Sulfonamide compound, and harmful-arthropod extermination composition containing same

Abstract

According to the present invention, a compound represented by formula (I) (wherein, Q (# denotes a bonding site with a sulfur atom, and ● denotes a bonding site with Het) represented in the formula denotes a group or the like represented by formula Q1, R2a and R2b may be the same or different and represent a C1-C6 alkyl group or the like that may be substituted with one or more halogen atoms, R3a, R3b, and R3d may be the same or different and represent a hydrogen atom or the like, Het represents a group or the like represented by formula Het1, A2 represents a nitrogen atom or CR4a, A3 represents a nitrogen atom or CR4b, W1 represents an oxygen atom or a sulfur atom, R4a and R4b may be the same or different and represent a C1-C6 chain hydrocarbon group or the like, R6 represents a C1-C6 chain hydrocarbon group or the like, and T represents a C1-C10 chain hydrocarbon group {the C1-C10 chain hydrocarbon group having one or more substituents selected from the group consisting of a cyano group and a halogen atom} or the like) exhibits an excellent extermination effect against harmful arthropods.

Description

Sulfonamide compound and pest control composition containing the same

[0001] This patent application claims priority under the Paris Convention to and the benefit of Japanese Patent Application No. 2022-155034 (filed September 28, 2022), the entire contents of which are incorporated herein by reference. The present invention relates to sulfonamide compounds and arthropod pest control compositions containing the same.

[0002] Various compounds have been investigated so far for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes that certain compounds have pest control effects.

[0003] International Publication No. 2018 / 008727

[0004] An object of the present invention is to provide a compound having excellent control activity against harmful arthropods.

[0005] The present invention is as follows: [1] A compound represented by formula (I) [Wherein, Q represented by the following formula represents a group represented by formula Q1, a group represented by formula Q2, a group represented by formula Q3, a group represented by formula Q4, a group represented by formula Q5, a group represented by formula Q6, or a group represented by formula Q7 (# represents a bonding site to a sulfur atom, and ● represents a bonding site to Het), A 1 is NR 5 , an oxygen atom or a sulfur atom; 1 , G 2 , G 3 and G 4 The combination of 1 is a nitrogen atom or CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c A combination in which: 1 is CR 3a and G 2 is a nitrogen atom, and G 3 is CR3d and G 4 is CR 3c A combination in which: 1 is CR 3a and G 2 is CR 3b and G 3 is a nitrogen atom, and G 4 is CR 3c or a combination 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 represents a combination in which R is a nitrogen atom; 2a and R 2b are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 2a and R 2b may, together with the nitrogen atom to which they are attached, form an aziridinyl group, an azetidinyl group, a pyrrolidinyl group, or a piperidyl group; R 3a , R 3b , R 3c , R 3d , R 3f , R 3g , R 3i and R 3k are the same or different and each represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group E, a phenyl group optionally substituted with one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group H, OR 12 , N.R. 11 R 12 , N.R. 11a R 12a , N.R. 24 NR 11 R 12 , N.R. 24 OR 11 , N.R. 11 C(O)R13 , N.R. 24 NR 11 C(O)R 13 , N.R. 11 C(O)OR 14 , N.R. 24 NR 11 C(O)OR 14 , N.R. 11 C(O)NR 31 R 32 , N.R. 24 NR 11 C(O)NR 31 R 32 , N=CHNR 31 R 32 , N=S(O) p R 15 R 16 , C(O)R 13 , C(O)OR 17 , C(O)NR 31 R 32 , C(O)NR 11 S(O)2R 23 , C.R. 30 = NOR 17 , N.R. 11 CR 24 = NOR 17 , S(O) q R 23 , a cyano group, a nitro group, a hydrogen atom, or a halogen atom; R 3e and R 3h are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a phenyl group optionally substituted with one or more substituents selected from group H, and when Q is a group represented by formula Q1, R 3a , R 3b and R 3dtwo adjacent substituents among the following may, together with the two carbon atoms to which they are bonded, form a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring or a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring and the pyrazine ring are optionally substituted with one or more substituents selected from Group H} or a triazole ring optionally substituted with one or more substituents selected from Group I, p represents 0 or 1, q represents 0, 1 or 2, R 30 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, OR 35 , N.R. 36 R 37 or a hydrogen atom, R 17 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, or a hydrogen atom; R 12 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J, a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from Group J, a phenyl group optionally substituted with one or more substituents selected from Group D, a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a hydrogen atom, or S(O)R 23 represents R 23 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a phenyl group optionally substituted with one or more substituents selected from Group D, R 11a and R 12aR together with the nitrogen atom to which they are bonded represent a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group E; 13 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, or a hydrogen atom; R 14 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group (the phenyl moiety in the phenyl C1-C3 alkyl group optionally substituted with one or more substituents selected from Group D), R 15 and R 16 are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms; R 31 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 32 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group J, or a hydrogen atom, Het represents a group represented by formula Het1, a group represented by formula Het2, a group represented by formula Het3, a group represented by formula Het4, a group represented by formula Het5, a group represented by formula Het6, or a group represented by formula Het7, A 2 is a nitrogen atom or CR 4a represents, 3 is a nitrogen atom or CR 4b represents, 4 is a nitrogen atom or CR 4c represents W 1represents an oxygen atom or a sulfur atom, and when Het is a group represented by the formula Het5 or Het6, A 2 and A 3 The combination is A 2 is CR 4a and A 3 is a nitrogen atom or CR 4b or a combination 2 is a nitrogen atom, and A 3 is CR 4b B represents a combination 1 , B 2 and B 3 The combination is B 1 is CR 6e and B 2 is a nitrogen atom or CR 6b and B 3 is a nitrogen atom or CR 6c A combination in which: 1 is a nitrogen atom or CR 6a and B 2 is CR 6e and B 3 is a nitrogen atom or CR 6c or B 1 is a nitrogen atom or CR 6a and B 2 is a nitrogen atom or CR 6b and B 3 is CR 6e When Het is a group represented by the formula Het7, 2 and A 3 The combination is A 2 is CR 4a and A 3 is a nitrogen atom or CR 4b or a combination 2 is a nitrogen atom, and A 3 is a nitrogen atom or CR 4b B represents a combination 1 , B 2 , B 3 and B 4 The combination is B 1 is a nitrogen atom or CR 6a and B2 is CR 6e and B 3 is a nitrogen atom or CR 6c and B 4 is a nitrogen atom or CR 6d A combination in which: 1 is a nitrogen atom or CR 6a and B 2 is a nitrogen atom or CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom or CR 6d A combination in which: 1 is a nitrogen atom or CR 6a and B 2 is a nitrogen atom or CR 6b and B 3 is CR 6c and B 4 is CR 6e A combination in which: 1 is a nitrogen atom or CR 6a and B 2 is CR 6b and B 3 is a nitrogen atom, and B 4 is CR 6e or B 1 is CR 6a and B 2 is a nitrogen atom, and B 3 is a nitrogen atom, and B 4 is CR 6e R represents a combination in which 4a , R 4b , R 4c , R 6a , R 6b , R 6c , R 6d are the same or different and are each a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a nitro group, OR 18 , N.R. 18 R 19 , a cyano group, an amino group, a halogen atom, or a hydrogen atom; R 6erepresents a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 , a halogen atom, or OS(O)R 7 represents R 6 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group F, a C3-C6 cycloalkyl group optionally substituted with one or more substituents selected from Group J, a phenyl group optionally substituted with one or more substituents selected from Group H, or a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group H, T represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy)C2-C5 alkyl group, a (C3-C5 alkenyloxy)C2-C5 alkyl group, a (C3-C5 alkynyloxy)C2-C5 alkyl group, a (C1-C5 alkyl)-S(O) w -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) w -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) w -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) w-(C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group is substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom}, a (C3-C7 cycloalkyl)C1-C3 alkyl group substituted with one or more substituents selected from Group G, a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G, OR 1 , S(O) v R 1 , OS(O)2R 1 , CH2OR 1 , N.R. 1 R 29 , C(O)R 1 , C(O)NR 1 R 29 , N.R. 29 C(O)R 1 , N=CR 1 R 30 , a group represented by formula T-1, a group represented by formula T-2, a group represented by formula T-3, a group represented by formula T-4, a group represented by formula T-5, a group represented by formula T-6, a group represented by formula T-7, a group represented by formula T-8, a group represented by formula T-9, a group represented by formula T-10, a group represented by formula T-11, or a group represented by formula T-12, X 1 is a nitrogen atom or CR 1a represents X 2 is a nitrogen atom or CR 1b represents X 3 is a nitrogen atom or CR 1c represents X 4 is a nitrogen atom or CR 1d represents X 5 is a nitrogen atom or CR 1e represents R 1x represents a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms, OR 7 , OS(O)2R 7 , S(O) m R 7 , N.R. 8 S(O)2R 7 or a halogen atom, R 1a , R 1b, R 1c , R 1d and R 1e are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom; Y 1 is NR 25 , an oxygen atom or a sulfur atom; Y 2 is a nitrogen atom or CR 26 represents Y 3 is a nitrogen atom or CR 27 represents Y 4 is a nitrogen atom or CR 28 represents R 5 and R 25 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 26 , R 27 and R 28 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom; R 1y represents a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms, OR 7 , OS(O)2R 7 , S(O) m R 7 , N.R. 8 S(O)2R 7 , a cyano group, or a halogen atom; R 1ay and R 7 are the same or different and represent a C1-C6 chain hydrocarbon group substituted with one or more halogen atoms; m and v are the same or different and represent 0, 1 or 2; w and t are the same or different and represent 0, 1 or 2; R 1represents a C1-C10 chain hydrocarbon group, a (C1-C5 alkoxy) C2-C5 alkyl group, a (C3-C5 alkenyloxy) C2-C5 alkyl group, a (C3-C5 alkynyloxy) C2-C5 alkyl group, a (C1-C5 alkyl)-S(O) t -(C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) t -(C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) t -(C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group is substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom), a (C3-C7 cycloalkyl)C1-C3 alkyl group substituted with one or more substituents selected from Group G, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G; R 18 and R 35 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms; R 8 , R 11 , R 19 , R 24 , R 29 , R 36 and R 37are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom. Group B: a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group C: a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, and halogen atoms. Group D: a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, hydroxy groups, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, sulfanyl groups, C1-C6 alkylsulfanyl groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups optionally substituted with one or more halogen atoms, amino groups, NHR 21 , N.R. 21 R 22 , C(O)R 21 , O.C.(O.)R 21 , C(O)OR 21 , a cyano group, a nitro group, and a halogen atom. 21 and R 22are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms. Group E: a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group. Group F: a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group C, an amino group, NHR 21 , N.R. 21 R 22 , a halogen atom, and a cyano group. Group G: a halogen atom, a C1-C6 haloalkyl group, and a cyano group. Group H: a C1-C6 alkyl group optionally substituted with one or more halogen atoms, OR 10 , N.R. 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 , O.C.(O.)R 9 , OC(O)OR 9 , N.R. 10 C(O)R 9 , N.R. 10 C(O)OR 9 , C(O)OR 10 , a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group. 9 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, R 10represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. Group I: a group consisting of a C2-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C2-C6 alkylcarbonyl group optionally substituted with one or more halogen atoms, a C2-C6 alkoxycarbonyl group optionally substituted with one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms. Group J: a group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. [2] A compound represented by formula (I) or an N-oxide thereof according to [1], wherein Q is a group represented by formula Q1 or a group represented by formula Q5, or an N-oxide thereof. [3] A compound represented by formula (I) or an N-oxide thereof according to [1], wherein Q is a group represented by formula Q5, or an N-oxide thereof. [4] G 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c [5] The compound according to [3], wherein Het is a group represented by the formula Het1, and A is an N-oxide thereof. 2 is CR 4a and A 3 is CR 4b or a nitrogen atom. [6] The compound according to any one of [1] to [4], or an N-oxide thereof, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a and A 3 is CR 4band B 1 is CR 6a and B 2 is CR 6e and B 3 [7] The compound according to any one of [1] to [4], wherein A is a nitrogen atom, or an N-oxide thereof. 2 is CR 4a and A 3 is a nitrogen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d

[0013] The compound or N-oxide thereof according to any one of [1] to [4], wherein the compound or N-oxide thereof is:

[0014]

[0015]

[0016]

[0017]

[0018]

[0019]

[0020]

[0021]

[0022]

[0023]

[0024]

[0025]

[0026]

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[0029]

[0030]

[0031]

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[0034]

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[0036]

[0037]

[0038]

[0039]

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[0042]

[0050]

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[0055]

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[0060]

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[0070]

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[0073]

[0074]

[0080]

[0081]

[0082]

[0083]

[0084]

[0090]

[0091]

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[0093]

[0094]

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[0096]

[0097]

[0097]

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[0099]

[0100]

[0099]

[0110]

[0099]

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[0111]

[0099]

[0099]

[0099]

[0121]

[0099]

[0099]

[0132]

[0099] [

[11] A seed or a vegetative reproductive organ carrying an effective amount of the compound according to any one of [1] to [7] or an N-oxide thereof, or an effective amount of the composition according to [9].

[0006] According to the present invention, arthropod pests can be controlled.

[0007] Substituents in the present invention will be explained. A halogen atom refers to a fluorine atom, chlorine atom, bromine atom, or iodine atom. When a substituent is substituted with two or more halogen atoms or substituents, these halogen atoms or substituents may be the same or different. In this specification, the notation "CX-CY" means that the number of carbon atoms is X to Y. For example, the notation "C1-C6" means that the number of carbon atoms is 1 to 6. The chain hydrocarbon group represents an alkyl group, an alkenyl group, or an alkynyl group. Examples of alkyl groups include a methyl group, an ethyl group, a propyl group, an isopropyl group, a 1,1-dimethylpropyl group, a 1,2-dimethylpropyl group, a 1-ethylpropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group. A haloalkyl group refers to an alkyl group substituted with one or more halogen atoms. Examples of alkenyl groups include vinyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl. Examples of alkynyl groups include ethynyl, 1-propynyl, 2-propynyl, 1-methyl-2-propynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-butynyl, 4-pentynyl, and 5-hexynyl. Examples of alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentyloxy, and hexyloxy. Examples of alkenyloxy groups include 2-propenyloxy groups, 2-butenyloxy groups, and 5-hexenyloxy groups. Examples of alkynyloxy groups include 2-propynyloxy groups, 2-butynyloxy groups, and 5-hexynyloxy groups.

[0008] Examples of cycloalkyl groups include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and cycloheptyl groups. Examples of cycloalkenyl groups include cyclopropenyl, cyclobutenyl, cyclopentenyl, cyclohexenyl, and cycloheptenyl groups.

[0009] Examples of the 3- to 7-membered non-aromatic heterocyclic group include an aziridinyl group, an oxiranyl group, a thiiranyl group, an azetidinyl group, an oxetanyl group, a thietanyl group, a pyrrolidinyl group, a tetrahydrofuranyl group, a tetrahydrothienyl group, a piperidyl group, a pyranyl group, a dihydropyranyl group, a tetrahydropyranyl group, a tetrahydrothiopyranyl group, an azepanyl group, an oxepanyl group, a thiepanyl group, a pyrazolinyl group, a pyrazolidinyl group, an imidazolinyl group, an imidazolidinyl group, an oxazolinyl group, a thiazolinyl group, an oxazolidinyl group, a thiazolidinyl group, an isoxazolinyl group, an isoxazolidinyl group, an isothiazolinyl group, an isothiazolidinyl group, a dioxolyl group, a dioxolanyl group, a dioxanyl group, a morpholinyl group, a thiomorpholinyl group, and a piperazinyl group. Examples of 5- or 6-membered aromatic heterocyclic groups include pyrrolyl, furyl, thienyl, pyrazolyl, imidazolyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, triazinyl, and tetrazinyl groups. Examples of 6-membered aromatic heterocyclic groups include pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, triazinyl, and tetrazinyl groups. Examples of (C3-C6 cycloalkyl)C1-C3 alkyl groups optionally substituted with one or more halogen atoms include cyclopropylmethyl, (2-fluorocyclopropyl)methyl, cyclopropyl(fluoro)methyl, and (2-fluorocyclopropyl)(fluoro)methyl groups. (C1-C5 alkoxy)C2-C5 alkyl groups include, for example, 2-methoxyethyl groups, 3-methoxypropyl groups, and 3-ethoxypropyl groups.The (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms refers to a group in which a (C3-C7 cycloalkyl) and / or a (C1-C6 alkyl) is optionally substituted with one or more halogen atoms, and examples thereof include a (2,2-difluorocyclopropyl)methyl group, a 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, a 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl group, a (2,2-difluorocyclopropyl)propyl group, a (2,2-difluorocyclopropyl)butyl group, a (2,2-difluorocyclopropyl)pentyl group, and a (2,2-difluorocyclopropyl)hexyl group. The (C3-C7 cycloalkyl)C1-C3 alkyl group substituted by one or more substituents selected from Group G refers to a group in which a (C3-C7 cycloalkyl) and / or a (C1-C3 alkyl) is substituted by one or more substituents selected from Group G, and examples thereof include a (2,2-difluorocyclopropyl)methyl group, a [1-(trifluoromethyl)cyclopropyl]methyl group, a [2-(trifluoromethyl)cyclopropyl]methyl group, a 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, a 2-cyclopropyl-3,3,3-trifluoropropyl group, and a 1,1,2,2-tetrafluoro-2-[2-(trifluoromethyl)cyclopropyl]ethyl group. Examples of the phenyl C1-C3 alkyl group (the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group M) include a benzyl group, a 2-fluorobenzyl group, a 4-chlorobenzyl group, a 4-(trifluoromethyl)benzyl group, and a 2-[4-(trifluoromethyl)phenyl]ethyl group. Examples of the alkylsulfanyl group include a methylsulfanyl group, an ethylsulfanyl group, a propylsulfanyl group, and an isopropylsulfanyl group. Examples of the alkylsulfinyl group include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group.Examples of alkylsulfonyl groups include methylsulfonyl, ethylsulfonyl, propylsulfonyl, and isopropylsulfonyl groups. Examples of alkylcarbonyl groups include acetyl, propanoyl, 2-methylpropanoyl, and hexanoyl groups. Examples of alkoxycarbonyl groups include methoxycarbonyl, ethoxycarbonyl, isopropoxycarbonyl, and pentyloxycarbonyl groups.

[0010] Examples of the N-oxide of the compound of formula (I) include the compounds of the following formula: (wherein the symbols have the same meanings as defined above.)

[0011] The compound of the present invention may exist in one or more stereoisomers. Examples of stereoisomers include enantiomers, diastereomers, and geometric isomers. The compound of the present invention includes each stereoisomer and a mixture of stereoisomers in any ratio.

[0012] The compound of the present invention may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid. The acid addition salt can be obtained by mixing the compound of the present invention with an acid.

[0013] The following compounds are examples of the compound N of the present invention.

[0014] [Aspect 1] A compound of the present invention, wherein Q is a group represented by formula Q1 or a group represented by formula Q5 in compound N of the present invention. [Aspect 2] In aspect 1, G 1 is a nitrogen atom or CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c and R 3a , R 3b , R 3c , and R 3dare the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group E, a phenyl group optionally substituted with one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group H, OR 12 , C.R. 30 = NOR 17 , a hydrogen atom or a halogen atom, R 17 and R 30 are the same or different and are C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, R 12 is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J, or a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D. [Aspect 3] A compound in aspect 2, wherein R 3a and R 3c is a hydrogen atom, and R 3b and R 3d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more halogen atoms, OR 12 , a hydrogen atom or a halogen atom, R 12 is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms. 3b and R 3d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydrogen atom, or a halogen atom. [Aspect 5] A compound of the present invention, compound N, in which Q is a group represented by formula Q1. [Aspect 6] A compound of aspect 5, in which R 3a , R 3b , and R 3dare the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group E, a phenyl group optionally substituted with one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group H, OR 12 , C.R. 30 = NOR 17 , a hydrogen atom or a halogen atom, R 17 and R 30 are the same or different and are C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, R 12 is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J, or a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D. [Aspect 7] A compound in aspect 6, wherein R 3a is a hydrogen atom, and R 3b and R 3d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more halogen atoms, OR 12 , a hydrogen atom or a halogen atom, R 12 is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms. 3b and R 3d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydrogen atom, or a halogen atom. [Aspect 9] A compound of the present invention N, in which Q is a group represented by formula Q5. [Aspect 10] A compound of Aspect 9, in which G 1 is a nitrogen atom or CR 3a and G 2 is CR 3b and G 3 is CR3d and G 4 is CR 3c and R 3a , R 3b , R 3c , and R 3d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group E, a phenyl group optionally substituted with one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group H, OR 12 , C.R. 30 = NOR 17 , a hydrogen atom or a halogen atom, R 17 and R 30 are the same or different and are C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, R 12 is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J, or a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D. [Aspect 11] A compound in Aspect 10, wherein R 3a and R 3c is a hydrogen atom, and R 3b and R 3d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more halogen atoms, OR 12 , a hydrogen atom or a halogen atom, R 12 is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms. 3b and R 3dare the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydrogen atom, or a halogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2bare the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom.2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2b are the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. 2a and R 2bare the same or different and are a methyl group, an ethyl group, a cyclopropyl group, or a hydrogen atom. [Aspect 39] A compound in any of Aspects 1 to 14 or Compound N of the present invention, wherein Het is a group represented by formula Het1, a group represented by formula Het3, a group represented by formula Het5, or a group represented by formula Het7. [Aspect 40] A compound in any of Aspects 1 to 14 or Compound N of the present invention, wherein Het is a group represented by formula Het1 or a group represented by formula Het3. [Aspect 41] A compound in any of Aspects 1 to 14 or Compound N of the present invention, wherein Het is a group represented by formula Het5 or a group represented by formula Het7. [Aspect 42] A compound in any of Aspects 1 to 14 or Compound N of the present invention, wherein Het is a group represented by formula Het1. [Aspect 43] A compound in any of Aspects 1 to 14 or Compound N of the present invention, wherein Het is a group represented by formula Het3. [Aspect 44] A compound in any one of Aspects 1 to 14 or Compound N of the present invention, wherein Het is a group represented by the formula Het5. [Aspect 45] A compound in any one of Aspects 1 to 14 or Compound N of the present invention, wherein Het is a group represented by the formula Het7. [Aspect 46] A compound in Aspect 39, wherein A 2 is CR 4a and A 3 is a nitrogen atom or CR 4b and A 4 is CR 4c and B 1 is CR 6a and B 2 is CR 6e and B 3 is a nitrogen atom or CR 6c and B 4 is CR 6d and R 4a , R 4b , R 4c , R 6a , R 6c , R 6d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7or a halogen atom, R 6 is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, and T is OR 1 and R 1 is a C1-C10 chain hydrocarbon group having one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a C3-C7 cycloalkyl group having one or more substituents selected from Group G. [Aspect 47] A compound according to aspect 39, wherein A 2 is CR 4a and A 3 is a nitrogen atom or CR 4b and A 4 is CR 4c and B 1 is CR 6a and B 2 is CR 6b and B 3 is a nitrogen atom or CR 6e and B 4 is CR 6d and R 4a , R 4b , R 4c , R 6a , R 6b , and R 6d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or a halogen atom, R 6 is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, and T is OR 1 and R 1 is a C1-C10 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G. [Aspect 48] A compound according to aspect 42, wherein A 2 is CR 4a and A 3 is a nitrogen atom or CR 4b and R4a and R 4b are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, and R 6 is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, and T is OR 1 and R 1 is a C1-C10 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G. [Aspect 49] A compound according to aspect 43, wherein A 2 is CR 4a and A 3 is a nitrogen atom or CR 4b and A 4 is CR 4c and R 4a , R 4b , and R 4c are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, and T is OR 1 and R 1 is a C1-C10 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G. [Aspect 50] A compound according to aspect 44, wherein A 2 is CR 4a and A 3 is CR 4b and B 1 is CR 6a and B 2 is CR 6e and B 3 is a nitrogen atom or CR 6c and R 4a , R 4b , R 6a , and R 6c are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, and R 6eis a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or a halogen atom. [Aspect 51] In aspect 45, A 2 is CR 4a and A 3 is CR 4b and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 4a , R 4b , R 6a , R 6c , and R 6d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or a halogen atom. 2 is CR 4a and A 3 is CR 4b and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 4a , R 4b , R 6a , R 6c , and R 6d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7or a halogen atom. 2 is CR 4a and A 3 is CR 4b and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4b , R 6a , R 6b , and R 6d are the same or different and are a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, OR 7 or a halogen atom. 4a and R 4b is a hydrogen atom, and R 6 is a methyl group. 4a , R 4b , and R 4c is a hydrogen atom. [Aspect 56] In aspect 50, B 3 is a nitrogen atom, and R 4a , R 4b , and R 6a is a hydrogen atom. [Aspect 57] In aspect 51, R 4a , R 4b , R 6a , R 6c , and R 6d is a hydrogen atom. [Aspect 58] In aspect 52, R 4a , R 4b , R 6a , R 6c , and R 6d is a hydrogen atom. 4a , R 4b , R 6a , R6b , and R 6d is a hydrogen atom. [Embodiment 60] In any one of embodiments 1 to 38 or compound N of the present invention, W 1 is an oxygen atom. [Aspect 61] In aspect 39, W 1 is an oxygen atom. [Aspect 62] In aspect 40, W 1 is an oxygen atom. [Aspect 63] In aspect 41, W 1 is an oxygen atom. [Aspect 64] In aspect 42, W 1 is an oxygen atom. [Aspect 65] In aspect 43, W 1 is an oxygen atom. [Aspect 66] In aspect 44, W 1 is an oxygen atom. [Aspect 67] In aspect 45, W 1 is an oxygen atom. [Aspect 68] In aspect 46, W 1 is an oxygen atom. [Aspect 69] In aspect 47, W 1 is an oxygen atom. [Aspect 70] In aspect 48, W 1 is an oxygen atom. [Embodiment 71] In embodiment 49, W 1 is an oxygen atom. [Aspect 72] In aspect 50, W 1 is an oxygen atom. [Aspect 73] In aspect 51, W 1 is an oxygen atom. [Embodiment 74] In embodiment 52, W 1 is an oxygen atom. [Aspect 75] In aspect 53, W 1 is an oxygen atom. [Aspect 76] In aspect 54, W 1 is an oxygen atom. [Embodiment 77] In embodiment 55, W 1 is an oxygen atom. [Aspect 78] In aspect 56, W 1 is an oxygen atom. [Embodiment 79] In embodiment 57, W 1 is an oxygen atom. [Aspect 80] In aspect 58, W 1 is an oxygen atom. [Aspect 81] In aspect 59, W 1 A compound in which the oxygen atom is

[0015] Next, the method for producing the compound of the present invention will be described.

[0016] Production Method 1 The compound represented by formula (I) (compound N of the present invention) can be produced by reacting a compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) with a compound represented by formula (M-2) (hereinafter referred to as compound (M-2)). [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent. Examples of the solvent include ethers (hereinafter referred to as ethers) such as tetrahydrofuran (hereinafter referred to as THF), 1,4-dioxane, 1,2-dimethoxyethane (hereinafter referred to as DME), methyl tert-butyl ether (hereinafter referred to as MTBE), and diethyl ether; halogenated hydrocarbons (hereinafter referred to as halogenated hydrocarbons) such as dichloromethane and chloroform; aromatic hydrocarbons (hereinafter referred to as aromatic hydrocarbons) such as toluene and xylene; nitriles (hereinafter referred to as nitriles) such as acetonitrile; water, and mixtures of two or more thereof. In the reaction, compound (M-2) is usually used in a ratio of 0.8 to 10 moles per mole of compound (M-1). The reaction can be carried out by mixing compound (M-1) and compound (M-2). The reaction may be carried out in the presence of a base, if necessary. Examples of the base include alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); tertiary amines such as triethylamine (hereinafter referred to as tertiary amines); and nitrogen-containing aromatic compounds such as pyridine (hereinafter referred to as nitrogen-containing aromatic compounds). When a base is used in the reaction, the base is typically used in a ratio of 1 to 3 moles per mole of compound (M-1). The reaction temperature is typically within the range of -20 to 200°C. The reaction time is typically within the range of 0.1 to 24 hours. After completion of the reaction, compound (I) can be obtained by pouring water into the reaction mixture, extracting with an organic solvent, and performing post-treatments such as drying and concentrating the organic layer. Compound (M-2) is a commercially available compound or can be produced using known methods.

[0017] Production Method 2 The compound represented by formula (I-a) (hereinafter referred to as compound (I-a)) can be produced by reacting a compound represented by formula (M-3) (hereinafter referred to as compound (M-3)) with a compound represented by formula (M-4) (hereinafter referred to as compound (M-4)) in the presence of a base. [Wherein, Het A represents Het3, Het5, Het6, or Het7, and other symbols have the same meanings as above.] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents (hereinafter referred to as aprotic polar solvents) such as dimethylformamide (hereinafter referred to as DMF), N-methylpyrrolidone (hereinafter referred to as NMP), and dimethyl sulfoxide (hereinafter referred to as DMSO); water, and mixtures of two or more thereof. Examples of the base include alkali metal carbonates and alkali metal hydrides (hereinafter referred to as alkali metal hydrides) such as sodium hydride. In the reaction, compound (M-4) is usually used in a ratio of 0.8 to 1.2 moles, and a base is usually used in a ratio of 1 to 3 moles per mole of compound (M-3). The reaction temperature is usually within the range of −20 to 200° C. The reaction time is usually within the range of 0.5 to 24 hours. After the reaction is complete, water is added to the reaction mixture, followed by extraction with an organic solvent, and the resulting organic layer is dried, concentrated, or other post-treatment procedures to obtain compound (I-a). Compound (M-3) is known or can be produced, for example, according to the methods described in WO 2018 / 008727, WO 2019 / 131575, or WO 2019 / 131587.

[0018] Production Method 3 Compound (I-a) can be produced by reacting compound (M-3) with a compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) in the presence of a metal catalyst. [In the formula, X arepresents a chlorine atom, a bromine atom, or an iodine atom, and other symbols have the same meanings as above.] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents, and mixtures of two or more thereof. A base may be used in the reaction, if necessary. Examples of the base include organic bases such as tertiary amines and nitrogen-containing aromatic compounds (hereinafter referred to as organic bases); alkali metal carbonates, and alkali metal hydrides. In the reaction, compound (M-5) is usually used in a ratio of 0.8 to 1.2 moles, and the base is usually used in a ratio of 1 to 3 moles, relative to 1 mole of compound (M-3). Examples of the metal catalyst include copper catalysts such as copper(I) iodide, copper(I) bromide, copper(I) chloride, copper(I) oxide, copper(I) trifluoromethanesulfonate benzene complex, tetrakis(acetonitrile)copper(I) hexafluorophosphate, and copper(I) 2-thiophenecarboxylate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), and tris(dibenzylideneacetone)dipalladium(II). When a metal catalyst is used in the reaction, the metal catalyst is typically used in a ratio of 0.01 to 0.5 moles per mole of compound (M-1). A ligand may also be used in the reaction, if necessary. Examples of the ligand include triphenylphosphine, 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (hereinafter referred to as Xantphos), 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine.When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-1). The reaction temperature is usually in the range of -20°C to 150°C. The reaction time is usually in the range of 0.5 to 24 hours. After completion of the reaction, compound (I-a) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer.

[0019] Production Method 4 Compound (I-b) can be produced by reacting a compound represented by formula (M-6) (hereinafter referred to as compound (M-6)) with compound (M-5) in the presence of a metal catalyst. [Wherein, Het Brepresents Het1, Het2, or Het4, M represents 9-borabicyclo[3.3.1]nonan-9-yl group, borono group, 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl group, tributylstannyl group, or ZnCl, and other symbols have the same meanings as above.] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; aprotic polar solvents; water, and mixtures of two or more thereof. Examples of metal catalysts used in the reaction include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), 1,1'-bis(diphenylphosphino)ferrocenepalladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; iron catalysts such as iron(III) chloride and iron(III) acetylacetonate; and copper catalysts such as copper(I) iodide and copper(I) chloride. If necessary, a ligand, a base, and / or an inorganic halide may be added to the reaction. Ligands used in the reaction include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline. Bases used in the reaction include, for example, alkali metal hydrides; alkali metal carbonates, and organic bases. Inorganic halides used in the reaction include alkali metal fluorides such as potassium fluoride and sodium fluoride; and alkali metal chlorides such as lithium chloride and sodium chloride. In the reaction, compound (M-5) is usually used in a proportion of 1 to 10 moles, a metal catalyst is usually used in a proportion of 0.01 to 0.5 moles, a ligand is usually used in a proportion of 0.01 to 1 moles, a base is usually used in a proportion of 0.1 to 5 moles, and an inorganic halide is usually used in a proportion of 0.1 to 5 moles, relative to 1 mole of compound (M-6).The reaction temperature is usually in the range of -20°C to 200°C. The reaction time is usually in the range of 0.1 to 24 hours. After completion of the reaction, compound (I-b) can be obtained by post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer. Compound (M-6) is known or can be produced, for example, according to the method described in WO 2018 / 221720.

[0020] Reference Production Method 1 Compound (M-1) can be produced by reacting a compound represented by formula (M-7) (hereinafter referred to as compound (M-7)) with a chlorinating agent in the presence of chlorosulfonic acid. [In the formula, the symbols have the same meanings as defined above.] The reaction may be carried out in a solvent, if necessary. Examples of solvents used in the reaction include ethers; aromatic hydrocarbons; aromatic hydrocarbons, and mixtures of two or more thereof. Examples of chlorinating agents used in the reaction include phosphorus oxychloride and thionyl chloride. In the reaction, chlorosulfonic acid is usually used in a ratio of 1 to 10 moles, and the chlorinating agent is usually used in a ratio of 1 to 10 moles, per mole of compound (M-7). The reaction temperature is usually in the range of -20°C to 200°C. The reaction time is usually in the range of 0.1 to 24 hours. After completion of the reaction, compound (M-1) can be obtained by post-treatment operations such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer. Compound (M-7) is known or can be produced in accordance with the methods described in, for example, WO 2018 / 008727, WO 2018 / 221720, WO 2019 / 131575, or WO 2019 / 131587.

[0021] Reference Production Method 2 The compound represented by formula (M-9) (hereinafter referred to as compound (M-9)) can be produced by reacting a compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) with a chlorinating agent in the presence of chlorosulfonic acid. [In the formula, the symbols have the same meanings as defined above.] The reaction can be carried out using compound (M-8) instead of compound (M-7) in accordance with the method described in Reference Production Method 1. Compound (M-8) is a commercially available compound or can be produced using known methods.

[0022] Reference Production Method 3 Compound (M-5) can be produced by reacting compound (M-9) with compound (M-2). [wherein the symbols have the same meanings as defined above.] The reaction can be carried out according to the method described in Production Method 1, except that compound (M-9) is used in place of compound (M-1).

[0023] Reference Production Method 4 Compound (M-4) can be produced by reacting compound (M-5) with a fluorinating agent. [In the formula, the symbols have the same meanings as above.] The reaction is usually carried out in a solvent. Examples of the solvent include aromatic hydrocarbons; aprotic polar solvents, and mixtures of two or more thereof. Examples of the fluorinating agent used in the reaction include cesium fluoride and potassium fluoride. In the reaction, the fluorinating agent is usually used in a ratio of 1 to 10 moles per mole of compound (M-7). The reaction temperature is usually in the range of 20°C to 300°C. The reaction time is usually in the range of 0.1 to 24 hours. After completion of the reaction, compound (M-4) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer.

[0024] The compound of the present invention can be mixed or used in combination with one or more components selected from the group consisting of Group (a), Group (b), Group (c), and Group (d) below (hereinafter referred to as the present component). The term "mixed or used in combination" means that the compound of the present invention and the present component are used simultaneously, separately, or with a time interval. When the compound of the present invention and the present component are used simultaneously, the compound of the present invention and the present component may be contained in separate preparations or in a single preparation. One aspect of the present invention is a composition (hereinafter referred to as Composition A) containing one or more components selected from the group consisting of Group (a), Group (b), Group (c), and Group (d) (i.e., the present component) and the compound of the present invention.

[0025] Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABAergic chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride channel allosteric modulators (e.g., macrolide insecticides), juvenile hormone mimics, multisite inhibitors, chordotonal organ TRPV channel modulators, mite growth inhibitors, microbial insect midgut membrane disruptors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, mitochondrial electron transport chain complexes I and II, The group consisting of inhibitors of classes III and IV, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide insecticides), chordotonal organ modulators, microbial insecticides, and other insecticidal, acaricidal, and nematicidal active ingredients, which are described in the IRAC mechanism-based classification.

[0026] Group (b) consists of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiratory inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyridine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multisite contact-active fungicides, microbial fungicides, and other fungicidal active ingredients. These are listed in the FRAC classification based on the mechanism of action.

[0027] Group (c) is a group of plant growth regulators (including mycorrhizal fungi and rhizobia).

[0028] Group (d) is a group of repellent ingredients.

[0029] Examples of combinations of the present ingredient and the compound of the present invention are described below. For example, alanycarb + SX refers to a combination of alanycarb and SX. The abbreviation SX refers to any one of the present compounds selected from the compound group SX1 to SX964. The present ingredients described below are all known ingredients and can be obtained from commercially available preparations or produced by known methods. When the present ingredient is a microorganism, it can also be obtained from a bacterial depository. The number in parentheses indicates the CAS RN (registered trademark).

[0030] Combinations of the present ingredient of the above group (a) with the compound of the present invention: abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetoprole + SX, acrinathrin + SX, acinonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminum phosphide + SX, Amitraz + SX, azadirachtin + SX, azamethiphos + SX, azinphos-ethyl + SX, azinphos-methyl + SX, azocyclotin + SX, Celastrus angulatus bark + SX, bendiocarb + SX, benfluthrin + SX, benfuracarb + SX, bensultap + SX, benzoximate + SX, benzpyrimoxan + SX, beta-cyfluthrin + SX, beta-cypermethrin + SX, bifenazate + SX, bifenthrin + SX, bioallethrin + SX,Bioresmethrin + SX, bistrifluron + SX, borax + SX, boric acid + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butocarboxim + SX, butoxycarboxim + SX, cadusafos + SX, calcium phosphide + SX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, cartap hydrochloride + SX, cartap + SX Chinomethionate + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chloropicrin + SX, chlorpyrifos + SX, chlorpyrifos-methyl + SX, chromafenozide + SX, clofentezine + SX, clothianidin + SX, concanamycin A A) + SX, coumaphos + SX, cryolite + SX, cyanophos + SX, cyantraniliprole + SX,Cyclaniliprole + SX, cyclobutrifluram + SX, cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyetpyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + SX, cyhexatin + SX, cypermethrin + SX, cyphenothrin + SX, cyproflanilide + SX, cyromazine + SX, Dazomet + SX, deltamethrin + SX, demeton-S-methyl + SX, diafenthiuron + SX, diazinon + SX, dichlorvos + SX, dichloromezotiaz + SX, dicofol + SX, dicrotophos + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX, dimethoate + SX, dimethylvinphos + SX, dimpropyridaz + SX, Dinotefuran + SX, disodium octaborate + SX, disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX,Dried leaves of Dryopteris filix (mas) + SX, emamectin benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethifencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, etofenprox + SX. Etoxazole + SX, Artemisia absinthium extract + SX, Azadirachta indica extract + SX, Cassia nigricans extract + SX, Clitoria ternatea extract + SX, Symphytum officinale extract + SX, Chenopodium ambrosioides extract + SX, Tansy extract + SX, Urtica dioica extract + SX, Viscum album extract + SX, Famphur + SX, Fenamiphos + SX Fenazaquin + SX,Fenbutatin oxide + SX, fenitrothion + SX, fenmezoditiaz + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthion + SX, fenvalerate + SX, fipronil + SX, flometoquin + SX, flonicamid + SX, fluacrypyrim + SX, fluazaindolizine + SX, fluazuron + SX, Flubendiamide + SX, fluchlordiniliprole + SX, flucycloxuron + SX, flucythrinate + SX, fluensulfone + SX, flufenprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupentiofenox + SX, flupyradifurone + SX, flupyrimin + SX, flupyroxystrobin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, furamethrin + SX,Furathiocarb + SX, gamma-cyhalothrin + SX, GS-omega / kappa HXTX-Hv1a peptide + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, potassium salt of hop beta acid + SX, hydramethylnon + SX, hydroprene + SX, imicyafos + SX, Imidacloprid + SX, imidaclothiz + SX, imiprothrin + SX, indazapyroxamet + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoprocarb + SX, isopropyl-O-(methoxyaminothiophosphoryl) salicylate + SX, isoxathion + SX, ivermectin + SX, kadethrin + SX, kappa-tefluthrin + SX Kappa-bifenthrin + SX, kinoprene + SX, lambda-cyhalothrin + SX, ledprona + SX, lenoremycin + SX,Lepimectin + SX, lime sulfur + SX, lotilaner + SX, lufenuron + SX, machine oil + SX, malathion + SX, mecarbam + SX, meperfluthrin + SX, metaflumizone + SX, metam + SX, methamidophos + SX, methidathion + SX, methiocarb + SX, methomyl + SX, methoprene + SX, methoxychlor + SX, methoxyfenozide + SX, Methyl bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX, milbemectin + SX, milbemycin oxime + SX, mivorilaner + SX, modoflaner + SX, momfluorothrin + SX, monocrotophos + SX, moxidectin + SX, naled + SX, nicofluprole + SX, nicotine + SX, nicotine sulfate + SX, Nitenpyram + SX, Novaluron + SX, Noviflumuron + SX,Chenopodium anthelminticum seed oil + SX, omethoate + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, phosalone + SX, phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX Pirimicarb + SX, pirimiphos-methyl + SX, prallethrin + SX, profenofos + SX, profluthrin + SX, propargite + SX, propetamphos + SX, propoxur + SX, propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalyl + SX, Pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX,Pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spidoxamat + SX, spinetoram + SX, spinosad + SX, spirobudifen + SX, spirodiclofen + SX, spiromesifen + SX, spiropidione + SX, spirotetramat + SX, sulfiflumin + SX, sulfluramid + SX, sulfotep + SX, sulfoxaflor + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic + SX, tau-fluvalinate + SX, tebufenozide + SX, Tebufenpyrad + SX, Tebupirimfos + SX, Teflubenzuron + SX, Tefluthrin + SX, Temephos + SX, Terbufos + SX,Terpene constituents of the extract of Chenopodium ambrosioides near ambrosioides + SX, tetrachlorantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX, tetramethrin + SX, tetramethylfluthrin + SX, tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, Thiometon + SX, thiosultap disodium + SX, thiosultap monosodium + SX, tigolaner + SX, thioantraniliprole + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, triazamate + SX, triazophos + SX, trichlorfon + SX, trifluenfuronate + SX, triflumezopyrim + SX, Triflumuron + SX, trimethacarb + SX,Tyclopyrazoflor + SX, umifoxolaner + SX, vamidothion + SX, Quassia amara wood extract + SX, 3,5-dimethylphenyl N-methylcarbamate (XMC) + SX, xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methanesulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX,2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, BT crop protein Cry1Ab (BT crop protein Cry1Ab) + SX, BT crop protein Cry1Ac (BT crop protein Cry1Ac) + SX, BT crop protein Cry1Fa (BT crop protein Cry1Fa) + SX, BT crop protein Cry1A.105 (BT crop protein Cry1A.105) + SX, BT crop protein Cry2Ab (BT crop protein Cry2Ab) + SX,BT crop protein Vip3A + SX, BT crop protein mCry3A + SX, BT crop protein Cry3Ab + SX, BT crop protein Cry3Bb + SX, BT crop protein Cry34Ab1 / Cry35Ab1 + SX, Adoxophyes orana granulovirus BV-0001 + SX, Anticarsia gemmatalis MNPV (multiple nucleocapsid nucleopolyhedrovirus) + SX, Autographa californica MNPV + SX, Cydia pomonella GV strain V15 + SX, Cydia pomonella GV strain V22 + SX, Cryptophlebia leucotreta GV + SX, Dendrolimus punctatus cypovirus + SX, Helicoverpa armigera nucleopolyhedrovirus BV-0003 + SX, Helicoverpa zea ... NPV) + SX, Lymantria dispar NPV + SX, Mamestra brassicae NPV + SX,Mamestra configurata nucleopolyhedrosis virus (NPV) + SX, Neodiprion abietis nucleopolyhedrosis virus (NPV) + SX, Neodiprion lecontei nucleopolyhedrosis virus (NPV) + SX, Neodiprion sertifer nucleopolyhedrosis virus (NPV) + SX, Nosema locustae + SX, Orgyia pseudotsugata nucleopolyhedrosis virus (NPV) + SX, Pieris rapae granulosis virus (GV) + SX, Plodia interpunctella granulosis virus (GV) + SX, Spodoptera exigua MNPV + SX, Spodoptera littoralis MNPV + SX, Spodoptera littoralis NPV + SX, Arthrobotrys dactyloides + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus megaterium + SX, Bacillus sp. strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b+ SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus thuringiensis strain AQ52 + SX,Bacillus thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp. Aizawai strain AM65-52 + SX, Bacillus thuringiensis subsp. Aizawai strain GC-91 + SX, Bacillus thuringiensis subsp. Aizawai strain NB200 + SX, Bacillus thuringiensis subsp. Aizawai Serotype strain H-7 + SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306) + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2348 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX,Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp. Tenebriosis strain NB176 + SX, Bacillus thuringiensis subsp. Thuringiensis strain MPPL002 + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis var. colmeri + SX, Bacillus thuringiensis var. darmstadiensis strain 24-91 + SX, Bacillus thuringiensis var. dendrolimus + SX, Bacillus thuringiensis var. galleriae + SX, Bacillus thuringiensis var. israelensis strain BMP144 + SX, Bacillus thuringiensis var. israelensis serotype strain H-14 + SX, Bacillus thuringiensis var. japonensis strain buibui + SX, Bacillus thuringiensis var. san diego strain M-7 + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. aegypti + SX, Bacillus thuringiensis var. T36 + SX, Beauveria bassiana strain ANT-03 + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain GHA + SX, Beauveria brongniartii + SX, Burkholderia rinogensis strain A396 + SX,Chromobacterium subtsugae strain PRAA4-1T + SX, Dactyllela ellipsospora + SX, Dectylaria thaumasia + SX, Hirsutella minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Lagenidium giganteum + SX, Lecanicillium lecanii strain KV01 + SX, Lecanicillium lecanii conidia of strain DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX, Lecanicillium muscarium strain Ve6 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae var. acridum + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium flavoviride + SX, Monacrosporium phymatopagum + SX, Paecilomyces fumosoroseus Apopka strain 97 + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 + SX, Paenibacillus popilliae + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria usgae + SX, Pasteuria thornei + SX, Serratia entomophila + SX, Verticillium chlamydosporium + SX, Verticillium lecani strain NCIM1312 + SX,Wolbachia pipientis + SX。,

[0031] Combinations of the present ingredient of the above group (b) with the compound of the present invention: acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, Benthiavalicarb-isopropyl + SX, benzovindiflupyr + SX, binapacryl + SX, biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin S + SX, Bordeaux mixture + SX, boscalid + SX, bromothalonil + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, carpropamid + SX, chinomethionate + SX, chitin + SX, chloroinconazide + SX, chloroneb + ​​SX,Chlorothalonil + SX, chlozolinate + SX, colletochlorin B + SX, copper(II) acetate + SX, copper(II) hydroxide + SX, copper oxychloride + SX, copper(II) sulfate + SX, coumoxystrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX, cyprodinil + SX, dichlobentiazox + SX, Dichlofluanid + SX, diclocymet + SX, diclomezine + SX, dicloran + SX, diethofencarb + SX, difenoconazole + SX, diflumetorim + SX, dimethachlone + SX, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, diniconazole-M + SX, dinocap + SX, dipotassium hydrogenphosphite + SX, dipymetitrone + SX, dithianon + SX,Dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt + SX, dodemorph + SX, dodine + SX, edifenphos + SX, enoxastrobin + SX, epoxiconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, garlic extract (Allium sativum) + SX, extract of the cotyledons of lupine plantlets (BLAD) + SX, horsetail extract (Equisetum arvense) + SX SX, tea tree extract (Melaleuca alternifolia) + SX, giant knotweed extract (Reynoutria sachalinensis) + SX, nasturtium extract (Tropaeolus majus) + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin + SX, fenarimol + SX, fenbuconazole + SX, fenfuram + SX, fenhexamid + SX, fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX Fenpropidin + SX, Fenpropimorph + SX,Fenpyrazamine + SX, triphenyltin acetate + SX, triphenyltin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX, florylpicoxamid + SX, fluazinam + SX, flubeneteram + SX, fludioxonil + SX, flufenoxadiazam + SX, flufenoxystrobin + SX, fluindapyr + SX, flumetylsulforim + SX, flumorph + SX, fluopicolide + SX, fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxapiprolin + SX, fluoxastrobin + SX, fluoxytioconazole + SX, fluquinconazole + SX, flusilazole + SX, flusulfamide + SX, flutianil + SX, flutolanil + SX, flutriafol + SX, fluxapyroxad + SX, folpet + SX, Fosetyl + SX, fosetyl-aluminium + SX, fuberidazole + SX, furalaxyl + SX, furametpyr + SX,Guazatine + SX, hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX, iminoctadine triacetate + SX, inpyrfluxam + SX, iodocarb + SX, ipconazole + SX, ipfentrifluconazole + SX, ipflufenoquin + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX Isofetamide + SX, isoflucipram + SX, isoprothiolane + SX, isopyrazam + SX, isotianil + SX, kasugamycin + SX, kresoxim-methyl + SX, laminarin + SX, oak leaves and bark of quercus + SX, mancozeb + SX, mandestrobin + SX, mandipropamid + SX, maneb + ​​SX, mefentrifluconazole + SX, mepanipyrim + SX, Mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M + SX, metarylpicoxamid + SX,Metconazole + SX, methasulfocarb + SX, metiram + SX, metominostrobin + SX, metrafenone + SX, metyltetraprole + SX, myclobutanil + SX, naftifine + SX, nuarimol + SX, octhilinone + SX, ofurace + SX, orysastrobin + SX, oxadixyl + SX, oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, Oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphorous acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin + SX, piperalin + SX, polyoxins + SX, Potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX,Probenazole + SX, prochloraz + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole + SX, propineb + ​​SX, proquinazid + SX, prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, pyraclostrobin + SX, pyrametostrobin + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, Pyrazophos + SX, pyribencarb + SX, pyributicarb + SX, pyridaclomethyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyrisoxazole + SX, pyroquilon + SX, Quillaja extract + SX, quinconazole + SX, quinofumelin + SX, quinoxyfen + SX, quintozene + SX, quinoa saponins Chenopodium quinoa + SX, seboctylamine + SX, sedaxane + SX, silthiofam + SX,Simeconazole + SX, sodium hydrogencarbonate + SX, spiroxamine + SX, streptomycin + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tecnazene + SX, terbinafine + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, Thymol + SX, tiadinil + SX, tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triadimefon + SX, triadimenol + SX, triazoxide + SX, triclopyricarb + SX, tricyclazole + SX, tridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole + SX, Validamycin + SX, valifenalate + SX, vinclozolin + SX,マスタードパウダー(yellow mustard powder) + SX, zinc thiazole + SX, ジネブ(zineb) + SX, ジラム(ziram) + SX, ゾキサミド(zoxamide) + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055589-28-9) + SX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylmethanimidamide (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylmethanimidamide (2101814-55-3) + SX, N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylmethanimidamide (1817828-69-5) + SX,4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX, (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-07-3) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R, 2S, 5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S, 2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-carboxylate (1791398-02-1) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX,methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-(1-benzyl-3,3,3-trifluoro-1-methylpropyl)-8-fluoroquinoline-3-carboxamide (2132414-00-5) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N'-ethyl-N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SX,3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromoindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX, N-methoxy-N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX,1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, ethyl 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylate + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine + SX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + SX, methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, ethyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, methyl 2-[2-(trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide + SX, 1-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX,5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX,(5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-(5-cyclohexyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX,(Z)-2-[(3-异丙基-1H-吡唑-1-基)-2-甲基苯氧基]-3-甲氧基丙酸甲酯 + SX、1-(4,5-二甲基-1H-苯并咪唑-1-基)-4,4-二氟-3,3-二甲基-3,4-二氢异喹啉 + SX、1-(4,5-二甲基-1H-苯并咪唑-1-基)-4,4,5-三氟-3,3-二甲基-3,4-二氢异喹啉 + SX、1-(吡唑并[1,5-a]吡啶-3-基)-4,4-二氟-3,3-二甲基-3,4-二氢异喹啉 + SX、1-(6,7-二甲基吡唑并[1,5-a]吡啶-3-基)-6-氟-3,3-二甲基异喹啉-4(3H)-酮 + SX、(2Z)-3-甲氧基-2-[(4-甲基[1,1'-联苯]-3-基)氧基]丙酸甲酯 + SX、放射形土壤杆菌菌株K1026 + SX、放射形土壤杆菌菌株K84 + SX、解淀粉芽孢杆菌菌株PTA-4838(Aveo(商标) EZ杀线虫剂) + SX、解淀粉芽孢杆菌菌株AT332 + SX、解淀粉芽孢杆菌菌株B3 + SX、解淀粉芽孢杆菌菌株D747 + SX、解淀粉芽孢杆菌菌株DB101 + SX、解淀粉芽孢杆菌菌株DB102 + SX、解淀粉芽孢杆菌菌株GB03 + SXBacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain MBI600 + SX, Bacillus amyloliquefaciens strain QST713 + SX, Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens subsp. plantarum strain D747 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus simplex strain CGF2856 + SX, Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain IAB / BS03 + SX,Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 + SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24 + SX, Bacillus subtilis strain Y1336 + SX, Burkholderia cepacia + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX, Candida oleophila strain O + SX, Candida saitoana + SX, Chaetomium cupreum + SX, Clonostachys rosea + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-8 + SX, cryptococcus albidus + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Fusarium oxysporum strain Fo47 + SX, Gliocladium catenulatum strain J1446 + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Pantoea agglomerans strain E325 + SX, Phlebiopsis gigantea strain VRA1992 + SX,Pseudomonas aureofaciens strain TX-1 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SX, Pseudomonas fluorescens strain 1629RS + SX, Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain G7090 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain MA-4 + SX, Pseudozyma flocculosa strain PF-A22UL + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum SKT-1 + SX, Trichoderma asperellum strain T25 + SX, Trichoderma asperellum strain T34 + SX,Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain SC1 + SX, Trichoderma atroviride strain SKT-1 + SX, Trichoderma atroviride strain T11 + SX, Trichoderma gamsii strain ICC080 + SX, Trichoderma harzianum strain 21 + SX, Trichoderma harzianum strain DB104 + SX, Trichoderma harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX, Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX, Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain kd + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain SF + SX, Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma polysporum strain IMI206039 + SX, trichoderma stromaticum + SX,Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 + SX, Trichoderma viride + SX, Variovorax paradoxus strain CGF4526 + SX, Harpin protein + SX。,

[0032] Combinations of the present ingredient in group (c) above with the compound of the present invention: 1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 2,3,5-triiodobenzoic acid + SX, (1H-indol-3-yl)acetic acid (IAA) + SX, 4-(1H-indol-3-yl)butyric acid (IBA) + SX, 2-(4-chloro-2-methylphenoxy)acetic acid (MCPA) + SX, 4-(4-chloro-2-methylphenoxy)butyric acid (MCPB) + SX, 4-chlorophenoxyacetic acid (4-CPA) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat chloride + SX, chlorpropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, Cyclanilide + SX,Daminozide + SX, decan-1-ol + SX, dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat + SX, ethephon + SX, ethychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX, gibberellin A + SX, gibberellin A3 + SX, inabenfide + SX, Kinetin + SX, lipochitooligosaccharide SP104 + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat chloride + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, sintophen + SX, sodium 1-naphthaleneacetate + SX, sodium cyanate + SX, Thidiazuron + SX, triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX,Uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, Methyl 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, Claroideoglomus etunicatum + SX, Claroideoglomus claroideum + SX, Funneliformis mosseae + SX, Gigaspora margarita + SX, Gigaspora rosea + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus monosporum + SX, Paraglomus brasillianum + SX, Rhizophagus clarus + SX, Rhizophagus intraradices RTI-801 + SX, Rhizophagus irregularis DAOM 197198 + SX, Azorhizobium caulinodans + SX, Azospirillum amazonense + SX, Azospirillum brasilense XOH + SX, Azospirillum brasilense Ab-V5 + SX, Azospirillum brasilense Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Bradyrhizobium elkanii SEMIA 587 + SX, Bradyrhizobium elkanii SEMIA 5019 + SX, Bradyrhizobium japonicum TA-11 + SX,Bradyrhizobium japonicum USDA 110 + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Delftia acidovorans RAY209 + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium leguminosarum bv. Phaseoli + SX, Rhizobium leguminosarum bv. Trifolii + SX, Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, Zucchini Yellow Mosaik Virus weak strain + SX. ,

[0033] Combinations of the present component of the above group (d) with the compound of the present invention: anthraquinone + SX, deet + SX, icaridin + SX.

[0034] The ratio of the compound of the present invention to the present component is not particularly limited, and examples thereof include a weight ratio (compound of the present invention:present component) of 1000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:50, and the like.

[0035] The compound of the present invention is effective against harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful mollusks. Examples of harmful arthropods, harmful nematodes, and harmful mollusks include the following.

[0036] Hemiptera: Small brown planthopper (Laodelphax striatellus), Brown planthopper (Nilaparvata lugens), White-backed planthopper (Sogatella furcifera), Corn planthopper (Peregrinus maidis), Yellow leafhopper (Javesella pellucida), Black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, Stenocranus pacificus and other Delphacidae; Green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), Black-striped green rice leafhopper (Nephotettix nigropictus), Lightning leafhopper (Recilia dorsalis), Tea green leafhopper (Empoasca Cicadellidae, such as the potato leafhopper (Empoasca fabae), the corn leafhopper (Dalbulus maidis), the white giant leafhopper (Cofana spectra), and Amrasca biguttula biguttula; Aphrophoridae, such as the European spittlebug (Philaenus spumarius); Cercopidae, such as Mahanarva posticata and Mahanarva fimbriolata;Black bean aphid (Aphis fabae), soybean aphid (Aphis glycines), cotton aphid (Aphis gossypii), European apple aphid (Aphis pomi), willow aphid (Aphis spiraecola), green peach aphid (Myzus persicae), strawberry aphid (Brachycaudus helichrysi), radish aphid (Brevicoryne brassicae), rosy apple aphid (Dysaphis plantaginea), false radish aphid (Lipaphis erysimi), tulip aphid (Macrosiphum euphorbiae), potato aphid (Aulacorthum solani), lettuce aphid (Nasonovia ribisnigri), wheat collar aphid (Rhopalosiphum padi), corn aphid (Rhopalosiphum maidis), citrus black aphid (Toxoptera citricida), peach butterbur aphid (Hyalopterus pruni), barnyard millet aphid (Melanaphis sacchari), Japanese black aphid (Tetraneura nigriabdominalis), cotton aphid (Ceratovacuna lanigera), apple aphid (Eriosoma lanigerum), English grain aphid (Sitobion avenae), etc. Aphididae; grape aphid (Daktulosphaira vitifoliae), pecan phylloxera (Phylloxera devastatrix), pecan leaf phylloxera (Phylloxera notabilis), southern pecan leaf phylloxera (Phylloxera Phylloxeridae, such as (Russelae);Adelgidae, such as the Japanese hemlock aphid (Adelges tsugae), the balsam woolly aphid (Adelges piceae), and the small brown aphid (Aphrastasia pectinatae); Scotinophara lurida, Scotinophara coarctata, Nezara antennata, Eysarcoris aeneus, Eysarcoris lewisi, Eysarcoris ventralis, Eysarcoris annamita, Halyomorpha halys, and Nezara Pentatomidae, such as the brown stink bug (Euschistus heros), the red-banded stink bug (Piezodorus guildinii), Oebalus pugnax, Dichelops melacanthus, and the spotted stink bug (Piezodorus hybneri); Cydnidae, such as the narrow-banded stink bug (Riptortus clavatus), the spider stink bug (Leptocorisa chinensis), and the narrow-banded stink bug (Leptocorisa acuta); Cletus punctiger, Leptoglossus Coreidae, such as Cavelerius saccharivorus, Togo hemipterus, and Blissus leucopterus; Lygaeidae, such as Cavelerius saccharivorus, Togo hemipterus, and Blissus leucopterus;Miridae (Miridae) such as the red-bearded green rice bug (Trigonotylus caelestialium), the red-striped rice bug (Stenotus rubrovittatus), the long-spined wheat rice bug (Stenodema calcarata), and the rusty rice bug (Lygus lineolaris); Aleyrodidae (Aleyrodidae) such as the greenhouse whitefly (Trialeurodes vaporariorum), the tobacco whitefly (Bemisia tabaci), the citrus whitefly (Dialeurodes citri), the citrus spine whitefly (Aleurocanthus spiniferus), the tea spine whitefly (Aleurocanthus camelliae), and the Japanese oak leaf butterflies (Pealius euryae); cyanophylli), red scale (Aonidiella aurantii), pear scale (Diaspidiotus perniciosus), mulberry scale (Pseudaulacaspis pentagona), Yanon scale (Unaspis yanonensis), false Yanon scale (Unaspis citri) and other scale insects (Diaspididae); Coccidae such as ruby ​​scale (Ceroplastes rubens); Margarodidae such as Icerya purchasi and yellow cotton scale (Icerya seychellarum);Pseudococcidae, such as the eggplant mealybug (Phenacoccus solani), the sable mealybug (Phenacoccus solenopsis), the wisteria mealybug (Planococcus kraunhiae), the mulberry mealybug (Pseudococcus comstocki), the citrus mealybug (Planococcus citri), the moth mealybug (Pseudococcus calceolariae), the long-legged mealybug (Pseudococcus longispinus), and the tuttlemey bug (Brevennia rehi); the citrus psyllid (Diaphorina citri), the citrus psyllid (Trioza erytreae), the pear psyllid (Cacopsylla pyrisuga), and the Chinese pear psyllid (Cacopsylla Psyllidae, such as the Japanese chinensis, the potato psyllid (Bactericera cockerelli), and the cacopsylla (Cacopsylla pyricola); Tingidae, such as the plane tree earworm (Corythucha ciliata), the goldenrod earworm (Corythucha marmorata), the Japanese pear earworm (Stephanitis nashi), and the azalea earworm (Stephanitis pyrioides); Cimicidae, such as the bedbug (Cimex lectularius) and the netted whitefly (Cimex hemipterus); Cicadidae, such as the Quesada gigas; Triatoma infestans, Triatoma rubrofasciata, and Triatoma Reduviidae, such as the Venezuelan assassin bug (Rhodonius prolixus);

[0037] Lepidoptera: Chilo suppressalis, Dark-headed stem borer, Chilo polychrysus, White stem borer, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Rice leaf borer, Cnaphalocrocis medinalis, Marasmia patnalis, Rice casino borer, Marasmia exigua, Cotton borer, Notarcha derogata, European corn borer, Ostrinia furnacalis, European corn borer, Hellula undalis, Black-spotted corn borer, Herpetogramma luctuosale, Rice stalk moth, Nymphula Crambidae, such as the Japanese corn moth (Elasmopalpus lignosellus), the Indian meal moth (Plodia interpunctella), the Japanese two-spotted moth (Euzophera batangensis), and the Japanese striped moth (Cadra cautella);Common cutworm (Spodoptera litura), beet armyworm (Spodoptera exigua), armyworm (Mythimna separata), armyworm (Mamestra brassicae), rice armyworm (Sesamia inferens), white armyworm (Spodoptera mauritia), two-banded cutworm (Naranga aenescens), leaf fall armyworm (Spodoptera frugiperda), African armyworm (Spodoptera exempta), Spodoptera cosmioides, semi-tropical armyworm (Spodoptera eridania), red cutworm (Agrotis ipsilon), turnip cutworm (Agrotis segetum), red rice looper (Autographa nigrisigna), rice yellow looper (Plusia festucae), soybean Heliothis spp. such as the cotton bollworm (Chrysodeixis includens), Trichoplusia spp., and Heliothis spp. such as the false tobacco budworm (Heliothis virescens), Helicoverpa spp. such as the cotton bollworm (Helicoverpa armigera) and the corn earworm (Helicoverpa zea), Noctuidae such as the velvet bean caterpillar (Anticarsia gemmatalis), the cotton leafworm (Alabama argillacea), and the hop wine borer (Hydraecia immanis); Pieridae such as the cabbage white butterfly (Pieris rapae);Pear fruit moth (Grapholita molesta), plum fruit moth (Grapholita dimorpha), bean fruit moth (Leguminivora glycinivorella), adzuki bean pea moth (Matsumuraeses azukivora), apple smaller tortrix (Adoxophyes orana fasciata), tea smaller tortrix (Adoxophyes honmai), tea tortrix (Homona magnanima), green tea tortrix (Archips fuscocupreanus), codling moth (Cydia pomonella), citrus fruit borer (Tetramoera schistaceana), bean shoot borer (Epinotia aporema), citrus fruit borer (Citripestis sagittiferella), European grape wine moth (Lobesia Tortricidae such as Caloptilia theivora and Phyllonorycter ringoniella; Gracilariae such as Carposinidae; Leucoptera coffeella, Lyonetiidae such as Lyonetia clerkella, Lyonetia prunifoliella; Lymantria spp. such as Lymantria dispar, Euproctis spp. such as Euproctis pseudoconspersa; Plutella xylostella Plutellidae, such as Plutellidae (Plutella xylostella);Gelechiidae (Gelechiidae) such as the peach leaf moth (Anarsia lineatella), the potato leaf moth (Helcystogramma triannulella), the red bollworm moth (Pectinophora gossypiella), the potato tuber moth (Pthorimaea operculella), and the tomato leaf moth (Tuta absoluta); Arctiidae (Arctiidae) such as the American fall webworm (Hyphantria cunea); Castniidae (Castniidae) such as the giant sugarcane borer (Telchin licus); Cossidae (Cossidae) such as the small box moth (Cossus insularis); Geometridae (Geometridae) such as the mugwort geometrid (Ascotis selenaria); Parasa Limacodidae such as Stathmopodidae (Stathmopoda masinissa) and the like; Sphingidae such as Acherontia lachesis (Sphingidae); Sesiidae such as Nokona feralis (Nokona feralis), Synanthedon hector (Synanthedon tenuis) and the like; Hesperiidae such as Parnara guttata (Parnara guttata); Tineidae such as Tinea translucens (Tineola bisselliella) and the like.

[0038] Thysanoptera: Thripidae such as Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, Echinothrips americanus, and Scirtothrips perseae; Phlaeothripidae such as Haplothrips aculeatus.

[0039] Diptera: Anthomyiidae such as Delia platura, Delia antiqua, and Pegomya cunicularia; Ulidiidae such as Tetanops myopaeformis; Agromyzidae such as Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, and Chromatomyia horticola; Chloropidae such as Chlorops oryzae; Bactrocera Tephritidae, such as the Oriental fruit fly (Bactrocera dorsalis), the eggplant fly (Bactrocera latifrons), the olive fruit fly (Bactrocera oleae), the Queensland fruit fly (Bactrocera tryoni), the Mediterranean fruit fly (Ceratitis capitata), the apple maggot (Rhagoletis pomonella), and the cherry fruit fly (Rhacochlaena japonica); Ephydridae, such as the rice leafminer (Hydrellia griseola), the Asian rice leafminer (Hydrellia philippina), and the rice leafminer (Hydrellia sasakii); Drosophila suzukii Drosophilidae, such as Drosophila melanogaster (Drosophila suzukii) and Drosophila melanogaster; Phoridae, such as Megaselia spiracularis; Psychodidae, such as Clogmia albipunctata;Sciaridae (Sciaridae) such as Bradysia difformis and Bradysia odoriphaga; Cecidomyiidae (Cecidomyiidae) such as Mayetiola destructor and Orseolia oryzae; Diopsidae (Diopsis macrophthalma); Glossinidae (Tsetse flies) such as Glossina palpalis and Glossina morsitans; Simuliidae (Simuliidae) such as Simulium japonicum and Simulium damnosum; Phlebotominae (Phlebotominae); Tipula aino (Craned fly), Tipula oleracea (Common crane fly), and Tipula Tipulidae such as Culex pipiens pallens, Culex tritaeniorhynchus, Culex pipiens f. molestus, Culex quinquefasciatus, Culex pipiens pipiens, Culex vishnui, Aedes albopictus, Aedes aegypti, Anopheles sinensis, Anopheles gambiae, Anopheles stephensi, Anopheles coluzzii, Anopheles albimanus, Anopheles sundaicus, Anopheles mosquito family (Culicidae) such as arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus;Simulidae (Family Simuliidae) such as Prosimulium yezoensis and Simulium ornatum; Tabanidae (Family Tabanus trigonus) and other such flies; Muscidae (Family Musca domestica), Muscina stabulans, Stomoxys calcitrans, Haematobia irritans and other such flies; Calliphoridae (Family Sarcophagidae); Chironomidae (Family Chironomidae) such as Chironomus plumosus, Chironomus yoshimatsui, Glyptotendipes tokunagai and other such flies; Fannidae (Family Fannidae);

[0040] Coleoptera: Diabrotica spp. (e.g., Western corn rootworm (Diabrotica virgifera virgifera), Southern corn rootworm (Diabrotica undecimpunctata howardi), Northern corn rootworm (Diabrotica barberi), Mexican corn rootworm (Diabrotica virgifera zeae), Banded cucumber beetle (Diabrotica balteata), Cucumber beetle (Diabrotica speciosa), etc.), Bean leaf beetle (Cerotoma trifurcata), Red-necked leaf beetle (Oulema melanopus), Cucumber leaf beetle (Aulacophora femoralis), Striped flea beetle (Phyllotreta striolata), Cabbage leaf beetle (Phyllotreta cruciferae), Western black leaf beetle (Phyllotreta pusilla, cabbage stem beetle (Psylliodes chrysocephala), hop beetle (Psylliodes punctulata), Colorado potato beetle (Leptinotarsa ​​decemlineata), rice leaf beetle (Oulema oryzae), grape colaspis (Colaspis brunnea), corn beetle (Chaetocnema pulicaria), sweet potato leaf beetle (Chaetocnema confinis), potato beetle (Epitrix cucumeris), rice spur beetle (Dicladispa armigera), southern corn leaf beetle (Myochrous denticollis), four-spotted tortoise beetle (Laccoptera quadrimaculata), tobacco flea beetle (Epitrix hirtipennis), radish leaf beetle (Phaedon Chrysomelidae, such as the two-striped leaf beetle (Medythia nigrobilineata);Carabidae beetles such as the seed corn beetle (Stenolophus lecontei) and the slender seed corn beetle (Clivina impressifrons); Phyllophaga spp. such as the cuprea beetle (Anomala cuprea), the rufocuprea beetle (Anomala rufocuprea), the green beetle (Anomala albopilosa), the Japanese beetle (Popillia japonica), the long-legged beetle (Heptophylla picea), the European chafer (Rhizotrogus majalis), the black marsh beetle (Tomarus gibbosus), the black beetle (Holotrichia spp.), and the June beetle (Phyllophaga crinita); Diloboderus spp. such as Diloboderus abderus. Scarabaeidae (Scarabaeidae) such as Araecerus coffeae (Boll weevil); Anthriibidae (Anthriibidae) such as Cylas formicarius (Sweet potato weevil); Bruchidae (Brachiidae) such as Zabrotes subfasciatus (Brazilian bean weevil); Scolytidae (Scolytidae) such as Tomicus piniperda (Pine bark beetle), Hypothenemus hampei (Coffee berry borer);Potato weevil (Euscepes postfasciatus), alfalfa weevil (Hypera postica), maize weevil (Sitophilus zeamais), rice weevil (Sitophilus oryzae), granaria weevil (Sitophilus granarius), rice weevil (Echinocnemus squameus), rice water weevil (Lissorhoptrus oryzophilus), white grain weevil (Rhabdoscelus lineaticollis), boll weevil (Anthonomus grandis), grass band weevil (Sphenophorus venatus), southern cornbill bug (Sphenophorus callosus), soybean stalk weevil (Sternechus subsignatus), sugarcane weevil (Sphenophorus levis), rust gourd weevil (Scepticus The Aracanthus spp. (Aracanthus spp.) such as Aracanthus griseus, Scepticus uniformis, Aracanthus mourei, and the cotton root borer (Eutinobothrus brasiliensis) are also included in the Curculionidae family; the Tenebrionidae (Tenebrionidae) such as Tribolium castaneum, Tribolium confusum, and Alphitobius diaperinus are also included in the Coccinellidae family; the Flat-headed Ladybird (Lyctus brunneus), the Rhizopertha dominica); Ptinidae; Cerambycidae, such as Anoplophora malasiaca, Migdolus fryanus, and Aromia bungii;Elateridae beetles such as the Okinawan wireworm beetle (Melanotus okinawensis), the brown-headed wireworm beetle (Agriotes fuscicollis), the comb beetle (Melanotus legatus), the foot-striped wireworm beetle (Anchastus spp.), the Conoderus spp., the Ctenicera spp., the Limonius spp., and the Aeolus spp.; Staphylinidae beetles such as the blue-leaf rove beetle (Paederus fuscipes); the small-leaved weevils (Anthrenus verbasci) and the white-striped weevils (Dermestes Dermestidae such as Trogoderma granarium (Trogoderma maculates) and the like; Anobiidae such as Lasioderma serricorne (tobacco beetle) and Stegobium paniceum (Anobiidae); Laemophloeidae such as Cryptolestes ferrugineus (Laemophloeidae); Silvanidae such as Oryzaephilus surinamensis (Silvanidae); Nitidulidae such as Brassicogethes aeneus (Blossom beetle).

[0041] Orthoptera: Migratory locust (Locusta migratoria), Moroccan locust (Dociostaurus maroccanus), Australian locust (Chortoicetes terminifera), Red locust (Nomadacris septemfasciata), Brown locust (Locustana pardalina), Tree locust (Anacridium melanorhodon), Italian locust (Calliptamus italicus), Differential grasshopper (Melanoplus differentialis), Two-striped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-legged grasshopper (Melanoplus femurrubrum), Clear-winged grasshopper (Camnula pellucida), Desert grasshopper (Schistocerca The grasshoppers (Acrididae) include the common locust (Oxya gregaria), yellow-winged locust (Gastrimargus musicus), sparse-throated locust (Austracris guttulosa), oriental grasshopper (Oxya yezoensis), long-winged locust (Oxya japonica), and Taiwan grasshopper (Patanga succincta); the grasshoppers (Gryllotalpidae) include the common house cricket (Gryllotalpa orientalis); the crickets (Gryllidae) include the European house cricket (Acheta domestica) and the field cricket (Teleogryllus emma); and the katydids (Tettigoniidae) include the Mormon cricket (Anabrus simplex).

[0042] Hymenoptera: Tenthredinidae such as Athalia rosae and Athalia japonica; Solenopsis spp. such as Solenopsis invicta and Solenopsis geminata, Atta spp. such as Atta capiguara, Acromyrmex spp., Paraponera clavata, Ochetellus glaber, Monomorium pharaonis, Linepithema humile, Formica japonica, Pristomyrmex punctutus, Pheidole Camponotus spp. such as Camponotus noda, Pheidole megacephala, Camponotus japonicus, Camponotus obscuripes, Pogonomyrmex spp. such as Pogonomyrmex occidentalis, Wasmania spp. such as Wasmania auropunctata, Formicidae such as Anoplolepis gracilipes; Vespa mandarinia, Vespa simillima, Vespa analis, Vespa Vespidae, such as Polistes velutina and Polistes jokahamae; Siricidae, such as Urocerus gigas; and Bethylidae.

[0043] Blattodea: Ectobiidae, such as the German cockroach (Blattella germanica); Blattidae, such as the American cockroach (Periplaneta fuliginosa), the American cockroach (Periplaneta americana), the American cockroach (Periplaneta australasiae), the brown cockroach (Periplaneta brunnea), and the Asian cockroach (Blatta orientalis); Reticulitermes speratus, Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, and Neotermes Termites of the family Termitidae, such as the Satsuma termite (Glyptotermes satsumensis), Nakajima termite (Glyptotermes nakajimai), Katan termite (Glyptotermes fuscus), Hodotermopsis sjostedti, Koshu termite (Coptotermes guangzhouensis), Amami termite (Reticulitermes amamianus), Miyatake termite (Reticulitermes miyatakei), Formosan termite (Reticulitermes kanmonensis), Takasago termite (Nasutitermes takasagoensis), Snocapritermes nitobei, Sinocapritermes mushae, and Cornitermes cumulans.

[0044] Order Siphonaptera: Family Pulicidae such as human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.; Family Hectopsyllidae such as sand flea (Tunga penetrans); Family Ceratophyllidae such as European rat flea (Nosopsyllus fasciatus).

[0045] Psocodae: Pediculidae, such as head louse (Pediculus humanus capitis); Pthiridae, such as pubic louse (Pthirus pubis); Haematopinidae, such as cow louse (Haematopinus eurysternus) and pig louse (Haematopinus suis); Linognathidae, such as cow louse (Linognathus vituli), sheep trunk louse (Linognathus ovillus), and woolly cow louse (Solenopotes capillatus); Bovicola bovis, sheep louse (Bovicola ovis), Bovicola breviceps, Damalinia Bovicoliidae, such as Trichodectes canis and Felicola subrostratus; Menoponidae, such as Menopon gallinae, Menacanthus stramineus, and Trinoton spp.; Trimenoponidae, such as Cummingsia spp.; Trogiidae, such as Trogium pulsatorium; Liposcelis corrodens and Liposcelis Liposcelidae or Liposcelididae, such as Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelis entomophila.

[0046] Thysanura: Family Lepismatidae, including the Japanese silverfish (Ctenolepisma villosa) and the European silverfish (Lepisma saccharina).

[0047] Acari: Tetranychidae such as Tetranychus urticae, Tetranychus kanzawai, Tetranychus evansi, Panonychus citri, Panonychus ulmi, Oligonychus spp.; Aculops pelekassi, Aculops citri, Aculops lycopersici, Calacarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculops spp. Eriophyidae such as Aceria diospyri, Aceria tosichella, and Shevtchenkella sp.; Tarsonemidae such as Polyphagotarsonemus latus; Tenuipalpidae such as Brevipalpus phoenicis; Tuckerellidae;Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysalis japonica, Haemaphysalis campanulata, Dermacentor variabilis, Dermacentor taiwanensis, Rocky Mountain wood tick (Dermacentor andersoni), Dermacentor reticulatus, Ixodes ovatus, Ixodes persulcatus, Black-legged tick (Ixodes scapularis), Western black-legged tick (Ixodes pacificus), Ixodes holocyclus, Ixodes ricinus, Lone star tick (Amblyomma Ixodidae ticks such as Amblyomma americanum, Amblyomma maculatum, Rhipicephalus microplus, Rhipicephalus annulatus, Rhipicephalus sanguineus, Rhipicephalus appendiculatus, and Rhipicephalus decoloratus; Argasidae ticks such as Argas persicus, Ornithodoros hermsi, and Ornithodoros turicata; Acaridae ticks such as Tyrophagus putrescentiae and Tyrophagus similis; Dermatophagoides farinae and Dermatophagoides pteronyssinus. Pyroglyphidae, such as Pteronyssinus;Cheyletidae such as Cheyletus eruditus, Cheyletus malaccensis, Chelacaropsis moorei, and Cheyletiella yasguri; Psoroptidae such as Psoroptes ovis, Psoroptes equi, Knemidocoptes mutans, Otodectes cynotis, and Chorioptes spp.; Notoedres cati, Notoedres muris, and Sarcoptes Sarcoptidae such as (Scabiei); Listrophoridae such as (Listrophorus gibbus); Dermanyssidae such as (Dermanyssus gallinae); Macronyssidae such as (Ornithonyssus sylviarum) and (Ornithonyssus bacoti); Varroa destructor such as (Varroa jacobsoni); Demodicidae such as (Demodex canis) and (Demodex cati); Leptotrombidium akamushi and (Leptotrombidium Trombiculidae, such as Leptotrombidium scutellare, Leptotrombidium pallidum, and Leptotrombidium scutellare.

[0048] Araneae: Eutichuridae, such as Cheiracanthium japonicum; Theridiidae, such as Latrodectus hasseltii. Polydesmida: Paradoxosomatidae, such as Oxidus gracilis and Nedyopus tambanus. Isopoda: Armadillidiidae, such as Armadillidium vulgare. Chilopoda: Scutigeridae such as Thereuonema hilgendorfi; Scolopendridae such as Scolopendra subspinipes; Ethopolyidae such as Bothropolys rugosus. Class Gastropoda: Family Limacidae such as the brown slug (Limax marginatus) and the yellow slug (Limax flavus); Family Philomycidae such as the slug (Meghimatium bilineatum); Family Ampullariidae such as the apple snail (Pomacea canaliculata); Family Lymnaeidae such as the lymnae snail (Austropeplea ollula).

[0049] Nematoda: Aphelenchoididae, such as the rice root-lesion nematode (Aphelenchoides besseyi); Pratylenchidae, such as Pratylenchus coffeae, Pratylenchus brachyurus, Pratylenchus neglectus, and Radopholus similis; Meloidogyne javanica, Meloidogyne incognita, guava root-knot nematodes (Meloidogyne enterolobii), Meloidogyne hapla, soybean cyst nematode (Heterodera glycines), potato cyst nematode (Globodera Heteroderidae such as Globodera rostochiensis, potato white cyst nematode (Globodera pallida), and Colombian root-knot nematode (Meloidogyne chitwoodi); Hoplolaimidae such as Rotylenchulus reniformis; Anguinidae such as Nothotylenchus acris and Ditylenchus dipsaci; Tylenchulidae such as Tylenchulus semipenetrans; Longidoridae such as Xiphinema index; Trichodoridae; Parasitaphelenchidae such as Bursaphelenchus xylophilus.

[0050] The harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes may be harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes that have reduced sensitivity to insecticides, acaricides, molluscicides, or nematocides, or that have developed resistance to the insecticides, acaricides, molluscicides, or nematocides.

[0051] The method for controlling arthropod pests of the present invention is carried out by applying an effective amount of the compound of the present invention or composition A directly to the arthropod pests and / or to the habitat of the arthropod pests (plants, soil, houses, animals, etc.). Examples of the method for controlling arthropod pests of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, fumigation treatment, water surface treatment, and seed treatment.

[0052] The compound of the present invention or Composition A is typically formulated into aqueous suspensions, oil suspensions, oil solutions, emulsifiable concentrates, emulsions, microemulsions, microcapsule formulations, wettable powders, water dispersible granules, dusts, granules, tablets, aerosols, resin formulations, etc. by mixing an inactive inactivated carrier such as a solid carrier, a liquid carrier, or a gaseous carrier with a surfactant, and optionally adding formulation adjuvants such as binders, dispersants, and stabilizers. In addition to these formulations, the compound of the present invention or Composition A can also be formulated into dosage forms described in the Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271 to 276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN:0259-2517. These formulations typically contain 0.0001 to 99% by weight of the compound of the present invention or Composition A.

[0053] Examples of solid carriers include clay (pyrophyllite clay, kaolin clay, etc.), talc, calcium carbonate, diatomaceous earth, zeolite, bentonite, acid clay, attapulgite, white carbon, ammonium sulfate, vermiculite, perlite, pumice, silica sand, fine powder and granular chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and resins (polyethylene, polypropylene, polyester, polyurethane, polyamide, polyvinyl chloride, etc.).

[0054] Examples of liquid carriers include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, etc.), aromatic hydrocarbons (xylene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, methyl oleate, propylene carbonate, etc.), nitriles (acetonitrile, etc.), ethers (ethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, N,N-dimethyloctanamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.), fatty acids (oleic acid, etc.), and vegetable oils (soybean oil, etc.).

[0055] Examples of gaseous carriers include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide gas.

[0056] Examples of surfactants include nonionic surfactants (polyoxyethylene alkyl ethers, polyoxyethylene alkylaryl ethers, polyethylene glycol fatty acid esters, etc.) and anionic surfactants (alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, etc.).

[0057] Other formulation adjuvants include binders, dispersants, colorants, stabilizers, etc., and specific examples include polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), acid isopropyl phosphate, and dibutylhydroxytoluene.

[0058] In addition, adjuvants can be used as components that enhance or support the efficacy of the compound of the present invention. Specific examples include Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol (registered trademark), Silwet L-77 (registered trademark), BreakThru (registered trademark), Sundance II (registered trademark), Induce (registered trademark), Penetrator (registered trademark), AgriDex (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), and BANOLE (registered trademark).

[0059] In the present invention, the plant includes the whole plant, stems and leaves, flowers, spikes, fruits, trunks, branches, crowns, seeds, vegetative reproductive organs, and seedlings.

[0060] Vegetative reproductive organs refer to plant roots, stems, leaves, and other parts that can grow when separated from the main body and placed in soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms (or solid bulbs), tubers, rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. Stolons are sometimes called runners, and propagules are also called bulbils and are divided into broad buds and bulbils. Vines refer to shoots (a collective term for leaves and stems) of plants such as sweet potatoes and Japanese yams. Bulbs, corms, tubers, rhizomes, stem fragments, rhizophores, and tuberous roots are collectively called bulbils. Potato cultivation begins by planting tubers in the soil, and the tubers used are generally called seed potatoes.

[0061] Examples of the method for controlling harmful arthropods by applying an effective amount of the compound of the present invention or composition A to soil include a method of applying an effective amount of the compound of the present invention or composition A to soil before or after planting a plant. More specifically, for example, planting hole treatment (spraying in planting holes, mixing in planting hole treatment soil), plant base treatment (spraying in planting holes, mixing in plant base soil, plant base irrigation, plant base treatment in the latter half of the seedling raising period), planting furrow treatment (spraying in planting furrows, mixing in planting furrow soil), row treatment (row spraying, row soil mixing, row spraying in the growing season), row treatment at sowing (row spraying at sowing, mixing in row soil at sowing), overall treatment (overall soil spraying, overall soil mixing), side row treatment, water surface treatment (water surface application, water surface application after flooding), other soil spray treatments (foliar spraying of granules during the growing season, spraying under the crown or around the main trunk, soil surface spraying, soil surface mixing, seeding hole spraying, furrow surface spraying, spraying between plants), and others. Other irrigation treatments include soil irrigation, seedling irrigation, chemical injection treatment, ground level irrigation, chemical drip irrigation, chemigation), seedling tray treatments (seedling tray spraying, seedling tray irrigation, seedling tray flooding), seedling tray treatments (seedling tray spraying, seedling tray irrigation, seedling tray flooding), seedling bed treatments (seedling bed spraying, seedling bed irrigation, water seedling bed spraying, seedling immersion), bed soil mixing treatments (bed soil mixing, bed soil mixing before sowing, spraying before soil covering at sowing, spraying after soil covering at sowing, covering soil mixing), and other treatments (hilling soil mixing, plowing in, topsoil mixing, rain-drop soil mixing, planting position treatment, granular inflorescence spraying, paste fertilizer mixing).

[0062] Seed treatments include, for example, treatment of seeds or vegetative reproductive organs with the compound of the present invention or Composition A. More specifically, examples include spray treatments in which a suspension of the compound of the present invention or Composition A is sprayed onto the surface of seeds or vegetative reproductive organs in a mist; smear treatments in which the compound of the present invention or Composition A is applied to seeds or vegetative reproductive organs; immersion treatments in which seeds or vegetative reproductive organs are immersed in a solution of the compound of the present invention or Composition A for a certain period of time; and methods of coating seeds or vegetative reproductive organs with a carrier containing the compound of the present invention or Composition A (film coating treatment, pellet coating treatment, etc.). Seed potatoes are particularly examples of the vegetative reproductive organs mentioned above. When applying Composition A to seeds or vegetative reproductive organs, Composition A can be applied to the seeds or vegetative reproductive organs as a single formulation, or different formulations of Composition A can be applied to the seeds or vegetative reproductive organs in multiple separate applications. Examples of methods for treating seeds or vegetative reproductive organs with multiple different formulations of Composition A include a method of treating seeds or vegetative reproductive organs with a formulation containing only the compound of the present invention as an active ingredient, air-drying the seeds or vegetative reproductive organs, and then treating with a formulation containing this ingredient; and a method of treating seeds or vegetative reproductive organs with a formulation containing both the compound of the present invention and this ingredient as active ingredients, air-drying the seeds or vegetative reproductive organs, and then treating with a formulation containing a component other than the component already treated. In the present invention, "seeds or vegetative reproductive organs carrying the compound of the present invention or Composition A" refers to seeds or vegetative reproductive organs to which the compound of the present invention or Composition A is attached. The seeds or vegetative reproductive organs carrying the compound of the present invention or Composition A may have materials other than the compound of the present invention or Composition A attached to them before or after the compound of the present invention or Composition A is attached to the seeds or vegetative reproductive organs. Furthermore, when Composition A is attached to the surface of the seeds or vegetative reproductive organs in layers, the layers may consist of one layer or multiple layers. Furthermore, when the layer consists of multiple layers, each layer may contain one or more active ingredients, or may consist of a layer containing one or more active ingredients and a layer containing no active ingredients. Seeds or vegetative reproductive organs carrying the compound of the present invention or Composition A can be obtained, for example, by applying a formulation containing the compound of the present invention or Composition A to seeds or vegetative reproductive organs by the seed treatment method described above.

[0063] When the compound of the present invention or composition A is used for controlling harmful arthropods in the agricultural field, the application amount is 10,000 m 2 The amount of the compound of the present invention is usually 1 to 10,000 g per kg of seed or vegetative reproductive organ. When treating seeds or vegetative reproductive organs, the compound of the present invention is usually applied in an amount within the range of 0.001 to 100 g per kg of seed or vegetative reproductive organ. When the compound of the present invention or Composition A is formulated as an emulsifiable concentrate, wettable powder, flowable concentrate, etc., it is usually applied after being diluted with water to an active ingredient concentration of 0.01 to 10,000 ppm, and granules, dusts, etc. are usually applied as is.

[0064] The compound of the present invention or composition A can also be applied by wrapping a resin preparation in the form of a sheet or string around the crop, stretching it near the crop, or spreading it on the soil around the base of the plant.

[0065] When the compound of the present invention or composition A is used to control harmful arthropods living in houses, the application amount is 1 / 2 m / day for surface treatment. 2 The amount of the compound of the present invention per square meter is usually 0.01 to 1,000 mg. 3 When the compound of the present invention or Composition A is formulated as an emulsifiable concentrate, wettable powder, flowable concentrate or the like, it is usually applied after diluting with water so that the active ingredient concentration becomes 0.1 to 10,000 ppm, whereas oil solutions, aerosols, fumigants, poison baits and the like are applied as they are.

[0066] When the compound of the present invention or Composition A is used to control ectoparasites in livestock such as cattle, horses, pigs, sheep, goats, and chickens, or small animals such as dogs, cats, rats, and mice, it can be administered to animals by methods known in veterinary medicine. Specific methods of administration include, for example, administration by tablet, incorporation into feed, suppository, or injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.) for systemic control, and administration by methods such as spraying an oil or aqueous liquid, pour-on application, spot-on application, washing the animal with a shampoo formulation, or attaching a resin formulation to the animal as a collar or ear tag. When administered to animals, the amount of the compound of the present invention or Composition A is usually in the range of 0.1 to 1000 mg per kg of the animal's body weight.

[0067] The compound of the present invention or Composition A can be used as an agent for controlling harmful arthropods in agricultural lands such as fields, paddy fields, lawns, orchards, etc. Examples of plants include the following.

[0068] Corn (horse-tooth, hard grain, soft grain, explosive, glutinous, sweet, field corn), rice (long grain, short grain, medium grain, japonica, tropical japonica, indica, javanica, paddy rice, upland rice, floating rice, direct-seeded rice, transplanted rice, glutinous rice), wheat (bread wheat (hard, soft, medium, red wheat, white wheat), durum wheat, spelt wheat, club wheat, each winter wheat type, spring wheat type), barley (two-row barley (= beer barley), six-row barley, naked barley, waxy barley, each winter barley type, spring barley type), rye (winter rye type, spring rye type), triticale (winter triticale type, spring triticale type), oats (winter oat type, spring oat type), sorghum, cotton (upland type, pima type), soybean (fully harvested seed varieties, edamame varieties, green-harvested varieties, indeterminate, determinate, semi-determinate types), peanuts, buckwheat, sugar beet (sugar production, animal feed, root vegetable, leafy vegetable, fuel), rapeseed (winter rapeseed type, spring rapeseed type), canola (winter canola type, spring canola type), sunflower (oil production, food, ornamental), sugarcane, tobacco, tea plant, mulberry, solanaceous vegetables (eggplant, tomato, bell pepper, chili pepper) , potatoes, etc.), Cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon, etc.), Cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard greens, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, garland chrysanthemum, artichoke, lettuce, etc.), Liliaceae vegetables (leeks, onions, garlic, asparagus, etc.), Umbelliferae vegetables (carrots, parsley, celery, parsley, etc.), Chenopodiaceae vegetables (spinach, Swiss chard, etc.), Lamiaceae vegetables (perilla, mint, basil, etc.), strawberries, sweet potatoes, yams, scallions, Sweet potatoes, pome fruits (apples, European pears, Japanese pears, Chinese pears, quince, quince, etc.), stone fruits (peaches, plums, nectarines, plums, cherries, apricots, prunes, etc.), citrus fruits (Satsuma mandarins, oranges, lemons, limes, grapefruits, etc.), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashew nuts, macadamia nuts, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, figs, olives, loquats, bananas, coffee, dates, coconuts, ornamental plants, forest plants,Turfgrass, pasture grass,

[0069] The above-mentioned plants are not particularly limited as long as they are varieties that are commonly cultivated, and include plants that can be produced by natural crossbreeding, plants that can be generated by mutation, F1 hybrid plants, and genetically modified crops. Examples of genetically modified crops include plants that have been conferred resistance to herbicides such as HPPD (4-hydroxyphenylpyruvate dioxygenase enzyme) inhibitors such as isoxaflutole, ALS (acetolactate synthase) inhibitors such as imazethapyr and thifensulfuron methyl, EPSP (5-enolpyruvylshikimate-3-phosphate synthase) inhibitors, glutamine synthetase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, bromoxynil, or dicamba; plants that are capable of synthesizing selective toxins known to be found in the genus Bacillus, such as Bacillus thuringiensis; and plants that can be conferred specific insecticidal activity by synthesizing gene fragments that partially match endogenous genes derived from harmful insects and inducing gene silencing (RNAi; RNA interference) in the target harmful insect.

[0070] The present invention will be explained in more detail below with reference to Production Examples, Formulation Examples, and Test Examples, but the present invention is not limited to these examples. In this specification, Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, i-Pr represents an isopropyl group, t-Bu represents a tert-butyl group, C2F5 represents a perfluoroethyl group, c-Pr represents a cyclopropyl group, Ph represents a phenyl group, Py2 represents a 2-pyridyl group, Py3 represents a 3-pyridyl group, and Py4 represents a 4-pyridyl group. When c-Pr, Ph, Py2, Py3, and Py4 are substituted with a substituent, the substituent and the substitution position are written before the symbol. For example, 1-CN-c-Pr represents a 1-cyanocyclopropyl group, 3,4-F2-Ph represents a 3,4-difluorophenyl group, 2-C2F5-Ph represents a 2-(perfluoroethyl)phenyl group, 4-SO2CF3-Ph represents a 4-(trifluoromethanesulfonyl)phenyl group, 3,4-(OCF3)2-Ph represents a 3,4-bis(trifluoromethoxy)phenyl group, 3-SCF3-4-OCF3-Ph represents a 3-[(trifluoromethyl)thio]-4-(trifluoromethoxy)phenyl group, and 4-CF3-Py2 represents a 4-(trifluoromethyl)-2-pyridyl group.

[0071] First, examples of the preparation of the compounds of the present invention and their intermediates will be shown.

[0072] Reference Production Example 1 To a mixture of 2.2 g of 3-(2-bromoacetyl)-1-methyl-6-(2,2,3,3,3-pentafluoropropoxy)-2(1H)-pyridinone, produced by the method described in WO 2019 / 124548, and 30 mL of ethanol, 1.04 g of 5-(trifluoromethyl)-2-aminopyridine was added at room temperature, and the mixture was stirred under reflux for 9 hours. The resulting mixture was cooled to room temperature and then concentrated under reduced pressure. Water was added to the resulting residue, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 2.10 g of intermediate 1 represented by the following formula: Intermediate 1: 1H-NMR (CDCl3) δ: 8.70 (1H, s), 8.50 (2H, dt), 7.64 (1H, d), 7.31 (1H, dd), 5.78 (1H, d), 4.55 (2H, t), 3.62 (3H, s).

[0073] Reference Production Example 2 The compound produced in accordance with Reference Production Example 1 and its physical properties are shown below. In the compound represented by the formula 3 , R 3b , and R 3d A compound in which the combination of is any of the combinations described in [Table A1].

[0074] Intermediate 2: 1 H-NMR (CDCl3) δ: 3.47 (3H, s), 5.12 (2H, t), 6.24 (1H, d), 7.50 (1H, d), 7.58 (1H, d), 8.39 (1H, d), 8.66 (1H, s), 9.04 (1H, s). Intermediate 3: 1 H-NMR (CDCl3) δ: 3.61 (3H, s), 4.54 (2H, t), 5.77 (1H, d), 7.33-7.41 (2H, m), 8.38 (1H, s), 8.50-8.55 (2H, m). Intermediate 4: 1 H-NMR (CDCl3) δ: 3.55 (3H, s), 4.93 (2H, t), 7.21 (1H, d), 7.45 (1H, d), 8.25 (1H, s), 8.44 (1H, s), 8.71 (1H, s). Intermediate 5: 1 H-NMR (CDCl3) δ: 3.57 (3H, s), 4.94 (2H, t), 7.34-7.38 (2H, m), 8.38 (1H, s), 8.43 (1H, s), 8.73 (1H, s). Intermediate 6: 1H-NMR (CDCl3) δ: 3.58 (3H, s), 4.96 (2H, t), 6.94 (1H, d), 7.89 (1H, s), 8.23 ​​(1H, d), 8.60 (1H, s), 8.77 (1H, s). Intermediate 16: 1 H-NMR (CDCl3) δ: 3.58 (3H, s), 4.95 (2H, t), 7.32 (1H, d), 7.66 (1H, d), 8.49 (1H, d), 8.59 (1H, s), 8.76 (1H, s). Intermediate 17: 1 H-NMR (CDCl3) δ: 3.57 (3H, s), 4.94 (2H, t), 7.00 (1H, d), 7.87 (1H, d), 8.00 (1H, d), 8.45 (1H, s), 8.72 (1H, s).

[0075] Reference Production Example 3: To a mixture of 3.00 g of 4-(trifluoromethyl)anthranilic acid and 22 mL of THF was added dropwise a mixture of 1.52 g of triphosgene and 15 mL of THF under ice-cooling. The resulting mixture was stirred at room temperature for 4 hours. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to obtain 3.30 g of intermediate 7 represented by the following formula: Intermediate 7: 1 H-NMR (DMSO-D6) δ: 11.98 (1H, br s), 8.10 (1H, d), 7.54 (1H, d), 7.37 (1H, s).

[0076] Reference Production Example 4 Intermediate 8 represented by the following formula was obtained according to Reference Production Example 3, except that 2-amino-5-(trifluoromethoxy)benzoic acid was used instead of 4-(trifluoromethyl)anthranilic acid. Intermediate 8: 1 H-NMR (DMSO-D6) δ: 9.92 (1H, s), 5.83 (1H, d), 5.80-5.77 (1H, m), 5.26 (1H, d).

[0077] Reference Production Example 5: To a mixture of 1.00 g of 6-iodo-imidazo[1,2-a]pyridin-2-amine (prepared by the method described in Bioorganic & Medicinal Chemistry Letters, 2011, 21, 6586) and 7.7 mL of THF, 7.7 mL of potassium bis(trimethylsilyl)amide (1 mol / L THF solution) was added dropwise under a nitrogen atmosphere at −78°C, and the mixture was stirred for 30 minutes. 0.95 g of Intermediate 8 and THF were added to the resulting mixture, and the mixture was stirred at 0°C for 30 minutes. A saturated aqueous ammonium chloride solution was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. Hexane was added to the resulting residue, and the resulting solid was filtered. The filter cake was washed with hexane and then dried under reduced pressure, yielding 1.75 g of Intermediate 9 represented by the following formula: Intermediate 9: 1 H-NMR (CDCl3) δ: 9.66 (1H, s), 8.19-8.19 (1H, m), 7.99 (1H, s), 7.28 (1H, d), 7.15 (1H, dd), 6.99-6.96 (1H, m), 6.85 (1H, d), 6.56 (1H, d), 5.54 (2H, br s).

[0078] Reference Production Example 6 Intermediate 10 represented by the following formula was obtained in accordance with Reference Production Example 5, except that Intermediate 7 was used instead of Intermediate 8. Intermediate 10: 1 H-NMR (CDCl3) δ: 9.79 (1H, s), 8.36 (1H, dd), 8.16 (1H, s), 7.65 (1H, d), 7.29 (1H, dd), 6.98 (1H, d), 6.94 (1H, d), 6.82 (1H, d), 5.84 (2H, s).

[0079] Reference Production Example 7: A mixture of 1.75 g of Intermediate 9 and 38 mL of triethyl orthoformate was stirred at 120° C. for 40 minutes. The resulting mixture was allowed to cool to room temperature and concentrated under reduced pressure. The resulting solid was washed with hexane to obtain 1.60 g of Intermediate 11 represented by the following formula: Intermediate 11: 1H-NMR (CDCl3) δ: 9.44 (1H, s), 8.49 (1H, s), 8.47 (1H, dd), 8.24 (1H, d), 7.86 (1H, d), 7.64 (1H, dd), 7.48 (1H, dd), 7.42 (1H, d).

[0080] Reference Production Example 8 Intermediate 12 represented by the following formula was obtained according to Reference Production Example 7, except that Intermediate 10 was used instead of Intermediate 9. Intermediate 12: 1 H-NMR (CDCl3) δ: 9.53 (1H, s), 8.56 (1H, d), 8.53 (1H, s), 8.50 (1H, dd), 8.14-8.11 (1H, m), 7.80 (1H, dd), 7.52 (1H, dd), 7.45 (1H, d).

[0081] Reference Production Example 9: To a mixture of 2.14 g of 6-iodo-imidazo[1,2-a]pyridin-2-amine (prepared by the method described in Bioorganic & Medicinal Chemistry Letters, 2011, 21, 6586) and 28 mL of THF, 1.85 g of potassium tert-butoxide was added at 0°C under a nitrogen atmosphere and stirred for 5 minutes. 0.95 g of 5-bromoisatoic anhydride was added to the resulting mixture and stirred at room temperature for 1 hour. A saturated aqueous ammonium chloride solution was added to the resulting mixture, which was then concentrated under reduced pressure, and the resulting solid was filtered. 50 mL of triethyl orthoformate was added to the residue and stirred at 100°C for 2 hours. The resulting mixture was allowed to cool to room temperature and concentrated under reduced pressure. The resulting solid was washed with MTBE to obtain 2.25 g of intermediate 13 represented by the following formula: Intermediate 13: 1 H-NMR (CDCl3) δ: 9.44 (1H, s), 8.56 (1H, s), 8.50 (1H, s), 8.49-8.47 (1H, m), 7.91 (1H, d), 7.70 (1H, d), 7.49 (1H, d), 7.43 (1H, d).

[0082] Reference Preparation Example 10 A mixture of 1.48 g of 6-bromo-2-chloro-imidazo[1,2-a]pyridine prepared by the method described in WO 2019 / 124548, 2.4 mL of chlorosulfonic acid, and 13 mL of phosphorus oxychloride was stirred at 110 ° C. for 5 hours. The resulting mixture was concentrated under reduced pressure, and 2.7 mL of triethylamine, 13 mL of acetonitrile, and 3 mL of dimethylamine (7% tetrahydrofuran solution) were added to the resulting residue and stirred at room temperature for 1 hour. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 1.9 g of intermediate 14 represented by the following formula: Intermediate 14: 1 H-NMR (CDCl3) δ: 9.05 (1H, s), 7.53-7.55 (2H, m), 2.93 (6H, s).

[0083] Reference Preparation Example 11: A mixture of 0.9 g of intermediate 14, 1.5 g of cesium fluoride, and 5 mL of DMSO was stirred at 120°C for 4 hours. After the resulting mixture was cooled to room temperature, ethyl acetate and water were added successively, and the mixture was filtered. The filtrate was separated, and the resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.3 g of intermediate 15 represented by the following formula: Intermediate 15: 1 H-NMR (CDCl3) δ: 8.95 (1H, s), 7.50-7.59 (2H, m), 2.91 (6H, s).

[0084] Reference Preparation Example 12 A mixture of 6.6 g of 2-chloropyridine-3-sulfonyl chloride, 1.5 mL of triethylamine, 8 mL of acetonitrile, and 5 mL of dimethylamine (7% solution in tetrahydrofuran) was stirred at room temperature for 1 hour. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. 9.0 g of cesium fluoride and 30 mL of DMSO were added to the resulting residue, and the mixture was stirred at room temperature for 6 hours. After the resulting mixture was cooled to room temperature, ethyl acetate and water were added sequentially, and the mixture was filtered. The filtrate was separated, and the resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 3.4 g of intermediate 16 represented by the following formula: Intermediate 16: 1 H-NMR (CDCl3) δ: 8.40-8.43 (1H, m), 8.29-8.34 (1H, m), 7.35-7.40 (1H, m), 2.91 (6H, s).

[0085] Reference Production Example 13 Intermediate 17 represented by the following formula was obtained according to Reference Production Example 9. Intermediate 17: 1 H-NMR (CDCl3) δ: 9.41 (1H, s), 8.47 (1H, s), 8.45 (1H, d), 8.26 (1H, d), 7.99 (1H, d), 7.67 (1H, dd), 7.40-7.49 (2H, m).

[0086] Preparation Example 1: A mixture of 0.56 g of Intermediate 1, 0.5 mL of chlorosulfonic acid, and 3 mL of phosphorus oxychloride was stirred at 110° C. for 5 hours. The resulting mixture was concentrated under reduced pressure, and 0.5 mL of triethylamine, 3 mL of acetonitrile, and 0.5 mL of methylamine (7% solution in tetrahydrofuran) were added to the resulting residue, followed by stirring at room temperature for 1 hour. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.12 g of Compound 1 of the present invention, which is represented by the following formula: Compound 1 of the present invention: 1H-NMR (CDCl3) δ: 9.41 (1H, s), 7.88 (1H, d), 7.77 (1H, d), 7.55(1H, d), 7.40 (1H, d), 5.79 (1H, d), 4.54 (2H, t), 3.59 (3H, s), 2.85 (3H, d).

[0087] Production Example 2 In Production Example 1, the compound and the physical properties of the compound and the compound produced by the manufacturer are shown below. Compound 2 of this invention: 1 H-NMR (CDCl3) δ: 9.12 (1H, s), 7.81 (1H, d), 7.55 (1H, d), 7.46-7.42 (1H, m), 7.37-7.32 (1H, m), 5.76 (1H, d), 4.53 (2H, t), 3.56 (3H, s), 3.22-3.15 (2H, m), 1.22 (3H, t).

[0088] This compound 3: 1 H-NMR (CDCl3) δ: 8.95 (1H, s), 7.63 (1H, d), 7.59 (1H, d), 7.51-7.47 (1H, m), 5.64 (1H, d), 4.53 (2H, t), 3.54 (3H, s), 2.75 (6H, s).

[0089] This compound 4: 1 H-NMR (CDCl3) δ: 9.28 (1H, s), 7.85 (1H, d), 7.58 (1H, d), 7.46-7.43 (1H, m), 7.39-7.34 (1H, m), 5.79 (1H, d), 4.55 (2H, t), 3.59 (3H, s), 2.85 (3H, d).

[0090] Compound 5 of this invention: 1H-NMR (CDCl3) δ: 9.27 (1H, s), 8.16 (1H, s), 7.62 (1H, d), 7.53-7.49 (1H, m), 7.03 (1H, s), 4.95 (2H, t), 3.55 (3H, s), 2.50-2.45 (1H, m), 0.85-0.79 (2H, m), 0.75-0.70 (2H, m).

[0091] This compound 6: 1 H-NMR (CDCl3) δ: 9.06 (1H, s), 8.17 (1H, s), 7.64 (1H, d), 7.55-7.51 (1H, m), 6.03 (2H, s), 4.96 (2H, t), 3.56 (3H, s).

[0092] This compound 7: 1 H-NMR (CDCl3) δ: 9.25 (1H, s), 8.13 (1H, s), 7.60 (1H, d), 7.49 (1H, d), 6.80-6.76 (1H, m), 4.93 (2H, t), 3.54 (3H, s), 2.85 (3H, d).

[0093] This compound 8: 1 H-NMR (CDCl3) δ: 8.75 (1H, s), 8.13-8.11 (2H, m), 7.23-7.27 (1H, m), 6.78-6.81 (1H, m), 4.93 (2H, t), 3.54 (3H, s), 2.82 (3H, d).

[0094] Compound 9 of this invention: 1 H-NMR (CDCl3) δ: 9.31 (1H, s), 8.17 (1H, s), 7.82 (1H, d), 7.58(1H, d), 6.84-6.87 (1H, m), 4.94 (2H, t), 3.56 (3H, s), 2.86 (3H, d).

[0095] Compound 10 of this invention: 1H-NMR (CDCl3) δ: 9.15 (1H, d), 8.16 (1H, s), 8.02 (1H, s), 7.19 (1H, d), 6.84-6.92 (1H, m), 4.94 (2H, t), 3.55 (3H, s), 2.86 (3H, d).

[0096] Compound 11 of this invention: 1 H-NMR (CDCl3) δ: 9.02-9.01 (1H, m), 8.15 (1H, d), 8.05 (1H, s), 7.85 (1H, d), 7.76 (1H, dd), 7.66 (1H, dd), 7.59 (1H, dd), 2.86 (6H, s).

[0097] Compound 12 of this invention: 1 H-NMR (CDCl3) δ: 9.22 (1H, dd), 8.32 (1H, s), 8.16 (1H, d), 7.87 (1H, d), 7.74 (1H, dd), 7.68 (1H, dd), 7.57 (1H, dd), 6.07 (1H, q), 2.92 (3H, d).

[0098] This compound 13: 1 H-NMR (CDCl3) δ: 9.24-9.23 (1H, m), 8.50 (1H, d), 8.34 (1H, s), 7.95 (1H, dd), 7.75 (1H, dd), 7.71 (1H, d), 7.58 (1H, dd), 6.12-6.07 (1H, m), 2.93 (3H, d).

[0099] Production Example 3: To a mixture of 0.17 g of sodium hydride (oil, 60%) and 16 mL of NMP, 0.95 g of 4-(2,2,3,3,3-pentafluoropropoxy)-2(1H)-pyridinone was added under ice-cooling and stirred for 10 minutes, after which 0.80 g of Intermediate 16 was added and stirred at 60°C for 5 hours. The resulting mixture was cooled to room temperature, and water was added to the residue, followed by extraction with ethyl acetate. The resulting organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.60 g of the present compound 14 represented by the following formula: Compound 14 of the present invention: 1 H-NMR (CDCl3) δ: 8.70 (1H, s), 8.52-8.48 (2H, m), 7.64 (1H, d), 7.31 (1H, dd), 5.78 (1H, d), 4.55 (2H, t), 2.86 (6H, s).

[0100] Production Example 4 Compounds produced according to Production Example 3 and their physical properties are shown below. Compound 15 of the present invention: 1 H-NMR (CDCl3) δ: 8.88 (1H, s), 7.69-7.63 (2H, m), 7.56 (1H, d), 7.40 (1H, s), 6.86 (1H, d), 2.87 (6H, s).

[0101] Production Example 5 Compounds produced in accordance with Production Example 1 and their physical properties are shown below. Compound 16 of the present invention: 1 H-NMR (CDCl3) δ: 9.12 (1H, d), 8.12 (1H, s), 7.60 (1H, d), 7.50 (1H, dd), 6.80 (1H, t), 4.93 (2H, t), 3.55 (3H, s), 3.19-3.26 (2H, m), 1.23 (3H, t).

[0102] Compound 17 of the present invention: 1H-NMR (DMSO-D6) δ: 8.96 (1H, s), 8.50 (1H, s), 8.12 (1H, d), 8.03 (1H, d), 7.97 (1H, dd), 7.79-7.83 (2H, m), 6.69 (1H, d), 2.45 (3H, d).

[0103] Next, examples of the compound of the present invention that can be produced according to any of the production methods described in the Examples and the production methods described in this specification are shown below.

[0104] Formula (L-1) In the compound represented by the formula (hereinafter referred to as compound (L-1)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX1).

[0105]

[0106]

[0107] In compound (L-1), R 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX2). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX3). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX4). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX5). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX6). 2a and R 2b is a methyl group, and R 6 is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX7). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX8).

[0108] Formula (L-2) In the compound represented by the formula (hereinafter referred to as compound (L-2)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX9). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX10). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX11). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6is an ethyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX12). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX13). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX14). 2a and R 2b is a methyl group, and R 6 is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX15). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX16).

[0109] Formula (L-3) In the compound represented by the formula (hereinafter referred to as compound (L-3)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX17). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX18). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX19). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX20). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX21). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX22). 2a and R 2b is a methyl group, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX23). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX24).

[0110] Formula (L-4) In the compound represented by the formula (hereinafter referred to as compound (L-4)), R 2a and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX25). 2a is a methyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX26).2a is an ethyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX27). 2a and R 2b is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX28).

[0111] Formula (L-5) In the compound represented by the formula (hereinafter referred to as compound (L-5)), R 2a and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX29). 2a is a methyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX30). 2a is an ethyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX31). 2a and R 2b is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX32).

[0112] Formula (L-6) In the compound represented by the formula (hereinafter referred to as compound (L-6)), R 2a and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX33). 2a is a methyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX34). 2a is an ethyl group, and R2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX35). 2a and R 2b is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX36).

[0113] Formula (L-9) In the compound represented by the formula (hereinafter referred to as compound (L-9)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX37).

[0114]

[0115]

[0116] In compound (L-9), R 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX38). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX39). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3bis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX40). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX41). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX42). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX43). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX44). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX45). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3bis a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX46). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX47). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX48). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX49). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX50). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX51). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3dis a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX52).

[0117] Formula (L-10) In the compound represented by the formula (hereinafter referred to as compound (L-10)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX53). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX54). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX55). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX56). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX57). 2a is a methyl group, and R2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX58). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX59). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX60). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX61). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX62). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX63).2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX64). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX65). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX66). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX67). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX68).

[0118] Formula (L-11) In the compound represented by the formula (hereinafter referred to as compound (L-11)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX69). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX70). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX71). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX72). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX73). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX74). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX75). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX76). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX77). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX78). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX79). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX80). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX81). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX82). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX83). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX84).

[0119] Formula (L-12) In the compound represented by the formula (hereinafter referred to as compound (L-12)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX85). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX86). 2a and R2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX87). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX88). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX89). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX90). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX91). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX92).2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX93). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX94). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX95). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX96). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX97). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX98). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX99). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX100).

[0120] Formula (L-13) In the compound represented by the formula (hereinafter referred to as compound (L-13)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX101). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX102). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX103). 2a and R 2b is a hydrogen atom, and R6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX104). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX105). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX106). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX107). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX108). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX109). 2ais an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX110). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX111). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX112). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX113). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX114). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX115).2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX116).

[0121] Formula (L-14) In the compound represented by the formula (hereinafter referred to as compound (L-14)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX117). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX118). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX119). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX120). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX121). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX122). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX123). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX124). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX125). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX126). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX127). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX128). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX129). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX130). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX131). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX132).

[0122] Formula (L-15) In the compound represented by the formula (hereinafter referred to as compound (L-15)), R2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX137). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX138). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX139). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX140). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX141). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX142). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX143). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX144). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX145). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX146). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX147). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX148). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX149). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX150). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX151). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX152).

[0123] Formula (L-16) In the compound represented by the formula (hereinafter referred to as compound (L-16)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX153). 2aand R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX154). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX155). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX156). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX157). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX158). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX159).2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX160). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX161). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX162). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX163). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX164). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX165). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX166). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX167). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX168).

[0124] Formula (L-17) In the compound represented by the formula (hereinafter referred to as compound (L-17)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX169). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX170). 2a and R 2b is a hydrogen atom, and R6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX171). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX172). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX173). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX174). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX175). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX176). 2a is an ethyl group, and R2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX177). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX178). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX179). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX180). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX181). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX182).2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX183). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX184).

[0125] Formula (L-18) In the compound represented by the formula (hereinafter referred to as compound (L-18)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX185). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX186). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX187). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3bis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX188). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX189). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX190). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX191). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX192). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX193). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX194). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX195). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX196). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX197). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX198). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX199). 2a and R 2b is a methyl group, and R 6is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents listed in [Table 7A] to [Table 15A] (hereinafter referred to as compound group SX200).

[0126] Formula (L-19) In the compound represented by the formula (hereinafter referred to as compound (L-19)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX201). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX202). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX203). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX204). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX205). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX206). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX207). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX208). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX209). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX210). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX211). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX212). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX213). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX214). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX215). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX216).

[0127] Formula (L-20) In the compound represented by the formula (hereinafter referred to as compound (L-20)), R2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX217). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX218). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX219). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX220). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX221). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX222). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX223). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX224). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX225). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX226). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX227). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX228). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX229). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX230). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX231). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX232).

[0128] Formula (L-21) In the compound represented by the formula (hereinafter referred to as compound (L-21)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX233). 2a and R 2bis a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX234). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX235). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX236). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX237). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX238). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX239). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX240).

[0129] Formula (L-22) In the compound represented by the formula (hereinafter referred to as compound (L-22)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX241). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX242). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX243). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX244). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX245). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX246). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX247). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX248).

[0130] Formula (L-23) In the compound represented by the formula (hereinafter referred to as compound (L-23)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX249). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX250). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX251). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX252). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX253). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX254). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX255). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX256).

[0131] Formula (L-24) In the compound represented by the formula (hereinafter referred to as compound (L-24)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX257). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX258). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX259).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX260). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX261). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX262). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX263). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX264).

[0132] Formula (L-25) In the compound represented by the formula (hereinafter referred to as compound (L-25)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX265). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX266). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX267). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX268). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX269). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX270). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX271). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX272).

[0133] Formula (L-26) In the compound represented by the formula (hereinafter referred to as compound (L-26)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX273). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX274). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX275). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX276). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX277). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX278). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX279). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX280).

[0134] Formula (L-27) In the compound represented by the formula (hereinafter referred to as compound (L-27)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX281). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX282). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX283). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX284). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX285). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX286). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX287). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX288).

[0135] Formula (L-28) In the compound represented by the formula (hereinafter referred to as compound (L-28)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX289). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX290). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX291).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX292). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX293). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX294). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX295). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX296).

[0136] Formula (L-29) In the compound represented by the formula (hereinafter referred to as compound (L-29)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX297). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX298). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX299). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX300). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX301). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX302). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX303). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX304).

[0137] Formula (L-30) In the compound represented by the formula (hereinafter referred to as compound (L-30)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX305). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX306). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX307). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX308). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX309). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX310). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX311). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX312).

[0138] Formula (L-31) In the compound represented by the formula (hereinafter referred to as compound (L-31)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX313). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX314). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX315). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX316). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX317). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX318). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX319). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX320).

[0139] Formula (L-32) In the compound represented by the formula (hereinafter referred to as compound (L-32)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX321). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX322). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX323).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX324). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX325). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX326). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX327). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX328).

[0140] Formula (L-33) In the compound represented by the formula (hereinafter referred to as compound (L-33)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX329). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX330). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX331). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX332). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX333). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX334). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX335). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX336).

[0141] Formula (L-34) In the compound represented by the formula (hereinafter referred to as compound (L-34)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX337). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX338). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX339). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX340). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX341). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX342). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX343). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX344).

[0142] Formula (L-35) In the compound represented by the formula (hereinafter referred to as compound (L-35)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX345). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX346). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX347). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX348). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX349). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX350). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX351). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX352).

[0143] Formula (L-36) In the compound represented by the formula (hereinafter referred to as compound (L-36)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX353). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX354). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX355).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX356). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX357). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX358). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX359). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX360).

[0144] Formula (L-37) In the compound represented by the formula (hereinafter referred to as compound (L-37)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX361). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX362). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX363). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX364). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX365). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX366). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX367). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX368).

[0145] Formula (L-38) In the compound represented by the formula (hereinafter referred to as compound (L-38)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX369). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX370). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX371). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX372). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX373). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX374). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX375). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX376).

[0146] Formula (L-39) In the compound represented by the formula (hereinafter referred to as compound (L-39)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX377). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX378). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX379). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX380). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX381). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX382). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX383). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX384).

[0147] Formula (L-40) In the compound represented by the formula (hereinafter referred to as compound (L-40)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX385). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX386). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX387).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX388). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX389). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX390). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX391). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX392).

[0148] Formula (L-41) In the compound represented by the formula (hereinafter referred to as compound (L-41)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX393). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX394). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX395). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX396). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX397). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX398). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX399). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX400).

[0149] Formula (L-42) In the compound represented by the formula (hereinafter referred to as compound (L-42)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX401). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX402). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX403). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX404). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX405). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX406). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX407). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX408).

[0150] Formula (L-43) In the compound represented by the formula (hereinafter referred to as compound (L-43)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX409). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX410). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX411). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX412). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX413). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX414). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX415). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX416).

[0151] Formula (L-44) In the compound represented by the formula (hereinafter referred to as compound (L-44)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX417). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX418). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX419).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX420). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX421). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX422). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX423). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX424).

[0152] Formula (L-45) In the compound represented by the formula (hereinafter referred to as compound (L-45)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX425). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX426). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX427). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX428). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX429). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX430). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX431). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX432).

[0153] Formula (L-46) In the compound represented by the formula (hereinafter referred to as compound (L-46)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX433). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX434). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX435). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX436). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX437). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX438). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX439). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX440).

[0154] Formula (L-47) In the compound represented by the formula (hereinafter referred to as compound (L-47)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX441). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX442). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX443). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX444). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX445). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX446). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX447). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX448).

[0155] Formula (L-48) In the compound represented by the formula (hereinafter referred to as compound (L-48)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX449). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX450). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX451).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX452). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX453). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX454). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX455). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX456).

[0156] Formula (L-49) In the compound represented by the formula (hereinafter referred to as compound (L-49)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX457). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX458). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX459). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX460). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX461). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX462). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX463). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX464).

[0157] Formula (L-50) In the compound represented by the formula (hereinafter referred to as compound (L-50)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX501). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX502). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX503). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX504). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX505). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX506). 2a and R 2b is a methyl group, and R 6 is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX507). 2a and R 2b is a methyl group, and R6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX508).

[0158] Formula (L-51) In the compound represented by the formula (hereinafter referred to as compound (L-51)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX509). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX510). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX511). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX512). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX513). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX514). 2a and R 2b is a methyl group, and R 6is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX515). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX516).

[0159] Formula (L-52) In the compound represented by the formula (hereinafter referred to as compound (L-52)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX517). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX518). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX519). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX520). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX521). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX522). 2a and R 2b is a methyl group, and R 6 is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX523). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX524).

[0160] Formula (L-53) In the compound represented by the formula (hereinafter referred to as compound (L-53)), R 2a and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX525). 2a is a methyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX526). 2a is an ethyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX527). 2a and R 2b is a methyl group, and T is any of the substituents listed in Tables 1A to 6A (hereinafter referred to as compound group SX528).

[0161] Formula (L-54) In the compound represented by the formula (hereinafter referred to as compound (L-54)), R 2a and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX529).2a is a methyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX530). 2a is an ethyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX531). 2a and R 2b is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX532).

[0162] Formula (L-55) In the compound represented by the formula (hereinafter referred to as compound (L-55)), R 2a and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX533). 2a is a methyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX534). 2a is an ethyl group, and R 2b is a hydrogen atom, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX535). 2a and R 2b is a methyl group, and T is any of the substituents shown in Tables 1A to 6A (hereinafter referred to as compound group SX536).

[0163] Formula (L-56) In the compound represented by the formula (hereinafter referred to as compound (L-56)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX537). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX538). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX539). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX540). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX541). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX542). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX543). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX544). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX545). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX546). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX547). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX548). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX549). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX550). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX551). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX552).

[0164] Formula (L-57) In the compound represented by the formula (hereinafter referred to as compound (L-57)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX553). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX554). 2aand R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX555). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX556). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX557). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX558). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX559). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3bis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX560). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX561). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX562). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX563). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX564). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX565). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3bis a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX566). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX567). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX568).

[0165] Formula (L-58) In the compound represented by the formula (hereinafter referred to as compound (L-58)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX569). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX570). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX571). 2a and R2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX572). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX573). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX574). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX575). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX576). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX577). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX578). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX579). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX580). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX581). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX582). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX583). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX584).

[0166] Formula (L-59) In the compound represented by the formula (hereinafter referred to as compound (L-59)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX585). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX586). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX587). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX588). 2a is a methyl group, and R 2bis a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX589). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX590). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX591). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX592). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX593). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX594).2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX595). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX596). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX597). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX598). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX599). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX600).

[0167] Formula (L-60) In the compound represented by the formula (hereinafter referred to as compound (L-60)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX601). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX602). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX603). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX604). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX605). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX606). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX607). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX608). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX609). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX610). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX611). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX612). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX613). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX614). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX615). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX616).

[0168] Formula (L-61) In the compound represented by the formula (hereinafter referred to as compound (L-61)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX617). 2aand R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX618). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX619). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX620). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX621). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX622). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX623).2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX624). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX625). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX626). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX627). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX628). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX629). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX630). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX631). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX632).

[0169] Formula (L-62) In the compound represented by the formula (hereinafter referred to as compound (L-62)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX637). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX638). 2a and R 2b is a hydrogen atom, and R6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX639). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX640). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX641). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX642). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX643). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX644). 2a is an ethyl group, and R2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX645). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX646). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX647). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX648). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX649). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX650).2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX651). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX652).

[0170] Formula (L-63) In the compound represented by the formula (hereinafter referred to as compound (L-63)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX653). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX654). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX655). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3bis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX656). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX657). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX658). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX659). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX660). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX661). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX662). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX663). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX664). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX665). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX666). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX667). 2a and R 2b is a methyl group, and R 6is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX668).

[0171] Formula (L-64) In the compound represented by the formula (hereinafter referred to as compound (L-64)), R 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX669). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX670). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX671). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX672). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX673). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX674). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX675). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX676). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX677). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX678). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX679). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX680). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX681). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX682). 2a and R 2b is a methyl group, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX683). 2a and R 2b is a methyl group, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX684).

[0172] Formula (L-65) In the compound represented by the formula (hereinafter referred to as compound (L-65)), R2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX685). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX686). 2a and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX687). 2a and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX688). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX689). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX690). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX691). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX692). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX693). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6 is an ethyl group, and R 3b is a hydrogen at...

Claims

1. Equation (I) 【Chemistry 1】 [During the ceremony, Q is expressed by the following formula 【Chemistry 2】 This represents the group shown in formula Q1, the group shown in formula Q2, the group shown in formula Q3, the group shown in formula Q4, the group shown in formula Q5, the group shown in formula Q6, or the group shown in formula Q7 (# represents a bonding site with a sulfur atom, and ● represents a bonding site with Het). 【Transformation 3】 A 1 NR 5 , representing an oxygen atom or a sulfur atom, G 1 G 2 G 3 and G 4 The combination is, G 1 is a nitrogen atom or CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c a combination; G 1 CR 3a G 2 is a nitrogen atom, G 3 CR 3d G 4 CR 3c The combinations that are; G 1 CR 3a G 2 CR 3b G 3 is a nitrogen atom, G 4 CR 3c The combination is; or G 1 CR 3a G 2 CR 3b G 3 CR 3d G 4 This represents a combination where the atom is a nitrogen atom. R 2a and R 2b This represents a C1-C6 alkyl group, a C3-C6 cycloalkyl group, or a hydrogen atom, which may be the same or different in phase and may be substituted with one or more halogen atoms. R 2a and R 2b These may, together with the nitrogen atom to which they are bonded, form an azilidinyl group, an azetidinyl group, a pyrrolidinyl group, or a piperidyl group. R 3a 、R 3b 、R 3c 、R 3d 、R 3f 、R 3g 、R 3i and R 3k are the same or different and may be substituted with one or more substituents selected from Group B, a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from Group E, a C3-C7 cycloalkyl group which may be substituted with one or more substituents selected from Group H, a phenyl group which may be substituted with one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group H, OR 12 、NR 11 R 12 、NR 11a R 12a 、NR 24 NR 11 R 12 、NR 24 OR 11 、NR 11 C(O)R 13 、NR 24 NR 11 C(O)R 13 、NR 11 C(O)OR 14 ​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​​ 17 , S(O) q R 23 , represents a cyano group, a nitro group, a hydrogen atom, or a halogen atom, R 3e and R 3h This represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from group H, When Q is a group represented by formula Q1, R 3a , R 3b and R 3d Among two adjacent substituents, together with the two carbon atoms to which they are attached, form a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring may be substituted with one or more substituents selected from group H}, or a triazole ring which may be substituted with one or more substituents selected from group I may be formed. p represents 0 or 1, q represents 0, 1, or 2. R 30 This is a C1-C6 chain hydrocarbon group, a halogen atom, OR which may be substituted with one or more halogen atoms. 35 , NR 36 R 37 , or representing a hydrogen atom, R 17 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group D, or a hydrogen atom. R 12 This may be a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group substituted with one or more substituents selected from group J, a C3-C7 cycloalkenyl group substituted with one or more substituents selected from group J, a phenyl group substituted with one or more substituents selected from group D, a 6-membered aromatic heterocyclic group substituted with one or more substituents selected from group D, a hydrogen atom, or S(O) 2 R 23 This represents, R 23 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from group D. R 11a and R 12a This represents a 3-7 member non-aromatic heterocyclic group which, together with the nitrogen atom to which they are bonded, may be substituted with one or more substituents selected from group E. R 13 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group D, a 5 or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group D, or a hydrogen atom. R 14 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl) C1-C3 alkyl group which may be substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl portion of the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from group D}. R 15 and R 16 This represents a C1-C6 alkyl group that is the same or different in phase and may be substituted with one or more halogen atoms. R 31 This represents a C1-C6 alkyl group or hydrogen atom which may be substituted with one or more halogen atoms. R 32 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group which may be substituted with one or more substituents selected from group J, or a hydrogen atom. Het represents the group shown in formula Het1, formula Het2, formula Het3, formula Het4, formula Het5, formula Het6, or formula Het7. 【Chemistry 4】 A 2 is a nitrogen atom or CR 4a This represents, A 3 is a nitrogen atom or CR 4b This represents, A 4 is a nitrogen atom or CR 4c This represents, W 1 This represents an oxygen atom or a sulfur atom, If Het is a group represented by formula Het5 or formula Het6, A 2 and A 3 The combination is, A 2 CR 4a A 3 is a nitrogen atom or CR 4b A combination that is; or, A 2 A is a nitrogen atom, 3 CR 4b This represents a combination of the following: B 1 , B 2 and B 3 The combination is, B 1 CR 6e B 2 is a nitrogen atom or CR 6b B 3 is a nitrogen atom or CR 6c The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 CR 6e B 3 is a nitrogen atom or CR 6c The combination is; or B 1 is a nitrogen atom or CR 6a B 2 is a nitrogen atom or CR 6b B 3 CR 6e This represents a combination of the following: If Het is the base represented by formula Het7, A 2 and A 3 The combination is, A 2 CR 4a A 3 is a nitrogen atom or CR 4b A combination that is; or, A 2 A is a nitrogen atom, 3 is a nitrogen atom or CR 4b This represents a combination of the following: B 1 , B 2 , B 3 and B 4 The combination is, B 1 is a nitrogen atom or CR 6a B 2 CR 6e B 3 is a nitrogen atom or CR 6c B 4 is a nitrogen atom or CR 6d The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 is a nitrogen atom or CR 6b B 3 CR 6e B 4 is a nitrogen atom or CR 6d The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 is a nitrogen atom or CR 6b B 3 CR 6c B 4 CR 6e The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 CR 6b B 3 is a nitrogen atom, B 4 CR 6e The combination is; or B 1 CR 6a B 2 is a nitrogen atom, B 3 is a nitrogen atom, B 4 CR 6e This represents a combination of the following: R 4a , R 4b , R 4c , R 6a , R 6b , R 6c , R 6d These are C1-C6 chain hydrocarbon groups, nitro groups, OR which may be the same or different in phase and substituted with one or more halogen atoms. 18 , NR 18 R 19 , represents a cyano group, an amino group, a halogen atom, or a hydrogen atom, R 6e This includes a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms, a C3-C4 cycloalkyl group which may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms, and S(O). m R 7 , OR 7 , halogen atom, or OS(O) 2 R 7 This represents, R 6 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group F, a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from group J, a phenyl group which may be substituted with one or more substituents selected from group H, or a 5 or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group H. T is a C1-C10 chain hydrocarbon group, (C1-C5 alkoxy)C2-C5 alkyl group, (C3-C5 alkenyloxy)C2-C5 alkyl group, (C3-C5 alkynyloxy)C2-C5 alkyl group, (C1-C5 alkyl)-S(O) w - (C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) w - (C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) w - (C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) w - (C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) w - (C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) w - (C2-C5 alkyl) group, and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group are substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms, (C3-C7 cycloalkyl) C1-C3 alkyl group substituted with one or more substituents selected from group G, C3-C7 cycloalkyl group substituted with one or more substituents selected from group G, OR 1 , S(O) v R 1 OS(O) 2 R 1 ,CH 2 OR 1 , NR 1 R 29 , C(O)R 1 , C(O)NR 1 R 29 , NR 29 C(O)R 1 N=CR 1 R 30 , represents the group represented by formula T-1, the group represented by formula T-2, the group represented by formula T-3, the group represented by formula T-4, the group represented by formula T-5, the group represented by formula T-6, the group represented by formula T-7, the group represented by formula T-8, the group represented by formula T-9, the group represented by formula T-10, the group represented by formula T-11, or the group represented by formula T-12. 【Transformation 5】 【Transformation 6】 【Transformation 7】 X 1 is a nitrogen atom or CR 1a This represents, X 2 is a nitrogen atom or CR 1b This represents, X 3 is a nitrogen atom or CR 1c This represents, X 4 is a nitrogen atom or CR 1d This represents, X 5 is a nitrogen atom or CR 1e This represents, R 1x OR is a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms. 7 OS(O) 2 R 7 , S(O) m R 7 , NR 8 S(O) 2 R 7 , or representing a halogen atom, R 1a , R 1b , R 1c , R 1d and R 1e This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, which may be the same or different in phase. Y 1 NR 25 , representing an oxygen atom or a sulfur atom, Y 2 is a nitrogen atom or CR 26 This represents, Y 3 is a nitrogen atom or CR 27 This represents, Y 4 is a nitrogen atom or CR 28 This represents, R 5 and R 25 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C6 alkoxy group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. R 26 , R 27 and R 28 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, a halogen atom, or a hydrogen atom, which may be the same or different in phase. R 1y OR is a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms. 7 OS(O) 2 R 7 , S(O) m R 7 , NR 8 S(O) 2 R 7 , represents a cyano group or a halogen atom, R 1ay and R 7 This represents a C1-C6 chain hydrocarbon group that is identical or different in phase and substituted with one or more halogen atoms. m and v are the same or different, and represent 0, 1, or 2. w and t are the same or different, and represent 0, 1, or 2. R 1 This refers to a C1-C10 chain hydrocarbon group, (C1-C5 alkoxy)C2-C5 alkyl group, (C3-C5 alkenyloxy)C2-C5 alkyl group, (C3-C5 alkynyloxy)C2-C5 alkyl group, and (C1-C5 alkyl)-S(O). t - (C2-C5 alkyl) group, (C3-C5 alkenyl)-S(O) t - (C2-C5 alkyl) group, (C3-C5 alkynyl)-S(O) t - (C2-C5 alkyl) group, (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group {the C1-C10 chain hydrocarbon group, the (C1-C5 alkoxy)C2-C5 alkyl group, the (C3-C5 alkenyloxy)C2-C5 alkyl group, the (C3-C5 alkynyloxy)C2-C5 alkyl group, the (C1-C5 alkyl)-S(O) t - (C2-C5 alkyl) group, the (C3-C5 alkenyl)-S(O) t - (C2-C5 alkyl) group, the (C3-C5 alkynyl)-S(O) t The (C2-C5 alkyl) group and the (C1-C5 alkyl)-C(O)-(C1-C5 alkyl) group are substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group substituted with one or more substituents selected from group G, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from group G. R 18 and R 35 This represents a C1-C6 chain hydrocarbon group that is identical or different in phase and may be substituted with one or more halogen atoms. R 8 , R 11 , R 19 , R 24 , R 29 , R 36 and R 37 This represents a C1-C6 chain hydrocarbon group, which may be the same or different in phase and may be substituted with one or more halogen atoms, or a hydrogen atom. Group B: A group consisting of C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted with one or more halogen atoms, C1-C6 alkylsulfanyl groups which may be substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups which may be substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups which may be substituted with one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted with one or more halogen atoms, cyano groups, hydroxyl groups, and halogen atoms. Group C: A group consisting of C1-C6 chain hydrocarbon groups which may be substituted with one or more halogen atoms, C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted with one or more halogen atoms, and halogen atoms. Group D: C1-C6 chain hydrocarbon groups that may be substituted with one or more halogen atoms, hydroxyl groups, C1-C6 alkoxy groups that may be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups that may be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups that may be substituted with one or more halogen atoms, sulfanyl groups, C1-C6 alkylsulfanyl groups that may be substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups that may be substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups that may be substituted with one or more halogen atoms, amino groups, NHR 21 , NR 21 R 22 , C(O)R 21 OC(O)R 21 , C(O)OR 21 A group consisting of cyano groups, nitro groups, and halogen atoms. R 21 and R 22 This represents a C1-C6 alkyl group that is the same or different in phase and may be substituted with one or more halogen atoms. Group E: A group consisting of C1-C6 chain hydrocarbon groups which may be substituted with one or more halogen atoms, C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted with one or more halogen atoms, halogen atoms, oxo groups, hydroxyl groups, cyano groups, and nitro groups. Group F: C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, phenyl groups which may be substituted with one or more substituents selected from Group D, 5 or 6-membered aromatic heterocyclic groups which may be substituted with one or more substituents selected from Group D, C3-C7 cycloalkyl groups which may be substituted with one or more halogen atoms, 3-7 membered non-aromatic heterocyclic groups which may be substituted with one or more substituents selected from Group C, amino groups, NHR 21 , NR 21 R 22 A group consisting of halogen atoms and cyano groups. Group G: A group consisting of halogen atoms, C1-C6 haloalkyl groups, and cyano groups. Group H: C1-C6 alkyl groups, OR which may be substituted with one or more halogen atoms. 10 , NR 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 OC(O)R 9 , OC(O)OR 9 , NR 10 C(O)R 9 , NR 10 C(O)OR 9 , C(O)OR 10 A group consisting of halogen atoms, nitro groups, cyano groups, amino groups, and five- or six-membered aromatic heterocyclic groups. R 9 This represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms. R 10 This represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. Group I: A group consisting of C2-C6 chain hydrocarbon groups which may be substituted with one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted with one or more halogen atoms, phenyl groups which may be substituted with one or more substituents selected from Group D, 5 or 6-membered aromatic heterocyclic groups which may be substituted with one or more substituents selected from Group D, C2-C6 alkylcarbonyl groups which may be substituted with one or more halogen atoms, C2-C6 alkoxycarbonyl groups which may be substituted with one or more halogen atoms, aminocarbonyl groups, (C1-C6 alkyl)aminocarbonyl groups which may be substituted with one or more halogen atoms, methyl groups, and di(C1-C4 alkyl)aminocarbonyl groups which may be substituted with one or more halogen atoms. Group J: A group consisting of C1-C6 alkyl groups, halogen atoms, and cyano groups, which may be substituted with one or more halogen atoms. The compound shown or its N oxide.

2. The compound according to claim 1, or its N oxide, wherein Q is a group represented by formula Q1 or a group represented by formula Q5.

3. The compound according to claim 1, or its N oxide, wherein Q is the group represented by formula Q5.

4. G 1 CR 3a G 2 CR 3b G 3 CR 3d G 4 CR 3c The compound or its N oxide according to claim 3.

5. Het is the group represented by formula Het1, and A 2 CR 4a A 3 CR 4b The compound according to any one of claims 1 to 4, or its N oxide, which is a nitrogen atom.

6. Het is the group represented by formula Het5, and A 2 CR 4a A 3 CR 4b B 1 CR 6a B 2 CR 6e B 3 The compound according to any one of claims 1 to 4, or its N oxide, wherein is a nitrogen atom.

7. Het is the group represented by formula Het7, and A 2 CR 4a A 3 is a nitrogen atom, B 1 CR 6a B 2 CR 6e B 3 CR 6c B 4 CR 6d The compound according to any one of claims 1 to 4 or its N oxide.

8. A pest control composition comprising a compound according to any one of claims 1 to 4 or its N oxide and an inert carrier.

9. A composition containing one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and the compound described in any of claims 1 to 4 or its N oxide: Group (a): A group consisting of insecticidal components, acaricidal components, and nematicidal components; Group (b): bactericidal active ingredient; Group (c): plant growth regulating ingredients; Group (d): Repellent components.

10. A method for controlling harmful arthropods, comprising applying an effective amount of the compound or its N oxide described in any one of claims 1 to 4 to a harmful arthropod or to the habitat of a harmful arthropod.

11. A method for controlling harmful arthropods, comprising applying an effective amount of the composition described in Claim 9 to a harmful arthropod or to a habitat of a harmful arthropod.

12. Seeds or vegetative reproductive organs that retain an effective amount of the compound or its N oxide according to any one of claims 1 to 4.

13. A seed or vegetative reproductive organ holding an effective amount of the composition described in Claim 9.

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