Sulfonamide composition and harmful-arthropod control composition containing same
Patent Information
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Filing Date
- 2023-10-13
- Publication Date
- 2026-08-05
AI Technical Summary
Current compounds for controlling harmful arthropods do not offer excellent control efficacy, necessitating the development of a more effective compound for pest management.
A sulfonamide compound represented by Formula (I), which includes specific structural groups and substituents, is discovered to exhibit excellent control effects on harmful arthropods, and can be used in a composition with an inert carrier for application against arthropod pests.
The sulfonamide compound effectively controls harmful arthropods, providing a composition that can be applied to pests or their habitats, offering improved pest management compared to existing solutions.
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Abstract
Description
Sulfonamide compound and pest control composition containing the same
[0001] This patent application claims priority under the Paris Convention to and the benefit of Japanese Patent Application No. 2022-165233 (filed October 14, 2022), the entire contents of which are incorporated herein by reference. The present invention relates to sulfonamide compounds and arthropod pest control compositions containing the same.
[0002] Various compounds have been investigated so far for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes that certain compounds have a pest control effect.
[0003] International Publication No. 2020 / 158889
[0004] An object of the present invention is to provide a compound having excellent control activity against arthropod pests.
[0005] The present inventors have conducted research to find a compound having excellent control activity against harmful arthropods, and have found that a compound represented by the following formula (I) has excellent control activity against harmful arthropods. That is, the present invention is as follows: [1] Formula (I) [Wherein, Q represented by the following formula represents a group represented by formula Q1, a group represented by formula Q2, a group represented by formula Q3, a group represented by formula Q4, a group represented by formula Q5, a group represented by formula Q6, or a group represented by formula Q7 (# represents a bonding site to a sulfur atom, and ● represents a bonding site to Het), A 1 is NR 5 , an oxygen atom or a sulfur atom; 1 , G 2 , G 3 and G 4 The combination of 1 is a nitrogen atom or CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3cA combination in which: 1 is CR 3a and G 2 is a nitrogen atom, and G 3 is CR 3d and G 4 is CR 3c A combination in which: 1 is CR 3a and G 2 is CR 3b and G 3 is a nitrogen atom, and G 4 is CR 3c or a combination 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 represents a combination in which R is a nitrogen atom; 2a and R 2b are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b may be taken together with the nitrogen atom to which they are attached to form an aziridinyl group, an azetidinyl group, a pyrrolidinyl group, or a piperidyl group; R 3a , R 3b , R 3c , R 3d , R 3f , R 3g , R 3i and R 3k are the same or different and each represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group E, a phenyl group optionally substituted with one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group H, OR 12 , N.R. 11 R 12 , N.R. 11a R 12a , N.R. 24NR 11 R 12 , N.R. 24 OR 11 , N.R. 11 C(O)R 13 , N.R. 24 NR 11 C(O)R 13 , N.R. 11 C(O)OR 14 , N.R. 24 NR 11 C(O)OR 14 , N.R. 11 C(O)NR 31 R 32 , N.R. 24 NR 11 C(O)NR 31 R 32 , N=CHNR 31 R 32 , N=S(O) p R 15 R 16 , C(O)R 13 , C(O)OR 17 , C(O)NR 31 R 32 , C(O)NR 11 S(O)2R 23 , C.R. 30 = NOR 17 , N.R. 11 CR 24 = NOR 17 , S(O) q R 23 , a cyano group, a nitro group, a hydrogen atom, or a halogen atom; R 3e and R 3h are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a phenyl group optionally substituted with one or more substituents selected from group H, and when Q is a group represented by formula Q1, R 3a , R 3b and R 3dtwo adjacent substituents among the following may, together with the two carbon atoms to which they are bonded, form a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring or a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring and the pyrazine ring are optionally substituted with one or more substituents selected from Group H} or a triazole ring optionally substituted with one or more substituents selected from Group I, p represents 0 or 1, q represents 0, 1 or 2, R 30 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, OR 35 , N.R. 36 R 37 or a hydrogen atom, R 17 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, or a hydrogen atom; R 12 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J, a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from Group J, a phenyl group optionally substituted with one or more substituents selected from Group D, a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a hydrogen atom, or S(O)R 23 represents R 23 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a phenyl group optionally substituted with one or more substituents selected from Group D, R 11a and R 12atogether with the nitrogen atom to which they are attached form a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group E, R 13 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, or a hydrogen atom; R 14 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group (the phenyl moiety in the phenyl C1-C3 alkyl group optionally substituted with one or more substituents selected from Group D), R 15 and R 16 are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms; R 31 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 32 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group J, or a hydrogen atom, Het represents a group represented by formula Het5, a group represented by formula Het6, or a group represented by formula Het7, A 2 is NR 5a , or CR 4a R 4d represents, 3 is CR 4b R 4e represents, 4 is NR 5b , or CR 4c R 4f represents W 1represents an oxygen atom or a sulfur atom, and when Het is a group represented by the formula Het5, B 1 , B 2 and B 3 The combination is B 1 is CR 6e and B 2 is a nitrogen atom or CR 6b and B 3 is a nitrogen atom or CR 6c A combination in which: 1 is a nitrogen atom or CR 6a and B 2 is CR 6e and B 3 is a nitrogen atom or CR 6c or B 1 is a nitrogen atom or CR 6a and B 2 is a nitrogen atom or CR 6b and B 3 is CR 6e When Het is a group represented by the formula Het6, 2 and A 4 The combination is A 2 is CR 4a R 4d and A 4 NR 5b or CR 4c R 4f or a combination 2 NR 5a and A 4 is CR 4c R 4f A combination in which: 1 , B 2 and B 3 The combination is B 1 is CR 6e and B 2 is a nitrogen atom or CR 6b and B 3 is a nitrogen atom or CR 6c A combination in which: 1 is a nitrogen atom or CR 6a and B 2 is CR 6e and B 3is a nitrogen atom or CR 6c or B 1 is a nitrogen atom or CR 6a and B 2 is a nitrogen atom or CR 6b and B 3 is CR 6e When Het is a group of formula Het7, then A 2 and A 4 The combination is A 2 is CR 4a R 4d and A 4 NR 5b or CR 4c R 4f or a combination 2 NR 5a and A 4 is CR 4c R 4f A combination in which: 1 , B 2 , B 3 and B 4 The combination is B 1 is a nitrogen atom or CR 6a and B 2 is CR 6e and B 3 is a nitrogen atom or CR 6c and B 4 is a nitrogen atom or CR 6d A combination in which: 1 is a nitrogen atom or CR 6a and B 2 is a nitrogen atom or CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom or CR 6d A combination in which: 1 is a nitrogen atom or CR 6a and B 2 is a nitrogen atom or CR 6b and B 3 is CR 6c and B 4 is CR 6e A combination in which: 1is a nitrogen atom or CR 6a and B 2 is CR 6b and B 3 is a nitrogen atom, and B 4 is CR 6e or B 1 is CR 6a and B 2 is a nitrogen atom, and B 3 is a nitrogen atom, and B 4 is CR 6e R represents a combination where 4a , R 4b , R 4c , R 6a , R 6b , R 6c , and R 6d are the same or different and are each a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a nitro group, OR 18 , N.R. 18 R 19 , a cyano group, an amino group, a halogen atom, or a hydrogen atom; R 4d , R 4e and R 4f are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a cyano group, a halogen atom, or a hydrogen atom; R 6e represents a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 , a halogen atom, or OS(O)R 7 represents R 5 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 5a and R5b are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group K, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 7 represents a C1-C6 chain hydrocarbon group substituted with one or more halogen atoms, m represents 0, 1 or 2, R 18 and R 35 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms; R 11 , R 19 , R 24 , R 36 and R 37are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom. Group B: a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group C: a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, and halogen atoms. Group D: a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, hydroxy groups, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, sulfanyl groups, C1-C6 alkylsulfanyl groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups optionally substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups optionally substituted with one or more halogen atoms, amino groups, NHR 21 , N.R. 21 R 22 , C(O)R 21 , O.C.(O.)R 21 , C(O)OR 21 , a cyano group, a nitro group, and a halogen atom. 21 and R 22are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms. Group E: a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group. Group F: a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group C, an amino group, NHR 21 , N.R. 21 R 22 , a halogen atom, and a cyano group. Group H: a C1-C6 alkyl group optionally substituted with one or more halogen atoms, OR 10 , N.R. 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 , O.C.(O.)R 9 , OC(O)OR 9 , N.R. 10 C(O)R 9 , N.R. 10 C(O)OR 9 , C(O)OR 10 , a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group. 9 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, R 10represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. Group I: a group consisting of a C2-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C2-C6 alkylcarbonyl group optionally substituted with one or more halogen atoms, a C2-C6 alkoxycarbonyl group optionally substituted with one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms. Group J: a group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. Group K: a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, and a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group C.] (hereinafter referred to as Compound N of the Present Invention) or an N-oxide thereof (hereinafter, the compound represented by formula (I) or the N-oxide thereof will be referred to as Compound of the Present Invention). [2] The compound or the N-oxide thereof according to [1], wherein Q is a group represented by formula Q2, a group represented by formula Q3, or a group represented by formula Q4. [3] The compound or the N-oxide thereof according to [1], wherein Q is a group represented by formula Q1 or a group represented by formula Q5. [4] The compound or the N-oxide thereof according to [1], wherein Q is a group represented by formula Q5. [5] Q is a group represented by formula Q5, and G 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G4 is CR 3c [6] The compound according to [1], wherein Q is a group represented by the formula Q5, and G is an N-oxide thereof. 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c and R 3a is a hydrogen atom, and R 3b is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group B, a hydrogen atom, or a halogen atom, and R 3c is a hydrogen atom, and R 3d is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group B, a hydrogen atom, or a halogen atom, or an N-oxide thereof. [7] A compound according to [1], wherein A is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group B, a hydrogen atom, or a halogen atom. 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom. [8] A pest arthropod control composition containing the compound or N-oxide thereof according to any one of [1] to [7] and an inert carrier. [9] A composition containing one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and the compound or N-oxide thereof according to any one of [1] to [7]: Group (a): a group consisting of insecticidal active components, acaricidal active components, and nematicidal active components; Group (b): fungicidal active components; Group (c): plant growth regulator components; Group (d): repellent components.
[10] A method for controlling pest arthropods, comprising applying an effective amount of the compound or N-oxide thereof according to any one of [1] to [7] or an effective amount of the composition according to [9] to pest arthropods or to a habitat of pest arthropods.
[11] A seed or a vegetative reproductive organ carrying an effective amount of the compound according to any one of [1] to [7] or an N-oxide thereof, or an effective amount of the composition according to [9].
[0006] According to the present invention, arthropod pests can be controlled.
[0007] The substituents used in the present invention will be explained. A halogen atom refers to a fluorine atom, chlorine atom, bromine atom, or iodine atom. When a substituent is substituted with two or more halogen atoms or substituents, these halogen atoms or substituents may be the same or different. In this specification, the notation "CX-CY" means that the number of carbon atoms is X to Y. For example, the notation "C1-C6" means that the number of carbon atoms is 1 to 6. The chain hydrocarbon group represents an alkyl group, an alkenyl group, or an alkynyl group. Examples of alkyl groups include a methyl group, an ethyl group, a propyl group, an isopropyl group, a 1,1-dimethylpropyl group, a 1,2-dimethylpropyl group, a 1-ethylpropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group. Examples of alkenyl groups include vinyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl. Examples of alkynyl groups include ethynyl, 1-propynyl, 2-propynyl, 1-methyl-2-propynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-butynyl, 4-pentynyl, and 5-hexynyl. Examples of alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentyloxy, and hexyloxy. Examples of alkenyloxy groups include 2-propenyloxy groups, 2-butenyloxy groups, and 5-hexenyloxy groups. Examples of alkynyloxy groups include 2-propynyloxy groups, 2-butynyloxy groups, and 5-hexynyloxy groups.
[0008] Examples of cycloalkyl groups include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and cycloheptyl groups. Examples of cycloalkenyl groups include cyclopropenyl, cyclobutenyl, cyclopentenyl, cyclohexenyl, and cycloheptenyl groups.
[0009] Examples of the 3- to 7-membered non-aromatic heterocyclic group include an aziridinyl group, an oxiranyl group, a thiiranyl group, an azetidinyl group, an oxetanyl group, a thietanyl group, a pyrrolidinyl group, a tetrahydrofuranyl group, a tetrahydrothienyl group, a piperidyl group, a pyranyl group, a dihydropyranyl group, a tetrahydropyranyl group, a tetrahydrothiopyranyl group, an azepanyl group, an oxepanyl group, a thiepanyl group, a pyrazolinyl group, a pyrazolidinyl group, an imidazolinyl group, an imidazolidinyl group, an oxazolinyl group, a thiazolinyl group, an oxazolidinyl group, a thiazolidinyl group, an isoxazolinyl group, an isoxazolidinyl group, an isothiazolinyl group, an isothiazolidinyl group, a dioxolyl group, a dioxolanyl group, a dioxanyl group, a morpholinyl group, a thiomorpholinyl group, and a piperazinyl group. Examples of the 5- or 6-membered aromatic heterocyclic group include a pyrrolyl group, a furyl group, a thienyl group, a pyrazolyl group, an imidazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, a thiazolyl group, an isothiazolyl group, an oxadiazolyl group, a thiadiazolyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group. Examples of the 6-membered aromatic heterocyclic group include a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group. The (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms refers to a (C3-C6 cycloalkyl) and / or (C1-C3 alkyl) group optionally substituted with one or more halogen atoms, and examples thereof include a cyclopropylmethyl group, a (2-fluorocyclopropyl)methyl group, a cyclopropyl(fluoro)methyl group, and a (2-fluorocyclopropyl)(fluoro)methyl group.The (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms refers to a group in which a (C3-C7 cycloalkyl) and / or a (C1-C6 alkyl) is optionally substituted with one or more halogen atoms, and examples thereof include a (2,2-difluorocyclopropyl)methyl group, a 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, a 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl group, a (2,2-difluorocyclopropyl)propyl group, a (2,2-difluorocyclopropyl)butyl group, a (2,2-difluorocyclopropyl)pentyl group, and a (2,2-difluorocyclopropyl)hexyl group. Examples of the phenyl C1-C3 alkyl group (the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D) include a benzyl group, a 2-fluorobenzyl group, a 4-(difluoromethyl)benzyl group, a 4-fluorobenzyl group, a 4-(trifluoromethyl)benzyl group, and a 2-[4-(trifluoromethyl)phenyl]ethyl group. The alkylsulfanyl group, alkylsulfinyl group, and alkylsulfonyl group are S(O). zrepresents an alkyl group having a moiety represented by the formula:
[0043] Examples of alkylsulfanyl groups in which z is 0 include methylsulfanyl groups, ethylsulfanyl groups, propylsulfanyl groups, and isopropylsulfanyl groups. Examples of alkylsulfinyl groups in which z is 1 include methylsulfinyl groups, ethylsulfinyl groups, propylsulfinyl groups, and isopropylsulfinyl groups. Examples of alkylsulfonyl groups in which z is 2 include methylsulfonyl groups, ethylsulfonyl groups, propylsulfonyl groups, and isopropylsulfonyl groups. Examples of alkylcarbonyl groups include acetyl groups, propanoyl groups, 2-methylpropanoyl groups, and hexanoyl groups. Examples of alkoxycarbonyl groups include methoxycarbonyl groups, ethoxycarbonyl groups, isopropoxycarbonyl groups, and pentyloxycarbonyl groups. Examples of (C1-C6 alkyl)aminocarbonyl groups include methylaminocarbonyl, ethylaminocarbonyl, propylaminocarbonyl, isopropylaminocarbonyl, butylaminocarbonyl, pentylaminocarbonyl, and hexylaminocarbonyl groups. Examples of di(C1-C4 alkyl)aminocarbonyl groups include those in which the two (C1-C4 alkyl) moieties are the same or different, and examples include dimethylaminocarbonyl, diethylaminocarbonyl, dipropylaminocarbonyl, dibutylaminocarbonyl, ethylmethylaminocarbonyl, and ethylisopropylaminocarbonyl groups.
[0010] Examples of the N-oxide of the compound of formula (I) include the compounds of the following formula: (wherein the symbols have the same meanings as defined above.)
[0011] In this specification, when the term "compound of the present invention" is used, the compound of the present invention includes compound N of the present invention unless otherwise specified. The compound of the present invention may exist as one or more stereoisomers. Examples of stereoisomers include enantiomers, diastereomers, and geometric isomers. The compound of the present invention includes each stereoisomer and a mixture of stereoisomers in any ratio.
[0012] The compound of the present invention may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid. The acid addition salt can be obtained by mixing the compound of the present invention with an acid.
[0013] Embodiments of compound N of the present invention include the following compounds. [Aspect 1] A compound of compound N of the present invention, in which Q is a group represented by formula Q2, a group represented by formula Q3, or a group represented by formula Q4. [Aspect 2] A compound of compound N of the present invention, in which Q is a group represented by formula Q1 or a group represented by formula Q5. [Aspect 3] A compound of compound N of the present invention, in which Q is a group represented by formula Q5. [Aspect 4] A compound of compound N of the present invention, in which Q is a group represented by formula Q5, and G 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c [Embodiment 5] In the compound N of the present invention, Q is a group represented by the formula Q5, and G 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c and R 3a is a hydrogen atom, and R 3b is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group B, a hydrogen atom, or a halogen atom, and R 3c is a hydrogen atom, and R 3dis a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group B, a hydrogen atom, or a halogen atom. [Embodiment 6] In compound N of the present invention, Q is a group represented by formula Q5, and G 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c and R 3a is a hydrogen atom, and R 3b is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group B, or a halogen atom, and R 3c is a hydrogen atom, and R 3d is a hydrogen atom. [Embodiment 7] In the compound N of the present invention, Q is a group represented by the formula Q5, and G 1 is CR 3a and G 2 is CR 3b and G 3 is CR 3d and G 4 is CR 3c and R 3a , R 3c , and R 3d is a hydrogen atom, and R 3b is a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group B. [Embodiment 8] A compound of the present invention, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom. [Embodiment 9] In the compound N of the present invention, Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Embodiment 10] In the compound N of the present invention, Het is a group represented by the formula Het5, and A2 is CR 4a R 4d and A 3 is CR 4b R 4e [Embodiment 11] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d [Embodiment 12] In the compound N of the present invention, Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and W 1 is an oxygen atom. [Embodiment 13] In the compound N of the present invention, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom. [Embodiment 14] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 6a , R 6c and R 6d is a hydrogen atom. [Embodiment 15] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6c , and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 16] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 17] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. [Embodiment 18] A compound N of the present invention, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6bA compound in which Het is a group represented by the formula Het5, and A is a hydrogen atom. 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 20] A compound according to aspect 1, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom. [Aspect 21] A compound according to aspect 2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom. [Aspect 22] A compound according to aspect 3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom. [Aspect 23] A compound according to aspect 4, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4dand A 4 NR 5b and W 1 is an oxygen atom. [Aspect 24] The compound according to aspect 5, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom. [Aspect 25] A compound according to aspect 6, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom. [Aspect 26] The compound according to aspect 7, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom. [Aspect 27] A compound according to aspect 1, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect 28] The compound according to aspect 2, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect 29] The compound according to aspect 3, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect 30] A compound according to aspect 4, wherein Het is a group represented by the formula Het6, and A2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect 31] A compound according to aspect 5, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect 32] The compound according to aspect 6, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect 33] The compound according to aspect 7, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect 34] A compound according to aspect 1, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e [Aspect 35] In aspect 2, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e [Aspect 36] In aspect 3, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e[Aspect 37] In aspect 4, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e [Aspect 38] In aspect 5, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e [Aspect 39] In aspect 6, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e [Aspect 40] In aspect 7, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e [Aspect 41] In aspect 1, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4is CR 6d [Aspect 42] In aspect 2, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d [Aspect 43] In aspect 3, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d[Aspect 44] In aspect 4, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d [Aspect 45] In aspect 5, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d[Aspect 46] In aspect 6, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d [Aspect 47] In aspect 7, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d[Aspect 48] In aspect 1, Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 NR 5b or CR 4c R 4f and W 1 is an oxygen atom. [Aspect 49] In aspect 2, Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 NR 5b or CR 4c R 4f and W 1 is an oxygen atom. [Aspect 50] A compound according to aspect 3, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 NR 5b or CR 4c R 4f and W 1 is an oxygen atom. [Aspect 51] A compound according to aspect 4, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 NR 5b or CR 4c R 4f and W 1 is an oxygen atom. [Aspect 52] In aspect 5, Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 NR 5b or CR 4c R 4f and W 1 is an oxygen atom. [Aspect 53] In aspect 6, Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 NR 5b or CR4c R 4f and W 1 is an oxygen atom. [Aspect 54] The compound according to aspect 7, wherein Het is a group represented by the formula Het6, and A 2 is CR 4a R 4d and A 4 NR 5b or CR 4c R 4f and W 1 is an oxygen atom. [Aspect 55] A compound according to aspect 1, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom. [Aspect 56] The compound according to aspect 2, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom. [Aspect 57] The compound according to aspect 3, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom. [Aspect 58] The compound according to aspect 4, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom. [Aspect 59] In aspect 5, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1is an oxygen atom. [Aspect 60] In aspect 6, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom. [Aspect 61] The compound according to aspect 7, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom. [Aspect 62] In aspect 1, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 6a , R 6c , and R 6d is a hydrogen atom. [Aspect 63] The compound according to aspect 2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 6a , R 6c , and R 6dis a hydrogen atom. [Aspect 64] The compound according to aspect 3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 6a , R 6c , and R 6d is a hydrogen atom. [Aspect 65] The compound according to aspect 4, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 6a , R 6c , and R 6d is a hydrogen atom. [Aspect 66] The compound according to aspect 5, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 6a , R 6c , and R 6dis a hydrogen atom. [Aspect 67] The compound according to aspect 6, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 6a , R 6c , and R 6d is a hydrogen atom. [Aspect 68] In aspect 7, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 6a , R 6c , and R 6d is a hydrogen atom. [Aspect 69] In aspect 1, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 4a , R 4d , R 6a , R6c , and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 70] In embodiment 2, Het is a group represented by formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6c , and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 71] The compound according to embodiment 3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 4a , R4d , R 6a , R 6c , and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 72] The compound according to embodiment 4, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6c , and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 73] The compound according to embodiment 5, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6dand R 4a , R 4d , R 6a , R 6c , and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 74] The compound according to embodiment 6, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6c , and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 75] In embodiment 7, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B4 is CR 6d and R 4a , R 4d , R 6a , R 6c , and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 76] In embodiment 1, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 77] In embodiment 2, Het is a group represented by formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 78] In embodiment 3, Het is a group represented by formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 79] In embodiment 4, Het is a group represented by formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 80] The compound according to aspect 5, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 81] The compound according to aspect 6, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6aand B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 82] In aspect 7, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 83] In embodiment 1, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. [Embodiment 84] A compound according to embodiment 2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. [Aspect 85] A compound according to aspect 3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. [Aspect 86] A compound according to aspect 4, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. [Aspect 87] A compound according to aspect 5, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6eis a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. [Aspect 88] A compound according to aspect 6, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. [Aspect 89] A compound according to aspect 7, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 NR 5b and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom. [Aspect 90] A compound according to aspect 1, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4dand A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom. [Aspect 91] In aspect 2, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom. [Aspect 92] In aspect 3, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom. [Aspect 93] The compound according to aspect 4, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom. [Aspect 94] In aspect 5, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom. [Aspect 95] The compound according to aspect 6, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom. [Aspect 96] The compound according to aspect 7, wherein Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom. [Aspect 97] In aspect 1, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 98] In aspect 2, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R4d , R 4e and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 99] In aspect 3, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 100] In aspect 4, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6bis a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 101] In aspect 5, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 102] In aspect 6, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom, and R 6ea C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect 103] In aspect 7, Het is a group represented by the formula Het5, and A 2 is CR 4a R 4d and A 3 is CR 4b R 4e and W 1 is an oxygen atom, and B 1 is CR 6e and B 2 is CR 6b and B 3 is a nitrogen atom, and R 4a , R 4b , R 4d , R 4e and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Embodiment 104] In any one of embodiments 1 to 103 or compound N of the present invention, R 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b are taken together with the nitrogen atom to which they are attached to form a pyrrolidinyl group or a piperidyl group. [Embodiment 105] In any of embodiments 1 to 103 or compound N of the present invention, R 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms or a hydrogen atom, or R 2a and R2b are taken together with the nitrogen atom to which they are attached to form a pyrrolidinyl group or a piperidyl group. [Embodiment 106] In any of embodiments 1 to 103 or compound N of the present invention, R 2a and R 2b are the same or different and are C1-C6 alkyl groups optionally substituted with one or more halogen atoms.
[0014] [Aspect A1] A compound of the present invention N, in which Q is a group represented by the formula Q1. [Aspect A2] A compound of the present invention N, in which Q is a group represented by the formula Q1, and R 3a is a hydrogen atom, and R 3b a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more halogen atoms, OR 12 , a hydrogen atom, or a halogen atom; R 12 is a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, and R 3d is a hydrogen atom. [Aspect A3] In the compound N of the present invention, Q is a group represented by the formula Q1, and R 3a is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is a hydrogen atom. [Aspect A4] Compound N of the present invention, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect A5] Compound N of the present invention, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 , B 2, B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom; B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom; or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d [Aspect A6] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 6a and R 6c is a hydrogen atom. [Aspect A7] A compound of the present invention, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3is CR 6c and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6c is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A8] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6c is a hydrogen atom, and R 6e is a halogen atom. [Aspect A9] Compound N of the present invention, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 6aand R 6b is a hydrogen atom. [Aspect A10] Compound N of the present invention, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A11] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6b is a hydrogen atom, and R 6eis a halogen atom. [Aspect A12] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 6a , R 6b and R 6d is a hydrogen atom. [Aspect A13] Compound N of the present invention, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 4c , R 4f , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A14] In the compound N of the present invention, Het is a group represented by the formula Het7, and A 2 is CR 4a R4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 4c , R 4f , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a halogen atom. [Aspect A15] A compound according to aspect A1, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect A16] A compound according to aspect A1, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom; B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4is a nitrogen atom; or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d [Aspect A17] In aspect A1, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 6a and R 6c is a hydrogen atom. [Aspect A18] A compound according to aspect A1, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6c is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7or a halogen atom. [Aspect A19] A compound in which Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6c is a hydrogen atom, and R 6e is a halogen atom. [Aspect A20] A compound according to aspect A1, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 6a and R 6b is a hydrogen atom. [Aspect A21] A compound according to aspect A1, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6eand B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A22] A compound in which Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6b is a hydrogen atom, and R 6e is a halogen atom. [Aspect A23] A compound according to aspect A1, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 6a , R6b and R 6d is a hydrogen atom. [Aspect A24] A compound according to aspect A1, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 4c , R 4f , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A25] A compound in which Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 4c , R 4f , R 6a , R 6b and R 6dis a hydrogen atom, and R 6e is a halogen atom. [Aspect A26] A compound according to aspect A2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect A27] A compound according to aspect A2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom; B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom; or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d [Aspect A28] In aspect A2, Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 6a and R 6c is a hydrogen atom. [Aspect A29] A compound according to aspect A2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6c is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A30] A compound in which Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c, R 4f , R 6a and R 6c is a hydrogen atom, and R 6e is a halogen atom. [Aspect A31] A compound according to aspect A2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 6a and R 6b is a hydrogen atom. [Aspect A32] A compound in which Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A33] A compound according to aspect A2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4aR 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6b is a hydrogen atom, and R 6e is a halogen atom. [Aspect A34] A compound according to aspect A2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 6a , R 6b and R 6d is a hydrogen atom. [Aspect A35] A compound according to aspect A2, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R4d , R 4c , R 4f , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A36] A compound according to aspect A2, wherein Het is a group represented by formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 4c , R 4f , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a halogen atom. [Aspect A37] A compound according to aspect A3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom. [Aspect A38] A compound according to aspect A3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B1 , B 2 , B 3 and B 4 The combination of 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom; B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom; or B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d [Aspect A39] In aspect A3, Het is a group represented by formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 6a and R 6c is a hydrogen atom. [Aspect A40] A compound according to aspect A3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6c is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A41] A compound according to aspect A3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6e and B 3 is CR 6c and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6c is a hydrogen atom, and R 6e is a halogen atom. [Aspect A42] A compound according to aspect A3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4is a nitrogen atom, and R 6a and R 6b is a hydrogen atom. [Aspect A43] A compound according to aspect A3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6b is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A44] A compound according to aspect A3, wherein Het is a group represented by formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is a nitrogen atom, and R 4a , R 4d , R 4c , R 4f , R 6a and R 6b is a hydrogen atom, and R 6eis a halogen atom. [Aspect A45] A compound according to aspect A3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 6a , R 6b and R 6d is a hydrogen atom. [Aspect A46] A compound according to aspect A3, wherein Het is a group represented by the formula Het7, and A 2 is CR 4a R 4d and A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 4c , R 4f , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; OR 7 or a halogen atom. [Aspect A47] A compound in which Het is a group represented by the formula Het7, and A 2 is CR 4a R 4dand A 4 is CR 4c R 4f and W 1 is an oxygen atom, and B 1 is CR 6a and B 2 is CR 6b and B 3 is CR 6e and B 4 is CR 6d and R 4a , R 4d , R 4c , R 4f , R 6a , R 6b and R 6d is a hydrogen atom, and R 6e is a halogen atom. [Aspect A48] In any one of Aspects A1 to A47, R 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b are taken together with the nitrogen atom to which they are bonded to form a pyrrolidinyl group or a piperidyl group. [Aspect A49] In any of Aspects A1 to A47, R 2a and R 2b are the same or different and are a C1-C6 alkyl group optionally substituted with one or more halogen atoms or a hydrogen atom, or R 2a and R 2b are taken together with the nitrogen atom to which they are bonded to form a pyrrolidinyl group or a piperidyl group. [Aspect A50] In any one of A1 to A47, R 2a and R 2b are the same or different and are C1-C6 alkyl groups optionally substituted with one or more halogen atoms.
[0015] Next, the method for producing the compounds of the present invention (including compound N of the present invention) will be described.
[0016] Production Method 1 The compound represented by formula (I) (compound N of the present invention) can be produced by reacting a compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) with a compound represented by formula (M-2) (hereinafter referred to as compound (M-2)). [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent. Examples of the solvent include ethers (hereinafter referred to as ethers) such as tetrahydrofuran (hereinafter referred to as THF), 1,4-dioxane, 1,2-dimethoxyethane (hereinafter referred to as DME), methyl tert-butyl ether (hereinafter referred to as MTBE), and diethyl ether; halogenated hydrocarbons (hereinafter referred to as halogenated hydrocarbons) such as dichloromethane and chloroform; aromatic hydrocarbons (hereinafter referred to as aromatic hydrocarbons) such as toluene and xylene; nitriles (hereinafter referred to as nitriles) such as acetonitrile; water, and mixtures of two or more thereof. In the reaction, compound (M-2) is usually used in a ratio of 0.8 to 10 moles per mole of compound (M-1). The reaction can be carried out by mixing compound (M-1) and compound (M-2). The reaction may be carried out in the presence of a base, if necessary. Examples of the base include alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); tertiary amines such as triethylamine (hereinafter referred to as tertiary amines); and nitrogen-containing aromatic compounds such as pyridine (hereinafter referred to as nitrogen-containing aromatic compounds). When a base is used in the reaction, the base is typically used in a ratio of 1 to 3 moles per mole of compound (M-1). The reaction temperature is typically within the range of -20 to 200°C. The reaction time is typically within the range of 0.1 to 24 hours. After completion of the reaction, the reaction mixture is added with water, followed by extraction with an organic solvent, and post-treatment such as drying and concentrating the organic layer can be performed to obtain compound N of the present invention. Compound (M-2) is a commercially available compound or can be produced using known methods.
[0017] Production Method 2 The compound represented by formula (I) (compound N of the present invention) can be produced by reacting a compound represented by formula (M-3) (hereinafter referred to as compound (M-3)) with a compound represented by formula (M-4) (hereinafter referred to as compound (M-4)) in the presence of a base. [In the formula, the symbols have the same meanings as above.] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents (hereinafter referred to as aprotic polar solvents) such as dimethylformamide (hereinafter referred to as DMF), N-methylpyrrolidone (hereinafter referred to as NMP), and dimethyl sulfoxide (hereinafter referred to as DMSO); water, and mixtures of two or more thereof. Examples of the base include alkali metal carbonates and alkali metal hydrides (hereinafter referred to as alkali metal hydrides) such as sodium hydride. In the reaction, compound (M-4) is usually used in a ratio of 0.8 to 1.2 moles, and a base is usually used in a ratio of 1 to 3 moles per mole of compound (M-3). The reaction temperature is usually within the range of −20 to 200° C. The reaction time is usually within the range of 0.5 to 24 hours. After the reaction is complete, water is poured into the reaction mixture, followed by extraction with an organic solvent, and post-treatment such as drying and concentrating the organic layer can be performed to obtain the compound N of the present invention. Compound (M-3) is known or can be produced in accordance with the method described in, for example, Bioorganic & Medicinal Chemistry Letters 2016, 26, 3822-3825., Journal of Heterocyclic Chemistry 2003, 40, 677-679., Bioorg. Med. Chem. Lett. 2009, 19, 1773-1778. or Org. Process Res. Dev. 2021, 25, 858-870.
[0018] Production Method 3 The compound represented by formula (I) (compound N of the present invention) can be produced by reacting compound (M-3) with a compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) in the presence of a metal catalyst. [In the formula, X arepresents a chlorine atom, a bromine atom, or an iodine atom, and other symbols have the same meanings as above.] The reaction is usually carried out in a solvent. Examples of the solvent include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents; and mixtures of two or more thereof. Examples of the metal catalyst include copper catalysts such as copper(I) iodide, copper(I) bromide, copper(I) chloride, copper(I) oxide, copper(I) trifluoromethanesulfonate benzene complex, tetrakis(acetonitrile)copper(I) hexafluorophosphate, and copper(I) 2-thiophenecarboxylate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), and tris(dibenzylideneacetone)dipalladium(II). In the reaction, compound (M-5) is usually used in a ratio of 0.8 to 1.2 moles and a metal catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-3). A ligand may be used in the reaction, if necessary. Examples of the ligand include triphenylphosphine, 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (hereinafter referred to as Xantphos), 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine. When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-1). A base may be used in the reaction, if necessary. Examples of the base include organic bases such as tertiary amines and nitrogen-containing aromatic compounds (hereinafter referred to as organic bases); alkali metal carbonates; and alkali metal hydrides.When a base is used in the reaction, the base is usually used in a ratio of 1 to 3 moles per mole of compound (M-3). The reaction temperature is usually in the range of -20°C to 150°C. The reaction time is usually in the range of 0.5 to 24 hours. After completion of the reaction, water is added to the reaction mixture, and the mixture is extracted with an organic solvent, followed by post-treatment such as drying and concentrating the organic layer, to obtain compound N of the present invention.
[0019] Reference Production Method 1 Compound (M-1) can be produced by reacting a compound represented by formula (M-7) (hereinafter referred to as compound (M-7)) with a chlorinating agent in the presence of chlorosulfonic acid. [In the formula, the symbols have the same meanings as above.] The reaction may be carried out in a solvent, if necessary. Examples of solvents used in the reaction include ethers; aromatic hydrocarbons; aromatic hydrocarbons; and mixtures of two or more thereof. Examples of chlorinating agents include phosphorus oxychloride and thionyl chloride. For the reaction, chlorosulfonic acid is typically used in a ratio of 1 to 10 moles, and the chlorinating agent is typically used in a ratio of 1 to 10 moles per mole of compound (M-7). The reaction temperature is typically in the range of -20°C to 200°C. The reaction time is typically in the range of 0.1 to 24 hours. After completion of the reaction, compound (M-1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer. Compound (M-7) is known or can be produced, for example, according to the method described in WO 2020 / 203763.
[0020] Reference Production Method 2 The compound represented by formula (M-9) (hereinafter referred to as compound (M-9)) can be produced by reacting a compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) with a chlorinating agent in the presence of chlorosulfonic acid. [In the formula, the symbols have the same meanings as defined above.] The reaction can be carried out using compound (M-8) instead of compound (M-7) in accordance with the method described in Reference Production Method 1. Compound (M-8) is a commercially available compound or can be produced using known methods.
[0021] Reference Production Method 3 Compound (M-5) can be produced by reacting compound (M-9) with compound (M-2). [wherein the symbols have the same meanings as defined above.] The reaction can be carried out in accordance with the method described in Production Method 1, except that compound (M-9) is used in place of compound (M-1).
[0022] Reference Production Method 4 Compound (M-4) can be produced by reacting compound (M-5) with a fluorinating agent. [In the formula, the symbols have the same meanings as above.] The reaction is usually carried out in a solvent. Examples of the solvent include aromatic hydrocarbons; aprotic polar solvents; and mixtures of two or more thereof. Examples of the fluorinating agent include cesium fluoride and potassium fluoride. In the reaction, the fluorinating agent is usually used in a ratio of 1 to 10 moles per mole of compound (M-5). The reaction temperature is usually in the range of 20°C to 300°C. The reaction time is usually in the range of 0.1 to 24 hours. After completion of the reaction, compound (M-4) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer.
[0023] The compound of the present invention (including Compound N of the present invention) can be mixed or used in combination with one or more components selected from the group consisting of Group (a), Group (b), Group (c), and Group (d) below (hereinafter referred to as the present component). The term "mixed or used in combination" means that the compound of the present invention and the present component are used simultaneously, separately, or with a time interval. When the compound of the present invention and the present component are used simultaneously, the compound of the present invention and the present component may be contained in separate preparations or in a single preparation. One aspect of the present invention is a composition (hereinafter referred to as Composition A) containing one or more components selected from the group consisting of Group (a), Group (b), Group (c), and Group (d) (i.e., the present component) and the compound of the present invention.
[0024] Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABAergic chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride channel allosteric modulators (e.g., macrolide insecticides), juvenile hormone mimics, multisite inhibitors, chordotonal organ TRPV channel modulators, mite growth inhibitors, microbial insect midgut membrane disruptors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, mitochondrial electron transport chain complexes I and II, The group consisting of inhibitors of classes III and IV, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide insecticides), chordotonal organ modulators, microbial insecticides, and other insecticidal, acaricidal, and nematicidal active ingredients, which are described in the IRAC mechanism-based classification.
[0025] Group (b) consists of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiratory inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyridine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multisite contact-active fungicides, microbial fungicides, and other fungicidal active ingredients. These are listed in the FRAC classification based on the mechanism of action.
[0026] Group (c) is a group of plant growth regulators (including mycorrhizal fungi and rhizobia).
[0027] Group (d) is a group of repellent ingredients.
[0028] Examples of combinations of the present components and compounds of the present invention (including Compound N of the present invention) are described below. For example, alanycarb + SX refers to a combination of alanycarb and SX. The abbreviation SX refers to any one compound of the present invention (including Compound N of the present invention) selected from the compound group SX1 to SX944. The present components described below are all known and can be obtained from commercially available preparations or produced by known methods. When the present components are microorganisms, they can also be obtained from bacterial depositories. The numbers in parentheses represent CAS RNs (registered trademarks).
[0029] Combinations of the present ingredient of the above group (a) with the compound of the present invention (including compound N of the present invention): abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetoprole + SX, acrinathrin + SX, acinonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminum phosphide + SX, amitraz + SX, azadirachtin + SX, azamethiphos + SX, azinphos-ethyl + SX, azinphos-methyl + SX, azocyclotin + SX, Celastrus angulatus bark + SX, bendiocarb + SX, benfluthrin + SX, benfuracarb + SX, bensultap + SX, benzoximate + SX, benzpyrimoxan + SX, beta-cyfluthrin + SX, beta-cypermethrin + SX, bifenazate + SX, bifenthrin + SX, bioallethrin + SX,Bioresmethrin + SX, bistrifluron + SX, borax + SX, boric acid + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butocarboxim + SX, butoxycarboxim + SX, cadusafos + SX, calcium phosphide + SX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, cartap hydrochloride + SX, cartap + SX Chinomethionate + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chloropicrin + SX, chlorpyrifos + SX, chlorpyrifos-methyl + SX, chromafenozide + SX, clofentezine + SX, clothianidin + SX, concanamycin A A) + SX, coumaphos + SX, cryolite + SX, cyanophos + SX, cyantraniliprole + SX,Cyclaniliprole + SX, cyclobutrifluram + SX, cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyetpyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + SX, cyhexatin + SX, cypermethrin + SX, cyphenothrin + SX, cyproflanilide + SX, cyromazine + SX, Dazomet + SX, deltamethrin + SX, demeton-S-methyl + SX, diafenthiuron + SX, diazinon + SX, dichlorvos + SX, dichloromezotiaz + SX, dicofol + SX, dicrotophos + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX, dimethoate + SX, dimethylvinphos + SX, dimpropyridaz + SX, Dinotefuran + SX, disodium octaborate + SX, disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX,Dried leaves of Dryopteris filix (mas) + SX, emamectin benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethifencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, etofenprox + SX. Etoxazole + SX, Artemisia absinthium extract + SX, Azadirachta indica extract + SX, Cassia nigricans extract + SX, Clitoria ternatea extract + SX, Symphytum officinale extract + SX, Chenopodium ambrosioides extract + SX, Tansy extract + SX, Urtica dioica extract + SX, Viscum album extract + SX, Famphur + SX, Fenamiphos + SX Fenazaquin + SX,Fenbutatin oxide + SX, fenitrothion + SX, fenmezoditiaz + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthion + SX, fenvalerate + SX, fipronil + SX, flometoquin + SX, flonicamid + SX, fluacrypyrim + SX, fluazaindolizine + SX, fluazuron + SX, Flubendiamide + SX, fluchlordiniliprole + SX, flucycloxuron + SX, flucythrinate + SX, fluensulfone + SX, flufenprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupentiofenox + SX, flupyradifurone + SX, flupyrimin + SX, flupyroxystrobin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, furamethrin + SX,Furathiocarb + SX, gamma-cyhalothrin + SX, GS-omega / kappa HXTX-Hv1a peptide + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, potassium salt of hop beta acid + SX, hydramethylnon + SX, hydroprene + SX, imicyafos + SX, Imidacloprid + SX, imidaclothiz + SX, imiprothrin + SX, indazapyroxamet + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoprocarb + SX, isopropyl-O-(methoxyaminothiophosphoryl) salicylate + SX, isoxathion + SX, ivermectin + SX, kadethrin + SX, kappa-tefluthrin + SX Kappa-bifenthrin + SX, kinoprene + SX, lambda-cyhalothrin + SX, ledprona + SX, lenoremycin + SX,Lepimectin + SX, lime sulfur + SX, lotilaner + SX, lufenuron + SX, machine oil + SX, malathion + SX, mecarbam + SX, meperfluthrin + SX, metaflumizone + SX, metam + SX, methamidophos + SX, methidathion + SX, methiocarb + SX, methomyl + SX, methoprene + SX, methoxychlor + SX, methoxyfenozide + SX, Methyl bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX, milbemectin + SX, milbemycin oxime + SX, mivorilaner + SX, modoflaner + SX, momfluorothrin + SX, monocrotophos + SX, moxidectin + SX, naled + SX, nicofluprole + SX, nicotine + SX, nicotine sulfate + SX, Nitenpyram + SX, Novaluron + SX, Noviflumuron + SX,Chenopodium anthelminticum seed oil + SX, omethoate + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, phosalone + SX, phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX Pirimicarb + SX, pirimiphos-methyl + SX, prallethrin + SX, profenofos + SX, profluthrin + SX, propargite + SX, propetamphos + SX, propoxur + SX, propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalyl + SX, Pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX,Pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spidoxamat + SX, spinetoram + SX, spinosad + SX, spirobudifen + SX, spirodiclofen + SX, spiromesifen + SX, spiropidione + SX, spirotetramat + SX, sulfiflumin + SX, sulfluramid + SX, sulfotep + SX, sulfoxaflor + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic + SX, tau-fluvalinate + SX, tebufenozide + SX, Tebufenpyrad + SX, Tebupirimfos + SX, Teflubenzuron + SX, Tefluthrin + SX, Temephos + SX, Terbufos + SX,Terpene constituents of the extract of Chenopodium ambrosioides near ambrosioides + SX, tetrachlorantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX, tetramethrin + SX, tetramethylfluthrin + SX, tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, Thiometon + SX, thiosultap disodium + SX, thiosultap monosodium + SX, tigolaner + SX, thioantraniliprole + SX, tioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, triazamate + SX, triazophos + SX, trichlorfon + SX, trifluenfuronate + SX, triflumezopyrim + SX, Triflumuron + SX, trimethacarb + SX,Tyclopyrazoflor + SX, umifoxolaner + SX, vamidothion + SX, Quassia amara wood extract + SX, 3,5-dimethylphenyl N-methylcarbamate (XMC) + SX, xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methanesulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX,2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, BT crop protein Cry1Ab (BT crop protein Cry1Ab) + SX, BT crop protein Cry1Ac (BT crop protein Cry1Ac) + SX, BT crop protein Cry1Fa (BT crop protein Cry1Fa) + SX, BT crop protein Cry1A.105 (BT crop protein Cry1A.105) + SX, BT crop protein Cry2Ab (BT crop protein Cry2Ab) + SX,BT crop protein Vip3A + SX, BT crop protein mCry3A + SX, BT crop protein Cry3Ab + SX, BT crop protein Cry3Bb + SX, BT crop protein Cry34Ab1 / Cry35Ab1 + SX, Adoxophyes orana granulovirus BV-0001 + SX, Anticarsia gemmatalis MNPV (multiple nucleocapsid nucleopolyhedrovirus) + SX, Autographa californica MNPV + SX, Cydia pomonella GV strain V15 + SX, Cydia pomonella GV strain V22 + SX, Cryptophlebia leucotreta GV + SX, Dendrolimus punctatus cypovirus + SX, Helicoverpa armigera nucleopolyhedrovirus BV-0003 + SX, Helicoverpa zea ... NPV) + SX, Lymantria dispar NPV + SX, Mamestra brassicae NPV + SX,Mamestra configurata nucleopolyhedrosis virus (NPV) + SX, Neodiprion abietis nucleopolyhedrosis virus (NPV) + SX, Neodiprion lecontei nucleopolyhedrosis virus (NPV) + SX, Neodiprion sertifer nucleopolyhedrosis virus (NPV) + SX, Nosema locustae + SX, Orgyia pseudotsugata nucleopolyhedrosis virus (NPV) + SX, Pieris rapae granulosis virus (GV) + SX, Plodia interpunctella granulosis virus (GV) + SX, Spodoptera exigua MNPV + SX, Spodoptera littoralis MNPV + SX, Spodoptera littoralis NPV + SX, Arthrobotrys dactyloides + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus megaterium + SX, Bacillus sp. strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b+ SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus thuringiensis strain AQ52 + SX,Bacillus thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp. Aizawai strain AM65-52 + SX, Bacillus thuringiensis subsp. Aizawai strain GC-91 + SX, Bacillus thuringiensis subsp. Aizawai strain NB200 + SX, Bacillus thuringiensis subsp. Aizawai Serotype strain H-7 + SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306) + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2348 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX,Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp. Tenebriosis strain NB176 + SX, Bacillus thuringiensis subsp. Thuringiensis strain MPPL002 + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis var. colmeri + SX, Bacillus thuringiensis var. darmstadiensis strain 24-91 + SX, Bacillus thuringiensis var. dendrolimus + SX, Bacillus thuringiensis var. galleriae + SX, Bacillus thuringiensis var. israelensis strain BMP144 + SX, Bacillus thuringiensis var. israelensis serotype strain H-14 + SX, Bacillus thuringiensis var. japonensis strain buibui + SX, Bacillus thuringiensis var. san diego strain M-7 + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. aegypti + SX, Bacillus thuringiensis var. T36 + SX, Beauveria bassiana strain ANT-03 + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain GHA + SX, Beauveria brongniartii + SX, Burkholderia rinogensis strain A396 + SX,Chromobacterium subtsugae strain PRAA4-1T + SX, Dactyllela ellipsospora + SX, Dectylaria thaumasia + SX, Hirsutella minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Lagenidium giganteum + SX, Lecanicillium lecanii strain KV01 + SX, Lecanicillium lecanii conidia of strain DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX, Lecanicillium muscarium strain Ve6 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae var. acridum + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium flavoviride + SX, Monacrosporium phymatopagum + SX, Paecilomyces fumosoroseus Apopka strain 97 + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 + SX, Paenibacillus popilliae + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria usgae + SX, Pasteuria thornei + SX, Serratia entomophila + SX, Verticillium chlamydosporium + SX, Verticillium lecani strain NCIM1312 + SX,Wolbachia pipientis + SX。,
[0030] Combinations of the present ingredient of the above group (b) with the compound of the present invention (including compound N of the present invention): acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, Benthiavalicarb-isopropyl + SX, benzovindiflupyr + SX, binapacryl + SX, biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin S + SX, Bordeaux mixture + SX, boscalid + SX, bromothalonil + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, carpropamid + SX, chinomethionate + SX, chitin + SX, chloroinconazide + SX, chloroneb + SX,Chlorothalonil + SX, chlozolinate + SX, colletochlorin B + SX, copper(II) acetate + SX, copper(II) hydroxide + SX, copper oxychloride + SX, copper(II) sulfate + SX, coumoxystrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX, cyprodinil + SX, dichlobentiazox + SX, Dichlofluanid + SX, diclocymet + SX, diclomezine + SX, dicloran + SX, diethofencarb + SX, difenoconazole + SX, diflumetorim + SX, dimethachlone + SX, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, diniconazole-M + SX, dinocap + SX, dipotassium hydrogenphosphite + SX, dipymetitrone + SX, dithianon + SX,Dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt + SX, dodemorph + SX, dodine + SX, edifenphos + SX, enoxastrobin + SX, epoxiconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, garlic extract (Allium sativum) + SX, extract of the cotyledons of lupine plantlets (BLAD) + SX, horsetail extract (Equisetum arvense) + SX SX, tea tree extract (Melaleuca alternifolia) + SX, giant knotweed extract (Reynoutria sachalinensis) + SX, nasturtium extract (Tropaeolus majus) + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin + SX, fenarimol + SX, fenbuconazole + SX, fenfuram + SX, fenhexamid + SX, fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX Fenpropidin + SX, Fenpropimorph + SX,Fenpyrazamine + SX, triphenyltin acetate + SX, triphenyltin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX, florylpicoxamid + SX, fluazinam + SX, flubeneteram + SX, fludioxonil + SX, flufenoxadiazam + SX, flufenoxystrobin + SX, fluindapyr + SX, flumetylsulforim + SX, flumorph + SX, fluopicolide + SX, fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxapiprolin + SX, fluoxastrobin + SX, fluoxytioconazole + SX, fluquinconazole + SX, flusilazole + SX, flusulfamide + SX, flutianil + SX, flutolanil + SX, flutriafol + SX, fluxapyroxad + SX, folpet + SX, Fosetyl + SX, fosetyl-aluminium + SX, fuberidazole + SX, furalaxyl + SX, furametpyr + SX,Guazatine + SX, hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX, iminoctadine triacetate + SX, inpyrfluxam + SX, iodocarb + SX, ipconazole + SX, ipfentrifluconazole + SX, ipflufenoquin + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX Isofetamide + SX, isoflucipram + SX, isoprothiolane + SX, isopyrazam + SX, isotianil + SX, kasugamycin + SX, kresoxim-methyl + SX, laminarin + SX, oak leaves and bark of quercus + SX, mancozeb + SX, mandestrobin + SX, mandipropamid + SX, maneb + SX, mefentrifluconazole + SX, mepanipyrim + SX, Mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M + SX, metarylpicoxamid + SX,Metconazole + SX, methasulfocarb + SX, metiram + SX, metominostrobin + SX, metrafenone + SX, metyltetraprole + SX, myclobutanil + SX, naftifine + SX, nuarimol + SX, octhilinone + SX, ofurace + SX, orysastrobin + SX, oxadixyl + SX, oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, Oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphorous acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin + SX, piperalin + SX, polyoxins + SX, Potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX,Probenazole + SX, prochloraz + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole + SX, propineb + SX, proquinazid + SX, prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, pyraclostrobin + SX, pyrametostrobin + SX, pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, Pyrazophos + SX, pyribencarb + SX, pyributicarb + SX, pyridaclomethyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyrisoxazole + SX, pyroquilon + SX, Quillaja extract + SX, quinconazole + SX, quinofumelin + SX, quinoxyfen + SX, quintozene + SX, quinoa saponins Chenopodium quinoa + SX, seboctylamine + SX, sedaxane + SX, silthiofam + SX,Simeconazole + SX, sodium hydrogencarbonate + SX, spiroxamine + SX, streptomycin + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tecnazene + SX, terbinafine + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, Thymol + SX, tiadinil + SX, tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triadimefon + SX, triadimenol + SX, triazoxide + SX, triclopyricarb + SX, tricyclazole + SX, tridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole + SX, Validamycin + SX, valifenalate + SX, vinclozolin + SX,マスタードパウダー(yellow mustard powder) + SX, zinc thiazole + SX, ジネブ(zineb) + SX, ジラム(ziram) + SX, ゾキサミド(zoxamide) + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N '-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055589-28-9) + SX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylmethanimidamide (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylmethanimidamide (2101814-55-3) + SX, N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylmethanimidamide (1817828-69-5) + SX,4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX, (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-07-3) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R, 2S, 5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S, 2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-carboxylate (1791398-02-1) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX,methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-(1-benzyl-3,3,3-trifluoro-1-methylpropyl)-8-fluoroquinoline-3-carboxamide (2132414-00-5) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N'-ethyl-N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SX,3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromoindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX, N-methoxy-N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX,1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, ethyl 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylate + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine + SX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide + SX, methyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, ethyl 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, methyl 2-[2-(trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propanoate + SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide + SX, 1-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX,5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimi din-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX,(5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-(5-cyclohexyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX,methyl (Z)-2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy]-3-methoxyprop-2-enoate + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, methyl (2Z)-3-methoxy-2-[(4-methyl[1,1'-biphenyl]-3-yl)oxy]prop-2-enoate + SX, Agrobacterium radiobactor strain K1026 + SX, Agrobacterium radiobactor strain K84 + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo(Trademark) EZ Nematicide) + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX, Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain GB03 + SX,Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain MBI600 + SX, Bacillus amyloliquefaciens strain QST713 + SX, Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens subsp. plantarum strain D747 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus simplex strain CGF2856 + SX, Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain IAB / BS03 + SX,Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 + SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24 + SX, Bacillus subtilis strain Y1336 + SX, Burkholderia cepacia + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX, Candida oleophila strain O + SX, Candida saitoana + SX, Chaetomium cupreum + SX, Clonostachys rosea + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-8 + SX, cryptococcus albidus + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Fusarium oxysporum strain Fo47 + SX, Gliocladium catenulatum strain J1446 + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Pantoea agglomerans strain E325 + SX, Phlebiopsis gigantea strain VRA1992 + SX,Pseudomonas aureofaciens strain TX-1 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SX, Pseudomonas fluorescens strain 1629RS + SX, Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain G7090 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain MA-4 + SX, Pseudozyma flocculosa strain PF-A22UL + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum SKT-1 + SX, Trichoderma asperellum strain T25 + SX, Trichoderma asperellum strain T34 + SX,Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain SC1 + SX, Trichoderma atroviride strain SKT-1 + SX, Trichoderma atroviride strain T11 + SX, Trichoderma gamsii strain ICC080 + SX, Trichoderma harzianum strain 21 + SX, Trichoderma harzianum strain DB104 + SX, Trichoderma harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX, Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX, Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain kd + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain SF + SX, Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma polysporum strain IMI206039 + SX, trichoderma stromaticum + SX,Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 + SX, Trichoderma viride + SX, Variovorax paradoxus strain CGF4526 + SX, Harpin protein + SX。,
[0031] Combinations of the present component of the above group (c) with the compound of the present invention (including compound N of the present invention): 1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 2,3,5-triiodobenzoic acid + SX, (1H-indol-3-yl)acetic acid (IAA) + SX, 4-(1H-indol-3-yl)butyric acid (IBA) + SX, 2-(4-chloro-2-methylphenoxy)acetic acid (MCPA) + SX, 4-(4-chloro-2-methylphenoxy)butyric acid (MCPB) + SX, 4-chlorophenoxyacetic acid (4-CPA) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat chloride + SX, chlorpropham + SX, choline chloride + SX, cloprop + SX, Cyanamide + SX, cyclanilide + SX,Daminozide + SX, decan-1-ol + SX, dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat + SX, ethephon + SX, ethychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX, gibberellin A + SX, gibberellin A3 + SX, inabenfide + SX, Kinetin + SX, lipochitooligosaccharide SP104 + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat chloride + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, sintophen + SX, sodium 1-naphthaleneacetate + SX, sodium cyanate + SX, Thidiazuron + SX, triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX,Uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, Methyl 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, Claroideoglomus etunicatum + SX, Claroideoglomus claroideum + SX, Funneliformis mosseae + SX, Gigaspora margarita + SX, Gigaspora rosea + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus monosporum + SX, Paraglomus brasillianum + SX, Rhizophagus clarus + SX, Rhizophagus intraradices RTI-801 + SX, Rhizophagus irregularis DAOM 197198 + SX, Azorhizobium caulinodans + SX, Azospirillum amazonense + SX, Azospirillum brasilense XOH + SX, Azospirillum brasilense Ab-V5 + SX, Azospirillum brasilense Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Bradyrhizobium elkanii SEMIA 587 + SX, Bradyrhizobium elkanii SEMIA 5019 + SX, Bradyrhizobium japonicum TA-11 + SX,Bradyrhizobium japonicum USDA 110 + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Delftia acidovorans RAY209 + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium leguminosarum bv. Phaseoli + SX, Rhizobium leguminosarum bv. Trifolii + SX, Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, Zucchini Yellow Mosaik Virus weak strain + SX. ,
[0032] Combinations of the present component of the above group (d) with the compound of the present invention (including compound N of the present invention): anthraquinone + SX, deet + SX, icaridin + SX.
[0033] The ratio of the compound of the present invention (including compound N of the present invention) to the present component is not particularly limited, and examples thereof include a weight ratio (compound of the present invention:present component) of 1000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:50, and the like.
[0034] The compound N of the present invention or the compounds of the present invention are effective against harmful arthropods such as harmful insects and harmful mites, harmful nematodes, and harmful mollusks. Examples of harmful arthropods, harmful nematodes, and harmful mollusks include the following.
[0035] Hemiptera: Small brown planthopper (Laodelphax striatellus), Brown planthopper (Nilaparvata lugens), White-backed planthopper (Sogatella furcifera), Corn planthopper (Peregrinus maidis), Yellow leafhopper (Javesella pellucida), Black horned planthopper (Perkinsiella saccharicida), Tagosodes orizicolus, Stenocranus pacificus and other Delphacidae; Green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), Black-striped green rice leafhopper (Nephotettix nigropictus), Lightning leafhopper (Recilia dorsalis), Tea green leafhopper (Empoasca Cicadellidae, such as the potato leafhopper (Empoasca fabae), the corn leafhopper (Dalbulus maidis), the white giant leafhopper (Cofana spectra), and Amrasca biguttula biguttula; Aphrophoridae, such as the European spittlebug (Philaenus spumarius); Cercopidae, such as Mahanarva posticata and Mahanarva fimbriolata;Black bean aphid (Aphis fabae), soybean aphid (Aphis glycines), cotton aphid (Aphis gossypii), European apple aphid (Aphis pomi), willow aphid (Aphis spiraecola), green peach aphid (Myzus persicae), strawberry aphid (Brachycaudus helichrysi), radish aphid (Brevicoryne brassicae), rosy apple aphid (Dysaphis plantaginea), false radish aphid (Lipaphis erysimi), tulip aphid (Macrosiphum euphorbiae), potato aphid (Aulacorthum solani), lettuce aphid (Nasonovia ribisnigri), wheat collar aphid (Rhopalosiphum padi), corn aphid (Rhopalosiphum maidis), citrus black aphid (Toxoptera citricida), peach butterbur aphid (Hyalopterus pruni), barnyard millet aphid (Melanaphis sacchari), Japanese black aphid (Tetraneura nigriabdominalis), cotton aphid (Ceratovacuna lanigera), apple aphid (Eriosoma lanigerum), English grain aphid (Sitobion avenae), etc. Aphididae; grape aphid (Daktulosphaira vitifoliae), pecan phylloxera (Phylloxera devastatrix), pecan leaf phylloxera (Phylloxera notabilis), southern pecan leaf phylloxera (Phylloxera Phylloxeridae, such as (Russelae);Adelgidae, such as the Japanese hemlock aphid (Adelges tsugae), the balsam woolly aphid (Adelges piceae), and the small brown aphid (Aphrastasia pectinatae); Scotinophara lurida, Scotinophara coarctata, Nezara antennata, Eysarcoris aeneus, Eysarcoris lewisi, Eysarcoris ventralis, Eysarcoris annamita, Halyomorpha halys, and Nezara Pentatomidae, such as the brown stink bug (Euschistus heros), the red-banded stink bug (Piezodorus guildinii), Oebalus pugnax, Dichelops melacanthus, and the spotted stink bug (Piezodorus hybneri); Cydnidae, such as the narrow-banded stink bug (Riptortus clavatus), the spider stink bug (Leptocorisa chinensis), and the narrow-banded stink bug (Leptocorisa acuta); Cletus punctiger, Leptoglossus Coreidae, such as Cavelerius saccharivorus, Togo hemipterus, and Blissus leucopterus; Lygaeidae, such as Cavelerius saccharivorus, Togo hemipterus, and Blissus leucopterus;Miridae (Miridae) such as the red-bearded green rice bug (Trigonotylus caelestialium), the red-striped rice bug (Stenotus rubrovittatus), the long-spined wheat rice bug (Stenodema calcarata), and the rusty rice bug (Lygus lineolaris); Aleyrodidae (Aleyrodidae) such as the greenhouse whitefly (Trialeurodes vaporariorum), the tobacco whitefly (Bemisia tabaci), the citrus whitefly (Dialeurodes citri), the citrus spine whitefly (Aleurocanthus spiniferus), the tea spine whitefly (Aleurocanthus camelliae), and the Japanese oak leaf butterflies (Pealius euryae); cyanophylli), red scale (Aonidiella aurantii), pear scale (Diaspidiotus perniciosus), mulberry scale (Pseudaulacaspis pentagona), Yanon scale (Unaspis yanonensis), false Yanon scale (Unaspis citri) and other scale insects (Diaspididae); Coccidae such as ruby scale (Ceroplastes rubens); Margarodidae such as Icerya purchasi and yellow cotton scale (Icerya seychellarum);Pseudococcidae, such as the eggplant mealybug (Phenacoccus solani), the sable mealybug (Phenacoccus solenopsis), the wisteria mealybug (Planococcus kraunhiae), the mulberry mealybug (Pseudococcus comstocki), the citrus mealybug (Planococcus citri), the moth mealybug (Pseudococcus calceolariae), the long-legged mealybug (Pseudococcus longispinus), and the tuttlemey bug (Brevennia rehi); the citrus psyllid (Diaphorina citri), the citrus psyllid (Trioza erytreae), the pear psyllid (Cacopsylla pyrisuga), and the Chinese pear psyllid (Cacopsylla Psyllidae, such as the Japanese chinensis, the potato psyllid (Bactericera cockerelli), and the cacopsylla (Cacopsylla pyricola); Tingidae, such as the plane tree earworm (Corythucha ciliata), the goldenrod earworm (Corythucha marmorata), the Japanese pear earworm (Stephanitis nashi), and the azalea earworm (Stephanitis pyrioides); Cimicidae, such as the bedbug (Cimex lectularius) and the netted whitefly (Cimex hemipterus); Cicadidae, such as the Quesada gigas; Triatoma infestans, Triatoma rubrofasciata, and Triatoma Reduviidae, such as the Venezuelan assassin bug (Rhodonius prolixus);
[0036] Lepidoptera: Chilo suppressalis, Dark-headed stem borer, Chilo polychrysus, White stem borer, Scirpophaga innotata, Scirpophaga incertulas, Rupela albina, Rice leaf borer, Cnaphalocrocis medinalis, Marasmia patnalis, Rice casino borer, Marasmia exigua, Cotton borer, Notarcha derogata, European corn borer, Ostrinia furnacalis, European corn borer, Hellula undalis, Black-spotted corn borer, Herpetogramma luctuosale, Rice stalk moth, Nymphula Crambidae, such as the Japanese corn moth (Elasmopalpus lignosellus), the Indian meal moth (Plodia interpunctella), the Japanese two-spotted moth (Euzophera batangensis), and the Japanese striped moth (Cadra cautella);Common cutworm (Spodoptera litura), beet armyworm (Spodoptera exigua), armyworm (Mythimna separata), armyworm (Mamestra brassicae), rice armyworm (Sesamia inferens), white armyworm (Spodoptera mauritia), two-banded cutworm (Naranga aenescens), leaf fall armyworm (Spodoptera frugiperda), African armyworm (Spodoptera exempta), Spodoptera cosmioides, semi-tropical armyworm (Spodoptera eridania), red cutworm (Agrotis ipsilon), turnip cutworm (Agrotis segetum), red rice looper (Autographa nigrisigna), rice yellow looper (Plusia festucae), soybean Heliothis spp. such as the cotton bollworm (Chrysodeixis includens), Trichoplusia spp., and Heliothis spp. such as the false tobacco budworm (Heliothis virescens), Helicoverpa spp. such as the cotton bollworm (Helicoverpa armigera) and the corn earworm (Helicoverpa zea), Noctuidae such as the velvet bean caterpillar (Anticarsia gemmatalis), the cotton leafworm (Alabama argillacea), and the hop wine borer (Hydraecia immanis); Pieridae such as the cabbage white butterfly (Pieris rapae);Pear fruit moth (Grapholita molesta), plum fruit moth (Grapholita dimorpha), bean fruit moth (Leguminivora glycinivorella), adzuki bean pea moth (Matsumuraeses azukivora), apple smaller tortrix (Adoxophyes orana fasciata), tea smaller tortrix (Adoxophyes honmai), tea tortrix (Homona magnanima), green tea tortrix (Archips fuscocupreanus), codling moth (Cydia pomonella), citrus fruit borer (Tetramoera schistaceana), bean shoot borer (Epinotia aporema), citrus fruit borer (Citripestis sagittiferella), European grape wine moth (Lobesia Tortricidae such as Caloptilia theivora and Phyllonorycter ringoniella; Gracilariae such as Carposinidae; Leucoptera coffeella, Lyonetiidae such as Lyonetia clerkella, Lyonetia prunifoliella; Lymantria spp. such as Lymantria dispar, Euproctis spp. such as Euproctis pseudoconspersa; Plutella xylostella Plutellidae, such as Plutellidae (Plutella xylostella);Gelechiidae (Gelechiidae) such as the peach leaf moth (Anarsia lineatella), the potato leaf moth (Helcystogramma triannulella), the red bollworm moth (Pectinophora gossypiella), the potato tuber moth (Pthorimaea operculella), and the tomato leaf moth (Tuta absoluta); Arctiidae (Arctiidae) such as the American fall webworm (Hyphantria cunea); Castniidae (Castniidae) such as the giant sugarcane borer (Telchin licus); Cossidae (Cossidae) such as the small box moth (Cossus insularis); Geometridae (Geometridae) such as the mugwort geometrid (Ascotis selenaria); Parasa Limacodidae such as Stathmopodidae (Stathmopoda masinissa) and the like; Sphingidae such as Acherontia lachesis (Sphingidae); Sesiidae such as Nokona feralis (Nokona feralis), Synanthedon hector (Synanthedon tenuis) and the like; Hesperiidae such as Parnara guttata (Parnara guttata); Tineidae such as Tinea translucens (Tineola bisselliella) and the like.
[0037] Thysanoptera: Thripidae such as Frankliniella occidentalis, Thrips palmi, Scirtothrips dorsalis, Thrips tabaci, Frankliniella intonsa, Stenchaetothrips biformis, Echinothrips americanus, and Scirtothrips perseae; Phlaeothripidae such as Haplothrips aculeatus.
[0038] Diptera: Anthomyiidae such as Delia platura, Delia antiqua, and Pegomya cunicularia; Ulidiidae such as Tetanops myopaeformis; Agromyzidae such as Agromyza oryzae, Liriomyza sativae, Liriomyza trifolii, and Chromatomyia horticola; Chloropidae such as Chlorops oryzae; Bactrocera Tephritidae, such as the Oriental fruit fly (Bactrocera dorsalis), the eggplant fly (Bactrocera latifrons), the olive fruit fly (Bactrocera oleae), the Queensland fruit fly (Bactrocera tryoni), the Mediterranean fruit fly (Ceratitis capitata), the apple maggot (Rhagoletis pomonella), and the cherry fruit fly (Rhacochlaena japonica); Ephydridae, such as the rice leafminer (Hydrellia griseola), the Asian rice leafminer (Hydrellia philippina), and the rice leafminer (Hydrellia sasakii); Drosophila suzukii Drosophilidae, such as Drosophila melanogaster (Drosophila suzukii) and Drosophila melanogaster; Phoridae, such as Megaselia spiracularis; Psychodidae, such as Clogmia albipunctata;Sciaridae (Sciaridae) such as Bradysia difformis and Bradysia odoriphaga; Cecidomyiidae (Cecidomyiidae) such as Mayetiola destructor and Orseolia oryzae; Diopsidae (Diopsis macrophthalma); Glossinidae (Tsetse flies) such as Glossina palpalis and Glossina morsitans; Simuliidae (Simuliidae) such as Simulium japonicum and Simulium damnosum; Phlebotominae (Phlebotominae); Tipula aino (Craned fly), Tipula oleracea (Common crane fly), and Tipula Tipulidae such as Culex pipiens pallens, Culex tritaeniorhynchus, Culex pipiens f. molestus, Culex quinquefasciatus, Culex pipiens pipiens, Culex vishnui, Aedes albopictus, Aedes aegypti, Anopheles sinensis, Anopheles gambiae, Anopheles stephensi, Anopheles coluzzii, Anopheles albimanus, Anopheles sundaicus, Anopheles mosquito family (Culicidae) such as arabiensis, Anopheles funestus, Anopheles darlingi, Anopheles farauti, Anopheles minimus;Simulidae (Family Simuliidae) such as Prosimulium yezoensis and Simulium ornatum; Tabanidae (Family Tabanus trigonus) and other such flies; Muscidae (Family Musca domestica), Muscina stabulans, Stomoxys calcitrans, Haematobia irritans and other such flies; Calliphoridae (Family Sarcophagidae); Chironomidae (Family Chironomidae) such as Chironomus plumosus, Chironomus yoshimatsui, Glyptotendipes tokunagai and other such flies; Fannidae (Family Fannidae);
[0039] Coleoptera: Diabrotica spp. (e.g., Western corn rootworm (Diabrotica virgifera virgifera), Southern corn rootworm (Diabrotica undecimpunctata howardi), Northern corn rootworm (Diabrotica barberi), Mexican corn rootworm (Diabrotica virgifera zeae), Banded cucumber beetle (Diabrotica balteata), Cucumber beetle (Diabrotica speciosa), etc.), Bean leaf beetle (Cerotoma trifurcata), Red-necked leaf beetle (Oulema melanopus), Cucumber leaf beetle (Aulacophora femoralis), Striped flea beetle (Phyllotreta striolata), Cabbage leaf beetle (Phyllotreta cruciferae), Western black leaf beetle (Phyllotreta pusilla, cabbage stem beetle (Psylliodes chrysocephala), hop beetle (Psylliodes punctulata), Colorado potato beetle (Leptinotarsa decemlineata), rice leaf beetle (Oulema oryzae), grape colaspis (Colaspis brunnea), corn beetle (Chaetocnema pulicaria), sweet potato leaf beetle (Chaetocnema confinis), potato beetle (Epitrix cucumeris), rice spur beetle (Dicladispa armigera), southern corn leaf beetle (Myochrous denticollis), four-spotted tortoise beetle (Laccoptera quadrimaculata), tobacco flea beetle (Epitrix hirtipennis), radish leaf beetle (Phaedon Chrysomelidae, such as the two-striped leaf beetle (Medythia nigrobilineata);Carabidae beetles such as the seed corn beetle (Stenolophus lecontei) and the slender seed corn beetle (Clivina impressifrons); Phyllophaga spp. such as the cuprea beetle (Anomala cuprea), the rufocuprea beetle (Anomala rufocuprea), the green beetle (Anomala albopilosa), the Japanese beetle (Popillia japonica), the long-legged beetle (Heptophylla picea), the European chafer (Rhizotrogus majalis), the black marsh beetle (Tomarus gibbosus), the black beetle (Holotrichia spp.), and the June beetle (Phyllophaga crinita); Diloboderus spp. such as Diloboderus abderus. Scarabaeidae (Scarabaeidae) such as Araecerus coffeae (Boll weevil); Anthriibidae (Anthriibidae) such as Cylas formicarius (Sweet potato weevil); Bruchidae (Brachiidae) such as Zabrotes subfasciatus (Brazilian bean weevil); Scolytidae (Scolytidae) such as Tomicus piniperda (Pine bark beetle), Hypothenemus hampei (Coffee berry borer);Potato weevil (Euscepes postfasciatus), alfalfa weevil (Hypera postica), maize weevil (Sitophilus zeamais), rice weevil (Sitophilus oryzae), granaria weevil (Sitophilus granarius), rice weevil (Echinocnemus squameus), rice water weevil (Lissorhoptrus oryzophilus), white grain weevil (Rhabdoscelus lineaticollis), boll weevil (Anthonomus grandis), grass band weevil (Sphenophorus venatus), southern cornbill bug (Sphenophorus callosus), soybean stalk weevil (Sternechus subsignatus), sugarcane weevil (Sphenophorus levis), rust gourd weevil (Scepticus The Aracanthus spp. (Aracanthus spp.) such as Aracanthus griseus, Scepticus uniformis, Aracanthus mourei, and the cotton root borer (Eutinobothrus brasiliensis) are also included in the Curculionidae family; the Tenebrionidae (Tenebrionidae) such as Tribolium castaneum, Tribolium confusum, and Alphitobius diaperinus are also included in the Coccinellidae family; the Flat-headed Ladybird (Lyctus brunneus), the Rhizopertha dominica); Ptinidae; Cerambycidae, such as Anoplophora malasiaca, Migdolus fryanus, and Aromia bungii;Elateridae beetles such as the Okinawan wireworm beetle (Melanotus okinawensis), the brown-headed wireworm beetle (Agriotes fuscicollis), the comb beetle (Melanotus legatus), the foot-striped wireworm beetle (Anchastus spp.), the Conoderus spp., the Ctenicera spp., the Limonius spp., and the Aeolus spp.; Staphylinidae beetles such as the blue-leaf rove beetle (Paederus fuscipes); the small-leaved weevils (Anthrenus verbasci) and the white-striped weevils (Dermestes Dermestidae such as Trogoderma granarium (Trogoderma maculates) and the like; Anobiidae such as Lasioderma serricorne (tobacco beetle) and Stegobium paniceum (Anobiidae); Laemophloeidae such as Cryptolestes ferrugineus (Laemophloeidae); Silvanidae such as Oryzaephilus surinamensis (Silvanidae); Nitidulidae such as Brassicogethes aeneus (Blossom beetle).
[0040] Orthoptera: Migratory locust (Locusta migratoria), Moroccan locust (Dociostaurus maroccanus), Australian locust (Chortoicetes terminifera), Red locust (Nomadacris septemfasciata), Brown locust (Locustana pardalina), Tree locust (Anacridium melanorhodon), Italian locust (Calliptamus italicus), Differential grasshopper (Melanoplus differentialis), Two-striped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-legged grasshopper (Melanoplus femurrubrum), Clear-winged grasshopper (Camnula pellucida), Desert grasshopper (Schistocerca The grasshoppers (Acrididae) include the common locust (Oxya gregaria), yellow-winged locust (Gastrimargus musicus), sparse-throated locust (Austracris guttulosa), oriental grasshopper (Oxya yezoensis), long-winged locust (Oxya japonica), and Taiwan grasshopper (Patanga succincta); the grasshoppers (Gryllotalpidae) include the common house cricket (Gryllotalpa orientalis); the crickets (Gryllidae) include the European house cricket (Acheta domestica) and the field cricket (Teleogryllus emma); and the katydids (Tettigoniidae) include the Mormon cricket (Anabrus simplex).
[0041] Hymenoptera: Tenthredinidae such as Athalia rosae and Athalia japonica; Solenopsis spp. such as Solenopsis invicta and Solenopsis geminata, Atta spp. such as Atta capiguara, Acromyrmex spp., Paraponera clavata, Ochetellus glaber, Monomorium pharaonis, Linepithema humile, Formica japonica, Pristomyrmex punctutus, Pheidole Camponotus spp. such as Camponotus noda, Pheidole megacephala, Camponotus japonicus, Camponotus obscuripes, Pogonomyrmex spp. such as Pogonomyrmex occidentalis, Wasmania spp. such as Wasmania auropunctata, Formicidae such as Anoplolepis gracilipes; Vespa mandarinia, Vespa simillima, Vespa analis, Vespa Vespidae, such as Polistes velutina and Polistes jokahamae; Siricidae, such as Urocerus gigas; and Bethylidae.
[0042] Blattodea: Ectobiidae, such as the German cockroach (Blattella germanica); Blattidae, such as the American cockroach (Periplaneta fuliginosa), the American cockroach (Periplaneta americana), the American cockroach (Periplaneta australasiae), the brown cockroach (Periplaneta brunnea), and the Asian cockroach (Blatta orientalis); Reticulitermes speratus, Coptotermes formosanus, Incisitermes minor, Cryptotermes domesticus, Odontotermes formosanus, and Neotermes Termites of the family Termitidae, such as the Satsuma termite (Glyptotermes satsumensis), Nakajima termite (Glyptotermes nakajimai), Katan termite (Glyptotermes fuscus), Hodotermopsis sjostedti, Koshu termite (Coptotermes guangzhouensis), Amami termite (Reticulitermes amamianus), Miyatake termite (Reticulitermes miyatakei), Formosan termite (Reticulitermes kanmonensis), Takasago termite (Nasutitermes takasagoensis), Snocapritermes nitobei, Sinocapritermes mushae, and Cornitermes cumulans.
[0043] Order Siphonaptera: Family Pulicidae such as human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), chicken flea (Echidnophaga gallinacea), etc.; Family Hectopsyllidae such as sand flea (Tunga penetrans); Family Ceratophyllidae such as European rat flea (Nosopsyllus fasciatus).
[0044] Psocodae: Pediculidae, such as head louse (Pediculus humanus capitis); Pthiridae, such as pubic louse (Pthirus pubis); Haematopinidae, such as cow louse (Haematopinus eurysternus) and pig louse (Haematopinus suis); Linognathidae, such as cow louse (Linognathus vituli), sheep trunk louse (Linognathus ovillus), and woolly cow louse (Solenopotes capillatus); Bovicola bovis, sheep louse (Bovicola ovis), Bovicola breviceps, Damalinia Bovicoliidae, such as Trichodectes canis and Felicola subrostratus; Menoponidae, such as Menopon gallinae, Menacanthus stramineus, and Trinoton spp.; Trimenoponidae, such as Cummingsia spp.; Trogiidae, such as Trogium pulsatorium; Liposcelis corrodens and Liposcelis Liposcelidae or Liposcelididae, such as Liposcelis bostrychophila, Liposcelis pearmani, and Liposcelis entomophila.
[0045] Thysanura: Family Lepismatidae, including the Japanese silverfish (Ctenolepisma villosa) and the European silverfish (Lepisma saccharina).
[0046] Acari: Tetranychidae such as Tetranychus urticae, Tetranychus kanzawai, Tetranychus evansi, Panonychus citri, Panonychus ulmi, Oligonychus spp.; Aculops pelekassi, Aculops citri, Aculops lycopersici, Calacarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculops spp. Eriophyidae such as Aceria diospyri, Aceria tosichella, and Shevtchenkella sp.; Tarsonemidae such as Polyphagotarsonemus latus; Tenuipalpidae such as Brevipalpus phoenicis; Tuckerellidae;Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysalis japonica, Haemaphysalis campanulata, Dermacentor variabilis, Dermacentor taiwanensis, Rocky Mountain wood tick (Dermacentor andersoni), Dermacentor reticulatus, Ixodes ovatus, Ixodes persulcatus, Black-legged tick (Ixodes scapularis), Western black-legged tick (Ixodes pacificus), Ixodes holocyclus, Ixodes ricinus, Lone star tick (Amblyomma Ixodidae ticks such as Amblyomma americanum, Amblyomma maculatum, Rhipicephalus microplus, Rhipicephalus annulatus, Rhipicephalus sanguineus, Rhipicephalus appendiculatus, and Rhipicephalus decoloratus; Argasidae ticks such as Argas persicus, Ornithodoros hermsi, and Ornithodoros turicata; Acaridae ticks such as Tyrophagus putrescentiae and Tyrophagus similis; Dermatophagoides farinae and Dermatophagoides pteronyssinus. Pyroglyphidae, such as Pteronyssinus;Cheyletidae such as Cheyletus eruditus, Cheyletus malaccensis, Chelacaropsis moorei, and Cheyletiella yasguri; Psoroptidae such as Psoroptes ovis, Psoroptes equi, Knemidocoptes mutans, Otodectes cynotis, and Chorioptes spp.; Notoedres cati, Notoedres muris, and Sarcoptes Sarcoptidae such as (Scabiei); Listrophoridae such as (Listrophorus gibbus); Dermanyssidae such as (Dermanyssus gallinae); Macronyssidae such as (Ornithonyssus sylviarum) and (Ornithonyssus bacoti); Varroa destructor such as (Varroa jacobsoni); Demodicidae such as (Demodex canis) and (Demodex cati); Leptotrombidium akamushi and (Leptotrombidium Trombiculidae, such as Leptotrombidium scutellare, Leptotrombidium pallidum, and Leptotrombidium scutellare.
[0047] Araneae: Eutichuridae, such as Cheiracanthium japonicum; Theridiidae, such as Latrodectus hasseltii. Polydesmida: Paradoxosomatidae, such as Oxidus gracilis and Nedyopus tambanus. Isopoda: Armadillidiidae, such as Armadillidium vulgare. Chilopoda: Scutigeridae such as Thereuonema hilgendorfi; Scolopendridae such as Scolopendra subspinipes; Ethopolyidae such as Bothropolys rugosus. Class Gastropoda: Family Limacidae such as the brown slug (Limax marginatus) and the yellow slug (Limax flavus); Family Philomycidae such as the slug (Meghimatium bilineatum); Family Ampullariidae such as the apple snail (Pomacea canaliculata); Family Lymnaeidae such as the lymnae snail (Austropeplea ollula).
[0048] Nematoda: Aphelenchoididae, such as the rice root-lesion nematode (Aphelenchoides besseyi); Pratylenchidae, such as Pratylenchus coffeae, Pratylenchus brachyurus, Pratylenchus neglectus, and Radopholus similis; Meloidogyne javanica, Meloidogyne incognita, guava root-knot nematodes (Meloidogyne enterolobii), Meloidogyne hapla, soybean cyst nematode (Heterodera glycines), potato cyst nematode (Globodera Heteroderidae such as Globodera rostochiensis, potato white cyst nematode (Globodera pallida), and Colombian root-knot nematode (Meloidogyne chitwoodi); Hoplolaimidae such as Rotylenchulus reniformis; Anguinidae such as Nothotylenchus acris and Ditylenchus dipsaci; Tylenchulidae such as Tylenchulus semipenetrans; Longidoridae such as Xiphinema index; Trichodoridae; Parasitaphelenchidae such as Bursaphelenchus xylophilus.
[0049] The harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes may be harmful insects, harmful arthropods such as harmful mites, harmful mollusks, and harmful nematodes that have reduced chemical sensitivity or have developed chemical resistance to insecticides, acaricides, molluscicides, or nematocides.
[0050] The method for controlling arthropod pests of the present invention is carried out by applying an effective amount of the compound of the present invention or composition A directly to the arthropod pests and / or to the habitat of the arthropod pests (plants, soil, houses, animals, etc.). Examples of the method for controlling arthropod pests of the present invention include foliage treatment, soil treatment, root treatment, shower treatment, fumigation treatment, water surface treatment, and seed treatment.
[0051] The compound of the present invention or Composition A is typically formulated into aqueous suspensions, oil suspensions, oil solutions, emulsifiable concentrates, emulsions, microemulsions, microcapsule formulations, wettable powders, water dispersible granules, dusts, granules, tablets, aerosols, resin formulations, etc. by mixing an inactive inactivated carrier such as a solid carrier, a liquid carrier, or a gaseous carrier with a surfactant, and optionally adding formulation adjuvants such as binders, dispersants, and stabilizers. In addition to these formulations, the compound of the present invention or Composition A can also be formulated into dosage forms described in the Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271 to 276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN:0259-2517. These formulations typically contain 0.0001 to 99% by weight of the compound of the present invention or Composition A.
[0052] Examples of solid carriers include clay (pyrophyllite clay, kaolin clay, etc.), talc, calcium carbonate, diatomaceous earth, zeolite, bentonite, acid clay, attapulgite, white carbon, ammonium sulfate, vermiculite, perlite, pumice, silica sand, fine powder and granular chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), and resins (polyethylene, polypropylene, polyester, polyurethane, polyamide, polyvinyl chloride, etc.).
[0053] Examples of liquid carriers include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, etc.), aromatic hydrocarbons (xylene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, methyl oleate, propylene carbonate, etc.), nitriles (acetonitrile, etc.), ethers (ethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, N,N-dimethyloctanamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.), fatty acids (oleic acid, etc.), and vegetable oils (soybean oil, etc.).
[0054] Examples of gaseous carriers include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide gas.
[0055] Examples of surfactants include nonionic surfactants (polyoxyethylene alkyl ethers, polyoxyethylene alkylaryl ethers, polyethylene glycol fatty acid esters, etc.) and anionic surfactants (alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, etc.).
[0056] Other formulation adjuvants include binders, dispersants, colorants, stabilizers, etc., and specific examples include polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acids, etc.), acid isopropyl phosphate, and dibutylhydroxytoluene.
[0057] In addition, adjuvants can be used as components that enhance or support the efficacy of the compound of the present invention. Specific examples include Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol (registered trademark), Silwet L-77 (registered trademark), BreakThru (registered trademark), Sundance II (registered trademark), Induce (registered trademark), Penetrator (registered trademark), AgriDex (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), and BANOLE (registered trademark).
[0058] In the present invention, the plant includes the whole plant, stems and leaves, flowers, spikes, fruits, trunks, branches, crowns, seeds, vegetative reproductive organs, and seedlings.
[0059] Vegetative reproductive organs refer to plant roots, stems, leaves, and other parts that can grow when separated from the main body and placed in soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms (or solid bulbs), tubers, rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. Stolons are sometimes called runners, and propagules are also called bulbils and are divided into broad buds and bulbils. Vines refer to shoots (a collective term for leaves and stems) of plants such as sweet potatoes and Japanese yams. Bulbs, corms, tubers, rhizomes, stem fragments, rhizophores, and tuberous roots are collectively called bulbils. Potato cultivation begins by planting tubers in the soil, and the tubers used are generally called seed potatoes.
[0060] Examples of the method for controlling harmful arthropods by applying an effective amount of the compound of the present invention or composition A to soil include a method of applying an effective amount of the compound of the present invention or composition A to soil before or after planting a plant. More specifically, for example, planting hole treatment (spraying in planting holes, mixing in planting hole treatment soil), plant base treatment (spraying in planting holes, mixing in plant base soil, plant base irrigation, plant base treatment in the latter half of the seedling raising period), planting furrow treatment (spraying in planting furrows, mixing in planting furrow soil), row treatment (row spraying, row soil mixing, row spraying in the growing season), row treatment at sowing (row spraying at sowing, mixing in row soil at sowing), overall treatment (overall soil spraying, overall soil mixing), side row treatment, water surface treatment (water surface application, water surface application after flooding), other soil spray treatments (foliar spraying of granules during the growing season, spraying under the crown or around the main trunk, soil surface spraying, soil surface mixing, seeding hole spraying, furrow surface spraying, spraying between plants), and others. Other irrigation treatments include soil irrigation, seedling irrigation, chemical injection treatment, ground level irrigation, chemical drip irrigation, chemigation), seedling tray treatments (seedling tray spraying, seedling tray irrigation, seedling tray flooding), seedling tray treatments (seedling tray spraying, seedling tray irrigation, seedling tray flooding), seedling bed treatments (seedling bed spraying, seedling bed irrigation, water seedling bed spraying, seedling immersion), bed soil mixing treatments (bed soil mixing, bed soil mixing before sowing, spraying before soil covering at sowing, spraying after soil covering at sowing, covering soil mixing), and other treatments (hilling soil mixing, plowing in, topsoil mixing, rain-drop soil mixing, planting position treatment, granular inflorescence spraying, paste fertilizer mixing).
[0061] Seed treatments include, for example, treatment of seeds or vegetative reproductive organs with the compound of the present invention or Composition A. More specifically, examples include spray treatments in which a suspension of the compound of the present invention or Composition A is sprayed onto the surface of seeds or vegetative reproductive organs in a mist; smear treatments in which the compound of the present invention or Composition A is applied to seeds or vegetative reproductive organs; immersion treatments in which seeds or vegetative reproductive organs are immersed in a solution of the compound of the present invention or Composition A for a certain period of time; and methods of coating seeds or vegetative reproductive organs with a carrier containing the compound of the present invention or Composition A (film coating treatment, pellet coating treatment, etc.). Seed potatoes are particularly examples of the vegetative reproductive organs mentioned above. When applying Composition A to seeds or vegetative reproductive organs, Composition A can be applied to the seeds or vegetative reproductive organs as a single formulation, or different formulations of Composition A can be applied to the seeds or vegetative reproductive organs in multiple separate applications. Examples of methods for treating seeds or vegetative reproductive organs with multiple different formulations of Composition A include a method of treating seeds or vegetative reproductive organs with a formulation containing only the compound of the present invention as an active ingredient, air-drying the seeds or vegetative reproductive organs, and then treating with a formulation containing this ingredient; and a method of treating seeds or vegetative reproductive organs with a formulation containing both the compound of the present invention and this ingredient as active ingredients, air-drying the seeds or vegetative reproductive organs, and then treating with a formulation containing a component other than the component already treated. In the present invention, "seeds or vegetative reproductive organs carrying the compound of the present invention or Composition A" refers to seeds or vegetative reproductive organs to which the compound of the present invention or Composition A is attached. The seeds or vegetative reproductive organs carrying the compound of the present invention or Composition A may have materials other than the compound of the present invention or Composition A attached to them before or after the compound of the present invention or Composition A is attached to the seeds or vegetative reproductive organs. Furthermore, when Composition A is attached to the surface of the seeds or vegetative reproductive organs in layers, the layers may consist of one layer or multiple layers. Furthermore, when the layer consists of multiple layers, each layer may contain one or more active ingredients, or may consist of a layer containing one or more active ingredients and a layer containing no active ingredients. Seeds or vegetative reproductive organs carrying the compound of the present invention or Composition A can be obtained, for example, by applying a formulation containing the compound of the present invention or Composition A to seeds or vegetative reproductive organs by the seed treatment method described above.
[0062] When the compound of the present invention or composition A is used for controlling harmful arthropods in the agricultural field, the application amount is 10,000 m 2 The amount of the compound of the present invention is usually 1 to 10,000 g per kg of seed or vegetative reproductive organ. When treating seeds or vegetative reproductive organs, the compound of the present invention is usually applied in an amount within the range of 0.001 to 100 g per kg of seed or vegetative reproductive organ. When the compound of the present invention or Composition A is formulated as an emulsifiable concentrate, wettable powder, flowable concentrate, etc., it is usually applied after being diluted with water to an active ingredient concentration of 0.01 to 10,000 ppm, and granules, dusts, etc. are usually applied as is.
[0063] The compound of the present invention or composition A can also be applied by wrapping a resin preparation in the form of a sheet or string around the crop, stretching it near the crop, or spreading it on the soil around the base of the plant.
[0064] When the compound of the present invention or composition A is used to control harmful arthropods living in houses, the application amount is 1 / 2 m / day for surface treatment. 2 The amount of the compound of the present invention per square meter is usually 0.01 to 1,000 mg. 3 When the compound of the present invention or Composition A is formulated as an emulsifiable concentrate, wettable powder, flowable concentrate or the like, it is usually applied after diluting with water so that the active ingredient concentration becomes 0.1 to 10,000 ppm, whereas oil solutions, aerosols, fumigants, poison baits and the like are applied as they are.
[0065] When the compound of the present invention or Composition A is used to control ectoparasites in livestock such as cattle, horses, pigs, sheep, goats, and chickens, or small animals such as dogs, cats, rats, and mice, it can be administered to animals by methods known in veterinary medicine. Specific methods of administration include, for example, administration by tablet, incorporation into feed, suppository, or injection (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.) for systemic control, and administration by methods such as spraying an oil or aqueous liquid, pour-on application, spot-on application, washing the animal with a shampoo formulation, or attaching a resin formulation to the animal as a collar or ear tag. When administered to animals, the amount of the compound of the present invention or Composition A is usually in the range of 0.1 to 1000 mg per kg of the animal's body weight.
[0066] The compound of the present invention or Composition A can be used as an agent for controlling harmful arthropods in agricultural lands such as fields, paddy fields, lawns, orchards, etc. Examples of plants include the following.
[0067] Corn (horse-tooth, hard grain, soft grain, explosive, glutinous, sweet, field corn), rice (long grain, short grain, medium grain, japonica, tropical japonica, indica, javanica, paddy rice, upland rice, floating rice, direct-seeded rice, transplanted rice, glutinous rice), wheat (bread wheat (hard, soft, medium, red wheat, white wheat), durum wheat, spelt wheat, club wheat, each winter wheat type, spring wheat type), barley (two-row barley (= beer barley), six-row barley, naked barley, waxy barley, each winter barley type, spring barley type), rye (winter rye type, spring rye type), triticale (winter triticale type, spring triticale type), oats (winter oat type, spring oat type), sorghum, cotton (upland type, pima type), soybean (fully harvested seed varieties, edamame varieties, green-harvested varieties, indeterminate, determinate, semi-determinate types), peanuts, buckwheat, sugar beet (sugar production, animal feed, root vegetable, leafy vegetable, fuel), rapeseed (winter rapeseed type, spring rapeseed type), canola (winter canola type, spring canola type), sunflower (oil production, food, ornamental), sugarcane, tobacco, tea plant, mulberry, solanaceous vegetables (eggplant, tomato, bell pepper, chili pepper) , potatoes, etc.), Cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon, etc.), Cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard greens, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, garland chrysanthemum, artichoke, lettuce, etc.), Liliaceae vegetables (leeks, onions, garlic, asparagus, etc.), Umbelliferae vegetables (carrots, parsley, celery, parsley, etc.), Chenopodiaceae vegetables (spinach, Swiss chard, etc.), Lamiaceae vegetables (perilla, mint, basil, etc.), strawberries, sweet potatoes, yams, scallions, Sweet potatoes, pome fruits (apples, European pears, Japanese pears, Chinese pears, quince, quince, etc.), stone fruits (peaches, plums, nectarines, plums, cherries, apricots, prunes, etc.), citrus fruits (Satsuma mandarins, oranges, lemons, limes, grapefruits, etc.), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashew nuts, macadamia nuts, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, figs, olives, loquats, bananas, coffee, dates, coconuts, ornamental plants, forest plants,Turfgrass, pasture grass,
[0068] The above-mentioned plants are not particularly limited as long as they are varieties that are commonly cultivated, and include plants that can be produced by natural crossbreeding, plants that can be generated by mutation, F1 hybrid plants, and genetically modified crops. Examples of genetically modified crops include plants that have been conferred resistance to herbicides such as HPPD (4-hydroxyphenylpyruvate dioxygenase enzyme) inhibitors such as isoxaflutole, ALS (acetolactate synthase) inhibitors such as imazethapyr and thifensulfuron methyl, EPSP (5-enolpyruvylshikimate-3-phosphate synthase) inhibitors, glutamine synthetase inhibitors, PPO (protoporphyrinogen oxidase) inhibitors, bromoxynil, or dicamba; plants that are capable of synthesizing selective toxins known to be found in the genus Bacillus, such as Bacillus thuringiensis; and plants that can be conferred specific insecticidal activity by synthesizing gene fragments that partially match endogenous genes derived from harmful insects and inducing gene silencing (RNAi; RNA interference) in the target harmful insect.
[0069] The present invention will be explained in more detail below with reference to production examples, formulation examples, and test examples, but the present invention is not limited to these examples. In this specification, Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, i-Pr represents an isopropyl group, Bu represents a butyl group, t-Bu represents a tert-butyl group, Boc represents a tert-butoxycarbonyl group, Hex represents a hexyl group, c-Pr represents a cyclopropyl group, c-Bu represents a cyclobutyl group, Ph represents a phenyl group, Py2 represents a 2-pyridyl group, Py3 represents a 3-pyridyl group, and Py4 represents a 4-pyridyl group. When c-Pr, c-Bu, Ph, Py2, Py3, and Py4 are substituted with a substituent, the substituent and the substitution position are written before the symbol. For example, 1-CN-c-Pr represents a 1-cyanocyclopropyl group, 3,4-F2-Ph represents a 3,4-difluorophenyl group, and 4-CF3-Py2 represents a 4-(trifluoromethyl)-2-pyridyl group.
[0070] First, examples of the preparation of the compounds of the present invention and their intermediates will be shown.
[0071] When the physical properties of a compound are measured by liquid chromatography / mass spectrometry (hereinafter referred to as LCMS), the measured molecular ion value [M+H] + or [M-H] - and retention time (hereinafter referred to as RT). The conditions for liquid chromatography (hereinafter referred to as LC) are as follows:
[0072] [LC conditions] Column: L-column 2 ODS, inner diameter 4.6 mm, length 30 mm, particle size 3 μm (Chemicals Evaluation and Research Institute, Japan) UV measurement wavelength: 254 nm Mobile phase: Solution A: 0.1% formic acid aqueous solution, Solution B: 0.1% formic acid acetonitrile Flow rate: 2.0 mL / min Gradient conditions: Solution was delivered at the concentration gradient shown in [Table LC1].
[0073]
[0074] [MS conditions] Detector: LCMS-2020 (Shimadzu Corporation) Ionization method: DUIS method
[0075] Reference Production Example 1: To a mixture of 5.9 g of ethyl 3-(trifluoromethyl)-1H-pyrazole-5-carboxylate and 70 mL of THF, 9.0 g of triphenylphosphine, 5.3 mL of 2-(tert-butoxycarbonylamino)-1-ethanol, and 10 g of bis(2-methoxyethyl)azodicarboxylate were added at 0°C, and the mixture was stirred at room temperature for 6 hours. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 7.8 g of intermediate 1 represented by the following formula: Intermediate 1: 1 H-NMR (CDCl3) δ: 7.09 (1H, s), 4.79 (1H, br s), 4.74-4.71 (2H, m), 4.37 (2H, q), 3.63 (2H, q), 1.40-1.37 (12H, m).
[0076] Reference Production Example 2: To a mixture of 0.51 g of Intermediate 1 and 5 mL of cyclopentyl methyl ether, 6 mL of hydrogen chloride solution (approximately 4 mol / L cyclopentyl methyl ether solution) was added at 0°C, and the mixture was stirred at room temperature for 4 hours, and the resulting mixture was concentrated under reduced pressure. A saturated aqueous sodium carbonate solution was added to the resulting residue, and the mixture was stirred at room temperature for 3 hours, followed by extraction with chloroform containing 25% 2-propanol. The resulting organic layer was dried over sodium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.26 g of Intermediate 2 represented by the following formula: Intermediate 2: 1 H-NMR (CDCl3) δ: 7.12 (1H, s), 6.16 (1H, br s), 4.48 (2H, t), 3.87-3.83 (2H, m).
[0077] Production Example 1: To a mixture of 0.1 g of 6-bromo-3,4-dihydroisoquinolin-1(2H)-one, 0.09 g of 2-fluoro-N,N-dimethylpyridine-3-sulfonamide, and 4 mL of dimethylformamide, 0.040 g of sodium hydride (oily, 60%) was added at 0°C under a nitrogen atmosphere, and the mixture was stirred at 0°C for 4 hours. Water was added to the resulting mixture, and the mixture was extracted with ethyl acetate. The resulting organic layer was dried over magnesium sulfate and concentrated under reduced pressure. The resulting residue was subjected to silica gel column chromatography to obtain 0.05 g of the present compound 1, which is represented by the following formula: Compound 1 of the present invention: LCMS: 410 [M+H] + , RT = 1.64 minutes
[0078] Production Example 2 Compounds produced in accordance with Production Example 1 and their physical properties are shown below. Compound 2 of the present invention: 1 H-NMR (CDCl3) δ: 8.79 (1H, dd), 8.43 (1H, dd), 8.32 (1H, d), 7.55 (1H, dd), 7.37 (1H, d), 4.12-4.20 (1H, m), 3.90-3.96 (1H, m), 3.68-3.77 (1H, m), 3.20-3.24 (1H, m), 2.76 (6H, s).
[0079] Compound 3 of the present invention: 1 H-NMR (CDCl3) δ: 8.79 (1H, dd), 8.75 (1H, d), 8.49 (1H, d), 8.43 (1H, dd), 7.55 (1H, dd), 4.12-4.19 (1H, m), 3.92-3.97 (1H, m), 3.63-3.72 (1H, m), 3.19-3.25 (1H, m), 2.77 (6H, s).
[0080] Production Example 3: To a mixture of 0.3 g of Intermediate 2, 0.3 g of 2-fluoro-N,N-dimethylpyridine-3-sulfonamide, and 5 mL of dimethyl sulfoxide, 0.95 g of cesium carbonate was added and stirred for 10 hours at 40° C. The resulting mixture was allowed to cool to room temperature, water was added, and the precipitated solid was filtered off to obtain 0.38 g of Compound 4 of the present invention represented by the following formula. Compound 4 of the present invention: 1 H-NMR (CDCl3) δ: 8.80 (1H, dd), 8.42 (1H, dd), 7.59 (1H, dd), 7.18 (1H, s), 4.79-4.87 (1H, m), 4.61-4.65 (1H, m), 4.34-4.41 (1H, m), 4.00-4.05 (1H, m), 2.78 (6H, s).
[0081] Next, examples of the compound of the present invention that can be produced according to any of the production methods described in the Examples and the production methods described in this specification are shown below.
[0082] Formula (L-1) In the compound represented by the formula (hereinafter referred to as compound (L-1)), R 2a and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX1).
[0083]
[0084] In compound (L-1), R 2ais a methyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX2). 2a is a methyl group, and R 2b is a methyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX3). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX4). 2a , and R 2b is an ethyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX5). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX6). 2a , and R 2b is a propyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX7). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as Compound Group SX8).2a and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX9). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX10). 2a , and R 2b is a methyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX11). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX12). 2a , and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX13). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX14). 2a , and R 2b is a propyl group, and R 6c is a fluorine atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX15). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX16). 2a and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX17). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX18). 2a , and R 2b is a methyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX19). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX20). 2a , and R 2b is an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX21). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX22). 2a , and R 2b is a propyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX23). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX24). 2a and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX25). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX26). 2a , and R 2b is a methyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX27). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX28). 2a , and R 2b is an ethyl group, and R 6c is a bromine atom, and R6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX29). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX30). 2a , and R 2b is a propyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX31). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX32). 2a and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX33). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX34). 2a , and R 2b is a methyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX35). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6cis an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX36). 2a , and R 2b is an ethyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX37). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX38). 2a , and R 2b is a propyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX39). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX40).
[0085] Formula (L-2) In the compound represented by the formula (hereinafter referred to as compound (L-2)), R 2a and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX41).
[0086] In compound (L-2), R 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX42). 2a is a methyl group, and R 2b is a methyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX43). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX44). 2a , and R 2b is an ethyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX45). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX46). 2a , and R 2b is a propyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX47). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX48). 2a and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX49). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX50). 2a , and R 2b is a methyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX51). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX52). 2a , and R 2b is an ethyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX53). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX54). 2a , and R 2b is a propyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX55). 2a is a methyl group, and R 2b is an ethyl group, and R 6bis a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX56). 2a and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX57). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX58). 2a , and R 2b is a methyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX59). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX60). 2a , and R 2b is an ethyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX61). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX62). 2a , and R 2b is a propyl group, and R 6bis a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX63). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX64). 2a and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX65). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX66). 2a , and R 2b is a methyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX67). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX68). 2a , and R 2b is an ethyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX69). 2a is a propyl group, and R 2b is a hydrogen atom, and R6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX70). 2a , and R 2b is a propyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX71). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX72). 2a and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX73). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX74). 2a , and R 2b is a methyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX75). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX76). 2a , and R 2b is an ethyl group, and R6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX77). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX78). 2a , and R 2b is a propyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX79). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX80).
[0087] Formula (L-3) In the compound represented by the formula (hereinafter referred to as compound (L-3)), R 2a and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX81).
[0088] In compound (L-3), R 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX82). 2a is a methyl group, and R 2b is a methyl group, and R 6c is a hydrogen atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX83). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX84). 2a , and R 2b is an ethyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX85). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX86). 2a , and R 2b is a propyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX87). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX88). 2a and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX89). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX90). 2a , and R 2b is a methyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX91). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX92). 2a , and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX93). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX94). 2a , and R 2b is a propyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX95). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX96). 2a and R 2b is a hydrogen atom, and R 6cis a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX97). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX98). 2a , and R 2b is a methyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX99). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX100). 2a , and R 2b is an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX101). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX102). 2a , and R 2b is a propyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX103). 2a is a methyl group, and R 2b is an ethyl group, and R6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX104). 2a and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX105). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX106). 2a , and R 2b is a methyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX107). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX108). 2a , and R 2b is an ethyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX109). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX110). 2a , and R 2bis a propyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX111). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX112). 2a and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX113). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX114). 2a , and R 2b is a methyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX115). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX116). 2a , and R 2b is an ethyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX117). 2ais a propyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX118). 2a , and R 2b is a propyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX119). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX120).
[0089] Formula (L-4) In the compound represented by the formula (hereinafter referred to as compound (L-4)), R 2a and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX121).
[0090] In compound (L-4), R 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX122). 2a is a methyl group, and R 2b is a methyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX123). 2a is an ethyl group, and R 2b is a hydrogen atom, and R6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX124). 2a , and R 2b is an ethyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX125). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX126). 2a , and R 2b is a propyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX127). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX128). 2a and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX129). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX130). 2a , and R 2bis a methyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX131). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX132). 2a , and R 2b is an ethyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX133). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX134). 2a , and R 2b is a propyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX135). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX136). 2a and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX137). 2ais a methyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX138). 2a , and R 2b is a methyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX139). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX140). 2a , and R 2b is an ethyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX141). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX142). 2a , and R 2b is a propyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX143). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX144).2a and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX145). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX146). 2a , and R 2b is a methyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX147). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX148). 2a , and R 2b is an ethyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX149). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX150). 2a , and R 2b is a propyl group, and R 6b is a bromine atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX151). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX152). 2a and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX153). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX154). 2a , and R 2b is a methyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX155). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX156). 2a , and R 2b is an ethyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX157). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6bis an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX158). 2a , and R 2b is a propyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX159). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX160).
[0091] Formula (L-5) In the compound represented by the formula (hereinafter referred to as compound (L-5)), R 2a and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX161).
[0092] In compound (L-5), R 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX162). 2a is a methyl group, and R 2b is a methyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX163). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX164). 2a , and R 2b is an ethyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX165). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX166). 2a , and R 2b is a propyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX167). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX168). 2a and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX169). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX170). 2a , and R 2b is a methyl group, and R 6c is a fluorine atom, and R6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX171). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX172). 2a , and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX173). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX174). 2a , and R 2b is a propyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX175). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX176). 2a and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX177). 2a is a methyl group, and R 2b is a hydrogen atom, and R6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX178). 2a , and R 2b is a methyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX179). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX180). 2a , and R 2b is an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX181). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX182). 2a , and R 2b is a propyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX183). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX184). 2a and R 2bis a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX185). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX186). 2a , and R 2b is a methyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX187). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX188). 2a , and R 2b is an ethyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX189). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX190). 2a , and R 2b is a propyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX191). 2a is a methyl group, and R2b is an ethyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX192). 2a and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX193). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX194). 2a , and R 2b is a methyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX195). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX196). 2a , and R 2b is an ethyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX197). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX198).2a , and R 2b is a propyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX199). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX200).
[0093] Formula (L-6) In the compound represented by the formula (hereinafter referred to as compound (L-6)), R 2a and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX201).
[0094] In compound (L-6), R 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX202). 2a is a methyl group, and R 2b is a methyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX203). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX204). 2a , and R 2b is an ethyl group, and R6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX205). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX206). 2a , and R 2b is a propyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX207). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a hydrogen atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX208). 2a and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX209). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX210). 2a , and R 2b is a methyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX211). 2a is an ethyl group, and R2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX212). 2a , and R 2b is an ethyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX213). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX214). 2a , and R 2b is a propyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX215). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX216). 2a and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX217). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX218).2a , and R 2b is a methyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX219). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX220). 2a , and R 2b is an ethyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX221). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX222). 2a , and R 2b is a propyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX223). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX224). 2a and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX225). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX226). 2a , and R 2b is a methyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX227). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX228). 2a , and R 2b is an ethyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX229). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX230). 2a , and R 2b is a propyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX231). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a bromine atom, and R6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX232). 2a and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX233). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX234). 2a , and R 2b is a methyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX235). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX236). 2a , and R 2b is an ethyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX237). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX238). 2a , and R 2b is a propyl group, and R 6bis an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX239). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX240).
[0095] Formula (L-7) In the compound represented by the formula (hereinafter referred to as compound (L-7)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX241).
[0096]
[0097]
[0098] In compound (L-7), R 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX242). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX243). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX244).2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX245). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX246). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX247). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX248).
[0099] Formula (L-8) In the compound represented by the formula (hereinafter referred to as compound (L-8)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX249). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX250). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX251). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX252). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX253). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX254). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX255). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX256).
[0100] Formula (L-9) In the compound represented by the formula (hereinafter referred to as compound (L-9)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX257).2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX258). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX259). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX260). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX261). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX262). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX263). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX264).
[0101] Formula (L-10) In the compound represented by the formula (hereinafter referred to as compound (L-10)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX265). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX266). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX267). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX268). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX269). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX270). 2a and R 2b is a methyl group, and R3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX271). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX272).
[0102] Formula (L-11) In the compound represented by the formula (hereinafter referred to as compound (L-11)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX273). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX274). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX275). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX276). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX277). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX278). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX279). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX280).
[0103] Formula (L-12) In the compound represented by the formula (hereinafter referred to as compound (L-12)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX281). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX282). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX283).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX284). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX285). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX286). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX287). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX288).
[0104] Formula (L-13) In the compound represented by the formula (hereinafter referred to as compound (L-13)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX289). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX290). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX291). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX292). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX293). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX294). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX295). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX296).
[0105] Formula (L-14) In the compound represented by the formula (hereinafter referred to as compound (L-14)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX297). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX298). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX299). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX300). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX301). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX302). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX303). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX304).
[0106] Formula (L-15) In the compound represented by the formula (hereinafter referred to as compound (L-15)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX305). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX306). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX307). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX308). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX309). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX310). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX311). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX312).
[0107] Formula (L-16) In the compound represented by the formula (hereinafter referred to as compound (L-16)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX313). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX314). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX315).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX316). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX317). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX318). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX319). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX320).
[0108] Formula (L-17) In the compound represented by the formula (hereinafter referred to as compound (L-17)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX321). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX322). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX323). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX324). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX325). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX326). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX327). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX328).
[0109] Formula (L-18) In the compound represented by the formula (hereinafter referred to as compound (L-18)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX329). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX330). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX331). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX332). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX333). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX334). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX335). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX336).
[0110] Formula (L-19) In the compound represented by the formula (hereinafter referred to as compound (L-19)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX337). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX338). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX339). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX340). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX341). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX342). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX343). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX344).
[0111] Formula (L-20) In the compound represented by the formula (hereinafter referred to as compound (L-20)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX345). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX346). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX347).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX348). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX349). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX350). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX351). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX352).
[0112] Formula (L-21) In the compound represented by the formula (hereinafter referred to as compound (L-21)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX353). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX354). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX355). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX356). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX357). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX358). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX359). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX360).
[0113] Formula (L-22) In the compound represented by the formula (hereinafter referred to as compound (L-22)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX361). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX362). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX363). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX364). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX365). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX366). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX367). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX368).
[0114] Formula (L-23) In the compound represented by the formula (hereinafter referred to as compound (L-23)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX369). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX370). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX371). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX372). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX373). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX374). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX375). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX376).
[0115] Formula (L-24) In the compound represented by the formula (hereinafter referred to as compound (L-24)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX377). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX378). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX379).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX380). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX381). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX382). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX383). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX384).
[0116] Formula (L-25) In the compound represented by the formula (hereinafter referred to as compound (L-25)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX385). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX386). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX387). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX388). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX389). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX390). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX391). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX392).
[0117] Formula (L-26) In the compound represented by the formula (hereinafter referred to as compound (L-26)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX393). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX394). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX395). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX396). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX397). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX398). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX399). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX400).
[0118] Formula (L-27) In the compound represented by the formula (hereinafter referred to as compound (L-27)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX401). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX402). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX403). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX404). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX405). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX406). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX407). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX408).
[0119] Formula (L-28) In the compound represented by the formula (hereinafter referred to as compound (L-28)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX409). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX410). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX411).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX412). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX413). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX414). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX415). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX416).
[0120] Formula (L-29) In the compound represented by the formula (hereinafter referred to as compound (L-29)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX417). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX418). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX419). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX420). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX421). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX422). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX423). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX424).
[0121] Formula (L-30) In the compound represented by the formula (hereinafter referred to as compound (L-30)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX425). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX426). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX427). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX428). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX429). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX430). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX431). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX432).
[0122] Formula (L-31) In the compound represented by the formula (hereinafter referred to as compound (L-31)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX433). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX434). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX435). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX436). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX437). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX438). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX439). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX440).
[0123] Formula (L-32) In the compound represented by the formula (hereinafter referred to as compound (L-32)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX441). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX442). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX443).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX444). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX445). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX446). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX447). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX448).
[0124] Formula (L-33) In the compound represented by the formula (hereinafter referred to as compound (L-33)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX449). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX450). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX451). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX452). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX453). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX454). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX455). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX456).
[0125] Formula (L-34) In the compound represented by the formula (hereinafter referred to as compound (L-34)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX457). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX458). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX459). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX460). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX461). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX462). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX463). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX464).
[0126] Formula (L-35) In the compound represented by the formula (hereinafter referred to as compound (L-35)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX465). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX466). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX467). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX468). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX469). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX470). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX471). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX472).
[0127] Formula (L-36) In the compound represented by the formula (hereinafter referred to as compound (L-36)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX473). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX474). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX475).2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX476). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX477). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX478). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX479). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX480).
[0128] Formula (L-37) In the compound represented by the formula (hereinafter referred to as compound (L-37)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX481). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX482). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX483). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX484). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX485). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX486). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX487). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX488).
[0129] Formula (L-38) In the compound represented by the formula (hereinafter referred to as compound (L-38)), R 2a and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX489). 2a and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX490). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX491). 2a is a methyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX492). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3b is a hydrogen atom, and R 3d is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX493). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX494). 2a and R 2b is a methyl group, and R 3b is a hydrogen atom, and R 3dis any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX495). 2a and R 2b is a methyl group, and R 3d is a hydrogen atom, and R 3b is any one of the substituents shown in Tables 7A to 15A (hereinafter referred to as compound group SX496).
[0130] Formula (L-39) In the compound represented by the formula (hereinafter referred to as compound (L-39)), R 2a and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX497). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX498). 2a , and R 2b is a methyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX499). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX500). 2a , and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX501).2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX502). 2a , and R 2b is a propyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX503). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX504). 2a and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX505). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX506). 2a , and R 2b is a methyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX507). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX508). 2a , and R 2b is an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX509). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX510). 2a , and R 2b is a propyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX511). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX512). 2a and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX513). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX514). 2a , and R 2b is a methyl group, and R 6c is a bromine atom, and R6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX515). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX516). 2a , and R 2b is an ethyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX517). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX518). 2a , and R 2b is a propyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX519). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX520). 2a and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX521). 2a is a methyl group, and R 2b is a hydrogen atom, and R6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX522). 2a , and R 2b is a methyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX523). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX524). 2a , and R 2b is an ethyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX525). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX526). 2a , and R 2b is a propyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX527). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX528).
[0131] Formula (L-40) In the compound represented by the formula (hereinafter referred to as compound (L-40)), R 2a and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX529). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX530). 2a , and R 2b is a methyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX531). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX532). 2a , and R 2b is an ethyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX533). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX534). 2a , and R 2b is a propyl group, and R 6b is a fluorine atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX535). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX536). 2a and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX537). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX538). 2a , and R 2b is a methyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX539). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX540). 2a , and R 2b is an ethyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX541). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6bis a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX542). 2a , and R 2b is a propyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX543). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX544). 2a and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX545). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX546). 2a , and R 2b is a methyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX547). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX548). 2a , and R 2b is an ethyl group, and R6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX549). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX550). 2a , and R 2b is a propyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX551). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is a bromine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX552). 2a and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX553). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX554). 2a , and R 2b is a methyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX555). 2a is an ethyl group, and R2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX556). 2a , and R 2b is an ethyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX557). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX558). 2a , and R 2b is a propyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX559). 2a is a methyl group, and R 2b is an ethyl group, and R 6b is an iodine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX560).
[0132] Formula (L-41) In the compound represented by the formula (hereinafter referred to as compound (L-41)), R 2a and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX561). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6eis any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX562). 2a , and R 2b is a methyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX563). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX564). 2a , and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX565). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX566). 2a , and R 2b is a propyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX567). 2a is a methyl group, and R 2b is an ethyl group, and R 6c is a fluorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX568). 2a and R 2b is a hydrogen atom, and R 6cis a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX569). 2a is a methyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX570). 2a , and R 2b is a methyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX571). 2a is an ethyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX572). 2a , and R 2b is an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX573). 2a is a propyl group, and R 2b is a hydrogen atom, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX574). 2a , and R 2b is a propyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX575). 2a is a methyl group, and R 2bis an ethyl group, and R 6c is a chlorine atom, and R 6e is any one of the substituents shown in Tables 1A to 3A (hereinafter referred to as compound group SX576). 2a and R 2b is a hydrogen atom, and R ...
Claims
1. Equation (I) 【Chemistry 1】 [During the ceremony, Q is expressed by the following formula 【Chemistry 2】 This represents the group shown in formula Q1, the group shown in formula Q2, the group shown in formula Q3, the group shown in formula Q4, the group shown in formula Q5, the group shown in formula Q6, or the group shown in formula Q7 (# represents a bonding site with a sulfur atom, and ● represents a bonding site with Het). 【Transformation 3】 A 1 NR 5 , representing an oxygen atom or a sulfur atom, G 1 G 2 G 3 and G 4 The combination is, G 1 is a nitrogen atom or CR 3a where G 2 is CR 3b where G 3 is CR 3d where G 4 is CR 3c a combination; G 1 CR 3a G 2 is a nitrogen atom, G 3 CR 3d G 4 CR 3c The combinations that are; G 1 CR 3a G 2 CR 3b G 3 is a nitrogen atom, G 4 CR 3c The combination is; or G 1 CR 3a G 2 CR 3b G 3 CR 3d G 4 This represents a combination where the atom is a nitrogen atom. R 2a and R 2b This represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b These may, together with the nitrogen atom to which they are bonded, form an azilidinyl group, an azetidinyl group, a pyrrolidinyl group, or a piperidyl group. R 3a 、R 3b 、R 3c 、R 3d 、R 3f 、R 3g 、R 3i and R 3k are the same or different and may be substituted with one or more substituents selected from Group B, a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from Group E, a C3-C7 cycloalkyl group which may be substituted with one or more substituents selected from Group H, a phenyl group which may be substituted with one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from Group H, OR 12 、NR 11 R 12 、NR 11a R 12a 、NR 24 NR 11 R 12 、NR 24 OR 11 、NR 11 C(O)R 13 、NR 24 NR 11 C(O)R 13 、NR 11 C(O)OR 14 、NR 24 NR 11 C(O)OR 14 、NR 11 C(O)NR 31 R<000清00070>、NR 24 NR 11 C(O)NR 31 [[ID=清68]]R[[ID=6清9]] 32 、N=CHNR 31 R 32 、N=S(O) p R 15 R 16 、C(O)R 13 、C(O)OR 17 、C(O)NR 31 R 32 、C(O)NR 11 S(O) 2 R 23 、CR[[ID=清95]] 30 =NOR<000008清8>、NR 11 CR 24 =NOR It should be noted that there seem to be some unclear or incorrect parts in the original text, especially in the form of some tags and the repetition of certain content. The translation is carried out as accurately as possible based on the existing text. 17 , S(O) q R 23 , represents a cyano group, a nitro group, a hydrogen atom, or a halogen atom, R 3e and R 3h This represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from group H. When Q is a group represented by formula Q1, R 3a , R 3b and R 3d Among two adjacent substituents of, together with the two carbon atoms to which they are attached, a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring may be substituted with one or more substituents selected from group H}, or a triazole ring which may be substituted with one or more substituents selected from group I may be formed, p represents 0 or 1, q represents 0, 1, or 2. R 30 This is a C1-C6 chain hydrocarbon group, a halogen atom, OR which may be substituted with one or more halogen atoms. 35 , NR 36 R 37 , or representing a hydrogen atom, R 17 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group D, or a hydrogen atom. R 12 This may be a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group substituted with one or more substituents selected from group J, a C3-C7 cycloalkenyl group substituted with one or more substituents selected from group J, a phenyl group substituted with one or more substituents selected from group D, a 6-membered aromatic heterocyclic group substituted with one or more substituents selected from group D, a hydrogen atom, or S(O) 2 R 23 This represents, R 23 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from group D. R 11a and R 12a Together with the nitrogen atom to which they are bonded, they form a 3-7 member non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group E. R 13 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group D, a 5 or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group D, or a hydrogen atom. R 14 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl) C1-C3 alkyl group which may be substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl portion of the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from group D}. R 15 and R 16 This represents a C1-C6 alkyl group that is the same or different in phase and may be substituted with one or more halogen atoms. R 31 This represents a C1-C6 alkyl group or hydrogen atom which may be substituted with one or more halogen atoms. R 32 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group which may be substituted with one or more substituents selected from group J, or a hydrogen atom. Het represents the group shown in formula Het5, the group shown in formula Het6, or the group shown in formula Het7. 【Chemistry 4】 A 2 NR 5a , or CR 4a R 4d This represents, A 3 CR 4b R 4e This represents, A 4 NR 5b , or CR 4c R 4f This represents, W 1 This represents an oxygen atom or a sulfur atom, If Het is the base represented by formula Het5, B 1 , B 2 and B 3 The combination is, B 1 CR 6e B 2 is a nitrogen atom or CR 6b B 3 is a nitrogen atom or CR 6c The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 CR 6e B 3 is a nitrogen atom or CR 6c The combination is; or B 1 is a nitrogen atom or CR 6a B 2 is a nitrogen atom or CR 6b B 3 CR 6e This represents a combination of the following: If Het is the base represented by formula Het6, A 2 and A 4 The combination is, A 2 CR 4a R 4d A 4 NR 5b or CR 4c R 4f The combination is; or A 2 NR 5a A 4 CR 4c R 4f The combinations that are; B 1 , B 2 and B 3 The combination is, B 1 CR 6e B 2 is a nitrogen atom or CR 6b B 3 is a nitrogen atom or CR 6c The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 CR 6e B 3 is a nitrogen atom or CR 6c The combination is; or B 1 is a nitrogen atom or CR 6a B 2 is a nitrogen atom or CR 6b B 3 CR 6e This represents a combination of the following: If Het is the base represented by formula Het7, A 2 and A 4 The combination is, A 2 CR 4a R 4d A 4 NR 5b or CR 4c R 4f The combination is; or A 2 NR 5a A 4 CR 4c R 4f The combinations that are; B 1 , B 2 , B 3 and B 4 The combination is, B 1 is a nitrogen atom or CR 6a B 2 CR 6e B 3 is a nitrogen atom or CR 6c B 4 is a nitrogen atom or CR 6d The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 is a nitrogen atom or CR 6b B 3 CR 6e B 4 is a nitrogen atom or CR 6d The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 is a nitrogen atom or CR 6b B 3 CR 6c B 4 CR 6e The combinations that are; B 1 is a nitrogen atom or CR 6a B 2 CR 6b B 3 is a nitrogen atom, B 4 CR 6e The combination is; or B 1 CR 6a B 2 is a nitrogen atom, B 3 is a nitrogen atom, B 4 CR 6e This represents a combination of the following: R 4a , R 4b , R 4c , R 6a , R 6b , R 6c , and R 6d These are C1-C6 chain hydrocarbon groups, nitro groups, OR which may be the same or different in phase and substituted with one or more halogen atoms. 18 , NR 18 R 19 , represents a cyano group, an amino group, a halogen atom, or a hydrogen atom, R 4d , R 4e and R 4f This represents a C1-C6 chain hydrocarbon group, a cyano group, a halogen atom, or a hydrogen atom, which may be the same or different in phase and may be substituted with one or more halogen atoms. R 6e This includes a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms, a C3-C4 cycloalkyl group which may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms, and S(O). m R 7 , OR 7 , halogen atom, or OS(O) 2 R 7 This represents, R 5 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C6 alkoxy group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. R 5a and R 5b This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group K, which may be the same or different in phase, a C1-C6 alkoxy group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. R 7 This represents a C1-C6 chain hydrocarbon group substituted with one or more halogen atoms. m represents 0, 1, or 2. R 18 and R 35 This represents a C1-C6 chain hydrocarbon group that is the same or different in phase and may be substituted with one or more halogen atoms. R 11 , R 19 , R 24 , R 36 and R 37 This represents a C1-C6 chain hydrocarbon group, which may be the same or different in phase and may be substituted with one or more halogen atoms, or a hydrogen atom. Group B: A group consisting of C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted with one or more halogen atoms, C1-C6 alkylsulfanyl groups which may be substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups which may be substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups which may be substituted with one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted with one or more halogen atoms, cyano groups, hydroxyl groups, and halogen atoms. Group C: A group consisting of C1-C6 chain hydrocarbon groups which may be substituted with one or more halogen atoms, C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted with one or more halogen atoms, and halogen atoms. Group D: C1-C6 chain hydrocarbon groups that may be substituted with one or more halogen atoms, hydroxyl groups, C1-C6 alkoxy groups that may be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups that may be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups that may be substituted with one or more halogen atoms, sulfanyl groups, C1-C6 alkylsulfanyl groups that may be substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups that may be substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups that may be substituted with one or more halogen atoms, amino groups, NHR 21 , NR 21 R 22 , C(O)R 21 OC(O)R 21 , C(O)OR 21 A group consisting of cyano groups, nitro groups, and halogen atoms. R 21 and R 22 This represents a C1-C6 alkyl group that is the same or different in phase and may be substituted with one or more halogen atoms. Group E: A group consisting of C1-C6 chain hydrocarbon groups which may be substituted with one or more halogen atoms, C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted with one or more halogen atoms, halogen atoms, oxo groups, hydroxyl groups, cyano groups, and nitro groups. Group F: C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, phenyl groups which may be substituted with one or more substituents selected from Group D, 5 or 6-membered aromatic heterocyclic groups which may be substituted with one or more substituents selected from Group D, C3-C7 cycloalkyl groups which may be substituted with one or more halogen atoms, 3-7 membered non-aromatic heterocyclic groups which may be substituted with one or more substituents selected from Group C, amino groups, NHR 21 , NR 21 R 22 A group consisting of halogen atoms and cyano groups. Group H: C1-C6 alkyl groups, OR which may be substituted with one or more halogen atoms. 10 , NR 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 OC(O)R 9 , OC(O)OR 9 , NR 10 C(O)R 9 , NR 10 C(O)OR 9 , C(O)OR 10 A group consisting of halogen atoms, nitro groups, cyano groups, amino groups, and five- or six-membered aromatic heterocyclic groups. R 9 This represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms. R 10 This represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. Group I: A group consisting of C2-C6 chain hydrocarbon groups which may be substituted with one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted with one or more halogen atoms, phenyl groups which may be substituted with one or more substituents selected from Group D, 5 or 6-membered aromatic heterocyclic groups which may be substituted with one or more substituents selected from Group D, C2-C6 alkylcarbonyl groups which may be substituted with one or more halogen atoms, C2-C6 alkoxycarbonyl groups which may be substituted with one or more halogen atoms, aminocarbonyl groups, (C1-C6 alkyl)aminocarbonyl groups which may be substituted with one or more halogen atoms, methyl groups, and di(C1-C4 alkyl)aminocarbonyl groups which may be substituted with one or more halogen atoms. Group J: A group consisting of C1-C6 alkyl groups, halogen atoms, and cyano groups, which may be substituted with one or more halogen atoms. Group K: A group consisting of C1-C6 alkoxy groups which may be substituted with one or more halogen atoms, phenyl groups which may be substituted with one or more substituents selected from Group D, 5 or 6-membered aromatic heterocyclic groups which may be substituted with one or more substituents selected from Group D, C3-C7 cycloalkyl groups which may be substituted with one or more halogen atoms, and 3-7 membered non-aromatic heterocyclic groups which may be substituted with one or more substituents selected from Group C. The compound shown or its N oxide.
2. The compound according to claim 1, or its N oxide, wherein Q is a group represented by formula Q2, a group represented by formula Q3, or a group represented by formula Q4.
3. The compound according to claim 1, or its N oxide, wherein Q is a group represented by formula Q1 or a group represented by formula Q5.
4. The compound according to claim 1, or its N oxide, wherein Q is the group represented by formula Q5.
5. Q is the base shown by formula Q5, and G 1 CR 3a G 2 CR 3b G 3 CR 3d G 4 CR 3c The compound according to claim 1 or its N oxide.
6. Q is the base shown by formula Q5, and G 1 CR 3a G 2 CR 3b G 3 CR 3d G 4 CR 3c And R 3a is a hydrogen atom, R 3b R is a C1-C6 chain hydrocarbon group, a hydrogen atom, or a halogen atom which may be substituted with one or more substituents selected from group B, 3c is a hydrogen atom, R 3d The compound according to claim 1 or its N oxide, wherein is a C1-C6 chain hydrocarbon group, a hydrogen atom, or a halogen atom which may be substituted with one or more substituents selected from group B.
7. Het is the group represented by formula Het7, and A 2 CR 4a R 4d A 4 NR 5b And, W 1 The compound according to claim 1, or its N oxide, wherein is an oxygen atom.
8. A pest control composition comprising a compound according to any one of claims 1 to 7 or its N oxide and an inert carrier.
9. A composition containing one or more components selected from the group consisting of group (a), group (b), group (c), and group (d), and a compound or its N oxide according to any one of claims 1 to 7: Group (a): A group consisting of insecticidal components, acaricidal components, and nematicidal components; Group (b): bactericidal active ingredient; Group (c): plant growth regulating ingredients; Group (d): Repellent components.
10. A method for controlling harmful arthropods, comprising applying an effective amount of the compound or its N oxide described in any one of claims 1 to 7 to a harmful arthropod or to the habitat of a harmful arthropod.
11. A method for controlling harmful arthropods, comprising applying an effective amount of the composition described in claim 9 to a harmful arthropod or to the habitat of a harmful arthropod.
12. Seeds or vegetative reproductive organs that retain an effective amount of the compound or its N oxide according to any one of claims 1 to 7.
13. A seed or vegetative reproductive organ holding an effective amount of the composition described in claim 9.