid, malic acid), their salts and esters, N-acetyltyrosine and its derivatives, undecenoylphenylalanine, gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, thujaplicin and its derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranone, preferably senkyu nolide, vinylguacol, ethylguacol, dionic acid, preferably octodecendionic acid and / or azelaic acid, nitrogen oxide synthesis inhibitors, preferably L-nitroarginine and its derivatives, 2,7-Dinitroindazole or thiocitrulline, metal chelating agents (preferably α-hydroxy fatty acids, phytic acid, humic acid, bile acids, bile extracts, EDTA, EGTA and their derivatives), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for lightening skin and hair, the latter preferably used in the form of plant extracts, preferably bamboo grass extract, rice extract, papaya extract, turmeric extract, mulberry extract, sedum extract, feverfew extract, licorice root extract or concentrated or isolated components therefrom, preferably glabridin or licochalcone A, Artiocarpus extract, Lumex and Lamrus extracts, pine (pinus) extract, Vitis extract or stilbene derivatives isolated or concentrated therefrom, Saxifraga extract, Scutellaria extract, grape extract and / or microalgae extract, especially Tetraselmis suecica extract.

[0066] In this respect, beneficial skin and hair sun protection active ingredients include tyrosinases such as L-tyrosine, N-acetyltyrosine, L-DOPA, and L-dihydroxyphenylalanine; xanthine alkaloids and their derivatives such as caffeine, theobromine, and theophylline; proopiomelanocortin peptides such as ACTH and α-MSH, their peptide analogs, and other substances that bind to melanocortin receptors; peptides such as Val-Gly-Val-Ala-Pro-Gly,Lys-lle-Gly-Arg-Lys, or Leu-lle-Gly-Lys; purines, pyrimidines, folic acid, copper salts such as copper gluconate, copper chloride, and copper pyrrolidone; 1,3,4-oxadiazole-2-thiols such as 5-pyrazine-2-yl-1,3,4-oxadiazole-2-thiol; curcumin; zinc diglycinate (Zn(GIy)2), e.g., EP0 The following are examples of compounds that activate the migration of melanosomes to keratinocytes, such as manganese(II) bicarbonate complexes ("pseudocatalases") described in 584178, tetrasubstituted cyclohexene derivatives described in WO2005 / 032501, isoprenoids described in WO2005 / 102252 and WO2006 / 010661, melanin derivatives such as MELASYN-100 and MELANZE, diacylglycerols, aliphatic or cyclic diols, psoralens, prostaglandins and their analogs, adenylate cyclase activators, and compounds that activate the migration of melanosomes to keratinocytes, such as serine proteases and PAR-2 ​​receptor agonists, extracts of plants and plant parts of Chrysanthemum species and Sanguisorba species, walnut extracts, Uruk extracts, rhubarb extracts, microalgae extracts, especially Isochrysis galbana, trehalose, erythrolucose, dihydroxyacetone substrates or substrate analogs. Flavonoids that cause skin and hair discoloration or browning (e.g., quercetin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and diosmetine, morin, quercitrin, naringenin, hesperidin, phlorizin and phloretin) may also be used.

[0067] Next, the amount of the additional active ingredients (one or more compounds) for regulating skin and hair pigmentation in the product according to the present invention, as described in the above examples, is preferably 0.00001-30% by weight, preferably 0.0001-20% by weight, and particularly preferably 0.001-5% by weight, based on the total weight of the preparation.

[0068] <Hair growth stimulants or inhibitors> The hair growth activator is preferably selected from the group consisting of the following: pyrimidine derivatives, for example, 2,4-diaminopyrimidine-3-oxide (aminexil), 2,4-diamino-6-piperidinopyrimidine-3-oxide (minoxidil) and its derivatives, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and its derivatives, xanthine alkaloids such as caffeine, theobromine and theophylline and their derivatives, quercetin and its derivatives, dihydroquercetin (taxifolin) and its derivatives, potassium chrysanthemum Diuretics, antiandrogens, synthetic or natural 5-reductase inhibitors, nicotinic acid esters such as tocopheryl nicotinate, benzyl nicotinate and C1-C6 alkyl nicotinates, proteins such as tripeptide Lys-Pro-Val, diphencyprene, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, cyproterone acetate, spironolactone and other diuretics, FK506 (tacrolimus, Fujima Calcineurin inhibitors such as isine and its derivatives, cyclosporine A and its derivatives, zinc and zinc salts, polyphenols, procyanidins, proanthocyanidins, phytosterols such as β-sitosterol and biotin, eugenol, (±)-β-citronellol, panthenol, glycogen derived from mussels, microorganisms, algae, plants and extracts from plant parts of the genus Leontodon or Taraxacum, orthosiphon, Vitex, Co Fia, Paulinia, Theobroma, Asiasalum, Cucurbitaceae or Stifolobium, Selenoa repens (saw palmetto), Sophora flavecens, Pydium africanum, Panicum myriaceum, Simisifuga racemosa, Glycine max, Eugenia caryophyllata, Cotinus cogiglia, Hibiscus rosa sinensis, Camellia sinensis, Ilex paraguariansis, Lis galbana, Licorice, Grapes, Apples, Barley, Hops, or / or hydrolysates of rice or wheat.

[0069] Alternatively, the formulations and products according to the present invention may include one or more hair growth inhibitors (as described above), i.e., agents for reducing or preventing hair growth. The hair growth inhibitors are preferably selected from the group consisting of the following: Activin, activin derivatives or activin agonists, ornithine decarboxylase inhibitors such as α-difluoromethylornithine, or pentacyclic triterpenes such as ursolic acid, betulin, betulinic acid, oleanolic acid and its derivatives, 5α-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, gamma-glutamyl transpeptidase inhibitors, lanceglutaminase inhibitors, soy-derived serine protease inhibitors, microorganisms, algae, different microalgae or plants, and for example, legumes, nightshades, grasses, milkweed or cucurbits, genera such as Condorus, Groiopertis, Ceramium, Dervilleia, Glycine max, Sanguisorba officinalis, Calendula, Hamamelis virginiana, Arnica montana, Salix alba, Hypericum, or Gymnema sylvestre.

[0070] <Physiological coolants and physiological warmers> Physiological coolants are preferably selected from the group formed by the species (including their optical isomers and racemates) shown in the table below. [Table 6] JPEG0007896053000013.jpg4285

[0071] Physiological warming agents can be selected from the group consisting of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homocapsaicin, homodihydrocapsaicin nonibamide, and chili pepper extract.

[0072] <Anti-inflammatory drugs> Appropriate anti-inflammatory agents can be selected from the group formed by the following:

[0073] (i) Corticosteroid-type steroidal anti-inflammatory substances, especially hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, (ii) Nonsteroidal anti-inflammatory substances, especially oxicams such as piroxicam and tenoxicam, salicylates such as aspirin, disalside, sorprine, and fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin, and clindanac, fenamate salts such as mefenum, meclofenum, flufenum, and niflumic, propionic acid derivatives such as ibufenum and niflumic, acetic acid derivatives such as tolmetin and clindanac, fenamic acid derivatives such as mefenum, meclofenum, flufenum, and niflum, propionic acid derivatives such as ibuprofen, naproxen, and benoxaprofen, pyrazoles such as phenylbutazone, oxyphenylbutazone, febrazone, and azapropazone, (iii) Natural or naturally occurring anti-inflammatory substances, or substances that reduce redness and / or itching, especially chamomile, aloe vera, Commiphora species, Rubia species, willow, willow herb, oats, calendula, arnica, St. John's wort, honeysuckle, rosemary, passionflower, witch hazel, ginger or echinacea, or a single active compound thereof. (iv) Histamine receptor antagonists, serine protease inhibitors (e.g., soy extract), TRPV1 antagonists (e.g., 4-t-butylcyclohexanol), NK1 antagonists (e.g., aprepitant, hydroxyphenylpropamide benzoate), cannabinoid receptor agonists (e.g., palmitoylethanolamine), and TRPV3 antagonists.

[0074] <Antibacterial agent> Suitable antimicrobial agents are, in principle, all substances effective against Gram-positive bacteria, such as 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether (triclosan), 4-chloro-3,5-dimethylphenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chlorophenol, 3-(4-chlorophenoxy The ingredients are (C)-1,2-propanediol, 3-iodo-2-propynylbutylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antimicrobial fragrance, thymol, thyme oil, eugenol, clove oil, menthol, mint oil, farnesol, phenoxyethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprate (DMC), salicylic acid N-alkylamide, such as n-octylsalicylic acid or n-decylsalicylic acid.

[0075] <Enzyme inhibitors> Suitable enzyme inhibitors are, for example, esterase inhibitors. Preferably, trialkyl citrates such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate, and especially triethyl citrate (Hydagen CAT). These substances inhibit enzyme activity and suppress odor generation. Other substances suitable as esterase inhibitors are as follows: sulfates or phosphates of sterols, e.g., sulfates or phosphates of lanosterol, cholesterol, campesterol, stigmasterol and sitosterol; dicarboxylic acids and their esters, e.g., glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate; hydroxycarboxylic acids and their esters, e.g., citric acid, malic acid, tartaric acid or diethyl tartrate; zinc glycinate.

[0076] <Odor Absorbent and Antiperspirant Activator> A suitable odor absorber is a substance that can absorb and retain most odor-forming compounds. Adsorbents reduce the partial pressure of each component and decrease its diffusion rate. It is important that the fragrance is not damaged in this process. Odor absorbers are ineffective against bacteria. These consist of specific, mainly odor-neutral fragrances, such as a zinc complex salt of ricinoleic acid as the main component, or, as those skilled in the art know, a "fixative," such as an extract of labdanum or styrax, or certain abietic acid derivatives. Odor masking agents are fragrances or oils that, in addition to their function as odor maskers, impart their respective fragrance notes to the deodorant. Examples include mixtures of natural and synthetic fragrances. Natural fragrances are extracts from flowers, stems, leaves, fruits, peels, roots, trees, herbs, grasses, needles, branches, resins, and balsams. Animal products such as civet and castoreum are also suitable. Typical synthetic fragrance compounds are ester, ether, aldehyde, ketone, alcohol, and hydrocarbon type products. Examples of ester-type fragrance compounds include benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styryl propionate, and benzyl salicylate. Examples of ethers include benzyl ethyl ether; examples of aldehydes include linear alcanals with 8-18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, lilial, and bourgeonal; examples of ketones include ionone and methylcedyl ketone; alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linaol, phenylethyl alcohol, and terpineol; and hydrocarbons mainly include terpenes and balsams. However, it is preferable to use a mixture of different fragrances to create a pleasant fragrance note.Essential oils with relatively low volatility are mainly used as aromatic ingredients, but they are also suitable as perfume oils, such as sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil, labdanum oil, and lavandin oil. It is preferable to use bergamot oil, dihydromyrcenoyl, lilial, liral, citronellol, phenylethyl alcohol, α-hexyl cinnamaldehyde, geraniol, benzylacetone, cyclamenaldehyde, linalool, boasanblenforte, ambroxan, indole, hedione, sandelice, lemon oil, mandarin oil, orange oil, allylamyl glycolate, cyclobertal, lavandin oil, clary sage oil, β-damascone, geranium oil bourbon, cyclohexyl salicylate, veltofix cool, iso-E-super, fixolid NP, evanyl, iraldine gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, ilotyl, or floramat, either alone or in mixtures.

[0077] Suitable astringent antiperspirant active ingredients are primarily salts of aluminum, zirconium, or zinc. Such suitable astringent antiperspirant active ingredients include, for example, aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, aluminum sesquichlorohydrate and their complex compounds, such as complex compounds with 1,2-propylene glycol, aluminum hydroxyallantoinate, aluminum chloride tartrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate and their complex compounds, such as complex compounds with amino acids such as glycine.

[0078] <Film-forming agents and anti-dandruff agents> Standard film-forming agents include, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, acrylic acid series polymers, quaternized cellulose derivatives, collagen, hyaluronic acid and its salts, and similar compounds.

[0079] Suitable anti-dandruff agents include piroctone olamine (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), BAYPIVAL (registered trademark) (CLIMBAZOLE), KETOCONAZOL (registered trademark) (4-acetyl-1-{4-[2-(2,4-dichlorophenyl)R-2-(1H-imidazole-1-ylmethyl)-1,3-dioxirane-C-4-ylmethoxyphenyl}-piperazine, ketoconazol These are selenium, erbiol, selenium disulfide, colloidal sulfur, sulfur polyethylene glycol sorbitan monooleate, sulfur ricinol polyethoxylate, sulfur tar distillate, salicylic acid (or in combination with hexachlorophene), undecylenic acid, monoethanolamide sulfosuccinate sodium salt, LAMEPON (registered trademark) UD (protein / undecylenic acid condensate), zinc pyrithione, aluminum pyrithione, and magnesium pyrithione / dipyrithione magnesium sulfate.

[0080] <Carriers and Hydrotropes> Preferred cosmetic carrier materials are solid or liquid (including highly viscous substances) at 25°C and 10¹³ mbar, such as glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water, and mixtures of two or more liquid carrier materials with water. Optionally, these preparations according to the present invention may be prepared using preservatives or solubilizers. Other preferred liquid carrier substances that may be components of the preparations according to the present invention are selected from the group consisting of oils such as vegetable oils, neutral oils, and mineral oils.

[0081] Preferred solid carrier materials that may be components of the preparation according to the present invention include hydrocolloids, such as starch, hydrolyzed starch, chemically or physically modified starch, dextrin, (powdered) maltodextrin (preferably with a dextrose equivalent of 5-25, preferably 10-20), lactose, silicon dioxide, glucose, modified cellulose, gum arabic, ghati gum, tragacanth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, carob bean flour, alginate, agar, pectin, inulin, and mixtures of two or more of these solids, particularly maltodextrin (preferably with a glucose equivalent of 15-20), lactose, silicon dioxide, and / or glucose.

[0082] Furthermore, to improve the flow behavior, hydrotropes such as ethanol, isopropyl alcohol, or polyols can be used. Suitable polyols preferably contain 2-15 carbon atoms and at least 2 hydroxyl groups. Polyols may also contain other functional groups, particularly amino groups, and may be nitrogen-modified. Typical examples are as follows: Glycerol; • Alkylene glycols, such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol, and polyethylene glycol with an average molecular weight of 100 to 1000 daltons; Industrial oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10, for example, industrial diglycerol mixtures with a diglycerol content of 40 to 50% by weight; Methylol compounds, for example, particularly trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol; Lower alkyl glucosides, particularly those containing 1-8 carbon atoms in the alkyl group, such as methyl and butyl glucosides; • Sugar alcohols containing 5-12 carbon atoms, such as sorbitol or mannitol; Sugars containing 5-12 carbon atoms, such as glucose and sucrose; • Amino sugars, such as glucamine; • Dialcoholamines such as diethanolamine or 2-aminopropane-1,3-diol.

[0083] <Preservatives and / or product protectants> Appropriate preservatives are listed in Appendix 6, Parts A and B of the Kosmetikver-ordnung ("Cosmetics Directive").

[0084] A suitable species can be selected from the group of preservatives, which consists of the following: Benzoic acid and parahydroxybenzoic acid, their esters and salts, benzyl benzoate, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, levulinic acid and its salts, anisic acid and its salts, perillic acid and its salts, cinnamic acid and its salts, formaldehyde and paraformaldehyde, 4-hydroxybenzaldehyde, ortho-, meta- and para-anisaldehyde, cinnamaldehyde, cinnamon alcohol, 2-hydroxybiphenyl ether and its salts, 2-zinc sulfidopyridine-N-oxide, inorganic sulfites and bisulfites, sodium iodate, chlorobutanol, 4-ethylmercury(II)5-amino-1,3-bis(2-hydroxybenzoic acid), its salts and esters, dehydrated acetic acid, formic acid, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, sodium salt of ethylmercury(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecylenic acid and its salts, 5-amino-1,3-bis(2- Ethylhexyl)-5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)-urea, 4-chloro-m-cresol, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether, 4-chloro-3,5-dimethylphenol, 1,1'-methylene-bis(3-(1-hydroxymethyl-2,4-dioxy) Midazolidine-5-yl)urea), poly-(hexamethylenediguanide)hydrochloride, (benzyloxymethoxy)-methanolhexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azonia-adamantan chloride, 1-(4-chlorophenoxy)-1-(1H-imidazole-1-yl)-3,3-dimethyl-2-butanone, 1,3-bis-(hydroxymethyl)-5,5-dimethyl-2,4-imidazolidinedione, 1,2-dibromo-2,4-dicyabutane, 2,2'-Methylene-bis(6-bromo-4-chlorophenol), bromochlorophene, 5-chloro-2-methyl-3(2H)-isothiazolinone, mixture of 2-methyl-3(2H)-isothiazolinone and magnesium chloride and magnesium nitrate, 2-octyl-2H-isothiazol-3-one, 1,2-benzisothiazol-3(2H)-one, 2-benzyl-4-chlorophenol, 3-(4-chlorphenoxy)-1,2-propanediol (chlorphenesin), 2-chloroacetamide, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride Cydin, N-alkyl(C12-C22)trimethylammonium bromide and chloride, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3-di(hydroxymethyl)-2,5-dioxoimidazolidine-4-yl)-N'-hydroxymethylurea, 1,6-bis(4-amidino-phenoxy)-n-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamine, alkyl-(C8-C18)-dimethylbenzyl-ammonium chloride Alkyl-(C8-C18)-dimethylbenzylammonium bromide, alkyl-(C8-C18)-dimethylbenzylammonium saccharinate, benzyl hemiformal, 3-iodo-2-propynyl butylcarbamate, sodium hydroxymethylaminoacetate, sodium hydroxymethylaminoacetate, imidazolidinyl urea, diazolidinyl urea, sodium hydroxymethylglycinate, DMDM ​​hydantoin, tropolone, (ethylenedioxy)dimethanol, 2-Brome-2-(bromomethyl)pentanedinitrile, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, α,α',α”-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, pyridine-2-thiol-1-oxide, sodium salt, tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5-d]imidazole-2,5(1H,3H)-dione, 1,3-bis(hydroxymethyl)-1-(1,3,4-Tris(hydroxymethyl)-2,5-dioxoimidazolidine-4-yl)urea (diazolidinylurea), 1,3-bis(hydroxymethyl)-5,5-dimethylimidazolidine-2,4-dione, 3-acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, cetylpyridinium chloride, caprylhydroxamic acid, sorbohydroxamic acid and mixtures thereof; 1,3-propanediol, methylpropanediol, 1,2-pentanediol, 1,2-hexane Diol, 1,2-octanediol, 1,2-decanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, 1,2-decanediol, ethylhexylglycerin, hexoxy-propane-1,2-diol, heptoxy-propane-1,2-diol, octoxy-propane-1,2-diol, 3-phenoxy-propane-1,2-diol, 3-benzyloxy-propane-1,2-diol, 3-phenylethyloxy-propane- 1,2-diol, 3-phenylpropyloxypropane-1,2-diol, 3-methylbenzyloxypropane-1,2-diol, sorbitan caprylate, triclosan, crimbazole, octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridone, 2-aminoethanol), chitosan, farnesol, 2-butyloctanoic acid, 2-benzylheptan-1-ol, glycerol monolaurate, bis(2-pyridone) Dylthio)zinc 1,1'-dioxide, N,N'-(decane-1,10)-diyldipyridine-1-yl-4-ylidene)-dioctan-1-amine dihydrochloride (octenidine dihydrochloride), thymol, eugenol, benzyl alcohol, 2-phenylethyl alcohol, 3-phenylpropanol, 2-phenoxyethanol, 1-phenoxy-propan-2-ol, 3-phenoxypropanol, benzyloxymethanol, 4-hydroxyacetophenone, and mixtures thereof.

[0085] <dye> Suitable dyes are, for example, any of the substances approved and suitable for cosmetic purposes as described in the publication "Kosmetische Farbemittel" of the Farbstoffkommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pp. 81-106. Examples include cochineal red A (CI 16255), patent blue V (CI 42051), indigotine (CI 73015), chlorophyllin (CI 75810), quinoline yellow (CI 47005), titanium dioxide (CI 77891), indantrene blue RS (CI 69800), and madder lake (CI 58000). Luminol can also exist as a luminescent pigment. Favorable coloring pigments include, for example, titanium dioxide, mica, iron oxides (e.g., Fe2O3, Fe3O4, FeO(OH)) and / or tin oxide. Advantageous dyes include, for example, carmine, berlin blue, chromium oxide green, ultramarine blue, and / or manganese violet.

[0086] <Pharmacy> Preferred compositions according to the present invention are selected from a group of products, preferably as leave-on products (meaning that one or more compounds remain on the skin and / or hair for an extended period, compared to rinse-off products), for use as products for treating, protecting, caring for and cleansing skin and / or hair, or as makeup products.

[0087] The formulations according to the present invention are preferably in the form of emulsions, such as W / O (water in oil), O / W (oil in water), W / O / W (oil in water), O / W / O (water in oil) emulsions, PIT emulsions, Pickering emulsions, low oil content emulsions, microemulsions or nanoemulsions, or solutions. For example, oils (fatty oils or fatty acid esters, especially C6-C32 fatty acid C2-C30 esters) or silicone oils, in dispersions, suspensions, creams, lotions or milks, depending on the manufacturing method and ingredients, gels (hydrogels, water-dispersed gels, oleogels), sprays (e.g., pump sprays or sprays with propellants), or foams or impregnating solutions for cosmetic wipes, detergents, e.g., soaps, synthetic detergents, liquid detergents, shower and bath additives, bath products (capsules, oils, tablets, salts, bath additives, soaps, etc.), foaming agents, skincare products, e.g., lotions (as above), ointments, pastes, gels (as above), oils, balsams, serums, powders (e.g., face powders, body powders), eau de perfumes, eau de toilettes, aftershaves, masks, pencils, sticks, roll-ons, pumps, aerosols (foaming, non-foaming or post-foaming), deodorants These include antiperspirants and / or deodorants, mouthwashes and mouth rinses, foot care products (including exfoliants and deodorants), insect repellents, sunscreens, after-sun preparations, shaving products, aftershave balms, pre- and aftershave lotions, depilatory agents, hair care products such as shampoos (including 2-in-1 shampoos, anti-dandruff shampoos, baby shampoos, shampoos for dry scalps, and concentrated shampoos), conditioners, hair tonics, hair waters, hair rinses, styling creams, pomades, perm and setting lotions, hair sprays, styling aids (such as gels and waxes), hair smoothing agents (detangling agents, relaxers), hair dyes (such as temporary direct dyes, semi-permanent dyes, and permanent dyes), hair conditioners, hair mousses, eye care products, makeup, makeup removers, and baby products.

[0088] Auxiliary substances and additives may be included in amounts of 5 to 99% by weight, preferably 10 to 80% by weight, based on the total weight of the formulation. The amount of cosmetic or dermatological auxiliary agents, additives, and fragrances used in each case can be easily determined by simple trial and error by those skilled in the art, depending on the properties of the particular product.

[0089] The compound may also contain water in an amount of up to 99% by weight, preferably about 5 to about 80% by weight, more preferably about 10 to about 50% by weight or about 60 to about 80% by weight, based on the total weight of the compound.

[0090] <Household composition> Another object of the present invention relates to household compositions containing, preferably in an amount of about 0.1 to about 5% by weight, more preferably about 0.2 to about 2% by weight, and most preferably about 0.5 to about 1% by weight, a fragrance according to formula (I), a fragrance mixture according to formula (I), (II), and optionally (III), or a perfume composition containing the same. Suitable examples of detergents include heavy powder detergents, heavy liquid detergents, light powder detergents, light liquid detergents, detergent tablets, fabric softeners, manual dishwashing detergents, all-purpose cleaners, and the like.

[0091] The detergent compositions according to the present invention may contain any of the components conventionally found in such compositions, such as anionic, nonionic, cationic, amphoteric or zwitterionic (co)surfactants, organic solvents, builders, enzymes, and additional auxiliaries such as soil water repellents, thickeners, colorants, and fragrances. For surfactants as additives, please refer to the examples disclosed for cosmetic compositions.

[0092] <Organic solvents> The liquid light or heavy detergent may contain an organic solvent, preferably one that is miscible with water. Polydiols, ethers, alcohols, ketones, amides, and / or esters are preferably used as the organic solvent for this purpose in an amount of 0 to 90% by weight. Preferably, it is 0.1 to 70% by weight. Particularly preferred is 0.1 to 60% by weight. For example, low molecular weight polar substances such as methanol, ethanol, propylene carbonate, acetone, acetonylacetone, diacetone alcohol, ethyl acetate, 2-propanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol, dipropylene glycol monomethyl ether, and dimethylformamide, or mixtures thereof, are preferred.

[0093] <Enzyme> Cellulase enzyme. If a cellulase enzyme is optionally used in the instant detergent composition, it is preferably incorporated at a level sufficient to provide up to about 5 mg by weight, more preferably about 0.01 mg to about 3 mg, of the active enzyme per gram of composition. Unless otherwise specified, the compositions herein preferably contain about 0.001% to about 5% by weight, more preferably 0.01% to 1% by weight of a commercially available enzyme preparation.

[0094] Suitable cellulases for the present invention include bacterial or fungal cellulases. Preferably, they will have an optimal pH between 5 and 9.5. Suitable cellulases are fungal cellulases produced from Humicola insolens and Humicola strain DSM1800 or cellulase 212-producing bacteria belonging to the genus Aeromonas, and cellulases extracted from the hepatopancreas of marine mollusks (Dolabella auricula Solander), suitable cellulases are also disclosed in GB 2,075,028A. Furthermore, cellulases particularly suitable for use herein are disclosed in WO1992 / 013057A1. Most preferably, the cellulase used in the instant detergent composition is purchased from Novo Industries A / S under the product names CAREZYMEO and CELLUZYMEO.

[0095] Other enzymes. Additional enzymes may be included in the detergent compositions herein for a wide variety of fabric washing purposes, including, for example, the removal of protein-based, carbohydrate-based, or triglyceride-based stains, the prevention of refugee dye migration, and the repair of fabrics. Examples of additional enzymes to be incorporated include proteases, amylases, lipases, peroxidases, and mixtures thereof. Other types of enzymes may also be included. These enzymes may be of any origin, such as plant, animal, bacterial, fungal, or yeast. However, their selection is governed by several factors, including optimal pH activity and / or stability, heat resistance, stability against active detergents, builder properties, and the potential to cause unpleasant odors during use. In this regard, bacterial or fungal enzymes, such as bacterial amylases and proteases, are preferred.

[0096] The enzyme is typically incorporated at a level sufficient to provide up to about 5 mg by weight per gram of composition, more typically about 0.01 mg to about 3 mg of active enzyme. In other words, the compositions herein typically contain about 0.001% to about 5% by weight, preferably 0.01% to 1% by weight, of a commercially available enzyme preparation. The protease enzyme is usually present in such commercially available preparations at a level sufficient to provide 0.005–0.1 anson units (AU) of activity per gram of composition.

[0097] A suitable example of a protease is subtilisin, obtained from specific strains of B. subtilis and B. licheniforms. Another suitable protease is obtained from Bacillus strains, exhibiting maximum activity in the pH range of 8–12, and is developed and marketed by Novo Industries A / S under the registered trademark name ESPERASE. Preparations of this enzyme and similar enzymes are described in Novo's GB1,243,784. Commercially available proteases suitable for removing protein-based stains include ALCALASE and SAVINASE from Novo Industries A / S, and MAXATASE from International Bio-Synthetics, Inc. Other proteases include protease A; protease B, and proteases manufactured by Genencor International, Inc. according to US5,204,015 and US5,244,791.

[0098] Examples of amylases include α-amylases such as RAPIDASE (registered trademark), International Bio-Synthetics, Inc., and TERMAMYL (registered trademark), Novo Industries.

[0099] Suitable lipase enzymes for detergent applications include those produced by microorganisms of the Pseudomonas group, such as Pseudomonas Stutzeri ATCC 19154. This lipase is available from Amano Pharmaceutical Co., Ltd. under the trade name "Lipase." This lipase is also marketed by Amano Pharmaceutical Co., Ltd. under the trade name Lipase P "Amano." Other commercially available lipases include Amano-Ces, lipases derived from Chromobacter Viscosum, such as Chromobacter Viscosum Var. Lipolyticum NRRLB 3673, which is marketed by Toyo Jozo Co., Ltd., as well as Chromobacter Viscosum lipases marketed by US Biochemical Corp. and Disoynth Co., and lipases derived from Pseudomonas Gladioli. LIPOLASE® enzyme (commercially available from Novo Industries A / S), derived from Humicola Lanuginosa, is the preferred lipase for use herein.

[0100] Peroxidase enzymes are used in combination with oxygen sources, such as percarbonates, perborates, persulfates, and hydrogen peroxide. Peroxidase enzymes are used in "solution bleaching," i.e., to prevent dyes or pigments removed from a substrate during a washing operation from migrating to other substrates in the washing solution. Peroxidase enzymes are known in the art and include, for example, horseradish peroxidase, ligninase, and haloperoxidases such as chloroperoxidase and bromoperoxidase. Peroxidase-containing detergent compositions are disclosed, for example, in WO1989 / 099813A.

[0101] <Enzyme stabilizer> The enzymes used herein are stabilized by the presence of a water-soluble source of calcium and / or magnesium ions in the finished detergent composition, supplying such ions to the enzyme. (Calcium ions are generally somewhat more effective than magnesium ions and are preferred herein when using only one type of cation). Further stability may be provided by the presence of various other technically disclosed stabilizers, particularly borates (see US4,537,706, which is incorporated herein in whole). Typical detergents, especially liquids, contain about 1 to about 30, preferably about 2 to about 20, more preferably about 5 to about 15, and most preferably about 8 to about 12 mmol of calcium ions per liter of the finished composition. In solid detergent compositions, the formulation may include a water-soluble calcium ion source in sufficient quantity to supply such an amount to the laundry liquid. Alternatively, the hardness of natural water may suffice.

[0102] It should be understood that the aforementioned levels of calcium and / or magnesium ions are sufficient to provide enzyme stability. More calcium and / or magnesium ions can be added to the composition to provide an additional measure of grease removal performance. Thus, as a general proposition, the compositions herein typically contain about 0.05% to about 2% by weight of a water-soluble source of calcium or magnesium ions, or both. The amount may, of course, vary depending on the amount and type of enzyme employed in the composition.

[0103] The compositions herein may also optionally, but preferably, contain various additional stabilizers, particularly borate-type stabilizers. Typically, such stabilizers are used at levels of about 0.25% to about 10%, preferably about 0.5% to about 5%, and more preferably about 0.75% to about 3%, relative to the weight of boric acid or other borate compounds that can form boric acid in the composition (calculated relative to boric acid). While boric acid is preferred, other compounds such as boron oxide, borax, and other alkali metal borates (e.g., sodium ortho-, meta-, and pyroborates, and sodium pentaborate) are also suitable. Alternatively, substituted boric acids (such as phenylboronic acid, butaneboronic acid, and p-bromophenylboronic acid) may be used instead of boric acid.

[0104] <Builder> Zeolite. Fine-crystalline synthetic zeolites containing bound water can be used as builders, for example, preferably zeolite A and / or zeolite P (commercially available from Crosfield), with zeolite P being particularly preferred. However, zeolite X, as well as mixtures of A, X, Y, and / or P, are also suitable. Co-crystallized sodium / potassium aluminum silicate of zeolite A and zeolite X, such as Vegobond® RX. (commercially available from Condea Augusta SpA), is also of particular interest. Preferably, the zeolite can be used as a spray-dried powder. If the zeolite is added as a suspension, this may include a small amount of nonionic surfactant as a stabilizer, for example, 1-3% by weight of zeolite, of ethoxylated C12-C18 fatty alcohols having 2-5 ethylene oxide groups, C12-C14 fatty alcohols having 4-5 ethylene oxide groups, or ethoxylated isotridecanol. A suitable zeolite has an average particle size of less than 10 μm (test method: volume distribution Coulter counter) and preferably contains 18-22% by weight, particularly 20-22% by weight, bound water. Separately, phosphates can also be used as a builder.

[0105] Layered silicate. A suitable alternative or partial alternative to phosphates and zeolites is crystalline layered sodium silicate. These types of crystalline layered silicates are described, for example, in European Patent Application EP0164514A1. A preferred crystalline layered silicate is obtained, for example, from the process described in WO91 / 08171A1.

[0106] Amorphous silicate. Preferred builders also include amorphous sodium silicate with a modulus (Na2O:SiO2 ratio) of 1:2-1:3.3, preferably 1:2-1:2.8, more preferably 1:2-1:2.6, which dissolve with delay and exhibit multiple wash cycle properties. Delayed dissolution compared to conventional amorphous sodium silicate can be achieved in various ways, for example, by surface treatment, compounding, compression / molding, or over-drying. In the context of this invention, the term “amorphous” also means “X-ray amorphous.” In other words, silicates do not produce the sharp X-ray emission typical of crystalline materials in X-ray diffraction experiments, but at best produce one or more maxima of scattered X-rays with a diffraction angle width of several degrees. However, particularly excellent builder properties can be achieved even when silicate particles produce indistinct or sharp diffraction maxima in electron diffraction experiments. This is interpreted as meaning that the product has a microcrystalline region of 10-hundreds of nm, with a maximum value of 50 nm, and a particularly preferred value of 20 nm. This type of X-ray amorphous silicate also exhibits delayed dissolution compared to conventional water glass, as described, for example, in DE 4400024A1. Compressed / densified amorphous silicates, compounded amorphous silicates, and over-dried X-ray amorphous silicates are particularly preferred.

[0107] Phosphate. In addition, commonly known phosphates can be added as builders unless their use should be avoided for ecological reasons. Sodium salts of orthophosphates, pyrophosphates, and especially tripolyphosphates are particularly suitable. Their content is generally 25% by weight or less, preferably 20% by weight or less, based on the finished composition. In some cases, tripolyphosphates in particular have been shown to provide a synergistic improvement in secondary cleaning power when combined with other builders, even at low amounts of up to 10% by weight, based on the finished composition. The preferred amount of phosphate is 10% by weight or less, especially 0% by weight.

[0108] <Cobuilder> Polycarboxylic acid. Useful organic cobuilders are polycarboxylic acids, for example, polycarboxylic acids usable in the form of sodium salts thereof, where polycarboxylic acid is understood to be a carboxylic acid having two or more acidic functions. These include, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA) and its derivatives and mixtures thereof. Preferred salts are salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.

[0109] organic acid. Acids themselves can also be used. In addition to their building effects, acids typically possess the properties of acidifying components and therefore also play a role in establishing a relatively low and mild pH in detergent or cleansing compositions. Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid, and mixtures thereof are particularly noteworthy in this regard. More suitable acidifying agents are known pH adjusters such as sodium bicarbonate and sodium bisulfate.

[0110] polymer. Particularly preferred polymer cobuilders are polyacrylates, which preferably have a molecular weight of 2,000–20,000 g / mol. Due to their excellent solubility, preferred representatives of this group are also short-chain polyacrylates, which have a molecular weight of 2,000–10,000 g / mol, and more particularly 3,000–5,000 g / mol. Suitable polymers also include substances consisting partially or entirely of vinyl alcohol units or their derivatives.

[0111] Further preferred copolymer polycarboxylates are copolymers of acrylic acid and methacrylic acid, and copolymers of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid and maleic acid, consisting of 50-90% by weight of acrylic acid and 50-10% by weight of maleic acid, have proven particularly suitable. The relative molecular weight based on free acid is generally 2,000-70,000 g / mol, preferably 20,000-50,000 g / mol, and particularly 30,000-40,000 g / mol. The (co)polymer polycarboxylate can be added as an aqueous solution or, preferably, as a powder. To improve water solubility, the polymer may also contain allyl sulfonic acid as a monomer, such as allyloxybenzenesulfonic acid and methallyl sulfonic acid, as disclosed in EP0727448B1.

[0112] Biodegradable polymers consisting of two or more different monomer units are particularly preferred, examples of which include those consisting of acrylic acid and maleic acid salts, and vinyl alcohol or vinyl alcohol derivatives as monomers, as in DE4300772A, or those consisting of acrylic acid and 2-alkylallylsulfonic acid salts and sugar derivatives as monomers. More preferred copolymers are those described in DE4303320A1 and DE4417734A1, which preferably contain acrolein and acrylic acid / acrylate, or acrolein and vinyl acetate as monomers.

[0113] Similarly, other preferred builders are polymeric aminodicarboxylic acids, their salts, or precursors. Polyaspartic acids or their salts and derivatives disclosed in DE 19540086A are particularly preferred as they possess bleach-stabilizing properties in addition to their co-building properties.

[0114] A more preferred builder is a polyacetal, which can be obtained by treating a dialdehyde with a polyol carboxylic acid having 5-7 carbon atoms and at least 3 hydroxyl groups, as described in EP0280223A1. Preferred polyacetals can be obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof, as well as from polycarboxylic acids such as gluconic acid and / or glucoheptonic acid.

[0115] carbohydrates. Further preferred organic cobuilders are dextrins, for example, oligomers or polymers of carbohydrates that can be obtained by partial hydrolysis of starch. Hydrolysis can be carried out using typical processes, such as acidic or enzyme-catalyzed processes. The hydrolysis product preferably has an average molecular weight in the range of 400 to 500,000 g / mol. Polysaccharides with a dextrose equivalent (DE) of 0.5 to 40, particularly 2 to 30, are preferred, as DE is recognized as a measure of the reducing effect of polysaccharides compared to dextrose having a DE of 100. Maltodextrins with a DE of 3 to 20, dry glucose syrups with a DE of 20 to 37, and so-called yellow dextrins and white dextrins with relatively high molecular weights of 2,000 to 30,000 g / mol can also be used. Preferred dextrins are described in UK Patent Application 9419091.

[0116] Such oxidized derivatives of dextrins relate to reaction products with oxidizing compositions that can oxidize at least one alcohol functional group of the saccharide ring to a carboxylic acid functional group. Such oxidized dextrins and methods for producing them are known, for example, from European Patent Application EP0232202A. Products oxidized at C6 of the sugar ring are particularly advantageous.

[0117] Other derivatives of oxydisuccinate and disuccinate, preferably ethylenediamine disuccinate, are also more suitable cobuilders. Here, ethylenediamine-N,N'-disuccinate (EDDS), whose synthesis is described, for example, in US3,158,615, is used, preferably in the form of its sodium or magnesium salt. In this context, glycerin disuccinate and glycerin disuccinate are also particularly preferred, including, for example, those described in US4,524,009. Appropriate amounts added to zeolite-containing and / or silicate-containing formulations are in the range of 3–15% by weight.

[0118] Lactones. Other useful organic cobuilders are, for example, acetylated hydroxycarboxylic acids and their salts, which may optionally exist in the form of lactones, and which contain at least four carbon atoms, at least one hydroxyl group and at most two acid groups. Such cobuilders are described, for example, in WO / 1995020029A1.

[0119] <Bleaching compounds, bleaching agents, and bleaching activators> The detergent compositions herein may optionally contain a bleaching agent, or a bleaching composition comprising a bleaching agent and one or more bleaching activators. If present, the bleaching agent is typically present in an amount of about 1% to about 30%, more typically about 5% to about 20%, of the detergent composition, and is particularly intended for washing fabrics. If present, the amount of bleaching activators is typically present in an amount of about 0.1% to about 60%, more typically about 0.5% to about 40%, of the bleaching composition consisting of bleaching agent plus bleaching activators.

[0120] The bleaching agents used herein may be any bleaching agents currently known or becoming known that are useful in detergent compositions for textile cleaning, hard surface cleaning, or other cleaning purposes. These include oxygen-based bleaching agents and other bleaching agents. Perborate bleaching agents, such as sodium perborate (e.g., monohydrate or tetrahydrate), may be used herein.

[0121] Another category of bleaches that can be used without restriction includes percarboxylic acid bleaches and their salts. Preferred examples of this class of agents include magnesium monoperoxyphthalate hexahydrate, magnesium salts of meta-chloroperbenzoic acid, 4-nonylamino-4-oxoperoxybutyric acid, and diperoxide decanedioic acid.

[0122] Peroxide bleaches can also be used. Suitable peroxide bleaches include sodium carbonate peroxyhydrate and equivalent "percarbonate" bleaches, sodium pyrophosphate peroxyhydrate, urea peroxyhydrate, and sodium peroxide. Persulfate bleaches (e.g., OXONEO®, commercially available from DuPont) can also be used.

[0123] A preferred percarbonate bleach consists of dry particles having an average particle size in the range of about 500 μm to about 1,000 μm, wherein about 10% by weight or less of the particles are smaller than about 200 μm, and about 10% by weight or less of the particles are larger than about 1,250 μm. Optionally, the percarbonate can be coated with a silicate, borate, or water-soluble surfactant. Percarbonates are available from a variety of commercial sources.

[0124] A mixture of bleaching agents can also be used.

[0125] Peroxygen bleaches, perborates, and percarbonates are preferably combined with bleach activators, which in turn generate peroxy acids corresponding to the bleach activator in aqueous solution (i.e., during the washing process). Nonanoyloxybenzene sulfonates (NOBS) and tetraacetylethylenediamine (TAED) activators are typical examples, and mixtures thereof can also be used.

[0126] Preferred amide-derived bleaching agents include (6-octanamide caproyl)oxybenzenesulfonate, (6-nonanamide caproyl)oxybenzenesulfonate, (6-decanamide caproyl)oxybenzenesulfonate, and mixtures thereof.

[0127] Another class of bleaching activators consists of benzoxazine-type activators disclosed in US4,966,723, which is incorporated herein by reference.

[0128] Highly preferred lactam activators include: benzoyl caprolactam, octanoyl caprolactam, 3,5,5-trimethylhexanoyl caprolactam, nonanoyl caprolactam, decanoyl caprolactam, undecenoyl caprolactam, benzoyl valerolactam, octanoyl valerolactam, decanoyl valerolactam, undecenoyl valerolactam, nonanoyl valerolactam, 3,5,5-trimethylhexanoyl valerolactam, and mixtures thereof. Optionally, they may be adsorbed onto a solid carrier, such as acyl caprolactam, preferably benzoyl caprolactam, and onto sodium perborate.

[0129] Other bleaching agents besides oxygen bleaching agents are also known in the art and can be used herein. One type of non-oxygen bleaching agent of particular interest includes photoactivating bleaching agents such as zinc sulfonate and / or aluminum phthalocyanine. When used, the detergent composition will typically contain about 0.025% to about 1.25% by weight of such bleaching agent, in particular zinc phthalocyanine sulfonate.

[0130] If desired, the bleaching compound can be catalyzed with a manganese compound. Such manganese catalysts are well known in the art and include MnIV2(uO)3(1,4,7-trimethyl-1,4,7-triazacyclononane)2(PF6)2, MnIII2(uO)1(U-OAc)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)2, MnIV4(UO)6(1,4,7-triazacyclononane)4(ClO4)4, MnIIIMnIV4(UO)1(U-OAC)2(1,4,7-trimethyl-1,4,7-triazacyclononane)2(ClO4)3, MnIV(1,4,7-trimethyl-1,4,7-triazacyclononane)-(OCH3)3(PF6), and mixtures thereof.

[0131] In practice, but not limited to, the compositions and processes described herein can be adjusted to provide at least one part per ten million of an active bleaching catalyst species in an aqueous laundry solution, preferably from about 0.1 ppm to about 700 ppm, more preferably from about 1 ppm to about 500 ppm of catalyst species in the laundry solution.

[0132] <Polymer soil (dirt) release agent> Any polymer soil release agent known to those skilled in the art can be optionally incorporated into the detergent composition and process of the present invention. The polymer soil release agent is characterized by having both a hydrophilic segment that hydrophilizes the surface of hydrophobic fibers such as polyester or nylon, and a hydrophobic segment that deposits on the hydrophobic fibers and remains attached there until the completion of the wash and rinse cycle, and thus functions as an anchor for the hydrophilic segment. Therefore, it functions as an anchor for the hydrophilic segment. This makes it easier to wash away dirt generated after treatment with the soil release agent in subsequent washing steps.

[0133] Polymer soil release agents useful in this specification include, in particular, soil release agents having the following: (a)(i) A polyoxyethylene segment having at least 2 degrees of polymerization, or (ii) One or more nonionic hydrophilic components essentially consisting of oxypropylene or polyoxypropylene segments having a degree of polymerization of 2 to 10, wherein the hydrophilic segments do not contain oxypropylene units unless they are bonded to adjacent sites at each end by ether bonds, or (iii) A mixture of oxyalkylene units consisting of oxyethylene units and 1 to about 30 oxypropylene units, wherein the mixture contains a sufficient amount of oxyethylene units such that the hydrophilic component has a sufficient amount of hydrophilicity to increase the hydrophilicity of the surface of conventional polyester synthetic fibers when a soil release agent is deposited on such surface, wherein the hydrophilic segment preferably consists of at least about 25% oxyethylene units, and more preferably, in particular, with respect to such component having about 20 to about 30 oxypropylene units, consists of at least about 50% oxyethylene units; or, (b) One or more hydrophobic components including the following: (i) C3 oxyalkylene terephthalate segment, where the hydrophobic component also includes oxyethylene terephthalate, the ratio of oxyethylene terephthalate to C3 oxyalkylene terephthalate units is approximately 2:2; the ratio of C3 oxyalkylene terephthalate units is approximately 2:1 or less. (ii) C4-C6 alkylene or oxy C4-C6 alkylene segment, or mixture thereof, (iii) A poly(vinyl ester) segment having at least 2 degrees of polymerization, preferably polyvinyl acetate), or (iv) C1-C4 alkyl ether or C4 hydroxyalkyl ether substituents, or mixtures thereof, wherein the substituents exist in the form of C1-C4 alkyl ether or C4 hydroxyalkyl ether cellulose derivatives, or mixtures thereof, and such cellulose derivatives are amphiphilic, such cellulose derivatives have sufficient levels of C1-C4 alkyl ether units and / or C4 hydroxyalkyl ether units to adhere to the surface of a conventional polyester synthetic fiber, and once adhered to such a conventional synthetic fiber surface, retain sufficient levels of hydroxyl to enhance the hydrophilicity of the fiber surface, or A combination of (a) and (b).

[0134] Typically, the polyoxyethylene segment of (a)(i) may be used at higher levels, but will have a degree of polymerization of about 200, preferably 3 to about 150, more preferably 6 to about 100. Suitable oxy C4-C6 alkylene hydrophobic segments include, but are not limited to, end caps for polymer soil release agents.

[0135] Polymer soil release agents useful in the present invention also include hydroxyether cellulose polymers, cellulose derivatives such as copolymer blocks of ethylene terephthalate or propylene terephthalate with polyethylene oxide or polypropylene oxide terephthalate. Such agents are commercially available and include cellulose hydroxyethers such as METHOCEL® (dow). Cellulosic soil release agents used herein also include those selected from the group consisting of c1-c4 alkyl and c4 hydroxyalkyl cellulose.

[0136] Examples of soil release agents characterized by a poly(vinyl ester) hydrophobic segment include graft copolymers of poly(vinyl ester), such as C1-C6 vinyl ester, preferably poly(vinyl acetate), grafted onto a polyalkylene oxide skeleton, such as a polyethylene oxide skeleton; see EP0219048, which is incorporated herein by reference. Examples of commercially available soil release agents of this type include SOKALAN® type materials, such as SOKALAN® HP-22 available from BASF.

[0137] One preferred type of soil release agent is a copolymer having random blocks of ethylene terephthalate and polyethylene oxide (PEO) terephthalate. The molecular weight of this polymer soil release agent is preferably in the range of about 25,000 to about 55,000.

[0138] Another preferred polymer soil release agent is a polyester having repeating units of ethylene terephthalate units, containing 10-15% by weight of ethylene terephthalate units along with 90-80% by weight of polyoxyethylene terephthalate units, derived from polyoxyethylene glycol with an average molecular weight of 300-5,000. Examples of such polymers include the commercially available ZELCON® 5126 (DuPont) and MILEASE® T (ICI).

[0139] Another preferred polymeric soil release agent is a sulfonated product of a substantially linear ester oligomer consisting of an oligomeric ester backbone of terephthaloyl and oxyalkyleneoxy repeat units and end portions covalently bonded to the backbone. These soil release agents are described in detail in US 4,968,451. Other suitable polymeric soil release agents include the terephthalate polyesters of US 4,711,730, the anionically end-capped oligomeric esters of US 4,721,580, the block polyester oligomer compounds of US 4,702,857, and the anionically, particularly sulfoaroyl, end-capped terephthalate esters of US 4,877,896. These patents are hereby incorporated by reference in their entirety.

[0140] Yet another preferred soil release agent is an oligomer having repeat units of terephthaloyl units, sulfoisoterephthaloyl units, oxyethyleneoxy units and oxy-1,2-propylene units. The repeat units form the backbone of the oligomer and are preferably terminated with modified isethionate end caps. A particularly preferred soil release agent of this type consists of about 1 sulfoisophthaloyl unit, 5 terephthaloyl units, about a 1.7 to about 1.8 ratio of oxyethyleneoxy units and oxy-1,2-propyleneoxy units, and 2 end cap units of sodium 2-(2-hydroxyethoxy)-ethanesulfonate. The soil release agent also preferably contains from about 0.5% to about 20% of a crystallization reducing stabilizer selected from the group consisting of xylenesulfonate, cumenesulfonate, toluenesulfonate, and mixtures thereof, based on the weight of the oligomer.

[0141] When utilized, the soil release agent generally constitutes from about 0.01% to about 10.0% by weight of the detergent compositions herein, typically from about 0.1% to about 5%, preferably from about 0.2% to about 3.0%.

[0142] <Polymeric Dispersant> Polymeric dispersants can be advantageously utilized in the detergent compositions herein at levels from about 0.1% to about 7% by weight, particularly in the presence of zeolites and / or layered silicate builders. Suitable polymeric dispersants include polymeric polycarboxylates and polyethylene glycols, although other materials known in the art can also be used. When used in combination with other builders (including low molecular weight polycarboxylates), polymeric dispersants are thought, without intending to be limited by theory, to enhance the overall detergent builder performance by crystal growth inhibition, particulate soil release inhibition, and redeposition prevention.

[0143] Polymeric polycarboxylate materials can be prepared by polymerizing or copolymerizing suitable unsaturated monomers, preferably in acid form. Unsaturated monomer acids that can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid, and methylenemalonic acid. The presence in the present specification of polymeric polycarboxylates, or monomer segments that do not contain carboxylic acid radicals such as vinyl methyl ether, styrene, ethylene, etc., is suitable provided that such segments do not exceed about 40% by weight.

[0144] Particularly suitable polymeric polycarboxylates can be derived from acrylic acid. Such acrylic acid-based polymers useful herein are water-soluble salts of polymerized acrylic acid. The average molecular weight of the acid form of such polymers is preferably in the range of about 2,000 to 10,000, more preferably about 4,000 to 7,000, and most preferably about 4,000 to 5,000. Water-soluble salts of such acrylic acid polymers can include, for example, alkali metal salts, ammonium salts, and substituted ammonium salts. Water-soluble polymers of this type are known materials. The use of this type of polyacrylate in detergent compositions is disclosed, for example, in US 3,308,067.

[0145] Acrylic acid / maleic acid copolymers can also be used as preferred components of dispersion / reprecipitation inhibitors. Examples of such materials include water-soluble salts of copolymers of acrylic acid and maleic acid. The average molecular weight of the acid form of such copolymers is preferably in the range of about 2,000 to 100,000, more preferably about 5,000 to 75,000, and most preferably about 7,000 to 65,000. The ratio of acrylate segments to maleic acid segments in such copolymers is generally in the range of about 30:1 to about 1:1, and more preferably about 10:1 to 2:1. Examples of water-soluble salts of such acrylic acid / maleic acid copolymers include alkali metal salts, ammonium salts, and substituted ammonium salts. This type of soluble acrylic acid / maleic acid copolymer is a known material described in EP0193360A, which also describes such polymers consisting of hydroxypropyl acrylate. Other useful dispersants include maleic acid / acrylic acid / vinyl alcohol terpolymers, such as acrylic acid / maleic acid / vinyl alcohol 45 / 45 / 10 terpolymers.

[0146] Another polymer material that may be included is polyethylene glycol (PEG). PEG not only exhibits dispersant properties but can also act as a clay soil release-anti-deposition agent. Typical molecular weight ranges for these purposes are about 500 to about 100,000, preferably about 1,000 to about 50,000, and more preferably about 1,500 to about 10,000.

[0147] Polyaspartate and polyglutamate dispersants can also be used, particularly in combination with zeolite builders. Dispersants such as polyaspartate preferably have a molecular weight (average) of about 10,000.

[0148] <Foam inhibitors / Foam suppressants> When used in automated cleaning processes in particular, it is advantageous to add conventional foam inhibitors to the composition. Suitable foam inhibitors include, for example, natural or synthetic soaps with a high C18-C24 fatty acid content. Suitable non-surface-active foam inhibitors include, for example, organopolysiloxanes and fine particles, mixtures thereof with silanized silica, and mixtures thereof with paraffin, wax, microcrystalline wax and silanized silica or bis-stearylethylenediamide. Mixtures of various foam inhibitors, such as mixtures of silicone, paraffin, or wax, are also advantageous. Preferably, the foam inhibitors, especially silicone-containing and / or paraffin-containing foam inhibitors, are supported on granular, water-soluble, or dispersible carrier materials. In particular in this case, a mixture of paraffin and bis-stearylethylenediamide is preferred.

[0149] Compounds for reducing or suppressing foam formation can be incorporated into the detergent composition of the present invention. Foam inhibitors are particularly important in so-called "high-concentration washing processes" and in front-loading European-style washing machines.

[0150] A wide variety of materials can be used as foam inhibitors, and foam inhibitors are well known to those skilled in the art. For example, see Kirk Othmer Encyclopedia Of Chemical Technology, Third Edition, Volume 7, Pages 430-447 (John Wiley & Sons, Inc., 1979). One category of foam inhibitors of particular interest includes monocarboxylic acid fatty acids and their soluble salts. Monocarboxylic acid fatty acids and their salts used as foam inhibitors typically have a hydrocarbyl chain of 10 to about 24 carbon atoms, preferably 12 to 18 carbon atoms. Suitable salts include alkali metal salts such as sodium salts, potassium salts, and lithium salts, as well as ammonium salts and alkanolammonium salts.

[0151] The detergent compositions herein may also contain non-surfactant foam inhibitors. These include, for example, high molecular weight hydrocarbons such as paraffins, fatty acid esters (e.g., fatty acid triglycerides), fatty acid esters of monohydric alcohols, and aliphatic C18-C40 ketones (e.g., stearone). Other foam inhibitors include N-alkylated aminotriazines such as tri-,hexa-alkylmelamine or di-,tetra-alkyldiamine chlortriazine, propylene oxide formed as a product of cyanuryl chloride and 2 or 3 moles of a primary or secondary amine containing 1-24 carbon atoms, and monostearyl phosphate esters such as monostearyl alcohol phosphate esters and monostearyl di-alkali metal (e.g., K, Na, Li) phosphate esters and phosphate esters. Hydrocarbons such as paraffins and haloparaffins can be used in liquid form. Liquid hydrocarbons are liquid at room temperature and atmospheric pressure, have a pour point in the range of about -40°C to about 50°C, and a minimum boiling point of about 110°C (at atmospheric pressure) or higher. Preferably, waxy hydrocarbons having a melting point of about 100°C or less are also known to be used. Hydrocarbon foam inhibitors are known in the art and include aliphatic, alicyclic, aromatic, and heterocyclic saturated or unsaturated hydrocarbons having about 12 to about 70 carbon atoms. The term “paraffin” as used in this discussion of foam inhibitors is intended to include mixtures of true paraffins and cyclic hydrocarbons.

[0152] Another preferred category of non-surfactant foam inhibitors consists of silicone foam inhibitors. This category includes the use of polyorganosiloxane oils such as polydimethylsiloxane, dispersions or emulsions of polyorganosiloxane oils or resins, and combinations of polyorganosiloxane and silica particles in which the polyorganosiloxane is chemiadsorbed or fused onto silica. Silicone foam inhibitors are well known in the art.

[0153] Other silicone foam inhibitors are disclosed in US3,455,839, which is entirely incorporated herein, relating to compositions and processes for defoaming aqueous solutions by incorporating a small amount of polydimethylsiloxane fluid therein.

[0154] A mixture of silicone and silica silane is described, for example, in DE-OS2124526, which is incorporated herein in whole. Silicone defoamers and sud control agents in granular detergent compositions are disclosed in US4,652,392, which is incorporated herein in whole.

[0155] In preferred silicone foam inhibitors used herein, the solvent of the continuous phase consists of a specific polyethylene glycol or polyethylene-polypropylene glycol copolymer or a mixture thereof (preferably), or polypropylene glycol. The main silicone foam inhibitor is branched / crosslinked and preferably not linear.

[0156] The silicone foam inhibitors used herein preferably consist of polyethylene glycol and polyethylene glycol / polypropylene glycol copolymers, all having an average molecular weight of less than about 1000, preferably between about 100 and 800. The polyethylene glycol and polyethylene / polypropylene glycol copolymers used herein have a solubility in water at room temperature of about 2% by weight or more, preferably about 5% by weight or more.

[0157] Preferred solvents in this specification are polyethylene glycol having an average molecular weight of less than about 1,000, more preferably between about 100 and 800, and most preferably between 200 and 400, and polyethylene glycol / polypropylene glycol copolymers, preferably PPG200 / PEG300. Preferably, the weight ratio of polyethylene glycol to polyethylene-polypropylene glycol copolymer is between about 1:1 and 1:10, most preferably between 1:3 and 1:6.

[0158] Preferred silicone foam inhibitors used herein do not contain polypropylene glycol with a molecular weight of 4,000. They also preferably do not contain ethylene oxide-propylene oxide block copolymers such as PLURONIC® L101.

[0159] Other foam inhibitors useful herein consist of secondary alcohols (e.g., 2-alkyl alkanols) and mixtures of such alcohols with silicone oils. Examples of secondary alcohols include C6-C16 alkyl alcohols having C1-C16 chains. A preferred alcohol is 2-butyloctanol, available from Condea under the registered trademark ISOFOL® 12. Mixtures of secondary alcohols are available from Enichem under the registered trademark ISALCHEM® 123. Mixed foam inhibitors typically consist of an alcohol-silicone mixture in a weight ratio of 1:5 to 5:1.

[0160] The compositions herein generally contain 0% to about 5% of foam inhibitors. When used as foam inhibitors, monocarboxylic acid fatty acids and their salts are generally present in amounts up to about 5% by weight of the detergent composition. Preferably, about 0.5% to about 3% of fatty monocarboxylic acid foam inhibitors are used. Silicone foam inhibitors are typically used in amounts up to about 2.0% by weight of the detergent composition, although higher amounts may also be used. This upper limit is essentially practical, mainly due to concerns about minimizing costs and the effectiveness of low amounts in effectively controlling foaming. Preferably, about 0.01% to about 1% of silicone foam inhibitors are used, more preferably about 0.25% to about 0.5%. When used herein, these wt% values ​​include any silica that can be used in combination with polyorganosiloxanes, and any auxiliary materials that can be used. Monostearyl phosphate foam inhibitors are generally used in amounts ranging from about 0.1% to about 2% by weight of the composition. Hydrocarbon foam inhibitors are generally used in amounts ranging from about 0.01% to about 5.0%, although higher levels can also be used. Alcohol foam inhibitors are typically used in amounts ranging from 0.2% to 3% by weight of the finished composition.

[0161] <Cellulating agents and chelating agents> Salts of polyphosphonic acids can be considered as chelating agents and stabilizers for peroxy compounds and enzymes that are particularly sensitive to heavy metal ions. Here, for example, sodium salts of 1-hydroxyethane-1,1-diphosphonic acid, diethylenetriaminepentamethylenephosphonic acid, or ethylenediaminetetramethylenephosphonic acid are used in amounts ranging from 0.1% to 5% by weight.

[0162] The detergent compositions herein can also optionally contain one or more chelating agents for iron and / or manganese. Such chelating agents can be selected from the group consisting of aminocarboxylates, aminophosphonates, polyfunctional substituted aromatic chelating agents, and mixtures thereof, all of which are as defined below. Without wishing to be bound by theory, the advantages of these materials are thought to be due in part to their excellent ability to remove iron and manganese ions from the washing liquor by forming soluble chelates. Some of the detergent builders described herein can function as chelating agents, and it is understood that if such detergent builders are present in sufficient amounts, both functions can be provided.

[0163] Aminocarboxylates useful as optional chelating agents include ethylenediaminetetraacetate, N-hydroxyethylethylenediamine￢triacetate, nitrilotriacetate, ethylenediaminetetrapropionate, triethylenetetraminehexacetate, diethylenetriamine￢pentaacetate, and ethanol diglycine, their alkali metal salts, ammonium salts, substituted ammonium salts, and mixtures thereof.

[0164] Aminophosphonates are also suitable for use as chelating agents in the compositions of the present invention when a low level of total phosphorus in the detergent composition is acceptable, and examples include ethylenediaminetetrakis(methylenephosphonate) under the name DEQUEST. Preferably, these aminophosphonates do not contain an alkyl or alkenyl group having more than about 6 carbon atoms.

[0165] Polyfunctional substituted aromatic chelating agents are also useful in the compositions herein. Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1,2-dihydroxy-3,5-disulfobenzene.

[0166] Preferred biodegradable chelating agents used herein are ethylenediamine disuccinates ("EDDS"), particularly the [S,S] isomer.

[0167] When used, these chelating agents generally constitute about 0.1% to about 10% by weight of the detergent composition as specified herein. More preferably, when used, the chelating agents constitute about 0.1% to about 3.0% by weight of such composition. <Clay soil release / redeposition prevention agent> The detergent compositions of the present invention may also optionally contain water-soluble ethoxylated amines having clay soil release and anti-re-adhesion properties. Granular detergent compositions containing these compounds typically contain about 0.01% to about 10.0% by weight of water-soluble ethoxylated amines; liquid detergent compositions typically contain about 0.01% to about 5% by weight.

[0168] The most preferred soil release and redeposition inhibitor is ethoxylated tetraethylenepentamine. Exemplary ethoxylated amines are further described in US4,597,898. Other groups of preferred clay soil release and redeposition inhibitors include cationic compounds disclosed in EP0111965A1, ethoxylated amine polymers disclosed in EP0111984A1, zwitterionic polymers disclosed in EP0112592A1, and amine oxides disclosed in US4,548,744. Another type of preferred redeposition inhibitor is carboxymethylcellulose (CMC) material. These materials are well known in the art.

[0169] <Graying inhibitors> Graying inhibitors have the function of keeping dirt removed from fibers suspended in the cleaning solution and preventing the dirt from re-adhering. Suitable for this purpose are mainly organic water-soluble colloids, such as water-soluble salts of (co)polymerized carboxylic acids, glues, gelatin, ether carboxylic acids and ether sulfonic acid salts of starch and cellulose, and acidic sulfate ester salts of cellulose and starch. Water-soluble acid group-containing polyamides are also suitable for this purpose. Furthermore, soluble starch preparations can also be used as the above-mentioned starches, such as decomposed starch and aldehyde starch. Polyvinylpyrrolidone can also be used. However, the use of cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, as well as polyvinylpyrrolidone, is preferred, and these can be added, for example, in amounts from 0.1% to 5% by weight based on the composition.

[0170] <Fluorescent whitening agents and UV absorbers> Any fluorescent whitening agent or other glossing or whitening agent known in the art can be incorporated into the detergent compositions herein, typically at levels of about 0.05% to about 1.2% by weight. Commercially available fluorescent whitening agents useful in the present invention include, but are not limited to, stilbenes, pyrazolines, coumarins, carboxylic acids, methyncyanines, dibenzotifen-5,5-dioxide, azoles, 5-membered ring- and 6-membered ring-heterocyclic compounds, and derivatives of other miscellaneous agents, and can be classified into subgroups.

[0171] Preferred glossing agents include those from Verona's PHORWHITE® series. Other glossing agents disclosed in this document include: Tinopal® UNPA, Tinopal CBS, and Tinopal 5BM; available from Ciba-Geigy; Artic White® CC and Artic White CWD; available from Hilton-Davis; 2-(4-strylphenyl)-2H-naphthol[1,2-D]triazole; 4,4'-bis-(1,2,3-triazole-2-yl)-stilbene; 4,4'-bis(stryl)bisphenyl; and aminocoumarin. Specific examples of these brighteners include 4-methyl-7-diethyl-aminocoumarin; 1,2-bis(benzimidazole-2-yl)ethylene; 1,3-diphenyl-furazoline; 2,5-bis(benzoxazole-2-yl)thiophene; 2-stryl-naphtho-[1,2-d]oxazole; and 2-(stilben-4-yl)-2H-naphtho-[1,2-d]triazole. In this specification, anionic gloss agents are preferred.

[0172] The composition may contain, for example, a derivative of diaminostilbenndisulfonic acid or an alkali metal salt thereof as a fluorescent whitening agent. Suitable fluorescent whitening agents include, for example, salts of 4,4'-bis-(2-anilino-4-morpholino-1,3,5-triazinyl-6-amino)stilbene-2,2'-di-sulfonic acid, or compounds with similar structures containing a diethanolamino group, methylamino group, anilino group, or 2-methoxyethylamino group instead of a morpholino group. Substituted diphenylstyryl type brighteners may also exist, such as alkali metal salts of 4,4'-bis(2-sulfostyryl)diphenyl, 4,4'-bis(4-chloro-3-sulfostyryl)diphenyl, or 4-(4-chlorostyryl)-4'-(2-sulfostyryl)diphenyl. Mixtures of the brighteners mentioned may also be used.

[0173] Furthermore, UV adsorbents can also be added. These are compounds with a clear ability to adsorb ultraviolet light, and by protecting the fibers from UV light that penetrates them, they not only improve the photostability of colorants and pigments for the skin of the wearer of the textile product, but also contribute as UV stabilizers. Generally, efficient non-radioactive compounds are mainly benzophenone derivatives substituted with hydroxyl and / or alkoxy groups at the 2 and / or 4 positions. Also suitable are substituted benzotriazoles, acrylates (cinnamic acid derivatives) with a phenyl substitution at the 3 position, acrylates optionally having a cyano group at the 2 position, salicylates, organic Ni complexes, and natural substances such as umbelliferone and endogenous urocanic acid. In preferred embodiments, the UV adsorbent absorbs UV-A and UV-B radiation, as well as possible UV-C radiation, and re-emits blue wavelength light, thus further providing an optical whitening effect. Preferred UV adsorbents include triazine derivatives, such as hydroxyaryl-1,3,5-triazine, sulfonated 1,3,5-triazine, O-hydroxyphenylbenzotriazole and 2-aryl-2H-benzotriazole, as well as bis(anilinotriazinyl-amino)stilbendisulfonic acid and their derivatives. UV-absorbing pigments such as titanium dioxide can also be used as UV adsorbents.

[0174] <Dye transfer inhibitors> The detergent composition of the present invention may also contain one or more materials that are effective in inhibiting the transfer of dye from one fabric to another during the washing process. Generally, such dye transfer inhibitors include polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, manganese phthalocyanines, peroxidases, and mixtures thereof. When used, these inhibitors typically constitute about 0.01% to about 10% by weight, preferably about 0.01% to about 5% by weight, and more preferably about 0.05% to about 2% by weight of the composition.

[0175] More specifically, polyamine N-oxide polymers preferred for use herein are described in US6,491,728, which is incorporated herein by reference.

[0176] Any polymer backbone can be used as long as the formed amine oxide polymer is water-soluble and has dye transfer inhibitory properties. Examples of suitable polymer backbones are polyvinyl, polyalkylene, polyester, polyether, polyamide, polyimide, polyacrylate, and mixtures thereof. These polymers include random or block copolymers in which one monomer is an amine N-oxide and the other monomer is an N-oxide. Amine N-oxide polymers typically have an amine-to-amine N-oxide ratio of 10:1 to 1:1,000,000. However, the number of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerization or appropriate degree of N-oxidation. Polyamine oxides can be obtained at almost any degree of polymerization. Typically, the average molecular weight is in the range of 500 to 1,000,000; more preferably 1,000 to 500,000; most preferably 5,000 to 100,000. This preferred class of materials can be called "PVNO".

[0177] The most preferred polyamine N-oxide useful for the detergent compositions of this specification is poly(4-vinylpyridine-N-oxide) having an average molecular weight of about 50,000 and an amine-to-amine N-oxide ratio of about 1:4.

[0178] Copolymers of N-vinylpyrrolidone and N-vinylimidazole polymers (collectively referred to as "PVPVI") are also preferred for use herein. Preferably, PVPVI has an average molecular weight in the range of 5,000–1,000,000, more preferably 5,000–200,000, and most preferably 10,000–20,000. PVPVI copolymers typically have a molar ratio of N-vinylimidazole to N-vinylpyrrolidone of 1:1 to 0.2:1, more preferably 0.8:1 to 0.3:1, and most preferably 0.6:1 to 0.4:1. These copolymers may be linear or branched.

[0179] The compositions of the present invention may also use polyvinylpyrrolidone ("PVP") having an average molecular weight of about 5,000 to about 400,000, preferably about 5,000 to about 200,000, and more preferably about 5,000 to about 50,000. PVP is known to those skilled in the field of detergents. Compositions containing PVP may also contain polyethylene glycol ("PEG") having an average molecular weight of about 500 to about 100,000, preferably about 1,000 to about 10,000. Preferably, the ratio of PPM-based PEG to PVP supplied in the cleaning solution is about 2:1 to about 50:1, and more preferably about 3:1 to about 10:1.

[0180] The detergent compositions herein may also optionally contain certain hydrophilic fluorescent whitening agents, in amounts of about 0.005% to 5% by weight, which also provide dye transfer inhibitory activity. When used, the compositions herein preferably contain about 0.01% to 1% by weight of such fluorescent whitening agents.

[0181] One preferred brightener is 4,4'-bis[(4-anilino-6-(N-2-bis-hydroxyethyl)-S-triazine-2-yl)amino]-2,2'-stilbendisulfonic acid and its disodium salt. This particular brightener species is commercially available from Ciba-Geigy Corporation under the trade name Tinopal-UNPA-GX®. Tinopal-UNPA-GX is a preferred hydrophilic fluorescent whitening agent useful in the detergent compositions described herein.

[0182] Another preferred glossing agent is 4,4'-bis[(4-anilino-6-(N-2-hydroxyethyl-N-methylamino)-S-triazine-2-yl)amino]2,2'-stilbendisulfonic acid disodium salt. This particular glossing agent is commercially available from Ciba-Geigy Corporation under the trade name Tinopal5BM-GX®.

[0183] Another preferred glossing agent is 4,4'-bis[(4-anilino-6-morphilino-s-triazine-2-yl)amino]2,2'-stilbendisulfonic acid, sodium salt. This particular type of glossing agent is commercially marketed by Ciba-Geigy Corporation under the trade name Tinopalams-GX®.

[0184] The specific fluorescent whitening agent species selected for use in the present invention offer particularly effective dye transfer inhibition advantages when used in combination with the selected polymeric dye transfer inhibitors described herein. The combination of such selected polymeric materials (e.g., PVNO and / or PVPVI) and such selected fluorescent whitening agents (e.g., Tinopal UNPA-GX, Tinopal 5BM-GX and / or Tinopal AMS-GX) provides significantly better dye transfer inhibition in aqueous cleaning solutions than either of these two detergent composition components used alone. Without being bound by theory, it is thought that such brighteners function in this way because they have a high affinity for fabrics in the cleaning solution and therefore deposit relatively quickly on these fabrics. The degree to which a brightener precipitates on fabric in the cleaning solution can be defined by a variable called the "abrasion coefficient." The attrition coefficient is generally defined as the ratio of the glossing agent material that settles on the fabric (a) to the initial concentration of the glossing agent in the cleaning solution (b). Glossing agents with a relatively high attrition coefficient are most suitable for inhibiting dye migration in the context of the present invention.

[0185] Of course, it will be understood that other conventional fluorescent whitening agent compounds can be optionally used in this composition to provide the "brightness" benefit of conventional fabrics, rather than a true dye migration inhibitory effect. Such uses are conventionally known in detergent formulations.

[0186] Thickening agent The composition may also include general thickeners and anti-deposition compositions, as well as viscosity modifiers such as polyacrylates, polycarboxylic acids, polysaccharides and their derivatives, polyurethanes, polyvinylpyrrolidone, castor oil derivatives, quaternized and / or ethoxylated hexamethylenediamine and other polyamine derivatives, and any mixtures thereof. Preferred compositions have a viscosity of 10,000 mPa*s or less, as measured with a Brookfield viscometer at a temperature of 20°C and a shear rate of 50 min-1.

[0187] <Inorganic salts> Further preferred components of the composition are water-soluble inorganic salts such as bicarbonates, carbonates, amorphous silicates, or mixtures thereof; alkali carbonates and amorphous silicates are particularly used, mainly sodium silicates with a molar ratio of Na2O:SiO2 of 1:1-1:4.5, preferably 1:2-1:3.5. Preferred compositions contain alkali salts, builders and / or cobuilders, preferably sodium carbonate, zeolites, crystalline, layered sodium silicates and / or trisodium citrate in amounts of anhydrous substances of 0.5-70% by weight, preferably 0.5 to 50% by weight, particularly 0.5 to 30% by weight.

[0188] <Coloring agent> The composition may further contain typical detergent and cleansing composition components, such as colorants, preferably those that leave no or negligible color on the fabric being washed. The preferred total amount of added colorant is 1% by weight or less, preferably 0.1% by weight or less, based on the composition. The composition may also contain a white pigment, such as TiO2.

[0189] <Industrial Use> Another object of the present invention relates to a method for improving the olfactory aspects of a fragrance and / or preventing unpleasant olfactory aspects, comprising or consisting of the following steps.

[0190] (i) A process for providing a fragrance that requires olfactory support; (ii) A step of applying a fragrance according to formula (I), or a fragrance mixture of components (I) and (II), to the fragrance; Preferably, the amount is in the range of about 0.001 to about 1% by weight, more preferably about 0.01 to about 0.1% by weight. Finally, the present invention also applies to the use of fragrances according to formula (I), fragrance mixtures of components (I) and (II), or perfume compositions containing them, for the purpose of improving the olfactory aspects of a fragrance and / or preventing unpleasant olfactory aspects of a fragrance.

[0191] For the sake of order, it should be noted that all of the preferred embodiments described above, particularly with respect to mixtures and mixing ratios, have been included without needing to be repeated in relation to the processes and uses of the present invention described above. [Examples]

[0192] <Example 1> (5-Isopropyl-2-methylene-cyclohexyl)acetate [ka] Chemical formula weight: 196.29; Molecular formula: C12H20O2

[0193] 5-Isopropyl-2-methylene-cyclohexanol (53.8 g, 70.5 mmol; prepared according to the literature), toluene (530 ml), and Na2CO3 (1.9 g, 17.6 mmol) were mixed with acetyl acetate (10.9 g, 105.7 mmol) under reflux (118-120 °C). After addition, the reaction mixture was maintained at 120 °C. After the reaction was complete, water was added very carefully between 80 and 85 °C and maintained for 30 minutes. The organic layer was evaporated, and the crude product was purified by Kugelrohr (KRD) at 0.5 mbar and 90 °C to obtain 56.2 g, Y = 82% (GC purity > 98%).

[0194] 1HNMR(400MHz,CDCl3)δ5.38(t,J=3.3Hz,1H),5.22-5.15(m,1H),4.96-4.89(m,1H ),4.86-4.79(m,1H),4.73(t,J=1.8Hz,2H),2.43(ddd,J=13.6,4.1,2.7Hz,1H),2.3 4-2.19(m,2H),2.11-1.99(m,8H),1.95(dtd,J=14.0,3.5,2.3Hz,1H),1.84-1.65(m ,2H),1.65-1.38(m,4H),1.38-1.27(m,1H),1.20-0.98(m,3H),0.92-0.82(m,12H).

[0195] 13CNMR(101MHz,CDCl3)δ170.30,170.19,146.93,146.05,111.80,104.25,74.63,73.99,42.60,37.7 2,36.91,35.52,33.85,32.25,31.89,30.79,30.44,30.17,21.51,21.17,19.86,19.76,19.71,19.53. MS:154,136,121,107,93,79,69,55,43,27. Aroma: Fresh, mushroom, rosewood, fruity, pear, violet

[0196] <Example 2> Masking of unpleasant notes in perfume composition

[0197] The following perfume compositions A, B, and C were obtained by formulating ingredients according to Table 1 below. Compositions B and C are according to the present invention, while A serves as a comparison.

[0198] Table 1 Fragrance composition [Table 7]

[0199] Fragrance stripes were treated with compositions A, B, and C, and experienced judges assessed the intensity of specific olfactory aspects on a scale from (0) = not detected to (10) = very strong. The results are summarized in Table 2:

[0200] Table 2 Olfactory aspects [Table 8]

[0201] These results clearly demonstrate that adding a fragrance according to formula (I) enhances the positive notes of the perfume composition while virtually eliminating the negative notes. Using fragrance blends according to formulas (I) and (II) further enhances the positive results.

[0202] <Examples of cosmetic composition formulations> Examples F1-F55 below illustrate various formulations for cosmetic compositions. "Fragrance I or I+II" means a fragrance according to formula (I), or a fragrance obtained by mixing formulas (I) and (II) in a 1:1 weight ratio.

[0203] Table F1 Liquid soap; transparent (concentration: weight %) [Table 9]

[0204] Table F2 Syndet soap; liquid (concentration: weight %) [Table 10]

[0205] Table F3 Body wash lotion (concentration: weight %) [Table 11]

[0206] Table F4 Triclosan-containing body soap lotion (concentration: weight %) [Table 12]

[0207] Table F5 Intimate Wash (Formulation: weight %) [Table 13]

[0208] Table F6 Liquid soap (concentration: weight %) [Table 14]

[0209] Table F7 Shampoo (amount: weight %) [Table 15]

[0210] Table F8 2-in-1 shampoo (composition: weight %) [Table 16]

[0211] Table F9 Dandruff prevention shampoo (amount of ingredients: weight %) [Table 17]

[0212] Table F10 Hair conditioner containing Clinipan. Rinse-off (amount: weight %) [Table 18]

[0213] Table F11 A spray-on hair conditioner containing zinc pyritrion. Leave-on (concentration: %) [Table 19]

[0214] Table F12 UV-protective hair conditioner (weight) [Table 20] Table 13 Shower gel (concentration: weight %) [Table 21]

[0215] Table F14 Shaving foam (composition: weight %) [Table 22]

[0216] Table F15 Hair removal cream (concentration: weight %) [Table 23]

[0217] Table F16 Aftershave tonic (concentration: weight %) [Table 24]

[0218] Table F17 Roll-on gel deodorant formulation (concentration: weight %) [Table 25]

[0219] Table F18 Clear Deo Antiperspirant Roll-On (Formulation: %) [Table 26]

[0220] Table F19 Stick-type deodorant (concentration: weight %) [Table 27]

[0221] Table F20 Zirconium suspendant antiperspirant stick (concentration: weight %) [Table 28]

[0222] Table F21 Deodorant pump spray containing Symclariol (concentration: weight %) [Table 29]

[0223] Table F22 Antiperspirant ingredients (amount: weight %) [Table 30]

[0224] Table F23 Deodorant spray containing triclosan (concentration: weight %) [Table 31]

[0225] Table F24 O / W lotion (composition: weight %) [Table 32]

[0226] Table F25 Body lotion (concentration: weight %) [Table 33]

[0227] Table F26 Cream (concentration: weight %) [Table 34]

[0228] Table F27 Cream (concentration: weight %) [Table 35]

[0229] Table F28 Hand cream and body cream (concentration: weight %) [Table 36]

[0230] Table F29 Face cream (concentration: weight %) [Table 37]

[0231] Table F30 Moisturizing body care cream (concentration: weight %) [Table 38]

[0232] Table F31 Wrinkle prevention cream (concentration: weight %) [Table 39]

[0233] Table F32 Antibacterial functional skin oil (concentration: weight %) [Table 40]

[0234] Table F33 Septic wound cream (concentration: weight %) [Table 41]

[0235] Table F34 Moisturizing and disinfecting face mask (ingredients: weight %) [Table 42]

[0236] Table F35 Spray-type disinfectant gel (concentration: weight %) [Table 43]

[0237] Table F36 Mineral wash and cleansing gel (concentration: weight %) [Table 44]

[0238] Table F37 Anti-acne cleansing agent (amount: weight %) [Table 45]

[0239] Table F38 Cosmetic sunscreen composition (concentration: weight %) [Table 46]

[0240] Table F39 Sunscreen spray (concentration: weight %) [Table 47]

[0241] Table F40 Sunscreen spray O / W. SPE 15-20 (composition: weight %) [Table 48]

[0242] Table F41 Sunscreen soft serve ice cream (W / O). SPF 40 (Concentration: weight %) [Table 49]

[0243] Table F42 Sunscreen Milk (W / O) (Concentration: weight %) [Table 50]

[0244] Table F43 After-sun gel (concentration: weight %) [Table 51]

[0245] Table F44 After-sun lotion (concentration: weight %) [Table 52]

[0246] Table F45 Hair styling gel (concentration: weight %) [Table 53]

[0247] Table F46 Silicone emulsion (concentration: weight %) [Table 54]

[0248] Table F47 Microemulsion gel (concentration: weight %) [Table 55]

[0249] Table F48 Gel-type fragrance (concentration: weight %) [Table 56]

[0250] Table F49 Cleaner. Alkaline pH 8-10 (concentration: weight %) [Table 57]

[0251] Table F50 Fabric softener (amount: by weight %) [Table 58]

[0252] Table F51 Liquid detergent (composition: weight %) [Table 59]

[0253] Table F52 Concentrated liquid detergent (composition: weight %) [Table 60]

[0254] Table F53 Toilet cleaner (composition: weight %) [Table 61]

[0255] Table F54 Concentrated dishwashing detergent (amount: weight %) [Table 62]

[0256] Table F55 Concentrated dishwashing detergent (amount: weight %) [Table 63]

[0257] Table F56 Solution for wet wipes (concentration: weight %) [Table 64]

Claims

1. Fragrances containing formula (Ia) and / or formula (Ib). 【Chemistry 1】

2. The fragrance according to claim 1, comprising two isomers of formula (Ia) and formula (Ib) in a weight ratio of about 1:99 to about 99:

1.

3. Fragrance mixtures that include, or consist solely of, the following: (a) at least one of compounds (Ia) and (Ib) 【Chemistry 2】 and (b) at least one of compounds (IIa) and (IIb) 【Transformation 3】 Here, R1 and R2 represent a C1-C4 alkyl group, a methoxy group, or an ethoxy group, respectively.

4. The fragrance mixture according to claim 3, comprising component (a) and component (b) in a weight ratio of about 1:99 to about 99:

1.

5. The fragrance mixture according to claim 3, further comprising at least one compound of formula (III) as component (c). 【Chemistry 4】 Here, R3 represents a methyl group, ethyl group, methoxy group, or ethoxy group, and the dotted line indicates a single bond or a double bond.

6. The mixture according to claim 3, comprising component (a + b) and component (c) in a weight ratio of approximately 75:25 to approximately 99:

1.

7. A perfume composition comprising the fragrance of claim 1 or the fragrance mixture of claim 3.

8. A perfume composition according to claim 7, comprising about 0.001 to about 75% by weight of the fragrance according to claim 1 or the fragrance mixture according to claim 3.

9. A cosmetic or household composition comprising the fragrance of claim 1, the fragrance mixture of claim 3, or the perfume composition of claim 7.

10. A method for improving the olfactory aspects of a fragrance and / or preventing unpleasant olfactory aspects, (i) A process for providing fragrances that require olfactory support, (ii) A step of applying the fragrance of claim 1 or the fragrance mixture of claim 3 to the fragrance, A method that includes or consists only of [something].

11. Use of the fragrance of claim 1, the fragrance mixture of claim 3, or the perfume composition of claim 7 for improving the olfactory aspects of a fragrance and / or preventing unpleasant olfactory aspects.

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