COMPOSITIONS FOR PERSONAL CARE.

MX433868BActive Publication Date: 2026-05-19COLGATE PALMOLIVE CO

Patent Information

Authority / Receiving Office
MX · MX
Patent Type
Patents
Current Assignee / Owner
COLGATE PALMOLIVE CO
Filing Date
2022-06-23
Publication Date
2026-05-19

AI Technical Summary

Technical Problem

Powdered soaps produced by conventional methods have poor flow and feel, limiting their application in personal care products due to high water content, which affects solubility and usability.

Method used

A soap powder composition comprising discrete particles with a specific distribution of cationic polymer, clay, and fatty component, formulated to have low water content and optimized particle sizes, enhancing fluidity and solubility.

Benefits of technology

The composition achieves improved flow and feel while maintaining solubility, making it suitable for personal care applications such as hand, body, and hair soaps.

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Abstract

The present description describes a powder soap comprising a plurality of particles, each of the particles comprising: an ionic polymer; and a fatty component comprising compounds having C8 to C18 chains.
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Description

PERSONAL CARE COMPOSITIONS BACKGROUND Powdered soaps are typically produced by preparing an aqueous soap solution, drying the solution using a spray-drying or similar method, then adding a binder such as water and a non-ionic surfactant, and grinding it into a powder with a high-speed mixer. To increase solubility, the water content of powdered soaps prepared in this way is usually kept to approximately 7 to 15%. However, such powdered soaps have poor flowability and / or feel. Therefore, these powdered soaps are preferably used only as laundry detergents that require high solubility and can be scooped with a measuring cup. To improve flowability, the water content is between 1% and 3%.Therefore, there is a need for a powdered soap that can exhibit good flowability and a good feel and maintain solubility; in this way, a powdered soap suitable for personal care applications is manufactured. BRIEF DESCRIPTION OF THE INVENTION According to some embodiments, the present invention is directed to a powder soap comprising a plurality of particles, each of the particles comprising: an ionic polymer; a fatty component comprising compounds having Cs to C1e chains. Additional areas of applicability of the present invention will become apparent from the detailed description provided below. It should be understood that the detailed description and specific examples, while indicating the preferred embodiment of the invention, are for illustrative purposes only and are not intended to limit the scope of the invention. DETAILED DESCRIPTION OF THE INVENTION The following description of the preferred embodiment(s) is merely illustrative in nature and is not intended in any way to limit the invention, its application, or its uses. As used throughout this description, intervals are used as shorthand to describe each and every value within the interval. Any value within the interval can be selected as the endpoint of the interval. Additionally, all references cited in this description are hereby incorporated by reference in their entirety. In the event of a conflict between a definition in this description and that in a cited reference, this description shall prevail. Unless otherwise specified, all percentages and quantities expressed in this description and elsewhere in the specification are to be understood as percentages by weight. The quantities stated are based on the active weight of the material. cf i ηη / ζζηζ / Ε / γίΛΐ Unless otherwise specified, all percentages and quantities expressed in this description and elsewhere in the specification are to be understood as percentages by weight. The quantities stated are based on the active weight of the material. For the purposes of this application, the term “approximately” means + / - 5% of the reference value. For the purposes of this application, the term “substantially free” means less than approximately 0.1% by weight, based on the total reference value. The following description of the preferred embodiment(s) is merely illustrative in nature and is not intended in any way to limit the invention, its application, or its uses. As used throughout this description, intervals are used as shorthand to describe each and every value within the interval. Any value within the interval can be selected as the endpoint of the interval. Additionally, all references cited in this description are hereby incorporated by reference in their entirety. In the event of a conflict between a definition in this description and that in a cited reference, this description shall prevail. Unless otherwise specified, all percentages and quantities expressed in this description and elsewhere in the specification are to be understood as percentages by weight. The quantities stated are based on the active weight of the material. The present invention relates to a personal care product, which may be a soap. The soap may be a hand soap, a body soap, and / or a hair soap. The soap may be a powdered soap, also called granular soap. The powdered soap may comprise a plurality of discrete particles having an average particle size and shape. The shape of each of the plurality of discrete particles can be spherical. In other configurations, the discrete particles can be ellipsoids, conics, cylinders, cubics, cuboids, and the like. In some configurations, the discrete particles can have a non-geometric shape. The plurality of discrete particles may have a particle size distribution. The size distribution may include approximately 8% to approximately 10% of the plurality of particles having a particle size greater than 1,400 microns. The size distribution may include approximately 76% to approximately 78% of the plurality of particles having a particle size greater than approximately 840 microns and less than approximately 1,400 microns. The size distribution may include approximately 9% to approximately 10% of the plurality of particles having a particle size greater than approximately 500 microns and less than approximately 840 microns. The size distribution may include approximately 0.4% to approximately 9% of the plurality of particles having a particle size greater than approximately 290 microns and less than approximately 500 microns.The size distribution may include from approximately 0.6% to approximately cfr i nn / zznz / E / YiAi. 0.9% of the plurality of particles having a particle size less than approximately 290 microns. Each particle may comprise a soap composition comprising a cationic polymer, a clay, and a fatty component. In some embodiments, the soap composition further comprises a pigment. In some embodiments, the soap composition further comprises a fragrance. The cationic polymer may be present in an amount ranging from approximately 0.009% by weight to approximately 4.5% by weight—including all intermediate percentages and sub-intervals—based on the total weight of the soap composition. Each particle may be formed entirely from the soap composition; therefore, the weight percentages referred to herein may also refer to the total weight of the respective particle. In a preferred embodiment, the cationic polymer may be present in an amount ranging from approximately 0.009% by weight to approximately 0.9% by weight—including all intermediate percentages and sub-intervals—based on the total weight of the soap composition. The cationic polymer may comprise a polyquaternary ammonium compound - referred to herein as polyquat. The polyquat of the present invention may comprise a compound having formula (I) - which may also be referred to as “diquat”; cfr i nn / zznz / E / YiAi K, XI® I® I® Θ R: X -N — RI — X — R / |n · 2|ZII Rs R / 11 Formula (I) wherein Ri, R2, R3, Rr, R2', Rs·, R4, Rs, in the above formula may be identical or different, and are selected independently of hydrogen, an alkyl group, an aryl group, a benzyl group, an aralkyl group, or a C1-C20 alkylaryl group. Each C1-C20 alkyl group may be substituted or unsubstituted, linear or branched. Rey R? in the above formula may be identical or different, and are selected independently of (CH2)m, or (CH2)m—(CH=CH)m—(CH2)m, wherein 12=>m>=1, 10=>m'>=1, and 150>=n=>5; and Z is an anionic residue including, without limitation, F, Cl, Br, I, and COOH. The polyquat of the present invention may have a weight average molecular weight Mw, with the maximum preference approximately 4,600 to 11,000. The non-limiting polyquats of the present invention include each of the polyquaternium compounds 1-47. In a non-limiting example, the polyquaternium of the present invention may comprise polyquaternium-1: α-4-[1-tris(2-hydroxyethyl)ammonium-2-butenyl] chloride poly[1-dimethylammonium-2-butenyl]-ωtris(2-hydroxyethyl)ammonium, having the chemical structure described in formula (II): cf i ηη / ζζηζ / Ε / γίΛΐ Formula (II) Other non-limiting examples of such polyquaterniums include, but are not limited to: (1) the quaternary ammonium polymer salt of hydroxyethylcellulose reacting with a trimethylammonium-substituted epoxide, called Polyquaternium-10; (2) the quaternary ammonium derivative of hydroxypropyl guar, called guar hydroxypropyltrimonium chloride; (3) the copolymer of hydroxyethylcellulose and DADMAC, called Polyquaternium-4; (4) the copolymer of acrylamide and METAMS, called Polyquaternium-5; (5) the homopolymer of DADMAC, called Polyquaternium-6; (6) the copolymer of acrylamide and DADMAC, called Polyquaternium-7; (7) the copolymer of vinylpyrrolidone and METAMS, called Polyquaternium-11; (8) the homopolymer of METAMS, called Polyquaternium-14; (9) the methacrylamide and METAMS copolymer, called Polyquaternium-15;(10) the quaternary ammonium polymer salt of hydroxyethylcellulose reacted with a lauryldimethylammonium substituted epoxide, designated Polyquaternium-24; (11) the copolymer of vinylpyrrolidone and MAPTAC, designated Polyquaternium-28; (12) the copolymer of acrylamide and METAC, designated Polyquaternium-32; (13) the copolymer of acrylamide and AETAC, designated Polyquaternium-33; (14) the copolymer of butyl methacrylate, dimethylaminoethyl methacrylate and METAMS, designated Polyquaternium-36; (15) the homopolymer of METAC, designated Polyquaternium-37; (16) the copolymer of METAMS, methyl methacrylate and hydroxyethyl methacrylate, designated Polyquaternium-45; (17) the MAPTAC homopolymer, called polymethacrylamidopropyltrimonium chloride;(18) starch hydroxypropyltrimethylammonium chloride ether derivatives, as generally described by CAS Registry Number 5670-58-6, the starch of which may be derived from a variety of natural sources such as corn, potato, rice, tapioca, wheat, or other sources; (19) the copolymer of DADMAC and acrylic acid, designated Polyquaternium-22; (20) the copolymer of DADMAC, acrylic acid, and acrylamide, designated Polyquaternium-39; and (21) the copolymer of MAPTAC, acrylic acid, and methyl (meth)acrylate, designated Polyquaternium-47. In a preferred embodiment, the cationic polymer is the DADMAC homopolymer, called Polyquaternium-6. The clay of the present invention may be present in an amount ranging from approximately 0.05% by weight to approximately 2.0% by weight—including all intermediate percentages and sub-intervals—based on the total weight of the soap composition. Each particle may be formed entirely by the soap composition; therefore, the weight percentages referred to herein may also refer to the total weight of the respective particle. In a preferred embodiment, the clay may be present in an amount ranging from approximately 0.1% by weight to approximately 1.0% by weight—including all intermediate percentages and sub-intervals—based on the total weight of the soap composition. The clay may comprise one or more of kaolin, kaolinite, dickite, halloysite, nacrite, smectite, montmorillonite, nontronite, ilithite, bentonite, attapulgite, palygorskite, sepiolite, hormite, pyrophyllite, chlorite, aluminosilicates, and mixtures thereof. In a preferred embodiment, the clay comprises calcined kaolin. The fat component in the present invention may be present in an amount ranging from approximately 94% by weight to approximately 98% by weight—including all intermediate percentages and sub-intervals—based on the total weight of the soap composition. Each particle may be formed entirely from the soap composition; therefore, the weight percentages referred to herein may also refer to the total weight of the respective particle. In a preferred embodiment, the fat component may be present in an amount ranging from approximately 96% by weight to approximately 98% by weight—including all intermediate percentages and sub-intervals—based on the total weight of the soap composition. The fatty component may be an ionic compound that is a salt of a fatty acid. Non-limiting fatty acids include saturated and unsaturated C30 fatty acids. Illustrative fatty acids include, but are not limited to, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, ricinoleic acid, vacenic acid, linoleic acid, α-linolenic acid, γ-linolenic acid, arachidic acid, gadoleic acid, arachidonic acid, behenic acid, erucic acid, lignoceric acid, and mixtures thereof. In a non-limiting embodiment, the ionic fat component may comprise a solubilizing cation such as sodium, potassium, ammonium, or substituted ammonium. The fat component may be present in an amount ranging from approximately 85% to approximately 95% by weight—based on the total weight of the soap composition—including all intermediate percentages and sub-ranges. Each particle may be formed entirely from the soap composition; therefore, the weight percentages referred to here may also refer to the total weight of the respective particle. In some embodiments, the fat component may be present in an amount ranging from approximately 94% to approximately 98% by weight—based on the total weight of the soap composition—including all intermediate percentages and sub-ranges. According to the present invention, the fatty component may comprise compounds that are a salt of fatty acid Ce—such as caprylic acid. Salts of fatty acid Cs may be present in an amount ranging from approximately 0% by weight to approximately 4.5% by weight based on the total weight of the fatty component—including all intermediate amounts and sub-ranges. In some embodiments, salts of fatty acid Ce may be present in an amount ranging from approximately 0.6% by weight to approximately 1% by weight—including all intermediate amounts and sub-ranges.In some formulations, salts of fatty acid Ce may be present in an amount of approximately 0.8% by weight, based on the total weight of the fat component. In some formulations, salts of fatty acid Ce may be present in an amount of approximately 2.25% by weight, based on the total weight of the fat component. According to the present invention, the fatty component may comprise compounds that are salts of a fatty acid C10, such as capric acid. Salts of fatty acid C10 may be present in amounts ranging from approximately 0% by weight to approximately 3.6% by weight based on the total weight of the fatty component, including all intermediate amounts and sub-ranges. In some embodiments, salts of fatty acid C10 may be present in amounts ranging from approximately 0.6% by weight to approximately 0.9% by weight based on the total weight of the fatty component, including all intermediate amounts and sub-ranges.In some embodiments, salts of fatty acid Cw may be present in amounts ranging from approximately 0.6% to approximately 3.6% by weight based on the total weight of the fat component—including all intermediate amounts and sub-ranges. In some embodiments, salts of fatty acid Cío may be present in amounts of approximately 0.75% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-ranges. In some embodiments, salts of fatty acid Cío may be present in amounts of approximately 1.8% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-ranges. According to the present invention, the fatty component may comprise compounds that are salts of a C12 fatty acid, such as lauric acid. The C12 fatty acid salts may be present in amounts ranging from approximately 8.0% by weight to approximately 49.5% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-intervals. In some embodiments, the C12 fatty acid salts may be present in amounts ranging from approximately 8.0% by weight to approximately 9.2% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-intervals. In some embodiments, the C12 fatty acid salts may be present in amounts ranging from approximately 40.5% by weight to approximately 49.5% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-intervals.In other embodiments, C12 fatty acid salts may be present in an amount of approximately 8.6% by weight, based on the total weight of the fat component—which includes all amounts and intermediate sub-intervals. In other embodiments, C12 fatty acid salts may be present in an amount of approximately 45% by weight, based on the total weight of the fat component—which includes all amounts and intermediate sub-intervals. According to the present invention, the fatty component may comprise compounds that are salts of a Cm- fatty acid, such as myristic acid. The C14 fatty acid salts may be present in amounts ranging from approximately 2.7% by weight to approximately 16.4% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-ranges. In some embodiments, the C14 fatty acid salts may be present in amounts ranging from approximately 2.7% by weight to approximately 5.3% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-ranges. In some embodiments, the C14 fatty acid salts may be present in amounts ranging from approximately 11.8% by weight to approximately 16.4% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-ranges.In some formulations, C14 fatty acid salts may be present in an amount of approximately 4% by weight, based on the total weight of the fat component—which includes all amounts and intermediate sub-ranges. In some formulations, C14 fatty acid salts may be present in an amount of approximately 14% by weight, based on the total weight of the fat component—which includes all amounts and intermediate sub-ranges. According to the present invention, the fatty component may comprise compounds that are salts of a Cw fatty acid, such as palmitic acid. In some embodiments, the salts of the Cw fatty acid may be present in an amount ranging from approximately 10% by weight to approximately 44.1% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-ranges. In some embodiments, the salts of the C16 fatty acid may be present in an amount ranging from approximately 34.9% by weight to approximately 44.1% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-ranges. In some embodiments, the salts of the C16 fatty acid may be present in an amount ranging from approximately 10% by weight to approximately 14.6% by weight, based on the total weight of the fatty component, including all intermediate amounts and sub-ranges.In some formulations, salts of fatty acid Cíe may be present in an amount of approximately 39.5% by weight, based on the total weight of the fat component. In some formulations, salts of fatty acid Cw may be present in an amount of approximately 12.2% by weight, based on the total weight of the fat component. cf i ηη / ζζηζ / Ε / γίΛΐ According to the present invention, the fatty component may comprise compounds that are salts of a fatty acid Cie—such as stearic acid, oleic acid, linoleic acid, linolenic acid, and mixtures thereof. In some embodiments, the salts of fatty acid Cw may be present in an amount ranging from approximately 15% by weight to approximately 52% by weight, based on the total weight of the fatty component—which includes all intermediate amounts and sub-ranges. The fatty acid Cíe can be fully saturated—just like stearic acid—so that the stearic acid salt is present in an amount ranging from approximately 1.7% to approximately 14.1% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-intervals. In some embodiments, the stearic acid salt is present in an amount ranging from approximately 1.7% to approximately 4.2% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-intervals. In some embodiments, the stearic acid salt is present in an amount ranging from approximately 6.7% to approximately 14.1% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-intervals. In some embodiments, the stearic acid salt is present in an amount of approximately 2.96% by weight, based on the total weight of the fat component. In some formulations, stearic acid salt is present at approximately 10.4% by weight, based on the total weight of the fat component. The fatty acid C1e can be partially unsaturated with a single unsaturated C=C bond—such as oleic acid—so that the oleic acid salt is present in an amount ranging from approximately 12% to approximately 32.1% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-intervals. In some embodiments, the oleic acid salt is present in an amount ranging from approximately 21.5% to approximately 32.1% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-intervals. In some embodiments, the oleic acid salt is present in an amount ranging from approximately 12% to approximately 21.75% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-intervals. In some embodiments, the oleic acid salt is present in an amount of approximately 26.8% by weight, based on the total weight of the fat component. In some formulations, the oleic acid salt is present at approximately 16.9% by weight, based on the total weight of the fat component. The fatty acid C1e can be partially unsaturated with two unsaturated C1-C bonds—such as linoleic acid—so that the linoleic acid salt is present in an amount that varies from approximately 1.42% by weight to approximately 5.8% by weight, based on the total weight of the fat component—which includes all intermediate amounts and sub-intervals. In some embodiments, the linoleic acid salt is present in an amount that varies from approximately 2.2% by weight to approximately 5.8% by weight, based on the total weight of the fat component—which includes all intermediate amounts and sub-intervals. In some embodiments, the linoleic acid salt is present in an amount that varies from approximately 1.4% by weight to approximately 3.7% by weight, based on the total weight of the fat component—which includes all intermediate amounts and sub-intervals.In some formulations, linoleic acid salt is present at approximately 2.53% by weight, based on the total weight of the fat component. In some formulations, linoleic acid salt is present at approximately 4% by weight, based on the total weight of the fat component. The fatty acid C1e may be partially unsaturated with three unsaturated C=C bonds—such as linolenic acid—so that the linoleic acid salt is present in an amount ranging from approximately 0% to approximately 0.92% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-intervals. In some embodiments, the linoleic acid salt is present in an amount ranging from approximately 0% to approximately 0.25% by weight, based on the total weight of the fat component—including all intermediate amounts and sub-intervals. In some embodiments, the linolenic acid salt is present in an amount of approximately 0.125% by weight, based on the total weight of the fat component. In some embodiments, the linolenic acid salt is present in an amount of approximately 0.46% by weight, based on the total weight of the fat component. By way of non-limiting example, the fat component may comprise salts of the following fatty acids in the respective amounts based on the total weight of the fat component: 0.8% by weight of a caprylic acid salt; 0.75% by weight of a capric acid salt; 8.6% by weight of a lauric acid salt; 4.0% by weight of a myristic acid salt; 39.5% by weight of a palmitic acid salt; 10.4% by weight of a stearic acid salt; 26.8% by weight of an oleic acid salt; 4.0% by weight of a linoleic acid salt; and 0.125% by weight of a linolenic acid salt. By way of non-limiting example, the fat component may comprise salts of the following fatty acids in the respective amounts based on the total weight of the fat component: 0.8 wt. or 2.25 wt. of a caprylic acid salt; 0.75 wt. or 1.8 wt. of a capric acid salt; 8.6 wt. or 45 wt. of a lauric acid salt; 4 wt. or 14 wt. of a myristic acid salt; 12.2 wt. or 39.5 wt. of a palmitic acid salt; 2.96 wt. or 10.4 wt. of a stearic acid salt; 16.9 wt. or 26.8 wt. of an oleic acid salt; 2.53 wt. or 4 wt. of a linoleic acid salt; and 0.125% by weight or 0.46% by weight of a linolenic acid salt. The soap composition may also include one or more fragrances. The fragrance may be present in an amount ranging from approximately 1% to approximately 1.5% by weight—based on the total weight of the soap composition—which includes all percentages and intermediate sub-intervals. Each particle may be formed entirely from the soap composition; therefore, the weight percentages referred to here may also refer to the total weight of the respective particle. In some embodiments, the fragrance may be present in an amount ranging from approximately 0.5% to approximately 1.7% by weight—based on the total weight of the soap composition—which includes all percentages and intermediate sub-intervals. Non-limiting examples of fragrances and perfumes include selected odor compounds from: 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene, α-ionone, β-ionone, γ-ionone, α-isomethylionone, methylcedrilone, methyl dihydrojasmonate, methyl 1,6,10-methyl-2,5,9-cyclododecatriene-1-yl ketone, 7-acetyl-1,1,3,4,4,6-hexamethyltetraline, 4-acetyl-6-tert-butyl-1,1-dimethylindane, hydroxyphenylbutanone, benzophenone, methyl β-naphthyl ketone, 6-acetyl-1,1,2,3,3,5-hexamethylindane, 5-acetyl-3-isopropyl-1,1,2,6-tetramethylindane, 1-dodecanal, 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde, 7-hydroxy-3,7-dimethyloctanal, 10-undecen-1-al, isohexaenylcyclohexylcarboxaldehyde, formyltricyclodecane, condensation products of hydroxycitronellal and methyl anthranilate, condensation products of hydroxycitronellal and indole, condensation products of phenylacetaldehyde and indole, 2-methyl-3-(para-tert-butylphenyl)propionaldehyde, ethylvanillin, heliotropin, hexylcinnamaldehyde,amylcinnamaldehyde, 2-methyl-2-(isopropylphen¡l)propíonaldehyde, coumarin, y-decalactone, cyclopentadecanolide, 16-hydroxy-9-hexadeceno¡ic acid lactone, 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8hexamethylcyclopenta-y-2-benzopyran, β-naphthol methyl ether, ambroxane, dodecahydro-3a,6,6,9atetramethylnaphtho[2,1B]furan, cedrol, 5-(2,2,3-trimet¡lcyclopent-3-en¡l)-3-methylpentan-2-ol, 2-ethyl-4-(2,2,3trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, caryophyllene alcohol, tricyclodecenyl propionate, tricyclodecenyl acetate, benzyl salicylate, cedryl acetate, and tert-butylcyclohexyl acetate. Other fragrances may include scent compounds selected from essential oils, resinoids, and resins from a large number of sources, such as, for example, Peru balsam, frankincense resinoid, styrax, labdanum resin, nutmeg, cassia oil, benzoin resin, coriander, and lavandin. Suitable additional fragrances include odor compounds selected from phenylethyl alcohol, terpineol, linalool, linalyl acetate, geraniol, nerol, 2-(1,1-dimethylethyl)cyclohexanol acetate, benzyl acetate, and eugenol. The fragrances or perfumes may be used as individual substances or in a mixture with each other. The soap composition may also include one or more colorants. Colorants may be pigments, dyes, or mixtures thereof. Non-limiting examples of pigments include titanium dioxide, zinc oxide, kaolin, mica, etc. Non-limiting examples of dyes include food-grade dyes suitable for food, pharmaceutical, and cosmetic applications, and mixtures thereof. Some coloring agents (dyes) are known as FD&C dyes. cf i ηη / ζζηζ / Ε / γίΛΐ Colorants may be present in amounts ranging from approximately 0.0001% by weight to approximately 0.4% by weight – based on the total weight of the soap composition – including all intermediate percentages and sub-intervals. Each particle may be formed entirely from the soap composition; therefore, the weight percentages referred to here may also refer to the total weight of the respective particle. In some embodiments, colorants may be present in amounts ranging from approximately 0.0001% by weight to approximately 4% by weight – based on the total weight of the soap composition – including all intermediate percentages and sub-intervals. The discrete particles that make up the powdered soap of the present invention may have a liquid carrier content—such as water or organic solvents—of less than approximately 9% by weight, based on the total weight of each discrete particle. In some embodiments, the discrete particles that make up the powdered soap of the present invention may have a liquid carrier content—such as water or organic solvents—of less than approximately 7% by weight, based on the total weight of each discrete particle. In some embodiments, the discrete particles that make up the powdered soap of the present invention may have a liquid carrier content—such as water or organic solvents—of less than approximately 5% by weight, based on the total weight of each discrete particle. The discrete particles that make up the powdered soap of the present invention can be provided as discrete solid particles. In particular, the discrete particles can have a solids content of at least approximately 90% based on the total weight of each discrete particle. Preferably, the discrete particles can have a solids content of at least approximately 95% based on the total weight of each discrete particle. Preferably, the discrete particles can have a solids content of at least approximately 96% based on the total weight of each discrete particle. The soap composition in the powdered soap of the present invention may have a solids content of at least approximately 97%, based on the total weight of the soap composition. Preferably, the soap composition in the powdered soap may have a solids content of at least approximately 98%, based on the total weight of the soap composition. Preferably, the soap composition in the powdered soap may have a solids content of at least approximately 99%, based on the total weight of the soap composition. The soap composition in the powdered soap may have a liquid carrier content—such as water or organic solvents—of less than 3% by weight, based on the total weight of the soap composition. In some embodiments, the soap composition in the powdered soap of the present invention may have a liquid carrier content—such as water or organic solvents—of less than approximately 2% by weight, based on the total weight of the soap composition. In some embodiments, the soap composition in the powdered soap may have a liquid carrier content—such as water or organic solvents—of less than approximately 1% by weight, based on the total weight of each soap composition. In some embodiments, the soap composition that forms the powdered soap of the present invention may be substantially free of liquid carrier - such as water or organic solvents. The powdered soap of the present invention can be manufactured by forming a mixture of the cationic polymer, clay, and fatty component. According to embodiments containing colorant, fragrance, and other additives, additional components can also be added to the mixture. The mixture can be gently stirred until the various components are uniformly distributed throughout. According to some embodiments, the mixture may further comprise one or more liquid carriers (e.g., water, non-aqueous solvent) to aid in the stirring of the various components. Once stirred, the mixture can be dried to remove the liquid carrier. The resulting dry mixture can then be subjected to mechanical stress (e.g., grinding), which breaks the mixture down into smaller particles that form the plurality of discrete particles of the powdered soap. Non-limiting examples of grinding include subjecting the dry mixture to a high-speed mixer, a Henschel mixer, or a Loedige mixer. After milling, a variety of discrete particles can be collected. In some embodiments, these particles may be screened to remove small or large particles unsuitable for powdered soap. In other embodiments, the particles are not screened. The resulting powdered soap can then be distributed into the reservoir of a soap dispenser. For example, the soap dispenser could be a bag, box, or other airtight container.

Claims

1. A personal care powder soap composition comprising a plurality of particles, each particle comprising: an ionic polymer; and a fatty component comprising compounds having Cs to C1e chains.

2. The powdered soap according to claim 1, wherein the fat component comprises compounds having Cw chains in an amount ranging from approximately 15% by weight to approximately 52% by weight, based on the total weight of the fat component.

3. The powdered soap according to any of the preceding claims, wherein the fatty component comprises compounds having Cie chains in an amount ranging from approximately 10% by weight to approximately 44.1% by weight, based on the total weight of the fatty component.

4. The powdered soap according to any of the preceding claims, wherein the fatty component comprises compounds having C14 chains in an amount ranging from approximately 2.7% by weight to approximately 16.4% by weight, based on the total weight of the fatty component.

5. The powdered soap according to any of the preceding claims, wherein the fat component comprises compounds having C12 chains in an amount ranging from approximately 8% by weight to approximately 49.5% by weight, based on the total weight of the fat component.

6. The powdered soap according to any of the preceding claims, wherein the fat component comprises compounds having C10 chains in an amount of up to approximately 3.6% by weight, based on the total weight of the fat component.

7. The powdered soap according to any of the preceding claims, wherein the fatty component comprises compounds having Cs chains in an amount of up to approximately 4.5% by weight, based on the total weight of the fatty component. cfr i nn / zznz / E / YiAi 8. Powdered soap according to any of the preceding claims, wherein the particles further comprise clay.

9. The powdered soap according to any of the preceding claims, wherein the fatty component is present in an amount that varies from approximately 85% by weight to approximately 95% by weight, based on the total weight of each particle.

10. The powdered soap according to any of the preceding claims, wherein the plurality of particles has an average particle size of at least 600 microns.

11. Powdered soap according to any of the preceding claims, wherein the fatty component is ionic.

12. A personal care composition comprising: a plurality of particles, wherein each particle comprises: an ionic polymer; and a fatty component comprising compounds having Os to Cis chains.

13. The personal care composition according to claim 12, further comprising a fragrance.

14. The personal care composition according to claim 12 or claim 13, wherein the fat component comprises compounds having Cw chains in an amount ranging from approximately 15% by weight to approximately 52% by weight, based on the total weight of the fat component.

15. The personal care composition according to any of claims 12 to 14, wherein the fat component comprises compounds having C-ιθ chains in an amount ranging from approximately 10% by weight to approximately 44.1% by weight, based on the total weight of the fat component.

16. The personal care composition according to any of claims 12 to 15, wherein the fatty component comprises compounds having Cu chains in an amount ranging from approximately 2.7% by weight to approximately 16.4% by weight, based on the total weight of the fatty component.

17. The personal care composition according to any of claims 12 to 16, wherein the fat component comprises compounds having C12 chains in an amount ranging from approximately 8% by weight to approximately 49.5% by weight, based on the total weight of the fat component.

18. The personal care composition according to any of claims 12 to 17, wherein the fat component comprises compounds having C10 chains in an amount of up to approximately 3.6% by weight, based on the total weight of the fat component.

19. The personal care composition according to any of claims 12 to 18, wherein the fat component comprises compounds having Cs chains in an amount of up to approximately 4.5% by weight, based on the total weight of the fat component.

20. The personal care composition according to any of claims 12 to 19, wherein each particle further comprises titanium dioxide or any other suitable pigment.

21. The personal care composition according to claim 20, wherein titanium dioxide is present in an amount ranging from approximately 0.1% by weight to approximately 0.5% by weight, based on the total weight of each particle.

22. The personal care composition according to any of claims 12 to 21, wherein the plurality of particles has an average particle size of at least 600 microns.

23. The personal care composition according to any of claims 12 to 22, wherein the particle plurality has a d77 value of 840 microns.

24. The personal care composition according to any of claims 12 to 23, wherein the personal care composition is in a form selected from: a hand soap; a body wash; a shampoo; a conditioner; and an exfoliant (for example, a facial scrub or a scrub).

25. The personal care composition according to any of claims 12 to 24, wherein the plurality of particles has a medium solubility requiring a limited amount of water during use. cfr i nn / zznz / E / YiAi 26. The personal care composition according to any of claims 12 to 25, wherein the plurality of particles has a medium hardness that allows a limited amount of water during use.

27. The personal care composition according to any of claims 12 to 26, wherein the plurality of particles has a dissolution rate that requires a limited amount of water during use.

28. A method for cleaning a keratin surface comprising applying a soap according to any of claims 1 to 11, or a personal care composition according to any of claims 12 to 27, to a keratin surface of a subject in need.

29. A method for cleaning a keratinous surface comprising applying any of the soaps described herein or any of the personal care compositions described herein to a keratinous surface of a subject in need; and optionally rinsing said keratinous surface.

30. The method according to claim 28 or claim 29, wherein the method does not include a rinsing step.

31. The method according to any of claims 28 to 30, wherein the keratin surface is selected from: skin; hair; a nail; and a combination of two or more of the same.