Ammonia Gas Turbine for Slip Ammonia and NOx Reduction

Abstract

The present invention relates to a slip ammonia and NOx reduction ammonia gas turbine. A slip ammonia and NOx reduction ammonia gas turbine according to one embodiment of the present invention may include a combustion unit for burning ammonia, a rotary adsorption drum containing an adsorbent for adsorbing and treating slip ammonia contained in the flue gas of a combustor, and a post-treatment unit for removing NOx from the flue gas that has passed through the rotary adsorption drum and resupplying it to the rotary adsorption drum. The rotary adsorption drum may include an adsorption separation unit that separates ammonia adsorbed on the adsorbent using the thermal energy of the flue gas discharged from the combustor, an adsorption unit that adsorbs and removes slip ammonia contained in the flue gas that has passed through the adsorption separation unit, and a drum driving unit that rotates the rotary adsorption drum to switch the positions of the adsorption unit and the adsorption separation unit when the adsorption of ammonia in the adsorption unit becomes saturated.

Description

Technology Field

[0001] The present invention relates to an ammonia gas turbine for reducing slip ammonia and NOx, and more specifically, to a technology that minimizes the emission of slip ammonia contained in flue gas by adsorbing it with an adsorbent, separates and recovers the ammonia adsorbed by the adsorbent using the heat of the flue gas, and ensures combustion stability and minimizes NOx generation by preheating the ammonia gas. Background Technology

[0003] With the recent strengthening of international demands for carbon neutrality and greenhouse gas reduction, power generation technologies utilizing ammonia (NH3), a carbon-free fuel that emits no carbon dioxide (CO2), are garnering attention. Ammonia is easier to store and transport compared to hydrogen and features high compatibility with existing energy infrastructure. Due to these characteristics, ammonia holds significant potential as a gas turbine fuel, and power generation technologies utilizing it are regarded as an important alternative for a sustainable energy transition.

[0004] However, gas turbine systems using ammonia as fuel face several technical challenges. During the combustion process, some of the ammonia that does not fully react may leak out through exhaust outlets in the form of slip ammonia. Slip ammonia can react with NOx and SOx in the atmosphere to generate secondary particulate matter, or it may be classified as a toxic substance under the Occupational Safety and Health Act, potentially causing harmful effects to human health and the environment. These issues act as significant obstacles to the practical utilization of ammonia fuel.

[0005] Furthermore, since ammonia contains nitrogen, it generates a large amount of NOx during combustion. This causes air pollution and is highly likely to violate environmental regulations. Existing low-NOx combustor designs alone are insufficient to adequately address these issues, necessitating the parallel application of post-treatment equipment technology. In addition, ammonia has a high ignition temperature and a slow combustion speed, making it difficult to ensure combustion stability. In particular, there is a high probability of stalling or incomplete combustion occurring during low-load operation, requiring technical improvements for stable combustion. Against this backdrop, there is an urgent need for the development of technologies that can effectively reduce slip ammonia and NOx while ensuring combustion stability. Prior art literature

[0007] (Patent Document 0001) CN 118836065 A (2024.10.25)(Patent Document 0002) EP 2360360 A1 (2011.08.24)(Patent Document 0003) JP 3880353 B2 (2006.11.17)(Patent Document 0004) JP 7729461 B2 (2025.08.18) The problem to be solved

[0008] The objective of the present invention is to provide a slip ammonia and NOx reduction ammonia gas turbine that minimizes emissions by adsorbing slip ammonia contained in flue gas with an adsorbent, separates and recovers the ammonia adsorbed on the adsorbent using the heat of the flue gas, and ensures combustion stability and minimizes NOx generation by preheating the ammonia gas. means of solving the problem

[0010] In one embodiment of the present invention, a slip ammonia and NOx-reducing ammonia gas turbine may be provided. The slip ammonia and NOx-reducing ammonia gas turbine may include a combustor that burns ammonia, a rotary adsorption drum containing an adsorbent that adsorbs and treats slip ammonia contained in the flue gas of the combustor, and a post-treatment unit that removes NOx from the flue gas passing through the rotary adsorption drum and recirculates it to the rotary adsorption drum. The rotary adsorption drum may include an adsorption separation unit that separates ammonia adsorbed on the adsorbent using the thermal energy of the flue gas discharged from the combustor, an adsorption unit that adsorbs and removes slip ammonia contained in the flue gas passing through the adsorption separation unit, and a drum driving unit that rotates the rotary adsorption drum to switch the positions of the adsorption unit and the adsorption separation unit when the adsorption of ammonia in the adsorption unit becomes saturated.

[0011] In one embodiment of the present invention, the slip ammonia and NOx reduction ammonia gas turbine may include a flow path cover that sets the inflow and outflow paths of the exhaust gas such that the adsorption section and the adsorption separation section are configured identically in a form in which the movement paths of the exhaust gas are reversed from each other, and when the positions of the adsorption separation section and the adsorption section are rotated to be reversed, the functions of the adsorption separation section and the adsorption section are also reversed.

[0012] In one embodiment of the present invention, the adsorption separation unit may include an exhaust gas pipe through which the exhaust gas exchanges heat while passing through the adsorbent so as to separate ammonia adsorbed on the adsorbent by exchanging heat while the adsorbent and the exhaust gas are not in contact with each other.

[0013] In one embodiment of the present invention, the adsorption separation unit may include a preheating pipe through which the ammonia or air passes to preheat the ammonia or air supplied to the combustor by exchanging heat with the exhaust gas.

[0014] In one embodiment of the present invention, the adsorption unit may include an adsorption supply port for supplying the exhaust gas to the adsorbent so as to adsorb and remove slip ammonia contained in the exhaust gas by the adsorbent.

[0015] In one embodiment of the present invention, the rotary adsorption drum may include an insulating material that insulates the space between the adsorption separation part and the adsorption part.

[0016] In one embodiment of the present invention, the adsorbent may include a zeolite or a metal halide. Effects of the invention

[0018] According to one embodiment of the present invention, slip ammonia contained in flue gas is adsorbed by an adsorbent using a rotary adsorption drum, and the ammonia adsorbed by the adsorbent is separated using the thermal energy of the flue gas, thereby minimizing the emission of slip ammonia and reducing environmental pollution. According to one embodiment of the present invention, the separated ammonia can be reused as fuel or utilized as a reducing agent, and by preheating the ammonia and supplying it to a combustor, combustion stability can be ensured and NOx generation can be minimized. Furthermore, since the adsorbent can be regenerated and reused by switching the position of the rotary adsorption drum, the efficiency of the system can be improved and maintenance costs can be reduced. Brief explanation of the drawing

[0020] FIG. 1 is a schematic diagram of a slip ammonia and NOx-reducing ammonia gas turbine according to one embodiment of the present invention. FIG. 2 is a side cross-sectional view illustrating a rotary adsorption drum constituting a slip ammonia and NOx-reducing ammonia gas turbine according to one embodiment of the present invention. FIG. 3 is a perspective view showing a rotary adsorption drum constituting a slip ammonia and NOx reduction ammonia gas turbine according to one embodiment of the present invention, with the flow path cover separated. Specific details for implementing the invention

[0021] Hereinafter, embodiments of the present invention will be described in detail with reference to the attached drawings.

[0022] In describing the embodiments of the present invention, descriptions of technical details that are well known in the technical field to which the present invention belongs and are not directly related to the present invention are omitted.

[0023] This is intended to convey the essence of the invention more clearly without obscuring it by omitting unnecessary explanations.

[0024] In addition, when describing the components of the present invention, different reference numerals may be assigned to components with the same name depending on the drawing, and the same reference numeral may be assigned even to different drawings.

[0025] However, even in such cases, this does not mean that the component has different functions depending on the embodiment or has the same function in different embodiments, and the function of each component must be determined based on the description of each component in the respective embodiment.

[0026] Furthermore, technical terms used in this specification shall be interpreted in the sense generally understood by those skilled in the art to which the present invention pertains, unless specifically defined otherwise in this specification, and shall not be interpreted in an overly broad or overly narrow sense.

[0027] Additionally, singular expressions used in this specification include plural expressions unless the context otherwise indicates.

[0028] In this application, terms such as "composed" or "comprising" should not be interpreted as necessarily including all of the various components or steps described in the specification, and should be interpreted as potentially excluding some of the components or steps, or including additional components or steps.

[0030] FIG. 1 is a schematic diagram of a slip ammonia and NOx-reducing ammonia gas turbine according to one embodiment of the present invention. FIG. 2 is a side cross-sectional view illustrating a rotary adsorption drum constituting a slip ammonia and NOx-reducing ammonia gas turbine according to one embodiment of the present invention. FIG. 3 is a perspective view illustrating a rotary adsorption drum constituting a slip ammonia and NOx-reducing ammonia gas turbine according to one embodiment of the present invention, with the flow path cover separated.

[0032] Referring to FIGS. 1 to 3, a slip ammonia and NOx-reducing ammonia gas turbine (100) according to one embodiment of the present invention may include a combustor (110), a rotary adsorption drum (120), a post-treatment unit (180), and a recirculation pipe (190). The slip ammonia and NOx-reducing ammonia gas turbine (100) may be used to generate power using ammonia as fuel. The slip ammonia and NOx-reducing ammonia gas turbine (100) may reduce the emission of slip ammonia and nitrogen oxides (NOx) generated during the combustion process.

[0033] The combustor (110) may be a device that uses ammonia as fuel for combustion. The combustor (110) may receive ammonia and air from the outside to generate high-temperature combustion gas. The generated combustion gas may be used to drive a turbine to produce electricity. The exhaust gas discharged from the combustor (110) may contain unreacted slip ammonia and nitrogen oxides (NOx) generated during the combustion process.

[0034] A rotary adsorption drum (120) may be positioned at the rear end of a combustor (110). The rotary adsorption drum (120) can adsorb and treat slip ammonia contained in the exhaust gas discharged from the combustor (110). The rotary adsorption drum (120) may have a cylindrical shape and may contain an adsorbent inside. The rotary adsorption drum (120) may include a drum shaft (121), an adsorption separation section (130), an adsorption section (140), an insulating material (150), a flow path cover (160), and a drum driving section (170).

[0035] The drum shaft (121) is located on both sides of the center of the rotating suction drum (120) and can serve as a central axis of rotation. The drum shaft (121) can be connected to the drum drive unit (170). The drum shaft (121) can receive power from the drum drive unit (170) to rotate the rotating suction drum (120).

[0036] The adsorption separation unit (130) may constitute a portion of the rotary adsorption drum (120). The adsorption separation unit (130) may utilize the thermal energy of the high-temperature exhaust gas discharged from the combustor (110). The adsorption separation unit (130) may perform the function of separating (desorbing) ammonia adsorbed on the adsorbent using thermal energy. The adsorption separation unit (130) may include an exhaust gas pipe (131), a preheating pipe (133), a separated ammonia discharge port (137), a separated ammonia discharge socket (138), and a leak prevention plug (139).

[0037] The exhaust gas pipe (131) can be placed inside the adsorption separation unit (130). The exhaust gas pipe (131) can be configured to penetrate the adsorbent. The exhaust gas pipe (131) can provide a passageway for high-temperature exhaust gas discharged from the combustor (110). As the exhaust gas passes through the exhaust gas pipe (131), it can heat the adsorbent through heat exchange without directly contacting the adsorbent. The adsorbed ammonia can be separated from the heated adsorbent.

[0038] The preheating pipe (133) may be placed inside the adsorption separation section (130). The preheating pipe (133) may provide a passageway through which ammonia or air supplied to the combustor (110) passes. The ammonia or air passing through the preheating pipe (133) may exchange heat with the high-temperature exhaust gas passing through the exhaust gas pipe (131). The ammonia or air may be preheated through heat exchange. The preheated ammonia or air may be supplied to the combustor (110). The combustor (110) may receive the preheated ammonia or air to improve combustion stability. The combustor (110) may also suppress the generation of nitrogen oxides (NOx).

[0039] The separated ammonia outlet (137) may be a passage through which ammonia gas separated from the adsorption separation unit (130) is discharged. The separated ammonia outlet (137) may be formed on the outer surface of the rotary adsorption drum (120). The separated ammonia discharge socket (138) may be connected to the separated ammonia outlet (137). The separated ammonia discharge socket (138) may serve to transport the separated ammonia to the outside. The recovered ammonia may be reused as fuel for the combustor (110) through the recirculation pipe (190), or the recovered ammonia may be utilized as a reducing agent for the post-treatment unit (180). The leak prevention plug (139) may serve to block the separated ammonia outlet (137) located on the side of the adsorption unit (140) to prevent the exhaust gas supplied to the adsorption unit (140) from leaking to the outside.

[0040] The adsorption section (140) may constitute the remaining area of ​​the rotary adsorption drum (120) excluding the adsorption separation section (130). The adsorption section (140) may perform the function of adsorbing and removing slip ammonia contained in the exhaust gas that has passed through the adsorption separation section (130). The adsorption section (140) may include an adsorption supply port (141). The adsorption supply port (141) may directly supply the exhaust gas to an adsorbent. Through this, the slip ammonia contained in the exhaust gas can be removed by adsorbing it with the adsorbent.

[0041] The adsorbent may be composed of a material capable of adsorbing ammonia. The adsorbent may be composed of a material capable of desorbing upon heating. For example, the adsorbent may be a zeolite, activated carbon, silica gel, alumina, a metal-organic framework (MOF), a metal halide, or a porous polymer. However, the present invention is not limited thereto. In one embodiment of the present invention, the adsorbent may comprise a zeolite or a metal halide.

[0042] The exhaust gas from which slip ammonia has been removed through the adsorption supply port (141) can be exhausted to the outside with NOx and slip ammonia removed through an exhaust port located opposite the rotating adsorption drum (120).

[0043] An insulating material (150) may be placed between the adsorption separation section (130) and the adsorption section (140). The insulating material (150) may serve to block heat transfer between the high-temperature adsorption separation section (130) and the low-temperature adsorption section (140). The insulating material (150) may prevent heat from the adsorption separation section (130) from being transferred to the adsorption section (140). This prevents a decrease in adsorption efficiency.

[0044] Here, half of the rotating adsorption drum (120) may be composed of an adsorption separation section (130) and the other half of an adsorption section (140), and the adsorption separation section (130) and the adsorption section (140) are merely functionally distinct components, and depending on the rotation of the rotating adsorption drum (120), the adsorption separation section (130) may perform the function of the adsorption section (140), or the adsorption section (140) may perform the function of the adsorption separation section (130).

[0045] The adsorption section (140) and the adsorption separation section (130) may each be configured with an exhaust gas pipe (131), a preheating pipe (133), and an adsorption supply port (141) arranged symmetrically with respect to the insulation material (150). The adsorption section (140) and the adsorption separation section (130) may change the path of the exhaust gas by means of a flow path cover (160) so that when the exhaust gas is supplied to the adsorption supply port (141), it performs the function of the adsorption section (140), or when the exhaust gas is supplied to the exhaust gas pipe (131), it performs the function of the adsorption separation section (130).

[0046] In one embodiment, the adsorption separation unit (130) is located on the upper part of the rotating adsorption drum (120), and the adsorption unit (140) is located on the lower part of the adsorption separation unit (130).

[0047] The Euro cover (160) can be installed on both sides of the rotary adsorption drum (120). The Euro cover (160) can control the path of exhaust gas flowing into and out of the adsorption separation section (130) and the adsorption section (140) when the rotary adsorption drum (120) rotates. The Euro cover (160) may include a separation section (161), an adsorption section (165), and a partition wall (169). The Euro cover (160) can set the path of exhaust gas inflow and outflow so that when the rotary adsorption drum (120) rotates and the positions of the adsorption separation section (130) and the adsorption section (140) are reversed, the functions of the adsorption separation section (130) and the adsorption section (140) are also reversed.

[0048] The separation passage section (161) may be an area corresponding to the adsorption separation section (130) in the passage cover (160). The separation passage section (161) may include a flue gas connection port (162), a heat exchange connection port (163), and an adsorption supply port plug section (164). The flue gas connection port (162) may be a passage for supplying high-temperature flue gas discharged from the combustor (110) to the flue gas pipe (131). The heat exchange connection port (163) may be a passage for supplying ammonia or air to the preheating pipe (133) and discharging it. The adsorption supply port plug section (164) may block the adsorption supply port (141). This prevents the flue gas from coming into direct contact with the adsorbent of the adsorption separation section (130).

[0049] The exhaust gas connection port (162) of the Euro cover (160) located on one side is connected to a pipe through which exhaust gas is supplied from the combustor (110), and the exhaust gas connection port (162) of the Euro cover (160) located on the other side can be connected to a post-treatment device (180) for removing NOx contained in the exhaust gas.

[0050] Additionally, air or ammonia supplied to the combustor (110) can be supplied to the heat exchange connector (163) of the Euro cover (160) located on the other side, and a pipe can be connected to the heat exchange connector (163) of the Euro cover (160) located on one side to supply air or ammonia preheated through the adsorption separation unit (130) to the combustor (110).

[0051] The adsorption flow path (165) may be an area corresponding to the adsorption section (140) in the flow path cover (160). The adsorption flow path (165) may include an exhaust gas plug section (166), a heat exchange plug section (167), and an adsorption opening (168). The exhaust gas plug section (166) may block the inlet and outlet of the exhaust gas pipe (131). This prevents exhaust gas from passing through. The heat exchange plug section (167) may block the inlet and outlet of the preheating pipe (133). This prevents ammonia or air from passing through. The adsorption opening (168) may be connected to the adsorption supply port (141), and may be connected to the post-treatment unit (180) via piping so that exhaust gas from which NOx has been removed is introduced through the post-treatment unit (180) to the adsorption opening (168) of the flow path cover (160) located on the other side.

[0052] The adsorption opening (168) of the Euro cover (160) located on one side can be connected to an exhaust port through which exhaust gas from which slip ammonia has been removed by contacting an adsorbent is discharged to the outside.

[0053] The adsorption opening (168) can induce the exhaust gas to come into direct contact with the adsorbent of the adsorption section (140). The partition wall (169) can separate the separation flow path (161) and the adsorption flow path (165). This prevents the mixing of gases.

[0054] The drum drive unit (170) can provide power to rotate the rotary adsorption drum (120). The drum drive unit (170) may include a driving device such as a motor. When the adsorption of ammonia in the adsorption unit (140) reaches a saturated state, the drum drive unit (170) can rotate the rotary adsorption drum (120) to switch the positions of the adsorption unit (140) and the adsorption separation unit (130). Through this, the saturated adsorption unit (140) can move to the position of the adsorption separation unit (130) and be regenerated by the thermal energy of the exhaust gas. The adsorption separation unit (140), which has moved to the position of the adsorption unit (140), can adsorb slip ammonia contained in the exhaust gas.

[0055] In one embodiment of the present invention, the post-treatment unit (180) can remove NOx from the exhaust gas that has passed through the rotary adsorption drum (120). The post-treatment unit (180) can resupply the exhaust gas from which NOx has been removed to the rotary adsorption drum (120). The post-treatment unit (180) may be a device for removing nitrogen oxides (NOx) contained in the exhaust gas that has passed through the adsorption section (140) of the rotary adsorption drum (120). The post-treatment unit (180) may include a Selective Catalytic Reduction (SCR) device, etc. The post-treatment unit (180) can discharge the exhaust gas from which nitrogen oxides (NOx) have been removed to the outside. The post-treatment unit (180) may be supplied with exhaust gas that has passed through the adsorption separation section (130) to remove nitrogen oxides (NOx), and the removed exhaust gas may be supplied to the adsorption section (140).

[0056] The recirculation pipe (190) may be a pipe for transporting ammonia recovered from the adsorption separation unit (130). The ammonia recovered through the recirculation pipe (190) may be supplied as fuel to the combustion unit (110). Alternatively, the recovered ammonia may be used as a reducing agent to remove nitrogen oxides (NOx) in the post-treatment unit (180). Reusing ammonia through the recirculation pipe (190) can increase fuel efficiency. Reusing ammonia through the recirculation pipe (190) can reduce operating costs.

[0057] The interactions and effects between each component described above are explained.

[0058] According to one embodiment of the present invention, a slip ammonia and NOx-reducing ammonia gas turbine (100) operates the gas turbine (100) using combustion heat from a combustor (110) to generate power or use power. The combustor (110) uses ammonia as fuel and combusts it mixed with air, and the exhaust gas generated during combustion is supplied to a rotary adsorption drum (130). The exhaust gas is first supplied to an adsorption separation unit (130) through the adsorption passage section (161) of a flow path cover (160) located on one side.

[0059] The exhaust gas supplied to the adsorption passage (161) of the Euro cover (160) passes through the exhaust gas pipe (131) via the exhaust gas connection port (162) and exchanges heat with the adsorbent to separate the ammonia adsorbed on the adsorbent. At this time, the high-temperature energy of the exhaust gas is used to exchange heat with the air or ammonia passing through the preheating pipe (133). The preheated air and ammonia are provided to the combustion device (110).

[0060] The exhaust gas that has consumed thermal energy through the exhaust gas pipe (131) is supplied to the post-treatment unit (180), and is supplied to the adsorption unit (140) after the NOx contained in the exhaust gas is removed as it passes through the post-treatment unit (180). The exhaust gas is supplied to the adsorption supply port (141) through the adsorption opening (168) of the Euro cover (160) located on the other side, and after removing slip ammonia by coming into contact with the adsorbent, it is exhausted through the exhaust port.

[0061] Meanwhile, a concentration measuring sensor is installed at the exhaust port to measure the slip ammonia concentration of the exhaust gas being discharged using the concentration measuring sensor (not shown), and if the concentration is higher than a preset concentration, it is determined that the adsorption of ammonia in the adsorbent is saturated, and the rotating adsorption drum (120) is rotated by the drum driving unit (170).

[0062] When the positions of the adsorption section (140) and the adsorption separation section (130) are reversed by the rotation of the rotary adsorption drum (120), the exhaust gas passes through the exhaust gas pipe (131) of the previous adsorption section (140) by the Euro cover (160) that does not rotate together, thereby separating the ammonia adsorbed on the adsorbent and regenerating the adsorbent. Since the previous adsorption separation section (130) is in a state where ammonia has been separated and regenerated by the thermal energy of the exhaust gas, it is possible to adsorb and remove the slip ammonia contained in the exhaust gas onto the adsorbent.

[0063] In this way, the rotary adsorption drum (120) can regenerate the adsorbent by continuously rotating the adsorption separation section (130) and the adsorption section (140) so that they are reversed according to the slip ammonia adsorption performance of the adsorbent, and by preheating air or ammonia and supplying it to the combustion device (110) while simultaneously adsorbing and removing slip ammonia from the adsorbent, it is possible to prevent environmental pollution and minimize the amount of ammonia released into the atmosphere.

[0065] Accordingly, the slip ammonia and NOx reduction ammonia gas turbine (100) according to the present invention can prevent environmental pollution by minimizing the emission of slip ammonia by adsorbing and removing slip ammonia contained in the flue gas through a rotary adsorption drum (120) and separating the adsorbed slip ammonia into the thermal energy of the flue gas.

[0066] In addition, by configuring the rotating adsorption drum (120) to pass air or ammonia through it, preheated air and ammonia are supplied to the combustor (110), thereby improving combustion efficiency and minimizing the generation of NOx through stable combustion.

[0067] In addition, the separated ammonia can be circulated through a recirculation pipe (190) to be used as a reducing agent to remove NOx or as fuel to increase its utility.

[0068] In addition, since the adsorbent can be regenerated and reused by switching the position of the rotary adsorption drum, system efficiency can be improved and maintenance costs can be reduced.

[0070] Although embodiments of the present invention have been described with reference to the foregoing, those skilled in the art to which the present invention pertains will understand that the present invention may be implemented in other specific forms without altering its technical concept or essential features.

[0071] Therefore, the embodiments described above should be understood as exemplary in all respects and not limiting, and the scope of the invention as described in the detailed description above is defined by the claims set forth below, and all modifications or variations derived from the meaning and scope of the claims and equivalent concepts thereof should be interpreted as being included within the scope of the invention. Explanation of the symbols

[0073] 100: Ammonia gas turbine 110: Combustion device 120: Rotating suction drum 121: Drum shaft 130: Adsorption separation unit 131: Exhaust gas pipe 133: Preheating pipe 137: Separated ammonia outlet 138: Separated Ammonia Discharge Socket 139: Leak-proof cap 140: Adsorption part 141: Adsorption supply port 150: Insulation material 160: Eurocover 161: Separation Euro section 162: Exhaust gas connection 163: Heat exchange connector 164: Suction supply port plug 165: Adsorption channel 166: Exhaust gas plug 167: Heat exchange plug 168: Adsorption opening 169: Partition wall 170: Drum drive unit 180: Post-processor 190: Recirculation pipe

Claims

Claim 1 A gas turbine for reducing slip ammonia and NOx, comprising a combustor for burning ammonia, a rotary adsorption drum containing an adsorbent for adsorbing and treating slip ammonia contained in the flue gas of the combustor, and a post-treatment unit for removing NOx from the flue gas that has passed through the rotary adsorption drum and resupplying it to the rotary adsorption drum, wherein the rotary adsorption drum comprises an adsorption separation unit that separates ammonia adsorbed on the adsorbent using the thermal energy of the flue gas discharged from the combustor, an adsorption unit that adsorbs and removes slip ammonia contained in the flue gas that has passed through the adsorption separation unit, and a drum driving unit that rotates the rotary adsorption drum to switch the positions of the adsorption unit and the adsorption separation unit when the adsorption of ammonia in the adsorption unit becomes saturated, wherein the adsorption separation unit comprises a preheating pipe through which the ammonia or air passes to preheat the ammonia or air supplied to the combustor by exchanging heat with the flue gas. Claim 2 A slip ammonia and NOx reduction ammonia gas turbine according to claim 1, characterized in that the adsorption unit and the adsorption separation unit are configured identically such that the paths of the flue gas are reversed from each other, and the paths of the flue gas inflow and outflow are set such that when the positions of the adsorption separation unit and the adsorption unit are reversed, the functions of the adsorption separation unit and the adsorption unit are also reversed. Claim 3 Slip ammonia and NOx reduction ammonia gas turbine according to claim 1, wherein the adsorption separation unit includes a flue gas pipe through which the flue gas exchanges heat while passing through the adsorbent to separate ammonia adsorbed on the adsorbent by exchanging heat while the adsorbent and the flue gas are in a state where they are not in contact with each other. Claim 4 delete Claim 5 A slip ammonia and NOx-reducing ammonia gas turbine according to claim 1, wherein the adsorption unit comprises an adsorption supply port for supplying the flue gas to the adsorbent to adsorb and remove slip ammonia contained in the flue gas by the adsorbent. Claim 6 A slip ammonia and NOx-reducing ammonia gas turbine according to claim 1, wherein the rotary adsorption drum comprises an insulating material that insulates the space between the adsorption separation section and the adsorption section. Claim 7 A slip ammonia and NOx-reducing ammonia gas turbine according to claim 1, wherein the adsorbent comprises a zeolite or a metal halide.

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