Fuel components

Abstract

Page 1 of 1 Summary of the invention. Fuel components The components of fuel for spark ignition of an internal combustion engine. It contains additives with a chemical structure that includes six aromatic ring components. This uses two adjacent aromatic carbon atoms along with a saturated 6- heterocyclic ring portion. Or 7 with a saturated heterocyclic ring portion 6- or 7 which consists of atoms of Nitrogen is attached to one of the carbon atoms that are directly shared to form a secondary amine. And atoms selected from oxygen or nitrogen are directly attached to other shared carbon atoms. The remaining atoms in the heterocyclic 6- or 7-carbon ring are additive carbons, which increase the octave value. The fuel manufacturer should improve the characteristics of the fuel's automatic ignition.

Description

FUEL COMPOSITIONSField of the InventionThis invention relates to additives for use in a fuel for a spark-ignition internal combustion engine. In particular, the invention relates to additives for use in increasing the octane number of a fuel for a spark-ignition internal combustion engine. The invention further relates to fuels for a spark-ignition internal combustion engine comprising the octane-boosting additives.Background of the InventionSpark-ignition internal combustion engines are widely used for power, both domestically and in industry. For instance, spark-ignition internal combustion engines are commonly used to power vehicles, such as passenger cars, in the automotive industry.Combustion in spark-ignition internal combustion engines is initiated by a spark which creates a flame front. The flame front progresses from the spark-plug and travels across the combustion chamber rapidly and smoothly until almost all of the fuel is consumed.Spark-ignition internal combustion engines are widely thought to be more efficient when operating at higher compression ratios, i.e. when a higher degree of compression is placed upon the fuel / air mix in the engine prior to its ignition. Thus, modern, high performance spark-ignition internal combustion engines tend to operate at highcompression ratios. Higher compression ratios are also desired when an engine has a high degree of supplemental pressure boosting to the intake charge.However, increasing the compression ratio in an engine increases the possibility of abnormal combustion including that of auto-ignition, particularly when the engine is pressure-boosted. A form of auto-ignition occurs when the end gas, typically understood to be the unburnt gas between the flame front and combustion chamber walls / piston, ignites spontaneously. On ignition, the end gas burns rapidly and prematurely ahead of the flame front in the combustion chamber, causing the pressure in the cylinder to rise sharply. This creates the characteristic knocking or pinking sound and is known as "knock", "detonation" or "pinking". In some cases, particularly with pressure-boosted engines, other forms of auto-ignition can even lead to destructive events known as "mega-knock" or "super-knock".Knock occurs because the octane number (also known as the anti-knock rating or the octane rating) of the fuel is below the anti-knock requirement of the engine. Octane number is a standard measure used to assess the point at which knock will occur for a given fuel. A higher octane number means that a fuel / air mixture can withstand more compression before auto-ignition of the end gas occurs. In other words, the higher the octane number, the better the anti-knock properties of a fuel. Whilst the research octane number (RON) or the motor octane number (MON) may be used to assess the anti-knock performance of a fuel, in recent literature more weight is being given to the RON as an indicator of a fuel's anti-knock performance in modern automotive engines.Accordingly, there is a need for fuels for spark-ignition internal combustion engines which have a high octane number, e.g. a high RON. There is a particular need for fuels for high compression ratio engines, including those utilising a high degree of supplemental pressure boosting to the intake charge, to have a high octane number so that higher engine efficiency may be enjoyed in the absence of knock.In order to increase the octane number, octane improving additives are typically added to a fuel. Such additisation may be carried out by refineries or other suppliers, e.g. fuel terminals or bulk fuel blenders, so that the fuel meets applicable fuel specifications when the base fuel octane number is otherwise too low.Organometallic compounds, comprising e.g. iron, lead or manganese are well- known octane improvers, with tetraethyl lead (TEL) having been extensively used as a highly effective octane improver. However, TEL and other organometallic compounds are generally now only used in fuels in small amounts, if at all, as they can be toxic, damaging to the engine and damaging to the environment.Octane improvers which are not based on metals include oxygenates (e.g. ethers and alcohols) and aromatic amines. However, these additives also suffer from various drawbacks. For instance, N-methyl aniline (NMA), an aromatic amine, must be used at a relatively high treat rate (1.5 to 2 % weight additive / weight base fuel) to have a significant effect on the octane number of the fuel. NMA can also be toxic. Oxygenates give a reduction in energy density in the fuel and, as with NMA, have to be added at high treat rates, potentially causing compatibility problems with fuel storage, fuel lines, seals and other engine components.Effort has been made to find alternative non-metallic octane improvers to NMA.GB 2 308 849 discloses dihydro benzoxazine derivatives for use as anti-knock agents. However, the derivatives provide a significantly smaller increase in the RON of a fuel than is provided by NMA at similar treat rates.Accordingly, there remains a need for additives for a fuel for a spark-ignition internal combustion engine that are able to achieve anti-knock effects, e.g. at least comparable anti-knock effects to NMA, while mitigating at least some of the problems highlighted above.Summary of the InventionSurprisingly, it has now been found that an additive having a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturatedheterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms to form a secondary amine and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon, provides a substantial increase to the octane number, particularly the RON, of a fuel for a spark-ignition internal combustion engine.Accordingly, the present invention provides a fuel composition for a spark-ignition internal combustion engine, the fuel composition comprising an additive having a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms to form a secondary amine and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon (hereinafter described as an "octane-boosting additive").Also provided is a fuel composition for a spark-ignition internal combustion engine, the fuel composition comprising an octane-boosting additive having the formula:where: ¾ is hydrogen;R2, R3, R4, R5, n and R12are each independently selected from hydrogen, alkyl, alkoxy, alkoxy-alkyl, secondary amine and tertiary amine groups;R6, R7, Rs and R9are each independently selected from hydrogen, alkyl, alkoxy, alkoxy-alkyl, secondary amine and tertiary amine groups;X is selected from -O- or -NR10-, where R10is selected from hydrogen and alkyl groups; andn is 0 or 1.The present invention also provides a process for producing a fuel composition of the present invention, the process comprising the step of combining a fuel for a spark- ignition internal combustion engine with an octane-boosting additive described herein.The present invention further provides the use of an octane-boosting additive described herein in a fuel for a spark-ignition internal combustion engine, and the use of an octane-boosting additive described herein for increasing the octane number of a fuel for a spark-ignition internal combustion engine, as well as for improving the auto-ignition characteristics of a fuel, e.g. by reducing the propensity of the fuel for at least one of auto- ignition, pre-ignition, knock, mega-knock and super-knock, when used in a spark-ignition internal combustion engine.Also provided is a method for increasing the octane number of a fuel for a spark- ignition internal combustion engine, as well as a method for improving the auto-ignition characteristics of a fuel, e.g. by reducing the propensity of a fuel for at least one of auto- ignition, pre-ignition, knock, mega-knock and super-knock, when used in a spark-ignition internal combustion engine, said methods comprising blending an octane-boosting additive described herein with the fuel.Brief Description of the FiguresFigures la-c show graphs of the change in octane number (both RON and MON) of fuels when treated with varying amounts of an octane-boosting additive described herein. Specifically, Figure la shows a graph of the change in octane number of an E0 fuel having a RON prior to additisation of 90; Figure lb shows a graph of the change in octane number of an E0 fuel having a RON prior to additisation of 95; and Figure lc shows a graph of the change in octane number of an El 0 fuel having a RON prior to additisation ofFigures 2a-c show graphs comparing the change in octane number (both RON and MON) of fuels when treated with octane-boosting additives described herein and N-methyl aniline. Specifically, Figure 2a shows a graph of the change in octane number of an E0 and an E10 fuel against treat rate; Figure 2b shows a graph of the change in octane number of an E0 fuel at a treat rate of 0.67 % w / w; and Figure 2c shows a graph of the change in octane number of an E10 fuel at a treat rate of 0.67 % w / w.Detailed Description of the InventionOctane-boosting additiveThe present invention provides a fuel composition for a spark-ignition internal combustion engine, said fuel composition comprising an octane-boosting additive.The octane-boosting additive has a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered otherwise saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms to form a secondary amine and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon (referred to in short as an octane-boosting additive described herein). As will be appreciated, the 6- or 7- membered heterocyclic ring sharing two adjacent aromatic carbon atoms with the 6-membered aromatic ring may be considered saturated but for those two shared carbon atoms, and may thus be termed "otherwise saturated."Alternatively stated, the octane-boosting additive used in the present invention may be a substituted or unsubstituted 3,4-dihydro-2H-benzo[b][l,4]oxazine (also known as benzomorpholine), or a substituted or unsubstituted 2,3,4,5-tetrahydro-l,5-benzoxazepine. In other words, the additive may be 3,4-dihydro-2H-benzo[b][l,4]oxazine or a derivative thereof, or 2,3,4,5-tetrahydro-l,5-benzoxazepine or a derivative thereof. Accordingly, the additive may comprise one or more substituents and is not particularly limited in relation to the number or identity of such substituents.Preferred additives have the following formula:where: ¾ is hydrogen;R2, R3, R4, R5, Rn and R12are each independently selected from hydrogen, alkyl, alkoxy, alkoxy-alkyl, secondary amine and tertiary amine groups;R6, R7, R8and R9 are each independently selected from hydrogen, alkyl, alkoxy, alkoxy-alkyl, secondary amine and tertiary amine groups;X is selected from -O- or -NR10-, where R10is selected from hydrogen and alkyl groups; andn is 0 or 1.In some embodiments, R2, R3, R4, R5, Rn and R12are each independently selected from hydrogen and alkyl groups, and preferably from hydrogen, methyl, ethyl, propyl and butyl groups. More preferably, R2, R3, R4, R5, Rn and R12are each independently selected from hydrogen, methyl and ethyl, and even more preferably from hydrogen and methyl.In some embodiments, R6, R7, R8and R9are each independently selected from hydrogen, alkyl and alkoxy groups, and preferably from hydrogen, methyl, ethyl, propyl, butyl, methoxy, ethoxy and propoxy groups. More preferably, R6, R7, R8and R9are each independently selected from hydrogen, methyl, ethyl and methoxy, and even more preferably from hydrogen, methyl and methoxy.Advantageously, at least one of R2, R3, R4, R5, R^, R7, Rg, R9, Rn and R12, and preferably at least one of R , R7, Rg and R9, is selected from a group other than hydrogen. More preferably, at least one of R7and R8is selected from a group other than hydrogen. Alternatively stated, the octane-boosting additive may be substituted in at least one of the positions represented by R2, R3, R4, R5, R^, R7, Rg, R9, Rn and R12, preferably in at least one of the positions represented by R6, R7, Rg and R , and more preferably in at least one of the positions represented by R7and Rg. It is believed that the presence of at least onegroup other than hydrogen may improve the solubility of the octane-boosting additives in a fuel.Also advantageously, no more than five, preferably no more than three, and more preferably no more than two, of R2, R3, R4, R5, R^, R7, R , R9, R and R12 are selected from a group other than hydrogen. Preferably, one or two of R2, R3, Rt, R5, R R7, Rs, R9, Rn and R12are selected from a group other than hydrogen. In some embodiments, only one of R2, R3, R4, R5, R^, R7, R8, R9, Rn and R12is selected from a group other than hydrogen.It is also preferred that at least one of R2and R3is hydrogen, and more preferred that both of R2and R3are hydrogen.In preferred embodiments, at least one of R4, R5, R7and Rg is selected from methyl, ethyl, propyl and butyl groups and the remainder of R2, R3, R4, R5, R6, R7, R8, R9, Rn and R12are hydrogen. More preferably, at least one of R7and Rg are selected from methyl, ethyl, propyl and butyl groups and the remainder of R2, R3, R4, R5, R6, R7, Rs, R9, R11 and R12are hydrogen.In further preferred embodiments, at least one of R4, R5, R7and R8is a methyl group and the remainder of R2, R3, R4, R5, R6, R7, R8, R9, Rn and R12are hydrogen. More preferably, at least one of R7and R8is a methyl group and the remainder of R2, R3, R4, R5, R6, R7, R8, R9, Rn and R12are hydrogen.Preferably, X is -O- or -NR10-, where Rio is selected from hydrogen, methyl, ethyl, propyl and butyl groups, and preferably from hydrogen, methyl and ethyl groups. More preferably, Rio is hydrogen. In preferred embodiments, X is -0-.n may be 0 or 1 , though it is preferred that n is 0.Octane-boostin additives that may be used in the present invention include:A mixture of additives may be used in the fuel composition. For instance, the fuel composition may com rise a mixture of:It will be appreciated that references to alkyl groups include different isomers of the alkyl group. For instance, references to propyl groups embrace n-propyl and i-propyl groups, and references to butyl embrace n-butyl, isobutyl, sec-butyl and tert-butyl groups. Fuel compositionThe octane-boosting additives described herein are used in a fuel composition for a spark-ignition internal combustion engine. It will be appreciated that the octane-boosting additives may be used in engines other than spark-ignition internal combustion engines, provided that the fuel in which the additive is used is suitable for use in a spark-ignition internal combustion engine. Gasoline fuels (including those containing oxygenates) are typically used in spark-ignition internal combustion engines. Commensurately, the fuel composition according to the present invention may be a gasoline fuel composition.The fuel composition may comprise a major amount (i. e. greater than 50 % by weight) of liquid fuel ("base fuel") and a minor amount (i.e. less than 50 % by weight) of octane-boosting additive described herein, i.e. an additive having a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms to form a secondary amine and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7-membered heterocyclic ring being carbon.Examples of suitable liquid fuels include hydrocarbon fuels, oxygenate fuels and combinations thereof.Hydrocarbon fuels that may be used in a spark-ignition internal combustion engine may be derived from mineral sources and / or from renewable sources such as biomass (e.g. biomass-to-liquid sources) and / or from gas-to-liquid sources and / or from coal-to-liquid sources.Oxygenate fuels that may be used in a spark-ignition internal combustion engine contain oxygenate fuel components, such as alcohols and ethers. Suitable alcohols include straight and / or branched chain alkyl alcohols having from 1 to 6 carbon atoms, e.g.methanol, ethanol, n-propanol, n-butanol, isobutanol, tert-butanol. Preferred alcohols include methanol and ethanol. Suitable ethers include ethers having 5 or more carbon atoms, e.g. methyl tert-butyl ether and ethyl tert-butyl ether.In some preferred embodiments, the fuel composition comprises ethanol, e.g.ethanol complying with EN 15376:2014. The fuel composition may comprise ethanol in an amount of up to 85 %, preferably from 1 % to 30 %, more preferably from 3 % to 20 %, and even more preferably from 5 % to 15 %, by volume. For instance, the fuel may contain ethanol in an amount of about 5 % by volume (i.e. an E5 fuel), about 10 % by volume (i.e. an E10 fuel) or about 15 % by volume (i.e. an E15 fuel). A fuel which is free from ethanol is referred to as an E0 fuel.Ethanol is believed to improve the solubility of the octane-boosting additives described herein in the fuel. Thus, in some embodiments, for instance where the octane- boosting additive is unsubstituted (e.g. an additive in which RlsR2, R3, R4, R5, R^, R7, R8and R9are hydrogen; X is -0-; and n is 0) it may be preferable to use the additive with a fuel which comprises ethanol.The fuel composition may meet particular automotive industry standards. For instance, the fuel composition may have a maximum oxygen content of 2.7 % by mass.The fuel composition may have maximum amounts of oxygenates as specified in EN 228, e.g. methanol: 3.0 % by volume, ethanol: 5.0 % by volume, iso-propanol: 10.0 % by volume, iso-butyl alcohol: 10.0 % by volume, tert-butanol: 7.0 % by volume, ethers (e.g. having 5 or more carbon atoms): 10 % by volume and other oxygenates (subject to suitable final boiling point): 10.0 % by volume.The fuel composition may have a sulfur content of up to 50.0 ppm by weight, e.g. up to 10.0 ppm by weight.Examples of suitable fuel compositions include leaded and unleaded fuel compositions. Preferred fuel compositions are unleaded fuel compositions.In embodiments, the fuel composition meets the requirements of EN 228, e.g. as set out in BS EN 228:2012. In other embodiments, the fuel composition meets therequirements of ASTM D 4814, e.g. as set out in ASTM D 4814-15a. It will beappreciated that the fuel compositions may meet both requirements, and / or other fuel standards.The fuel composition for a spark-ignition internal combustion engine may exhibit one or more (such as all) of the following, e.g. , as defined according to BS EN 228:2012: a minimum research octane number of 95.0, a minimum motor octane number of 85.0 a maximum lead content of 5.0 mg / 1, a density of 720.0 to 775.0 kg / m3, an oxidation stability of at least 360 minutes, a maximum existent gum content (solvent washed) of 5 mg / 100 ml, a class 1 copper strip corrosion (3 h at 50 °C), clear and bright appearance, a maximum olefin content of 18.0 % by weight, a maximum aromatics content of 35.0 % by weight, and a maximum benzene content of 1.00 % by volume.The fuel composition may contain the octane-boosting additive described herein in an amount of up to 20 %, preferably from 0.1 % to 10 %, and more preferably from 0.2 % to 5 % weight additive / weight base fuel. Even more preferably, the fuel composition contains the octane-boosting additive in an amount of from 0.25 % to 2 %, and even more preferably still from 0.3 % to 1 % weight additive / weight base fuel. It will be appreciated that, when more than one octane-boosting additive described herein is used, these values refer to the total amount of octane-boosting additive described herein in the fuel.The fuel compositions may comprise at least one other further fuel additive.Examples of such other additives that may be present in the fuel compositions include detergents, friction modifiers / anti-wear additives, corrosion inhibitors, combustion modifiers, anti-oxidants, valve seat recession additives, dehazers / demulsifiers, dyes, markers, odorants, anti-static agents, anti-microbial agents, and lubricity improvers.Further octane improvers may also be used in the fuel composition, i. e. octane improvers which are not octane-boosting additives described herein, i.e. they do not have a chemical structure comprising a 6-membered aromatic ring sharing two adjacent aromatic carbon atoms with a 6- or 7-membered saturated heterocyclic ring, the 6- or 7-membered saturated heterocyclic ring comprising a nitrogen atom directly bonded to one of the shared carbon atoms to form a secondary amine and an atom selected from oxygen or nitrogen directly bonded to the other shared carbon atom, the remaining atoms in the 6- or 7- membered heterocyclic ring being carbon.Examples of suitable detergents include polyisobutylene amines (PIB amines) and polyether amines.Examples of suitable friction modifiers and anti-wear additives include those that are ash-producing additives or ashless additives. Examples of friction modifiers and anti- wear additives include esters (e.g. glycerol mono-oleate) and fatty acids (e.g. oleic acid and stearic acid).Examples of suitable corrosion inhibitors include ammonium salts of organic carboxylic acids, amines and heterocyclic aromatics, e.g. alkylamines, imidazolines and tolyltriazoles.Examples of suitable anti-oxidants include phenolic anti-oxidants (e.g. 2,4-di-tert- butylphenol and 3,5-di-tert-butyl-4-hydroxyphenylpropionic acid) and aminic anti-oxidants (e.g. para-phenylenediamine, dicyclohexylamine and derivatives thereof).Examples of suitable valve seat recession additives include inorganic salts of potassium or phosphorus.Examples of suitable further octane improvers include non-metallic octane improvers include N-methyl aniline and nitrogen-based ashless octane improvers. Metal- containing octane improvers, including methylcyclopentadienyl manganese tricarbonyl, ferrocene and tetra-ethyl lead, may also be used. However, in preferred embodiments, the fuel composition is free of all added metallic octane improvers including methyl cyclopentadienyl manganese tricarbonyl and other metallic octane improvers including e.g. ferrocene and tetraethyl lead.Examples of suitable dehazers / demulsifiers include phenolic resins, esters, polyamines, sulfonates or alcohols which are grafted onto polyethylene or polypropylene glycols.Examples of suitable markers and dyes include azo or anthraquinone derivatives.Examples of suitable anti-static agents include fuel soluble chromium metals, polymeric sulfur and nitrogen compounds, quaternary ammonium salts or complex organic alcohols. However, the fuel composition is preferably substantially free from all polymeric sulfur and all metallic additives, including chromium based compounds.In some embodiments, the fuel composition comprises solvent, e.g. which has been used to ensure that the additives are in a form in which they can be stored or combined with the liquid fuel. Examples of suitable solvents include polyethers and aromatic and / or aliphatic hydrocarbons, e.g. heavy naphtha e.g. Solvesso (Trade mark), xylenes and kerosene.Representative typical and more typical independent amounts of additives (if present) and solvent in the fuel composition are given in the table below. For the additives, the concentrations are expressed by weight (of the base fuel) of active additive compounds, i.e. independent of any solvent or diluent. Where more than one additive of each type is present in the fuel composition, the total amount of each type of additive is expressed in the table below.In some embodiments, the fuel composition comprises or consists of additives and solvents in the typical or more typical amounts recited in the table above.Fuel compositions of the present invention may be produced by a process which comprises combining, in one or more steps, a fuel for a spark-ignition internal combustion engine with an octane-boosting additive described herein. In embodiments in which the fuel composition comprises one or more further fuel additives, the further fuel additives may also be combined, in one or more steps, with the fuel.In some embodiments, the octane-boosting additive may be combined with the fuel in the form of a refinery additive composition or as a marketing additive composition. Thus, the octane-boosting additive may be combined with one or more other components (e.g. additives and / or solvents) of the fuel composition as a marketing additive, e.g. at aterminal or distribution point. The octane-boosting additive may also be added on its own at a terminal or distribution point. The octane-boosting additive may also be combined with one or more other components (e.g. additives and / or solvents) of the fuel composition for sale in a bottle, e.g. for addition to fuel at a later time.The octane-boosting additive and any other additives of the fuel composition may be incorporated into the fuel composition as one or more additive concentrates and / or additive part packs, optionally comprising solvent or diluent.The octane-boosting additive may also be added to the fuel within a vehicle in which the fuel is used, either by addition of the additive to the fuel stream or by addition of the additive directly into the combustion chamber.It will also be appreciated that the octane-boosting additive may be added to the fuel in the form of a precursor compound which, under the combustion conditions encountered in an engine, breaks down to form an octane-boosting additive as defined herein.Uses and methodsThe octane-boosting additives disclosed herein are used in a fuel for a spark- ignition internal combustion engine. Examples of spark-ignition internal combustion engines include direct injection spark-ignition engines and port fuel injection spark- ignition engines. The spark-ignition internal combustion engine may be used in automotive applications, e.g. in a vehicle such as a passenger car.Examples of suitable direct injection spark-ignition internal combustion engines include boosted direct injection spark-ignition internal combustion engines, e.g.turbocharged boosted direct injection engines and supercharged boosted direct injection engines. Suitable engines include 2.0L boosted direct injection spark-ignition internal combustion engines. Suitable direct injection engines include those that have side mounted direct injectors and / or centrally mounted direct injectors.Examples of suitable port fuel injection spark-ignition internal combustion engines include any suitable port fuel injection spark-ignition internal combustion engine including e.g. a BMW 318i engine, a Ford 2.3L Ranger engine and an MB Mi l l engine.The octane-boosting additives disclosed herein may be used to increase the octane number of a fuel for a spark-ignition internal combustion engine. In some embodiments, the octane-boosting additives increase the RON or the MON of the fuel. In preferredembodiments, the octane-boosting additives increase the RON of the fuel, and more preferably the RON and MON of the fuel. The RON and MON of the fuel may be tested according to ASTM D2699-15a and ASTM D2700-13, respectively.Since the octane-boosting additives described herein increase the octane number of a fuel for a spark-ignition internal combustion engine, they may also be used to address abnormal combustion that may arise as a result of a lower than desirable octane number. Thus, the octane-boosting additives may be used for improving the auto-ignition characteristics of a fuel, e.g. by reducing the propensity of a fuel for at least one of auto- ignition, pre-ignition, knock, mega-knock and super-knock, when used in a spark-ignition internal combustion engine.Also contemplated is a method for increasing the octane number of a fuel for a spark-ignition internal combustion engine, as well as a method for improving the auto- ignition characteristics of a fuel, e.g. by reducing the propensity of a fuel for at least one of auto-ignition, pre-ignition, knock, mega-knock and super-knock, when used in a spark- ignition internal combustion engine. These methods comprise the step of blending an octane-boosting additive described herein with the fuel.The methods described herein may further comprise delivering the blended fuel to a spark-ignition internal combustion engine and / or operating the spark-ignition internal combustion engine.The invention will now be described with reference to the following non-limiting examples.ExamplesExample 1 : Preparation of octane-boosting additivesThe followin octane-boosting additives were prepared using standard methods:0X1 OX2 0X3X10 0X11 0X12X19Example 2: Octane number of fuels containing octane-boosting additivesThe effect of octane-boosting additives from Example 1 (0X1, 0X2, 0X3, 0X5, 0X6, 0X8, 0X9, 0X12, 0X13, 0X17 and 0X19) on the octane number of two different base fuels for a spark-ignition internal combustion engine was measured.The additives were added to the fuels at a relatively low treat rate of 0.67 % weight additive / weight base fuel, equivalent to a treat rate of 5 g additive / litre of fuel. The first fuel was an EO gasoline base fuel. The second fuel was an E10 gasoline base fuel. The RON and MON of the base fuels, as well as the blends of base fuel and octane-boosting additive, were determined according to ASTM D2699 and ASTM D2700, respectively.The following table shows the RON and MON of the fuel and the blends of fuel and octane-boosting additive, as well as the change in the RON and MON that was brought about by using the octane-boosting additives:EO base fuel E10 base fuelAdditiveRON MON ARON ΔΜΟΝ RON MON ARON ΔΜΟΝ- 95.4 86.0 n / a n / a 95.4 85.2 n / a n / a0X1 - - - - 97.3 86.3 1.9 1.10X2 97.7 87.7 2.3 1.7 97.8 86.5 2.4 1.30X3 97.0 86.7 1.6 0.7 97.1 85.5 1.7 0.30X5 97.0 86.5 1.6 0.5 97.1 85.5 1.7 0.30X6 98.0 87.7 2.6 1.7 98.0 86.8 2.6 1.60X8 96.9 86.1 1.5 0.1 96.9 85.7 1.5 0.50X9 97.6 86.9 2.2 0.9 97.6 86.5 2.2 1.30X12 97.4 86.3 2.0 0.3 97.3 86.1 1.9 0.90X13 97.9 86.5 2.5 0.5 97.7 86.1 2.3 0.90X17 97.5 86.4 2.1 0.4 97.4 86.4 2.0 1.20X19 97.4 86.1 2.0 0.1 97.6 85.9 2.2 0.7 It can be seen that the octane-boosting additives may be used to increase the RON of an ethanol-free and an ethanol-containing fuel for a spark-ignition internal combustion engine.Further additives from Example 1 (0X4, 0X7, OX10, 0X11, 0X14, 0X15, 0X16 and 0X18) were tested in the EO gasoline base fuel and the E10 gasoline base fuel. Each of the additives increased the RON of both fuels, aside from 0X7 where there was insufficient additive to carry out analysis with the ethanol-containing fuel.Example 3 : Variation of octane number with octane-boosting additive treat rateThe effect of an octane-boosting additive from Example 1 (0X6) on the octane number of three different base fuels for a spark-ignition internal combustion engine was measured over a range of treat rates (% weight additive / weight base fuel).The first and second fuels were EO gasoline base fuels. The third fuel was an E10 gasoline base fuel. As before, the RON and MON of the base fuels, as well as the blends of base fuel and octane-boosting additive, were determined according to ASTM D2699 andASTM D2700, respectively.The following table shows the RON and MON of the fuels and the blends of fuel and octane -boosting additive, as well as the change in the RON and MON that was brought about by using the octane-boosting additives:Additive treat rate Octane number(% w / w) RON MON ARON ΔΜΟΝE0 90 RON 0.00 89.9 82.8 0.0 0.00.20 91.5 83.5 1.6 0.70.30 92.0 83.6 2.1 0.80.40 92.5 83.8 2.6 1.00.50 92.9 83.8 3.0 1.00.67 93.6 84.2 3.7 1.41.01 94.7 85.0 4.8 2.21.34 95.9 85.4 6.0 2.610.00 104.5 87.9 14.6 5.1E0 95 RON 0.00 95.2 85.6 0.0 0.00.10 95.9 85.8 0.7 0.20.20 96.4 86.3 1.2 0.70.30 96.6 86.8 1.4 1.20.40 97.1 86.6 1.9 1.00.50 97.3 87.0 2.1 1.40.60 97.5 86.8 2.3 1.20.70 97.8 86.8 2.6 1.20.80 98.0 87.3 2.8 1.70.90 98.5 86.8 3.3 1.21.00 98.7 86.9 3.5 1.310.00 105.7 88.7 10.5 3.1E10 95 RON 0.00 95.4 85.1 0.0 0.00.10 95.9 85.2 0.5 0.10.20 96.3 86.3 0.9 1.20.30 96.8 86.3 1.4 1.20.40 96.9 85.8 1.5 0.70.50 97.3 85.9 1.9 0.80.60 97.4 85.9 2.0 0.80.70 97.9 86.0 2.5 0.90.80 98.2 86.8 2.8 1.70.90 98.7 86.3 3.3 1.21.00 98.8 86.5 3.4 1.410.00 105.1 87.8 9.7 2.7Graphs of the effect of the octane-boosting additive on the RON and MON of the three fuels are shown in Figures la-c. It can be seen that the octane-boosting additive had a significant effect on the octane numbers of each of the fuels, even at very low treat rates.Example 4: Comparison of octane-boosting additive with N-methyl anilineThe effect of octane-boosting additives from Example 1 (0X2 and 0X6) was compared with the effect of N-methyl aniline on the octane number of two different base fuels for a spark-ignition internal combustion engine over a range of treat rates (% weight additive / weight base fuel).The first fuel was an EO gasoline base fuel. The second fuel was an E10 gasoline base fuel. As before, the RON and MON of the base fuels, as well as the blends of base fuel and octane-boosting additive, were determined according to ASTM D2699 and ASTM D2700, respectively.A graph of the change in octane number of the EO and E10 fuels against treat rate of N-methyl aniline and an octane-boosting additive (0X6) is shown in Figure 2a. The treat rates are typical of those used in a fuel. It can be seen from the graph that the performance of the octane-boosting additives described herein is significantly better than that of N-methyl aniline across the treat rates.A comparison of the effect of two octane-boosting additives (OX2 and 0X6) andN-methyl aniline on the octane number of the EO and E10 fuels at a treat rate of 0.67 % w / w is shown in Figures 2b and 2c. It can be seen from the graph that the performance of octane-boosting additives described herein is significantly superior to that of N-methyl aniline. Specifically, an improvement of about 35 % to about 50 % is observed for the RON, and an improvement of about 45 % to about 75 % is observed for the MON.The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40 mm" is intended to mean "about 40 mm."Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this documentconflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope and spirit of this invention.

Claims

Revised 3 Sep 2018. No claims. ++++++++++++++++++++++++ Page 1 of 6. Claims:

1. A fuel composition for spark ignition of an internal combustion engine in which the fuel composition consists of additives whose chemical structure includes an aromatic 6-ring portion utilizing two adjacent aromatic carbon atoms, along with a saturated 6- or 7-ring heterocyclic portion containing a nitrogen atom directly attached to one of the shared carbon atoms to form a secondary amine with a selected oxygen or nitrogen atom directly attached to another shared carbon atom, where the remaining atoms in the saturated 6- or 7-ring are carbon. 2.The fuel composition according to claim 1, where the additives have the chemical formula: where: R, is hydrogen; R2, R3, R4, R5, R11 and R12 are each independently selected from hydrogen, alkyl, alkoxy, alkoxy-alkyl, secondary amine and tertiary amine groups; R6, R7, R8 and Rg are each independently selected from hydrogen, alkyl, alkoxy, alkoxy-alkyl, secondary amine and tertiary amine groups; function 2 of 6 functions X is selected from -O- or -NR10-, where R10 is selected from hydrogen and alkyl groups and n is 0 or 13. The fuel composition according to claim 2, where R2, R3, R4, R6, R1 and R12 are each independently selected from hydrogen groups. The fuel composition according to claim 2 or claim 3, where R6, R7, R8, and R9 are each independently selected from hydrogen, alkyl, and alkoxy groups; the best from hydrogen, methyl, ethyl, propyl, and butyl groups; the better from hydrogen, methyl, and ethyl groups; and the even better from hydrogen and methyl groups. 5.The fuel composition under any one of Reservations 2 to 4, where at least one of the R2, R3, R4, R5, R6, R7, R8, R9, R11 and R12, and ideally at least one of the R6, R7, R8 and R9, is selected from groups other than hydrogen.

6. The fuel composition under any one of Reservations 2 to 5, where no more than five, ideally no more than three and ideally no more than two of the R2, R3, R4, R5, R6, R7, R8, R9, R11 and R12, are selected from groups other than hydrogen.

7. The fuel composition under any one of Reservations 2 to 6, where... At least one of the R2 and R3 is hydrogen, and ideally, R2 and R3 are hydrogen.

8. Fuel composition according to any one of claims 2 to 7, where at least one of the R4, R5, R7, and R8 is chosen from the methyl, ethyl, propyl, and butyl groups, and the remaining R2, R3, R4, R5, R6, R7, R8, R9, R11, and R12 are hydrogen, and ideally, at least one of the R7 (3 of 6) and R8 is chosen from the methyl, ethyl, propyl, and butyl groups, and the remaining R2, R3, R4, R6, R7, R8, R9, R11, and R12 are hydrogen. 9.Fuel composition according to claim 8 where at least one of the R4, R5, R7 and R8 is methyl group and the remainder of R2, R3, R4, R5, R6, R7, R8, R9, R11 and R12 is hydrogen and ideally where at least one of the R7 and R8 is methyl group and the remainder of R2, R3, R4, R5, R6, R7, R8, R9, R11 and R12 is hydrogen.

10. Fuel composition according to any one of claims 2 through 9 where X is -0- or -NR10- where R10 is chosen from hydrogen, methyl, ethyl, propyl and butyl groups, ideally from hydrogen, methyl and ethyl groups and even better is hydrogen and ideally by Where X is -O? 11. Fuel composition according to any one of claims 2 through 10, where n is 0.

12. Fuel composition according to any prior claim, where the additives are selected from: Chemical formula page 4 of 6; Chemical formula page 5 of 6.

13. Fuel composition according to any prior claim, where the additives are present in the fuel composition in an additive quantity by weight / weight of base fuel up to 20%, ideally from 0.1% to 10%, better from 0.2% to 5%, even better from 0.25% to 2%, and even better from 0.3% to 1% 14. The composition of fuel under any prior claim where ethanol is present in the fuel composition in an amount up to 85%, ideally from 1% to 30%, better than that, from 3% to 20%, and even better than that, from 5% to 15% by volume.

15. The process of manufacturing the fuel composition of any of the claims 1-14 where the process involves combining the fuel for internal combustion engine spark ignition with any of the additives specified in any of the claims 1-14.

16. The use of any of the additives specified in any of the claims 1-14 in the fuel for internal combustion engine spark ignition.

17. The use of any of the additives specified in any of the claims 1-14 to increase the octane rating of the fuel for internal combustion engine spark ignition. 18.The use of any of the additives specified in Patent 1-14 to improve the autoignition characteristics of a fuel, for example, by reducing the fuel's propensity for at least one of the autoignition, pre-ignition, knock, mega-knock, and super-knock, when used in spark ignition of an internal combustion engine; page 6 of 6, page 19. Methods to increase the octane rating of fuel for spark ignition of an internal combustion engine where such method involves the blending of any of the additives specified in Patent 1-14 with the fuel; 20. Methods to improve the autoignition characteristics of a fuel, for example, by reducing the fuel's propensity for at least one of the autoignition, pre-ignition, knock, mega-knock, and super-knock, when used in spark ignition of an internal combustion engine where such method involves the blending of any of the additives specified in Patent 1-14 with the fuel;