Manufacturing methods of planarization films, materials for planarization films, planarization films, electronic devices and coatings

Abstract

This invention provides a method for manufacturing a planarization film with excellent productivity and the ability to form a planarization film with excellent planarity on the uneven surface of a substrate with low heat resistance, as well as a planarization film material and a planarization film. The method for manufacturing the planarization film 2 involves forming a planarization film 2 on a substrate 1 having an uneven surface 11 using a planarization film material via PECVD. The planarization film material comprises one or more organosilanes selected from the group consisting of alcohols and water, and an oxidant. The planarization film 2 is formed by sequentially or simultaneously forming and curing an uncured film derived from the planarization film material on the substrate 1. Both the formation and curing of the uncured film are caused by a plasma-induced chemical reaction.

Description

Technical field

[0001] The disclosure relates to a method for manufacturing a planarization film, a material for a planarization film, and a planarization film.

Prior Technology

[0002] The planarizing film is formed for the purpose of filling the grooves existing in the base material, or filling the surroundings of structures and particles protruding from the base material, so as to flatten the uneven surface of the base material.

[0003] In a semiconductor device such as a dynamic random access memory (Dynamic Random Access Memory, DRAM), an insulating film (element separation insulating film) is provided between adjacent elements, and the insulating film ensures the distance between the elements. insulation. Here, the element isolation insulating film is formed by embedding an insulating film in a groove (element isolation trench) provided in the semiconductor substrate.

[0004] As a method for flattening the unevenness of the substrate, for example, Patent Document 1 discloses a flowable chemical vapor deposition (Chemical Vapor Deposition, CVD) method. The embedding of the planarization film by the fluid CVD method is a method in which a fluid silicon compound (mainly silanol (Si(OH) )4)) After the film, it is modified into a silicon oxide film by oxidation reaction. A film of a fluid silicon compound can easily enter a narrow space, so it has the advantages of being excellent in embedding properties and less likely to generate voids. [Prior Art Documents] [Patent Documents]

[0005] [Patent Document 1] Japanese Patent Application Laid-Open No. 2012-231007

Content of invention

[0007] Therefore, in the method of Patent Document 1, due to the volume shrinkage of the silicon compound film, shrinkage or voids are generated in the obtained planarization film, whereby there is a problem that the flatness of the planarization film is reduced, or due to The shrinkage of the volume of the silicon compound film causes shrinkage stress on the obtained planarization film, thereby causing a problem in that the film strength of the planarization film decreases. In addition, the method of Patent Document 1 also has a problem in that it cannot be applied to substrates / structures with low heat resistance because oxidation annealing at high temperature thermally changes the structure of the substrate or surroundings. Furthermore, in the method of Patent Document 1, since two or more steps are required such as the formation of the silicon compound film and the subsequent oxidation annealing treatment, there is also a problem in terms of low productivity. Therefore, the present invention is made in view of the above-mentioned problems, and an object of the present invention is to provide a planarizing film that is excellent in productivity and can form a planarizing film with excellent flatness on the uneven surface of a base material with low heat resistance. A manufacturing method, a material for a planarizing film, and a planarizing film. [Means to solve the problem]

[0009] According to an aspect of the present disclosure, a method for manufacturing a planarized film is provided, which is formed by planarizing a substrate with a concave-convex surface by plasma-enhanced chemical vapor deposition (PECVD) method. The material for the planarization film forms a planarization film that planarizes the uneven surface. In the method for manufacturing the planarization film, the material for the planarization film includes: an organosilane compound, selected from the group consisting of alcohol and water One or more of them, and an oxidizing agent, the formation of the planarization film is performed by sequentially or simultaneously forming and curing an uncured film from the material for the planarization film on the substrate, so Both the formation and curing of the uncured film are caused by chemical reactions excited by the plasma.

[0010] According to an aspect of the present disclosure, as a planarizing film material for planarizing the uneven surface in the substrate, the following planarizing film material is provided, which contains the following formula (1 ), the group consisting of monosiloxane represented by formula (2), cyclic siloxane represented by formula (3), and trisiloxane represented by formula (4) more than one organosilane compound.

[0011] [chemical 1]

[0012] In the formula (1), R1 is phenyl or benzyl, or a linear, branched or cyclic alkyl group with 1 to 10 carbons, R2 is an alkenyl group with 1 to 10 carbons, a carbon number an alkynyl group of 1-10, an alkoxy group of 1-10 carbons, a hydroxyl group or a hydrogen atom, and a is an integer of 2-4.

[0013] [chemical 2]

[0014] In formula (2), R3 is phenyl or benzyl, or straight-chain, branched or cyclic alkyl with 1 to 10 carbons, R4 is alkenyl with 1 to 10 carbons, carbon number an alkynyl group of 1-10, an alkoxy group of 1-10 carbons, a hydroxyl group or a hydrogen atom, and b is an integer of 1-3.

[0015] [chemical 3]

[0016] In formula (3), R5 is phenyl or benzyl, or straight-chain, branched or cyclic alkyl with 1 to 10 carbons, R6 is alkenyl with 1 to 10 carbons, carbon number An alkynyl group of 1-10, an alkoxy group of 1-10 carbons, a hydroxyl group or a hydrogen atom, c is an integer of 0-2, and n is an integer of 2-6.

[0017] [chemical 4]

[0018] In formula (4), R7 is phenyl or benzyl, or straight-chain, branched or cyclic alkyl with 1 to 10 carbons, R8 is alkenyl with 1 to 10 carbons, carbon number an alkynyl group with 1 to 10 carbons, an alkoxy group with 1 to 10 carbons, a hydroxyl group or a hydrogen atom, R9 is a phenyl or benzyl group, or a linear, branched or cyclic alkyl group with 1 to 10 carbons, R10 is an alkenyl group with 1 to 10 carbons, an alkynyl group with 1 to 10 carbons, an alkoxy group with 1 to 10 carbons, a hydroxyl group or a hydrogen atom, d is an integer of 0 to 3, and e is an integer of 0 to 2 .

[0019] According to an aspect of the present disclosure, a planarization film is provided, including components derived from the material for the planarization film.

[0020] According to an aspect of the present disclosure, an electronic device is provided, including the planarization film.

[0021] According to an aspect of the present disclosure, a coating film including the planarization film is provided. [Effect of the invention]

[0022] According to an aspect of the present disclosure, there can be provided a method for producing a planarizing film that is excellent in productivity and can form a planarizing film with excellent planarity on the uneven surface of a substrate with low heat resistance, and a planarizing film. Materials and planarization films.

Implementation

[0024] Hereinafter, each aspect of the present disclosure will be described in detail.

[0025] <Method for manufacturing a planarizing film> The method for manufacturing a planarizing film of the present invention is to form a planarizing film from a material for a planarizing film by PECVD (plasma-enhanced chemical vapor deposition) on a substrate having a concave-convex surface. In the planarizing film for planarizing the concave-convex surface, in the method for manufacturing the planarizing film, the material for the planarizing film includes: an organosilane compound, one or more selected from the group consisting of alcohol and water, and an oxidizing agent, wherein the formation of the planarizing film is performed by sequentially or simultaneously forming and curing an uncured film derived from the material for the planarizing film on the substrate, and the formation of the uncured film Both curing and curing are caused by chemical reactions excited by plasma.

[0026] In this way, an organosilane compound is used as a material for a planarization film, and one or more oxidizing agents selected from the group consisting of alcohol and water are combined in it for a chemical reaction excited by plasma, so it can be An uncured film derived from the material for a planarizing film is formed on the uneven surface of the substrate. The uncured film formed at this time is formed along the unevenness on the surface of the substrate, and is preferably formed so as to be able to flow on the uneven surface, so it has the function of flattening the unevenness on the surface of the substrate. In addition, since the curing of the uncured film proceeds after the formation of the uncured film or simultaneously with the formation of the uncured film, a planarizing film can be formed without an additional step such as oxidation annealing at high temperature. Therefore, it is possible to provide a method for producing a planarization film that is excellent in productivity and can form a planarization film with excellent flatness on the uneven surface of a base material with low heat resistance, a material for a planarization film, and a planarization film.

[0027] <<organosilane compound>> The planarizing film material used in the preparation of the planarizing film of the present invention contains at least an organosilane compound. Here, the organosilane compound preferably contains a monosilane represented by the formula (1), a disiloxane represented by the formula (2), a cyclic siloxane represented by the formula (3), and a formula ( 4) More than one organosilane compound in the group consisting of the indicated trisiloxanes.

[0028] [Chemical 5]

[0029] In the formula (1), R1 is phenyl or benzyl, or a linear, branched or cyclic alkyl group with 1 to 10 carbons, and R2 is an alkenyl group with 1 to 10 carbons, or an alkenyl group with 1 to 10 carbons an alkynyl group of 1-10, an alkoxy group of 1-10 carbons, a hydroxyl group or a hydrogen atom, and a is an integer of 2-4.

[0030] [chemical 6]

[0031] In formula (2), R3 is phenyl or benzyl, or straight-chain, branched or cyclic alkyl with 1 to 10 carbons, R4 is alkenyl with 1 to 10 carbons, carbon number an alkynyl group of 1-10, an alkoxy group of 1-10 carbons, a hydroxyl group or a hydrogen atom, and b is an integer of 1-3.

[0032] [chemical 7]

[0033] In the formula (3), R5 is phenyl or benzyl, or a linear, branched or cyclic alkyl group with 1 to 10 carbons, R6 is an alkenyl group with 1 to 10 carbons, carbon number An alkynyl group of 1-10, an alkoxy group of 1-10 carbons, a hydroxyl group or a hydrogen atom, c is an integer of 0-2, and n is an integer of 2-6.

[0034] [chemical 8]

[0035] In formula (4), R7 is phenyl or benzyl, or straight-chain, branched or cyclic alkyl with 1 to 10 carbons, R8 is alkenyl with 1 to 10 carbons, carbon number an alkynyl group with 1 to 10 carbons, an alkoxy group with 1 to 10 carbons, a hydroxyl group or a hydrogen atom, R9 is a phenyl or benzyl group, or a linear, branched or cyclic alkyl group with 1 to 10 carbons, R10 is an alkenyl group with 1 to 10 carbons, an alkynyl group with 1 to 10 carbons, an alkoxy group with 1 to 10 carbons, a hydroxyl group or a hydrogen atom, d is an integer of 0 to 3, and e is an integer of 0 to 2 .

[0036] It is particularly preferred that R2, R4, R6, R8, and R10 are respectively an alkenyl group with 1 to 5 carbons, an alkynyl group with 1 to 5 carbons, an alkoxy group with 1 to 10 carbons, a hydroxyl group or a hydrogen atom.

[0037] In formulas (1) to (4), straight-chain, branched or cyclic alkyl groups having 1 to 10 carbon atoms include, for example, methyl, ethyl, n-propyl, iso Propyl, n-butyl, isobutyl, second-butyl, third-butyl, 2-ethylhexyl, cyclopropyl, cyclobutyl, cyclohexyl, etc.

[0038] In formulas (1) to (4), examples of alkenyl groups having 1 to 10 carbon atoms include vinyl, allyl, propenyl, isopropenyl, butenyl, and hexenyl , cyclohexenyl, etc.

[0039] In formulas (1) to (4), examples of the alkynyl group having 1 to 10 carbon atoms include ethynyl, 1-propynyl, 2-propynyl and the like.

[0040] In formulas (1) to (4), as an alkoxy group having 1 to 10 carbon atoms, for example, methoxy, ethoxy, n-propoxy, isopropoxy, n-butyl Oxygen, isobutoxy, second butoxy, third butoxy, n-pentoxy, second pentoxy, third pentoxy, neopentyloxy, n-hexyloxy, n-heptyloxy , n-octyloxy, 2-ethylhexyloxy, etc.

[0041] Among the compounds represented by formulas (1) to (4), compounds 1 to 13208 described later are more preferred. In addition, the thing represented by the abbreviation among the compounds 1-13208 is as follows. Me: methyl Et: ethyl nPr: n-propyl iPr: isopropyl nBu: n-butyl iBu: isobutyl secBu: second-butyl tBu: third-butyl OH: hydroxyl OMe: methoxy OEt: Ethoxy OnPr: n-propoxy OiPr: isopropoxy OnBu: n-butoxy OiBu: isobutoxy OsecBu: second butoxy OtBu: third butoxy

[0042] Therefore, for example, in the case of compound 1, it is expressed as a monosilane represented by formula (1) (that is, SiR1 (4-a) R2a), and R1 is a methyl group, and (4-a) is 2 (that is, a is 2), and both R2 are vinyl monosilanes. That is, Compound 1 is a monosilane represented by Si(CH3)2(C2H3)2.

[0043] Among the compounds represented by formulas (1) to (4), those having a molecular weight of 400 or less are preferred from the viewpoint of vapor pressure.

[0044] [Chemical 9] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1 Me 2 vinyl 2 Oh 0 0 2 Me 2 vinyl 1 Oh 1 0 3 Me 2 vinyl 1 Oh 0 1 4 Me 2 vinyl 0 Oh 2 0 5 Me 2 vinyl 0 Oh 1 1 6 Me 2 vinyl 0 Oh 0 2 7 Me 1 vinyl 3 Oh 0 0 8 Me 1 vinyl 2 Oh 1 0 9 Me 1 vinyl 2 Oh 0 1 10 Me 1 vinyl 1 Oh 2 0 11 Me 1 vinyl 1 Oh 1 1 12 Me 1 vinyl 1 Oh 0 2 13 Me 1 vinyl 0 Oh 3 0 14 Me 1 vinyl 0 Oh 2 1 15 Me 1 vinyl 0 Oh 1 2 16 Me 1 vinyl 0 Oh 0 3 17 Me 0 vinyl 4 Oh 0 0 18 Me 0 vinyl 3 Oh 1 0 19 Me 0 vinyl 3 Oh 0 1 20 Me 0 vinyl 2 Oh 2 0 twenty one Me 0 vinyl 2 Oh 1 1 twenty two Me 0 vinyl 2 Oh 0 2 twenty three Me 0 vinyl 1 Oh 3 0 twenty four Me 0 vinyl 1 Oh 2 1 25 Me 0 vinyl 1 Oh 1 2 26 Me 0 vinyl 1 Oh 0 3 27 Me 0 vinyl 0 Oh 4 0 28 Me 0 vinyl 0 Oh 3 1 29 Me 0 vinyl 0 Oh 2 2 30 Me 0 vinyl 0 Oh 1 3 31 Me 0 vinyl 0 Oh 0 4

[0045] [chemical 10] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 32 Me 2 Allyl 2 Oh 0 0 33 Me 2 Allyl 1 Oh 1 0 34 Me 2 Allyl 1 Oh 0 1 35 Me 2 Allyl 0 Oh 2 0 36 Me 2 Allyl 0 Oh 1 1 37 Me 2 Allyl 0 Oh 0 2 38 Me 1 Allyl 3 Oh 0 0 39 Me 1 Allyl 2 Oh 1 0 40 Me 1 Allyl 2 Oh 0 1 41 Me 1 Allyl 1 Oh 2 0 42 Me 1 Allyl 1 Oh 1 1 43 Me 1 Allyl 1 Oh 0 2 44 Me 1 Allyl 0 Oh 3 0 45 Me 1 Allyl 0 Oh 2 1 46 Me 1 Allyl 0 Oh 1 2 47 Me 1 Allyl 0 Oh 0 3 48 Me 0 Allyl 4 Oh 0 0 49 Me 0 Allyl 3 Oh 1 0 50 Me 0 Allyl 3 Oh 0 1 51 Me 0 Allyl 2 Oh 2 0 52 Me 0 Allyl 2 Oh 1 1 53 Me 0 Allyl 2 Oh 0 2 54 Me 0 Allyl 1 Oh 3 0 55 Me 0 Allyl 1 Oh 2 1 56 Me 0 Allyl 1 Oh 1 2 57 Me 0 Allyl 1 Oh 0 3 58 Me 0 Allyl 0 Oh 4 0 59 Me 0 Allyl 0 Oh 3 1 60 Me 0 Allyl 0 Oh 2 2 61 Me 0 Allyl 0 Oh 1 3 62 Me 0 Allyl 0 Oh 0 4

[0046] [chemical 11] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 63 Me 2 Ethynyl 2 Oh 0 0 64 Me 2 Ethynyl 1 Oh 1 0 65 Me 2 Ethynyl 1 Oh 0 1 66 Me 2 Ethynyl 0 Oh 2 0 67 Me 2 Ethynyl 0 Oh 1 1 68 Me 2 Ethynyl 0 Oh 0 2 69 Me 1 Ethynyl 3 Oh 0 0 70 Me 1 Ethynyl 2 Oh 1 0 71 Me 1 Ethynyl 2 Oh 0 1 72 Me 1 Ethynyl 1 Oh 2 0 73 Me 1 Ethynyl 1 Oh 1 1 74 Me 1 Ethynyl 1 Oh 0 2 75 Me 1 Ethynyl 0 Oh 3 0 76 Me 1 Ethynyl 0 Oh 2 1 77 Me 1 Ethynyl 0 Oh 1 2 78 Me 1 Ethynyl 0 Oh 0 3 79 Me 0 Ethynyl 4 Oh 0 0 80 Me 0 Ethynyl 3 Oh 1 0 81 Me 0 Ethynyl 3 Oh 0 1 82 Me 0 Ethynyl 2 Oh 2 0 83 Me 0 Ethynyl 2 Oh 1 1 84 Me 0 Ethynyl 2 Oh 0 2 85 Me 0 Ethynyl 1 Oh 3 0 86 Me 0 Ethynyl 1 Oh 2 1 87 Me 0 Ethynyl 1 Oh 1 2 88 Me 0 Ethynyl 1 Oh 0 3 89 Me 0 Ethynyl 0 Oh 4 0 90 Me 0 Ethynyl 0 Oh 3 1 91 Me 0 Ethynyl 0 Oh 2 2 92 Me 0 Ethynyl 0 Oh 1 3 93 Me 0 Ethynyl 0 Oh 0 4

[0047] [chemical 12] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 94 Me 2 vinyl 2 OMe 0 0 95 Me 2 vinyl 1 OMe 1 0 96 Me 2 vinyl 1 OMe 0 1 97 Me 2 vinyl 0 OMe 2 0 98 Me 2 vinyl 0 OMe 1 1 99 Me 2 vinyl 0 OMe 0 2 100 Me 1 vinyl 3 OMe 0 0 101 Me 1 vinyl 2 OMe 1 0 102 Me 1 vinyl 2 OMe 0 1 103 Me 1 vinyl 1 OMe 2 0 104 Me 1 vinyl 1 OMe 1 1 105 Me 1 vinyl 1 OMe 0 2 106 Me 1 vinyl 0 OMe 3 0 107 Me 1 vinyl 0 OMe 2 1 108 Me 1 vinyl 0 OMe 1 2 109 Me 1 vinyl 0 OMe 0 3 110 Me 0 vinyl 4 OMe 0 0 111 Me 0 vinyl 3 OMe 1 0 112 Me 0 vinyl 3 OMe 0 1 113 Me 0 vinyl 2 OMe 2 0 114 Me 0 vinyl 2 OMe 1 1 115 Me 0 vinyl 2 OMe 0 2 116 Me 0 vinyl 1 OMe 3 0 117 Me 0 vinyl 1 OMe 2 1 118 Me 0 vinyl 1 OMe 1 2 119 Me 0 vinyl 1 OMe 0 3 120 Me 0 vinyl 0 OMe 4 0 121 Me 0 vinyl 0 OMe 3 1 122 Me 0 vinyl 0 OMe 2 2 123 Me 0 vinyl 0 OMe 1 3 124 Me 0 vinyl 0 OMe 0 4

[0048] [chemical 13] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 125 Me 2 Allyl 2 OMe 0 0 126 Me 2 Allyl 1 OMe 1 0 127 Me 2 Allyl 1 OMe 0 1 128 Me 2 Allyl 0 OMe 2 0 129 Me 2 Allyl 0 OMe 1 1 130 Me 2 Allyl 0 OMe 0 2 131 Me 1 Allyl 3 OMe 0 0 132 Me 1 Allyl 2 OMe 1 0 133 Me 1 Allyl 2 OMe 0 1 134 Me 1 Allyl 1 OMe 2 0 135 Me 1 Allyl 1 OMe 1 1 136 Me 1 Allyl 1 OMe 0 2 137 Me 1 Allyl 0 OMe 3 0 138 Me 1 Allyl 0 OMe 2 1 139 Me 1 Allyl 0 OMe 1 2 140 Me 1 Allyl 0 OMe 0 3 141 Me 0 Allyl 4 OMe 0 0 142 Me 0 Allyl 3 OMe 1 0 143 Me 0 Allyl 3 OMe 0 1 144 Me 0 Allyl 2 OMe 2 0 145 Me 0 Allyl 2 OMe 1 1 146 Me 0 Allyl 2 OMe 0 2 147 Me 0 Allyl 1 OMe 3 0 148 Me 0 Allyl 1 OMe 2 1 149 Me 0 Allyl 1 OMe 1 2 150 Me 0 Allyl 1 OMe 0 3 151 Me 0 Allyl 0 OMe 4 0 152 Me 0 Allyl 0 OMe 3 1 153 Me 0 Allyl 0 OMe 2 2 154 Me 0 Allyl 0 OMe 1 3 155 Me 0 Allyl 0 OMe 0 4

[0049] [chemical 14] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 156 Me 2 Ethynyl 2 OMe 0 0 157 Me 2 Ethynyl 1 OMe 1 0 158 Me 2 Ethynyl 1 OMe 0 1 159 Me 2 Ethynyl 0 OMe 2 0 160 Me 2 Ethynyl 0 OMe 1 1 161 Me 2 Ethynyl 0 OMe 0 2 162 Me 1 Ethynyl 3 OMe 0 0 163 Me 1 Ethynyl 2 OMe 1 0 164 Me 1 Ethynyl 2 OMe 0 1 165 Me 1 Ethynyl 1 OMe 2 0 166 Me 1 Ethynyl 1 OMe 1 1 167 Me 1 Ethynyl 1 OMe 0 2 168 Me 1 Ethynyl 0 OMe 3 0 169 Me 1 Ethynyl 0 OMe 2 1 170 Me 1 Ethynyl 0 OMe 1 2 171 Me 1 Ethynyl 0 OMe 0 3 172 Me 0 Ethynyl 4 OMe 0 0 173 Me 0 Ethynyl 3 OMe 1 0 174 Me 0 Ethynyl 3 OMe 0 1 175 Me 0 Ethynyl 2 OMe 2 0 176 Me 0 Ethynyl 2 OMe 1 1 177 Me 0 Ethynyl 2 OMe 0 2 178 Me 0 Ethynyl 1 OMe 3 0 179 Me 0 Ethynyl 1 OMe 2 1 180 Me 0 Ethynyl 1 OMe 1 2 181 Me 0 Ethynyl 1 OMe 0 3 182 Me 0 Ethynyl 0 OMe 4 0 183 Me 0 Ethynyl 0 OMe 3 1 184 Me 0 Ethynyl 0 OMe 2 2 185 Me 0 Ethynyl 0 OMe 1 3 186 Me 0 Ethynyl 0 OMe 0 4

[0050] [chemical 15] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 187 Me 2 vinyl 2 OEt 0 0 188 Me 2 vinyl 1 OEt 1 0 189 Me 2 vinyl 1 OEt 0 1 190 Me 2 vinyl 0 OEt 2 0 191 Me 2 vinyl 0 OEt 1 1 192 Me 2 vinyl 0 OEt 0 2 193 Me 1 vinyl 3 OEt 0 0 194 Me 1 vinyl 2 OEt 1 0 195 Me 1 vinyl 2 OEt 0 1 196 Me 1 vinyl 1 OEt 2 0 197 Me 1 vinyl 1 OEt 1 1 198 Me 1 vinyl 1 OEt 0 2 199 Me 1 vinyl 0 OEt 3 0 200 Me 1 vinyl 0 OEt 2 1 201 Me 1 vinyl 0 OEt 1 2 202 Me 1 vinyl 0 OEt 0 3 203 Me 0 vinyl 4 OEt 0 0 204 Me 0 vinyl 3 OEt 1 0 205 Me 0 vinyl 3 OEt 0 1 206 Me 0 vinyl 2 OEt 2 0 207 Me 0 vinyl 2 OEt 1 1 208 Me 0 vinyl 2 OEt 0 2 209 Me 0 vinyl 1 OEt 3 0 210 Me 0 vinyl 1 OEt 2 1 211 Me 0 vinyl 1 OEt 1 2 212 Me 0 vinyl 1 OEt 0 3 213 Me 0 vinyl 0 OEt 4 0 214 Me 0 vinyl 0 OEt 3 1 215 Me 0 vinyl 0 OEt 2 2 216 Me 0 vinyl 0 OEt 1 3 217 Me 0 vinyl 0 OEt 0 4

[0051] [Chemical 16] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 218 Me 2 Allyl 2 OEt 0 0 219 Me 2 Allyl 1 OEt 1 0 220 Me 2 Allyl 1 OEt 0 1 221 Me 2 Allyl 0 OEt 2 0 222 Me 2 Allyl 0 OEt 1 1 223 Me 2 Allyl 0 OEt 0 2 224 Me 1 Allyl 3 OEt 0 0 225 Me 1 Allyl 2 OEt 1 0 226 Me 1 Allyl 2 OEt 0 1 227 Me 1 Allyl 1 OEt 2 0 228 Me 1 Allyl 1 OEt 1 1 229 Me 1 Allyl 1 OEt 0 2 230 Me 1 Allyl 0 OEt 3 0 231 Me 1 Allyl 0 OEt 2 1 232 Me 1 Allyl 0 OEt 1 2 233 Me 1 Allyl 0 OEt 0 3 234 Me 0 Allyl 4 OEt 0 0 235 Me 0 Allyl 3 OEt 1 0 236 Me 0 Allyl 3 OEt 0 1 237 Me 0 Allyl 2 OEt 2 0 238 Me 0 Allyl 2 OEt 1 1 239 Me 0 Allyl 2 OEt 0 2 240 Me 0 Allyl 1 OEt 3 0 241 Me 0 Allyl 1 OEt 2 1 242 Me 0 Allyl 1 OEt 1 2 243 Me 0 Allyl 1 OEt 0 3 244 Me 0 Allyl 0 OEt 4 0 245 Me 0 Allyl 0 OEt 3 1 246 Me 0 Allyl 0 OEt 2 2 247 Me 0 Allyl 0 OEt 1 3 248 Me 0 Allyl 0 OEt 0 4

[0052] [chemical 17] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 249 Me 2 Ethynyl 2 OEt 0 0 250 Me 2 Ethynyl 1 OEt 1 0 251 Me 2 Ethynyl 1 OEt 0 1 252 Me 2 Ethynyl 0 OEt 2 0 253 Me 2 Ethynyl 0 OEt 1 1 254 Me 2 Ethynyl 0 OEt 0 2 255 Me 1 Ethynyl 3 OEt 0 0 256 Me 1 Ethynyl 2 OEt 1 0 257 Me 1 Ethynyl 2 OEt 0 1 258 Me 1 Ethynyl 1 OEt 2 0 259 Me 1 Ethynyl 1 OEt 1 1 260 Me 1 Ethynyl 1 OEt 0 2 261 Me 1 Ethynyl 0 OEt 3 0 262 Me 1 Ethynyl 0 OEt 2 1 263 Me 1 Ethynyl 0 OEt 1 2 264 Me 1 Ethynyl 0 OEt 0 3 265 Me 0 Ethynyl 4 OEt 0 0 266 Me 0 Ethynyl 3 OEt 1 0 267 Me 0 Ethynyl 3 OEt 0 1 268 Me 0 Ethynyl 2 OEt 2 0 269 Me 0 Ethynyl 2 OEt 1 1 270 Me 0 Ethynyl 2 OEt 0 2 271 Me 0 Ethynyl 1 OEt 3 0 272 Me 0 Ethynyl 1 OEt 2 1 273 Me 0 Ethynyl 1 OEt 1 2 274 Me 0 Ethynyl 1 OEt 0 3 275 Me 0 Ethynyl 0 OEt 4 0 276 Me 0 Ethynyl 0 OEt 3 1 277 Me 0 Ethynyl 0 OEt 2 2 278 Me 0 Ethynyl 0 OEt 1 3 279 Me 0 Ethynyl 0 OEt 0 4

[0053] [chemical 18] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 280 Me 2 vinyl 2 o n PR 0 0 281 Me 2 vinyl 1 o n PR 1 0 282 Me 2 vinyl 1 o n PR 0 1 283 Me 2 vinyl 0 o n PR 2 0 284 Me 2 vinyl 0 o n PR 1 1 285 Me 2 vinyl 0 o n PR 0 2 286 Me 1 vinyl 3 o n PR 0 0 287 Me 1 vinyl 2 o n PR 1 0 288 Me 1 vinyl 2 o n PR 0 1 289 Me 1 vinyl 1 o n PR 2 0 290 Me 1 vinyl 1 o n PR 1 1 291 Me 1 vinyl 1 o n PR 0 2 292 Me 1 vinyl 0 o n PR 3 0 293 Me 1 vinyl 0 o n PR 2 1 294 Me 1 vinyl 0 o n PR 1 2 295 Me 1 vinyl 0 o n PR 0 3 296 Me 0 vinyl 4 o n PR 0 0 297 Me 0 vinyl 3 o n PR 1 0 298 Me 0 vinyl 3 o n PR 0 1 299 Me 0 vinyl 2 o n PR 2 0 300 Me 0 vinyl 2 o n PR 1 1 301 Me 0 vinyl 2 o n PR 0 2 302 Me 0 vinyl 1 o n PR 3 0 303 Me 0 vinyl 1 o n PR 2 1 304 Me 0 vinyl 1 o n PR 1 2 305 Me 0 vinyl 1 o n PR 0 3 306 Me 0 vinyl 0 o n PR 4 0 307 Me 0 vinyl 0 o n PR 3 1 308 Me 0 vinyl 0 o n PR 2 2 309 Me 0 vinyl 0 o n PR 1 3 310 Me 0 vinyl 0 o n PR 0 4

[0054] [chemical 19] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 311 Me 2 Allyl 2 o n PR 0 0 312 Me 2 Allyl 1 o n PR 1 0 313 Me 2 Allyl 1 o n PR 0 1 314 Me 2 Allyl 0 o n PR 2 0 315 Me 2 Allyl 0 o n PR 1 1 316 Me 2 Allyl 0 o n PR 0 2 317 Me 1 Allyl 3 o n PR 0 0 318 Me 1 Allyl 2 o n PR 1 0 319 Me 1 Allyl 2 o n PR 0 1 320 Me 1 Allyl 1 o n PR 2 0 321 Me 1 Allyl 1 o n PR 1 1 322 Me 1 Allyl 1 o n PR 0 2 323 Me 1 Allyl 0 o n PR 3 0 324 Me 1 Allyl 0 o n PR 2 1 325 Me 1 Allyl 0 o n PR 1 2 326 Me 1 Allyl 0 o n PR 0 3 327 Me 0 Allyl 4 o n PR 0 0 328 Me 0 Allyl 3 o n PR 1 0 329 Me 0 Allyl 3 o n PR 0 1 330 Me 0 Allyl 2 o n PR 2 0 331 Me 0 Allyl 2 o n PR 1 1 332 Me 0 Allyl 2 o n PR 0 2 333 Me 0 Allyl 1 o n PR 3 0 334 Me 0 Allyl 1 o n PR 2 1 335 Me 0 Allyl 1 o n PR 1 2 336 Me 0 Allyl 1 o n PR 0 3 337 Me 0 Allyl 0 o n PR 4 0 338 Me 0 Allyl 0 o n PR 3 1 339 Me 0 Allyl 0 o n PR 2 2 340 Me 0 Allyl 0 o n PR 1 3 341 Me 0 Allyl 0 o n PR 0 4

[0055] [Chem. 20] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 342 Me 2 Ethynyl 2 o n PR 0 0 343 Me 2 Ethynyl 1 o n PR 1 0 344 Me 2 Ethynyl 1 o n PR 0 1 345 Me 2 Ethynyl 0 o n PR 2 0 346 Me 2 Ethynyl 0 o n PR 1 1 347 Me 2 Ethynyl 0 o n PR 0 2 348 Me 1 Ethynyl 3 o n PR 0 0 349 Me 1 Ethynyl 2 o n PR 1 0 350 Me 1 Ethynyl 2 o n PR 0 1 351 Me 1 Ethynyl 1 o n PR 2 0 352 Me 1 Ethynyl 1 o n PR 1 1 353 Me 1 Ethynyl 1 o n PR 0 2 354 Me 1 Ethynyl 0 o n PR 3 0 355 Me 1 Ethynyl 0 o n PR 2 1 356 Me 1 Ethynyl 0 o n PR 1 2 357 Me 1 Ethynyl 0 o n PR 0 3 358 Me 0 Ethynyl 4 o n PR 0 0 359 Me 0 Ethynyl 3 o n PR 1 0 360 Me 0 Ethynyl 3 o n PR 0 1 361 Me 0 Ethynyl 2 o n PR 2 0 362 Me 0 Ethynyl 2 o n PR 1 1 363 Me 0 Ethynyl 2 o n PR 0 2 364 Me 0 Ethynyl 1 o n PR 3 0 365 Me 0 Ethynyl 1 o n PR 2 1 366 Me 0 Ethynyl 1 o n PR 1 2 367 Me 0 Ethynyl 1 o n PR 0 3 368 Me 0 Ethynyl 0 o n PR 4 0 369 Me 0 Ethynyl 0 o n PR 3 1 370 Me 0 Ethynyl 0 o n PR 2 2 371 Me 0 Ethynyl 0 o n PR 1 3 372 Me 0 Ethynyl 0 o n PR 0 4

[0056] [chemical 21] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 373 Me 2 vinyl 2 o i PR 0 0 374 Me 2 vinyl 1 o i PR 1 0 375 Me 2 vinyl 1 o i PR 0 1 376 Me 2 vinyl 0 o i PR 2 0 377 Me 2 vinyl 0 o i PR 1 1 378 Me 2 vinyl 0 o i PR 0 2 379 Me 1 vinyl 3 o i PR 0 0 380 Me 1 vinyl 2 o i PR 1 0 381 Me 1 vinyl 2 o i PR 0 1 382 Me 1 vinyl 1 o i PR 2 0 383 Me 1 vinyl 1 o i PR 1 1 384 Me 1 vinyl 1 o i PR 0 2 385 Me 1 vinyl 0 o i PR 3 0 386 Me 1 vinyl 0 o i PR 2 1 387 Me 1 vinyl 0 o i PR 1 2 388 Me 1 vinyl 0 o i PR 0 3 389 Me 0 vinyl 4 o i PR 0 0 390 Me 0 vinyl 3 o i PR 1 0 391 Me 0 vinyl 3 o i PR 0 1 392 Me 0 vinyl 2 o i PR 2 0 393 Me 0 vinyl 2 o i PR 1 1 394 Me 0 vinyl 2 o i PR 0 2 395 Me 0 vinyl 1 o i PR 3 0 396 Me 0 vinyl 1 o i PR 2 1 397 Me 0 vinyl 1 o i PR 1 2 398 Me 0 vinyl 1 o i PR 0 3 399 Me 0 vinyl 0 o i PR 4 0 400 Me 0 vinyl 0 o i PR 3 1 401 Me 0 vinyl 0 o i PR 2 2 402 Me 0 vinyl 0 o i PR 1 3 403 Me 0 vinyl 0 o i PR 0 4

[0057] [chemical 22] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 404 Me 2 Allyl 2 o i PR 0 0 405 Me 2 Allyl 1 o i PR 1 0 406 Me 2 Allyl 1 o i PR 0 1 407 Me 2 Allyl 0 o i PR 2 0 408 Me 2 Allyl 0 o i PR 1 1 409 Me 2 Allyl 0 o i PR 0 2 410 Me 1 Allyl 3 o i PR 0 0 411 Me 1 Allyl 2 o i PR 1 0 412 Me 1 Allyl 2 o i PR 0 1 413 Me 1 Allyl 1 o i PR 2 0 414 Me 1 Allyl 1 o i PR 1 1 415 Me 1 Allyl 1 o i PR 0 2 416 Me 1 Allyl 0 o i PR 3 0 417 Me 1 Allyl 0 o i PR 2 1 418 Me 1 Allyl 0 o i PR 1 2 419 Me 1 Allyl 0 o i PR 0 3 420 Me 0 Allyl 4 o i PR 0 0 421 Me 0 Allyl 3 o i PR 1 0 422 Me 0 Allyl 3 o i PR 0 1 423 Me 0 Allyl 2 o i PR 2 0 424 Me 0 Allyl 2 o i PR 1 1 425 Me 0 Allyl 2 o i PR 0 2 426 Me 0 Allyl 1 o i PR 3 0 427 Me 0 Allyl 1 o i PR 2 1 428 Me 0 Allyl 1 o i PR 1 2 429 Me 0 Allyl 1 o i PR 0 3 430 Me 0 Allyl 0 o i PR 4 0 431 Me 0 Allyl 0 o i PR 3 1 432 Me 0 Allyl 0 o i PR 2 2 433 Me 0 Allyl 0 o i PR 1 3 434 Me 0 Allyl 0 o i PR 0 4

[0058] [chemical 23] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 435 Me 2 Ethynyl 2 o i PR 0 0 436 Me 2 Ethynyl 1 o i PR 1 0 437 Me 2 Ethynyl 1 o i PR 0 1 438 Me 2 Ethynyl 0 o i PR 2 0 439 Me 2 Ethynyl 0 o i PR 1 1 440 Me 2 Ethynyl 0 o i PR 0 2 441 Me 1 Ethynyl 3 o i PR 0 0 442 Me 1 Ethynyl 2 o i PR 1 0 443 Me 1 Ethynyl 2 o i PR 0 1 444 Me 1 Ethynyl 1 o i PR 2 0 445 Me 1 Ethynyl 1 o i PR 1 1 446 Me 1 Ethynyl 1 o i PR 0 2 447 Me 1 Ethynyl 0 o i PR 3 0 448 Me 1 Ethynyl 0 o i PR 2 1 449 Me 1 Ethynyl 0 o i PR 1 2 450 Me 1 Ethynyl 0 o i PR 0 3 451 Me 0 Ethynyl 4 o i PR 0 0 452 Me 0 Ethynyl 3 o i PR 1 0 453 Me 0 Ethynyl 3 o i PR 0 1 454 Me 0 Ethynyl 2 o i PR 2 0 455 Me 0 Ethynyl 2 o i PR 1 1 456 Me 0 Ethynyl 2 o i PR 0 2 457 Me 0 Ethynyl 1 o i PR 3 0 458 Me 0 Ethynyl 1 o i PR 2 1 459 Me 0 Ethynyl 1 o i PR 1 2 460 Me 0 Ethynyl 1 o i PR 0 3 461 Me 0 Ethynyl 0 o i PR 4 0 462 Me 0 Ethynyl 0 o i PR 3 1 463 Me 0 Ethynyl 0 o i PR 2 2 464 Me 0 Ethynyl 0 o i PR 1 3 465 Me 0 Ethynyl 0 o i PR 0 4

[0059] [chemical 24] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 466 Me 2 vinyl 2 o n Bu 0 0 467 Me 2 vinyl 1 o n Bu 1 0 468 Me 2 vinyl 1 o n Bu 0 1 469 Me 2 vinyl 0 o n Bu 2 0 470 Me 2 vinyl 0 o n Bu 1 1 471 Me 2 vinyl 0 o n Bu 0 2 472 Me 1 vinyl 3 o n Bu 0 0 473 Me 1 vinyl 2 o n Bu 1 0 474 Me 1 vinyl 2 o n Bu 0 1 475 Me 1 vinyl 1 o n Bu 2 0 476 Me 1 vinyl 1 o n Bu 1 1 477 Me 1 vinyl 1 o n Bu 0 2 478 Me 1 vinyl 0 o n Bu 3 0 479 Me 1 vinyl 0 o n Bu 2 1 480 Me 1 vinyl 0 o n Bu 1 2 481 Me 1 vinyl 0 o n Bu 0 3 482 Me 0 vinyl 4 o n Bu 0 0 483 Me 0 vinyl 3 o n Bu 1 0 484 Me 0 vinyl 3 o n Bu 0 1 485 Me 0 vinyl 2 o n Bu 2 0 486 Me 0 vinyl 2 o n Bu 1 1 487 Me 0 vinyl 2 o n Bu 0 2 488 Me 0 vinyl 1 o n Bu 3 0 489 Me 0 vinyl 1 o n Bu 2 1 490 Me 0 vinyl 1 o n Bu 1 2 491 Me 0 vinyl 1 o n Bu 0 3 492 Me 0 vinyl 0 o n Bu 4 0 493 Me 0 vinyl 0 o n Bu 3 1 494 Me 0 vinyl 0 o n Bu 2 2 495 Me 0 vinyl 0 o n Bu 1 3 496 Me 0 vinyl 0 o n Bu 0 4

[0060] [chemical 25] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 497 Me 2 Allyl 2 o n Bu 0 0 498 Me 2 Allyl 1 o n Bu 1 0 499 Me 2 Allyl 1 o n Bu 0 1 500 Me 2 Allyl 0 o n Bu 2 0 501 Me 2 Allyl 0 o n Bu 1 1 502 Me 2 Allyl 0 o n Bu 0 2 503 Me 1 Allyl 3 o n Bu 0 0 504 Me 1 Allyl 2 o n Bu 1 0 505 Me 1 Allyl 2 o n Bu 0 1 506 Me 1 Allyl 1 o n Bu 2 0 507 Me 1 Allyl 1 o n Bu 1 1 508 Me 1 Allyl 1 o n Bu 0 2 509 Me 1 Allyl 0 o n Bu 3 0 510 Me 1 Allyl 0 o n Bu 2 1 511 Me 1 Allyl 0 o n Bu 1 2 512 Me 1 Allyl 0 o n Bu 0 3 513 Me 0 Allyl 4 o n Bu 0 0 514 Me 0 Allyl 3 o n Bu 1 0 515 Me 0 Allyl 3 o n Bu 0 1 516 Me 0 Allyl 2 o n Bu 2 0 517 Me 0 Allyl 2 o n Bu 1 1 518 Me 0 Allyl 2 o n Bu 0 2 519 Me 0 Allyl 1 o n Bu 3 0 520 Me 0 Allyl 1 o n Bu 2 1 521 Me 0 Allyl 1 o n Bu 1 2 522 Me 0 Allyl 1 o n Bu 0 3 523 Me 0 Allyl 0 o n Bu 4 0 524 Me 0 Allyl 0 o n Bu 3 1 525 Me 0 Allyl 0 o n Bu 2 2 526 Me 0 Allyl 0 o n Bu 1 3 527 Me 0 Allyl 0 o n Bu 0 4

[0061] [Chem. 26] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 528 Me 2 Ethynyl 2 o n Bu 0 0 529 Me 2 Ethynyl 1 o n Bu 1 0 530 Me 2 Ethynyl 1 o n Bu 0 1 531 Me 2 Ethynyl 0 o n Bu 2 0 532 Me 2 Ethynyl 0 o n Bu 1 1 533 Me 2 Ethynyl 0 o n Bu 0 2 534 Me 1 Ethynyl 3 o n Bu 0 0 535 Me 1 Ethynyl 2 o n Bu 1 0 536 Me 1 Ethynyl 2 o n Bu 0 1 537 Me 1 Ethynyl 1 o n Bu 2 0 538 Me 1 Ethynyl 1 o n Bu 1 1 539 Me 1 Ethynyl 1 o n Bu 0 2 540 Me 1 Ethynyl 0 o n Bu 3 0 541 Me 1 Ethynyl 0 o n Bu 2 1 542 Me 1 Ethynyl 0 o n Bu 1 2 543 Me 1 Ethynyl 0 o n Bu 0 3 544 Me 0 Ethynyl 4 o n Bu 0 0 545 Me 0 Ethynyl 3 o n Bu 1 0 546 Me 0 Ethynyl 3 o n Bu 0 1 547 Me 0 Ethynyl 2 o n Bu 2 0 548 Me 0 Ethynyl 2 o n Bu 1 1 549 Me 0 Ethynyl 2 o n Bu 0 2 550 Me 0 Ethynyl 1 o n Bu 3 0 551 Me 0 Ethynyl 1 o n Bu 2 1 552 Me 0 Ethynyl 1 o n Bu 1 2 553 Me 0 Ethynyl 1 o n Bu 0 3 554 Me 0 Ethynyl 0 o n Bu 4 0 555 Me 0 Ethynyl 0 o n Bu 3 1 556 Me 0 Ethynyl 0 o n Bu 2 2 557 Me 0 Ethynyl 0 o n Bu 1 3 558 Me 0 Ethynyl 0 o n Bu 0 4

[0062] [chemical 27] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 559 Me 2 vinyl 2 o i Bu 0 0 560 Me 2 vinyl 1 o i Bu 1 0 561 Me 2 vinyl 1 o i Bu 0 1 562 Me 2 vinyl 0 o i Bu 2 0 563 Me 2 vinyl 0 o i Bu 1 1 564 Me 2 vinyl 0 o i Bu 0 2 565 Me 1 vinyl 3 o i Bu 0 0 566 Me 1 vinyl 2 o i Bu 1 0 567 Me 1 vinyl 2 o i Bu 0 1 568 Me 1 vinyl 1 o i Bu 2 0 569 Me 1 vinyl 1 o i Bu 1 1 570 Me 1 vinyl 1 o i Bu 0 2 571 Me 1 vinyl 0 o i Bu 3 0 572 Me 1 vinyl 0 o i Bu 2 1 573 Me 1 vinyl 0 o i Bu 1 2 574 Me 1 vinyl 0 o i Bu 0 3 575 Me 0 vinyl 4 o i Bu 0 0 576 Me 0 vinyl 3 o i Bu 1 0 577 Me 0 vinyl 3 o i Bu 0 1 578 Me 0 vinyl 2 o i Bu 2 0 579 Me 0 vinyl 2 o i Bu 1 1 580 Me 0 vinyl 2 o i Bu 0 2 581 Me 0 vinyl 1 o i Bu 3 0 582 Me 0 vinyl 1 o i Bu 2 1 583 Me 0 vinyl 1 o i Bu 1 2 584 Me 0 vinyl 1 o i Bu 0 3 585 Me 0 vinyl 0 o i Bu 4 0 586 Me 0 vinyl 0 o i Bu 3 1 587 Me 0 vinyl 0 o i Bu 2 2 588 Me 0 vinyl 0 o i Bu 1 3 589 Me 0 vinyl 0 o i Bu 0 4

[0063] [Chemical 28] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 590 Me 2 Allyl 2 o i Bu 0 0 591 Me 2 Allyl 1 o i Bu 1 0 592 Me 2 Allyl 1 o i Bu 0 1 593 Me 2 Allyl 0 o i Bu 2 0 594 Me 2 Allyl 0 o i Bu 1 1 595 Me 2 Allyl 0 o i Bu 0 2 596 Me 1 Allyl 3 o i Bu 0 0 597 Me 1 Allyl 2 o i Bu 1 0 598 Me 1 Allyl 2 o i Bu 0 1 599 Me 1 Allyl 1 o i Bu 2 0 600 Me 1 Allyl 1 o i Bu 1 1 601 Me 1 Allyl 1 o i Bu 0 2 602 Me 1 Allyl 0 o i Bu 3 0 603 Me 1 Allyl 0 o i Bu 2 1 604 Me 1 Allyl 0 o i Bu 1 2 605 Me 1 Allyl 0 o i Bu 0 3 606 Me 0 Allyl 4 o i Bu 0 0 607 Me 0 Allyl 3 o i Bu 1 0 608 Me 0 Allyl 3 o i Bu 0 1 609 Me 0 Allyl 2 o i Bu 2 0 610 Me 0 Allyl 2 o i Bu 1 1 611 Me 0 Allyl 2 o i Bu 0 2 612 Me 0 Allyl 1 o i Bu 3 0 613 Me 0 Allyl 1 o i Bu 2 1 614 Me 0 Allyl 1 o i Bu 1 2 615 Me 0 Allyl 1 o i Bu 0 3 616 Me 0 Allyl 0 o i Bu 4 0 617 Me 0 Allyl 0 o i Bu 3 1 618 Me 0 Allyl 0 o i Bu 2 2 619 Me 0 Allyl 0 o i Bu 1 3 620 Me 0 Allyl 0 o i Bu 0 4

[0064] [chemical 29] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 621 Me 2 Ethynyl 2 o i Bu 0 0 622 Me 2 Ethynyl 1 o i Bu 1 0 623 Me 2 Ethynyl 1 o i Bu 0 1 624 Me 2 Ethynyl 0 o i Bu 2 0 625 Me 2 Ethynyl 0 o i Bu 1 1 626 Me 2 Ethynyl 0 o i Bu 0 2 627 Me 1 Ethynyl 3 o i Bu 0 0 628 Me 1 Ethynyl 2 o i Bu 1 0 629 Me 1 Ethynyl 2 o i Bu 0 1 630 Me 1 Ethynyl 1 o i Bu 2 0 631 Me 1 Ethynyl 1 o i Bu 1 1 632 Me 1 Ethynyl 1 o i Bu 0 2 633 Me 1 Ethynyl 0 o i Bu 3 0 634 Me 1 Ethynyl 0 o i Bu 2 1 635 Me 1 Ethynyl 0 o i Bu 1 2 636 Me 1 Ethynyl 0 o i Bu 0 3 637 Me 0 Ethynyl 4 o i Bu 0 0 638 Me 0 Ethynyl 3 o i Bu 1 0 639 Me 0 Ethynyl 3 o i Bu 0 1 640 Me 0 Ethynyl 2 o i Bu 2 0 641 Me 0 Ethynyl 2 o i Bu 1 1 642 Me 0 Ethynyl 2 o i Bu 0 2 643 Me 0 Ethynyl 1 o i Bu 3 0 644 Me 0 Ethynyl 1 o i Bu 2 1 645 Me 0 Ethynyl 1 o i Bu 1 2 646 Me 0 Ethynyl 1 o i Bu 0 3 647 Me 0 Ethynyl 0 o i Bu 4 0 648 Me 0 Ethynyl 0 o i Bu 3 1 649 Me 0 Ethynyl 0 o i Bu 2 2 650 Me 0 Ethynyl 0 o i Bu 1 3 651 Me 0 Ethynyl 0 o i Bu 0 4

[0065] [Chemical 30] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 652 Me 2 vinyl 2 o sec Bu 0 0 653 Me 2 vinyl 1 o sec Bu 1 0 654 Me 2 vinyl 1 o sec Bu 0 1 655 Me 2 vinyl 0 o sec Bu 2 0 656 Me 2 vinyl 0 o sec Bu 1 1 657 Me 2 vinyl 0 o sec Bu 0 2 658 Me 1 vinyl 3 o sec Bu 0 0 659 Me 1 vinyl 2 o sec Bu 1 0 660 Me 1 vinyl 2 o sec Bu 0 1 661 Me 1 vinyl 1 o sec Bu 2 0 662 Me 1 vinyl 1 o sec Bu 1 1 663 Me 1 vinyl 1 o sec Bu 0 2 664 Me 1 vinyl 0 o sec Bu 3 0 665 Me 1 vinyl 0 o sec Bu 2 1 666 Me 1 vinyl 0 o sec Bu 1 2 667 Me 1 vinyl 0 o sec Bu 0 3 668 Me 0 vinyl 4 o sec Bu 0 0 669 Me 0 vinyl 3 o sec Bu 1 0 670 Me 0 vinyl 3 o sec Bu 0 1 671 Me 0 vinyl 2 o sec Bu 2 0 672 Me 0 vinyl 2 o sec Bu 1 1 673 Me 0 vinyl 2 o sec Bu 0 2 674 Me 0 vinyl 1 o sec Bu 3 0 675 Me 0 vinyl 1 o sec Bu 2 1 676 Me 0 vinyl 1 o sec Bu 1 2 677 Me 0 vinyl 1 o sec Bu 0 3 678 Me 0 vinyl 0 o sec Bu 4 0 679 Me 0 vinyl 0 o sec Bu 3 1 680 Me 0 vinyl 0 o sec Bu 2 2 681 Me 0 vinyl 0 o sec Bu 1 3 682 Me 0 vinyl 0 o sec Bu 0 4

[0066] [Chemical 31] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 683 Me 2 Allyl 2 o sec Bu 0 0 684 Me 2 Allyl 1 o sec Bu 1 0 685 Me 2 Allyl 1 o sec Bu 0 1 686 Me 2 Allyl 0 o sec Bu 2 0 687 Me 2 Allyl 0 o sec Bu 1 1 688 Me 2 Allyl 0 o sec Bu 0 2 689 Me 1 Allyl 3 o sec Bu 0 0 690 Me 1 Allyl 2 o sec Bu 1 0 691 Me 1 Allyl 2 o sec Bu 0 1 692 Me 1 Allyl 1 o sec Bu 2 0 693 Me 1 Allyl 1 o sec Bu 1 1 694 Me 1 Allyl 1 o sec Bu 0 2 695 Me 1 Allyl 0 o sec Bu 3 0 696 Me 1 Allyl 0 o sec Bu 2 1 697 Me 1 Allyl 0 o sec Bu 1 2 698 Me 1 Allyl 0 o sec Bu 0 3 699 Me 0 Allyl 4 o sec Bu 0 0 700 Me 0 Allyl 3 o sec Bu 1 0 701 Me 0 Allyl 3 o sec Bu 0 1 702 Me 0 Allyl 2 o sec Bu 2 0 703 Me 0 Allyl 2 o sec Bu 1 1 704 Me 0 Allyl 2 o sec Bu 0 2 705 Me 0 Allyl 1 o sec Bu 3 0 706 Me 0 Allyl 1 o sec Bu 2 1 707 Me 0 Allyl 1 o sec Bu 1 2 708 Me 0 Allyl 1 o sec Bu 0 3 709 Me 0 Allyl 0 o sec Bu 4 0 710 Me 0 Allyl 0 o sec Bu 3 1 711 Me 0 Allyl 0 o sec Bu 2 2 712 Me 0 Allyl 0 o sec Bu 1 3 713 Me 0 Allyl 0 o sec Bu 0 4

[0067] [Chemical 32] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 714 Me 2 Ethynyl 2 o sec Bu 0 0 715 Me 2 Ethynyl 1 o sec Bu 1 0 716 Me 2 Ethynyl 1 o sec Bu 0 1 717 Me 2 Ethynyl 0 o sec Bu 2 0 718 Me 2 Ethynyl 0 o sec Bu 1 1 719 Me 2 Ethynyl 0 o sec Bu 0 2 720 Me 1 Ethynyl 3 o sec Bu 0 0 721 Me 1 Ethynyl 2 o sec Bu 1 0 722 Me 1 Ethynyl 2 o sec Bu 0 1 723 Me 1 Ethynyl 1 o sec Bu 2 0 724 Me 1 Ethynyl 1 o sec Bu 1 1 725 Me 1 Ethynyl 1 o sec Bu 0 2 726 Me 1 Ethynyl 0 o sec Bu 3 0 727 Me 1 Ethynyl 0 o sec Bu 2 1 728 Me 1 Ethynyl 0 o sec Bu 1 2 729 Me 1 Ethynyl 0 o sec Bu 0 3 730 Me 0 Ethynyl 4 o sec Bu 0 0 731 Me 0 Ethynyl 3 o sec Bu 1 0 732 Me 0 Ethynyl 3 o sec Bu 0 1 733 Me 0 Ethynyl 2 o sec Bu 2 0 734 Me 0 Ethynyl 2 o sec Bu 1 1 735 Me 0 Ethynyl 2 o sec Bu 0 2 736 Me 0 Ethynyl 1 o sec Bu 3 0 737 Me 0 Ethynyl 1 o sec Bu 2 1 738 Me 0 Ethynyl 1 o sec Bu 1 2 739 Me 0 Ethynyl 1 o sec Bu 0 3 740 Me 0 Ethynyl 0 o sec Bu 4 0 741 Me 0 Ethynyl 0 o sec Bu 3 1 742 Me 0 Ethynyl 0 o sec Bu 2 2 743 Me 0 Ethynyl 0 o sec Bu 1 3 744 Me 0 Ethynyl 0 o sec Bu 0 4

[0068] [Chemical 33] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 745 Me 2 vinyl 2 o t Bu 0 0 746 Me 2 vinyl 1 o t Bu 1 0 747 Me 2 vinyl 1 o t Bu 0 1 748 Me 2 vinyl 0 o t Bu 2 0 749 Me 2 vinyl 0 o t Bu 1 1 750 Me 2 vinyl 0 ot Bu 0 2 751 Me 1 vinyl 3 o t Bu 0 0 752 Me 1 vinyl 2 o t Bu 1 0 753 Me 1 vinyl 2 o t Bu 0 1 754 Me 1 vinyl 1 o t Bu 2 0 755 Me 1 vinyl 1 o t Bu 1 1 756 Me 1 vinyl 1 o t Bu 0 2 757 Me 1 vinyl 0 o t Bu 3 0 758 Me 1 vinyl 0 o t Bu 2 1 759 Me 1 vinyl 0 o t Bu 1 2 760 Me 1 vinyl 0 o t Bu 0 3 761 Me 0 vinyl 4 o t Bu 0 0 762 Me 0 vinyl 3 o t Bu 1 0 763 Me 0 vinyl 3 o t Bu 0 1 764 Me 0 vinyl 2 o t Bu 2 0 765 Me 0 vinyl 2 o t Bu 1 1 766 Me 0 vinyl 2 o t Bu 0 2 767 Me 0 vinyl 1 o t Bu 3 0 768 Me 0 vinyl 1 o t Bu 2 1 769 Me 0 vinyl 1 o t Bu 1 2 770 Me 0 vinyl 1 o t Bu 0 3 771 Me 0 vinyl 0 o t Bu 4 0 772 Me 0 vinyl 0 o t Bu 3 1 773 Me 0 vinyl 0 o t Bu 2 2 774 Me 0 vinyl 0 o t Bu 1 3 775 Me 0 vinyl 0 o t Bu 0 4

[0069] [Chemical 34] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 776 Me 2 Allyl 2 o t Bu 0 0 777 Me 2 Allyl 1 o t Bu 1 0 778 Me 2 Allyl 1 o t Bu 0 1 779 Me 2 Allyl 0 o t Bu 2 0 780 Me 2 Allyl 0 o t Bu 1 1 781 Me 2 Allyl 0 o t Bu 0 2 782 Me 1 Allyl 3 o t Bu 0 0 783 Me 1 Allyl 2 o t Bu 1 0 784 Me 1 Allyl 2 o t Bu 0 1 785 Me 1 Allyl 1 o t Bu 2 0 786 Me 1 Allyl 1 o t Bu 1 1 787 Me 1 Allyl 1 o t Bu 0 2 788 Me 1 Allyl 0 o t Bu 3 0 789 Me 1 Allyl 0 o t Bu 2 1 790 Me 1 Allyl 0 o t Bu 1 2 791 Me 1 Allyl 0 o t Bu 0 3 792 Me 0 Allyl 4 o t Bu 0 0 793 Me 0 Allyl 3 o t Bu 1 0 794 Me 0 Allyl 3 o t Bu 0 1 795 Me 0 Allyl 2 o t Bu 2 0 796 Me 0 Allyl 2 o t Bu 1 1 797 Me 0 Allyl 2 o t Bu 0 2 798 Me 0 Allyl 1 o t Bu 3 0 799 Me 0 Allyl 1 o t Bu 2 1 800 Me 0 Allyl 1 o t Bu 1 2 801 Me 0 Allyl 1 o t Bu 0 3 802 Me 0 Allyl 0 o t Bu 4 0 803 Me 0 Allyl 0 o t Bu 3 1 804 Me 0 Allyl 0 o t Bu 2 2 805 Me 0 Allyl 0 o t Bu 1 3 806 Me 0 Allyl 0 o t Bu 0 4

[0070] [Chemical 35] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 807 Me 2 Ethynyl 2 o t Bu 0 0 808 Me 2 Ethynyl 1 o t Bu 1 0 809 Me 2 Ethynyl 1 o t Bu 0 1 810 Me 2 Ethynyl 0 o t Bu 2 0 811 Me 2 Ethynyl 0 o t Bu 1 1 812 Me 2 Ethynyl 0 o t Bu 0 2 813 Me 1 Ethynyl 3 o t Bu 0 0 814 Me 1 Ethynyl 2 o t Bu 1 0 815 Me 1 Ethynyl 2 o t Bu 0 1 816 Me 1 Ethynyl 1 o t Bu 2 0 817 Me 1 Ethynyl 1 o t Bu 1 1 818 Me 1 Ethynyl 1 o t Bu 0 2 819 Me 1 Ethynyl 0 o t Bu 3 0 820 Me 1 Ethynyl 0 o t Bu 2 1 821 Me 1 Ethynyl 0 o t Bu 1 2 822 Me 1 Ethynyl 0 o t Bu 0 3 823 Me 0 Ethynyl 4 o t Bu 0 0 824 Me 0 Ethynyl 3 o t Bu 1 0 825 Me 0 Ethynyl 3 o t Bu 0 1 826 Me 0 Ethynyl 2 o t Bu 2 0 827 Me 0 Ethynyl 2 o t Bu 1 1 828 Me 0 Ethynyl 2 o t Bu 0 2 829 Me 0 Ethynyl 1 o t Bu 3 0 830 Me 0 Ethynyl 1 o t Bu 2 1 831 Me 0 Ethynyl 1 o t Bu 1 2 832 Me 0 Ethynyl 1 o t Bu 0 3 833 Me 0 Ethynyl 0 o t Bu 4 0 834 Me 0 Ethynyl 0 o t Bu 3 1 835 Me 0 Ethynyl 0 o t Bu 2 2 836 Me 0 Ethynyl 0 o t Bu 1 3 837 Me 0 Ethynyl 0 o t Bu 0 4

[0071] [Chemical 36] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 838 Et 2 vinyl 2 Oh 0 0 839 Et 2 vinyl 1 Oh 1 0 840 Et 2 vinyl 1 Oh 0 1 841 Et 2 vinyl 0 Oh 2 0 842 Et 2 vinyl 0 Oh 1 1 843 Et 2 vinyl 0 Oh 0 2 844 Et 1 vinyl 3 Oh 0 0 845 Et 1 vinyl 2 Oh 1 0 846 Et 1 vinyl 2 Oh 0 1 847 Et 1 vinyl 1 Oh 2 0 848 Et 1 vinyl 1 Oh 1 1 849 Et 1 vinyl 1 Oh 0 2 850 Et 1 vinyl 0 Oh 3 0 851 Et 1 vinyl 0 Oh 2 1 852 Et 1 vinyl 0 Oh 1 2 853 Et 1 vinyl 0 Oh 0 3 854 Et 0 vinyl 4 Oh 0 0 855 Et 0 vinyl 3 Oh 1 0 856 Et 0 vinyl 3 Oh 0 1 857 Et 0 vinyl 2 Oh 2 0 858 Et 0 vinyl 2 Oh 1 1 859 Et 0 vinyl 2 Oh 0 2 860 Et 0 vinyl 1 Oh 3 0 861 Et 0 vinyl 1 Oh 2 1 862 Et 0 vinyl 1 Oh 1 2 863 Et 0 vinyl 1 Oh 0 3 864 Et 0 vinyl 0 Oh 4 0 865 Et 0 vinyl 0 Oh 3 1 866 Et 0 vinyl 0 Oh 2 2 867 Et 0 vinyl 0 Oh 1 3 868 Et 0 vinyl 0 Oh 0 4

[0072] [Chemical 37] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 869 Et 2 Allyl 2 Oh 0 0 870 Et 2 Allyl 1 Oh 1 0 871 Et 2 Allyl 1 Oh 0 1 872 Et 2 Allyl 0 Oh 2 0 873 Et 2 Allyl 0 Oh 1 1 874 Et 2 Allyl 0 Oh 0 2 875 Et 1 Allyl 3 Oh 0 0 876 Et 1 Allyl 2 Oh 1 0 877 Et 1 Allyl 2 Oh 0 1 878 Et 1 Allyl 1 Oh 2 0 879 Et 1 Allyl 1 Oh 1 1 880 Et 1 Allyl 1 Oh 0 2 881 Et 1 Allyl 0 Oh 3 0 882 Et 1 Allyl 0 Oh 2 1 883 Et 1 Allyl 0 Oh 1 2 884 Et 1 Allyl 0 Oh 0 3 885 Et 0 Allyl 4 Oh 0 0 886 Et 0 Allyl 3 Oh 1 0 887 Et 0 Allyl 3 Oh 0 1 888 Et 0 Allyl 2 Oh 2 0 889 Et 0 Allyl 2 Oh 1 1 890 Et 0 Allyl 2 Oh 0 2 891 Et 0 Allyl 1 Oh 3 0 892 Et 0 Allyl 1 Oh 2 1 893 Et 0 Allyl 1 Oh 1 2 894 Et 0 Allyl 1 Oh 0 3 895 Et 0 Allyl 0 Oh 4 0 896 Et 0 Allyl 0 Oh 3 1 897 Et 0 Allyl 0 Oh 2 2 898 Et 0 Allyl 0 Oh 1 3 899 Et 0 Allyl 0 Oh 0 4

[0073] [Chemical 38] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 900 Et 2 Ethynyl 2 Oh 0 0 901 Et 2 Ethynyl 1 Oh 1 0 902 Et 2 Ethynyl 1 Oh 0 1 903 Et 2 Ethynyl 0 Oh 2 0 904 Et 2 Ethynyl 0 Oh 1 1 905 Et 2 Ethynyl 0 Oh 0 2 906 Et 1 Ethynyl 3 Oh 0 0 907 Et 1 Ethynyl 2 Oh 1 0 908 Et 1 Ethynyl 2 Oh 0 1 909 Et 1 Ethynyl 1 Oh 2 0 910 Et 1 Ethynyl 1 Oh 1 1 911 Et 1 Ethynyl 1 Oh 0 2 912 Et 1 Ethynyl 0 Oh 3 0 913 Et 1 Ethynyl 0 Oh 2 1 914 Et 1 Ethynyl 0 Oh 1 2 915 Et 1 Ethynyl 0 Oh 0 3 916 Et 0 Ethynyl 4 Oh 0 0 917 Et 0 Ethynyl 3 Oh 1 0 918 Et 0 Ethynyl 3 Oh 0 1 919 Et 0 Ethynyl 2 Oh 2 0 920 Et 0 Ethynyl 2 Oh 1 1 921 Et 0 Ethynyl 2 Oh 0 2 922 Et 0 Ethynyl 1 Oh 3 0 923 Et 0 Ethynyl 1 Oh 2 1 924 Et 0 Ethynyl 1 Oh 1 2 925 Et 0 Ethynyl 1 Oh 0 3 926 Et 0 Ethynyl 0 Oh 4 0 927 Et 0 Ethynyl 0 Oh 3 1 928 Et 0 Ethynyl 0 Oh 2 2 929 Et 0 Ethynyl 0 Oh 1 3 930 Et 0 Ethynyl 0 Oh 0 4

[0074] [Chemical 39] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 931 Et 2 vinyl 2 OMe 0 0 932 Et 2 vinyl 1 OMe 1 0 933 Et 2 vinyl 1 OMe 0 1 934 Et 2 vinyl 0 OMe 2 0 935 Et 2 vinyl 0 OMe 1 1 936 Et 2 vinyl 0 OMe 0 2 937 Et 1 vinyl 3 OMe 0 0 938 Et 1 vinyl 2 OMe 1 0 939 Et 1 vinyl 2 OMe 0 1 940 Et 1 vinyl 1 OMe 2 0 941 Et 1 vinyl 1 OMe 1 1 942 Et 1 vinyl 1 OMe 0 2 943 Et 1 vinyl 0 OMe 3 0 944 Et 1 vinyl 0 OMe 2 1 945 Et 1 vinyl 0 OMe 1 2 946 Et 1 vinyl 0 OMe 0 3 947 Et 0 vinyl 4 OMe 0 0 948 Et 0 vinyl 3 OMe 1 0 949 Et 0 vinyl 3 OMe 0 1 950 Et 0 vinyl 2 OMe 2 0 951 Et 0 vinyl 2 OMe 1 1 952 Et 0 vinyl 2 OMe 0 2 953 Et 0 vinyl 1 OMe 3 0 954 Et 0 vinyl 1 OMe 2 1 955 Et 0 vinyl 1 OMe 1 2 956 Et 0 vinyl 1 OMe 0 3 957 Et 0 vinyl 0 OMe 4 0 958 Et 0 vinyl 0 OMe 3 1 959 Et 0 vinyl 0 OMe 2 2 960 Et 0 vinyl 0 OMe 1 3 961 Et 0 vinyl 0 OMe 0 4

[0075] [C40] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 962 Et 2 Allyl 2 OMe 0 0 963 Et 2 Allyl 1 OMe 1 0 964 Et 2 Allyl 1 OMe 0 1 965 Et 2 Allyl 0 OMe 2 0 966 Et 2 Allyl 0 OMe 1 1 967 Et 2 Allyl 0 OMe 0 2 968 Et 1 Allyl 3 OMe 0 0 969 Et 1 Allyl 2 OMe 1 0 970 Et 1 Allyl 2 OMe 0 1 971 Et 1 Allyl 1 OMe 2 0 972 Et 1 Allyl 1 OMe 1 1 973 Et 1 Allyl 1 OMe 0 2 974 Et 1 Allyl 0 OMe 3 0 975 Et 1 Allyl 0 OMe 2 1 976 Et 1 Allyl 0 OMe 1 2 977 Et 1 Allyl 0 OMe 0 3 978 Et 0 Allyl 4 OMe 0 0 979 Et 0 Allyl 3 OMe 1 0 980 Et 0 Allyl 3 OMe 0 1 981 Et 0 Allyl 2 OMe 2 0 982 Et 0 Allyl 2 OMe 1 1 983 Et 0 Allyl 2 OMe 0 2 984 Et 0 Allyl 1 OMe 3 0 985 Et 0 Allyl 1 OMe 2 1 986 Et 0 Allyl 1 OMe 1 2 987 Et 0 Allyl 1 OMe 0 3 988 Et 0 Allyl 0 OMe 4 0 989 Et 0 Allyl 0 OMe 3 1 990 Et 0 Allyl 0 OMe 2 2 991 Et 0 Allyl 0 OMe 1 3 992 Et 0 Allyl 0 OMe 0 4

[0076]

[41] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 993 Et 2 Ethynyl 2 OMe 0 0 994 Et 2 Ethynyl 1 OMe 1 0 995 Et 2 Ethynyl 1 OMe 0 1 996 Et 2 Ethynyl 0 OMe 2 0 997 Et 2 Ethynyl 0 OMe 1 1 998 Et 2 Ethynyl 0 OMe 0 2 999 Et 1 Ethynyl 3 OMe 0 0 1000 Et 1 Ethynyl 2 OMe 1 0 1001 Et 1 Ethynyl 2 OMe 0 1 1002 Et 1 Ethynyl 1 OMe 2 0 1003 Et 1 Ethynyl 1 OMe 1 1 1004 Et 1 Ethynyl 1 OMe 0 2 1005 Et 1 Ethynyl 0 OMe 3 0 1006 Et 1 Ethynyl 0 OMe 2 1 1007 Et 1 Ethynyl 0 OMe 1 2 1008 Et 1 Ethynyl 0 OMe 0 3 1009 Et 0 Ethynyl 4 OMe 0 0 1010 Et 0 Ethynyl 3 OMe 1 0 1011 Et 0 Ethynyl 3 OMe 0 1 1012 Et 0 Ethynyl 2 OMe 2 0 1013 Et 0 Ethynyl 2 OMe 1 1 1014 Et 0 Ethynyl 2 OMe 0 2 1015 Et 0 Ethynyl 1 OMe 3 0 1016 Et 0 Ethynyl 1 OMe 2 1 1017 Et 0 Ethynyl 1 OMe 1 2 1018 Et 0 Ethynyl 1 OMe 0 3 1019 Et 0 Ethynyl 0 OMe 4 0 1020 Et 0 Ethynyl 0 OMe 3 1 1021 Et 0 Ethynyl 0 OMe 2 2 1022 Et 0 Ethynyl 0 OMe 1 3 1023 Et 0 Ethynyl 0 OMe 0 4

[0077]

[42] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1024 Et 2 vinyl 2 OEt 0 0 1025 Et 2 vinyl 1 OEt 1 0 1026 Et 2 vinyl 1 OEt 0 1 1027 Et 2 vinyl 0 OEt 2 0 1028 Et 2 vinyl 0 OEt 1 1 1029 Et 2 vinyl 0 OEt 0 2 1030 Et 1 vinyl 3 OEt 0 0 1031 Et 1 vinyl 2 OEt 1 0 1032 Et 1 vinyl 2 OEt 0 1 1033 Et 1 vinyl 1 OEt 2 0 1034 Et 1 vinyl 1 OEt 1 1 1035 Et 1 vinyl 1 OEt 0 2 1036 Et 1 vinyl 0 OEt 3 0 1037 Et 1 vinyl 0 OEt 2 1 1038 Et 1 vinyl 0 OEt 1 2 1039 Et 1 vinyl 0 OEt 0 3 1040 Et 0 vinyl 4 OEt 0 0 1041 Et 0 vinyl 3 OEt 1 0 1042 Et 0 vinyl 3 OEt 0 1 1043 Et 0 vinyl 2 OEt 2 0 1044 Et 0 vinyl 2 OEt 1 1 1045 Et 0 vinyl 2 OEt 0 2 1046 Et 0 vinyl 1 OEt 3 0 1047 Et 0 vinyl 1 OEt 2 1 1048 Et 0 vinyl 1 OEt 1 2 1049 Et 0 vinyl 1 OEt 0 3 1050 Et 0 vinyl 0 OEt 4 0 1051 Et 0 vinyl 0 OEt 3 1 1052 Et 0 vinyl 0 OEt 2 2 1053 Et 0 vinyl 0 OEt 1 3 1054 Et 0 vinyl 0 OEt 0 4

[0078]

[43] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1055 Et 2 Allyl 2 OEt 0 0 1056 Et 2 Allyl 1 OEt 1 0 1057 Et 2 Allyl 1 OEt 0 1 1058 Et 2 Allyl 0 OEt 2 0 1059 Et 2 Allyl 0 OEt 1 1 1060 Et 2 Allyl 0 OEt 0 2 1061 Et 1 Allyl 3 OEt 0 0 1062 Et 1 Allyl 2 OEt 1 0 1063 Et 1 Allyl 2 OEt 0 1 1064 Et 1 Allyl 1 OEt 2 0 1065 Et 1 Allyl 1 OEt 1 1 1066 Et 1 Allyl 1 OEt 0 2 1067 Et 1 Allyl 0 OEt 3 0 1068 Et 1 Allyl 0 OEt 2 1 1069 Et 1 Allyl 0 OEt 1 2 1070 Et 1 Allyl 0 OEt 0 3 1071 Et 0 Allyl 4 OEt 0 0 1072 Et 0 Allyl 3 OEt 1 0 1073 Et 0 Allyl 3 OEt 0 1 1074 Et 0 Allyl 2 OEt 2 0 1075 Et 0 Allyl 2 OEt 1 1 1076 Et 0 Allyl 2 OEt 0 2 1077 Et 0 Allyl 1 OEt 3 0 1078 Et 0 Allyl 1 OEt 2 1 1079 Et 0 Allyl 1 OEt 1 2 1080 Et 0 Allyl 1 OEt 0 3 1081 Et 0 Allyl 0 OEt 4 0 1082 Et 0 Allyl 0 OEt 3 1 1083 Et 0 Allyl 0 OEt 2 2 1084 Et 0 Allyl 0 OEt 1 3 1085 Et 0 Allyl 0 OEt 0 4

[0079]

[44] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1086 Et 2 Ethynyl 2 OEt 0 0 1087 Et 2 Ethynyl 1 OEt 1 0 1088 Et 2 Ethynyl 1 OEt 0 1 1089 Et 2 Ethynyl 0 OEt 2 0 1090 Et 2 Ethynyl 0 OEt 1 1 1091 Et 2 Ethynyl 0 OEt 0 2 1092 Et 1 Ethynyl 3 OEt 0 0 1093 Et 1 Ethynyl 2 OEt 1 0 1094 Et 1 Ethynyl 2 OEt 0 1 1095 Et 1 Ethynyl 1 OEt 2 0 1096 Et 1 Ethynyl 1 OEt 1 1 1097 Et 1 Ethynyl 1 OEt 0 2 1098 Et 1 Ethynyl 0 OEt 3 0 1099 Et 1 Ethynyl 0 OEt 2 1 1100 Et 1 Ethynyl 0 OEt 1 2 1101 Et 1 Ethynyl 0 OEt 0 3 1102 Et 0 Ethynyl 4 OEt 0 0 1103 Et 0 Ethynyl 3 OEt 1 0 1104 Et 0 Ethynyl 3 OEt 0 1 1105 Et 0 Ethynyl 2 OEt 2 0 1106 Et 0 Ethynyl 2 OEt 1 1 1107 Et 0 Ethynyl 2 OEt 0 2 1108 Et 0 Ethynyl 1 OEt 3 0 1109 Et 0 Ethynyl 1 OEt 2 1 1110 Et 0 Ethynyl 1 OEt 1 2 1111 Et 0 Ethynyl 1 OEt 0 3 1112 Et 0 Ethynyl 0 OEt 4 0 1113 Et 0 Ethynyl 0 OEt 3 1 1114 Et 0 Ethynyl 0 OEt 2 2 1115 Et 0 Ethynyl 0 OEt 1 3 1116 Et 0 Ethynyl 0 OEt 0 4

[0080]

[45] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1117 Et 2 vinyl 2 o n PR 0 0 1118 Et 2 vinyl 1 o n PR 1 0 1119 Et 2 vinyl 1 o n PR 0 1 1120 Et 2 vinyl 0 o n PR 2 0 1121 Et 2 vinyl 0 o n PR 1 1 1122 Et 2 vinyl 0 o n PR 0 2 1123 Et 1 vinyl 3 o n PR 0 0 1124 Et 1 vinyl 2 o n PR 1 0 1125 Et 1 vinyl 2 o n PR 0 1 1126 Et 1 vinyl 1 o n PR 2 0 1127 Et 1 vinyl 1 o n PR 1 1 1128 Et 1 vinyl 1 o n PR 0 2 1129 Et 1 vinyl 0 o n PR 3 0 1130 Et 1 vinyl 0 o n PR 2 1 1131 Et 1 vinyl 0 o n PR 1 2 1132 Et 1 vinyl 0 o n PR 0 3 1133 Et 0 vinyl 4 o n PR 0 0 1134 Et 0 vinyl 3 o n PR 1 0 1135 Et 0 vinyl 3 o n PR 0 1 1136 Et 0 vinyl 2 o n PR 2 0 1137 Et 0 vinyl 2 o n PR 1 1 1138 Et 0 vinyl 2 o n PR 0 2 1139 Et 0 vinyl 1 o n PR 3 0 1140 Et 0 vinyl 1 o n PR 2 1 1141 Et 0 vinyl 1 o n PR 1 2 1142 Et 0 vinyl 1 o n PR 0 3 1143 Et 0 vinyl 0 o n PR 4 0 1144 Et 0 vinyl 0 o n PR 3 1 1145 Et 0 vinyl 0 o n PR 2 2 1146 Et 0 vinyl 0 o n PR 1 3 1147 Et 0 vinyl 0 o n PR 0 4

[0081]

[46] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1148 Et 2 Allyl 2 o n PR 0 0 1149 Et 2 Allyl 1 o n PR 1 0 1150 Et 2 Allyl 1 o n PR 0 1 1151 Et 2 Allyl 0 o n PR 2 0 1152 Et 2 Allyl 0 o n PR 1 1 1153 Et 2 Allyl 0 o n PR 0 2 1154 Et 1 Allyl 3 o n PR 0 0 1155 Et 1 Allyl 2 o n PR 1 0 1156 Et 1 Allyl 2 o n PR 0 1 1157 Et 1 Allyl 1 o n PR 2 0 1158 Et 1 Allyl 1 o n PR 1 1 1159 Et 1 Allyl 1 o n PR 0 2 1160 Et 1 Allyl 0 o n PR 3 0 1161 Et 1 Allyl 0 o n PR 2 1 1162 Et 1 Allyl 0 o n PR 1 2 1163 Et 1 Allyl 0 o n PR 0 3 1164 Et 0 Allyl 4 o n PR 0 0 1165 Et 0 Allyl 3 o n PR 1 0 1166 Et 0 Allyl 3 o n PR 0 1 1167 Et 0 Allyl 2 o n PR 2 0 1168 Et 0 Allyl 2 o n PR 1 1 1169 Et 0 Allyl 2 o n PR 0 2 1170 Et 0 Allyl 1 o n PR 3 0 1171 Et 0 Allyl 1 o n PR 2 1 1172 Et 0 Allyl 1 o n PR 1 2 1173 Et 0 Allyl 1 o n PR 0 3 1174 Et 0 Allyl 0 o n PR 4 0 1175 Et 0 Allyl 0 o n PR 3 1 1176 Et 0 Allyl 0 o n PR 2 2 1177 Et 0 Allyl 0 o n PR 1 3 1178 Et 0 Allyl 0 o n PR 0 4

[0082] [Chemical 47] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1179 Et 2 Ethynyl 2 o n PR 0 0 1180 Et 2 Ethynyl 1 o n PR 1 0 1181 Et 2 Ethynyl 1 o n PR 0 1 1182 Et 2 Ethynyl 0 o n PR 2 0 1183 Et 2 Ethynyl 0 o n PR 1 1 1184 Et 2 Ethynyl 0 o n PR 0 2 1185 Et 1 Ethynyl 3 o n PR 0 0 1186 Et 1 Ethynyl 2 o n PR 1 0 1187 Et 1 Ethynyl 2 o n PR 0 1 1188 Et 1 Ethynyl 1 o n PR 2 0 1189 Et 1 Ethynyl 1 o n PR 1 1 1190 Et 1 Ethynyl 1 o n PR 0 2 1191 Et 1 Ethynyl 0 o n PR 3 0 1192 Et 1 Ethynyl 0 o n PR 2 1 1193 Et 1 Ethynyl 0 o n PR 1 2 1194 Et 1 Ethynyl 0 o n PR 0 3 1195 Et 0 Ethynyl 4 o n PR 0 0 1196 Et 0 Ethynyl 3 o n PR 1 0 1197 Et 0 Ethynyl 3 o n PR 0 1 1198 Et 0 Ethynyl 2 o n PR 2 0 1199 Et 0 Ethynyl 2 o n PR 1 1 1200 Et 0 Ethynyl 2 o n PR 0 2 1201 Et 0 Ethynyl 1 o n PR 3 0 1202 Et 0 Ethynyl 1 o n PR 2 1 1203 Et 0 Ethynyl 1 o n PR 1 2 1204 Et 0 Ethynyl 1 o n PR 0 3 1205 Et 0 Ethynyl 0 o n PR 4 0 1206 Et 0 Ethynyl 0 o n PR 3 1 1207 Et 0 Ethynyl 0 o n PR 2 2 1208 Et 0 Ethynyl 0 o n PR 1 3 1209 Et 0 Ethynyl 0 o n PR 0 4

[0083]

[48] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1210 Et 2 vinyl 2 o i PR 0 0 1211 Et 2 vinyl 1 o i PR 1 0 1212 Et 2 vinyl 1 o i PR 0 1 1213 Et 2 vinyl 0 o i PR 2 0 1214 Et 2 vinyl 0 o i PR 1 1 1215 Et 2 vinyl 0 o i PR 0 2 1216 Et 1 vinyl 3 o i PR 0 0 1217 Et 1 vinyl 2 o i PR 1 0 1218 Et 1 vinyl 2 o i PR 0 1 1219 Et 1 vinyl 1 o i PR 2 0 1220 Et 1 vinyl 1 o i PR 1 1 1221 Et 1 vinyl 1 o i PR 0 2 1222 Et 1 vinyl 0 o i PR 3 0 1223 Et 1 vinyl 0 o i PR 2 1 1224 Et 1 vinyl 0 o i PR 1 2 1225 Et 1 vinyl 0 o i PR 0 3 1226 Et 0 vinyl 4 o i PR 0 0 1227 Et 0 vinyl 3 o i PR 1 0 1228 Et 0 vinyl 3 o i PR 0 1 1229 Et 0 vinyl 2 o i PR 2 0 1230 Et 0 vinyl 2 o i PR 1 1 1231 Et 0 vinyl 2 o i PR 0 2 1232 Et 0 vinyl 1 o i PR 3 0 1233 Et 0 vinyl 1 o i PR 2 1 1234 Et 0 vinyl 1 o i PR 1 2 1235 Et 0 vinyl 1 o i PR 0 3 1236 Et 0 vinyl 0 o i PR 4 0 1237 Et 0 vinyl 0 o i PR 3 1 1238 Et 0 vinyl 0 o i PR 2 2 1239 Et 0 vinyl 0 o i PR 1 3 1240 Et 0 vinyl 0 o i PR 0 4

[0084] [Chemical 49] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1241 Et 2 Allyl 2 o i PR 0 0 1242 Et 2 Allyl 1 o i PR 1 0 1243 Et 2 Allyl 1 o i PR 0 1 1244 Et 2 Allyl 0 o i PR 2 0 1245 Et 2 Allyl 0 o i PR 1 1 1246 Et 2 Allyl 0 o i PR 0 2 1247 Et 1 Allyl 3 o i PR 0 0 1248 Et 1 Allyl 2 o i PR 1 0 1249 Et 1 Allyl 2 o i PR 0 1 1250 Et 1 Allyl 1 o i PR 2 0 1251 Et 1 Allyl 1 o i PR 1 1 1252 Et 1 Allyl 1 o i PR 0 2 1253 Et 1 Allyl 0 o i PR 3 0 1254 Et 1 Allyl 0 o i PR 2 1 1255 Et 1 Allyl 0 o i PR 1 2 1256 Et 1 Allyl 0 o i PR 0 3 1257 Et 0 Allyl 4 o i PR 0 0 1258 Et 0 Allyl 3 o i PR 1 0 1259 Et 0 Allyl 3 o i PR 0 1 1260 Et 0 Allyl 2 o i PR 2 0 1261 Et 0 Allyl 2 o i PR 1 1 1262 Et 0 Allyl 2 o i PR 0 2 1263 Et 0 Allyl 1 o i PR 3 0 1264 Et 0 Allyl 1 o i PR 2 1 1265 Et 0 Allyl 1 o i PR 1 2 1266 Et 0 Allyl 1 o i PR 0 3 1267 Et 0 Allyl 0 o i PR 4 0 1268 Et 0 Allyl 0 o i PR 3 1 1269 Et 0 Allyl 0 o i PR 2 2 1270 Et 0 Allyl 0 o i PR 1 3 1271 Et 0 Allyl 0 o i PR 0 4

[0085] [Chemical 50] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1272 Et 2 Ethynyl 2 o i PR 0 0 1273 Et 2 Ethynyl 1 o i PR 1 0 1274 Et 2 Ethynyl 1 o i PR 0 1 1275 Et 2 Ethynyl 0 o i PR 2 0 1276 Et 2 Ethynyl 0 o i PR 1 1 1277 Et 2 Ethynyl 0 o i PR 0 2 1278 Et 1 Ethynyl 3 o i PR 0 0 1279 Et 1 Ethynyl 2 o i PR 1 0 1280 Et 1 Ethynyl 2 o i PR 0 1 1281 Et 1 Ethynyl 1 o i PR 2 0 1282 Et 1 Ethynyl 1 o i PR 1 1 1283 Et 1 Ethynyl 1 oi PR 0 2 1284 Et 1 Ethynyl 0 o i PR 3 0 1285 Et 1 Ethynyl 0 o i PR 2 1 1286 Et 1 Ethynyl 0 o i PR 1 2 1287 Et 1 Ethynyl 0 o i PR 0 3 1288 Et 0 Ethynyl 4 o i PR 0 0 1289 Et 0 Ethynyl 3 o i PR 1 0 1290 Et 0 Ethynyl 3 o i PR 0 1 1291 Et 0 Ethynyl 2 o i PR 2 0 1292 Et 0 Ethynyl 2 o i PR 1 1 1293 Et 0 Ethynyl 2 o i PR 0 2 1294 Et 0 Ethynyl 1 o i PR 3 0 1295 Et 0 Ethynyl 1 o i PR 2 1 1296 Et 0 Ethynyl 1 o i PR 1 2 1297 Et 0 Ethynyl 1 o i PR 0 3 1298 Et 0 Ethynyl 0 o i PR 4 0 1299 Et 0 Ethynyl 0 o i PR 3 1 1300 Et 0 Ethynyl 0 o i PR 2 2 1301 Et 0 Ethynyl 0 o i PR 1 3 1302 Et 0 Ethynyl 0 o i PR 0 4

[0086] [Chemical 51] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1303 Et 2 vinyl 2 o n Bu 0 0 1304 Et 2 vinyl 1 o n Bu 1 0 1305 Et 2 vinyl 1 o n Bu 0 1 1306 Et 2 vinyl 0 o n Bu 2 0 1307 Et 2 vinyl 0 o n Bu 1 1 1308 Et 2 vinyl 0 o n Bu 0 2 1309 Et 1 vinyl 3 o n Bu 0 0 1310 Et 1 vinyl 2 o n Bu 1 0 1311 Et 1 vinyl 2 o n Bu 0 1 1312 Et 1 vinyl 1 o n Bu 2 0 1313 Et 1 vinyl 1 o n Bu 1 1 1314 Et 1 vinyl 1 o n Bu 0 2 1315 Et 1 vinyl 0 o n Bu 3 0 1316 Et 1 vinyl 0 o n Bu 2 1 1317 Et 1 vinyl 0 o n Bu 1 2 1318 Et 1 vinyl 0 o n Bu 0 3 1319 Et 0 vinyl 4 o n Bu 0 0 1320 Et 0 vinyl 3 o n Bu 1 0 1321 Et 0 vinyl 3 o n Bu 0 1 1322 Et 0 vinyl 2 o n Bu 2 0 1323 Et 0 vinyl 2 o n Bu 1 1 1324 Et 0 vinyl 2 o n Bu 0 2 1325 Et 0 vinyl 1 o n Bu 3 0 1326 Et 0 vinyl 1 o n Bu 2 1 1327 Et 0 vinyl 1 o n Bu 1 2 1328 Et 0 vinyl 1 o n Bu 0 3 1329 Et 0 vinyl 0 o n Bu 4 0 1330 Et 0 vinyl 0 o n Bu 3 1 1331 Et 0 vinyl 0 o n Bu 2 2 1332 Et 0 vinyl 0 o n Bu 1 3 1333 Et 0 vinyl 0 o n Bu 0 4

[0087] [Chemical 52] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1334 Et 2 Allyl 2 o n Bu 0 0 1335 Et 2 Allyl 1 o n Bu 1 0 1336 Et 2 Allyl 1 o n Bu 0 1 1337 Et 2 Allyl 0 o n Bu 2 0 1338 Et 2 Allyl 0 o n Bu 1 1 1339 Et 2 Allyl 0 o n Bu 0 2 1340 Et 1 Allyl 3 o n Bu 0 0 1341 Et 1 Allyl 2 o n Bu 1 0 1342 Et 1 Allyl 2 o n Bu 0 1 1343 Et 1 Allyl 1 o n Bu 2 0 1344 Et 1 Allyl 1 o n Bu 1 1 1345 Et 1 Allyl 1 o n Bu 0 2 1346 Et 1 Allyl 0 o n Bu 3 0 1347 Et 1 Allyl 0 o n Bu 2 1 1348 Et 1 Allyl 0 o n Bu 1 2 1349 Et 1 Allyl 0 o n Bu 0 3 1350 Et 0 Allyl 4 o n Bu 0 0 1351 Et 0 Allyl 3 o n Bu 1 0 1352 Et 0 Allyl 3 o n Bu 0 1 1353 Et 0 Allyl 2 o n Bu 2 0 1354 Et 0 Allyl 2 o n Bu 1 1 1355 Et 0 Allyl 2 o n Bu 0 2 1356 Et 0 Allyl 1 o n Bu 3 0 1357 Et 0 Allyl 1 o n Bu 2 1 1358 Et 0 Allyl 1 o n Bu 1 2 1359 Et 0 Allyl 1 o n Bu 0 3 1360 Et 0 Allyl 0 o n Bu 4 0 1361 Et 0 Allyl 0 o n Bu 3 1 1362 Et 0 Allyl 0 o n Bu 2 2 1363 Et 0 Allyl 0 o n Bu 1 3 1364 Et 0 Allyl 0 o n Bu 0 4

[0088] [Chemical 53] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1365 Et 2 Ethynyl 2 o n Bu 0 0 1366 Et 2 Ethynyl 1 o n Bu 1 0 1367 Et 2 Ethynyl 1 o n Bu 0 1 1368 Et 2 Ethynyl 0 o n Bu 2 0 1369 Et 2 Ethynyl 0 o n Bu 1 1 1370 Et 2 Ethynyl 0 o n Bu 0 2 1371 Et 1 Ethynyl 3 o n Bu 0 0 1372 Et 1 Ethynyl 2 o n Bu 1 0 1373 Et 1 Ethynyl 2 o n Bu 0 1 1374 Et 1 Ethynyl 1 o n Bu 2 0 1375 Et 1 Ethynyl 1 o n Bu 1 1 1376 Et 1 Ethynyl 1 o n Bu 0 2 1377 Et 1 Ethynyl 0 o n Bu 3 0 1378 Et 1 Ethynyl 0 o n Bu 2 1 1379 Et 1 Ethynyl 0 o n Bu 1 2 1380 Et 1 Ethynyl 0 o n Bu 0 3 1381 Et 0 Ethynyl 4 o n Bu 0 0 1382 Et 0 Ethynyl 3 o n Bu 1 0 1383 Et 0 Ethynyl 3 o n Bu 0 1 1384 Et 0 Ethynyl 2 o n Bu 2 0 1385 Et 0 Ethynyl 2 o n Bu 1 1 1386 Et 0 Ethynyl 2 o n Bu 0 2 1387 Et 0 Ethynyl 1 o n Bu 3 0 1388 Et 0 Ethynyl 1 o n Bu 2 1 1389 Et 0 Ethynyl 1 o n Bu 1 2 1390 Et 0 Ethynyl 1 o n Bu 0 3 1391 Et 0 Ethynyl 0 o n Bu 4 0 1392 Et 0 Ethynyl 0 o n Bu 3 1 1393 Et 0 Ethynyl 0 o n Bu 2 2 1394 Et 0 Ethynyl 0 o n Bu 1 3 1395 Et 0 Ethynyl 0 o n Bu 0 4

[0089] [Chemical 54] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1396 Et 2 vinyl 2 o i Bu 0 0 1397 Et 2 vinyl 1 o i Bu 1 0 1398 Et 2 vinyl 1 o i Bu 0 1 1399 Et 2 vinyl 0 o i Bu 2 0 1400 Et 2 vinyl 0 o i Bu 1 1 1401 Et 2 vinyl 0 o i Bu 0 2 1402 Et 1 vinyl 3 o i Bu 0 0 1403 Et 1 vinyl 2 o i Bu 1 0 1404 Et 1 vinyl 2 o i Bu 0 1 1405 Et 1 vinyl 1 o i Bu 2 0 1406 Et 1 vinyl 1 o i Bu 1 1 1407 Et 1 vinyl 1 o i Bu 0 2 1408 Et 1 vinyl 0 o i Bu 3 0 1409 Et 1 vinyl 0 o i Bu 2 1 1410 Et 1 vinyl 0 o i Bu 1 2 1411 Et 1 vinyl 0 o i Bu 0 3 1412 Et 0 vinyl 4 o i Bu 0 0 1413 Et 0 vinyl 3 o i Bu 1 0 1414 Et 0 vinyl 3 o i Bu 0 1 1415 Et 0 vinyl 2 o i Bu 2 0 1416 Et 0 vinyl 2 o i Bu 1 1 1417 Et 0 vinyl 2 o i Bu 0 2 1418 Et 0 vinyl 1 o i Bu 3 0 1419 Et 0 vinyl 1 o i Bu 2 1 1420 Et 0 vinyl 1 o i Bu 1 2 1421 Et 0 vinyl 1 o i Bu 0 3 1422 Et 0 vinyl 0 o i Bu 4 0 1423 Et 0 vinyl 0 o i Bu 3 1 1424 Et 0 vinyl 0 o i Bu 2 2 1425 Et 0 vinyl 0 o i Bu 1 3 1426 Et 0 vinyl 0 o i Bu 0 4

[0090] [Chemical 55] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1427 Et 2 Allyl 2 o i Bu 0 0 1428 Et 2 Allyl 1 o i Bu 1 0 1429 Et 2 Allyl 1 o i Bu 0 1 1430 Et 2 Allyl 0 o i Bu 2 0 1431 Et 2 Allyl 0 o i Bu 1 1 1432 Et 2 Allyl 0 o i Bu 0 2 1433 Et 1 Allyl 3 o i Bu 0 0 1434 Et 1 Allyl 2 o i Bu 1 0 1435 Et 1 Allyl 2 o i Bu 0 1 1436 Et 1 Allyl 1 o i Bu 2 0 1437 Et 1 Allyl 1 o i Bu 1 1 1438 Et 1 Allyl 1 o i Bu 0 2 1439 Et 1 Allyl 0 o i Bu 3 0 1440 Et 1 Allyl 0 o i Bu 2 1 1441 Et 1 Allyl 0 o i Bu 1 2 1442 Et 1 Allyl 0 o i Bu 0 3 1443 Et 0 Allyl 4 o i Bu 0 0 1444 Et 0 Allyl 3 o i Bu 1 0 1445 Et 0 Allyl 3 o i Bu 0 1 1446 Et 0 Allyl 2 o i Bu 2 0 1447 Et 0 Allyl 2 o i Bu 1 1 1448 Et 0 Allyl 2 o i Bu 0 2 1449 Et 0 Allyl 1 o i Bu 3 0 1450 Et 0 Allyl 1 o i Bu 2 1 1451 Et 0 Allyl 1 o i Bu 1 2 1452 Et 0 Allyl 1 o i Bu 0 3 1453 Et 0 Allyl 0 o i Bu 4 0 1454 Et 0 Allyl 0 o i Bu 3 1 1455 Et 0 Allyl 0 o i Bu 2 2 1456 Et 0 Allyl 0 o i Bu 1 3 1457 Et 0 Allyl 0 o i Bu 0 4

[0091] [Chemical 56] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1458 Et 2 Ethynyl 2 o i Bu 0 0 1459 Et 2 Ethynyl 1 o i Bu 1 0 1460 Et 2 Ethynyl 1 o i Bu 0 1 1461 Et 2 Ethynyl 0 o i Bu 2 0 1462 Et 2 Ethynyl 0 o i Bu 1 1 1463 Et 2 Ethynyl 0 o i Bu 0 2 1464 Et 1 Ethynyl 3 o i Bu 0 0 1465 Et 1 Ethynyl 2 o i Bu 1 0 1466 Et 1 Ethynyl 2 o i Bu 0 1 1467 Et 1 Ethynyl 1 o i Bu 2 0 1468 Et 1 Ethynyl 1 o i Bu 1 1 1469 Et 1 Ethynyl 1 o i Bu 0 2 1470 Et 1 Ethynyl 0 o i Bu 3 0 1471 Et 1 Ethynyl 0 o i Bu 2 1 1472 Et 1 Ethynyl 0 o i Bu 1 2 1473 Et 1 Ethynyl 0 o i Bu 0 3 1474 Et 0 Ethynyl 4 o i Bu 0 0 1475 Et 0 Ethynyl 3 o i Bu 1 0 1476 Et 0 Ethynyl 3 o i Bu 0 1 1477 Et 0 Ethynyl 2 o i Bu 2 0 1478 Et 0 Ethynyl 2 o i Bu 1 1 1479 Et 0 Ethynyl 2 o i Bu 0 2 1480 Et 0 Ethynyl 1 o i Bu 3 0 1481 Et 0 Ethynyl 1 o i Bu 2 1 1482 Et 0 Ethynyl 1 o i Bu 1 2 1483 Et 0 Ethynyl 1 o i Bu 0 3 1484 Et 0 Ethynyl 0 o i Bu 4 0 1485 Et 0 Ethynyl 0 o i Bu 3 1 1486 Et 0 Ethynyl 0 o i Bu 2 2 1487 Et 0 Ethynyl 0 o i Bu 1 3 1488 Et 0 Ethynyl 0 o i Bu 0 4

[0092] [Chemical 57] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1489 Et 2 vinyl 2 o sec Bu 0 0 1490 Et 2 vinyl 1 o sec Bu 1 0 1491 Et 2 vinyl 1 o sec Bu 0 1 1492 Et 2 vinyl 0 o sec Bu 2 0 1493 Et 2 vinyl 0 o sec Bu 1 1 1494 Et 2 vinyl 0 o sec Bu 0 2 1495 Et 1 vinyl 3 o sec Bu 0 0 1496 Et 1 vinyl 2 o sec Bu 1 0 1497 Et 1 vinyl 2 o sec Bu 0 1 1498 Et 1 vinyl 1 o sec Bu 2 0 1499 Et 1 vinyl 1 o sec Bu 1 1 1500 Et 1 vinyl 1 o sec Bu 0 2 1501 Et 1 vinyl 0 o sec Bu 3 0 1502 Et 1 vinyl 0 o sec Bu 2 1 1503 Et 1 vinyl 0 o sec Bu 1 2 1504 Et 1 vinyl 0 osec Bu 0 3 1505 Et 0 vinyl 4 o sec Bu 0 0 1506 Et 0 vinyl 3 o sec Bu 1 0 1507 Et 0 vinyl 3 o sec Bu 0 1 1508 Et 0 vinyl 2 o sec Bu 2 0 1509 Et 0 vinyl 2 o sec Bu 1 1 1510 Et 0 vinyl 2 o sec Bu 0 2 1511 Et 0 vinyl 1 o sec Bu 3 0 1512 Et 0 vinyl 1 o sec Bu 2 1 1513 Et 0 vinyl 1 o sec Bu 1 2 1514 Et 0 vinyl 1 o sec Bu 0 3 1515 Et 0 vinyl 0 o sec Bu 4 0 1516 Et 0 vinyl 0 o sec Bu 3 1 1517 Et 0 vinyl 0 o sec Bu 2 2 1518 Et 0 vinyl 0 o sec Bu 1 3 1519 Et 0 vinyl 0 o sec Bu 0 4

[0093] [Chemical 58] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1520 Et 2 Allyl 2 o sec Bu 0 0 1521 Et 2 Allyl 1 o sec Bu 1 0 1522 Et 2 Allyl 1 o sec Bu 0 1 1523 Et 2 Allyl 0 o sec Bu 2 0 1524 Et 2 Allyl 0 o sec Bu 1 1 1525 Et 2 Allyl 0 o sec Bu 0 2 1526 Et 1 Allyl 3 o sec Bu 0 0 1527 Et 1 Allyl 2 o sec Bu 1 0 1528 Et 1 Allyl 2 o sec Bu 0 1 1529 Et 1 Allyl 1 o sec Bu 2 0 1530 Et 1 Allyl 1 o sec Bu 1 1 1531 Et 1 Allyl 1 o sec Bu 0 2 1532 Et 1 Allyl 0 o sec Bu 3 0 1533 Et 1 Allyl 0 o sec Bu 2 1 1534 Et 1 Allyl 0 o sec Bu 1 2 1535 Et 1 Allyl 0 o sec Bu 0 3 1536 Et 0 Allyl 4 o sec Bu 0 0 1537 Et 0 Allyl 3 o sec Bu 1 0 1538 Et 0 Allyl 3 o sec Bu 0 1 1539 Et 0 Allyl 2 o sec Bu 2 0 1540 Et 0 Allyl 2 o sec Bu 1 1 1541 Et 0 Allyl 2 o sec Bu 0 2 1542 Et 0 Allyl 1 o sec Bu 3 0 1543 Et 0 Allyl 1 o sec Bu 2 1 1544 Et 0 Allyl 1 o sec Bu 1 2 1545 Et 0 Allyl 1 o sec Bu 0 3 1546 Et 0 Allyl 0 o sec Bu 4 0 1547 Et 0 Allyl 0 o sec Bu 3 1 1548 Et 0 Allyl 0 o sec Bu 2 2 1549 Et 0 Allyl 0 o sec Bu 1 3 1550 Et 0 Allyl 0 o sec Bu 0 4

[0094] [Chemical 59] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1551 Et 2 Ethynyl 2 o sec Bu 0 0 1552 Et 2 Ethynyl 1 o sec Bu 1 0 1553 Et 2 Ethynyl 1 o sec Bu 0 1 1554 Et 2 Ethynyl 0 o sec Bu 2 0 1555 Et 2 Ethynyl 0 o sec Bu 1 1 1556 Et 2 Ethynyl 0 o sec Bu 0 2 1557 Et 1 Ethynyl 3 o sec Bu 0 0 1558 Et 1 Ethynyl 2 o sec Bu 1 0 1559 Et 1 Ethynyl 2 o sec Bu 0 1 1560 Et 1 Ethynyl 1 o sec Bu 2 0 1561 Et 1 Ethynyl 1 o sec Bu 1 1 1562 Et 1 Ethynyl 1 o sec Bu 0 2 1563 Et 1 Ethynyl 0 o sec Bu 3 0 1564 Et 1 Ethynyl 0 o sec Bu 2 1 1565 Et 1 Ethynyl 0 o sec Bu 1 2 1566 Et 1 Ethynyl 0 o sec Bu 0 3 1567 Et 0 Ethynyl 4 o sec Bu 0 0 1568 Et 0 Ethynyl 3 o sec Bu 1 0 1569 Et 0 Ethynyl 3 o sec Bu 0 1 1570 Et 0 Ethynyl 2 o sec Bu 2 0 1571 Et 0 Ethynyl 2 o sec Bu 1 1 1572 Et 0 Ethynyl 2 o sec Bu 0 2 1573 Et 0 Ethynyl 1 o sec Bu 3 0 1574 Et 0 Ethynyl 1 o sec Bu 2 1 1575 Et 0 Ethynyl 1 o sec Bu 1 2 1576 Et 0 Ethynyl 1 o sec Bu 0 3 1577 Et 0 Ethynyl 0 o sec Bu 4 0 1578 Et 0 Ethynyl 0 o sec Bu 3 1 1579 Et 0 Ethynyl 0 o sec Bu 2 2 1580 Et 0 Ethynyl 0 o sec Bu 1 3 1581 Et 0 Ethynyl 0 o sec Bu 0 4

[0095] [C60] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1582 Et 2 vinyl 2 o t Bu 0 0 1583 Et 2 vinyl 1 o t Bu 1 0 1584 Et 2 vinyl 1 o t Bu 0 1 1585 Et 2 vinyl 0 o t Bu 2 0 1586 Et 2 vinyl 0 o t Bu 1 1 1587 Et 2 vinyl 0 o t Bu 0 2 1588 Et 1 vinyl 3 o t Bu 0 0 1589 Et 1 vinyl 2 o t Bu 1 0 1590 Et 1 vinyl 2 o t Bu 0 1 1591 Et 1 vinyl 1 o t Bu 2 0 1592 Et 1 vinyl 1 o t Bu 1 1 1593 Et 1 vinyl 1 o t Bu 0 2 1594 Et 1 vinyl 0 o t Bu 3 0 1595 Et 1 vinyl 0 o t Bu 2 1 1596 Et 1 vinyl 0 o t Bu 1 2 1597 Et 1 vinyl 0 o t Bu 0 3 1598 Et 0 vinyl 4 o t Bu 0 0 1599 Et 0 vinyl 3 o t Bu 1 0 1600 Et 0 vinyl 3 o t Bu 0 1 1601 Et 0 vinyl 2 o t Bu 2 0 1602 Et 0 vinyl 2 o t Bu 1 1 1603 Et 0 vinyl 2 o t Bu 0 2 1604 Et 0 vinyl 1 o t Bu 3 0 1605 Et 0 vinyl 1 o t Bu 2 1 1606 Et 0 vinyl 1 o t Bu 1 2 1607 Et 0 vinyl 1 o t Bu 0 3 1608 Et 0 vinyl 0 o t Bu 4 0 1609 Et 0 vinyl 0 o t Bu 3 1 1610 Et 0 vinyl 0 o t Bu 2 2 1611 Et 0 vinyl 0 o t Bu 1 3 1612 Et 0 vinyl 0 o t Bu 0 4

[0096] [Chemical 61] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1613 Et 2 Allyl 2 o t Bu 0 0 1614 Et 2 Allyl 1 o t Bu 1 0 1615 Et 2 Allyl 1 o t Bu 0 1 1616 Et 2 Allyl 0 o t Bu 2 0 1617 Et 2 Allyl 0 o t Bu 1 1 1618 Et 2 Allyl 0 o t Bu 0 2 1619 Et 1 Allyl 3 o t Bu 0 0 1620 Et 1 Allyl 2 o t Bu 1 0 1621 Et 1 Allyl 2 o t Bu 0 1 1622 Et 1 Allyl 1 o t Bu 2 0 1623 Et 1 Allyl 1 o t Bu 1 1 1624 Et 1 Allyl 1 o t Bu 0 2 1625 Et 1 Allyl 0 o t Bu 3 0 1626 Et 1 Allyl 0 o t Bu 2 1 1627 Et 1 Allyl 0 o t Bu 1 2 1628 Et 1 Allyl 0 o t Bu 0 3 1629 Et 0 Allyl 4 o t Bu 0 0 1630 Et 0 Allyl 3 o t Bu 1 0 1631 Et 0 Allyl 3 o t Bu 0 1 1632 Et 0 Allyl 2 o t Bu 2 0 1633 Et 0 Allyl 2 o t Bu 1 1 1634 Et 0 Allyl 2 o t Bu 0 2 1635 Et 0 Allyl 1 o t Bu 3 0 1636 Et 0 Allyl 1 o t Bu 2 1 1637 Et 0 Allyl 1 o t Bu 1 2 1638 Et 0 Allyl 1 o t Bu 0 3 1639 Et 0 Allyl 0 o t Bu 4 0 1640 Et 0 Allyl 0 o t Bu 3 1 1641 Et 0 Allyl 0 o t Bu 2 2 1642 Et 0 Allyl 0 o t Bu 1 3 1643 Et 0 Allyl 0 o t Bu 0 4

[0097] [Chemical 62] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1644 Et 2 Ethynyl 2 o t Bu 0 0 1645 Et 2 Ethynyl 1 o t Bu 1 0 1646 Et 2 Ethynyl 1 o t Bu 0 1 1647 Et 2 Ethynyl 0 o t Bu 2 0 1648 Et 2 Ethynyl 0 o t Bu 1 1 1649 Et 2 Ethynyl 0 o t Bu 0 2 1650 Et 1 Ethynyl 3 o t Bu 0 0 1651 Et 1 Ethynyl 2 o t Bu 1 0 1652 Et 1 Ethynyl 2 o t Bu 0 1 1653 Et 1 Ethynyl 1 o t Bu 2 0 1654 Et 1 Ethynyl 1 o t Bu 1 1 1655 Et 1 Ethynyl 1 o t Bu 0 2 1656 Et 1 Ethynyl 0 o t Bu 3 0 1657 Et 1 Ethynyl 0 o t Bu 2 1 1658 Et 1 Ethynyl 0 o t Bu 1 2 1659 Et 1 Ethynyl 0 o t Bu 0 3 1660 Et 0 Ethynyl 4 o t Bu 0 0 1661 Et 0 Ethynyl 3 o t Bu 1 0 1662 Et 0 Ethynyl 3 o t Bu 0 1 1663 Et 0 Ethynyl 2 o t Bu 2 0 1664 Et 0 Ethynyl 2 o t Bu 1 1 1665 Et 0 Ethynyl 2 o t Bu 0 2 1666 Et 0 Ethynyl 1 o t Bu 3 0 1667 Et 0 Ethynyl 1 o t Bu 2 1 1668 Et 0 Ethynyl 1 o t Bu 1 2 1669 Et 0 Ethynyl 1 o t Bu 0 3 1670 Et 0 Ethynyl 0 o t Bu 4 0 1671 Et 0 Ethynyl 0 o t Bu 3 1 1672 Et 0 Ethynyl 0 o t Bu 2 2 1673 Et 0 Ethynyl 0 o t Bu 1 3 1674 Et 0 Ethynyl 0 o t Bu 0 4

[0098] [Chemical 63] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1675 n PR 2 vinyl 2 Oh 0 0 1676 n PR 2 vinyl 1 Oh 1 0 1677 n PR 2 vinyl 1 Oh 0 1 1678 n PR 2 vinyl 0 Oh 2 0 1679 n PR 2 vinyl 0 Oh 1 1 1680 n PR 2 vinyl 0 Oh 0 2 1681 n PR 1 vinyl 3 Oh 0 0 1682 n PR 1 vinyl 2 Oh 1 0 1683 n PR 1 vinyl 2 Oh 0 1 1684 n PR 1 vinyl 1 Oh 2 0 1685 n PR 1 vinyl 1 Oh 1 1 1686 n PR 1 vinyl 1 Oh 0 2 1687 n PR 1 vinyl 0 Oh 3 0 1688 n PR 1 vinyl 0 Oh 2 1 1689 n PR 1 vinyl 0 Oh 1 2 1690 n PR 1 vinyl 0 Oh 0 3 1691 n PR 0 vinyl 4 Oh 0 0 1692 n PR 0 vinyl 3 Oh 1 0 1693 n PR 0 vinyl 3 Oh 0 1 1694 n PR 0 vinyl 2 Oh 2 0 1695 n PR 0 vinyl 2 Oh 1 1 1696 n PR 0 vinyl 2 Oh 0 2 1697 n PR 0 vinyl 1 Oh 3 0 1698 n PR 0 vinyl 1 Oh 2 1 1699 n PR 0 vinyl 1 Oh 1 2 1700 n PR 0 vinyl 1 Oh 0 3 1701 n PR 0 vinyl 0 Oh 4 0 1702 n PR 0 vinyl 0 Oh 3 1 1703 n PR 0 vinyl 0 Oh 2 2 1704 n PR 0 vinyl 0 Oh 1 3 1705 n PR 0 vinyl 0 Oh 0 4

[0099] [Chemical 64] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1706 n PR 2 Allyl 2 Oh 0 0 1707 n PR 2 Allyl 1 Oh 1 0 1708 n PR 2 Allyl 1 Oh 0 1 1709 n PR 2 Allyl 0 Oh 2 0 1710 n PR 2 Allyl 0 Oh 1 1 1711 n PR 2 Allyl 0 Oh 0 2 1712 n PR 1 Allyl 3 Oh 0 0 1713 n PR 1 Allyl 2 Oh 1 0 1714 n PR 1 Allyl 2 Oh 0 1 1715 n PR 1 Allyl 1 Oh 2 0 1716 n PR 1 Allyl 1 Oh 1 1 1717 n PR 1 Allyl 1 Oh 0 2 1718 n PR 1 Allyl 0 Oh 3 0 1719 n PR 1 Allyl 0 Oh 2 1 1720 n PR 1 Allyl 0 Oh 1 2 1721 n PR 1 Allyl 0 Oh 0 3 1722 n PR 0 Allyl 4 Oh 0 0 1723 n PR 0 Allyl 3 Oh 1 0 1724 n PR 0 Allyl 3 Oh 0 1 1725 n PR 0 Allyl 2 Oh 2 0 1726 n PR 0 Allyl 2 Oh 1 1 1727 n PR 0 Allyl 2 Oh 0 2 1728 n PR 0 Allyl 1 Oh 3 0 1729 n PR 0 Allyl 1 Oh 2 1 1730 n PR 0 Allyl 1 Oh 1 2 1731 n PR 0 Allyl 1 Oh 0 3 1732 n PR 0 Allyl 0 Oh 4 0 1733 n PR 0 Allyl 0 Oh 3 1 1734 n PR 0 Allyl 0 Oh 2 2 1735 n PR 0 Allyl 0 Oh 1 3 1736 n PR 0 Allyl 0 Oh 0 4

[0100] [Chemical 65] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1737 n PR 2 Ethynyl 2 Oh 0 0 1738 n PR 2 Ethynyl 1 Oh 1 0 1739 n PR 2 Ethynyl 1 Oh 0 1 1740 n PR 2 Ethynyl 0 Oh 2 0 1741 n PR 2 Ethynyl 0 Oh 1 1 1742 n PR 2 Ethynyl 0 Oh 0 2 1743 n PR 1 Ethynyl 3 Oh 0 0 1744 n PR 1 Ethynyl 2 Oh 1 0 1745 n PR 1 Ethynyl 2 Oh 0 1 1746 n PR 1 Ethynyl 1 Oh 2 0 1747 n PR 1 Ethynyl 1 Oh 1 1 1748 n PR 1 Ethynyl 1 Oh 0 2 1749 n PR 1 Ethynyl 0 Oh 3 0 1750 n PR 1 Ethynyl 0 Oh 2 1 1751 n PR 1 Ethynyl 0 Oh 1 2 1752 n PR 1 Ethynyl 0 Oh 0 3 1753 n PR 0 Ethynyl 4 Oh 0 0 1754 n PR 0 Ethynyl 3 Oh 1 0 1755 n PR 0 Ethynyl 3 Oh 0 1 1756 n PR 0 Ethynyl 2 Oh 2 0 1757 n PR 0 Ethynyl 2 Oh 1 1 1758 n PR 0 Ethynyl 2 Oh 0 2 1759 n PR 0 Ethynyl 1 Oh 3 0 1760 n PR 0 Ethynyl 1 Oh 2 1 1761 n PR 0 Ethynyl 1 Oh 1 2 1762 n PR 0 Ethynyl 1 Oh 0 3 1763 n PR 0 Ethynyl 0 Oh 4 0 1764 n PR 0 Ethynyl 0 Oh 3 1 1765 n PR 0 Ethynyl 0 Oh 2 2 1766 n PR 0 Ethynyl 0 Oh 1 3 1767 n PR 0 Ethynyl 0 Oh 0 4

[0101] [Chemical 66] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1768 n PR 2 vinyl 2 OMe 0 0 1769 n PR 2 vinyl 1 OMe 1 0 1770 n PR 2 vinyl 1 OMe 0 1 1771 n PR 2 vinyl 0 OMe 2 0 1772 n PR 2 vinyl 0 OMe 1 1 1773 n PR 2 vinyl 0 OMe 0 2 1774 n PR 1 vinyl 3 OMe 0 0 1775 n PR 1 vinyl 2 OMe 1 0 1776 n PR 1 vinyl 2 OMe 0 1 1777 n PR 1 vinyl 1 OMe 2 0 1778 n PR 1 vinyl 1 OMe 1 1 1779 n PR 1 vinyl 1 OMe 0 2 1780 n PR 1 vinyl 0 OMe 3 0 1781 n PR 1 vinyl 0 OMe 2 1 1782 n PR 1 vinyl 0 OMe 1 2 1783 n PR 1 vinyl 0 OMe 0 3 1784 n PR 0 vinyl 4 OMe 0 0 1785 n PR 0 vinyl 3 OMe 1 0 1786 n PR 0 vinyl 3 OMe 0 1 1787 n PR 0 vinyl 2 OMe 2 0 1788 n PR 0 vinyl 2 OMe 1 1 1789 n PR 0 vinyl 2 OMe 0 2 1790 n PR 0 vinyl 1 OMe 3 0 1791 n PR 0 vinyl 1 OMe 2 1 1792 n PR 0 vinyl 1 OMe 1 2 1793 n PR 0 vinyl 1 OMe 0 3 1794 n PR 0 vinyl 0 OMe 4 0 1795 n PR 0 vinyl 0 OMe 3 1 1796 n PR 0 vinyl 0 OMe 2 2 1797 n PR 0 vinyl 0 OMe 1 3 1798 n PR 0 vinyl 0 OMe 0 4

[0102] [Chemical 67] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1799 n PR 2 Allyl 2 OMe 0 0 1800 n PR 2 Allyl 1 OMe 1 0 1801 n PR 2 Allyl 1 OMe 0 1 1802 n PR 2 Allyl 0 OMe 2 0 1803 n PR 2 Allyl 0 OMe 1 1 1804 n PR 2 Allyl 0 OMe 0 2 1805 n PR 1 Allyl 3 OMe 0 0 1806 n PR 1 Allyl 2 OMe 1 0 1807 n PR 1 Allyl 2 OMe 0 1 1808 n PR 1 Allyl 1 OMe 2 0 1809 n PR 1 Allyl 1 OMe 1 1 1810 n PR 1 Allyl 1 OMe 0 2 1811 n PR 1 Allyl 0 OMe 3 0 1812 n PR 1 Allyl 0 OMe 2 1 1813 n PR 1 Allyl 0 OMe 1 2 1814 n PR 1 Allyl 0 OMe 0 3 1815 n PR 0 Allyl 4 OMe 0 0 1816 n PR 0 Allyl 3 OMe 1 0 1817 n PR 0 Allyl 3 OMe 0 1 1818 n PR 0 Allyl 2 OMe 2 0 1819 n PR 0 Allyl 2 OMe 1 1 1820 n PR 0 Allyl 2 OMe 0 2 1821 n PR 0 Allyl 1 OMe 3 0 1822 n PR 0 Allyl 1 OMe 2 1 1823 n PR 0 Allyl 1 OMe 1 2 1824 n PR 0 Allyl 1 OMe 0 3 1825 n PR 0 Allyl 0 OMe 4 0 1826 n PR 0 Allyl 0 OMe 3 1 1827 n PR 0 Allyl 0 OMe 2 2 1828 n PR 0 Allyl 0 OMe 1 3 1829 n PR 0 Allyl 0 OMe 0 4

[0103] [Chemical 68] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1830 n PR 2 Ethynyl 2 OMe 0 0 1831 n PR 2 Ethynyl 1 OMe 1 0 1832 n PR 2 Ethynyl 1 OMe 0 1 1833 n PR 2 Ethynyl 0 OMe 2 0 1834 n PR 2 Ethynyl 0 OMe 1 1 1835 n PR 2 Ethynyl 0 OMe 0 2 1836 n PR 1 Ethynyl 3 OMe 0 0 1837 n PR 1 Ethynyl 2 OMe 1 0 1838 n PR 1 Ethynyl 2 OMe 0 1 1839 n PR 1 Ethynyl 1 OMe 2 0 1840 n PR 1 Ethynyl 1 OMe 1 1 1841 n PR 1 Ethynyl 1 OMe 0 2 1842 n PR 1 Ethynyl 0 OMe 3 0 1843 n PR 1 Ethynyl 0 OMe 2 1 1844 n PR 1 Ethynyl 0 OMe 1 2 1845 n PR 1 Ethynyl 0 OMe 0 3 1846 n PR 0 Ethynyl 4 OMe 0 0 1847 n PR 0 Ethynyl 3 OMe 1 0 1848 n PR 0 Ethynyl 3 OMe 0 1 1849 n PR 0 Ethynyl 2 OMe 2 0 1850 n PR 0 Ethynyl 2 OMe 1 1 1851 n PR 0 Ethynyl 2 OMe 0 2 1852 n PR 0 Ethynyl 1 OMe 3 0 1853 n PR 0 Ethynyl 1 OMe 2 1 1854 n PR 0 Ethynyl 1 OMe 1 2 1855 n PR 0 Ethynyl 1 OMe 0 3 1856 n PR 0 Ethynyl 0 OMe 4 0 1857 n PR 0 Ethynyl 0 OMe 3 1 1858 n PR 0 Ethynyl 0 OMe 2 2 1859 n PR 0 Ethynyl 0 OMe 1 3 1860 n PR 0 Ethynyl 0 OMe 0 4

[0104] [Chemical 69] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1861 n PR 2 vinyl 2 OEt 0 0 1862 n PR 2 vinyl 1 OEt 1 0 1863 n PR 2 vinyl 1 OEt 0 1 1864 n PR 2 vinyl 0 OEt 2 0 1865 n PR 2 vinyl 0 OEt 1 1 1866 n PR 2 vinyl 0 OEt 0 2 1867 n PR 1 vinyl 3 OEt 0 0 1868 n PR 1 vinyl 2 OEt 1 0 1869 n PR 1 vinyl 2 OEt 0 1 1870 n PR 1 vinyl 1 OEt 2 0 1871 n PR 1 vinyl 1 OEt 1 1 1872 n PR 1 vinyl 1 OEt 0 2 1873 n PR 1 vinyl 0 OEt 3 0 1874 n PR 1 vinyl 0 OEt 2 1 1875 n PR 1 vinyl 0 OEt 1 2 1876 n PR 1 vinyl 0 OEt 0 3 1877 n PR 0 vinyl 4 OEt 0 0 1878 n PR 0 vinyl 3 OEt 1 0 1879 n PR 0 vinyl 3 OEt 0 1 1880 n PR 0 vinyl 2 OEt 2 0 1881 n PR 0 vinyl 2 OEt 1 1 1882 n PR 0 vinyl 2 OEt 0 2 1883 n PR 0 vinyl 1 OEt 3 0 1884 n PR 0 vinyl 1 OEt 2 1 1885 n PR 0 vinyl 1 OEt 1 2 1886 n PR 0 vinyl 1 OEt 0 3 1887 n PR 0 vinyl 0 OEt 4 0 1888 n PR 0 vinyl 0 OEt 3 1 1889 n PR 0 vinyl 0 OEt 2 2 1890 n PR 0 vinyl 0 OEt 1 3 1891 n PR 0 vinyl 0 OEt 0 4

[0105] [C70] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1892 n PR 2 Allyl 2 OEt 0 0 1893 n PR 2 Allyl 1 OEt 1 0 1894 n PR 2 Allyl 1 OEt 0 1 1895 n PR 2 Allyl 0 OEt 2 0 1896 n PR 2 Allyl 0 OEt 1 1 1897 n PR 2 Allyl 0 OEt 0 2 1898 n PR 1 Allyl 3 OEt 0 0 1899 n PR 1 Allyl 2 OEt 1 0 1900 n PR 1 Allyl 2 OEt 0 1 1901 n PR 1 Allyl 1 OEt 2 0 1902 n PR 1 Allyl 1 OEt 1 1 1903 n PR 1 Allyl 1 OEt 0 2 1904 n PR 1 Allyl 0 OEt 3 0 1905 n PR 1 Allyl 0 OEt 2 1 1906 n PR 1 Allyl 0 OEt 1 2 1907 n PR 1 Allyl 0 OEt 0 3 1908 n PR 0 Allyl 4 OEt 0 0 1909 n PR 0 Allyl 3 OEt 1 0 1910 n PR 0 Allyl 3 OEt 0 1 1911 n PR 0 Allyl 2 OEt 2 0 1912 n PR 0 Allyl 2 OEt 1 1 1913 n PR 0 Allyl 2 OEt 0 2 1914 n PR 0 Allyl 1 OEt 3 0 1915 n PR 0 Allyl 1 OEt 2 1 1916 n PR 0 Allyl 1 OEt 1 2 1917 n PR 0 Allyl 1 OEt 0 3 1918 n PR 0 Allyl 0 OEt 4 0 1919 n PR 0 Allyl 0 OEt 3 1 1920 n PR 0 Allyl 0 OEt 2 2 1921 n PR 0 Allyl 0 OEt 1 3 1922 n PR 0 Allyl 0 OEt 0 4

[0106] [Chemical 71] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1923 n PR 2 Ethynyl 2 OEt 0 0 1924 n PR 2 Ethynyl 1 OEt 1 0 1925 n PR 2 Ethynyl 1 OEt 0 1 1926 n PR 2 Ethynyl 0 OEt 2 0 1927 n PR 2 Ethynyl 0 OEt 1 1 1928 n PR 2 Ethynyl 0 OEt 0 2 1929 n PR 1 Ethynyl 3 OEt 0 0 1930 n PR 1 Ethynyl 2 OEt 1 0 1931 n PR 1 Ethynyl 2 OEt 0 1 1932 n PR 1 Ethynyl 1 OEt 2 0 1933 n PR 1 Ethynyl 1 OEt 1 1 1934 n PR 1 Ethynyl 1 OEt 0 2 1935 n PR 1 Ethynyl 0 OEt 3 0 1936 n PR 1 Ethynyl 0 OEt 2 1 1937 n PR 1 Ethynyl 0 OEt 1 2 1938 n PR 1 Ethynyl 0 OEt 0 3 1939 n PR 0 Ethynyl 4 OEt 0 0 1940 n PR 0 Ethynyl 3 OEt 1 0 1941 n PR 0 Ethynyl 3 OEt 0 1 1942 n PR 0 Ethynyl 2 OEt 2 0 1943 n PR 0 Ethynyl 2 OEt 1 1 1944 n PR 0 Ethynyl 2 OEt 0 2 1945 n PR 0 Ethynyl 1 OEt 3 0 1946 n PR 0 Ethynyl 1 OEt 2 1 1947 n PR 0 Ethynyl 1 OEt 1 2 1948 n PR 0 Ethynyl 1 OEt 0 3 1949 n PR 0 Ethynyl 0 OEt 4 0 1950 n PR 0 Ethynyl 0 OEt 3 1 1951 n PR 0 Ethynyl 0 OEt 2 2 1952 n PR 0 Ethynyl 0 OEt 1 3 1953 n PR 0 Ethynyl 0 OEt 0 4

[0107] [Chemical 72] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1954 n PR 2 vinyl 2 o n PR 0 0 1955 n PR 2 vinyl 1 o n PR 1 0 1956 n PR 2 vinyl 1 o n PR 0 1 1957 n PR 2 vinyl 0 o n PR 2 0 1958 n PR 2 vinyl 0 o n PR 1 1 1959 n PR 2 vinyl 0 o n PR 0 2 1960 n PR 1 vinyl 3 o n PR 0 0 1961 n PR 1 vinyl 2 o n PR 1 0 1962 n PR 1 vinyl 2 o n PR 0 1 1963 n PR 1 vinyl 1 o n PR 2 0 1964 n PR 1 vinyl 1 o n PR 1 1 1965 n PR 1 vinyl 1 o n PR 0 2 1966 n PR 1 vinyl 0 o n PR 3 0 1967 n PR 1 vinyl 0 o n PR 2 1 1968 n PR 1 vinyl 0 o n PR 1 2 1969 n PR 1 vinyl 0 o n PR 0 3 1970 n PR 0 vinyl 4 o n PR 0 0 1971 n PR 0 vinyl 3 o n PR 1 0 1972 n PR 0 vinyl 3 o n PR 0 1 1973 n PR 0 vinyl 2 o n PR 2 0 1974 n PR 0 vinyl 2 o n PR 1 1 1975 n PR 0 vinyl 2 o n PR 0 2 1976 n PR 0 vinyl 1 on PR 3 0 1977 n PR 0 vinyl 1 o n PR 2 1 1978 n PR 0 vinyl 1 o n PR 1 2 1979 n PR 0 vinyl 1 o n PR 0 3 1980 n PR 0 vinyl 0 o n PR 4 0 1981 n PR 0 vinyl 0 o n PR 3 1 1982 n PR 0 vinyl 0 o n PR 2 2 1983 n PR 0 vinyl 0 o n PR 1 3 1984 n PR 0 vinyl 0 o n PR 0 4

[0108] [C73] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 1985 n PR 2 Allyl 2 o n PR 0 0 1986 n PR 2 Allyl 1 o n PR 1 0 1987 n PR 2 Allyl 1 o n PR 0 1 1988 n PR 2 Allyl 0 o n PR 2 0 1989 n PR 2 Allyl 0 o n PR 1 1 1990 n PR 2 Allyl 0 o n PR 0 2 1991 n PR 1 Allyl 3 o n PR 0 0 1992 n PR 1 Allyl 2 o n PR 1 0 1993 n PR 1 Allyl 2 o n PR 0 1 1994 n PR 1 Allyl 1 o n PR 2 0 1995 n PR 1 Allyl 1 o n PR 1 1 1996 n PR 1 Allyl 1 o n PR 0 2 1997 n PR 1 Allyl 0 o n PR 3 0 1998 n PR 1 Allyl 0 o n PR 2 1 1999 n PR 1 Allyl 0 o n PR 1 2 2000 n PR 1 Allyl 0 o n PR 0 3 2001 n PR 0 Allyl 4 o n PR 0 0 2002 n PR 0 Allyl 3 o n PR 1 0 2003 n PR 0 Allyl 3 o n PR 0 1 2004 n PR 0 Allyl 2 o n PR 2 0 2005 n PR 0 Allyl 2 o n PR 1 1 2006 n PR 0 Allyl 2 o n PR 0 2 2007 n PR 0 Allyl 1 o n PR 3 0 2008 n PR 0 Allyl 1 o n PR 2 1 2009 n PR 0 Allyl 1 o n PR 1 2 2010 n PR 0 Allyl 1 o n PR 0 3 2011 n PR 0 Allyl 0 o n PR 4 0 2012 n PR 0 Allyl 0 o n PR 3 1 2013 n PR 0 Allyl 0 o n PR 2 2 2014 n PR 0 Allyl 0 o n PR 1 3 2015 n PR 0 Allyl 0 o n PR 0 4

[0109] [C74] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2016 n PR 2 Ethynyl 2 o n PR 0 0 2017 n PR 2 Ethynyl 1 o n PR 1 0 2018 n PR 2 Ethynyl 1 o n PR 0 1 2019 n PR 2 Ethynyl 0 o n PR 2 0 2020 n PR 2 Ethynyl 0 o n PR 1 1 2021 n PR 2 Ethynyl 0 o n PR 0 2 2022 n PR 1 Ethynyl 3 o n PR 0 0 2023 n PR 1 Ethynyl 2 o n PR 1 0 2024 n PR 1 Ethynyl 2 o n PR 0 1 2025 n PR 1 Ethynyl 1 o n PR 2 0 2026 n PR 1 Ethynyl 1 o n PR 1 1 2027 n PR 1 Ethynyl 1 o n PR 0 2 2028 n PR 1 Ethynyl 0 o n PR 3 0 2029 n PR 1 Ethynyl 0 o n PR 2 1 2030 n PR 1 Ethynyl 0 o n PR 1 2 2031 n PR 1 Ethynyl 0 o n PR 0 3 2032 n PR 0 Ethynyl 4 o n PR 0 0 2033 n PR 0 Ethynyl 3 o n PR 1 0 2034 nPR 0 Ethynyl 3 o n PR 0 1 2035 n PR 0 Ethynyl 2 o n PR 2 0 2036 n PR 0 Ethynyl 2 o n PR 1 1 2037 n PR 0 Ethynyl 2 o n PR 0 2 2038 n PR 0 Ethynyl 1 o n PR 3 0 2039 n PR 0 Ethynyl 1 o n PR 2 1 2040 n PR 0 Ethynyl 1 o n PR 1 2 2041 n PR 0 Ethynyl 1 o n PR 0 3 2042 n PR 0 Ethynyl 0 o n PR 4 0 2043 n PR 0 Ethynyl 0 o n PR 3 1 2044 n PR 0 Ethynyl 0 o n PR 2 2 2045 n PR 0 Ethynyl 0 o n PR 1 3 2046 n PR 0 Ethynyl 0 o n PR 0 4

[0110] [C75] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2047 n PR 2 vinyl 2 o i PR 0 0 2048 n PR 2 vinyl 1 o i PR 1 0 2049 n PR 2 vinyl 1 o i PR 0 1 2050 n PR 2 vinyl 0 o i PR 2 0 2051 n PR 2 vinyl 0 o i PR 1 1 2052 n PR 2 vinyl 0 o i PR 0 2 2053 n PR 1 vinyl 3 o i PR 0 0 2054 n PR 1 vinyl 2 o i PR 1 0 2055 n PR 1 vinyl 2 o i PR 0 1 2056 n PR 1 vinyl 1 o i PR 2 0 2057 n PR 1 vinyl 1 o i PR 1 1 2058 n PR 1 vinyl 1 o i PR 0 2 2059 n PR 1 vinyl 0 o i PR 3 0 2060 n PR 1 vinyl 0 o i PR 2 1 2061 n PR 1 vinyl 0 o i PR 1 2 2062 n PR 1 vinyl 0 o i PR 0 3 2063 n PR 0 vinyl 4 o i PR 0 0 2064 n PR 0 vinyl 3 o i PR 1 0 2065 n PR 0 vinyl 3 o i PR 0 1 2066 n PR 0 vinyl 2 o i PR 2 0 2067 n PR 0 vinyl 2 o i PR 1 1 2068 n PR 0 vinyl 2 o i PR 0 2 2069 n PR 0 vinyl 1 o i PR 3 0 2070 n PR 0 vinyl 1 o i PR 2 1 2071 n PR 0 vinyl 1 o i PR 1 2 2072 n PR 0 vinyl 1 o i PR 0 3 2073 n PR 0 vinyl 0 o i PR 4 0 2074 n PR 0 vinyl 0 o i PR 3 1 2075 n PR 0 vinyl 0 o i PR 2 2 2076 n PR 0 vinyl 0 o i PR 1 3 2077 n PR 0 vinyl 0 o i PR 0 4

[0111] [Chemical 76] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2078 n PR 2 Allyl 2 o i PR 0 0 2079 n PR 2 Allyl 1 o i PR 1 0 2080 n PR 2 Allyl 1 o i PR 0 1 2081 n PR 2 Allyl 0 o i PR 2 0 2082 n PR 2 Allyl 0 o i PR 1 1 2083 n PR 2 Allyl 0 o i PR 0 2 2084 n PR 1 Allyl 3 o i PR 0 0 2085 n PR 1 Allyl 2 o i PR 1 0 2086 n PR 1 Allyl 2 o i PR 0 1 2087 n PR 1 Allyl 1 o i PR 2 0 2088 n PR 1 Allyl 1 o i PR 1 1 2089 n PR 1 Allyl 1 o i PR 0 2 2090 n PR 1 Allyl 0 o i PR 3 0 2091 n PR 1 Allyl 0 o i PR 2 1 2092 n PR 1 Allyl 0 o i PR 1 2 2093 n PR 1 Allyl 0 o i PR 0 3 2094 n PR 0 Allyl 4 o i PR 0 0 2095 n PR 0 Allyl 3 o i PR 1 0 2096 n PR 0 Allyl 3 o i PR 0 1 2097 n PR 0 Allyl 2 o i PR 2 0 2098 n PR 0 Allyl 2 o i PR 1 1 2099 n PR 0 Allyl 2 o i PR 0 2 2100 n PR 0 Allyl 1 o i PR 3 0 2101 n PR 0 Allyl 1 o i PR 2 1 2102 n PR 0 Allyl 1 o i PR 1 2 2103 n PR 0 Allyl 1 o i PR 0 3 2104 n PR 0 Allyl 0 o i PR 4 0 2105 n PR 0 Allyl 0 o i PR 3 1 2106 n PR 0 Allyl 0 o i PR 2 2 2107 n PR 0 Allyl 0 o i PR 1 3 2108 n PR 0 Allyl 0 o i PR 0 4

[0112] [Chemical 77] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2109 n PR 2 Ethynyl 2 o i PR 0 0 2110 n PR 2 Ethynyl 1 o i PR 1 0 2111 n PR 2 Ethynyl 1 o i PR 0 1 2112 n PR 2 Ethynyl 0 o i PR 2 0 2113 n PR 2 Ethynyl 0 o i PR 1 1 2114 n PR 2 Ethynyl 0 o i PR 0 2 2115 n PR 1 Ethynyl 3 o i PR 0 0 2116 n PR 1 Ethynyl 2 o i PR 1 0 2117 n PR 1 Ethynyl 2 o i PR 0 1 2118 n PR 1 Ethynyl 1 o i PR 2 0 2119 n PR 1 Ethynyl 1 o i PR 1 1 2120 n PR 1 Ethynyl 1 o i PR 0 2 2121 n PR 1 Ethynyl 0 o i PR 3 0 2122 n PR 1 Ethynyl 0 o i PR 2 1 2123 n PR 1 Ethynyl 0 o i PR 1 2 2124 n PR 1 Ethynyl 0 o i PR 0 3 2125 n PR 0 Ethynyl 4 o i PR 0 0 2126 n PR 0 Ethynyl 3 o i PR 1 0 2127 n PR 0 Ethynyl 3 o i PR 0 1 2128 n PR 0 Ethynyl 2 o i PR 2 0 2129 n PR 0 Ethynyl 2 o i PR 1 1 2130 n PR 0 Ethynyl 2 o i PR 0 2 2131 n PR 0 Ethynyl 1 o i PR 3 0 2132 n PR 0 Ethynyl 1 o i PR 2 1 2133 n PR 0 Ethynyl 1 o i PR 1 2 2134 n PR 0 Ethynyl 1 o i PR 0 3 2135 n PR 0 Ethynyl 0 o i PR 4 0 2136 n PR 0 Ethynyl 0 o i PR 3 1 2137 n PR 0 Ethynyl 0 o i PR 2 2 2138 n PR 0 Ethynyl 0 o i PR 1 3 2139 n PR 0 Ethynyl 0 o i PR 0 4

[0113] [Chemical 78] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2140 n PR 2 vinyl 2 o n Bu 0 0 2141 n PR 2 vinyl 1 o n Bu 1 0 2142 n PR 2 vinyl 1 o n Bu 0 1 2143 n PR 2 vinyl 0 o n Bu 2 0 2144 n PR 2 vinyl 0 o n Bu 1 1 2145 n PR 2 vinyl 0 o n Bu 0 2 2146 n PR 1 vinyl 3 o n Bu 0 0 2147 n PR 1 vinyl 2 o n Bu 1 0 2148 n PR 1 vinyl 2 o n Bu 0 1 2149 n PR 1 vinyl 1 o n Bu 2 0 2150 n PR 1 vinyl 1 o n Bu 1 1 2151 n PR 1 vinyl 1 o n Bu 0 2 2152 n PR 1 vinyl 0 o n Bu 3 0 2153 n PR 1 vinyl 0 o n Bu 2 1 2154 n PR 1 vinyl 0 o n Bu 1 2 2155 n PR 1 vinyl 0 o n Bu 0 3 2156 n PR 0 vinyl 4 o n Bu 0 0 2157 n PR 0 vinyl 3 o n Bu 1 0 2158 n PR 0 vinyl 3 o n Bu 0 1 2159 n PR 0 vinyl 2 o n Bu 2 0 2160 n PR 0 vinyl 2 o n Bu 1 1 2161 n PR 0 vinyl 2 o n Bu 0 2 2162 n PR 0 vinyl 1 o n Bu 3 0 2163 n PR 0 vinyl 1 o n Bu 2 1 2164 n PR 0 vinyl 1 o n Bu 1 2 2165 n PR 0 vinyl 1 o n Bu 0 3 2166 n PR 0 vinyl 0 o n Bu 4 0 2167 n PR 0 vinyl 0 o n Bu 3 1 2168 n PR 0 vinyl 0 o n Bu 2 2 2169 n PR 0 vinyl 0 o n Bu 1 3 2170 n PR 0 vinyl 0 o n Bu 0 4

[0114] [Chemical 79] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2171 n PR 2 Allyl 2 o n Bu 0 0 2172 n PR 2 Allyl 1 o n Bu 1 0 2173 n PR 2 Allyl 1 o n Bu 0 1 2174 n PR 2 Allyl 0 o n Bu 2 0 2175 n PR 2 Allyl 0 o n Bu 1 1 2176 n PR 2 Allyl 0 o n Bu 0 2 2177 n PR 1 Allyl 3 o n Bu 0 0 2178 n PR 1 Allyl 2 o n Bu 1 0 2179 n PR 1 Allyl 2 o n Bu 0 1 2180 n PR 1 Allyl 1 o n Bu 2 0 2181 n PR 1 Allyl 1 o n Bu 1 1 2182 n PR 1 Allyl 1 o n Bu 0 2 2183 n PR 1 Allyl 0 o n Bu 3 0 2184 n PR 1 Allyl 0 o n Bu 2 1 2185 n PR 1 Allyl 0 o n Bu 1 2 2186 n PR 1 Allyl 0 o n Bu 0 3 2187 n PR 0 Allyl 4 o n Bu 0 0 2188 n PR 0 Allyl 3 o n Bu 1 0 2189 n PR 0 Allyl 3 o n Bu 0 1 2190 n PR 0 Allyl 2 o n Bu 2 0 2191 n PR 0 Allyl 2 o n Bu 1 1 2192 n PR 0 Allyl 2 o n Bu 0 2 2193 n PR 0 Allyl 1 o n Bu 3 0 2194 n PR 0 Allyl 1 o n Bu 2 1 2195 n PR 0 Allyl 1 o n Bu 1 2 2196 n PR 0 Allyl 1 o n Bu 0 3 2197 n PR 0 Allyl 0 o n Bu 4 0 2198 n PR 0 Allyl 0 o n Bu 3 1 2199 n PR 0 Allyl 0 o n Bu 2 2 2200 n PR 0 Allyl 0 o n Bu 1 3 2201 n PR 0 Allyl 0 o n Bu 0 4

[0115] [Chemical 80] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2202 n PR 2 Ethynyl 2 o n Bu 0 0 2203 n PR 2 Ethynyl 1 o n Bu 1 0 2204 n PR 2 Ethynyl 1 o n Bu 0 1 2205 n PR 2 Ethynyl 0 o n Bu 2 0 2206 n PR 2 Ethynyl 0 o n Bu 1 1 2207 n PR 2 Ethynyl 0 o n Bu 0 2 2208 n PR 1 Ethynyl 3 o n Bu 0 0 2209 n PR 1 Ethynyl 2 o n Bu 1 0 2210 n PR 1 Ethynyl 2 o n Bu 0 1 2211 n PR 1 Ethynyl 1 o n Bu 2 0 2212 n PR 1 Ethynyl 1 o n Bu 1 1 2213 n PR 1 Ethynyl 1 o n Bu 0 2 2214 n PR 1 Ethynyl 0 o n Bu 3 0 2215 n PR 1 Ethynyl 0 o n Bu 2 1 2216 n PR 1 Ethynyl 0 o n Bu 1 2 2217 n PR 1 Ethynyl 0 o n Bu 0 3 2218 n PR 0 Ethynyl 4 o n Bu 0 0 2219 n PR 0 Ethynyl 3 o n Bu 1 0 2220 n PR 0 Ethynyl 3 o n Bu 0 1 2221 n PR 0 Ethynyl 2 o n Bu 2 0 2222 n PR 0 Ethynyl 2 o n Bu 1 1 2223 n PR 0 Ethynyl 2 o n Bu 0 2 2224 n PR 0 Ethynyl 1 o n Bu 3 0 2225 n PR 0 Ethynyl 1 o n Bu 2 1 2226 n PR 0 Ethynyl 1 o n Bu 1 2 2227 n PR 0 Ethynyl 1 o n Bu 0 3 2228 n PR 0 Ethynyl 0 o n Bu 4 0 2229 n PR 0 Ethynyl 0 o n Bu 3 1 2230 n PR 0 Ethynyl 0 o n Bu 2 2 2231 n PR 0 Ethynyl 0 o n Bu 1 3 2232 n PR 0 Ethynyl 0 o n Bu 0 4

[0116] [Chemical 81] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2233 n PR 2 vinyl 2 o i Bu 0 0 2234 n PR 2 vinyl 1 o i Bu 1 0 2235 n PR 2 vinyl 1 o iBu 0 1 2236 n PR 2 vinyl 0 o i Bu 2 0 2237 n PR 2 vinyl 0 o i Bu 1 1 2238 n PR 2 vinyl 0 o i Bu 0 2 2239 n PR 1 vinyl 3 o i Bu 0 0 2240 n PR 1 vinyl 2 o i Bu 1 0 2241 n PR 1 vinyl 2 o i Bu 0 1 2242 n PR 1 vinyl 1 o i Bu 2 0 2243 n PR 1 vinyl 1 o i Bu 1 1 2244 n PR 1 vinyl 1 o i Bu 0 2 2245 n PR 1 vinyl 0 o i Bu 3 0 2246 n PR 1 vinyl 0 o i Bu 2 1 2247 n PR 1 vinyl 0 o i Bu 1 2 2248 n PR 1 vinyl 0 o i Bu 0 3 2249 n PR 0 vinyl 4 o i Bu 0 0 2250 n PR 0 vinyl 3 o i Bu 1 0 2251 n PR 0 vinyl 3 o i Bu 0 1 2252 n PR 0 vinyl 2 o i Bu 2 0 2253 n PR 0 vinyl 2 o i Bu 1 1 2254 n PR 0 vinyl 2 o i Bu 0 2 2255 n PR 0 vinyl 1 o i Bu 3 0 2256 n PR 0 vinyl 1 o i Bu 2 1 2257 n PR 0 vinyl 1 o i Bu 1 2 2258 n PR 0 vinyl 1 o i Bu 0 3 2259 n PR 0 vinyl 0 o i Bu 4 0 2260 n PR 0 vinyl 0 o i Bu 3 1 2261 n PR 0 vinyl 0 o i Bu 2 2 2262 n PR 0 vinyl 0 o i Bu 1 3 2263 n PR 0 vinyl 0 o i Bu 0 4

[0117] [Chemical 82] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2264 n PR 2 Allyl 2 o i Bu 0 0 2265 n PR 2 Allyl 1 o i Bu 1 0 2266 n PR 2 Allyl 1 o i Bu 0 1 2267 n PR 2 Allyl 0 o i Bu 2 0 2268 n PR 2 Allyl 0 o i Bu 1 1 2269 n PR 2 Allyl 0 o i Bu 0 2 2270 n PR 1 Allyl 3 o i Bu 0 0 2271 n PR 1 Allyl 2 o i Bu 1 0 2272 n PR 1 Allyl 2 o i Bu 0 1 2273 n PR 1 Allyl 1 o i Bu 2 0 2274 n PR 1 Allyl 1 o i Bu 1 1 2275 n PR 1 Allyl 1 o i Bu 0 2 2276 n PR 1 Allyl 0 o i Bu 3 0 2277 n PR 1 Allyl 0 o i Bu 2 1 2278 n PR 1 Allyl 0 o i Bu 1 2 2279 n PR 1 Allyl 0 o i Bu 0 3 2280 n PR 0 Allyl 4 o i Bu 0 0 2281 n PR 0 Allyl 3 o i Bu 1 0 2282 n PR 0 Allyl 3 o i Bu 0 1 2283 n PR 0 Allyl 2 o i Bu 2 0 2284 n PR 0 Allyl 2 o i Bu 1 1 2285 n PR 0 Allyl 2 o i Bu 0 2 2286 n PR 0 Allyl 1 o i Bu 3 0 2287 n PR 0 Allyl 1 o i Bu 2 1 2288 n PR 0 Allyl 1 o i Bu 1 2 2289 n PR 0 Allyl 1 o i Bu 0 3 2290 n PR 0 Allyl 0 o i Bu 4 0 2291 n PR 0 Allyl 0 o i Bu 3 1 2292 n PR 0 Allyl 0 o i Bu 2 2 2293 n PR 0 Allyl 0 o i Bu 1 3 2294 n PR 0 Allyl 0 o i Bu 0 4

[0118] [Chemical 83] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2295 n PR 2 Ethynyl 2 o i Bu 0 0 2296 n PR 2 Ethynyl 1 o i Bu 1 0 2297 n PR 2 Ethynyl 1 o i Bu 0 1 2298 n PR 2 Ethynyl 0 o i Bu 2 0 2299 n PR 2 Ethynyl 0 o i Bu 1 1 2300 n PR 2 Ethynyl 0 o i Bu 0 2 2301 n PR 1 Ethynyl 3 o i Bu 0 0 2302 n PR 1 Ethynyl 2 o i Bu 1 0 2303 n PR 1 Ethynyl 2 o i Bu 0 1 2304 n PR 1 Ethynyl 1 o i Bu 2 0 2305 n PR 1 Ethynyl 1 o i Bu 1 1 2306 n PR 1 Ethynyl 1 o i Bu 0 2 2307 n PR 1 Ethynyl 0 o i Bu 3 0 2308 n PR 1 Ethynyl 0 o i Bu 2 1 2309 n PR 1 Ethynyl 0 o i Bu 1 2 2310 n PR 1 Ethynyl 0 o i Bu 0 3 2311 n PR 0 Ethynyl 4 o i Bu 0 0 2312 n PR 0 Ethynyl 3 o i Bu 1 0 2313 n PR 0 Ethynyl 3 o i Bu 0 1 2314 n PR 0 Ethynyl 2 o i Bu 2 0 2315 n PR 0 Ethynyl 2 o i Bu 1 1 2316 n PR 0 Ethynyl 2 o i Bu 0 2 2317 n PR 0 Ethynyl 1 o i Bu 3 0 2318 n PR 0 Ethynyl 1 o i Bu 2 1 2319 n PR 0 Ethynyl 1 o i Bu 1 2 2320 n PR 0 Ethynyl 1 o i Bu 0 3 2321 n PR 0 Ethynyl 0 o i Bu 4 0 2322 n PR 0 Ethynyl 0 o i Bu 3 1 2323 n PR 0 Ethynyl 0 o i Bu 2 2 2324 n PR 0 Ethynyl 0 o i Bu 1 3 2325 n PR 0 Ethynyl 0 o i Bu 0 4

[0119] [Chemical 84] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2326 n PR 2 vinyl 2 o sec Bu 0 0 2327 n PR 2 vinyl 1 o sec Bu 1 0 2328 n PR 2 vinyl 1 o sec Bu 0 1 2329 n PR 2 vinyl 0 o sec Bu 2 0 2330 n PR 2 vinyl 0 o sec Bu 1 1 2331 n PR 2 vinyl 0 o sec Bu 0 2 2332 n PR 1 vinyl 3 o sec Bu 0 0 2333 n PR 1 vinyl 2 o sec Bu 1 0 2334 n PR 1 vinyl 2 o sec Bu 0 1 2335 n PR 1 vinyl 1 o sec Bu 2 0 2336 n PR 1 vinyl 1 o sec Bu 1 1 2337 n PR 1 vinyl 1 o sec Bu 0 2 2338 n PR 1 vinyl 0 o sec Bu 3 0 2339 n PR 1 vinyl 0 o sec Bu 2 1 2340 n PR 1 vinyl 0 o sec Bu 1 2 2341 n PR 1 vinyl 0 o sec Bu 0 3 2342 n PR 0 vinyl 4 o sec Bu 0 0 2343 n PR 0 vinyl 3 o sec Bu 1 0 2344 n PR 0 vinyl 3 o sec Bu 0 1 2345 n PR 0 vinyl 2 o sec Bu 2 0 2346 n PR 0 vinyl 2 o sec Bu 1 1 2347 n PR 0 vinyl 2 o sec Bu 0 2 2348 n PR 0 vinyl 1 o sec Bu 3 0 2349 n PR 0 vinyl 1 o sec Bu 2 1 2350 n PR 0 vinyl 1 o sec Bu 1 2 2351 n PR 0 vinyl 1 o sec Bu 0 3 2352 n PR 0 vinyl 0 o sec Bu 4 0 2353 n PR 0 vinyl 0 o sec Bu 3 1 2354 n PR 0 vinyl 0 o sec Bu 2 2 2355 n PR 0 vinyl 0 o sec Bu 1 3 2356 n PR 0 vinyl 0 o sec Bu 0 4

[0120] [Chemical 85] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2357 n PR 2 Allyl 2 o sec Bu 0 0 2358 n PR 2 Allyl 1 o sec Bu 1 0 2359 n PR 2 Allyl 1 o sec Bu 0 1 2360 n PR 2 Allyl 0 o sec Bu 2 0 2361 n PR 2 Allyl 0 o sec Bu 1 1 2362 n PR 2 Allyl 0 o sec Bu 0 2 2363 n PR 1 Allyl 3 o sec Bu 0 0 2364 n PR 1 Allyl 2 o sec Bu 1 0 2365 n PR 1 Allyl 2 o sec Bu 0 1 2366 n PR 1 Allyl 1 o sec Bu 2 0 2367 n PR 1 Allyl 1 o sec Bu 1 1 2368 n PR 1 Allyl 1 o sec Bu 0 2 2369 n PR 1 Allyl 0 o sec Bu 3 0 2370 n PR 1 Allyl 0 o sec Bu 2 1 2371 n PR 1 Allyl 0 o sec Bu 1 2 2372 n PR 1 Allyl 0 o sec Bu 0 3 2373 n PR 0 Allyl 4 o sec Bu 0 0 2374 n PR 0 Allyl 3 o sec Bu 1 0 2375 n PR 0 Allyl 3 o sec Bu 0 1 2376 n PR 0 Allyl 2 o sec Bu 2 0 2377 n PR 0 Allyl 2 o sec Bu 1 1 2378 n PR 0 Allyl 2 o sec Bu 0 2 2379 n PR 0 Allyl 1 o sec Bu 3 0 2380 n PR 0 Allyl 1 o sec Bu 2 1 2381 n PR 0 Allyl 1 osec Bu 1 2 2382 n PR 0 Allyl 1 o sec Bu 0 3 2383 n PR 0 Allyl 0 o sec Bu 4 0 2384 n PR 0 Allyl 0 o sec Bu 3 1 2385 n PR 0 Allyl 0 o sec Bu 2 2 2386 n PR 0 Allyl 0 o sec Bu 1 3 2387 n PR 0 Allyl 0 o sec Bu 0 4

[0121] [Chemical 86] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2388 n PR 2 Ethynyl 2 o sec Bu 0 0 2389 n PR 2 Ethynyl 1 o sec Bu 1 0 2390 n PR 2 Ethynyl 1 o sec Bu 0 1 2391 n PR 2 Ethynyl 0 o sec Bu 2 0 2392 n PR 2 Ethynyl 0 o sec Bu 1 1 2393 n PR 2 Ethynyl 0 o sec Bu 0 2 2394 n PR 1 Ethynyl 3 o sec Bu 0 0 2395 n PR 1 Ethynyl 2 o sec Bu 1 0 2396 n PR 1 Ethynyl 2 o sec Bu 0 1 2397 n PR 1 Ethynyl 1 o sec Bu 2 0 2398 n PR 1 Ethynyl 1 o sec Bu 1 1 2399 n PR 1 Ethynyl 1 o sec Bu 0 2 2400 n PR 1 Ethynyl 0 o sec Bu 3 0 2401 n PR 1 Ethynyl 0 o sec Bu 2 1 2402 n PR 1 Ethynyl 0 o sec Bu 1 2 2403 n PR 1 Ethynyl 0 o sec Bu 0 3 2404 n PR 0 Ethynyl 4 o sec Bu 0 0 2405 n PR 0 Ethynyl 3 o sec Bu 1 0 2406 n PR 0 Ethynyl 3 o sec Bu 0 1 2407 n PR 0 Ethynyl 2 o sec Bu 2 0 2408 n PR 0 Ethynyl 2 o sec Bu 1 1 2409 n PR 0 Ethynyl 2 o sec Bu 0 2 2410 n PR 0 Ethynyl 1 o sec Bu 3 0 2411 n PR 0 Ethynyl 1 o sec Bu 2 1 2412 n PR 0 Ethynyl 1 o sec Bu 1 2 2413 n PR 0 Ethynyl 1 o sec Bu 0 3 2414 n PR 0 Ethynyl 0 o sec Bu 4 0 2415 n PR 0 Ethynyl 0 o sec Bu 3 1 2416 n PR 0 Ethynyl 0 o sec Bu 2 2 2417 n PR 0 Ethynyl 0 o sec Bu 1 3 2418 n PR 0 Ethynyl 0 o sec Bu 0 4

[0122] [Chemical 87] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2419 n PR 2 vinyl 2 o t Bu 0 0 2420 n PR 2 vinyl 1 o t Bu 1 0 2421 n PR 2 vinyl 1 o t Bu 0 1 2422 n PR 2 vinyl 0 o t Bu 2 0 2423 n PR 2 vinyl 0 o t Bu 1 1 2424 n PR 2 vinyl 0 o t Bu 0 2 2425 n PR 1 vinyl 3 o t Bu 0 0 2426 n PR 1 vinyl 2 o t Bu 1 0 2427 n PR 1 vinyl 2 o t Bu 0 1 2428 n PR 1 vinyl 1 o t Bu 2 0 2429 n PR 1 vinyl 1 o t Bu 1 1 2430 n PR 1 vinyl 1 o t Bu 0 2 2431 n PR 1 vinyl 0 o t Bu 3 0 2432 n PR 1 vinyl 0 o t Bu 2 1 2433 n PR 1 vinyl 0 o t Bu 1 2 2434 n PR 1 vinyl 0 o t Bu 0 3 2435 n PR 0 vinyl 4 o t Bu 0 0 2436 n PR 0 vinyl 3 o t Bu 1 0 2437 n PR 0 vinyl 3 o t Bu 0 1 2438 n PR 0 vinyl 2 o t Bu 2 0 2439 nPR 0 vinyl 2 o t Bu 1 1 2440 n PR 0 vinyl 2 o t Bu 0 2 2441 n PR 0 vinyl 1 o t Bu 3 0 2442 n PR 0 vinyl 1 o t Bu 2 1 2443 n PR 0 vinyl 1 o t Bu 1 2 2444 n PR 0 vinyl 1 o t Bu 0 3 2445 n PR 0 vinyl 0 o t Bu 4 0 2446 n PR 0 vinyl 0 o t Bu 3 1 2447 n PR 0 vinyl 0 o t Bu 2 2 2448 n PR 0 vinyl 0 o t Bu 1 3 2449 n PR 0 vinyl 0 o t Bu 0 4

[0123] [Chemical 88] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2450 n PR 2 Allyl 2 o t Bu 0 0 2451 n PR 2 Allyl 1 o t Bu 1 0 2452 n PR 2 Allyl 1 o t Bu 0 1 2453 n PR 2 Allyl 0 o t Bu 2 0 2454 n PR 2 Allyl 0 o t Bu 1 1 2455 n PR 2 Allyl 0 o t Bu 0 2 2456 n PR 1 Allyl 3 o t Bu 0 0 2457 n PR 1 Allyl 2 o t Bu 1 0 2458 n PR 1 Allyl 2 o t Bu 0 1 2459 n PR 1 Allyl 1 o t Bu 2 0 2460 n PR 1 Allyl 1 o t Bu 1 1 2461 n PR 1 Allyl 1 o t Bu 0 2 2462 n PR 1 Allyl 0 o t Bu 3 0 2463 n PR 1 Allyl 0 o t Bu 2 1 2464 n PR 1 Allyl 0 o t Bu 1 2 2465 n PR 1 Allyl 0 o t Bu 0 3 2466 n PR 0 Allyl 4 o t Bu 0 0 2467 n PR 0 Allyl 3 o t Bu 1 0 2468 n PR 0 Allyl 3 o t Bu 0 1 2469 n PR 0 Allyl 2 o t Bu 2 0 2470 n PR 0 Allyl 2 o t Bu 1 1 2471 n PR 0 Allyl 2 o t Bu 0 2 2472 n PR 0 Allyl 1 o t Bu 3 0 2473 n PR 0 Allyl 1 o t Bu 2 1 2474 n PR 0 Allyl 1 o t Bu 1 2 2475 n PR 0 Allyl 1 o t Bu 0 3 2476 n PR 0 Allyl 0 o t Bu 4 0 2477 n PR 0 Allyl 0 o t Bu 3 1 2478 n PR 0 Allyl 0 o t Bu 2 2 2479 n PR 0 Allyl 0 o t Bu 1 3 2480 n PR 0 Allyl 0 o t Bu 0 4

[0124] [Chemical 89] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2481 n PR 2 Ethynyl 2 o t Bu 0 0 2482 n PR 2 Ethynyl 1 o t Bu 1 0 2483 n PR 2 Ethynyl 1 o t Bu 0 1 2484 n PR 2 Ethynyl 0 o t Bu 2 0 2485 n PR 2 Ethynyl 0 o t Bu 1 1 2486 n PR 2 Ethynyl 0 o t Bu 0 2 2487 n PR 1 Ethynyl 3 o t Bu 0 0 2488 n PR 1 Ethynyl 2 o t Bu 1 0 2489 n PR 1 Ethynyl 2 o t Bu 0 1 2490 n PR 1 Ethynyl 1 o t Bu 2 0 2491 n PR 1 Ethynyl 1 o t Bu 1 1 2492 n PR 1 Ethynyl 1 o t Bu 0 2 2493 n PR 1 Ethynyl 0 o t Bu 3 0 2494 n PR 1 Ethynyl 0 o t Bu 2 1 2495 n PR 1 Ethynyl 0 o t Bu 1 2 2496 n PR 1 Ethynyl 0 o t Bu 0 3 2497 n PR 0 Ethynyl 4 o t Bu 0 0 2498 n PR 0 Ethynyl 3 o t Bu 1 0 2499 n PR 0 Ethynyl 3 o t Bu 0 1 2500 n PR 0 Ethynyl 2 o t Bu 2 0 2501 n PR 0 Ethynyl 2 o t Bu 1 1 2502 n PR 0 Ethynyl 2 o t Bu 0 2 2503 n PR 0 Ethynyl 1 o t Bu 3 0 2504 n PR 0 Ethynyl 1 o t Bu 2 1 2505 n PR 0 Ethynyl 1 o t Bu 1 2 2506 n PR 0 Ethynyl 1 o t Bu 0 3 2507 n PR 0 Ethynyl 0 o t Bu 4 0 2508 n PR 0 Ethynyl 0 o t Bu 3 1 2509 n PR 0 Ethynyl 0 o t Bu 2 2 2510 n PR 0 Ethynyl 0 o t Bu 1 3 2511 n PR 0 Ethynyl 0 o t Bu 0 4

[0125] [Chemical 90] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2512 i PR 2 vinyl 2 Oh 0 0 2513 i PR 2 vinyl 1 Oh 1 0 2514 i PR 2 vinyl 1 Oh 0 1 2515 i PR 2 vinyl 0 Oh 2 0 2516 i PR 2 vinyl 0 Oh 1 1 2517 i PR 2 vinyl 0 Oh 0 2 2518 i PR 1 vinyl 3 Oh 0 0 2519 i PR 1 vinyl 2 Oh 1 0 2520 i PR 1 vinyl 2 Oh 0 1 2521 i PR 1 vinyl 1 Oh 2 0 2522 i PR 1 vinyl 1 Oh 1 1 2523 i PR 1 vinyl 1 Oh 0 2 2524 i PR 1 vinyl 0 Oh 3 0 2525 i PR 1 vinyl 0 Oh 2 1 2526 i PR 1 vinyl 0 Oh 1 2 2527 i PR 1 vinyl 0 Oh 0 3 2528 i PR 0 vinyl 4 Oh 0 0 2529 i PR 0 vinyl 3 Oh 1 0 2530 i PR 0 vinyl 3 Oh 0 1 2531 i PR 0 vinyl 2 Oh 2 0 2532 i PR 0 vinyl 2 Oh 1 1 2533 i PR 0 vinyl 2 Oh 0 2 2534 i PR 0 vinyl 1 Oh 3 0 2535 i PR 0 vinyl 1 Oh 2 1 2536 i PR 0 vinyl 1 Oh 1 2 2537 i PR 0 vinyl 1 Oh 0 3 2538 i PR 0 vinyl 0 Oh 4 0 2539 i PR 0 vinyl 0 Oh 3 1 2540 i PR 0 vinyl 0 Oh 2 2 2541 i PR 0 vinyl 0 Oh 1 3 2542 i PR 0 vinyl 0 Oh 0 4

[0126] [Chemical 91] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2543 i PR 2 Allyl 2 Oh 0 0 2544 i PR 2 Allyl 1 Oh 1 0 2545 i PR 2 Allyl 1 Oh 0 1 2546 i PR 2 Allyl 0 Oh 2 0 2547 i PR 2 Allyl 0 Oh 1 1 2548 i PR 2 Allyl 0 Oh 0 2 2549 i PR 1 Allyl 3 Oh 0 0 2550 i PR 1 Allyl 2 Oh 1 0 2551 i PR 1 Allyl 2 Oh 0 1 2552 i PR 1 Allyl 1 Oh 2 0 2553 i PR 1 Allyl 1 Oh 1 1 2554 i PR 1 Allyl 1 Oh 0 2 2555 i PR 1 Allyl 0 Oh 3 0 2556 i PR 1 Allyl 0 Oh 2 1 2557 i PR 1 Allyl 0 Oh 1 2 2558 i PR 1 Allyl 0 Oh 0 3 2559 i PR 0 Allyl 4 Oh 0 0 2560 i PR 0 Allyl 3 Oh 1 0 2561 i PR 0 Allyl 3 Oh 0 1 2562 i PR 0 Allyl 2 Oh 2 0 2563 i PR 0 Allyl 2 Oh 1 1 2564 i PR 0 Allyl 2 Oh 0 2 2565 i PR 0 Allyl 1 Oh 3 0 2566 i PR 0 Allyl 1 Oh 2 1 2567 i PR 0 Allyl 1 Oh 1 2 2568 i PR 0 Allyl 1 Oh 0 3 2569 i PR 0 Allyl 0 Oh 4 0 2570 i PR 0 Allyl 0 Oh 3 1 2571 i PR 0 Allyl 0 Oh 2 2 2572 i PR 0 Allyl 0 Oh 1 3 2573 i PR 0 Allyl 0 Oh 0 4

[0127] [Chemical 92] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2574 i PR 2 Ethynyl 2 Oh 0 0 2575 i PR 2 Ethynyl 1 Oh 1 0 2576 i PR 2 Ethynyl 1 Oh 0 1 2577 i PR 2 Ethynyl 0 Oh 2 0 2578 i PR 2 Ethynyl 0 Oh 1 1 2579 i PR 2 Ethynyl 0 Oh 0 2 2580 i PR 1 Ethynyl 3 Oh 0 0 2581 i PR 1 Ethynyl 2 Oh 1 0 2582 i PR 1 Ethynyl 2 Oh 0 1 2583 i PR 1 Ethynyl 1 Oh 2 0 2584 i PR 1 Ethynyl 1 Oh 1 1 2585 i PR 1 Ethynyl 1 Oh 0 2 2586 i PR 1 Ethynyl 0 Oh 3 0 2587 i PR 1 Ethynyl 0 Oh 2 1 2588 i PR 1 Ethynyl 0 Oh 1 2 2589 i PR 1 Ethynyl 0 Oh 0 3 2590 i PR 0 Ethynyl 4 Oh 0 0 2591 i PR 0 Ethynyl 3 Oh 1 0 2592 i PR 0 Ethynyl 3 Oh 0 1 2593 i PR 0 Ethynyl 2 Oh 2 0 2594 i PR 0 Ethynyl 2 Oh 1 1 2595 i PR 0 Ethynyl 2 Oh 0 2 2596 i PR 0 Ethynyl 1 Oh 3 0 2597 i PR 0 Ethynyl 1 Oh 2 1 2598 i PR 0 Ethynyl 1 Oh 1 2 2599 i PR 0 Ethynyl 1 Oh 0 3 2600 i PR 0 Ethynyl 0 Oh 4 0 2601 i PR 0 Ethynyl 0 Oh 3 1 2602 i PR 0 Ethynyl 0 Oh 2 2 2603 i PR 0 Ethynyl 0 Oh 1 3 2604 i PR 0 Ethynyl 0 Oh 0 4

[0128] [Chemical 93] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2605 i PR 2 vinyl 2 OMe 0 0 2606 i PR 2 vinyl 1 OMe 1 0 2607 i PR 2 vinyl 1 OMe 0 1 2608 i PR 2 vinyl 0 OMe 2 0 2609 i PR 2 vinyl 0 OMe 1 1 2610 i PR 2 vinyl 0 OMe 0 2 2611 i PR 1 vinyl 3 OMe 0 0 2612 i PR 1 vinyl 2 OMe 1 0 2613 i PR 1 vinyl 2 OMe 0 1 2614 i PR 1 vinyl 1 OMe 2 0 2615 i PR 1 vinyl 1 OMe 1 1 2616 i PR 1 vinyl 1 OMe 0 2 2617 i PR 1 vinyl 0 OMe 3 0 2618 i PR 1 vinyl 0 OMe 2 1 2619 i PR 1 vinyl 0 OMe 1 2 2620 i PR 1 vinyl 0 OMe 0 3 2621 i PR 0 vinyl 4 OMe 0 0 2622 i PR 0 vinyl 3 OMe 1 0 2623 i PR 0 vinyl 3 OMe 0 1 2624 i PR 0 vinyl 2 OMe 2 0 2625 i PR 0 vinyl 2 OMe 1 1 2626 i PR 0 vinyl 2 OMe 0 2 2627 i PR 0 vinyl 1 OMe 3 0 2628 i PR 0 vinyl 1 OMe 2 1 2629 i PR 0 vinyl 1 OMe 1 2 2630 i PR 0 vinyl 1 OMe 0 3 2631 i PR 0 vinyl 0 OMe 4 0 2632 i PR 0 vinyl 0 OMe 3 1 2633 i PR 0 vinyl 0 OMe 2 2 2634 i PR 0 vinyl 0 OMe 1 3 2635 i PR 0 vinyl 0 OMe 0 4

[0129] [Chemical 94] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2636 i PR 2 Allyl 2 OMe 0 0 2637 i PR 2 Allyl 1 OMe 1 0 2638 i PR 2 Allyl 1 OMe 0 1 2639 i PR 2 Allyl 0 OMe 2 0 2640 i PR 2 Allyl 0 OMe 1 1 2641 i PR 2 Allyl 0 OMe 0 2 2642 i PR 1 Allyl 3 OMe 0 0 2643 i PR 1 Allyl 2 OMe 1 0 2644 i PR 1 Allyl 2 OMe 0 1 2645 i PR 1 Allyl 1 OMe 2 0 2646 i PR 1 Allyl 1 OMe 1 1 2647 i PR 1 Allyl 1 OMe 0 2 2648 i PR 1 Allyl 0 OMe 3 0 2649 i PR 1 Allyl 0 OMe 2 1 2650 i PR 1 Allyl 0 OMe 1 2 2651 i PR 1 Allyl 0 OMe 0 3 2652 i PR 0 Allyl 4 OMe 0 0 2653 i PR 0 Allyl 3 OMe 1 0 2654 i PR 0 Allyl 3 OMe 0 1 2655 i PR 0 Allyl 2 OMe 2 0 2656 i PR 0 Allyl 2 OMe 1 1 2657 i PR 0 Allyl 2 OMe 0 2 2658 i PR 0 Allyl 1 OMe 3 0 2659 i PR 0 Allyl 1 OMe 2 1 2660 i PR 0 Allyl 1 OMe 1 2 2661 i PR 0 Allyl 1 OMe 0 3 2662 i PR 0 Allyl 0 OMe 4 0 2663 i PR 0 Allyl 0 OMe 3 1 2664 i PR 0 Allyl 0 OMe 2 2 2665 i PR 0 Allyl 0 OMe 1 3 2666 i PR 0 Allyl 0 OMe 0 4

[0130] [Chemical 95] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2667 i PR 2 Ethynyl 2 OMe 0 0 2668 i PR 2 Ethynyl 1 OMe 1 0 2669 i PR 2 Ethynyl 1 OMe 0 1 2670 i PR 2 Ethynyl 0 OMe 2 0 2671 i PR 2 Ethynyl 0 OMe 1 1 2672 i PR 2 Ethynyl 0 OMe 0 2 2673 i PR 1 Ethynyl 3 OMe 0 0 2674 i PR 1 Ethynyl 2 OMe 1 0 2675 i PR 1 Ethynyl 2 OMe 0 1 2676 i PR 1 Ethynyl 1 OMe 2 0 2677 i PR 1 Ethynyl 1 OMe 1 1 2678 i PR 1 Ethynyl 1 OMe 0 2 2679 i PR 1 Ethynyl 0 OMe 3 0 2680 i PR 1 Ethynyl 0 OMe 2 1 2681 i PR 1 Ethynyl 0 OMe 1 2 2682 i PR 1 Ethynyl 0 OMe 0 3 2683 i PR 0 Ethynyl 4 OMe 0 0 2684 i PR 0 Ethynyl 3 OMe 1 0 2685 i PR 0 Ethynyl 3 OMe 0 1 2686 i PR 0 Ethynyl 2 OMe 2 0 2687 i PR 0 Ethynyl 2 OMe 1 1 2688 i PR 0 Ethynyl 2 OMe 0 2 2689 i PR 0 Ethynyl 1 OMe 3 0 2690 i PR 0 Ethynyl 1 OMe 2 1 2691 i PR 0 Ethynyl 1 OMe 1 2 2692 i PR 0 Ethynyl 1 OMe 0 3 2693 i PR 0 Ethynyl 0 OMe 4 0 2694 i PR 0 Ethynyl 0 OMe 3 1 2695 i PR 0 Ethynyl 0 OMe 2 2 2696 i PR 0 Ethynyl 0 OMe 1 3 2697 i PR 0 Ethynyl 0 OMe 0 4

[0131] [Chemical 96] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2698 i PR 2 vinyl 2 OEt 0 0 2699 i PR 2 vinyl 1 OEt 1 0 2700 i PR 2 vinyl 1 OEt 0 1 2701 i PR 2 vinyl 0 OEt 2 0 2702 i PR 2 vinyl 0 OEt 1 1 2703 i PR 2 vinyl 0 OEt 0 2 2704 i PR 1 vinyl 3 OEt 0 0 2705 i PR 1 vinyl 2 OEt 1 0 2706 i PR 1 vinyl 2 OEt 0 1 2707 i PR 1 vinyl 1 OEt 2 0 2708 i PR 1 vinyl 1 OEt 1 1 2709 i PR 1 vinyl 1 OEt 0 2 2710 i PR 1 vinyl 0 OEt 3 0 2711 i PR 1 vinyl 0 OEt 2 1 2712 i PR 1 vinyl 0 OEt 1 2 2713 i PR 1 vinyl 0 OEt 0 3 2714 i PR 0 vinyl 4 OEt 0 0 2715 i PR 0 vinyl 3 OEt 1 0 2716 i PR 0 vinyl 3 OEt 0 1 2717 i PR 0 vinyl 2 OEt 2 0 2718 i PR 0 vinyl 2 OEt 1 1 2719 i PR 0 vinyl 2 OEt 0 2 2720 i PR 0 vinyl 1 OEt 3 0 2721 i PR 0 vinyl 1 OEt 2 1 2722 i PR 0 vinyl 1 OEt 1 2 2723 i PR 0 vinyl 1 OEt 0 3 2724 i PR 0 vinyl 0 OEt 4 0 2725 i PR 0 vinyl 0 OEt 3 1 2726 i PR 0 vinyl 0 OEt 2 2 2727 i PR 0 vinyl 0 OEt 1 3 2728 i PR 0 vinyl 0 OEt 0 4

[0132] [Chemical 97] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2729 i PR 2 Allyl 2 OEt 0 0 2730 i PR 2 Allyl 1 OEt 1 0 2731 i PR 2 Allyl 1 OEt 0 1 2732 i PR 2 Allyl 0 OEt 2 0 2733 i PR 2 Allyl 0 OEt 1 1 2734 i PR 2 Allyl 0 OEt 0 2 2735 i PR 1 Allyl 3 OEt 0 0 2736 i PR 1 Allyl 2 OEt 1 0 2737 i PR 1 Allyl 2 OEt 0 1 2738 i PR 1 Allyl 1 OEt 2 0 2739 i PR 1 Allyl 1 OEt 1 1 2740 i PR 1 Allyl 1 OEt 0 2 2741 i PR 1 Allyl 0 OEt 3 0 2742 i PR 1 Allyl 0 OEt 2 1 2743 i PR 1 Allyl 0 OEt 1 2 2744 i PR 1 Allyl 0 OEt 0 3 2745 i PR 0 Allyl 4 OEt 0 0 2746 i PR 0 Allyl 3 OEt 1 0 2747 i PR 0 Allyl 3 OEt 0 1 2748 i PR 0 Allyl 2 OEt 2 0 2749 i PR 0 Allyl 2 OEt 1 1 2750 i PR 0 Allyl 2 OEt 0 2 2751 i PR 0 Allyl 1 OEt 3 0 2752 i PR 0 Allyl 1 OEt 2 1 2753 i PR 0 Allyl 1 OEt 1 2 2754 i PR 0 Allyl 1 OEt 0 3 2755 i PR 0 Allyl 0 OEt 4 0 2756 i PR 0 Allyl 0 OEt 3 1 2757 i PR 0 Allyl 0 OEt 2 2 2758 i PR 0 Allyl 0 OEt 1 3 2759 i PR 0 Allyl 0 OEt 0 4

[0133] [Chemical 98] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2760 i PR 2 Ethynyl 2 OEt 0 0 2761 i PR 2 Ethynyl 1 OEt 1 0 2762 i PR 2 Ethynyl 1 OEt 0 1 2763 i PR 2 Ethynyl 0 OEt 2 0 2764 i PR 2 Ethynyl 0 OEt 1 1 2765 i PR 2 Ethynyl 0 OEt 0 2 2766 i PR 1 Ethynyl 3 OEt 0 0 2767 i PR 1 Ethynyl 2 OEt 1 0 2768 i PR 1 Ethynyl 2 OEt 0 1 2769 i PR 1 Ethynyl 1 OEt 2 0 2770 i PR 1 Ethynyl 1 OEt 1 1 2771 i PR 1 Ethynyl 1 OEt 0 2 2772 i PR 1 Ethynyl 0 OEt 3 0 2773 i PR 1 Ethynyl 0 OEt 2 1 2774 i PR 1 Ethynyl 0 OEt 1 2 2775 i PR 1 Ethynyl 0 OEt 0 3 2776 i PR 0 Ethynyl 4 OEt 0 0 2777 i PR 0 Ethynyl 3 OEt 1 0 2778 i PR 0 Ethynyl 3 OEt 0 1 2779 i PR 0 Ethynyl 2 OEt 2 0 2780 i PR 0 Ethynyl 2 OEt 1 1 2781 i PR 0 Ethynyl 2 OEt 0 2 2782 i PR 0 Ethynyl 1 OEt 3 0 2783 i PR 0 Ethynyl 1 OEt 2 1 2784 i PR 0 Ethynyl 1 OEt 1 2 2785 i PR 0 Ethynyl 1 OEt 0 3 2786 i PR 0 Ethynyl 0 OEt 4 0 2787 i PR 0 Ethynyl 0 OEt 3 1 2788 i PR 0 Ethynyl 0 OEt 2 2 2789 i PR 0 Ethynyl 0 OEt 1 3 2790 i PR 0 Ethynyl 0 OEt 0 4

[0134] [Chemical 99] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2791 i PR 2 vinyl 2 o n PR 0 0 2792 i PR 2 vinyl 1 o n PR 1 0 2793 i PR 2 vinyl 1 o n PR 0 1 2794 i PR 2 vinyl 0 o n PR 2 0 2795 i PR 2 vinyl 0 o n PR 1 1 2796 i PR 2 vinyl 0 o n PR 0 2 2797 i PR 1 vinyl 3 o n PR 0 0 2798 i PR 1 vinyl 2 o n PR 1 0 2799 i PR 1 vinyl 2 o n PR 0 1 2800 i PR 1 vinyl 1 o n PR 2 0 2801 i PR 1 vinyl 1 o n PR 1 1 2802 i PR 1 vinyl 1 o n PR 0 2 2803 i PR 1 vinyl 0 o n PR 3 0 2804 i PR 1 vinyl 0 o n PR 2 1 2805 i PR 1 vinyl 0 o n PR 1 2 2806 i PR 1 vinyl 0 o n PR 0 3 2807 i PR 0 vinyl 4 o n PR 0 0 2808 i PR 0 vinyl 3 o n PR 1 0 2809 i PR 0 vinyl 3 o nPR 0 1 2810 i PR 0 vinyl 2 o n PR 2 0 2811 i PR 0 vinyl 2 o n PR 1 1 2812 i PR 0 vinyl 2 o n PR 0 2 2813 i PR 0 vinyl 1 o n PR 3 0 2814 i PR 0 vinyl 1 o n PR 2 1 2815 i PR 0 vinyl 1 o n PR 1 2 2816 i PR 0 vinyl 1 o n PR 0 3 2817 i PR 0 vinyl 0 o n PR 4 0 2818 i PR 0 vinyl 0 o n PR 3 1 2819 i PR 0 vinyl 0 o n PR 2 2 2820 i PR 0 vinyl 0 o n PR 1 3 2821 i PR 0 vinyl 0 o n PR 0 4

[0135] [Chem. 100] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2822 i PR 2 Allyl 2 o n PR 0 0 2823 i PR 2 Allyl 1 o n PR 1 0 2824 i PR 2 Allyl 1 o n PR 0 1 2825 i PR 2 Allyl 0 o n PR 2 0 2826 i PR 2 Allyl 0 o n PR 1 1 2827 i PR 2 Allyl 0 o n PR 0 2 2828 i PR 1 Allyl 3 o n PR 0 0 2829 i PR 1 Allyl 2 o n PR 1 0 2830 i PR 1 Allyl 2 o n PR 0 1 2831 i PR 1 Allyl 1 o n PR 2 0 2832 i PR 1 Allyl 1 o n PR 1 1 2833 i PR 1 Allyl 1 o n PR 0 2 2834 i PR 1 Allyl 0 o n PR 3 0 2835 i PR 1 Allyl 0 o n PR 2 1 2836 i PR 1 Allyl 0 o n PR 1 2 2837 i PR 1 Allyl 0 o n PR 0 3 2838 i PR 0 Allyl 4 o n PR 0 0 2839 i PR 0 Allyl 3 o n PR 1 0 2840 i PR 0 Allyl 3 o n PR 0 1 2841 i PR 0 Allyl 2 o n PR 2 0 2842 i PR 0 Allyl 2 o n PR 1 1 2843 i PR 0 Allyl 2 o n PR 0 2 2844 i PR 0 Allyl 1 o n PR 3 0 2845 i PR 0 Allyl 1 o n PR 2 1 2846 i PR 0 Allyl 1 o n PR 1 2 2847 i PR 0 Allyl 1 o n PR 0 3 2848 i PR 0 Allyl 0 o n PR 4 0 2849 i PR 0 Allyl 0 o n PR 3 1 2850 i PR 0 Allyl 0 o n PR 2 2 2851 i PR 0 Allyl 0 o n PR 1 3 2852 i PR 0 Allyl 0 o n PR 0 4

[0136] [Chemical 101] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2853 i PR 2 Ethynyl 2 o n PR 0 0 2854 i PR 2 Ethynyl 1 o n PR 1 0 2855 i PR 2 Ethynyl 1 o n PR 0 1 2856 i PR 2 Ethynyl 0 o n PR 2 0 2857 i PR 2 Ethynyl 0 o n PR 1 1 2858 i PR 2 Ethynyl 0 o n PR 0 2 2859 i PR 1 Ethynyl 3 o n PR 0 0 2860 i PR 1 Ethynyl 2 o n PR 1 0 2861 i PR 1 Ethynyl 2 o n PR 0 1 2862 i PR 1 Ethynyl 1 o n PR 2 0 2863 i PR 1 Ethynyl 1 o n PR 1 1 2864 i PR 1 Ethynyl 1 o n PR 0 2 2865 i PR 1 Ethynyl 0 o n PR 3 0 2866 i PR 1 Ethynyl 0 o n PR 2 1 2867 i PR 1 Ethynyl 0 o n PR 1 2 2868 i PR 1 Ethynyl 0 o n PR 0 3 2869 i PR 0 Ethynyl 4 o n PR 0 0 2870 i PR 0 Ethynyl 3 o n PR 1 0 2871 i PR 0 Ethynyl 3 o n PR 0 1 2872 i PR 0 Ethynyl 2 o n PR 2 0 2873 i PR 0 Ethynyl 2 o n PR 1 1 2874 i PR 0 Ethynyl 2 o n PR 0 2 2875 i PR 0 Ethynyl 1 o n PR 3 0 2876 i PR 0 Ethynyl 1 o n PR 2 1 2877 i PR 0 Ethynyl 1 o n PR 1 2 2878 i PR 0 Ethynyl 1 o n PR 0 3 2879 i PR 0 Ethynyl 0 o n PR 4 0 2880 i PR 0 Ethynyl 0 o n PR 3 1 2881 i PR 0 Ethynyl 0 o n PR 2 2 2882 i PR 0 Ethynyl 0 o n PR 1 3 2883 i PR 0 Ethynyl 0 o n PR 0 4

[0137] [Chemical 102] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2884 i PR 2 vinyl 2 o i PR 0 0 2885 i PR 2 vinyl 1 o i PR 1 0 2886 i PR 2 vinyl 1 o i PR 0 1 2887 i PR 2 vinyl 0 o i PR 2 0 2888 i PR 2 vinyl 0 o i PR 1 1 2889 i PR 2 vinyl 0 o i PR 0 2 2890 i PR 1 vinyl 3 o i PR 0 0 2891 i PR 1 vinyl 2 o i PR 1 0 2892 i PR 1 vinyl 2 o i PR 0 1 2893 i PR 1 vinyl 1 o i PR 2 0 2894 i PR 1 vinyl 1 o i PR 1 1 2895 i PR 1 vinyl 1 o i PR 0 2 2896 i PR 1 vinyl 0 o i PR 3 0 2897 i PR 1 vinyl 0 o i PR 2 1 2898 i PR 1 vinyl 0 o i PR 1 2 2899 i PR 1 vinyl 0 o i PR 0 3 2900 i PR 0 vinyl 4 o i PR 0 0 2901 i PR 0 vinyl 3 o i PR 1 0 2902 i PR 0 vinyl 3 o i PR 0 1 2903 i PR 0 vinyl 2 o i PR 2 0 2904 i PR 0 vinyl 2 o i PR 1 1 2905 i PR 0 vinyl 2 o i PR 0 2 2906 i PR 0 vinyl 1 o i PR 3 0 2907 i PR 0 vinyl 1 o i PR 2 1 2908 i PR 0 vinyl 1 o i PR 1 2 2909 i PR 0 vinyl 1 o i PR 0 3 2910 i PR 0 vinyl 0 o i PR 4 0 2911 i PR 0 vinyl 0 o i PR 3 1 2912 i PR 0 vinyl 0 o i PR 2 2 2913 i PR 0 vinyl 0 o i PR 1 3 2914 i PR 0 vinyl 0 o i PR 0 4

[0138] [Chemical 103] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2915 i PR 2 Allyl 2 o i PR 0 0 2916 i PR 2 Allyl 1 o i PR 1 0 2917 i PR 2 Allyl 1 o i PR 0 1 2918 i PR 2 Allyl 0 o i PR 2 0 2919 i PR 2 Allyl 0 o i PR 1 1 2920 i PR 2 Allyl 0 o i PR 0 2 2921 i PR 1 Allyl 3 o i PR 0 0 2922 i PR 1 Allyl 2 o i PR 1 0 2923 i PR 1 Allyl 2 o i PR 0 1 2924 i PR 1 Allyl 1 o i PR 2 0 2925 i PR 1 Allyl 1 o i PR 1 1 2926 i PR 1 Allyl 1 o i PR 0 2 2927 i PR 1 Allyl 0 o i PR 3 0 2928 i PR 1 Allyl 0 o i PR 2 1 2929 i PR 1 Allyl 0 o i PR 1 2 2930 i PR 1 Allyl 0 o i PR 0 3 2931 i PR 0 Allyl 4 o i PR 0 0 2932 i PR 0 Allyl 3 o i PR 1 0 2933 i PR 0 Allyl 3 o i PR 0 1 2934 i PR 0 Allyl 2 o i PR 2 0 2935 i PR 0 Allyl 2 o i PR 1 1 2936 i PR 0 Allyl 2 o i PR 0 2 2937 i PR 0 Allyl 1 o i PR 3 0 2938 i PR 0 Allyl 1 o i PR 2 1 2939 i PR 0 Allyl 1 o i PR 1 2 2940 i PR 0 Allyl 1 o i PR 0 3 2941 i PR 0 Allyl 0 o i PR 4 0 2942 i PR 0 Allyl 0 o i PR 3 1 2943 i PR 0 Allyl 0 o i PR 2 2 2944 i PR 0 Allyl 0 o i PR 1 3 2945 i PR 0 Allyl 0 o i PR 0 4

[0139] [Chemical 104] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2946 i PR 2 Ethynyl 2 o i PR 0 0 2947 i PR 2 Ethynyl 1 o i PR 1 0 2948 i PR 2 Ethynyl 1 o i PR 0 1 2949 i PR 2 Ethynyl 0 o i PR 2 0 2950 i PR 2 Ethynyl 0 o i PR 1 1 2951 i PR 2 Ethynyl 0 o i PR 0 2 2952 i PR 1 Ethynyl 3 o i PR 0 0 2953 i PR 1 Ethynyl 2 o i PR 1 0 2954 i PR 1 Ethynyl 2 o i PR 0 1 2955 i PR 1 Ethynyl 1 o i PR 2 0 2956 i PR 1 Ethynyl 1 o i PR 1 1 2957 i PR 1 Ethynyl 1 o i PR 0 2 2958 i PR 1 Ethynyl 0 o i PR 3 0 2959 i PR 1 Ethynyl 0 o i PR 2 1 2960 i PR 1 Ethynyl 0 o i PR 1 2 2961 i PR 1 Ethynyl 0 o i PR 0 3 2962 i PR 0 Ethynyl 4 o i PR 0 0 2963 i PR 0 Ethynyl 3 o i PR 1 0 2964 i PR 0 Ethynyl 3 o i PR 0 1 2965 i PR 0 Ethynyl 2 o i PR 2 0 2966 i PR 0 Ethynyl 2 o i PR 1 1 2967 i PR 0 Ethynyl 2 o i PR 0 2 2968 i PR 0 Ethynyl 1 o i PR 3 0 2969 i PR 0 Ethynyl 1 o i PR 2 1 2970 i PR 0 Ethynyl 1 o i PR 1 2 2971 i PR 0 Ethynyl 1 o i PR 0 3 2972 i PR 0 Ethynyl 0 o i PR 4 0 2973 i PR 0 Ethynyl 0 o i PR 3 1 2974 i PR 0 Ethynyl 0 o i PR 2 2 2975 i PR 0 Ethynyl 0 o i PR 1 3 2976 i PR 0 Ethynyl 0 o i PR 0 4

[0140] [Chemical 105] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 2977 i PR 2 vinyl 2 o n Bu 0 0 2978 i PR 2 vinyl 1 o n Bu 1 0 2979 i PR 2 vinyl 1 o n Bu 0 1 2980 i PR 2 vinyl 0 o n Bu 2 0 2981 i PR 2 vinyl 0 o n Bu 1 1 2982 i PR 2 vinyl 0 o n Bu 0 2 2983 i PR 1 vinyl 3 o n Bu 0 0 2984 i PR 1 vinyl 2 o n Bu 1 0 2985 i PR 1 vinyl 2 o n Bu 0 1 2986 i PR 1 vinyl 1 o n Bu 2 0 2987 i PR 1 vinyl 1 o n Bu 1 1 2988 i PR 1 vinyl 1 o n Bu 0 2 2989 i PR 1 vinyl 0 o n Bu 3 0 2990 i PR 1 vinyl 0 o n Bu 2 1 2991 i PR 1 vinyl 0 o n Bu 1 2 2992 i PR 1 vinyl 0 o n Bu 0 3 2993 i PR 0 vinyl 4 o n Bu 0 0 2994 i PR 0 vinyl 3 o n Bu 1 0 2995 i PR 0 vinyl 3 o n Bu 0 1 2996 i PR 0 vinyl 2 o n Bu 2 0 2997 i PR 0 vinyl 2 o n Bu 1 1 2998 i PR 0 vinyl 2 o n Bu 0 2 2999 i PR 0 vinyl 1 o n Bu 3 0 3000 i PR 0 vinyl 1 o n Bu 2 1 3001 i PR 0 vinyl 1 o n Bu 1 2 3002 i PR 0 vinyl 1 o n Bu 0 3 3003 i PR 0 vinyl 0 o n Bu 4 0 3004 i PR 0 vinyl 0 o n Bu 3 1 3005 i PR 0 vinyl 0 o n Bu 2 2 3006 i PR 0 vinyl 0 o n Bu 1 3 3007 i PR 0 vinyl 0 o n Bu 0 4

[0141] [Chemical 106] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3008 i PR 2 Allyl 2 o n Bu 0 0 3009 i PR 2 Allyl 1 o n Bu 1 0 3010 i PR 2 Allyl 1 o n Bu 0 1 3011 i PR 2 Allyl 0 o n Bu 2 0 3012 i PR 2 Allyl 0 o n Bu 1 1 3013 i PR 2 Allyl 0 o n Bu 0 2 3014 i PR 1 Allyl 3 o n Bu 0 0 3015 i PR 1 Allyl 2 o n Bu 1 0 3016 i PR 1 Allyl 2 o n Bu 0 1 3017 i PR 1 Allyl 1 o n Bu 2 0 3018 i PR 1 Allyl 1 o n Bu 1 1 3019 i PR 1 Allyl 1 o n Bu 0 2 3020 i PR 1 Allyl 0 o n Bu 3 0 3021 i PR 1 Allyl 0 o n Bu 2 1 3022 i PR 1 Allyl 0 o n Bu 1 2 3023 i PR 1 Allyl 0 o n Bu 0 3 3024 i PR 0 Allyl 4 o n Bu 0 0 3025 i PR 0 Allyl 3 o n Bu 1 0 3026 i PR 0 Allyl 3 o n Bu 0 1 3027 i PR 0 Allyl 2 o n Bu 2 0 3028 i PR 0 Allyl 2 o n Bu 1 1 3029 i PR 0 Allyl 2 o n Bu 0 2 3030 i PR 0 Allyl 1 o n Bu 3 0 3031 i PR 0 Allyl 1 o n Bu 2 1 3032 i PR 0 Allyl 1 o n Bu 1 2 3033 i PR 0 Allyl 1 o n Bu 0 3 3034 i PR 0 Allyl 0 o n Bu 4 0 3035 i PR 0 Allyl 0 o n Bu 3 1 3036 i PR 0 Allyl 0 o n Bu 2 2 3037 i PR 0 Allyl 0 o n Bu 1 3 3038 i PR 0 Allyl 0 o n Bu 0 4

[0142] [Chemical 107] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3039 i PR 2 Ethynyl 2 o n Bu 0 0 3040 i PR 2 Ethynyl 1 o n Bu 1 0 3041 i PR 2 Ethynyl 1 o n Bu 0 1 3042 i PR 2 Ethynyl 0 o n Bu 2 0 3043 i PR 2 Ethynyl 0 o n Bu 1 1 3044 i PR 2 Ethynyl 0 o n Bu 0 2 3045 i PR 1 Ethynyl 3 o n Bu 0 0 3046 i PR 1 Ethynyl 2 o n Bu 1 0 3047 i PR 1 Ethynyl 2 o n Bu 0 1 3048 i PR 1 Ethynyl 1 o n Bu 2 0 3049 i PR 1 Ethynyl 1 o n Bu 1 1 3050 i PR 1 Ethynyl 1 o n Bu 0 2 3051 i PR 1 Ethynyl 0 o n Bu 3 0 3052 i PR 1 Ethynyl 0 o n Bu 2 1 3053 i PR 1 Ethynyl 0 o n Bu 1 2 3054 i PR 1 Ethynyl 0 o n Bu 0 3 3055 i PR 0 Ethynyl 4 o n Bu 0 0 3056 i PR 0 Ethynyl 3 o n Bu 1 0 3057 i PR 0 Ethynyl 3 o n Bu 0 1 3058 i PR 0 Ethynyl 2 o n Bu 2 0 3059 i PR 0 Ethynyl 2 o n Bu 1 1 3060 i PR 0 Ethynyl 2 o n Bu 0 2 3061 i PR 0 Ethynyl 1 o n Bu 3 0 3062 i PR 0 Ethynyl 1 o n Bu 2 1 3063 i PR 0 Ethynyl 1 o n Bu 1 2 3064 i PR 0 Ethynyl 1 o n Bu 0 3 3065 i PR 0 Ethynyl 0 o n Bu 4 0 3066 i PR 0 Ethynyl 0 o n Bu 3 1 3067 i PR 0 Ethynyl 0 o n Bu 2 2 3068 i PR 0 Ethynyl 0 o n Bu 1 3 3069 i PR 0 Ethynyl 0 o n Bu 0 4

[0143] [Chemical 108] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3070 i PR 2 vinyl 2 o i Bu 0 0 3071 i PR 2 vinyl 1 o i Bu 1 0 3072 i PR 2 vinyl 1 o i Bu 0 1 3073 i PR 2 vinyl 0 o i Bu 2 0 3074 i PR 2 vinyl 0 o i Bu 1 1 3075 i PR 2 vinyl 0 o i Bu 0 2 3076 i PR 1 vinyl 3 o i Bu 0 0 3077 i PR 1 vinyl 2 o i Bu 1 0 3078 i PR 1 vinyl 2 o i Bu 0 1 3079 i PR 1 vinyl 1 o i Bu 2 0 3080 i PR 1 vinyl 1 o i Bu 1 1 3081 i PR 1 vinyl 1 o i Bu 0 2 3082 i PR 1 vinyl 0 o i Bu 3 0 3083 i PR 1 vinyl 0 o i Bu 2 1 3084 i PR 1 vinyl 0 o i Bu 1 2 3085 i PR 1 vinyl 0 o i Bu 0 3 3086 i PR 0 vinyl 4 o i Bu 0 0 3087 i PR 0 vinyl 3 o i Bu 1 0 3088 i PR 0 vinyl 3 o i Bu 0 1 3089 i PR 0 vinyl 2 o i Bu 2 0 3090 i PR 0 vinyl 2 o i Bu 1 1 3091 i PR 0 vinyl 2 o i Bu 0 2 3092 i PR 0 vinyl 1 o i Bu 3 0 3093 i PR 0 vinyl 1 o i Bu 2 1 3094 i PR 0 vinyl 1 o i Bu 1 2 3095 i PR 0 vinyl 1 o i Bu 0 3 3096 i PR 0 vinyl 0 o i Bu 4 0 3097 i PR 0 vinyl 0 o i Bu 3 1 3098 i PR 0 vinyl 0 o i Bu 2 2 3099 i PR 0 vinyl 0 o i Bu 1 3 3100 i PR 0 vinyl 0 o i Bu 0 4

[0144] [Chemical 109] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3101 i PR 2 Allyl 2 o i Bu 0 0 3102 i PR 2 Allyl 1 o i Bu 1 0 3103 i PR 2 Allyl 1 o i Bu 0 1 3104 i PR 2 Allyl 0 o i Bu 2 0 3105 i PR 2 Allyl 0 o i Bu 1 1 3106 i PR 2 Allyl 0 o i Bu 0 2 3107 i PR 1 Allyl 3 o i Bu 0 0 3108 i PR 1 Allyl 2 o i Bu 1 0 3109 i PR 1 Allyl 2 o i Bu 0 1 3110 i PR 1 Allyl 1 o i Bu 2 0 3111 i PR 1 Allyl 1 o i Bu 1 1 3112 i PR 1 Allyl 1 o i Bu 0 2 3113 i PR 1 Allyl 0 o i Bu 3 0 3114 i PR 1 Allyl 0 o i Bu 2 1 3115 i PR 1 Allyl 0 o i Bu 1 2 3116 i PR 1 Allyl 0 o i Bu 0 3 3117 i PR 0 Allyl 4 o i Bu 0 0 3118 i PR 0 Allyl 3 o i Bu 1 0 3119 i PR 0 Allyl 3 o i Bu 0 1 3120 i PR 0 Allyl 2 o i Bu 2 0 3121 i PR 0 Allyl 2 o i Bu 1 1 3122 i PR 0 Allyl 2 o i Bu 0 2 3123 i PR 0 Allyl 1 o i Bu 3 0 3124 i PR 0 Allyl 1 o i Bu 2 1 3125 i PR 0 Allyl 1 o i Bu 1 2 3126 i PR 0 Allyl 1 o i Bu 0 3 3127 i PR 0 Allyl 0 o i Bu 4 0 3128 i PR 0 Allyl 0 o i Bu 3 1 3129 i PR 0 Allyl 0 o i Bu 2 2 3130 i PR 0 Allyl 0 o i Bu 1 3 3131 i PR 0 Allyl 0 o i Bu 0 4

[0145] [Chemical 110] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3132 i PR 2 Ethynyl 2 o i Bu 0 0 3133 i PR 2 Ethynyl 1 o i Bu 1 0 3134 i PR 2 Ethynyl 1 o i Bu 0 1 3135 i PR 2 Ethynyl 0 o i Bu 2 0 3136 i PR 2 Ethynyl 0 o i Bu 1 1 3137 i PR 2 Ethynyl 0 o i Bu 0 2 3138 i PR 1 Ethynyl 3 o i Bu 0 0 3139 i PR 1 Ethynyl 2 o i Bu 1 0 3140 i PR 1 Ethynyl 2 o i Bu 0 1 3141 i PR 1 Ethynyl 1 o i Bu 2 0 3142 i PR 1 Ethynyl 1 o i Bu 1 1 3143 i PR 1 Ethynyl 1 o i Bu 0 2 3144 i PR 1 Ethynyl 0 o i Bu 3 0 3145 i PR 1 Ethynyl 0 o i Bu 2 1 3146 i PR 1 Ethynyl 0 o i Bu 1 2 3147 i PR 1 Ethynyl 0 o i Bu 0 3 3148 i PR 0 Ethynyl 4 o i Bu 0 0 3149 i PR 0 Ethynyl 3 o i Bu 1 0 3150 i PR 0 Ethynyl 3 o i Bu 0 1 3151 i PR 0 Ethynyl 2 o i Bu 2 0 3152 i PR 0 Ethynyl 2 o i Bu 1 1 3153 i PR 0 Ethynyl 2 o i Bu 0 2 3154 i PR 0 Ethynyl 1 o i Bu 3 0 3155 i PR 0 Ethynyl 1 o i Bu 2 1 3156 i PR 0 Ethynyl 1 o i Bu 1 2 3157 i PR 0 Ethynyl 1 o i Bu 0 3 3158 i PR 0 Ethynyl 0 o i Bu 4 0 3159 i PR 0 Ethynyl 0 o i Bu 3 1 3160 i PR 0 Ethynyl 0 o i Bu 2 2 3161 i PR 0 Ethynyl 0 o i Bu 1 3 3162 i PR 0 Ethynyl 0 o i Bu 0 4

[0146] [Chemical 111] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3163 i PR 2 vinyl 2 o sec Bu 0 0 3164 i PR 2 vinyl 1 o sec Bu 1 0 3165 i PR 2 vinyl 1 o sec Bu 0 1 3166 i PR 2 vinyl 0 o sec Bu 2 0 3167 i PR 2 vinyl 0 o sec Bu 1 1 3168 i PR 2 vinyl 0 o sec Bu 0 2 3169 i PR 1 vinyl 3 o sec Bu 0 0 3170 i PR 1 vinyl 2 o sec Bu 1 0 3171 i PR 1 vinyl 2 o sec Bu 0 1 3172 i PR 1 vinyl 1 o sec Bu 2 0 3173 i PR 1 vinyl 1 o sec Bu 1 1 3174 i PR 1 vinyl 1 o sec Bu 0 2 3175 i PR 1 vinyl 0 o sec Bu 3 0 3176 i PR 1 vinyl 0 o sec Bu 2 1 3177 i PR 1 vinyl 0 o sec Bu 1 2 3178 i PR 1 vinyl 0 o sec Bu 0 3 3179 i PR 0 vinyl 4 o sec Bu 0 0 3180 i PR 0 vinyl 3 o sec Bu 1 0 3181 i PR 0 vinyl 3 o sec Bu 0 1 3182 i PR 0 vinyl 2 o sec Bu 2 0 3183 i PR 0 vinyl 2 o sec Bu 1 1 3184 i PR 0 vinyl 2 o sec Bu 0 2 3185 i PR 0 vinyl 1 o sec Bu 3 0 3186 i PR 0 vinyl 1 o sec Bu 2 1 3187 i PR 0 vinyl 1 o sec Bu 1 2 3188 i PR 0 vinyl 1 o sec Bu 0 3 3189 i PR 0 vinyl 0 o sec Bu 4 0 3190 i PR 0 vinyl 0 o sec Bu 3 1 3191 i PR 0 vinyl 0 o sec Bu 2 2 3192 i PR 0 vinyl 0 o sec Bu 1 3 3193 i PR 0 vinyl 0 o sec Bu 0 4

[0147] [Chemical 112] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3194 i PR 2 Allyl 2 o sec Bu 0 0 3195 i PR 2 Allyl 1 o sec Bu 1 0 3196 i PR 2 Allyl 1 o sec Bu 0 1 3197 i PR 2 Allyl 0 o sec Bu 2 0 3198 i PR 2 Allyl 0 o sec Bu 1 1 3199 i PR 2 Allyl 0 o sec Bu 0 2 3200 i PR 1 Allyl 3 o sec Bu 0 0 3201 i PR 1 Allyl 2 o sec Bu 1 0 3202 i PR 1 Allyl 2 o sec Bu 0 1 3203 i PR 1 Allyl 1 o sec Bu 2 0 3204 i PR 1 Allyl 1 o sec Bu 1 1 3205 i PR 1 Allyl 1 o sec Bu 0 2 3206 i PR 1 Allyl 0 o sec Bu 3 0 3207 i PR 1 Allyl 0 o sec Bu 2 1 3208 i PR 1 Allyl 0 o sec Bu 1 2 3209 i PR 1 Allyl 0 o sec Bu 0 3 3210 i PR 0 Allyl 4 o sec Bu 0 0 3211 i PR 0 Allyl 3 o sec Bu 1 0 3212 i PR 0 Allyl 3 o sec Bu 0 1 3213 i PR 0 Allyl 2 o sec Bu 2 0 3214 i PR 0 Allyl 2 o sec Bu 1 1 3215 i PR 0 Allyl 2 o sec Bu 0 2 3216 i PR 0 Allyl 1 o sec Bu 3 0 3217 i PR 0 Allyl 1 o sec Bu 2 1 3218 i PR 0 Allyl 1 o sec Bu 1 2 3219 i PR 0 Allyl 1 o sec Bu 0 3 3220 i PR 0 Allyl 0 o sec Bu 4 0 3221 i PR 0 Allyl 0 o sec Bu 3 1 3222 i PR 0 Allyl 0 o sec Bu 2 2 3223 i PR 0 Allyl 0 o sec Bu 1 3 3224 i PR 0 Allyl 0 o sec Bu 0 4

[0148] [Chemical 113] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3225 i PR 2 Ethynyl 2 o sec Bu 0 0 3226 i PR 2 Ethynyl 1 o sec Bu 1 0 3227 i PR 2 Ethynyl 1 o sec Bu 0 1 3228 i PR 2 Ethynyl 0 o sec Bu 2 0 3229 i PR 2 Ethynyl 0 o sec Bu 1 1 3230 i PR 2 Ethynyl 0 o sec Bu 0 2 3231 i PR 1 Ethynyl 3 o sec Bu 0 0 3232 i PR 1 Ethynyl 2 o sec Bu 1 0 3233 i PR 1 Ethynyl 2 o sec Bu 0 1 3234 i PR 1 Ethynyl 1 o sec Bu 2 0 3235 i PR 1 Ethynyl 1 o sec Bu 1 1 3236 i PR 1 Ethynyl 1 o sec Bu 0 2 3237 i PR 1 Ethynyl 0 o sec Bu 3 0 3238 i PR 1 Ethynyl 0 o sec Bu 2 1 3239 i PR 1 Ethynyl 0 o sec Bu 1 2 3240 i PR 1 Ethynyl 0 o sec Bu 0 3 3241 i PR 0 Ethynyl 4 o sec Bu 0 0 3242 i PR 0 Ethynyl 3 o sec Bu 1 0 3243 i PR 0 Ethynyl 3 o sec Bu 0 1 3244 i PR 0 Ethynyl 2 o sec Bu 2 0 3245 i PR 0 Ethynyl 2 o sec Bu 1 1 3246 i PR 0 Ethynyl 2 o sec Bu 0 2 3247 i PR 0 Ethynyl 1 o sec Bu 3 0 3248 i PR 0 Ethynyl 1 o sec Bu 2 1 3249 i PR 0 Ethynyl 1 o sec Bu 1 2 3250 i PR 0 Ethynyl 1 o sec Bu 0 3 3251 i PR 0 Ethynyl 0 o sec Bu 4 0 3252 i PR 0 Ethynyl 0 o sec Bu 3 1 3253 i PR 0 Ethynyl 0 o sec Bu 2 2 3254 i PR 0 Ethynyl 0 o sec Bu 1 3 3255 i PR 0 Ethynyl 0 o sec Bu 0 4

[0149] [Chemical 114] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3256 i PR 2 vinyl 2 o t Bu 0 0 3257 i PR 2 vinyl 1 o t Bu 1 0 3258 i PR 2 vinyl 1 o t Bu 0 1 3259 i PR 2 vinyl 0 o t Bu 2 0 3260 i PR 2 vinyl 0 o t Bu 1 1 3261 i PR 2 vinyl 0 o t Bu 0 2 3262 i PR 1 vinyl 3 o t Bu 0 0 3263 i PR 1 vinyl 2 o t Bu 1 0 3264 i PR 1 vinyl 2 o t Bu 0 1 3265 i PR 1 vinyl 1 o t Bu 2 0 3266 i PR 1 vinyl 1 o t Bu 1 1 3267 i PR 1 vinyl 1 o t Bu 0 2 3268 i PR 1 vinyl 0 o t Bu 3 0 3269 i PR 1 vinyl 0 o t Bu 2 1 3270 i PR 1 vinyl 0 o t Bu 1 2 3271 i PR 1 vinyl 0 o t Bu 0 3 3272 i PR 0 vinyl 4 o t Bu 0 0 3273 i PR 0 vinyl 3 o t Bu 1 0 3274 i PR 0 vinyl 3 o t Bu 0 1 3275 i PR 0 vinyl 2 o t Bu 2 0 3276 i PR 0 vinyl 2 o t Bu 1 1 3277 i PR 0 vinyl 2 o t Bu 0 2 3278 i PR 0 vinyl 1 o t Bu 3 0 3279 i PR 0 vinyl 1 o t Bu 2 1 3280 i PR 0 vinyl 1 o t Bu 1 2 3281 i PR 0 vinyl 1 o t Bu 0 3 3282 i PR 0 vinyl 0 o t Bu 4 0 3283 i PR 0 vinyl 0 o t Bu 3 1 3284 i PR 0 vinyl 0 o t Bu 2 2 3285 i PR 0 vinyl 0 o t Bu 1 3 3286 i PR 0 vinyl 0 o t Bu 0 4

[0150] [Chemical 115] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3287 i PR 2 Allyl 2 o t Bu 0 0 3288 i PR 2 Allyl 1 o t Bu 1 0 3289 i PR 2 Allyl 1 o t Bu 0 1 3290 i PR 2 Allyl 0 o t Bu 2 0 3291 i PR 2 Allyl 0 o t Bu 1 1 3292 i PR 2 Allyl 0 o t Bu 0 2 3293 i PR 1 Allyl 3 o t Bu 0 0 3294 i PR 1 Allyl 2 o t Bu 1 0 3295 i PR 1 Allyl 2 o t Bu 0 1 3296 i PR 1 Allyl 1 o t Bu 2 0 3297 i PR 1 Allyl 1 o t Bu 1 1 3298 i PR 1 Allyl 1 o t Bu 0 2 3299 i PR 1 Allyl 0 o t Bu 3 0 3300 i PR 1 Allyl 0 o t Bu 2 1 3301 i PR 1 Allyl 0 o t Bu 1 2 3302 i PR 1 Allyl 0 o t Bu 0 3 3303 i PR 0 Allyl 4 o t Bu 0 0 3304 i PR 0 Allyl 3 o t Bu 1 0 3305 i PR 0 Allyl 3 o t Bu 0 1 3306 i PR 0 Allyl 2 o t Bu 2 0 3307 i PR 0 Allyl 2 o t Bu 1 1 3308 i PR 0 Allyl 2 o t Bu 0 2 3309 i PR 0 Allyl 1 o t Bu 3 0 3310 i PR 0 Allyl 1 o t Bu 2 1 3311 i PR 0 Allyl 1 o t Bu 1 2 3312 i PR 0 Allyl 1 o t Bu 0 3 3313 i PR 0 Allyl 0 o t Bu 4 0 3314 i PR 0 Allyl 0 o t Bu 3 1 3315 i PR 0 Allyl 0 o t Bu 2 2 3316 i PR 0 Allyl 0 o t Bu 1 3 3317 i PR 0 Allyl 0 o t Bu 0 4

[0151] [Chemical 116] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3318 i PR 2 Ethynyl 2 o t Bu 0 0 3319 i PR 2 Ethynyl 1 o t Bu 1 0 3320 i PR 2 Ethynyl 1 o t Bu 0 1 3321 i PR 2 Ethynyl 0 o t Bu 2 0 3322 i PR 2 Ethynyl 0 o t Bu 1 1 3323 i PR 2 Ethynyl 0 o t Bu 0 2 3324 i PR 1 Ethynyl 3 o t Bu 0 0 3325 i PR 1 Ethynyl 2 o t Bu 1 0 3326 i PR 1 Ethynyl 2 o t Bu 0 1 3327 i PR 1 Ethynyl 1 o t Bu 2 0 3328 i PR 1 Ethynyl 1 o t Bu 1 1 3329 i PR 1 Ethynyl 1 o t Bu 0 2 3330 i PR 1 Ethynyl 0 o t Bu 3 0 3331 i PR 1 Ethynyl 0 o t Bu 2 1 3332 i PR 1 Ethynyl 0 o t Bu 1 2 3333 i PR 1 Ethynyl 0 o t Bu 0 3 3334 i PR 0 Ethynyl 4 o t Bu 0 0 3335 i PR 0 Ethynyl 3 o t Bu 1 0 3336 i PR 0 Ethynyl 3 o t Bu 0 1 3337 i PR 0 Ethynyl 2 o t Bu 2 0 3338 i PR 0 Ethynyl 2 o t Bu 1 1 3339 i PR 0 Ethynyl 2 o t Bu 0 2 3340 i PR 0 Ethynyl 1 o t Bu 3 0 3341 i PR 0 Ethynyl 1 o t Bu 2 1 3342 i PR 0 Ethynyl 1 o t Bu 1 2 3343 i PR 0 Ethynyl 1 o t Bu 0 3 3344 i PR 0 Ethynyl 0 o t Bu 4 0 3345 i PR 0 Ethynyl 0 o t Bu 3 1 3346 i PR 0 Ethynyl 0 o t Bu 2 2 3347 i PR 0 Ethynyl 0 o t Bu 1 3 3348 i PR 0 Ethynyl 0 o t Bu 0 4

[0152] [Chemical 117] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3349 n Bu 2 vinyl 2 Oh 0 0 3350 n Bu 2 vinyl 1 Oh 1 0 3351 n Bu 2 vinyl 1 Oh 0 1 3352 n Bu 2 vinyl 0 Oh 2 0 3353 n Bu 2 vinyl 0 Oh 1 1 3354 n Bu 2 vinyl 0 Oh 0 2 3355 n Bu 1 vinyl 3 Oh 0 0 3356 n Bu 1 vinyl 2 Oh 1 0 3357 n Bu 1 vinyl 2 Oh 0 1 3358 n Bu 1 vinyl 1 Oh 2 0 3359 n Bu 1 vinyl 1 Oh 1 1 3360 n Bu 1 vinyl 1 Oh 0 2 3361 n Bu 1 vinyl 0 Oh 3 0 3362 n Bu 1 vinyl 0 Oh 2 1 3363 n Bu 1 vinyl 0 Oh 1 2 3364 n Bu 1 vinyl 0 Oh 0 3 3365 n Bu 0 vinyl 4 Oh 0 0 3366 n Bu 0 vinyl 3 Oh 1 0 3367 n Bu 0 vinyl 3 Oh 0 1 3368 n Bu 0 vinyl 2 Oh 2 0 3369 n Bu 0 vinyl 2 Oh 1 1 3370 n Bu 0 vinyl 2 Oh 0 2 3371 n Bu 0 vinyl 1 Oh 3 0 3372 n Bu 0 vinyl 1 Oh 2 1 3373 n Bu 0 vinyl 1 Oh 1 2 3374 n Bu 0 vinyl 1 Oh 0 3 3375 n Bu 0 vinyl 0 Oh 4 0 3376 n Bu 0 vinyl 0 Oh 3 1 3377 n Bu 0 vinyl 0 Oh 2 2 3378 n Bu 0 vinyl 0 Oh 1 3 3379 n Bu 0 vinyl 0 Oh 0 4

[0153] [Chemical 118] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3380 n Bu 2 Allyl 2 Oh 0 0 3381 n Bu 2 Allyl 1 Oh 1 0 3382 n Bu 2 Allyl 1 Oh 0 1 3383 n Bu 2 Allyl 0 Oh 2 0 3384 n Bu 2 Allyl 0 Oh 1 1 3385 n Bu 2 Allyl 0 Oh 0 2 3386 n Bu 1 Allyl 3 Oh 0 0 3387 n Bu 1 Allyl 2 Oh 1 0 3388 n Bu 1 Allyl 2 Oh 0 1 3389 n Bu 1 Allyl 1 Oh 2 0 3390 n Bu 1 Allyl 1 Oh 1 1 3391 n Bu 1 Allyl 1 Oh 0 2 3392 n Bu 1 Allyl 0 Oh 3 0 3393 n Bu 1 Allyl 0 Oh 2 1 3394 n Bu 1 Allyl 0 Oh 1 2 3395 n Bu 1 Allyl 0 Oh 0 3 3396 n Bu 0 Allyl 4 Oh 0 0 3397 n Bu 0 Allyl 3 Oh 1 0 3398 n Bu 0 Allyl 3 Oh 0 1 3399 n Bu 0 Allyl 2 Oh 2 0 3400 n Bu 0 Allyl 2 Oh 1 1 3401 n Bu 0 Allyl 2 Oh 0 2 3402 n Bu 0 Allyl 1 Oh 3 0 3403 n Bu 0 Allyl 1 Oh 2 1 3404 n Bu 0 Allyl 1 Oh 1 2 3405 n Bu 0 Allyl 1 Oh 0 3 3406 n Bu 0 Allyl 0 Oh 4 0 3407 n Bu 0 Allyl 0 Oh 3 1 3408 n Bu 0 Allyl 0 Oh 2 2 3409 n Bu 0 Allyl 0 Oh 1 3 3410 n Bu 0 Allyl 0 Oh 0 4

[0154] [Chemical 119] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3411 n Bu 2 Ethynyl 2 Oh 0 0 3412 n Bu 2 Ethynyl 1 Oh 1 0 3413 n Bu 2 Ethynyl 1 Oh 0 1 3414 n Bu 2 Ethynyl 0 Oh 2 0 3415 n Bu 2 Ethynyl 0 Oh 1 1 3416 n Bu 2 Ethynyl 0 Oh 0 2 3417 n Bu 1 Ethynyl 3 Oh 0 0 3418 n Bu 1 Ethynyl 2 Oh 1 0 3419 n Bu 1 Ethynyl 2 Oh 0 1 3420 n Bu 1 Ethynyl 1 Oh 2 0 3421 n Bu 1 Ethynyl 1 Oh 1 1 3422 n Bu 1 Ethynyl 1 Oh 0 2 3423 n Bu 1 Ethynyl 0 Oh 3 0 3424 n Bu 1 Ethynyl 0 Oh 2 1 3425 n Bu 1 Ethynyl 0 Oh 1 2 3426 n Bu 1 Ethynyl 0 Oh 0 3 3427 n Bu 0 Ethynyl 4 Oh 0 0 3428 n Bu 0 Ethynyl 3 Oh 1 0 3429 n Bu 0 Ethynyl 3 Oh 0 1 3430 n Bu 0 Ethynyl 2 Oh 2 0 3431 n Bu 0 Ethynyl 2 Oh 1 1 3432 n Bu 0 Ethynyl 2 Oh 0 2 3433 n Bu 0 Ethynyl 1 Oh 3 0 3434 n Bu 0 Ethynyl 1 Oh 2 1 3435 n Bu 0 Ethynyl 1 Oh 1 2 3436 n Bu 0 Ethynyl 1 Oh 0 3 3437 n Bu 0 Ethynyl 0 Oh 4 0 3438 n Bu 0 Ethynyl 0 Oh 3 1 3439 n Bu 0 Ethynyl 0 Oh 2 2 3440 n Bu 0 Ethynyl 0 Oh 1 3 3441 n Bu 0 Ethynyl 0 Oh 0 4

[0155] [Chemical 120] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3442 n Bu 2 vinyl 2 OMe 0 0 3443 n Bu 2 vinyl 1 OMe 1 0 3444 n Bu 2 vinyl 1 OMe 0 1 3445 n Bu 2 vinyl 0 OMe 2 0 3446 n Bu 2 vinyl 0 OMe 1 1 3447 n Bu 2 vinyl 0 OMe 0 2 3448 n Bu 1 vinyl 3 OMe 0 0 3449 n Bu 1 vinyl 2 OMe 1 0 3450 n Bu 1 vinyl 2 OMe 0 1 3451 n Bu 1 vinyl 1 OMe 2 0 3452 n Bu 1 vinyl 1 OMe 1 1 3453 n Bu 1 vinyl 1 OMe 0 2 3454 n Bu 1 vinyl 0 OMe 3 0 3455 n Bu 1 vinyl 0 OMe 2 1 3456 n Bu 1 vinyl 0 OMe 1 2 3457 n Bu 1 vinyl 0 OMe 0 3 3458 n Bu 0 vinyl 4 OMe 0 0 3459 n Bu 0 vinyl 3 OMe 1 0 3460 n Bu 0 vinyl 3 OMe 0 1 3461 n Bu 0 vinyl 2 OMe 2 0 3462 n Bu 0 vinyl 2 OMe 1 1 3463 n Bu 0 vinyl 2 OMe 0 2 3464 n Bu 0 vinyl 1 OMe 3 0 3465 n Bu 0 vinyl 1 OMe 2 1 3466 n Bu 0 vinyl 1 OMe 1 2 3467 n Bu 0 vinyl 1 OMe 0 3 3468 n Bu 0 vinyl 0 OMe 4 0 3469 n Bu 0 vinyl 0 OMe 3 1 3470 n Bu 0 vinyl 0 OMe 2 2 3471 n Bu 0 vinyl 0 OMe 1 3 3472 n Bu 0 vinyl 0 OMe 0 4

[0156] [Chemical 121] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3473 n Bu 2 Allyl 2 OMe 0 0 3474 n Bu 2 Allyl 1 OMe 1 0 3475 n Bu 2 Allyl 1 OMe 0 1 3476 n Bu 2 Allyl 0 OMe 2 0 3477 n Bu 2 Allyl 0 OMe 1 1 3478 n Bu 2 Allyl 0 OMe 0 2 3479 n Bu 1 Allyl 3 OMe 0 0 3480 n Bu 1 Allyl 2 OMe 1 0 3481 n Bu 1 Allyl 2 OMe 0 1 3482 n Bu 1 Allyl 1 OMe 2 0 3483 n Bu 1 Allyl 1 OMe 1 1 3484 n Bu 1 Allyl 1 OMe 0 2 3485 n Bu 1 Allyl 0 OMe 3 0 3486 n Bu 1 Allyl 0 OMe 2 1 3487 n Bu 1 Allyl 0 OMe 1 2 3488 n Bu 1 Allyl 0 OMe 0 3 3489 n Bu 0 Allyl 4 OMe 0 0 3490 n Bu 0 Allyl 3 OMe 1 0 3491 n Bu 0 Allyl 3 OMe 0 1 3492 n Bu 0 Allyl 2 OMe 2 0 3493 n Bu 0 Allyl 2 OMe 1 1 3494 n Bu 0 Allyl 2 OMe 0 2 3495 n Bu 0 Allyl 1 OMe 3 0 3496 n Bu 0 Allyl 1 OMe 2 1 3497 n Bu 0 Allyl 1 OMe 1 2 3498 n Bu 0 Allyl 1 OMe 0 3 3499 n Bu 0 Allyl 0 OMe 4 0 3500 n Bu 0 Allyl 0 OMe 3 1 3501 n Bu 0 Allyl 0 OMe 2 2 3502 n Bu 0 Allyl 0 OMe 1 3 3503 n Bu 0 Allyl 0 OMe 0 4

[0157] [Chemical 122] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3504 n Bu 2 Ethynyl 2 OMe 0 0 3505 n Bu 2 Ethynyl 1 OMe 1 0 3506 n Bu 2 Ethynyl 1 OMe 0 1 3507 n Bu 2 Ethynyl 0 OMe 2 0 3508 n Bu 2 Ethynyl 0 OMe 1 1 3509 n Bu 2 Ethynyl 0 OMe 0 2 3510 n Bu 1 Ethynyl 3 OMe 0 0 3511 n Bu 1 Ethynyl 2 OMe 1 0 3512 n Bu 1 Ethynyl 2 OMe 0 1 3513 n Bu 1 Ethynyl 1 OMe 2 0 3514 n Bu 1 Ethynyl 1 OMe 1 1 3515 n Bu 1 Ethynyl 1 OMe 0 2 3516 n Bu 1 Ethynyl 0 OMe 3 0 3517 n Bu 1 Ethynyl 0 OMe 2 1 3518 n Bu 1 Ethynyl 0 OMe 1 2 3519 n Bu 1 Ethynyl 0 OMe 0 3 3520 n Bu 0 Ethynyl 4 OMe 0 0 3521 n Bu 0 Ethynyl 3 OMe 1 0 3522 n Bu 0 Ethynyl 3 OMe 0 1 3523 n Bu 0 Ethynyl 2 OMe 2 0 3524 n Bu 0 Ethynyl 2 OMe 1 1 3525 n Bu 0 Ethynyl 2 OMe 0 2 3526 n Bu 0 Ethynyl 1 OMe 3 0 3527 n Bu 0 Ethynyl 1 OMe 2 1 3528 n Bu 0 Ethynyl 1 OMe 1 2 3529 n Bu 0 Ethynyl 1 OMe 0 3 3530 n Bu 0 Ethynyl 0 OMe 4 0 3531 n Bu 0 Ethynyl 0 OMe 3 1 3532 n Bu 0 Ethynyl 0 OMe 2 2 3533 n Bu 0 Ethynyl 0 OMe 1 3 3534 n Bu 0 Ethynyl 0 OMe 0 4

[0158] [Chemical 123] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3535 n Bu 2 vinyl 2 OEt 0 0 3536 n Bu 2 vinyl 1 OEt 1 0 3537 n Bu 2 vinyl 1 OEt 0 1 3538 n Bu 2 vinyl 0 OEt 2 0 3539 n Bu 2 vinyl 0 OEt 1 1 3540 n Bu 2 vinyl 0 OEt 0 2 3541 n Bu 1 vinyl 3 OEt 0 0 3542 n Bu 1 vinyl 2 OEt 1 0 3543 n Bu 1 vinyl 2 OEt 0 1 3544 n Bu 1 vinyl 1 OEt 2 0 3545 n Bu 1 vinyl 1 OEt 1 1 3546 n Bu 1 vinyl 1 OEt 0 2 3547 n Bu 1 vinyl 0 OEt 3 0 3548 n Bu 1 vinyl 0 OEt 2 1 3549 n Bu 1 vinyl 0 OEt 1 2 3550 n Bu 1 vinyl 0 OEt 0 3 3551 n Bu 0 vinyl 4 OEt 0 0 3552 n Bu 0 vinyl 3 OEt 1 0 3553 n Bu 0 vinyl 3 OEt 0 1 3554 n Bu 0 vinyl 2 OEt 2 0 3555 n Bu 0 vinyl 2 OEt 1 1 3556 n Bu 0 vinyl 2 OEt 0 2 3557 n Bu 0 vinyl 1 OEt 3 0 3558 n Bu 0 vinyl 1 OEt 2 1 3559 n Bu 0 vinyl 1 OEt 1 2 3560 n Bu 0 vinyl 1 OEt 0 3 3561 n Bu 0 vinyl 0 OEt 4 0 3562 n Bu 0 vinyl 0 OEt 3 1 3563 n Bu 0 vinyl 0 OEt 2 2 3564 n Bu 0 vinyl 0 OEt 1 3 3565 n Bu 0 vinyl 0 OEt 0 4

[0159] [Chemical 124] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3566 n Bu 2 Allyl 2 OEt 0 0 3567 n Bu 2 Allyl 1 OEt 1 0 3568 n Bu 2 Allyl 1 OEt 0 1 3569 n Bu 2 Allyl 0 OEt 2 0 3570 n Bu 2 Allyl 0 OEt 1 1 3571 n Bu 2 Allyl 0 OEt 0 2 3572 n Bu 1 Allyl 3 OEt 0 0 3573 n Bu 1 Allyl 2 OEt 1 0 3574 n Bu 1 Allyl 2 OEt 0 1 3575 n Bu 1 Allyl 1 OEt 2 0 3576 n Bu 1 Allyl 1 OEt 1 1 3577 n Bu 1 Allyl 1 OEt 0 2 3578 n Bu 1 Allyl 0 OEt 3 0 3579 n Bu 1 Allyl 0 OEt 2 1 3580 n Bu 1 Allyl 0 OEt 1 2 3581 n Bu 1 Allyl 0 OEt 0 3 3582 n Bu 0 Allyl 4 OEt 0 0 3583 n Bu 0 Allyl 3 OEt 1 0 3584 n Bu 0 Allyl 3 OEt 0 1 3585 n Bu 0 Allyl 2 OEt 2 0 3586 n Bu 0 Allyl 2 OEt 1 1 3587 n Bu 0 Allyl 2 OEt 0 2 3588 n Bu 0 Allyl 1 OEt 3 0 3589 n Bu 0 Allyl 1 OEt 2 1 3590 n Bu 0 Allyl 1 OEt 1 2 3591 n Bu 0 Allyl 1 OEt 0 3 3592 n Bu 0 Allyl 0 OEt 4 0 3593 n Bu 0 Allyl 0 OEt 3 1 3594 n Bu 0 Allyl 0 OEt 2 2 3595 n Bu 0 Allyl 0 OEt 1 3 3596 n Bu 0 Allyl 0 OEt 0 4

[0160] [Chemical 125] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3597 n Bu 2 Ethynyl 2 OEt 0 0 3598 n Bu 2 Ethynyl 1 OEt 1 0 3599 n Bu 2 Ethynyl 1 OEt 0 1 3600 n Bu 2 Ethynyl 0 OEt 2 0 3601 n Bu 2 Ethynyl 0 OEt 1 1 3602 n Bu 2 Ethynyl 0 OEt 0 2 3603 n Bu 1 Ethynyl 3 OEt 0 0 3604 n Bu 1 Ethynyl 2 OEt 1 0 3605 n Bu 1 Ethynyl 2 OEt 0 1 3606 n Bu 1 Ethynyl 1 OEt 2 0 3607 n Bu 1 Ethynyl 1 OEt 1 1 3608 n Bu 1 Ethynyl 1 OEt 0 2 3609 n Bu 1 Ethynyl 0 OEt 3 0 3610 n Bu 1 Ethynyl 0 OEt 2 1 3611 n Bu 1 Ethynyl 0 OEt 1 2 3612 n Bu 1 Ethynyl 0 OEt 0 3 3613 n Bu 0 Ethynyl 4 OEt 0 0 3614 n Bu 0 Ethynyl 3 OEt 1 0 3615 n Bu 0 Ethynyl 3 OEt 0 1 3616 n Bu 0 Ethynyl 2 OEt 2 0 3617 n Bu 0 Ethynyl 2 OEt 1 1 3618 n Bu 0 Ethynyl 2 OEt 0 2 3619 n Bu 0 Ethynyl 1 OEt 3 0 3620 n Bu 0 Ethynyl 1 OEt 2 1 3621 n Bu 0 Ethynyl 1 OEt 1 2 3622 n Bu 0 Ethynyl 1 OEt 0 3 3623 n Bu 0 Ethynyl 0 OEt 4 0 3624 n Bu 0 Ethynyl 0 OEt 3 1 3625 n Bu 0 Ethynyl 0 OEt 2 2 3626 n Bu 0 Ethynyl 0 OEt 1 3 3627 n Bu 0 Ethynyl 0 OEt 0 4

[0161] [Chemical 126] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3628 n Bu 2 vinyl 2 o n PR 0 0 3629 n Bu 2 vinyl 1 o n PR 1 0 3630 n Bu 2 vinyl 1 o n PR 0 1 3631 n Bu 2 vinyl 0 o n PR 2 0 3632 n Bu 2 vinyl 0 o n PR 1 1 3633 n Bu 2 vinyl 0 o n PR 0 2 3634 n Bu 1 vinyl 3 o n PR 0 0 3635 n Bu 1 vinyl 2 o n PR 1 0 3636 n Bu 1 vinyl 2 o n PR 0 1 3637 n Bu 1 vinyl 1 o n PR 2 0 3638 n Bu 1 vinyl 1 o n PR 1 1 3639 n Bu 1 vinyl 1 o n PR 0 2 3640 n Bu 1 vinyl 0 o n PR 3 0 3641 n Bu 1 vinyl 0 o n PR 2 1 3642 n Bu 1 vinyl 0 on PR 1 2 3643 n Bu 1 vinyl 0 o n PR 0 3 3644 n Bu 0 vinyl 4 o n PR 0 0 3645 n Bu 0 vinyl 3 o n PR 1 0 3646 n Bu 0 vinyl 3 o n PR 0 1 3647 n Bu 0 vinyl 2 o n PR 2 0 3648 n Bu 0 vinyl 2 o n PR 1 1 3649 n Bu 0 vinyl 2 o n PR 0 2 3650 n Bu 0 vinyl 1 o n PR 3 0 3651 n Bu 0 vinyl 1 o n PR 2 1 3652 n Bu 0 vinyl 1 o n PR 1 2 3653 n Bu 0 vinyl 1 o n PR 0 3 3654 n Bu 0 vinyl 0 o n PR 4 0 3655 n Bu 0 vinyl 0 o n PR 3 1 3656 n Bu 0 vinyl 0 o n PR 2 2 3657 n Bu 0 vinyl 0 o n PR 1 3 3658 n Bu 0 vinyl 0 o n PR 0 4

[0162] [Chemical 127] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3659 n Bu 2 Allyl 2 o n PR 0 0 3660 n Bu 2 Allyl 1 o n PR 1 0 3661 n Bu 2 Allyl 1 o n PR 0 1 3662 n Bu 2 Allyl 0 o n PR 2 0 3663 n Bu 2 Allyl 0 o n PR 1 1 3664 n Bu 2 Allyl 0 o n PR 0 2 3665 n Bu 1 Allyl 3 o n PR 0 0 3666 n Bu 1 Allyl 2 o n PR 1 0 3667 n Bu 1 Allyl 2 o n PR 0 1 3668 n Bu 1 Allyl 1 o n PR 2 0 3669 n Bu 1 Allyl 1 o n PR 1 1 3670 n Bu 1 Allyl 1 o n PR 0 2 3671 n Bu 1 Allyl 0 o n PR 3 0 3672 n Bu 1 Allyl 0 o n PR 2 1 3673 n Bu 1 Allyl 0 o n PR 1 2 3674 n Bu 1 Allyl 0 o n PR 0 3 3675 n Bu 0 Allyl 4 o n PR 0 0 3676 n Bu 0 Allyl 3 o n PR 1 0 3677 n Bu 0 Allyl 3 o n PR 0 1 3678 n Bu 0 Allyl 2 o n PR 2 0 3679 n Bu 0 Allyl 2 o n PR 1 1 3680 n Bu 0 Allyl 2 o n PR 0 2 3681 n Bu 0 Allyl 1 o n PR 3 0 3682 n Bu 0 Allyl 1 o n PR 2 1 3683 n Bu 0 Allyl 1 o n PR 1 2 3684 n Bu 0 Allyl 1 o n PR 0 3 3685 n Bu 0 Allyl 0 o n PR 4 0 3686 n Bu 0 Allyl 0 o n PR 3 1 3687 n Bu 0 Allyl 0 o n PR 2 2 3688 n Bu 0 Allyl 0 o n PR 1 3 3689 n Bu 0 Allyl 0 o n PR 0 4

[0163] [Chemical 128] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3690 n Bu 2 Ethynyl 2 o n PR 0 0 3691 n Bu 2 Ethynyl 1 o n PR 1 0 3692 n Bu 2 Ethynyl 1 o n PR 0 1 3693 n Bu 2 Ethynyl 0 o n PR 2 0 3694 n Bu 2 Ethynyl 0 o n PR 1 1 3695 n Bu 2 Ethynyl 0 o n PR 0 2 3696 n Bu 1 Ethynyl 3 o n PR 0 0 3697 n Bu 1 Ethynyl 2 o n PR 1 0 3698 n Bu 1 Ethynyl 2 o n PR 0 1 3699 n Bu 1 Ethynyl 1 o n PR 2 0 3700 n Bu 1 Ethynyl 1 o n PR 1 1 3701 n Bu 1 Ethynyl 1 o n PR 0 2 3702 n Bu 1 Ethynyl 0 o n PR 3 0 3703 n Bu 1 Ethynyl 0 o n PR 2 1 3704 n Bu 1 Ethynyl 0 o n PR 1 2 3705 n Bu 1 Ethynyl 0 o n PR 0 3 3706 n Bu 0 Ethynyl 4 o n PR 0 0 3707 n Bu 0 Ethynyl 3 o n PR 1 0 3708 n Bu 0 Ethynyl 3 o n PR 0 1 3709 n Bu 0 Ethynyl 2 o n PR 2 0 3710 n Bu 0 Ethynyl 2 o n PR 1 1 3711 n Bu 0 Ethynyl 2 o n PR 0 2 3712 n Bu 0 Ethynyl 1 o n PR 3 0 3713 n Bu 0 Ethynyl 1 o n PR 2 1 3714 n Bu 0 Ethynyl 1 o n PR 1 2 3715 n Bu 0 Ethynyl 1 o n PR 0 3 3716 n Bu 0 Ethynyl 0 o n PR 4 0 3717 n Bu 0 Ethynyl 0 o n PR 3 1 3718 n Bu 0 Ethynyl 0 o n PR 2 2 3719 n Bu 0 Ethynyl 0 o n PR 1 3 3720 n Bu 0 Ethynyl 0 o n PR 0 4

[0164] [Chemical 129] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3721 n Bu 2 vinyl 2 o i PR 0 0 3722 n Bu 2 vinyl 1 o i PR 1 0 3723 n Bu 2 vinyl 1 o i PR 0 1 3724 n Bu 2 vinyl 0 o i PR 2 0 3725 n Bu 2 vinyl 0 o i PR 1 1 3726 n Bu 2 vinyl 0 o i PR 0 2 3727 n Bu 1 vinyl 3 o i PR 0 0 3728 n Bu 1 vinyl 2 o i PR 1 0 3729 n Bu 1 vinyl 2 o i PR 0 1 3730 n Bu 1 vinyl 1 o i PR 2 0 3731 n Bu 1 vinyl 1 o i PR 1 1 3732 n Bu 1 vinyl 1 o i PR 0 2 3733 n Bu 1 vinyl 0 o i PR 3 0 3734 n Bu 1 vinyl 0 o i PR 2 1 3735 n Bu 1 vinyl 0 o i PR 1 2 3736 n Bu 1 vinyl 0 o i PR 0 3 3737 n Bu 0 vinyl 4 o i PR 0 0 3738 n Bu 0 vinyl 3 o i PR 1 0 3739 n Bu 0 vinyl 3 o i PR 0 1 3740 n Bu 0 vinyl 2 o i PR 2 0 3741 n Bu 0 vinyl 2 o i PR 1 1 3742 n Bu 0 vinyl 2 o i PR 0 2 3743 n Bu 0 vinyl 1 o i PR 3 0 3744 n Bu 0 vinyl 1 o i PR 2 1 3745 n Bu 0 vinyl 1 o i PR 1 2 3746 n Bu 0 vinyl 1 o i PR 0 3 3747 n Bu 0 vinyl 0 o i PR 4 0 3748 n Bu 0 vinyl 0 o i PR 3 1 3749 n Bu 0 vinyl 0 o i PR 2 2 3750 n Bu 0 vinyl 0 o i PR 1 3 3751 n Bu 0 vinyl 0 o i PR 0 4

[0165] [Chemical 130] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3752 n Bu 2 Allyl 2 o i PR 0 0 3753 n Bu 2 Allyl 1 o i PR 1 0 3754 n Bu 2 Allyl 1 o i PR 0 1 3755 n Bu 2 Allyl 0 o i PR 2 0 3756 n Bu 2 Allyl 0 o i PR 1 1 3757 n Bu 2 Allyl 0 o iPR 0 2 3758 n Bu 1 Allyl 3 o i PR 0 0 3759 n Bu 1 Allyl 2 o i PR 1 0 3760 n Bu 1 Allyl 2 o i PR 0 1 3761 n Bu 1 Allyl 1 o i PR 2 0 3762 n Bu 1 Allyl 1 o i PR 1 1 3763 n Bu 1 Allyl 1 o i PR 0 2 3764 n Bu 1 Allyl 0 o i PR 3 0 3765 n Bu 1 Allyl 0 o i PR 2 1 3766 n Bu 1 Allyl 0 o i PR 1 2 3767 n Bu 1 Allyl 0 o i PR 0 3 3768 n Bu 0 Allyl 4 o i PR 0 0 3769 n Bu 0 Allyl 3 o i PR 1 0 3770 n Bu 0 Allyl 3 o i PR 0 1 3771 n Bu 0 Allyl 2 o i PR 2 0 3772 n Bu 0 Allyl 2 o i PR 1 1 3773 n Bu 0 Allyl 2 o i PR 0 2 3774 n Bu 0 Allyl 1 o i PR 3 0 3775 n Bu 0 Allyl 1 o i PR 2 1 3776 n Bu 0 Allyl 1 o i PR 1 2 3777 n Bu 0 Allyl 1 o i PR 0 3 3778 n Bu 0 Allyl 0 o i PR 4 0 3779 n Bu 0 Allyl 0 o i PR 3 1 3780 n Bu 0 Allyl 0 o i PR 2 2 3781 n Bu 0 Allyl 0 o i PR 1 3 3782 n Bu 0 Allyl 0 o i PR 0 4

[0166] [Chemical 131] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3783 n Bu 2 Ethynyl 2 o i PR 0 0 3784 n Bu 2 Ethynyl 1 o i PR 1 0 3785 n Bu 2 Ethynyl 1 o i PR 0 1 3786 n Bu 2 Ethynyl 0 o i PR 2 0 3787 n Bu 2 Ethynyl 0 o i PR 1 1 3788 n Bu 2 Ethynyl 0 o i PR 0 2 3789 n Bu 1 Ethynyl 3 o i PR 0 0 3790 n Bu 1 Ethynyl 2 o i PR 1 0 3791 n Bu 1 Ethynyl 2 o i PR 0 1 3792 n Bu 1 Ethynyl 1 o i PR 2 0 3793 n Bu 1 Ethynyl 1 o i PR 1 1 3794 n Bu 1 Ethynyl 1 o i PR 0 2 3795 n Bu 1 Ethynyl 0 o i PR 3 0 3796 n Bu 1 Ethynyl 0 o i PR 2 1 3797 n Bu 1 Ethynyl 0 o i PR 1 2 3798 n Bu 1 Ethynyl 0 o i PR 0 3 3799 n Bu 0 Ethynyl 4 o i PR 0 0 3800 n Bu 0 Ethynyl 3 o i PR 1 0 3801 n Bu 0 Ethynyl 3 o i PR 0 1 3802 n Bu 0 Ethynyl 2 o i PR 2 0 3803 n Bu 0 Ethynyl 2 o i PR 1 1 3804 n Bu 0 Ethynyl 2 o i PR 0 2 3805 n Bu 0 Ethynyl 1 o i PR 3 0 3806 n Bu 0 Ethynyl 1 o i PR 2 1 3807 n Bu 0 Ethynyl 1 o i PR 1 2 3808 n Bu 0 Ethynyl 1 o i PR 0 3 3809 n Bu 0 Ethynyl 0 o i PR 4 0 3810 n Bu 0 Ethynyl 0 o i PR 3 1 3811 n Bu 0 Ethynyl 0 o i PR 2 2 3812 n Bu 0 Ethynyl 0 o i PR 1 3 3813 n Bu 0 Ethynyl 0 o i PR 0 4

[0167] [Chemical 132] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3814 n Bu 2 vinyl 2 o n Bu 0 0 3815 n Bu 2 vinyl 1 o n Bu 1 0 3816 n Bu 2 vinyl 1 o n Bu 0 1 3817 n Bu 2 vinyl 0 o n Bu 2 0 3818 n Bu 2 vinyl 0 o n Bu 1 1 3819 n Bu 2 vinyl 0 o n Bu 0 2 3820 n Bu 1 vinyl 3 o n Bu 0 0 3821 n Bu 1 vinyl 2 o n Bu 1 0 3822 n Bu 1 vinyl 2 o n Bu 0 1 3823 n Bu 1 vinyl 1 o n Bu 2 0 3824 n Bu 1 vinyl 1 o n Bu 1 1 3825 n Bu 1 vinyl 1 o n Bu 0 2 3826 n Bu 1 vinyl 0 o n Bu 3 0 3827 n Bu 1 vinyl 0 o n Bu 2 1 3828 n Bu 1 vinyl 0 o n Bu 1 2 3829 n Bu 1 vinyl 0 o n Bu 0 3 3830 n Bu 0 vinyl 4 o n Bu 0 0 3831 n Bu 0 vinyl 3 o n Bu 1 0 3832 n Bu 0 vinyl 3 o n Bu 0 1 3833 n Bu 0 vinyl 2 o n Bu 2 0 3834 n Bu 0 vinyl 2 o n Bu 1 1 3835 n Bu 0 vinyl 2 o n Bu 0 2 3836 n Bu 0 vinyl 1 o n Bu 3 0 3837 n Bu 0 vinyl 1 o n Bu 2 1 3838 n Bu 0 vinyl 1 o n Bu 1 2 3839 n Bu 0 vinyl 1 o n Bu 0 3 3840 n Bu 0 vinyl 0 o n Bu 4 0 3841 n Bu 0 vinyl 0 o n Bu 3 1 3842 n Bu 0 vinyl 0 o n Bu 2 2 3843 n Bu 0 vinyl 0 o n Bu 1 3 3844 n Bu 0 vinyl 0 o n Bu 0 4

[0168] [Chemical 133] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3845 n Bu 2 Allyl 2 o n Bu 0 0 3846 n Bu 2 Allyl 1 o n Bu 1 0 3847 n Bu 2 Allyl 1 o n Bu 0 1 3848 n Bu 2 Allyl 0 o n Bu 2 0 3849 n Bu 2 Allyl 0 o n Bu 1 1 3850 n Bu 2 Allyl 0 o n Bu 0 2 3851 n Bu 1 Allyl 3 o n Bu 0 0 3852 n Bu 1 Allyl 2 o n Bu 1 0 3853 n Bu 1 Allyl 2 o n Bu 0 1 3854 n Bu 1 Allyl 1 o n Bu 2 0 3855 n Bu 1 Allyl 1 o n Bu 1 1 3856 n Bu 1 Allyl 1 o n Bu 0 2 3857 n Bu 1 Allyl 0 o n Bu 3 0 3858 n Bu 1 Allyl 0 o n Bu 2 1 3859 n Bu 1 Allyl 0 o n Bu 1 2 3860 n Bu 1 Allyl 0 o n Bu 0 3 3861 n Bu 0 Allyl 4 o n Bu 0 0 3862 n Bu 0 Allyl 3 o n Bu 1 0 3863 n Bu 0 Allyl 3 o n Bu 0 1 3864 n Bu 0 Allyl 2 o n Bu 2 0 3865 n Bu 0 Allyl 2 o n Bu 1 1 3866 n Bu 0 Allyl 2 o n Bu 0 2 3867 n Bu 0 Allyl 1 o n Bu 3 0 3868 n Bu 0 Allyl 1 o n Bu 2 1 3869 n Bu 0 Allyl 1 o n Bu 1 2 3870 n Bu 0 Allyl 1 o n Bu 0 3 3871 n Bu 0 Allyl 0 o n Bu 4 0 3872 n Bu 0 Allyl 0 o n Bu 3 1 3873 n Bu 0 Allyl 0 o n Bu 2 2 3874 n Bu 0 Allyl 0 o n Bu 1 3 3875 n Bu 0 Allyl 0 o n Bu 0 4

[0169] [Chemical 134] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3876 n Bu 2 Ethynyl 2 o n Bu 0 0 3877 n Bu 2 Ethynyl 1 o n Bu 1 0 3878 n Bu 2 Ethynyl 1 o n Bu 0 1 3879 n Bu 2 Ethynyl 0 o n Bu 2 0 3880 n Bu 2 Ethynyl 0 o n Bu 1 1 3881 n Bu 2 Ethynyl 0 o n Bu 0 2 3882 n Bu 1 Ethynyl 3 o n Bu 0 0 3883 n Bu 1 Ethynyl 2 o n Bu 1 0 3884 n Bu 1 Ethynyl 2 o n Bu 0 1 3885 n Bu 1 Ethynyl 1 o n Bu 2 0 3886 n Bu 1 Ethynyl 1 o n Bu 1 1 3887 n Bu 1 Ethynyl 1 o n Bu 0 2 3888 n Bu 1 Ethynyl 0 o n Bu 3 0 3889 n Bu 1 Ethynyl 0 o n Bu 2 1 3890 n Bu 1 Ethynyl 0 o n Bu 1 2 3891 n Bu 1 Ethynyl 0 o n Bu 0 3 3892 n Bu 0 Ethynyl 4 o n Bu 0 0 3893 n Bu 0 Ethynyl 3 o n Bu 1 0 3894 n Bu 0 Ethynyl 3 o n Bu 0 1 3895 n Bu 0 Ethynyl 2 o n Bu 2 0 3896 n Bu 0 Ethynyl 2 o n Bu 1 1 3897 n Bu 0 Ethynyl 2 o n Bu 0 2 3898 n Bu 0 Ethynyl 1 o n Bu 3 0 3899 n Bu 0 Ethynyl 1 o n Bu 2 1 3900 n Bu 0 Ethynyl 1 o n Bu 1 2 3901 n Bu 0 Ethynyl 1 o n Bu 0 3 3902 n Bu 0 Ethynyl 0 o n Bu 4 0 3903 n Bu 0 Ethynyl 0 o n Bu 3 1 3904 n Bu 0 Ethynyl 0 o n Bu 2 2 3905 n Bu 0 Ethynyl 0 o n Bu 1 3 3906 n Bu 0 Ethynyl 0 o n Bu 0 4

[0170] [Chemical 135] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3907 n Bu 2 vinyl 2 o i Bu 0 0 3908 n Bu 2 vinyl 1 o i Bu 1 0 3909 n Bu 2 vinyl 1 o i Bu 0 1 3910 n Bu 2 vinyl 0 o i Bu 2 0 3911 n Bu 2 vinyl 0 o i Bu 1 1 3912 n Bu 2 vinyl 0 o i Bu 0 2 3913 n Bu 1 vinyl 3 o i Bu 0 0 3914 n Bu 1 vinyl 2 o i Bu 1 0 3915 n Bu 1 vinyl 2 o i Bu 0 1 3916 n Bu 1 vinyl 1 o i Bu 2 0 3917 n Bu 1 vinyl 1 o i Bu 1 1 3918 n Bu 1 vinyl 1 o i Bu 0 2 3919 n Bu 1 vinyl 0 o i Bu 3 0 3920 n Bu 1 vinyl 0 o i Bu 2 1 3921 n Bu 1 vinyl 0 o i Bu 1 2 3922 n Bu 1 vinyl 0 o i Bu 0 3 3923 n Bu 0 vinyl 4 o i Bu 0 0 3924 n Bu 0 vinyl 3 o i Bu 1 0 3925 n Bu 0 vinyl 3 o i Bu 0 1 3926 n Bu 0 vinyl 2 o i Bu 2 0 3927 n Bu 0 vinyl 2 o i Bu 1 1 3928 n Bu 0 vinyl 2 o i Bu 0 2 3929 n Bu 0 vinyl 1 o i Bu 3 0 3930 n Bu 0 vinyl 1 o i Bu 2 1 3931 n Bu 0 vinyl 1 o i Bu 1 2 3932 n Bu 0 vinyl 1 o i Bu 0 3 3933 n Bu 0 vinyl 0 o i Bu 4 0 3934 n Bu 0 vinyl 0 o i Bu 3 1 3935 n Bu 0 vinyl 0 o i Bu 2 2 3936 n Bu 0 vinyl 0 o i Bu 1 3 3937 n Bu 0 vinyl 0 o i Bu 0 4

[0171] [Chemical 136] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3938 n Bu 2 Allyl 2 o i Bu 0 0 3939 n Bu 2 Allyl 1 o i Bu 1 0 3940 n Bu 2 Allyl 1 o i Bu 0 1 3941 n Bu 2 Allyl 0 o i Bu 2 0 3942 n Bu 2 Allyl 0 o i Bu 1 1 3943 n Bu 2 Allyl 0 o i Bu 0 2 3944 n Bu 1 Allyl 3 o i Bu 0 0 3945 n Bu 1 Allyl 2 o i Bu 1 0 3946 n Bu 1 Allyl 2 o i Bu 0 1 3947 n Bu 1 Allyl 1 o i Bu 2 0 3948 n Bu 1 Allyl 1 o i Bu 1 1 3949 n Bu 1 Allyl 1 o i Bu 0 2 3950 n Bu 1 Allyl 0 o i Bu 3 0 3951 n Bu 1 Allyl 0 o i Bu 2 1 3952 n Bu 1 Allyl 0 o i Bu 1 2 3953 n Bu 1 Allyl 0 o i Bu 0 3 3954 n Bu 0 Allyl 4 o i Bu 0 0 3955 n Bu 0 Allyl 3 o i Bu 1 0 3956 n Bu 0 Allyl 3 o i Bu 0 1 3957 n Bu 0 Allyl 2 o i Bu 2 0 3958 n Bu 0 Allyl 2 o i Bu 1 1 3959 n Bu 0 Allyl 2 o i Bu 0 2 3960 n Bu 0 Allyl 1 o i Bu 3 0 3961 n Bu 0 Allyl 1 o i Bu 2 1 3962 n Bu 0 Allyl 1 o i Bu 1 2 3963 n Bu 0 Allyl 1 o i Bu 0 3 3964 n Bu 0 Allyl 0 o i Bu 4 0 3965 n Bu 0 Allyl 0 o i Bu 3 1 3966 n Bu 0 Allyl 0 o i Bu 2 2 3967 n Bu 0 Allyl 0 o i Bu 1 3 3968 n Bu 0 Allyl 0 o i Bu 0 4

[0172] [Chemical 137] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 3969 n Bu 2 Ethynyl 2 o i Bu 0 0 3970 n Bu 2 Ethynyl 1 o i Bu 1 0 3971 n Bu 2 Ethynyl 1 o i Bu 0 1 3972 n Bu 2 Ethynyl 0 o i Bu 2 0 3973 n Bu 2 Ethynyl 0 o i Bu 1 1 3974 n Bu 2 Ethynyl 0 o i Bu 0 2 3975 n Bu 1 Ethynyl 3 o i Bu 0 0 3976 n Bu 1 Ethynyl 2 o i Bu 1 0 3977 n Bu 1 Ethynyl 2 o i Bu 0 1 3978 n Bu 1 Ethynyl 1 o i Bu 2 0 3979 n Bu 1 Ethynyl 1 o i Bu 1 1 3980 n Bu 1 Ethynyl 1 o i Bu 0 2 3981 n Bu 1 Ethynyl 0 o i Bu 3 0 3982 n Bu 1 Ethynyl 0 o i Bu 2 1 3983 n Bu 1 Ethynyl 0 o i Bu 1 2 3984 n Bu 1 Ethynyl 0 o i Bu 0 3 3985 n Bu 0 Ethynyl 4 o i Bu 0 0 3986 n Bu 0 Ethynyl 3 o i Bu 1 0 3987 n Bu 0 Ethynyl 3 o i Bu 0 1 3988 n Bu 0 Ethynyl 2 o i Bu 2 0 3989 n Bu 0 Ethynyl 2 o i Bu 1 1 3990 n Bu 0 Ethynyl 2 o i Bu 0 2 3991 n Bu 0 Ethynyl 1 o i Bu 3 0 3992 n Bu 0 Ethynyl 1 o i Bu 2 1 3993 n Bu 0 Ethynyl 1 o i Bu 1 2 3994 n Bu 0 Ethynyl 1 o i Bu 0 3 3995 n Bu 0 Ethynyl 0 o i Bu 4 0 3996 n Bu 0 Ethynyl 0 o i Bu 3 1 3997 n Bu 0 Ethynyl 0 o i Bu 2 2 3998 n Bu 0 Ethynyl 0 o i Bu 1 3 3999 n Bu 0 Ethynyl 0 o i Bu 0 4

[0173] [Chemical 138] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4000 n Bu 2 vinyl 2 o sec Bu 0 0 4001 n Bu 2 vinyl 1 o sec Bu 1 0 4002 n Bu 2 vinyl 1 o sec Bu 0 1 4003 n Bu 2 vinyl 0 o sec Bu 2 0 4004 n Bu 2 vinyl 0 o sec Bu 1 1 4005 n Bu 2 vinyl 0 o sec Bu 0 2 4006 n Bu 1 vinyl 3 o sec Bu 0 0 4007 n Bu 1 vinyl 2 o sec Bu 1 0 4008 n Bu 1 vinyl 2 o sec Bu 0 1 4009 n Bu 1 vinyl 1 o sec Bu 2 0 4010 n Bu 1 vinyl 1 o sec Bu 1 1 4011 n Bu 1 vinyl 1 o sec Bu 0 2 4012 n Bu 1 vinyl 0 o sec Bu 3 0 4013 n Bu 1 vinyl 0 o sec Bu 2 1 4014 n Bu 1 vinyl 0 o sec Bu 1 2 4015 n Bu 1 vinyl 0 o sec Bu 0 3 4016 n Bu 0 vinyl 4 o sec Bu 0 0 4017 n Bu 0 vinyl 3 o sec Bu 1 0 4018 n Bu 0 vinyl 3 o secBu 0 1 4019 n Bu 0 vinyl 2 o sec Bu 2 0 4020 n Bu 0 vinyl 2 o sec Bu 1 1 4021 n Bu 0 vinyl 2 o sec Bu 0 2 4022 n Bu 0 vinyl 1 o sec Bu 3 0 4023 n Bu 0 vinyl 1 o sec Bu 2 1 4024 n Bu 0 vinyl 1 o sec Bu 1 2 4025 n Bu 0 vinyl 1 o sec Bu 0 3 4026 n Bu 0 vinyl 0 o sec Bu 4 0 4027 n Bu 0 vinyl 0 o sec Bu 3 1 4028 n Bu 0 vinyl 0 o sec Bu 2 2 4029 n Bu 0 vinyl 0 o sec Bu 1 3 4030 n Bu 0 vinyl 0 o sec Bu 0 4

[0174] [Chemical 139] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4031 n Bu 2 Allyl 2 o sec Bu 0 0 4032 n Bu 2 Allyl 1 o sec Bu 1 0 4033 n Bu 2 Allyl 1 o sec Bu 0 1 4034 n Bu 2 Allyl 0 o sec Bu 2 0 4035 n Bu 2 Allyl 0 o sec Bu 1 1 4036 n Bu 2 Allyl 0 o sec Bu 0 2 4037 n Bu 1 Allyl 3 o sec Bu 0 0 4038 n Bu 1 Allyl 2 o sec Bu 1 0 4039 n Bu 1 Allyl 2 o sec Bu 0 1 4040 n Bu 1 Allyl 1 o sec Bu 2 0 4041 n Bu 1 Allyl 1 o sec Bu 1 1 4042 n Bu 1 Allyl 1 o sec Bu 0 2 4043 n Bu 1 Allyl 0 o sec Bu 3 0 4044 n Bu 1 Allyl 0 o sec Bu 2 1 4045 n Bu 1 Allyl 0 o sec Bu 1 2 4046 n Bu 1 Allyl 0 o sec Bu 0 3 4047 n Bu 0 Allyl 4 o sec Bu 0 0 4048 n Bu 0 Allyl 3 o sec Bu 1 0 4049 n Bu 0 Allyl 3 o sec Bu 0 1 4050 n Bu 0 Allyl 2 o sec Bu 2 0 4051 n Bu 0 Allyl 2 o sec Bu 1 1 4052 n Bu 0 Allyl 2 o sec Bu 0 2 4053 n Bu 0 Allyl 1 o sec Bu 3 0 4054 n Bu 0 Allyl 1 o sec Bu 2 1 4055 n Bu 0 Allyl 1 o sec Bu 1 2 4056 n Bu 0 Allyl 1 o sec Bu 0 3 4057 n Bu 0 Allyl 0 o sec Bu 4 0 4058 n Bu 0 Allyl 0 o sec Bu 3 1 4059 n Bu 0 Allyl 0 o sec Bu 2 2 4060 n Bu 0 Allyl 0 o sec Bu 1 3 4061 n Bu 0 Allyl 0 o sec Bu 0 4

[0175] [Chemical 140] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4062 n Bu 2 Ethynyl 2 o sec Bu 0 0 4063 n Bu 2 Ethynyl 1 o sec Bu 1 0 4064 n Bu 2 Ethynyl 1 o sec Bu 0 1 4065 n Bu 2 Ethynyl 0 o sec Bu 2 0 4066 n Bu 2 Ethynyl 0 o sec Bu 1 1 4067 n Bu 2 Ethynyl 0 o sec Bu 0 2 4068 n Bu 1 Ethynyl 3 o sec Bu 0 0 4069 n Bu 1 Ethynyl 2 o sec Bu 1 0 4070 n Bu 1 Ethynyl 2 o sec Bu 0 1 4071 n Bu 1 Ethynyl 1 o sec Bu 2 0 4072 n Bu 1 Ethynyl 1 o sec Bu 1 1 4073 n Bu 1 Ethynyl 1 o sec Bu 0 2 4074 n Bu 1 Ethynyl 0 o sec Bu 3 0 4075 n Bu 1 Ethynyl 0 o sec Bu 2 1 4076 n Bu 1 Ethynyl 0 o sec Bu 1 2 4077 n Bu 1 Ethynyl 0 o sec Bu 0 3 4078 n Bu 0 Ethynyl 4 o sec Bu 0 0 4079 n Bu 0 Ethynyl 3 o sec Bu 1 0 4080 n Bu 0 Ethynyl 3 o sec Bu 0 1 4081 n Bu 0 Ethynyl 2 o sec Bu 2 0 4082 n Bu 0 Ethynyl 2 o sec Bu 1 1 4083 n Bu 0 Ethynyl 2 o sec Bu 0 2 4084 n Bu 0 Ethynyl 1 o sec Bu 3 0 4085 n Bu 0 Ethynyl 1 o sec Bu 2 1 4086 n Bu 0 Ethynyl 1 o sec Bu 1 2 4087 n Bu 0 Ethynyl 1 o sec Bu 0 3 4088 n Bu 0 Ethynyl 0 o sec Bu 4 0 4089 n Bu 0 Ethynyl 0 o sec Bu 3 1 4090 n Bu 0 Ethynyl 0 o sec Bu 2 2 4091 n Bu 0 Ethynyl 0 o sec Bu 1 3 4092 n Bu 0 Ethynyl 0 o sec Bu 0 4

[0176] [Chemical 141] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4093 n Bu 2 vinyl 2 o t Bu 0 0 4094 n Bu 2 vinyl 1 o t Bu 1 0 4095 n Bu 2 vinyl 1 o t Bu 0 1 4096 n Bu 2 vinyl 0 o t Bu 2 0 4097 n Bu 2 vinyl 0 o t Bu 1 1 4098 n Bu 2 vinyl 0 o t Bu 0 2 4099 n Bu 1 vinyl 3 o t Bu 0 0 4100 n Bu 1 vinyl 2 o t Bu 1 0 4101 n Bu 1 vinyl 2 o t Bu 0 1 4102 n Bu 1 vinyl 1 o t Bu 2 0 4103 n Bu 1 vinyl 1 o t Bu 1 1 4104 n Bu 1 vinyl 1 o t Bu 0 2 4105 n Bu 1 vinyl 0 o t Bu 3 0 4106 n Bu 1 vinyl 0 o t Bu 2 1 4107 n Bu 1 vinyl 0 o t Bu 1 2 4108 n Bu 1 vinyl 0 o t Bu 0 3 4109 n Bu 0 vinyl 4 o t Bu 0 0 4110 n Bu 0 vinyl 3 o t Bu 1 0 4111 n Bu 0 vinyl 3 o t Bu 0 1 4112 n Bu 0 vinyl 2 o t Bu 2 0 4113 n Bu 0 vinyl 2 o t Bu 1 1 4114 n Bu 0 vinyl 2 o t Bu 0 2 4115 n Bu 0 vinyl 1 o t Bu 3 0 4116 n Bu 0 vinyl 1 o t Bu 2 1 4117 n Bu 0 vinyl 1 o t Bu 1 2 4118 n Bu 0 vinyl 1 o t Bu 0 3 4119 n Bu 0 vinyl 0 o t Bu 4 0 4120 n Bu 0 vinyl 0 o t Bu 3 1 4121 n Bu 0 vinyl 0 o t Bu 2 2 4122 n Bu 0 vinyl 0 o t Bu 1 3 4123 n Bu 0 vinyl 0 o t Bu 0 4

[0177] [Chemical 142] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4124 n Bu 2 Allyl 2 o t Bu 0 0 4125 n Bu 2 Allyl 1 o t Bu 1 0 4126 n Bu 2 Allyl 1 o t Bu 0 1 4127 n Bu 2 Allyl 0 o t Bu 2 0 4128 n Bu 2 Allyl 0 o t Bu 1 1 4129 n Bu 2 Allyl 0 o t Bu 0 2 4130 n Bu 1 Allyl 3 o t Bu 0 0 4131 n Bu 1 Allyl 2 o t Bu 1 0 4132 n Bu 1 Allyl 2 o t Bu 0 1 4133 n Bu 1 Allyl 1 o t Bu 2 0 4134 n Bu 1 Allyl 1 o t Bu 1 1 4135 n Bu 1 Allyl 1 o t Bu 0 2 4136 n Bu 1 Allyl 0 o t Bu 3 0 4137 n Bu 1 Allyl 0 o t Bu 2 1 4138 n Bu 1 Allyl 0 o t Bu 1 2 4139 n Bu 1 Allyl 0 o t Bu 0 3 4140 n Bu 0 Allyl 4 o t Bu 0 0 4141 n Bu 0 Allyl 3 o t Bu 1 0 4142 n Bu 0 Allyl 3 o t Bu 0 1 4143 n Bu 0 Allyl 2 o t Bu 2 0 4144 n Bu 0 Allyl 2 o t Bu 1 1 4145 n Bu 0 Allyl 2 o t Bu 0 2 4146 n Bu 0 Allyl 1 o t Bu 3 0 4147 n Bu 0 Allyl 1 o t Bu 2 1 4148 n Bu 0 Allyl 1 o t Bu 1 2 4149 n Bu 0 Allyl 1 o t Bu 0 3 4150 n Bu 0 Allyl 0 o t Bu 4 0 4151 n Bu 0 Allyl 0 o t Bu 3 1 4152 n Bu 0 Allyl 0 o t Bu 2 2 4153 n Bu 0 Allyl 0 o t Bu 1 3 4154 n Bu 0 Allyl 0 o t Bu 0 4

[0178] [Chemical 143] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4155 n Bu 2 Ethynyl 2 o t Bu 0 0 4156 n Bu 2 Ethynyl 1 o t Bu 1 0 4157 n Bu 2 Ethynyl 1 o t Bu 0 1 4158 n Bu 2 Ethynyl 0 o t Bu 2 0 4159 n Bu 2 Ethynyl 0 o t Bu 1 1 4160 n Bu 2 Ethynyl 0 o t Bu 0 2 4161 n Bu 1 Ethynyl 3 o t Bu 0 0 4162 n Bu 1 Ethynyl 2 o t Bu 1 0 4163 n Bu 1 Ethynyl 2 o t Bu 0 1 4164 n Bu 1 Ethynyl 1 o t Bu 2 0 4165 n Bu 1 Ethynyl 1 o t Bu 1 1 4166 n Bu 1 Ethynyl 1 o t Bu 0 2 4167 n Bu 1 Ethynyl 0 o t Bu 3 0 4168 n Bu 1 Ethynyl 0 o t Bu 2 1 4169 n Bu 1 Ethynyl 0 o t Bu 1 2 4170 n Bu 1 Ethynyl 0 o t Bu 0 3 4171 n Bu 0 Ethynyl 4 o t Bu 0 0 4172 n Bu 0 Ethynyl 3 o t Bu 1 0 4173 n Bu 0 Ethynyl 3 o t Bu 0 1 4174 n Bu 0 Ethynyl 2 o t Bu 2 0 4175 n Bu 0 Ethynyl 2 o t Bu 1 1 4176 n Bu 0 Ethynyl 2 o t Bu 0 2 4177 n Bu 0 Ethynyl 1 o t Bu 3 0 4178 n Bu 0 Ethynyl 1 o t Bu 2 1 4179 n Bu 0 Ethynyl 1 o t Bu 1 2 4180 n Bu 0 Ethynyl 1 o t Bu 0 3 4181 n Bu 0 Ethynyl 0 o t Bu 4 0 4182 n Bu 0 Ethynyl 0 o t Bu 3 1 4183 n Bu 0 Ethynyl 0 o t Bu 2 2 4184 n Bu 0 Ethynyl 0 o t Bu 1 3 4185 n Bu 0 Ethynyl 0 o t Bu 0 4

[0179] [Chemical 144] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4186 i Bu 2 vinyl 2 Oh 0 0 4187 i Bu 2 vinyl 1 Oh 1 0 4188 i Bu 2 vinyl 1 Oh 0 1 4189 i Bu 2 vinyl 0 Oh 2 0 4190 i Bu 2 vinyl 0 Oh 1 1 4191 i Bu 2 vinyl 0 Oh 0 2 4192 i Bu 1 vinyl 3 Oh 0 0 4193 i Bu 1 vinyl 2 Oh 1 0 4194 i Bu 1 vinyl 2 Oh 0 1 4195 i Bu 1 vinyl 1 Oh 2 0 4196 i Bu 1 vinyl 1 Oh 1 1 4197 i Bu 1 vinyl 1 Oh 0 2 4198 i Bu 1 vinyl 0 Oh 3 0 4199 i Bu 1 vinyl 0 Oh 2 1 4200 i Bu 1 vinyl 0 Oh 1 2 4201 i Bu 1 vinyl 0 Oh 0 3 4202 i Bu 0 vinyl 4 Oh 0 0 4203 i Bu 0 vinyl 3 Oh 1 0 4204 i Bu 0 vinyl 3 Oh 0 1 4205 i Bu 0 vinyl 2 Oh 2 0 4206 i Bu 0 vinyl 2 Oh 1 1 4207 i Bu 0 vinyl 2 Oh 0 2 4208 i Bu 0 vinyl 1 Oh 3 0 4209 i Bu 0 vinyl 1 Oh 2 1 4210 i Bu 0 vinyl 1 Oh 1 2 4211 i Bu 0 vinyl 1 Oh 0 3 4212 i Bu 0 vinyl 0 Oh 4 0 4213 i Bu 0 vinyl 0 Oh 3 1 4214 i Bu 0 vinyl 0 Oh 2 2 4215 i Bu 0 vinyl 0 Oh 1 3 4216 i Bu 0 vinyl 0 Oh 0 4

[0180] [Chemical 145] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4217 i Bu 2 Allyl 2 Oh 0 0 4218 i Bu 2 Allyl 1 Oh 1 0 4219 i Bu 2 Allyl 1 Oh 0 1 4220 i Bu 2 Allyl 0 Oh 2 0 4221 i Bu 2 Allyl 0 Oh 1 1 4222 i Bu 2 Allyl 0 Oh 0 2 4223 i Bu 1 Allyl 3 Oh 0 0 4224 i Bu 1 Allyl 2 Oh 1 0 4225 i Bu 1 Allyl 2 Oh 0 1 4226 i Bu 1 Allyl 1 Oh 2 0 4227 i Bu 1 Allyl 1 Oh 1 1 4228 i Bu 1 Allyl 1 Oh 0 2 4229 i Bu 1 Allyl 0 Oh 3 0 4230 i Bu 1 Allyl 0 Oh 2 1 4231 i Bu 1 Allyl 0 Oh 1 2 4232 i Bu 1 Allyl 0 Oh 0 3 4233 i Bu 0 Allyl 4 Oh 0 0 4234 i Bu 0 Allyl 3 Oh 1 0 4235 i Bu 0 Allyl 3 Oh 0 1 4236 i Bu 0 Allyl 2 Oh 2 0 4237 i Bu 0 Allyl 2 Oh 1 1 4238 i Bu 0 Allyl 2 Oh 0 2 4239 i Bu 0 Allyl 1 Oh 3 0 4240 i Bu 0 Allyl 1 Oh 2 1 4241 i Bu 0 Allyl 1 Oh 1 2 4242 i Bu 0 Allyl 1 Oh 0 3 4243 i Bu 0 Allyl 0 Oh 4 0 4244 i Bu 0 Allyl 0 Oh 3 1 4245 i Bu 0 Allyl 0 Oh 2 2 4246 i Bu 0 Allyl 0 Oh 1 3 4247 i Bu 0 Allyl 0 Oh 0 4

[0181] [Chemical 146] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4248 i Bu 2 Ethynyl 2 Oh 0 0 4249 i Bu 2 Ethynyl 1 Oh 1 0 4250 i Bu 2 Ethynyl 1 Oh 0 1 4251 i Bu 2 Ethynyl 0 Oh 2 0 4252 i Bu 2 Ethynyl 0 Oh 1 1 4253 i Bu 2 Ethynyl 0 Oh 0 2 4254 i Bu 1 Ethynyl 3 Oh 0 0 4255 i Bu 1 Ethynyl 2 Oh 1 0 4256 i Bu 1 Ethynyl 2 Oh 0 1 4257 i Bu 1 Ethynyl 1 Oh 2 0 4258 i Bu 1 Ethynyl 1 Oh 1 1 4259 i Bu 1 Ethynyl 1 Oh 0 2 4260 i Bu 1 Ethynyl 0 Oh 3 0 4261 i Bu 1 Ethynyl 0 Oh 2 1 4262 i Bu 1 Ethynyl 0 Oh 1 2 4263 i Bu 1 Ethynyl 0 Oh 0 3 4264 i Bu 0 Ethynyl 4 Oh 0 0 4265 i Bu 0 Ethynyl 3 Oh 1 0 4266 i Bu 0 Ethynyl 3 Oh 0 1 4267 i Bu 0 Ethynyl 2 Oh 2 0 4268 i Bu 0 Ethynyl 2 Oh 1 1 4269 i Bu 0 Ethynyl 2 Oh 0 2 4270 i Bu 0 Ethynyl 1 Oh 3 0 4271 i Bu 0 Ethynyl 1 Oh 2 1 4272 i Bu 0 Ethynyl 1 Oh 1 2 4273 i Bu 0 Ethynyl 1 Oh 0 3 4274 i Bu 0 Ethynyl 0 Oh 4 0 4275 i Bu 0 Ethynyl 0 Oh 3 1 4276 i Bu 0 Ethynyl 0 Oh 2 2 4277 i Bu 0 Ethynyl 0 Oh 1 3 4278 i Bu 0 Ethynyl 0 Oh 0 4

[0182] [Chemical 147] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4279 i Bu 2 vinyl 2 OMe 0 0 4280 i Bu 2 vinyl 1 OMe 1 0 4281 i Bu 2 vinyl 1 OMe 0 1 4282 i Bu 2 vinyl 0 OMe 2 0 4283 i Bu 2 vinyl 0 OMe 1 1 4284 i Bu 2 vinyl 0 OMe 0 2 4285 i Bu 1 vinyl 3 OMe 0 0 4286 i Bu 1 vinyl 2 OMe 1 0 4287 i Bu 1 vinyl 2 OMe 0 1 4288 i Bu 1 vinyl 1 OMe 2 0 4289 i Bu 1 vinyl 1 OMe 1 1 4290 i Bu 1 vinyl 1 OMe 0 2 4291 i Bu 1 vinyl 0 OMe 3 0 4292 i Bu 1 vinyl 0 OMe 2 1 4293 i Bu 1 vinyl 0 OMe 1 2 4294 i Bu 1 vinyl 0 OMe 0 3 4295 i Bu 0 vinyl 4 OMe 0 0 4296 i Bu 0 vinyl 3 OMe 1 0 4297 i Bu 0 vinyl 3 OMe 0 1 4298 i Bu 0 vinyl 2 OMe 2 0 4299 i Bu 0 vinyl 2 OMe 1 1 4300 i Bu 0 vinyl 2 OMe 0 2 4301 i Bu 0 vinyl 1 OMe 3 0 4302 i Bu 0 vinyl 1 OMe 2 1 4303 i Bu 0 vinyl 1 OMe 1 2 4304 i Bu 0 vinyl 1 OMe 0 3 4305 i Bu 0 vinyl 0 OMe 4 0 4306 i Bu 0 vinyl 0 OMe 3 1 4307 i Bu 0 vinyl 0 OMe 2 2 4308 i Bu 0 vinyl 0 OMe 1 3 4309 i Bu 0 vinyl 0 OMe 0 4

[0183] [Chemical 148] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4310 i Bu 2 Allyl 2 OMe 0 0 4311 i Bu 2 Allyl 1 OMe 1 0 4312 i Bu 2 Allyl 1 OMe 0 1 4313 i Bu 2 Allyl 0 OMe 2 0 4314 i Bu 2 Allyl 0 OMe 1 1 4315 i Bu 2 Allyl 0 OMe 0 2 4316 i Bu 1 Allyl 3 OMe 0 0 4317 i Bu 1 Allyl 2 OMe 1 0 4318 i Bu 1 Allyl 2 OMe 0 1 4319 i Bu 1 Allyl 1 OMe 2 0 4320 i Bu 1 Allyl 1 OMe 1 1 4321 i Bu 1 Allyl 1 OMe 0 2 4322 i Bu 1 Allyl 0 OMe 3 0 4323 i Bu 1 Allyl 0 OMe 2 1 4324 i Bu 1 Allyl 0 OMe 1 2 4325 i Bu 1 Allyl 0 OMe 0 3 4326 i Bu 0 Allyl 4 OMe 0 0 4327 i Bu 0 Allyl 3 OMe 1 0 4328 i Bu 0 Allyl 3 OMe 0 1 4329 i Bu 0 Allyl 2 OMe 2 0 4330 i Bu 0 Allyl 2 OMe 1 1 4331 i Bu 0 Allyl 2 OMe 0 2 4332 i Bu 0 Allyl 1 OMe 3 0 4333 i Bu 0 Allyl 1 OMe 2 1 4334 i Bu 0 Allyl 1 OMe 1 2 4335 i Bu 0 Allyl 1 OMe 0 3 4336 i Bu 0 Allyl 0 OMe 4 0 4337 i Bu 0 Allyl 0 OMe 3 1 4338 i Bu 0 Allyl 0 OMe 2 2 4339 i Bu 0 Allyl 0 OMe 1 3 4340 i Bu 0 Allyl 0 OMe 0 4

[0184] [Chemical 149] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4341 i Bu 2 Ethynyl 2 OMe 0 0 4342 i Bu 2 Ethynyl 1 OMe 1 0 4343 i Bu 2 Ethynyl 1 OMe 0 1 4344 i Bu 2 Ethynyl 0 OMe 2 0 4345 i Bu 2 Ethynyl 0 OMe 1 1 4346 i Bu 2 Ethynyl 0 OMe 0 2 4347 i Bu 1 Ethynyl 3 OMe 0 0 4348 i Bu 1 Ethynyl 2 OMe 1 0 4349 i Bu 1 Ethynyl 2 OMe 0 1 4350 i Bu 1 Ethynyl 1 OMe 2 0 4351 i Bu 1 Ethynyl 1 OMe 1 1 4352 i Bu 1 Ethynyl 1 OMe 0 2 4353 i Bu 1 Ethynyl 0 OMe 3 0 4354 i Bu 1 Ethynyl 0 OMe 2 1 4355 i Bu 1 Ethynyl 0 OMe 1 2 4356 i Bu 1 Ethynyl 0 OMe 0 3 4357 i Bu 0 Ethynyl 4 OMe 0 0 4358 i Bu 0 Ethynyl 3 OMe 1 0 4359 i Bu 0 Ethynyl 3 OMe 0 1 4360 i Bu 0 Ethynyl 2 OMe 2 0 4361 i Bu 0 Ethynyl 2 OMe 1 1 4362 i Bu 0 Ethynyl 2 OMe 0 2 4363 i Bu 0 Ethynyl 1 OMe 3 0 4364 i Bu 0 Ethynyl 1 OMe 2 1 4365 i Bu 0 Ethynyl 1 OMe 1 2 4366 i Bu 0 Ethynyl 1 OMe 0 3 4367 i Bu 0 Ethynyl 0 OMe 4 0 4368 i Bu 0 Ethynyl 0 OMe 3 1 4369 i Bu 0 Ethynyl 0 OMe 2 2 4370 i Bu 0 Ethynyl 0 OMe 1 3 4371 i Bu 0 Ethynyl 0 OMe 0 4

[0185] [Chemical 150] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4372 i Bu 2 vinyl 2 OEt 0 0 4373 i Bu 2 vinyl 1 OEt 1 0 4374 i Bu 2 vinyl 1 OEt 0 1 4375 i Bu 2 vinyl 0 OEt 2 0 4376 i Bu 2 vinyl 0 OEt 1 1 4377 i Bu 2 vinyl 0 OEt 0 2 4378 i Bu 1 vinyl 3 OEt 0 0 4379 i Bu 1 vinyl 2 OEt 1 0 4380 i Bu 1 vinyl 2 OEt 0 1 4381 i Bu 1 vinyl 1 OEt 2 0 4382 i Bu 1 vinyl 1 OEt 1 1 4383 i Bu 1 vinyl 1 OEt 0 2 4384 i Bu 1 vinyl 0 OEt 3 0 4385 i Bu 1 vinyl 0 OEt 2 1 4386 i Bu 1 vinyl 0 OEt 1 2 4387 i Bu 1 vinyl 0 OEt 0 3 4388 i Bu 0 vinyl 4 OEt 0 0 4389 i Bu 0 vinyl 3 OEt 1 0 4390 i Bu 0 vinyl 3 OEt 0 1 4391 i Bu 0 vinyl 2 OEt 2 0 4392 i Bu 0 vinyl 2 OEt 1 1 4393 i Bu 0 vinyl 2 OEt 0 2 4394 i Bu 0 vinyl 1 OEt 3 0 4395 i Bu 0 vinyl 1 OEt 2 1 4396 i Bu 0 vinyl 1 OEt 1 2 4397 i Bu 0 vinyl 1 OEt 0 3 4398 i Bu 0 vinyl 0 OEt 4 0 4399 i Bu 0 vinyl 0 OEt 3 1 4400 i Bu 0 vinyl 0 OEt 2 2 4401 i Bu 0 vinyl 0 OEt 1 3 4402 i Bu 0 vinyl 0 OEt 0 4

[0186] [Chemical 151] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4403 i Bu 2 Allyl 2 OEt 0 0 4404 i Bu 2 Allyl 1 OEt 1 0 4405 i Bu 2 Allyl 1 OEt 0 1 4406 i Bu 2 Allyl 0 OEt 2 0 4407 i Bu 2 Allyl 0 OEt 1 1 4408 i Bu 2 Allyl 0 OEt 0 2 4409 i Bu 1 Allyl 3 OEt 0 0 4410 i Bu 1 Allyl 2 OEt 1 0 4411 i Bu 1 Allyl 2 OEt 0 1 4412 i Bu 1 Allyl 1 OEt 2 0 4413 i Bu 1 Allyl 1 OEt 1 1 4414 i Bu 1 Allyl 1 OEt 0 2 4415 i Bu 1 Allyl 0 OEt 3 0 4416 i Bu 1 Allyl 0 OEt 2 1 4417 i Bu 1 Allyl 0 OEt 1 2 4418 i Bu 1 Allyl 0 OEt 0 3 4419 i Bu 0 Allyl 4 OEt 0 0 4420 i Bu 0 Allyl 3 OEt 1 0 4421 i Bu 0 Allyl 3 OEt 0 1 4422 i Bu 0 Allyl 2 OEt 2 0 4423 i Bu 0 Allyl 2 OEt 1 1 4424 i Bu 0 Allyl 2 OEt 0 2 4425 i Bu 0 Allyl 1 OEt 3 0 4426 i Bu 0 Allyl 1 OEt 2 1 4427 i Bu 0 Allyl 1 OEt 1 2 4428 i Bu 0 Allyl 1 OEt 0 3 4429 i Bu 0 Allyl 0 OEt 4 0 4430 i Bu 0 Allyl 0 OEt 3 1 4431 i Bu 0 Allyl 0 OEt 2 2 4432 i Bu 0 Allyl 0 OEt 1 3 4433 i Bu 0 Allyl 0 OEt 0 4

[0187] [Chemical 152] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4434 i Bu 2 Ethynyl 2 OEt 0 0 4435 i Bu 2 Ethynyl 1 OEt 1 0 4436 i Bu 2 Ethynyl 1 OEt 0 1 4437 i Bu 2 Ethynyl 0 OEt 2 0 4438 i Bu 2 Ethynyl 0 OEt 1 1 4439 i Bu 2 Ethynyl 0 OEt 0 2 4440 i Bu 1 Ethynyl 3 OEt 0 0 4441 i Bu 1 Ethynyl 2 OEt 1 0 4442 i Bu 1 Ethynyl 2 OEt 0 1 4443 i Bu 1 Ethynyl 1 OEt 2 0 4444 i Bu 1 Ethynyl 1 OEt 1 1 4445 i Bu 1 Ethynyl 1 OEt 0 2 4446 i Bu 1 Ethynyl 0 OEt 3 0 4447 i Bu 1 Ethynyl 0 OEt 2 1 4448 i Bu 1 Ethynyl 0 OEt 1 2 4449 i Bu 1 Ethynyl 0 OEt 0 3 4450 i Bu 0 Ethynyl 4 OEt 0 0 4451 i Bu 0 Ethynyl 3 OEt 1 0 4452 i Bu 0 Ethynyl 3 OEt 0 1 4453 i Bu 0 Ethynyl 2 OEt 2 0 4454 i Bu 0 Ethynyl 2 OEt 1 1 4455 i Bu 0 Ethynyl 2 OEt 0 2 4456 i Bu 0 Ethynyl 1 OEt 3 0 4457 i Bu 0 Ethynyl 1 OEt 2 1 4458 i Bu 0 Ethynyl 1 OEt 1 2 4459 i Bu 0 Ethynyl 1 OEt 0 3 4460 i Bu 0 Ethynyl 0 OEt 4 0 4461 i Bu 0 Ethynyl 0 OEt 3 1 4462 i Bu 0 Ethynyl 0 OEt 2 2 4463 i Bu 0 Ethynyl 0 OEt 1 3 4464 i Bu 0 Ethynyl 0 OEt 0 4

[0188] [Chemical 153] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4465 i Bu 2 vinyl 2 o n PR 0 0 4466 i Bu 2 vinyl 1 o n PR 1 0 4467 i Bu 2 vinyl 1 o n PR 0 1 4468 i Bu 2 vinyl 0 o n PR 2 0 4469 i Bu 2 vinyl 0 o n PR 1 1 4470 i Bu 2 vinyl 0 o n PR 0 2 4471 i Bu 1 vinyl 3 o n PR 0 0 4472 i Bu 1 vinyl 2 o n PR 1 0 4473 i Bu 1 vinyl 2 o n PR 0 1 4474 i Bu 1 vinyl 1 o n PR 2 0 4475 i Bu 1 vinyl 1 o n PR 1 1 4476 i Bu 1 vinyl 1 o n PR 0 2 4477 i Bu 1 vinyl 0 o n PR 3 0 4478 i Bu 1 vinyl 0 o n PR 2 1 4479 i Bu 1 vinyl 0 o n PR 1 2 4480 i Bu 1 vinyl 0 o n PR 0 3 4481 i Bu 0 vinyl 4 o n PR 0 0 4482 i Bu 0 vinyl 3 o n PR 1 0 4483 i Bu 0 vinyl 3 o n PR 0 1 4484 i Bu 0 vinyl 2 o n PR 2 0 4485 i Bu 0 vinyl 2 o n PR 1 1 4486 i Bu 0 vinyl 2 o n PR 0 2 4487 i Bu 0 vinyl 1 o n PR 3 0 4488 i Bu 0 vinyl 1 o n PR 2 1 4489 i Bu 0 vinyl 1 o n PR 1 2 4490 i Bu 0 vinyl 1 o n PR 0 3 4491 i Bu 0 vinyl 0 o n PR 4 0 4492 i Bu 0 vinyl 0 o n PR 3 1 4493 i Bu 0 vinyl 0 o n PR 2 2 4494 i Bu 0 vinyl 0 o n PR 1 3 4495 i Bu 0 vinyl 0 o n PR 0 4

[0189] [Chemical 154] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4496 i Bu 2 Allyl 2 o n PR 0 0 4497 i Bu 2 Allyl 1 o n PR 1 0 4498 i Bu 2 Allyl 1 o n PR 0 1 4499 i Bu 2 Allyl 0 o n PR 2 0 4500 i Bu 2 Allyl 0 o n PR 1 1 4501 i Bu 2 Allyl 0 o n PR 0 2 4502 i Bu 1 Allyl 3 o n PR 0 0 4503 i Bu 1 Allyl 2 o n PR 1 0 4504 i Bu 1 Allyl 2 o n PR 0 1 4505 i Bu 1 Allyl 1 o n PR 2 0 4506 i Bu 1 Allyl 1 o n PR 1 1 4507 i Bu 1 Allyl 1 o n PR 0 2 4508 i Bu 1 Allyl 0 o n PR 3 0 4509 i Bu 1 Allyl 0 o n PR 2 1 4510 i Bu 1 Allyl 0 o n PR 1 2 4511 i Bu 1 Allyl 0 o n PR 0 3 4512 i Bu 0 Allyl 4 o n PR 0 0 4513 i Bu 0 Allyl 3 o n PR 1 0 4514 i Bu 0 Allyl 3 o n PR 0 1 4515 i Bu 0 Allyl 2 o n PR 2 0 4516 i Bu 0 Allyl 2 o n PR 1 1 4517 i Bu 0 Allyl 2 o n PR 0 2 4518 i Bu 0 Allyl 1 o n PR 3 0 4519 i Bu 0 Allyl 1 o n PR 2 1 4520 i Bu 0 Allyl 1 o n PR 1 2 4521 i Bu 0 Allyl 1 o n PR 0 3 4522 i Bu 0 Allyl 0 o n PR 4 0 4523 i Bu 0 Allyl 0 o n PR 3 1 4524 i Bu 0 Allyl 0 o n PR 2 2 4525 i Bu 0 Allyl 0 o n PR 1 3 4526 i Bu 0 Allyl 0 o n PR 0 4

[0190] [Chemical 155] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4527 i Bu 2 Ethynyl 2 o n PR 0 0 4528 i Bu 2 Ethynyl 1 o n PR 1 0 4529 i Bu 2 Ethynyl 1 o n PR 0 1 4530 i Bu 2 Ethynyl 0 o n PR 2 0 4531 i Bu 2 Ethynyl 0 o n PR 1 1 4532 i Bu 2 Ethynyl 0 o n PR 0 2 4533 i Bu 1 Ethynyl 3 o n PR 0 0 4534 i Bu 1 Ethynyl 2 o n PR 1 0 4535 i Bu 1 Ethynyl 2 o n PR 0 1 4536 i Bu 1 Ethynyl 1 o n PR 2 0 4537 i Bu 1 Ethynyl 1 o n PR 1 1 4538 i Bu 1 Ethynyl 1 o n PR 0 2 4539 i Bu 1 Ethynyl 0 o n PR 3 0 4540 i Bu 1 Ethynyl 0 o n PR 2 1 4541 i Bu 1 Ethynyl 0 o n PR 1 2 4542 i Bu 1 Ethynyl 0 o n PR 0 3 4543 i Bu 0 Ethynyl 4 o n PR 0 0 4544 i Bu 0 Ethynyl 3 o n PR 1 0 4545 i Bu 0 Ethynyl 3 o n PR 0 1 4546 i Bu 0 Ethynyl 2 o n PR 2 0 4547 i Bu 0 Ethynyl 2 o n PR 1 1 4548 i Bu 0 Ethynyl 2 o n PR 0 2 4549 i Bu 0 Ethynyl 1 o n PR 3 0 4550 i Bu 0 Ethynyl 1 o n PR 2 1 4551 i Bu 0 Ethynyl 1 o n PR 1 2 4552 i Bu 0 Ethynyl 1 o n PR 0 3 4553 i Bu 0 Ethynyl 0 o n PR 4 0 4554 i Bu 0 Ethynyl 0 o n PR 3 1 4555 i Bu 0 Ethynyl 0 o n PR 2 2 4556 i Bu 0 Ethynyl 0 o n PR 1 3 4557 i Bu 0 Ethynyl 0 o n PR 0 4

[0191] [Chemical 156] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4558 i Bu 2 vinyl 2 o i PR 0 0 4559 i Bu 2 vinyl 1 o i PR 1 0 4560 i Bu 2 vinyl 1 o i PR 0 1 4561 i Bu 2 vinyl 0 o i PR 2 0 4562 i Bu 2 vinyl 0 o i PR 1 1 4563 i Bu 2 vinyl 0 o i PR 0 2 4564 i Bu 1 vinyl 3 o i PR 0 0 4565 i Bu 1 vinyl 2 o i PR 1 0 4566 i Bu 1 vinyl 2 o i PR 0 1 4567 i Bu 1 vinyl 1 o i PR 2 0 4568 i Bu 1 vinyl 1 o i PR 1 1 4569 i Bu 1 vinyl 1 o i PR 0 2 4570 i Bu 1 vinyl 0 o i PR 3 0 4571 i Bu 1 vinyl 0 o i PR 2 1 4572 i Bu 1 vinyl 0 o i PR 1 2 4573 i Bu 1 vinyl 0 o i PR 0 3 4574 i Bu 0 vinyl 4 o i PR 0 0 4575 i Bu 0 vinyl 3 o i PR 1 0 4576 i Bu 0 vinyl 3 o i PR 0 1 4577 i Bu 0 vinyl 2 o i PR 2 0 4578 i Bu 0 vinyl 2 o i PR 1 1 4579 i Bu 0 vinyl 2 o i PR 0 2 4580 i Bu 0 vinyl 1 o i PR 3 0 4581 i Bu 0 vinyl 1 o i PR 2 1 4582 i Bu 0 vinyl 1 o i PR 1 2 4583 i Bu 0 vinyl 1 o i PR 0 3 4584 i Bu 0 vinyl 0 o i PR 4 0 4585 i Bu 0 vinyl 0 o i PR 3 1 4586 i Bu 0 vinyl 0 o i PR 2 2 4587 i Bu 0 vinyl 0 o i PR 1 3 4588 i Bu 0 vinyl 0 o i PR 0 4

[0192] [Chemical 157] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4589 i Bu 2 Allyl 2 o i PR 0 0 4590 i Bu 2 Allyl 1 o i PR 1 0 4591 i Bu 2 Allyl 1 o i PR 0 1 4592 i Bu 2 Allyl 0 o i PR 2 0 4593 i Bu 2 Allyl 0 o i PR 1 1 4594 i Bu 2 Allyl 0 o i PR 0 2 4595 i Bu 1 Allyl 3 o i PR 0 0 4596 i Bu 1 Allyl 2 o i PR 1 0 4597 i Bu 1 Allyl 2 o i PR 0 1 4598 i Bu 1 Allyl 1 o i PR 2 0 4599 i Bu 1 Allyl 1 o i PR 1 1 4600 i Bu 1 Allyl 1 o i PR 0 2 4601 i Bu 1 Allyl 0 o i PR 3 0 4602 i Bu 1 Allyl 0 o i PR 2 1 4603 i Bu 1 Allyl 0 o i PR 1 2 4604 i Bu 1 Allyl 0 o i PR 0 3 4605 i Bu 0 Allyl 4 o i PR 0 0 4606 i Bu 0 Allyl 3 o i PR 1 0 4607 i Bu 0 Allyl 3 o i PR 0 1 4608 i Bu 0 Allyl 2 o i PR 2 0 4609 i Bu 0 Allyl 2 o i PR 1 1 4610 i Bu 0 Allyl 2 o i PR 0 2 4611 i Bu 0 Allyl 1 o i PR 3 0 4612 i Bu 0 Allyl 1 o i PR 2 1 4613 i Bu 0 Allyl 1 o i PR 1 2 4614 i Bu 0 Allyl 1 o i PR 0 3 4615 i Bu 0 Allyl 0 o i PR 4 0 4616 i Bu 0 Allyl 0 o i PR 3 1 4617 i Bu 0 Allyl 0 o i PR 2 2 4618 i Bu 0 Allyl 0 o i PR 1 3 4619 i Bu 0 Allyl 0 o i PR 0 4

[0193] [Chemical 158] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4620 i Bu 2 Ethynyl 2 o i PR 0 0 4621 i Bu 2 Ethynyl 1 o i PR 1 0 4622 i Bu 2 Ethynyl 1 o i PR 0 1 4623 i Bu 2 Ethynyl 0 o i PR 2 0 4624 i Bu 2 Ethynyl 0 o i PR 1 1 4625 i Bu 2 Ethynyl 0 o i PR 0 2 4626 i Bu 1 Ethynyl 3 o i PR 0 0 4627 i Bu 1 Ethynyl 2 o i PR 1 0 4628 i Bu 1 Ethynyl 2 o i PR 0 1 4629 i Bu 1 Ethynyl 1 o i PR 2 0 4630 i Bu 1 Ethynyl 1 o i PR 1 1 4631 i Bu 1 Ethynyl 1 o i PR 0 2 4632 i Bu 1 Ethynyl 0 o i PR 3 0 4633 i Bu 1 Ethynyl 0 o i PR 2 1 4634 i Bu 1 Ethynyl 0 o i PR 1 2 4635 i Bu 1 Ethynyl 0 o i PR 0 3 4636 i Bu 0 Ethynyl 4 o i PR 0 0 4637 i Bu 0 Ethynyl 3 o i PR 1 0 4638 i Bu 0 Ethynyl 3 o i PR 0 1 4639 i Bu 0 Ethynyl 2 o i PR 2 0 4640 i Bu 0 Ethynyl 2 o i PR 1 1 4641 i Bu 0 Ethynyl 2 o i PR 0 2 4642 i Bu 0 Ethynyl 1 o i PR 3 0 4643 i Bu 0 Ethynyl 1 o i PR 2 1 4644 i Bu 0 Ethynyl 1 o i PR 1 2 4645 i Bu 0 Ethynyl 1 o i PR 0 3 4646 i Bu 0 Ethynyl 0 o i PR 4 0 4647 i Bu 0 Ethynyl 0 o i PR 3 1 4648 i Bu 0 Ethynyl 0 o i PR 2 2 4649 i Bu 0 Ethynyl 0 o i PR 1 3 4650 i Bu 0 Ethynyl 0 o i PR 0 4

[0194] [Chemical 159] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4651 i Bu 2 vinyl 2 o n Bu 0 0 4652 i Bu 2 vinyl 1 o n Bu 1 0 4653 i Bu 2 vinyl 1 o n Bu 0 1 4654 i Bu 2 vinyl 0 o n Bu 2 0 4655 i Bu 2 vinyl 0 o n Bu 1 1 4656 i Bu 2 vinyl 0 o n Bu 0 2 4657 i Bu 1 vinyl 3 o n Bu 0 0 4658 i Bu 1 vinyl 2 o n Bu 1 0 4659 i Bu 1 vinyl 2 o n Bu 0 1 4660 i Bu 1 vinyl 1 o n Bu 2 0 4661 i Bu 1 vinyl 1 o n Bu 1 1 4662 i Bu 1 vinyl 1 o n Bu 0 2 4663 i Bu 1 vinyl 0 o n Bu 3 0 4664 i Bu 1 vinyl 0 o n Bu 2 1 4665 i Bu 1 vinyl 0 o n Bu 1 2 4666 i Bu 1 vinyl 0 o n Bu 0 3 4667 i Bu 0 vinyl 4 o n Bu 0 0 4668 i Bu 0 vinyl 3 o n Bu 1 0 4669 i Bu 0 vinyl 3 o n Bu 0 1 4670 i Bu 0 vinyl 2 o n Bu 2 0 4671 i Bu 0 vinyl 2 o n Bu 1 1 4672 i Bu 0 vinyl 2 o n Bu 0 2 4673 i Bu 0 vinyl 1 o n Bu 3 0 4674 i Bu 0 vinyl 1 o n Bu 2 1 4675 i Bu 0 vinyl 1 o n Bu 1 2 4676 i Bu 0 vinyl 1 o n Bu 0 3 4677 i Bu 0 vinyl 0 o n Bu 4 0 4678 i Bu 0 vinyl 0 o n Bu 3 1 4679 i Bu 0 vinyl 0 o n Bu 2 2 4680 i Bu 0 vinyl 0 o n Bu 1 3 4681 i Bu 0 vinyl 0 o n Bu 0 4

[0195] [Chemical 160] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4682 i Bu 2 Allyl 2 o n Bu 0 0 4683 i Bu 2 Allyl 1 o n Bu 1 0 4684 i Bu 2 Allyl 1 o n Bu 0 1 4685 i Bu 2 Allyl 0 o n Bu 2 0 4686 i Bu 2 Allyl 0 o n Bu 1 1 4687 i Bu 2 Allyl 0 o n Bu 0 2 4688 i Bu 1 Allyl 3 o n Bu 0 0 4689 i Bu 1 Allyl 2 o n Bu 1 0 4690 i Bu 1 Allyl 2 o n Bu 0 1 4691 i Bu 1 Allyl 1 o n Bu 2 0 4692 i Bu 1 Allyl 1 o n Bu 1 1 4693 i Bu 1 Allyl 1 o n Bu 0 2 4694 i Bu 1 Allyl 0 o n Bu 3 0 4695 i Bu 1 Allyl 0 o n Bu 2 1 4696 i Bu 1 Allyl 0 o n Bu 1 2 4697 i Bu 1 Allyl 0 o n Bu 0 3 4698 i Bu 0 Allyl 4 o n Bu 0 0 4699 i Bu 0 Allyl 3 o n Bu 1 0 4700 i Bu 0 Allyl 3 o n Bu 0 1 4701 i Bu 0 Allyl 2 o n Bu 2 0 4702 i Bu 0 Allyl 2 o n Bu 1 1 4703 i Bu 0 Allyl 2 o n Bu 0 2 4704 i Bu 0 Allyl 1 o n Bu 3 0 4705 i Bu 0 Allyl 1 o n Bu 2 1 4706 i Bu 0 Allyl 1 o n Bu 1 2 4707 i Bu 0 Allyl 1 o nBu 0 3 4708 i Bu 0 Allyl 0 o n Bu 4 0 4709 i Bu 0 Allyl 0 o n Bu 3 1 4710 i Bu 0 Allyl 0 o n Bu 2 2 4711 i Bu 0 Allyl 0 o n Bu 1 3 4712 i Bu 0 Allyl 0 o n Bu 0 4

[0196] [Chemical 161] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4713 i Bu 2 Ethynyl 2 o n Bu 0 0 4714 i Bu 2 Ethynyl 1 o n Bu 1 0 4715 i Bu 2 Ethynyl 1 o n Bu 0 1 4716 i Bu 2 Ethynyl 0 o n Bu 2 0 4717 i Bu 2 Ethynyl 0 o n Bu 1 1 4718 i Bu 2 Ethynyl 0 o n Bu 0 2 4719 i Bu 1 Ethynyl 3 o n Bu 0 0 4720 i Bu 1 Ethynyl 2 o n Bu 1 0 4721 i Bu 1 Ethynyl 2 o n Bu 0 1 4722 i Bu 1 Ethynyl 1 o n Bu 2 0 4723 i Bu 1 Ethynyl 1 o n Bu 1 1 4724 i Bu 1 Ethynyl 1 o n Bu 0 2 4725 i Bu 1 Ethynyl 0 o n Bu 3 0 4726 i Bu 1 Ethynyl 0 o n Bu 2 1 4727 i Bu 1 Ethynyl 0 o n Bu 1 2 4728 i Bu 1 Ethynyl 0 o n Bu 0 3 4729 i Bu 0 Ethynyl 4 o n Bu 0 0 4730 i Bu 0 Ethynyl 3 o n Bu 1 0 4731 i Bu 0 Ethynyl 3 o n Bu 0 1 4732 i Bu 0 Ethynyl 2 o n Bu 2 0 4733 i Bu 0 Ethynyl 2 o n Bu 1 1 4734 i Bu 0 Ethynyl 2 o n Bu 0 2 4735 i Bu 0 Ethynyl 1 o n Bu 3 0 4736 i Bu 0 Ethynyl 1 o n Bu 2 1 4737 i Bu 0 Ethynyl 1 o n Bu 1 2 4738 i Bu 0 Ethynyl 1 o n Bu 0 3 4739 i Bu 0 Ethynyl 0 o n Bu 4 0 4740 i Bu 0 Ethynyl 0 o n Bu 3 1 4741 i Bu 0 Ethynyl 0 o n Bu 2 2 4742 i Bu 0 Ethynyl 0 o n Bu 1 3 4743 i Bu 0 Ethynyl 0 o n Bu 0 4

[0197] [Chemical 162] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4744 i Bu 2 vinyl 2 o i Bu 0 0 4745 i Bu 2 vinyl 1 o i Bu 1 0 4746 i Bu 2 vinyl 1 o i Bu 0 1 4747 i Bu 2 vinyl 0 o i Bu 2 0 4748 i Bu 2 vinyl 0 o i Bu 1 1 4749 i Bu 2 vinyl 0 o i Bu 0 2 4750 i Bu 1 vinyl 3 o i Bu 0 0 4751 i Bu 1 vinyl 2 o i Bu 1 0 4752 i Bu 1 vinyl 2 o i Bu 0 1 4753 i Bu 1 vinyl 1 o i Bu 2 0 4754 i Bu 1 vinyl 1 o i Bu 1 1 4755 i Bu 1 vinyl 1 o i Bu 0 2 4756 i Bu 1 vinyl 0 o i Bu 3 0 4757 i Bu 1 vinyl 0 o i Bu 2 1 4758 i Bu 1 vinyl 0 o i Bu 1 2 4759 i Bu 1 vinyl 0 o i Bu 0 3 4760 i Bu 0 vinyl 4 o i Bu 0 0 4761 i Bu 0 vinyl 3 o i Bu 1 0 4762 i Bu 0 vinyl 3 o i Bu 0 1 4763 i Bu 0 vinyl 2 o i Bu 2 0 4764 i Bu 0 vinyl 2 o i Bu 1 1 4765 i Bu 0 vinyl 2 o i Bu 0 2 4766 i Bu 0 vinyl 1 o i Bu 3 0 4767 i Bu 0 vinyl 1 o i Bu 2 1 4768 i Bu 0 vinyl 1 o i Bu 1 2 4769 i Bu 0 vinyl 1 o i Bu 0 3 4770 i Bu 0 vinyl 0 o i Bu 4 0 4771 i Bu 0 vinyl 0 o i Bu 3 1 4772 i Bu 0 vinyl 0 o i Bu 2 2 4773 i Bu 0 vinyl 0 o i Bu 1 3 4774 i Bu 0 vinyl 0 o i Bu 0 4

[0198] [Chemical 163] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4775 i Bu 2 Allyl 2 o i Bu 0 0 4776 i Bu 2 Allyl 1 o i Bu 1 0 4777 i Bu 2 Allyl 1 o i Bu 0 1 4778 i Bu 2 Allyl 0 o i Bu 2 0 4779 i Bu 2 Allyl 0 o i Bu 1 1 4780 i Bu 2 Allyl 0 o i Bu 0 2 4781 i Bu 1 Allyl 3 o i Bu 0 0 4782 i Bu 1 Allyl 2 o i Bu 1 0 4783 i Bu 1 Allyl 2 o i Bu 0 1 4784 i Bu 1 Allyl 1 o i Bu 2 0 4785 i Bu 1 Allyl 1 o i Bu 1 1 4786 i Bu 1 Allyl 1 o i Bu 0 2 4787 i Bu 1 Allyl 0 o i Bu 3 0 4788 i Bu 1 Allyl 0 o i Bu 2 1 4789 i Bu 1 Allyl 0 o i Bu 1 2 4790 i Bu 1 Allyl 0 o i Bu 0 3 4791 i Bu 0 Allyl 4 o i Bu 0 0 4792 i Bu 0 Allyl 3 o i Bu 1 0 4793 i Bu 0 Allyl 3 o i Bu 0 1 4794 i Bu 0 Allyl 2 o i Bu 2 0 4795 i Bu 0 Allyl 2 o i Bu 1 1 4796 i Bu 0 Allyl 2 o i Bu 0 2 4797 i Bu 0 Allyl 1 o i Bu 3 0 4798 i Bu 0 Allyl 1 o i Bu 2 1 4799 i Bu 0 Allyl 1 o i Bu 1 2 4800 i Bu 0 Allyl 1 o i Bu 0 3 4801 i Bu 0 Allyl 0 o i Bu 4 0 4802 i Bu 0 Allyl 0 o i Bu 3 1 4803 i Bu 0 Allyl 0 o i Bu 2 2 4804 i Bu 0 Allyl 0 o i Bu 1 3 4805 i Bu 0 Allyl 0 o i Bu 0 4

[0199] [Chemical 164] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4806 i Bu 2 Ethynyl 2 o i Bu 0 0 4807 i Bu 2 Ethynyl 1 o i Bu 1 0 4808 i Bu 2 Ethynyl 1 o i Bu 0 1 4809 i Bu 2 Ethynyl 0 o i Bu 2 0 4810 i Bu 2 Ethynyl 0 o i Bu 1 1 4811 i Bu 2 Ethynyl 0 o i Bu 0 2 4812 i Bu 1 Ethynyl 3 o i Bu 0 0 4813 i Bu 1 Ethynyl 2 o i Bu 1 0 4814 i Bu 1 Ethynyl 2 o i Bu 0 1 4815 i Bu 1 Ethynyl 1 o i Bu 2 0 4816 i Bu 1 Ethynyl 1 o i Bu 1 1 4817 i Bu 1 Ethynyl 1 o i Bu 0 2 4818 i Bu 1 Ethynyl 0 o i Bu 3 0 4819 i Bu 1 Ethynyl 0 o i Bu 2 1 4820 i Bu 1 Ethynyl 0 o i Bu 1 2 4821 i Bu 1 Ethynyl 0 o i Bu 0 3 4822 i Bu 0 Ethynyl 4 o i Bu 0 0 4823 i Bu 0 Ethynyl 3 o i Bu 1 0 4824 i Bu 0 Ethynyl 3 o i Bu 0 1 4825 i Bu 0 Ethynyl 2 o i Bu 2 0 4826 i Bu 0 Ethynyl 2 o i Bu 1 1 4827 i Bu 0 Ethynyl 2 o i Bu 0 2 4828 i Bu 0 Ethynyl 1 o i Bu 3 0 4829 i Bu 0 Ethynyl 1 o i Bu 2 1 4830 i Bu 0 Ethynyl 1 o i Bu 1 2 4831 i Bu 0 Ethynyl 1 o i Bu 0 3 4832 i Bu 0 Ethynyl 0 o i Bu 4 0 4833 i Bu 0 Ethynyl 0 o i Bu 3 1 4834 i Bu 0 Ethynyl 0 o i Bu 2 2 4835 i Bu 0 Ethynyl 0 o i Bu 1 3 4836 i Bu 0 Ethynyl 0 o i Bu 0 4

[0200] [Chemical 165] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4837 i Bu 2 vinyl 2 o sec Bu 0 0 4838 i Bu 2 vinyl 1 o sec Bu 1 0 4839 i Bu 2 vinyl 1 o sec Bu 0 1 4840 i Bu 2 vinyl 0 o sec Bu 2 0 4841 i Bu 2 vinyl 0 o sec Bu 1 1 4842 i Bu 2 vinyl 0 o sec Bu 0 2 4843 i Bu 1 vinyl 3 o sec Bu 0 0 4844 i Bu 1 vinyl 2 o sec Bu 1 0 4845 i Bu 1 vinyl 2 o sec Bu 0 1 4846 i Bu 1 vinyl 1 o sec Bu 2 0 4847 i Bu 1 vinyl 1 o sec Bu 1 1 4848 i Bu 1 vinyl 1 o sec Bu 0 2 4849 i Bu 1 vinyl 0 o sec Bu 3 0 4850 i Bu 1 vinyl 0 o sec Bu 2 1 4851 i Bu 1 vinyl 0 o sec Bu 1 2 4852 i Bu 1 vinyl 0 o sec Bu 0 3 4853 i Bu 0 vinyl 4 o sec Bu 0 0 4854 i Bu 0 vinyl 3 o sec Bu 1 0 4855 i Bu 0 vinyl 3 o sec Bu 0 1 4856 i Bu 0 vinyl 2 o sec Bu 2 0 4857 i Bu 0 vinyl 2 o sec Bu 1 1 4858 i Bu 0 vinyl 2 o sec Bu 0 2 4859 i Bu 0 vinyl 1 o sec Bu 3 0 4860 i Bu 0 vinyl 1 o sec Bu 2 1 4861 i Bu 0 vinyl 1 o sec Bu 1 2 4862 i Bu 0 vinyl 1 o sec Bu 0 3 4863 i Bu 0 vinyl 0 o sec Bu 4 0 4864 i Bu 0 vinyl 0 o sec Bu 3 1 4865 i Bu 0 vinyl 0 o sec Bu 2 2 4866 i Bu 0 vinyl 0 o sec Bu 1 3 4867 i Bu 0 vinyl 0 o sec Bu 0 4

[0201] [Chemical 166] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4868 i Bu 2 Allyl 2 o sec Bu 0 0 4869 i Bu 2 Allyl 1 o sec Bu 1 0 4870 i Bu 2 Allyl 1 o sec Bu 0 1 4871 i Bu 2 Allyl 0 o sec Bu 2 0 4872 i Bu 2 Allyl 0 o sec Bu 1 1 4873 i Bu 2 Allyl 0 o sec Bu 0 2 4874 i Bu 1 Allyl 3 o sec Bu 0 0 4875 i Bu 1 Allyl 2 o sec Bu 1 0 4876 i Bu 1 Allyl 2 o sec Bu 0 1 4877 i Bu 1 Allyl 1 o sec Bu 2 0 4878 i Bu 1 Allyl 1 o sec Bu 1 1 4879 i Bu 1 Allyl 1 o sec Bu 0 2 4880 i Bu 1 Allyl 0 o sec Bu 3 0 4881 i Bu 1 Allyl 0 o sec Bu 2 1 4882 i Bu 1 Allyl 0 o sec Bu 1 2 4883 i Bu 1 Allyl 0 o sec Bu 0 3 4884 i Bu 0 Allyl 4 o sec Bu 0 0 4885 i Bu 0 Allyl 3 o sec Bu 1 0 4886 i Bu 0 Allyl 3 o sec Bu 0 1 4887 i Bu 0 Allyl 2 o sec Bu 2 0 4888 i Bu 0 Allyl 2 o sec Bu 1 1 4889 i Bu 0 Allyl 2 o sec Bu 0 2 4890 i Bu 0 Allyl 1 o sec Bu 3 0 4891 i Bu 0 Allyl 1 o sec Bu 2 1 4892 i Bu 0 Allyl 1 o sec Bu 1 2 4893 i Bu 0 Allyl 1 o sec Bu 0 3 4894 i Bu 0 Allyl 0 o sec Bu 4 0 4895 i Bu 0 Allyl 0 o sec Bu 3 1 4896 i Bu 0 Allyl 0 o sec Bu 2 2 4897 i Bu 0 Allyl 0 o sec Bu 1 3 4898 i Bu 0 Allyl 0 o sec Bu 0 4

[0202] [Chemical 167] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4899 i Bu 2 Ethynyl 2 o sec Bu 0 0 4900 i Bu 2 Ethynyl 1 o sec Bu 1 0 4901 i Bu 2 Ethynyl 1 o sec Bu 0 1 4902 i Bu 2 Ethynyl 0 o sec Bu 2 0 4903 i Bu 2 Ethynyl 0 o sec Bu 1 1 4904 i Bu 2 Ethynyl 0 o sec Bu 0 2 4905 i Bu 1 Ethynyl 3 o sec Bu 0 0 4906 i Bu 1 Ethynyl 2 o sec Bu 1 0 4907 i Bu 1 Ethynyl 2 o sec Bu 0 1 4908 i Bu 1 Ethynyl 1 o sec Bu 2 0 4909 i Bu 1 Ethynyl 1 o sec Bu 1 1 4910 i Bu 1 Ethynyl 1 o sec Bu 0 2 4911 i Bu 1 Ethynyl 0 o sec Bu 3 0 4912 i Bu 1 Ethynyl 0 o sec Bu 2 1 4913 i Bu 1 Ethynyl 0 o sec Bu 1 2 4914 i Bu 1 Ethynyl 0 o sec Bu 0 3 4915 i Bu 0 Ethynyl 4 o sec Bu 0 0 4916 i Bu 0 Ethynyl 3 o sec Bu 1 0 4917 i Bu 0 Ethynyl 3 o sec Bu 0 1 4918 i Bu 0 Ethynyl 2 o sec Bu 2 0 4919 i Bu 0 Ethynyl 2 o sec Bu 1 1 4920 i Bu 0 Ethynyl 2 o sec Bu 0 2 4921 i Bu 0 Ethynyl 1 o sec Bu 3 0 4922 i Bu 0 Ethynyl 1 o sec Bu 2 1 4923 i Bu 0 Ethynyl 1 o sec Bu 1 2 4924 i Bu 0 Ethynyl 1 o sec Bu 0 3 4925 i Bu 0 Ethynyl 0 o sec Bu 4 0 4926 i Bu 0 Ethynyl 0 o sec Bu 3 1 4927 i Bu 0 Ethynyl 0 o sec Bu 2 2 4928 i Bu 0 Ethynyl 0 o sec Bu 1 3 4929 i Bu 0 Ethynyl 0 o sec Bu 0 4

[0203] [Chemical 168] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4930 i Bu 2 vinyl 2 o t Bu 0 0 4931 i Bu 2 vinyl 1 o t Bu 1 0 4932 i Bu 2 vinyl 1 o t Bu 0 1 4933 i Bu 2 vinyl 0 o t Bu 2 0 4934 i Bu 2 vinyl 0 o t Bu 1 1 4935 i Bu 2 vinyl 0 o t Bu 0 2 4936 i Bu 1 vinyl 3 o t Bu 0 0 4937 i Bu 1 vinyl 2 o t Bu 1 0 4938 i Bu 1 vinyl 2 o t Bu 0 1 4939 i Bu 1 vinyl 1 o t Bu 2 0 4940 i Bu 1 vinyl 1 o t Bu 1 1 4941 i Bu 1 vinyl 1 o t Bu 0 2 4942 i Bu 1 vinyl 0 o t Bu 3 0 4943 i Bu 1 vinyl 0 o t Bu 2 1 4944 i Bu 1 vinyl 0 o t Bu 1 2 4945 i Bu 1 vinyl 0 o t Bu 0 3 4946 i Bu 0 vinyl 4 o t Bu 0 0 4947 i Bu 0 vinyl 3 o t Bu 1 0 4948 i Bu 0 vinyl 3 o t Bu 0 1 4949 i Bu 0 vinyl 2 o t Bu 2 0 4950 i Bu 0 vinyl 2 o t Bu 1 1 4951 i Bu 0 vinyl 2 o t Bu 0 2 4952 i Bu 0 vinyl 1 o t Bu 3 0 4953 i Bu 0 vinyl 1 o t Bu 2 1 4954 i Bu 0 vinyl 1 o t Bu 1 2 4955 i Bu 0 vinyl 1 o t Bu 0 3 4956 i Bu 0 vinyl 0 o t Bu 4 0 4957 i Bu 0 vinyl 0 o t Bu 3 1 4958 i Bu 0 vinyl 0 o t Bu 2 2 4959 i Bu 0 vinyl 0 o t Bu 1 3 4960 i Bu 0 vinyl 0 o t Bu 0 4

[0204] [Chemical 169] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4961 i Bu 2 Allyl 2 o t Bu 0 0 4962 i Bu 2 Allyl 1 o t Bu 1 0 4963 i Bu 2 Allyl 1 o t Bu 0 1 4964 i Bu 2 Allyl 0 o t Bu 2 0 4965 i Bu 2 Allyl 0 o t Bu 1 1 4966 i Bu 2 Allyl 0 o t Bu 0 2 4967 i Bu 1 Allyl 3 o t Bu 0 0 4968 i Bu 1 Allyl 2 o t Bu 1 0 4969 i Bu 1 Allyl 2 o t Bu 0 1 4970 i Bu 1 Allyl 1 o t Bu 2 0 4971 i Bu 1 Allyl 1 o t Bu 1 1 4972 i Bu 1 Allyl 1 o t Bu 0 2 4973 i Bu 1 Allyl 0 o t Bu 3 0 4974 i Bu 1 Allyl 0 o t Bu 2 1 4975 i Bu 1 Allyl 0 o t Bu 1 2 4976 i Bu 1 Allyl 0 o t Bu 0 3 4977 i Bu 0 Allyl 4 o t Bu 0 0 4978 i Bu 0 Allyl 3 o t Bu 1 0 4979 i Bu 0 Allyl 3 o t Bu 0 1 4980 i Bu 0 Allyl 2 o t Bu 2 0 4981 i Bu 0 Allyl 2 o t Bu 1 1 4982 i Bu 0 Allyl 2 o t Bu 0 2 4983 i Bu 0 Allyl 1 o t Bu 3 0 4984 i Bu 0 Allyl 1 o t Bu 2 1 4985 i Bu 0 Allyl 1 o t Bu 1 2 4986 i Bu 0 Allyl 1 o t Bu 0 3 4987 i Bu 0 Allyl 0 o t Bu 4 0 4988 i Bu 0 Allyl 0 o t Bu 3 1 4989 i Bu 0 Allyl 0 o t Bu 2 2 4990 i Bu 0 Allyl 0 o t Bu 1 3 4991 i Bu 0 Allyl 0 o t Bu 0 4

[0205] [Chemical 170] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 4992 i Bu 2 Ethynyl 2 o t Bu 0 0 4993 i Bu 2 Ethynyl 1 o t Bu 1 0 4994 i Bu 2 Ethynyl 1 o t Bu 0 1 4995 i Bu 2 Ethynyl 0 o t Bu 2 0 4996 i Bu 2 Ethynyl 0 o t Bu 1 1 4997 i Bu 2 Ethynyl 0 o t Bu 0 2 4998 i Bu 1 Ethynyl 3 o t Bu 0 0 4999 i Bu 1 Ethynyl 2 o t Bu 1 0 5000 i Bu 1 Ethynyl 2 o t Bu 0 1 5001 i Bu 1 Ethynyl 1 o t Bu 2 0 5002 i Bu 1 Ethynyl 1 o t Bu 1 1 5003 i Bu 1 Ethynyl 1 o t Bu 0 2 5004 i Bu 1 Ethynyl 0 o t Bu 3 0 5005 i Bu 1 Ethynyl 0 o t Bu 2 1 5006 i Bu 1 Ethynyl 0 o t Bu 1 2 5007 i Bu 1 Ethynyl 0 o t Bu 0 3 5008 i Bu 0 Ethynyl 4 o t Bu 0 0 5009 i Bu 0 Ethynyl 3 o t Bu 1 0 5010 i Bu 0 Ethynyl 3 o t Bu 0 1 5011 i Bu 0 Ethynyl 2 o t Bu 2 0 5012 i Bu 0 Ethynyl 2 o t Bu 1 1 5013 i Bu 0 Ethynyl 2 o t Bu 0 2 5014 i Bu 0 Ethynyl 1 o t Bu 3 0 5015 i Bu 0 Ethynyl 1 o t Bu 2 1 5016 i Bu 0 Ethynyl 1 o t Bu 1 2 5017 i Bu 0 Ethynyl 1 o t Bu 0 3 5018 i Bu 0 Ethynyl 0 o t Bu 4 0 5019 i Bu 0 Ethynyl 0 o t Bu 3 1 5020 i Bu 0 Ethynyl 0 o t Bu 2 2 5021 i Bu 0 Ethynyl 0 o t Bu 1 3 5022 i Bu 0 Ethynyl 0 o t Bu 0 4

[0206] [Chemical 171] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5023 sec Bu 2 vinyl 2 Oh 0 0 5024 sec Bu 2 vinyl 1 Oh 1 0 5025 sec Bu 2 vinyl 1 Oh 0 1 5026 sec Bu 2 vinyl 0 Oh 2 0 5027 sec Bu 2 vinyl 0 Oh 1 1 5028 sec Bu 2 vinyl 0 Oh 0 2 5029 sec Bu 1 vinyl 3 Oh 0 0 5030 sec Bu 1 vinyl 2 Oh 1 0 5031 sec Bu 1 vinyl 2 Oh 0 1 5032 sec Bu 1 vinyl 1 Oh 2 0 5033 sec Bu 1 vinyl 1 Oh 1 1 5034 sec Bu 1 vinyl 1 Oh 0 2 5035 sec Bu 1 vinyl 0 Oh 3 0 5036 sec Bu 1 vinyl 0 Oh 2 1 5037 sec Bu 1 vinyl 0 Oh 1 2 5038 sec Bu 1 vinyl 0 Oh 0 3 5039 sec Bu 0 vinyl 4 Oh 0 0 5040 sec Bu 0 vinyl 3 Oh 1 0 5041 sec Bu 0 vinyl 3 Oh 0 1 5042 sec Bu 0 vinyl 2 Oh 2 0 5043 sec Bu 0 vinyl 2 Oh 1 1 5044 sec Bu 0 vinyl 2 Oh 0 2 5045 sec Bu 0 vinyl 1 Oh 3 0 5046 sec Bu 0 vinyl 1 Oh 2 1 5047 sec Bu 0 vinyl 1 Oh 1 2 5048 sec Bu 0 vinyl 1 Oh 0 3 5049 sec Bu 0 vinyl 0 Oh 4 0 5050 sec Bu 0 vinyl 0 Oh 3 1 5051 sec Bu 0 vinyl 0 Oh 2 2 5052 sec Bu 0 vinyl 0 Oh 1 3 5053 sec Bu 0 vinyl 0 Oh 0 4

[0207] [Chemical 172] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5054 sec Bu 2 Allyl 2 Oh 0 0 5055 sec Bu 2 Allyl 1 Oh 1 0 5056 sec Bu 2 Allyl 1 Oh 0 1 5057 sec Bu 2 Allyl 0 Oh 2 0 5058 sec Bu 2 Allyl 0 Oh 1 1 5059 sec Bu 2 Allyl 0 Oh 0 2 5060 sec Bu 1 Allyl 3 Oh 0 0 5061 sec Bu 1 Allyl 2 Oh 1 0 5062 sec Bu 1 Allyl 2 Oh 0 1 5063 sec Bu 1 Allyl 1 Oh 2 0 5064 sec Bu 1 Allyl 1 Oh 1 1 5065 sec Bu 1 Allyl 1 Oh 0 2 5066 sec Bu 1 Allyl 0 Oh 3 0 5067 sec Bu 1 Allyl 0 Oh 2 1 5068 sec Bu 1 Allyl 0 Oh 1 2 5069 sec Bu 1 Allyl 0 Oh 0 3 5070 sec Bu 0 Allyl 4 Oh 0 0 5071 sec Bu 0 Allyl 3 Oh 1 0 5072 sec Bu 0 Allyl 3 Oh 0 1 5073 sec Bu 0 Allyl 2 Oh 2 0 5074 sec Bu 0 Allyl 2 Oh 1 1 5075 sec Bu 0 Allyl 2 Oh 0 2 5076 sec Bu 0 Allyl 1 Oh 3 0 5077 sec Bu 0 Allyl 1 Oh 2 1 5078 sec Bu 0 Allyl 1 Oh 1 2 5079 sec Bu 0 Allyl 1 Oh 0 3 5080 sec Bu 0 Allyl 0 Oh 4 0 5081 sec Bu 0 Allyl 0 Oh 3 1 5082 sec Bu 0 Allyl 0 Oh 2 2 5083 sec Bu 0 Allyl 0 Oh 1 3 5084 sec Bu 0 Allyl 0 Oh 0 4

[0208] [Chemical 173] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5085 sec Bu 2 Ethynyl 2 Oh 0 0 5086 sec Bu 2 Ethynyl 1 Oh 1 0 5087 sec Bu 2 Ethynyl 1 Oh 0 1 5088 sec Bu 2 Ethynyl 0 Oh 2 0 5089 sec Bu 2 Ethynyl 0 Oh 1 1 5090 sec Bu 2 Ethynyl 0 Oh 0 2 5091 sec Bu 1 Ethynyl 3 Oh 0 0 5092 sec Bu 1 Ethynyl 2 Oh 1 0 5093 sec Bu 1 Ethynyl 2 Oh 0 1 5094 sec Bu 1 Ethynyl 1 Oh 2 0 5095 sec Bu 1 Ethynyl 1 Oh 1 1 5096 sec Bu 1 Ethynyl 1 Oh 0 2 5097 sec Bu 1 Ethynyl 0 Oh 3 0 5098 sec Bu 1 Ethynyl 0 Oh 2 1 5099 sec Bu 1 Ethynyl 0 Oh 1 2 5100 sec Bu 1 Ethynyl 0 Oh 0 3 5101 sec Bu 0 Ethynyl 4 Oh 0 0 5102 sec Bu 0 Ethynyl 3 Oh 1 0 5103 sec Bu 0 Ethynyl 3 Oh 0 1 5104 sec Bu 0 Ethynyl 2 Oh 2 0 5105 sec Bu 0 Ethynyl 2 Oh 1 1 5106 sec Bu 0 Ethynyl 2 Oh 0 2 5107 sec Bu 0 Ethynyl 1 Oh 3 0 5108 sec Bu 0 Ethynyl 1 Oh 2 1 5109 sec Bu 0 Ethynyl 1 Oh 1 2 5110 sec Bu 0 Ethynyl 1 Oh 0 3 5111 sec Bu 0 Ethynyl 0 Oh 4 0 5112 sec Bu 0 Ethynyl 0 Oh 3 1 5113 sec Bu 0 Ethynyl 0 Oh 2 2 5114 sec Bu 0 Ethynyl 0 Oh 1 3 5115 sec Bu 0 Ethynyl 0 Oh 0 4

[0209] [Chemical 174] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5116 sec Bu 2 vinyl 2 OMe 0 0 5117 sec Bu 2 vinyl 1 OMe 1 0 5118 sec Bu 2 vinyl 1 OMe 0 1 5119 sec Bu 2 vinyl 0 OMe 2 0 5120 sec Bu 2 vinyl 0 OMe 1 1 5121 sec Bu 2 vinyl 0 OMe 0 2 5122 sec Bu 1 vinyl 3 OMe 0 0 5123 sec Bu 1 vinyl 2 OMe 1 0 5124 sec Bu 1 vinyl 2 OMe 0 1 5125 sec Bu 1 vinyl 1 OMe 2 0 5126 sec Bu 1 vinyl 1 OMe 1 1 5127 sec Bu 1 vinyl 1 OMe 0 2 5128 sec Bu 1 vinyl 0 OMe 3 0 5129 sec Bu 1 vinyl 0 OMe 2 1 5130 sec Bu 1 vinyl 0 OMe 1 2 5131 sec Bu 1 vinyl 0 OMe 0 3 5132 sec Bu 0 vinyl 4 OMe 0 0 5133 sec Bu 0 vinyl 3 OMe 1 0 5134 sec Bu 0 vinyl 3 OMe 0 1 5135 sec Bu 0 vinyl 2 OMe 2 0 5136 sec Bu 0 vinyl 2 OMe 1 1 5137 sec Bu 0 vinyl 2 OMe 0 2 5138 sec Bu 0 vinyl 1 OMe 3 0 5139 sec Bu 0 vinyl 1 OMe 2 1 5140 sec Bu 0 vinyl 1 OMe 1 2 5141 sec Bu 0 vinyl 1 OMe 0 3 5142 sec Bu 0 vinyl 0 OMe 4 0 5143 sec Bu 0 vinyl 0 OMe 3 1 5144 sec Bu 0 vinyl 0 OMe 2 2 5145 sec Bu 0 vinyl 0 OMe 1 3 5146 sec Bu 0 vinyl 0 OMe 0 4

[0210] [Chemical 175] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5147 sec Bu 2 Allyl 2 OMe 0 0 5148 sec Bu 2 Allyl 1 OMe 1 0 5149 sec Bu 2 Allyl 1 OMe 0 1 5150 sec Bu 2 Allyl 0 OMe 2 0 5151 sec Bu 2 Allyl 0 OMe 1 1 5152 sec Bu 2 Allyl 0 OMe 0 2 5153 sec Bu 1 Allyl 3 OMe 0 0 5154 sec Bu 1 Allyl 2 OMe 1 0 5155 sec Bu 1 Allyl 2 OMe 0 1 5156 sec Bu 1 Allyl 1 OMe 2 0 5157 sec Bu 1 Allyl 1 OMe 1 1 5158 sec Bu 1 Allyl 1 OMe 0 2 5159 sec Bu 1 Allyl 0 OMe 3 0 5160 sec Bu 1 Allyl 0 OMe 2 1 5161 sec Bu 1 Allyl 0 OMe 1 2 5162 sec Bu 1 Allyl 0 OMe 0 3 5163 sec Bu 0 Allyl 4 OMe 0 0 5164 sec Bu 0 Allyl 3 OMe 1 0 5165 sec Bu 0 Allyl 3 OMe 0 1 5166 sec Bu 0 Allyl 2 OMe 2 0 5167 sec Bu 0 Allyl 2 OMe 1 1 5168 sec Bu 0 Allyl 2 OMe 0 2 5169 sec Bu 0 Allyl 1 OMe 3 0 5170 sec Bu 0 Allyl 1 OMe 2 1 5171 sec Bu 0 Allyl 1 OMe 1 2 5172 sec Bu 0 Allyl 1 OMe 0 3 5173 sec Bu 0 Allyl 0 OMe 4 0 5174 sec Bu 0 Allyl 0 OMe 3 1 5175 sec Bu 0 Allyl 0 OMe 2 2 5176 sec Bu 0 Allyl 0 OMe 1 3 5177 sec Bu 0 Allyl 0 OMe 0 4

[0211] [Chem. 176] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5178 sec Bu 2 Ethynyl 2 OMe 0 0 5179 sec Bu 2 Ethynyl 1 OMe 1 0 5180 sec Bu 2 Ethynyl 1 OMe 0 1 5181 sec Bu 2 Ethynyl 0 OMe 2 0 5182 sec Bu 2 Ethynyl 0 OMe 1 1 5183 sec Bu 2 Ethynyl 0 OMe 0 2 5184 sec Bu 1 Ethynyl 3 OMe 0 0 5185 sec Bu 1 Ethynyl 2 OMe 1 0 5186 sec Bu 1 Ethynyl 2 OMe 0 1 5187 sec Bu 1 Ethynyl 1 OMe 2 0 5188 sec Bu 1 Ethynyl 1 OMe 1 1 5189 sec Bu 1 Ethynyl 1 OMe 0 2 5190 sec Bu 1 Ethynyl 0 OMe 3 0 5191 sec Bu 1 Ethynyl 0 OMe 2 1 5192 sec Bu 1 Ethynyl 0 OMe 1 2 5193 sec Bu 1 Ethynyl 0 OMe 0 3 5194 sec Bu 0 Ethynyl 4 OMe 0 0 5195 sec Bu 0 Ethynyl 3 OMe 1 0 5196 sec Bu 0 Ethynyl 3 OMe 0 1 5197 sec Bu 0 Ethynyl 2 OMe 2 0 5198 sec Bu 0 Ethynyl 2 OMe 1 1 5199 sec Bu 0 Ethynyl 2 OMe 0 2 5200 sec Bu 0 Ethynyl 1 OMe 3 0 5201 sec Bu 0 Ethynyl 1 OMe 2 1 5202 sec Bu 0 Ethynyl 1 OMe 1 2 5203 sec Bu 0 Ethynyl 1 OMe 0 3 5204 sec Bu 0 Ethynyl 0 OMe 4 0 5205 sec Bu 0 Ethynyl 0 OMe 3 1 5206 sec Bu 0 Ethynyl 0 OMe 2 2 5207 sec Bu 0 Ethynyl 0 OMe 1 3 5208 sec Bu 0 Ethynyl 0 OMe 0 4

[0212] [Chemical 177] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5209 sec Bu 2 vinyl 2 OEt 0 0 5210 sec Bu 2 vinyl 1 OEt 1 0 5211 sec Bu 2 vinyl 1 OEt 0 1 5212 sec Bu 2 vinyl 0 OEt 2 0 5213 sec Bu 2 vinyl 0 OEt 1 1 5214 sec Bu 2 vinyl 0 OEt 0 2 5215 sec Bu 1 vinyl 3 OEt 0 0 5216 sec Bu 1 vinyl 2 OEt 1 0 5217 sec Bu 1 vinyl 2 OEt 0 1 5218 sec Bu 1 vinyl 1 OEt 2 0 5219 sec Bu 1 vinyl 1 OEt 1 1 5220 sec Bu 1 vinyl 1 OEt 0 2 5221 sec Bu 1 vinyl 0 OEt 3 0 5222 sec Bu 1 vinyl 0 OEt 2 1 5223 sec Bu 1 vinyl 0 OEt 1 2 5224 sec Bu 1 vinyl 0 OEt 0 3 5225 sec Bu 0 vinyl 4 OEt 0 0 5226 sec Bu 0 vinyl 3 OEt 1 0 5227 sec Bu 0 vinyl 3 OEt 0 1 5228 sec Bu 0 vinyl 2 OEt 2 0 5229 sec Bu 0 vinyl 2 OEt 1 1 5230 sec Bu 0 vinyl 2 OEt 0 2 5231 sec Bu 0 vinyl 1 OEt 3 0 5232 sec Bu 0 vinyl 1 OEt 2 1 5233 sec Bu 0 vinyl 1 OEt 1 2 5234 sec Bu 0 vinyl 1 OEt 0 3 5235 sec Bu 0 vinyl 0 OEt 4 0 5236 sec Bu 0 vinyl 0 OEt 3 1 5237 sec Bu 0 vinyl 0 OEt 2 2 5238 sec Bu 0 vinyl 0 OEt 1 3 5239 sec Bu 0 vinyl 0 OEt 0 4

[0213] [Chemical 178] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5240 sec Bu 2 Allyl 2 OEt 0 0 5241 sec Bu 2 Allyl 1 OEt 1 0 5242 sec Bu 2 Allyl 1 OEt 0 1 5243 sec Bu 2 Allyl 0 OEt 2 0 5244 sec Bu 2 Allyl 0 OEt 1 1 5245 sec Bu 2 Allyl 0 OEt 0 2 5246 sec Bu 1 Allyl 3 OEt 0 0 5247 sec Bu 1 Allyl 2 OEt 1 0 5248 sec Bu 1 Allyl 2 OEt 0 1 5249 sec Bu 1 Allyl 1 OEt 2 0 5250 sec Bu 1 Allyl 1 OEt 1 1 5251 sec Bu 1 Allyl 1 OEt 0 2 5252 sec Bu 1 Allyl 0 OEt 3 0 5253 sec Bu 1 Allyl 0 OEt 2 1 5254 sec Bu 1 Allyl 0 OEt 1 2 5255 sec Bu 1 Allyl 0 OEt 0 3 5256 sec Bu 0 Allyl 4 OEt 0 0 5257 sec Bu 0 Allyl 3 OEt 1 0 5258 sec Bu 0 Allyl 3 OEt 0 1 5259 sec Bu 0 Allyl 2 OEt 2 0 5260 sec Bu 0 Allyl 2 OEt 1 1 5261 sec Bu 0 Allyl 2 OEt 0 2 5262 sec Bu 0 Allyl 1 OEt 3 0 5263 sec Bu 0 Allyl 1 OEt 2 1 5264 sec Bu 0 Allyl 1 OEt 1 2 5265 sec Bu 0 Allyl 1 OEt 0 3 5266 sec Bu 0 Allyl 0 OEt 4 0 5267 sec Bu 0 Allyl 0 OEt 3 1 5268 sec Bu 0 Allyl 0 OEt 2 2 5269 sec Bu 0 Allyl 0 OEt 1 3 5270 sec Bu 0 Allyl 0 OEt 0 4

[0214] [Chemical 179] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5271 sec Bu 2 Ethynyl 2 OEt 0 0 5272 sec Bu 2 Ethynyl 1 OEt 1 0 5273 sec Bu 2 Ethynyl 1 OEt 0 1 5274 sec Bu 2 Ethynyl 0 OEt 2 0 5275 sec Bu 2 Ethynyl 0 OEt 1 1 5276 sec Bu 2 Ethynyl 0 OEt 0 2 5277 sec Bu 1 Ethynyl 3 OEt 0 0 5278 sec Bu 1 Ethynyl 2 OEt 1 0 5279 sec Bu 1 Ethynyl 2 OEt 0 1 5280 sec Bu 1 Ethynyl 1 OEt 2 0 5281 sec Bu 1 Ethynyl 1 OEt 1 1 5282 sec Bu 1 Ethynyl 1 OEt 0 2 5283 sec Bu 1 Ethynyl 0 OEt 3 0 5284 sec Bu 1 Ethynyl 0 OEt 2 1 5285 sec Bu 1 Ethynyl 0 OEt 1 2 5286 sec Bu 1 Ethynyl 0 OEt 0 3 5287 sec Bu 0 Ethynyl 4 OEt 0 0 5288 sec Bu 0 Ethynyl 3 OEt 1 0 5289 sec Bu 0 Ethynyl 3 OEt 0 1 5290 sec Bu 0 Ethynyl 2 OEt 2 0 5291 sec Bu 0 Ethynyl 2 OEt 1 1 5292 sec Bu 0 Ethynyl 2 OEt 0 2 5293 sec Bu 0 Ethynyl 1 OEt 3 0 5294 sec Bu 0 Ethynyl 1 OEt 2 1 5295 sec Bu 0 Ethynyl 1 OEt 1 2 5296 sec Bu 0 Ethynyl 1 OEt 0 3 5297 sec Bu 0 Ethynyl 0 OEt 4 0 5298 sec Bu 0 Ethynyl 0 OEt 3 1 5299 sec Bu 0 Ethynyl 0 OEt 2 2 5300 sec Bu 0 Ethynyl 0 OEt 1 3 5301 sec Bu 0 Ethynyl 0 OEt 0 4

[0215] [Chemical 180] Formula 1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5302 sec Bu 2 vinyl 2 o n PR 0 0 5303 sec Bu 2 vinyl 1 o n PR 1 0 5304 sec Bu 2 vinyl 1 o n PR 0 1 5305 sec Bu 2 vinyl 0 o n PR 2 0 5306 sec Bu 2 vinyl 0 o n PR 1 1 5307 sec Bu 2 vinyl 0 o n PR 0 2 5308 sec Bu 1 vinyl 3 o n PR 0 0 5309 sec Bu 1 vinyl 2 o n PR 1 0 5310 sec Bu 1 vinyl 2 o n PR 0 1 5311 sec Bu 1 vinyl 1 o n PR 2 0 5312 sec Bu 1 vinyl 1 o n PR 1 1 5313 sec Bu 1 vinyl 1 o n PR 0 2 5314 sec Bu 1 vinyl 0 o n PR 3 0 5315 sec Bu 1 vinyl 0 o n PR 2 1 5316 sec Bu 1 vinyl 0 o n PR 1 2 5317 sec Bu 1 vinyl 0 o n PR 0 3 5318 sec Bu 0 vinyl 4 o n PR 0 0 5319 sec Bu 0 vinyl 3 o n PR 1 0 5320 sec Bu 0 vinyl 3 o n PR 0 1 5321 sec Bu 0 vinyl 2 o n PR 2 0 5322 sec Bu 0 vinyl 2 o n PR 1 1 5323 sec Bu 0 vinyl 2 o n PR 0 2 5324 sec Bu 0 vinyl 1 o n PR 3 0 5325 sec Bu 0 vinyl 1 o n PR 2 1 5326 sec Bu 0 vinyl 1 o n PR 1 2 5327 sec Bu 0 vinyl 1 o n PR 0 3 5328 sec Bu 0 vinyl 0 o n PR 4 0 5329 sec Bu 0 vinyl 0 o n PR 3 1 5330 sec Bu 0 vinyl 0 o n PR 2 2 5331 sec Bu 0 vinyl 0 o n PR 1 3 5332 sec Bu 0 vinyl 0 o n PR 0 4

[0216] [Chemical 181] Formula (1) compound R 1 R 2 alkenyl or alkynyl alkoxy or hydroxyl A hydrogen atom structure (4-a) structure Number structure Number Number 5333 sec Bu 2 Allyl 2 o n PR 0 0 5334 sec Bu 2 Allyl 1 o n PR 1 0 5335 sec Bu 2 Allyl 1 o n PR 0 1 5336 sec Bu 2 Allyl 0 o n PR 2 0 5337 sec Bu 2 Allyl 0 o n PR 1 1 5338 sec Bu 2 Allyl 0 o n PR 0 2 5339 sec Bu 1 Allyl 3 o n PR 0 0 5340 sec Bu 1 Allyl 2 o n PR 1 0 5341 sec Bu 1 Allyl 2 o n PR 0 1 5342 sec Bu 1 Allyl 1 o n PR 2 0 5343 sec Bu 1 Allyl 1 o n PR 1 1 5344 sec Bu 1 Allyl 1 o n PR 0 2 5345 sec Bu 1 Allyl 0 o n PR 3 0 5346 sec Bu 1 Allyl 0 o n PR 2 1 5347 sec Bu 1 Allyl 0 o n PR 1 2 5348 sec Bu 1 Allyl 0 o n PR 0 3 5349 sec Bu 0 Allyl 4 o n PR 0 0 5350 sec Bu 0 Allyl 3 o n PR 1 0 5351 sec Bu 0 Allyl 3 o n PR 0 1 5352 sec Bu 0 Allyl 2 o n PR 2 0 5353 sec Bu 0 Allyl 2 o n PR 1 1 5354 sec Bu 0 Allyl 2 o n PR 0 2 ...

Claims

1. A method for manufacturing a planarization film, wherein a planarization film is formed on a substrate having an uneven surface by plasma-enhanced chemical vapor deposition (PECVD) using a planarization film material to planarize the uneven surface, wherein the planarization film material comprises: an organosilane compound, an alcohol or a combination of an alcohol and water, and an oxidant, and the planarization film is formed by sequentially or simultaneously forming and curing an uncured film derived from the planarization film material on the substrate, wherein the formation and curing of the uncured film are both caused by a plasma-induced chemical reaction.

2. The method for manufacturing a planarization film as claimed in claim 1, wherein the formation and curing of the uncured film are performed in a single process.

3. A method for manufacturing a planarization film as described in claim 1 or claim 2, wherein the surface temperature of the substrate during the formation of the planarization film is below 300°C.

4. A method for manufacturing a planarization film as described in claim 1 or claim 2, wherein the ambient pressure during the formation of the planarization film is in the range of 0.01 Pa or more and 101325 Pa or less.

5. A method for manufacturing a planarization film as claimed in claim 1 or claim 2, wherein the planarization film is formed when the flow rate of the organosilicon compound used as the material for the planarization film is set to X [sccm], the flow rate of the alcohol or a combination of alcohol and water is set to Y [sccm], and the flow rate of the oxidant is set to Z [sccm], wherein the ratio of Y to X (Y / X ratio) is 20 or less, and the ratio of Z to X (Z / X ratio) is 20 or less.

6. A planarization film material, a planarization film material for planarizing uneven surfaces in a substrate, the planarization film material containing one or more organosilicon compounds selected from the group consisting of monosilanes represented by formula (1), disiloxanes represented by formula (2), cyclic siloxanes represented by formula (3), and trisiloxanes represented by formula (4), the planarization film material further containing an alcohol or a combination of an alcohol and water, wherein in formula (1), R1 is phenyl or benzyl, or a linear, branched, or cyclic alkyl group having 1 to 10 carbon atoms, R2 is an alkenyl, alkynyl, alkoxy, hydroxyl, or hydrogen atom having 1 to 10 carbon atoms, and a is an integer from 2 to 4, and in formula (2), R3 is phenyl or benzyl, or a linear, branched, or cyclic alkyl group having 1 to 10 carbon atoms. R4 is an alkenyl group, an alkynyl group, an alkoxy group, a hydroxyl group, or a hydrogen atom with 1 to 10 carbon atoms; b is an integer from 1 to 3. In formula (3), R5 is a phenyl or benzyl group, or a straight-chain, branched, or cyclic alkyl group with 1 to 10 carbon atoms; R6 is an alkenyl group, an alkynyl group, an alkoxy group, a hydroxyl group, or a hydrogen atom with 1 to 10 carbon atoms; c is an integer from 0 to 2; n is an integer from 2 to 6. In formula (4), R7 is a phenyl or benzyl group, or a straight-chain, branched, or cyclic alkyl group with 1 to 10 carbon atoms; R8 is an alkenyl group, an alkynyl group, an alkoxy group, a hydroxyl group, or a hydrogen atom with 1 to 10 carbon atoms; R9 is a phenyl or benzyl group, or a straight-chain, branched, or cyclic alkyl group with 1 to 10 carbon atoms. R10 is an alkenyl group, alkynyl group, alkoxy group, hydroxyl group, or hydrogen atom with 1 to 10 carbon atoms, d is an integer from 0 to 3, and e is an integer from 0 to 2.

7. The planarization film material as described in claim 6, used to form an organic electric field light-emitting element.

8. The planarization film material as described in claim 6 further contains an oxidizing agent.

9. A planarization film comprising at least one component derived from the organosilane compound in the planarization film material as described in any one of claims 6 to 8.

10. The planarization film as described in claim 9 is an unannealed product.

11. The planarization film as claimed in claim 9, wherein the carbon concentration in the planarization film is less than 10 atomic%.

12. An electronic device comprising a planarization film as described in claim 9.

13. The electronic device as claimed in claim 12 further includes an organic electric field light-emitting element.

14. A coating comprising a planarization film as described in claim 9.

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