An Electrolyte Solution Containing a Hybrid Additive

Abstract

This invention relates to an electrolyte solution to which hybrid additives are added, and the method of producing this electrolyte solution, with the aim of improving the performance of lead-acid batteries, particularly by reducing sulfation formation at the negative electrodes, preventing lead sulfate (PbSO₄) accumulation, increasing charge acceptance, and extending cycle life.

Description

AN ELECTROLYTE SOLUTION CONTAINING A HYBRID ADDITIVE Technical Area This invention aims to improve the performance of lead-acid batteries, especially negative lead-acid batteries. By reducing sulfation formation on the electrodes, lead sulfate (PbSO₄) accumulation is prevented. hybrid additives are used to prevent blocking, increase charge acceptance, and extend cycle life. an electrolyte solution to which the substances are added and the electrolyte solution in question It is related to the production method. Previous Technique Traditional lead-acid batteries do not use any additives. The battery's charging and discharging processes are carried out. However, this is the case today. This condition, known as sulfation in batteries, seriously affects battery performance. This leads to a problem that has a negative impact. Sulfation, especially at the negative electrodes. It is formed by the formation and accumulation of lead sulfate (PbSO₄) crystals. The issue is accumulation, where active material is becoming increasingly passive and the battery... This leads to a decrease in its capacity. As a result, the battery's ability to accept charge decreases. It is declining, cycle life is shortening, and performance losses are occurring. Lead sulfate crystals accumulate on the negative electrodes during the charging process. By not dissolving, it reduces the battery's capacity and efficiency. This situation This leads to a shorter battery cycle life and a decrease in performance. At the same time, sulfation reduces the battery's charge acceptance, increases charging time, and This situation negatively affects the battery's efficiency. Furthermore, the electrolyte... Failure to maintain chemical balance leads to inefficient charging and discharging processes, and An imbalance in pH levels can lead to a decrease in the overall performance of the battery. This is the reason. In addition, the self-discharge problem also causes the battery to last a long time. This causes energy loss and reduced efficiency during storage. 1. These problems are the main ones that prevent batteries from operating for a long time and with high efficiency. These are problems. Therefore, nowadays, controlling sulfation and charge acceptance are crucial. The need to use additives to increase and extend battery life It is heard. Brief Description of the Invention The aim of this invention is to improve the performance of lead-acid batteries and to increase battery charging time. To increase acceptance and extend cycle life, a hybrid additive of Na₂EDTA and Na₂SO₄ is used. an electrolyte solution to which the substance is added and the production of said electrolyte solution to implement the method. Detailed Description of the Invention To improve the performance of lead-acid batteries, especially in the negative electrodes. By reducing the sulfation that occurs, it prevents the accumulation of lead sulfate (PbSO₄), charging an invented electrolyte that increases acceptance and extends cycle life The solution contains sulfuric acid supplemented with a hybrid additive of Na₂EDTA and Na₂SO₄. The subject of the invention is an electrolyte solution containing sulfuric acid at a concentration of 30-40%. The electrolyte contains 4% Na₂EDTA and 1% Na₂SO₄. The solution is subjected to ultrasonic mixing or high-speed mechanical mixing. a homogeneous mixture is obtained by holding it. The electrolyte solution described in this invention improves the performance of lead-acid batteries. This is achieved by adding Na₂EDTA and Na₂SO₄ hybrid additives to the electrolyte. This is done. In the electrolyte solution, Na₂EDTA prevents sulfation at the negative electrodes. by reducing lead sulfate crystal formation and accumulation, Na₂SO₄ It maintains the chemical balance of the electrolyte solution, keeping the pH level stable. Hybrid additives of Na₂EDTA and Na₂SO₄ improve battery charge acceptance while extending cycle life. This extends the battery's lifespan. At the same time, the synergistic effect of Na₂EDTA and Na₂SO₄ extends the overall battery life. It significantly improves its performance compared to traditional methods. 2 To improve the performance of lead-acid batteries, especially in the negative electrodes. By reducing the sulfation that occurs, it prevents the accumulation of lead sulfate (PbSO₄), charging electrolyte solution production that increases acceptance and extends cycle life method, - Preparation of high-purity Na₂EDTA and Na₂SO₄ particles, -The surface properties of Na₂EDTA and Na₂SO₄ additives are compatible with sulfuric acid. to be brought into a state, - Preparation of a sulfuric acid solution at a concentration of 30-40%, -adding Na₂EDTA and Na₂SO₄ to the sulfuric acid solution and - homogeneous distribution of Na₂EDTA and Na₂SO₄ additives in sulfuric acid solution application of the mixing method for and -This includes the steps for obtaining an electrolyte solution containing a hybrid additive. The production method described in the invention initially involves obtaining high-purity Na₂EDTA and Na₂SO₄. is being processed and Na₂EDTA and Na₂SO₄ particles are being prepared in an appropriate size. They are prepared in this way, ensuring their stability within the electrolyte. After preparing Na₂EDTA and Na₂SO₄ particles of appropriate size, the surface Modification was carried out to remove the surface additives Na₂EDTA and Na₂SO₄. Its properties are made compatible with sulfuric acid. Thus, the additive in the solution... This ensures the homogeneous distribution of the substances and their stability in the electrolyte. The invention describes a production method in which Na₂EDTA and Na₂SO₄ particles will be added. The sulfuric acid solution is prepared at a concentration of 30-40%, and 4% is added to it. Na₂EDTA at a certain percentage and Na₂SO₄ at a certain percentage are added to the battery. This ratio is used to determine the battery's composition. Its design can be adjusted according to the desired performance criteria. Na₂EDTA and Ultrasonic mixing for even distribution of Na₂SO₄ additives in sulfuric acid. or at least one of the high-speed mechanical mixing processes is applied. This prevents the aggregation of added particles and ensures they are present throughout the electrolyte. Homogeneous distribution is ensured. 3. The subject of the invention is sulfuric acid supplemented with Na₂EDTA and Na₂SO₄ obtained by the production method. electrolyte solution to battery cells containing lead plates and other battery components The system is filled and the electrolyte is distributed evenly in each cell. Then the battery is charged and activated for the first time, and during this process hybrid additives are used. It interacts with the electrode surfaces. This interaction leads to an increase in battery performance. This is important to ensure that the battery performs as well as after the first charge following this process. The battery is subjected to tests to determine its capacity and charge-discharge efficiency. and its long-term durability is being evaluated. The subject of the invention is the use of a hybrid additive of Na₂EDTA and Na₂SO₄ in an electrolyte solution. Its use provides significant performance improvements in lead-acid batteries. The hybrid additive, Na₂EDTA, reduces the lead sulfate formed at the negative electrodes. By causing the crystals to dissolve, it reduces sulfation, thus extending the battery's cycle life. It extends the battery's lifespan. In addition, the addition of Na₂EDTA to the electrolyte extends the battery's lifespan. It provides an increase in capacity and efficiency. Na₂SO₄, on the other hand, is the chemical composition of the electrolyte. By maintaining its balance, it keeps the pH level stable and increases charge acceptance. The addition of Na₂SO₄ helps maintain pH balance during the battery's charging and discharging processes, resulting in better performance. It contributes to an efficient charging process. The hybrid additive of Na₂EDTA and Na₂SO₄... The synergistic effect it provides increases the electrical conductivity of the battery, thereby improving charge acceptance. It improves and reduces sulfate buildup. This allows the battery cycle to be extended. Efficiency increases and an improvement in C-rate performance is observed. Furthermore, Na₂EDTA addition controls positive active material morphology and formation. increasing efficiency in the process, reducing energy loss of the battery during storage It minimizes and reduces the self-discharge rate. Electrolyte Na₂EDTA and Na₂SO₄ added to the solution are low-cost and readily available. Since the materials are involved, the battery production processes are those that exist in the known state of the art. It is easy to integrate and requires no additional costs. Based on these fundamental concepts, the invention is titled "An Electrolyte Containing Hybrid Additives". It is possible to develop a wide variety of applications related to the "Solution", and the invention is presented here. It cannot be limited to the examples given; it is essentially as stated in the claims. 4

Claims

1. To improve the performance of lead-acid batteries, and especially the negative By reducing sulfation formation on the electrodes, lead sulfate (PbSO₄) accumulation is prevented. Na₂EDTA, which helps to block, improve charge acceptance and extend cycle life. and an electrolyte solution containing sulfuric acid with added Na₂SO₄ hybrid additive.

2. 30-40% sulfuric acid, 4% Na₂EDTA and 1% An electrolyte as described in Claim 1, characterized by containing Na₂SO₄ in the specified ratio. solution.

3. To improve the performance of lead-acid batteries, and especially the negative By reducing sulfation formation on the electrodes, lead sulfate (PbSO₄) accumulation is prevented. By preventing blocking, increasing charge acceptance and extending cycle life, - Preparation of high-purity Na₂EDTA and Na₂SO₄ particles, -The surface properties of Na₂EDTA and Na₂SO₄ additives are compatible with sulfuric acid. to be brought into being, - Preparation of a sulfuric acid solution at a concentration of 30-40%, -adding Na₂EDTA and Na₂SO₄ to the sulfuric acid solution and - homogeneous distribution of Na₂EDTA and Na₂SO₄ additives in sulfuric acid solution application of the mixing method for and - It includes the steps for obtaining an electrolyte solution containing a hybrid additive. A characterized method for producing an electrolyte solution.

4. Obtaining high-purity Na₂EDTA and Na₂SO₄ and processing Na₂EDTA and Na₂SO₄ The term is characterized by the preparation of particles of the appropriate size. A method for producing an electrolyte solution, as in step 3.

5. After preparing Na₂EDTA and Na₂SO₄ particles of appropriate size, the surface Modification was carried out to remove the surface additives Na₂EDTA and Na₂SO₄. Claim 3 is characterized by the harmonization of its properties with sulfuric acid. or an electrolyte solution production method as in 4.

6. A 30-40% sulfuric acid solution to which Na₂EDTA and Na₂SO₄ particles will be added. prepared at a concentration and containing 4% Na₂EDTA and 1% A claim like any of 3 to 5 characterized by the addition of Na₂SO₄. Method of producing electrolyte solution.

7. To ensure even distribution of Na₂EDTA and Na₂SO₄ additives in sulfuric acid. at least one of the following processes: ultrasonic mixing or high-speed mechanical mixing an electrolyte as in any of Claims 3 to 6 characterized by its application Solution production method. 6