TRPM8 modulators and related method for modulating TRPM8 receptors

Abstract

Suggested are specific TRPM8 modulators according to Formula (I) and their use as physiological cooling agents.

Description

TRPM8 modulators and related method for modulating TRPM8 receptors ___________________________________________________________________________________________________ AREA OF INVENTION

[0001] The present invention refers to the area of cosmetics and food preparation and relate to new physiological cooling agents capable of modulating TRPM8 receptors, topical and oral compositions comprising them and a related method for modulating TRPM8 receptors. BACKGROUND OF THE INVENTION

[0002] Physiological cooling actives achieve their cooling effect by modulation of TRPM8 receptors. They are used regularly in order to cause a cool sensory impression on the skin or mucosa, for example on the mucosa in the oral cavity, nasal cavity and / or pharyngeal cavity, even though no physical cooling as, for example, in the evaporation of solvents actually takes place. Physiological cooling actives used may be either individual components or mixtures. It should be taken into account here that not all compounds that influence receptors in vitro and are (also) involved in imparting a physiological cooling effect actually generate such an effect in vivo on the skin or mucosa. More particularly, such an effect will not always have an identical progression. This means, for example, that the intensity of the physiological cooling effect imparted and the progression of the intensity of the cooling effect over time cannot be concluded solely from the fact that a particular compound is an agonist of a receptor in- volved in the imparting of a cool impression. The most widely known physiologically active cooling active is L-menthol, but it has some disadvantages, for example a strong odour im- pression, high volatility and, in relatively high concentrations, a bitter and / or sharp intrinsic taste, or an irritating effect on the skin.

[0003] Over the past decades, a large number of different substances have been developed that possess physiological cooling properties and have since found their way into a wide range of sales products. In addition to a wide variety of menthol derivatives, amides of the WS type are particularly worthy of mention. However, while development in recent years has focused on providing increasingly powerful cooling agents in order to reduce the quantities used, or on synthesizing substances that produce a particularly long-lasting cooling experi- ence, the market is now occupied with the search for cooling agents that possess additional properties, so-called "multi-purpose products". In particular, there is interest in substances with outstanding cooling performance, but which are also capable at the same time, to mask the unpleasant odour or taste of ingredients that cannot be replaced in the formulation. A typical example is fluorine compounds used in dental care products. There is also a constant need for substances that perform important tasks in the above-mentioned preparations, suchas for example providing a physiological cooling effect on the skin or mucous membrane, while also exhibiting other properties that are important for the formulation. Special interest is shown in preparations which, preferably even in very small quantities, are capable of inten- sifying positive taste or odor impressions or of bringing them to bear in the first place. RELEVANT PRIOR ART

[0004] WO 2011061330 A2 (BASF) discloses modulators of TRPM8 receptors following one of the following structures:

[0005] WO 2019 043164 A1 (BASF) and WO 2022 207944 A1 (SYMRISE) claim a similar method involving modulators of for example the following structure:

[0006] WO 2021 074281 A1 (GIVAUDAN) refers TRPM8 inhibitors having the following structure:

[0007] US 2016 339026 (SENOMYX) discloses physiological cooling compounds of the fol- lowing structure:OBJECT OF THE INVENTION

[0008] Therefore, it has been the object of the present invention providing new TRPM8 modulators which are not only providing a cooling effect, but are also capable of masking unpleasant flavors, particularly unpleasant flavors of fluorine derivatives and bitter com- pounds; and / or enhance and / or boost the performance of a flavor, a sweetener or a soothing agent. BRIEF DESCRIPTION OF THE INVENTION

[0009] A first object of the present invention refers to TRPM8 modulators according to For- mula (I)in which the substituents have the following meanings:R1 or mono- or polynuclear aryl, arylalkyl and heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halo- gens, linear or branched C1-C6alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S; R2 mono- or polynuclear aryl, arylalkyl and heteroaryl groups carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6 alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S; R3 Independently from each other hydrogen; halogens; linear or branched C1-C6 alkyl groups optionally bearing 1, 2, 3 or 4 identical or different substituents selected from the group con- R4 sisting of NH2, OH, SH, halogens or linear or branched C1-C6alkyl groups; linear or branched C1- to C6-alkoxy groups optionally carrying 1, 2, 3 or 4 identical or different substituents R5 selected from the group consisting of NH2, OH, SH, halogens or C1-C6-alkoxy groups; mono- or polynuclear aryl, arylalkyl and heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or R6 different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6-alkyl groups; the heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms R7 which are the same or different and are selected from the group consisting of O, N and S, or two adjacent radicals R3, R4, R5, R6 and R7 together with the carbon atoms to which they are attached form a 4-, 5-, 6- or 7-membered, mono- or polyunsaturated heterocyclic ring op- tionally bearing 1, 2, 3, 4 or 5 identical or different substituents selected from the group con- sisting of linear or branched C1-C6 alkyl groups, and having 1, 2 or 3 ring heteroatoms, identi- cal or different, selected from the group consisting of O, N and S;; R8 Independently from each other linear or branched C1-C6 alkyl or alkoxy groups, or C2-C6 alkenyl groups; R9 R10 X linear or branched C1-C6alkylene groups or C2-C6alkenylene groups; Y hydrogen, linear or branched C1-C6 alkylene groups or C2-C6 alkenylene groups; Z oxygen or sulfur

[0010] In a preferred first embodiment the substituents of Formula (I) have the following meanings:R1 R2 mono- or polynuclear aryl, arylalkyl and heteroaryl groups carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6 alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S; R3 Independently from each other hydrogen; halogens; linear or branched C1-C6 alkyl groups optionally bearing 1, 2, 3 or 4 identical or different substituents selected from the group con- R4 sisting of NH2, OH, SH, halogens or linear or branched C1-C6 alkyl groups; linear or branched C1- to C6-alkoxy groups optionally carrying 1, 2, 3 or 4 identical or different substituents R5 selected from the group consisting of NH2, OH, SH, halogens or C1-C6-alkoxy groups; mono- or polynuclear aryl, arylalkyl and heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or R6 different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6-alkyl groups; the heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms R7 which are the same or different and are selected from the group consisting of O, N and S, or two adjacent radicals R3, R4, R5, R6 and R7 together with the carbon atoms to which they are attached form a 4-, 5-, 6- or 7-membered, mono- or polyunsaturated heterocyclic ring op- tionally bearing 1, 2, 3, 4 or 5 identical or different substituents selected from the group con- sisting of linear or branched C1-C6 alkyl groups, and having 1, 2 or 3 ring heteroatoms, identi- cal or different, selected from the group consisting of O, N and S;; R8 each standing for methyl R9 R10 X linear or branched C1-C4 alkylene groups or C2-C4 alkenylene groups; Y hydrogen Z oxygen

[0011] In another preferred embodiment the substituents of Formula (I) have the following meanings: R1 mono- or polynuclear aryl, arylalkyl and heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halo- gens, linear or branched C1-C6alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S;R2 mono- or polynuclear aryl, arylalkyl and heteroaryl groups carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of linear or branched C1-C6 alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S; R3 independently from each other hydrogen; halogens; linear or branched C1-C6alkyl groups optionally bearing 1, 2, 3 or 4 identical or different substituents selected from the group con- R4 sisting of NH2, OH, SH, halogens or linear or branched C1-C6 alkyl groups; linear or branched C1- to C6-alkoxy groups optionally carrying 1, 2, 3 or 4 identical or different substituents R5 selected from the group consisting of NH2, OH, SH, halogens or C1-C6-alkoxy groups; mono- or polynuclear aryl, arylalkyl and heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or R6 different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6-alkyl groups; the heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms R7 which are the same or different and are selected from the group consisting of O, N and S, or two adjacent radicals R3, R4, R5, R6 and R7 together with the carbon atoms to which they are attached form a 4-, 5-, 6- or 7-membered, mono- or polyunsaturated heterocyclic ring op- tionally bearing 1, 2, 3, 4 or 5 identical or different substituents selected from the group con- sisting of linear or branched C1-C6 alkyl groups, and having 1, 2 or 3 ring heteroatoms, identi- cal or different, selected from the group consisting of O, N and S;; R8 each standing for methyl R9 R10 X linear or branched C1-C4 alkylene groups or C2-C4 alkenylene groups; Y hydrogen Z oxygen

[0012] In the most preferred embodiment, the TRPM8 modulator has the following structure:

[0013] Surprisingly it has been found that slight structural modifications of already existing cooling agents improve their ability particularly to mask the unpleasant taste of bitter com- pounds, such as fluorine salts or polyphenols.Blends of cooling agents

[0014] Physiological cooling agents are liquid or solid, particular crystalline substances. The sensation of cold is not triggered physically, but by binding of the cooling agent to a cold receptor that is physiologically activated by cool temperatures. This is the cation channel TRPM8 from the family of TRP channels. TRPM8 is localized at free nerve terminals of afferent A and C fibers and is of central importance for the sensation of cold. Physiological cooling agents, forming component (a) such as menthol and menthol compounds are preferably se- lected from the group formed by the species depicted in the following table (including their optical isomers and racemates):

[0015] Component FEMA / GRAS Product / Trademark Menthol Menthol glyceryl acetal 3807 Frescolat° MGA Menthol glyceryl ketal 3808 Frescolat° MGA Menthol menthyl ether Menthone glyceryl acetal Menthone glyceryl ketal Menthoxy-1,2-propandiol 3784 Menthoxy-2-methyl-1,2-propanediol 3849 Menthyl acetate SymFresh° RF Menthyl ethylene glycol carbonate 3805 Frescolat° MGC Menthyl formiate Menthyl glutamate 4006 Menthyl glycerol carbonate Menthyl hydroxy isobutyrate Menthyl isobutyrate Menthyl lactate Frescolat° ML Menthyl malonate Menthyl methyl ether Menthyl N-ethyl oxamate Menthyl propylene glycol carbonate 3806 Frescolat° MPC Menthyl pyroglutamate Menthyl-(2-methoxy)acetate Menthyl-(2-methoxyethoxy)acetate Menthyl succinate 3810O-Menthyl succinic acid ester amide O-Menthyl succinic acid ester-NN-(dimethyl)amide Menthane carboxylic acid-N-(4-cyanophenyl)amide Menthane carboxylic acid-N-(4-cyanomethylphenyl)amide Menthane carboxylic acid-N-ethylamide (WS-3) (WS-4) Nα-(menthane carbonyl) glycinc ethylester (WS-5) (1R,2S,5R)-N-(4-Methoxyphenyl)-5-methyl-2-(1- isopropyl)cyclohexane-carboxamide (WS-12) (WS-14) 2,3-dimethyl-2-(2-propyl)-butyric acid-N-methylamide (WS23) Isopulegol acetate p-Menthane-3,8-diol Cubebol3-Methyl-2(1-pyrrolidinyl)-2-cyclopentene-1-one) Tetrahydropyrimidine-2-one N-(2-(pyridin-2-yl)ethyl)-3-p-menthanecarboxamide [(1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl] 2-(ethylamino)- X Cool 2-oxo-acetate Frescolat Fuji

[0016] A first important representative of the substances forming component (b) is mono- menthyl succinate, which as a substance was patented as early as 1963 by Brown & William- son Tobacco Corp. (US 3,111,127) and as a refrigerant is the subject of property rights US 5,725,865 and 5,843,466 (V.Mane Fils). Both the succinate and the analogous monomenthyl glutarate are important representatives of monomenthyl esters based on di- and polycarbox- ylic acids:

[0017] Examples of applications of these substances can be found, for example, in the print- ed documents WO 2003043431 (Unilever) or EP 1332772 A1 (IFF).

[0018] The next important group of menthol compounds preferred in the sense of the inven- tion comprises carbonate esters of menthol and polyols, such as glycols, glycerol or carbohy- drates, such as menthol ethylene glycol carbonates, menthol propylene glycol carbonates, menthol 2-methyl-1,2-propanediol carbonates or the corresponding sugar derivatives:

[0019] The use of such substances as a cooling agent for cigarettes is, for example, the sub- ject of the 1968 publication US 3,419,543 (Mold et al.); their use as a physiological cooling agent is claimed in DE 4226043 A1 (H&R).

[0020] In the sense of the invention, the menthol compounds menthyl lactate) and, in partic- ular, menthone glyceryl acetal or menthone glyceryl ketal are preferred.

[0021] The former structure is obtained by esterification of lactic acid with menthol, the latter by acetylation of menthone with glycerol (cf. DE 2608226 A1, H&R). This group of com- pounds also includes 3-(l-menthoxy)-1,2,propanediol, also known as Cooling Agent 10 (US 6,328,982, TIC), and 3-(l-menthoxy)-2-methyl-1,2,propanediol, which has an additional methyl group.

[0022] For example, 3-(l-menthoxy)-1,2,propanediol is prepared starting from menthol ac- cording to the following scheme (see US 4,459,425, Takasago):

[0023] Alternative routes in which menthol is reacted with epichlorohydrin in the first step are described in US 6,407,293 and US 6,515,188 (Takasago). The following is an overview of preferred menthol compounds characterized by CO bonding:

[0024] Among these substances, menthone glyceryl acetal / ketal and menthyl lactate as well as menthol ethylene glycol carbonate and menthol propylene glycol carbonate.

[0025] In the 1970s, menthol compounds were developed for the first time which have a C-C bond in the 3-position and of which a number of representatives can also be used in the sense of the invention. These substances are generally referred to as WS types. The basic body is a menthol derivative in which the hydroxyl group is replaced by a carboxyl group (WS-1). All other WS types are derived from this structure, such as the species WS-3, WS-4, WS-5, WS-12, WS-14 and WS-30, which are also preferred in the sense of the invention. The following two diagrams show the synthesis routes:

[0026] The esters derived from WS-1 are described, for example, in US 4,157,384, and the corresponding N-substituted amides in J. Soc. Cosmet. Chem. pp.185-200 (1978).

[0027] The preferred physiological cooling agents forming component (b) are selected from the group consisting of: • Menthol • Menthol glyceryl acetal • Menthol glyceryl ketal • Menthol menthyl ether • Menthone glyceryl acetal • Menthone glyceryl ketal• Menthoxy-1,2-propandiol • Menthoxy-2-methyl-1,2-propanediol • Menthyl acetate • Menthyl ethylene glycol carbonate • Menthyl formiate • Menthyl glutamate • Menthyl glycerol carbonate • Menthyl hydroxy isobutyrate • Menthyl isobutyrate • Menthyl lactate • Menthyl malonate • Menthyl methyl ether • Menthyl N-ethyl oxamate • Menthyl propylene glycol carbonate • Menthyl pyroglutamate • Menthyl-(2-methoxy)acetate • Menthyl-(2-methoxyethoxy)acetate • Menthyl succinate • O-Menthyl succinic acid ester amide • O-Menthyl succinic acid ester-NN-(dimethyl)amide • Menthane carboxylic acid-N-(4-cyanophenyl)amide • Menthane carboxylic acid-N-(4-cyanomethylphenyl)amide • Menthane carboxylic acid-N-ethylamide (WS-3) • (WS-4) • Nα-(menthane carbonyl) glycine ethylester (WS-5) • (1R,2S,5R)-N-(4-Methoxyphenyl)-5-methyl-2-(1-isopropyl)cyclohexane- carboxamide (WS-12) • (WS-14) • 2,3-dimethyl-2-(2-propyl)-butyric acid-N-methylamide (WS23) • 3-(-)-Menthoxy)propane-1,2-diol • Isopulegol acetate • p-Menthane-3,8-diol • Cubebol• 3-Methyl-2(1-pyrrolidinyl)-2-cyclopentene-1-one) • Tetrahydropyrimidine-2-one • N-(2-(pyridin-2-yl)ethyl)-3-p-menthanecarboxamide • [(1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl] 2-(ethylamino)-2-oxo-acetate, and most preferred:• (2E)-3-(1,3-benzodioxol-5-yl)-N-phenyl-N-(tetrahydro-3-furanyl)-2- propenamide

[0028] Components (a) and (b) are preferably present in a ratio by weight of from about 0.1:99.9 to about 99.9:0.1, more preferably from about 1:99 to about 99:1 and most preferred from about 10:90 to about 90:10. COSMETIC COMPOSITIONS

[0029] Another object of the present invention refers to cosmetic compositions, preferably skin care or oral care compositions, comprising the modulators or blends of modulators as defined above in a working amount, for example about 0.001 to about 1 % b.w., preferably about 0.01 to about 0.5 % b.w. and particularly from about 0.1 to about 2 % b.w. – calculated on the composition(s). The composition may represent for example a cosmetic cream, lotion, spray, emulsion, ointment, gel, mouse, tooth paste, mouth wash and the like.

[0030] The preparations according to the invention may contain antidandruff agents, irrita- tion-preventing agents, irritation-inhibiting agents, antioxidants, adstringents, perspiration- inhibiting agents, antiseptic agents, ant-statics, binders, buffers, carrier materials, chelating agents, cell stimulants, cleansing agents, care agents, deodorizing agents, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibres, film-forming agents, fixatives, foam- forming agents, foam stabilizers, substances for preventing foaming, foam boosters, gelling agents, gel-forming agents, hair care agents, hair-setting agents, hair-straightening agents, moisture-donating agents, moisturizing substances, moisture-retaining substances, bleaching agents, strengthening agents, stain-removing agents, optically brightening agents, impreg- nating agents, dirt-repellent agents, friction-reducing agents, lubricants, moisturizing creams, ointments, opacifying agents, plasticizing agents, covering agents, polish, gloss agents, pol- ymers, powders, proteins, re-oiling agents, abrading agents, silicones, hair promotion agents,cooling agents, skin-cooling agents, warming agents, skin-warming agents, stabilizers, UV- absorbing agents, UV filters, detergents, thickeners, vitamins, oils, waxes, fats, phospholipids, saturated fatty acids, mono- or polyunsaturated fatty acids, α-hydroxy acids, polyhydroxyfatty acids, liquefiers, dyestuffs, colour-protecting agents, pigments, odoriferous substances, poly- ols, surfactants, electrolytes, organic solvents or silicone derivatives and the like as additional auxiliaries and additives. Surfactants

[0031] Preferred auxiliaries and additives are anionic and / or amphoteric or zwitterionic sur- factants. Non-ionic and cationic surfactants can be also present in the composition. Suitable examples are mentioned along with the paragraph dealing with emulsifiers.

[0032] Typical examples for anionic and zwitterionic surfactants encompass: Almondami- dopropylamine Oxide, Almondamidopropyl Betaine, Aminopropyl Laurylglutamine, Ammoni- um C12-15 Alkyl Sulfate, Ammonium C12-16 Alkyl Sulfate, Ammonium Capryleth Sulfate, Ammonium Cocomonoglyceride Sulfate, Ammonium Coco-Sulfate, Ammonium Cocoyl Isethionate, Ammonium Cocoyl Sarcosinate, Ammonium C12-15 Pareth Sulfate, Ammonium C9-10 Perfluoroalkylsulfonate, Ammonium Dinonyl Sulfosuccinate, Ammonium Dodecylben- zenesulfonate, Ammonium Isostearate, Ammonium Laureth-6 Carboxylate, Ammonium Lau- reth-8 Carboxylate, Ammonium Laureth Sulfate, Ammonium Laureth-5 Sulfate, Ammonium Laureth-7 Sulfate, Ammonium Laureth-9 Sulfate, Ammonium Laureth-12 Sulfate, Ammonium Lauroyl Sarcosinate, Ammonium Lauryl Sulfate, Ammonium Lauryl Sulfosuccinate, Ammoni- um Myreth Sulfate, Ammonium Myristyl Sulfate, Ammonium Nonoxynol-4 Sulfate, Ammoni- um Nonoxynol-30 Sulfate, Ammonium Oleate, Ammonium Palm Kernel Sulfate, Ammonium Stearate, Ammonium Tallate, AMPD-lsostearoyl Hydrolyzed Collagen, AMPD-Rosin Hydro- lyzed Collagen, AMP-lsostearoyl Hydrolyzed Collagen, AMP-lsostearoyl Hydrolyzed Keratin, AMP-lsostearoyl Hydrolyzed Soy Protein, AMP-lsostearoyl Hydrolyzed Wheat Protein, Aprico- tamidopropyl Betaine, Arachidic Acid, Arginine Hexyldecyl Phosphate, Avocadamidopropyl Betaine, Avocado Oil Glycereth-8 Esters, Babassu Acid, Babassuamidopropylamine Oxide, Babassuamidopropyl Betaine, Beeswax Acid, Behenamidopropyl Betaine, Behenamine Oxide, Beheneth-25, Beheneth-30, Behenic Acid, Behenyl Betaine, Bis- Butyldimethicone Polyglycer- yl-3, Butoxynol-5 Carboxylic Acid, Butoxynol-19 Carboxylic Acid, Butyldimoniumhydroxypro- pyl Butylglucosides Chloride, Butyldimoniumhydroxypropyl Laurylglucosides Chloride, Butyl Glucoside, Butylglucoside Caprate, Butylglucosides Hydroxypropyltrimonium Chloride, Bu- tyloctanoic Acid, C18-36 Acid, C20-40 Acid, C30-50 Acid, C16-22 Acid Amide MEA, Calcium Dodecylbenzenesulfonate, Calcium Lauroyl Taurate, C9-16 Alkane / Cycloalkane, C10-14 Alkyl Benzenesulfonic Acid, C12-14 Alkyl Diaminoethylglycine HCL, C9-15 Alkyl Phosphate, Can- dida Bombicola / Glucose / Methyl Rapeseedate Ferment, Canolamidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Capryl / Capramidopropyl Betaine, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Caprylic Acid,Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Capry- lyl / Capryl Glucoside, Caprylyl / Capryl Wheat Bran / Straw Glycosides, Caprylyl Glucoside, Capry- lyl Glyceryl Ether, Caprylyl Pyrrolidone, Carnitine, Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ce- teareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth- 100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Ceteareth-4 Phosphate, Ce- teareth-5 Phosphate, Ceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ce- teth-20 Phosphate, Cetoleth-22, Cetoleth-24, Cetoleth-25, Cetoleth-30, Cetyl Betaine, Chry- santhemum Sinense Flower Extract, C12-14 Hydroxyalkyl Hydroxyethyl Beta-Alanine, C12-14 Hydroxyalkyl Hydroxyethyl Sarcosine, Cocamidoethyl Betaine, Cocamidopropylamine Oxide, Cocamidopropyl Betainamide MEA Chloride, Cocamidopropyl Betaine, Cocamidopropyl Hy- droxysultaine, Cocamine Oxide, Cocaminobutyric Acid, Cocaminopropionic Acid, Coceth-7 Carboxylic Acid, Coceth-4 Glucoside, Cocoamphodipropionic Acid, Cocobetainamido Am- phopropionate, Coco-Betaine, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Coco- dimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Coco-Glucoside, Cocoglucosides Hydroxypropyltrimonium Chloride, Coco- Hydroxysultaine, Coco-Morpholine Oxide, Coconut Acid, Coconut Oil Glycereth-8 Esters, Co- co / Oleamidopropyl Betaine, Coco-Sultaine, Coco / Sunfloweramidopropyl Betaine, Cocoylcho- line Methosulfate, Cocoyl Glutamic Acid, Cocoyl Hydrolyzed Collagen, Cocoyl Hydrolyzed Keratin, Cocoyl Hydrolyzed Oat Protein, Cocoyl Hydrolyzed Rice Protein, Cocoyl Hydrolyzed Silk, Cocoyl Hydrolyzed Soy Protein, Cocoyl Hydrolyzed Wheat Protein, Cocoyl Sarcosine, Corn Acid, Cottonseed Acid, Cottonseed Oil Glycereth-8 Esters, C10-16 Pareth-1, C10-16 Pa- reth-2, C11-13 Pareth-6, C11-13 Pareth-9, C11-13 Pareth-10, C11-15 Pareth-30, C11-15 Pa- reth-40, C12-13 Pareth-1, C12-13 Pareth- 23, C12-14 Pareth-5, C12-14 Pareth-9, C13-15 Pa- reth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20- 40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 Carboxylic Acid, C9-11 Pareth-8 Carboxylic Acid, C11-15 Pareth-7 Carboxylic Acid, C12-13 Pareth-5 Carboxylic Acid, C12-13 Pareth-7 Carbox- ylic Acid, C12-13 Pareth-8 Carboxylic Acid, C12-13 Pareth-12 Carboxylic Acid, C12-15 Pareth- 7 Carboxylic Acid, C12-15 Pareth-8 Carboxylic Acid, C12-15 Pareth- 12 Carboxylic Acid, C14- 15 Pareth-8 Carboxylic Acid, C6-10 Pareth-4 Phosphate, C12-13 Pareth-2 Phosphate, C12-13 Pareth-10 Phosphate, C12-15 Pareth-6 Phosphate, C12-15 Pareth-8 Phosphate, C12-15 Pa- reth-10 Phosphate, C12-16 Pareth-6 Phosphate, C4-18 Perfluoroalkylethyl Thiohydroxypro- pyltrimonium Chloride, Cupuassuamidopropyl Betaine, DEA-C12-13 Alkyl Sulfate, DEA-C12- 15 Alkyl Sulfate, DEA-Ceteareth-2 Phosphate, DEA-Cetyl Sulfate, DEA- Cocoamphodipropio- nate, DEA-C12-13 Pareth-3 Sulfate, DEA-Cyclocarboxypropyloleate, DEA- Dodecylbenzene- sulfonate, DEA-lsostearate, DEA-Laureth Sulfate, DEA-Lauryl Sulfate, DEA- Linoleate, DEA- Methyl Myristate Sulfonate, DEA-Myreth Sulfate, DEA-Myristate, DEA-Myristyl Sulfate, DEA- Oleth-5 Phosphate, DEA-Oleth-20 Phosphate, DEA PG-Oleate, Deceth-7 Carboxylic Acid, De- ceth-7 Glucoside, Deceth-9 Phosphate, Decylamine Oxide, Decyl Betaine, Decyl Glucoside,Decyltetradeceth-30, Decyltetradecylamine Oxide, Diammonium Lauramido-MEA Sulfosuc- cinate, Diammonium Lauryl Sulfosuccinate, Diammonium Oleamido PEG-2 Sulfosuccinate, Dibutoxymethane, Di-CI 2-15 Pareth-2 Phosphate, Di-CI 2-15 Pareth-4 Phosphate, Di-CI 2-15 Pareth-6 Phosphate, Di- C12-15 Pareth-8 Phosphate, Di-CI 2-15 Pareth-10 Phosphate, Di- dodecyl Butanetetracarboxylate, Diethylamine Laureth Sulfate, Diethylhexyl Sodium Sulfosuc- cinate, Dihydroxyethyl C8-10 Alkoxypropylamine Oxide, Dihydroxyethyl C9-11 Alkoxypropyl- amine Oxide, Dihydroxyethyl C12-15 Alkoxypropylamine Oxide, Dihydroxyethyl Cocamine Oxide, Dihydroxyethyl Lauramine Oxide, Dihydroxyethyl Stearamine Oxide, Dihydroxyethyl Tallowamine Oxide, Dimethicone PEG-7 Phosphate, Dimethicone PEG-10 Phosphate, Dime- thicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethi- cone / Polyglycerin-3 Crosspolymer, Dimethicone Propyl PG- Betaine, Dimyristyl Phosphate, Dioleoylamidoethyl Hydroxyethylmonium Methosulfate, DIPA- Hydrogenated Cocoate, DIPA- Lanolate, DIPA-Myristate, Dipotassium Capryloyl Glutamate, Dipotassium Lauryl Sulfosuccin- ate, Dipotassium Undecylenoyl Glutamate, Disodium Babassuamido MEA-Sulfosuccinate, Disodium Caproamphodiacetate, Disodium Caproamphodipropionate, Disodium Capryloam- phodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloyl Glutamate, Disodi- um Cetearyl Sulfosuccinate, Disodium Cetyl Phenyl Ether Disulfonate, Disodium Cetyl Sul- fosuccinate, Disodium Cocamido MEA-Sulfosuccinate, Disodium Cocamido MIPA PEG-4 Sul- fosuccinate, Disodium Cocamido MIPA-Sulfosuccinate, Disodium Cocamido PEG-3 Sulfosuc- cinate, Disodium Coceth-3 Sulfosuccinate, Disodium Cocoamphocarboxyethylhydroxypropyl- sulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Coco-Glucoside Sulfosuccinate, Disodium Coco-Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium Cocoyl Glutamate, Disodium C12-14 Pareth-1 Sulfosuc- cinate, Disodium C12-14 Pareth-2 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium C12-14 Sec-Pareth-3 Sulfosuccinate, Disodium C12-14 Sec-Pareth-5 Sulfosuccinate, Disodium C12-14 Sec-Pareth-7 Sulfosuccinate, Disodium C12-14 Sec-Pareth-9 Sulfosuccinate, Disodium C12-14 Sec-Pareth-12 Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosuccinate, Disodium Decyl Phenyl Ether Disulfonate, Disodium Dihydroxyethyl Sulfosuccinylundecylenate, Disodium Ethylene Dicocamide PEG-15 Disulfate, Disodium Hy- drogenated Cottonseed Glyceride Sulfosuccinate, Disodium Hydrogenated Tallow Glutamate, Disodium Hydroxydecyl Sorbitol Citrate, Disodium lsodecyl Sulfosuccinate, Disodium lsos- tearamido MEA-Sulfosuccinate, Disodium lsostearamido MIPA-Sulfosuccinate, Disodium Isos- tearoamphodiacetate, Disodium Isostearoamphodipropionate, Disodium lsostearyl Sulfosuc- cinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramido MEA-Sulfosuccinate, Disodi- um Lauramido MIPA Glycol Sulfosuccinate, Disodium Lauramido PEG-2 Sulfosuccinate, Diso- dium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-5 Carboxyamphodiacetate, Disodi- um Laureth-7 Citrate, Disodium Laureth Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lau- riminobishydroxypropylsulfonate, Disodium Lauriminodiacetate, Disodium Lauriminodipropi- onate, Disodium Lauriminodipropionate Tocopheryl Phosphates, Disodium Lauroamphodiac- etate, Disodium Lauroamphodipropionate, Disodium N- Lauroyl Aspartate, Disodium LauroylGlutamate, Disodium Lauryl Phenyl Ether Disulfonate, Disodium Lauryl Sulfosuccinate, Diso- dium Myristamido MEA-Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA-Sulfosuccinate, Disodium Oleamido MIPA-Sulfosuccinate, Disodium Oleami- do PEG-2 Sulfosuccinate, Disodium Oleoamphodipropionate, Disodium Oleth-3 Sulfosuccin- ate, Disodium Oleyl Phosphate, Disodium Oleyl Sulfosuccinate, Disodium Palmitamido PEG-2 Sulfosuccinate, Disodium Palmitoleamido PEG-2 Sulfosuccinate, Disodium PEG-4 Cocamido MIPA-Sulfosuccinate, Disodium PEG-12 Dimethicone Sulfosuccinate, Disodium PEG-8 Palm Glycerides Sulfosuccinate, Disodium PPG-2-lsodeceth-7 Carboxyamphodiacetate, Disodium Ricinoleamido MEA-Sulfosuccinate, Disodium Sitostereth-14 Sulfosuccinate, Disodium Soyamphodiacetate, Disodium Stearamido MEA-Sulfosuccinate, Disodium Steariminodi- propionate, Disodium Stearoamphodiacetate, Disodium Stearoyl Glutamate, Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium 2-Sulfolaurate, Disodium 2- Sulfopalmitate, Disodium Tallamido MEA-Sulfosuccinate, Disodium Tallowamido MEA- Sulfosuccinate, Disodium Tallowamphodiacetate, Disodium Tallowiminodipropionate, Disodi- um Tallow Sulfosuccinamate, Disodium Tridecylsulfosuccinate, Disodium Undecylenamido MEA-Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Un- decylenoyl Glutamate, Disodium Wheat Germamido MEA-Sulfosuccinate, Disodium Wheat Germamido PEG-2 Sulfosuccinate, Disodium Wheatgermamphodiacetate, Di-TEA-Cocamide Diacetate, Di-TEA-Oleamido PEG-2 Sulfosuccinate, Di-TEA-Palmitoyl Aspartate, Ditridecyl Sodium Sulfosuccinate, Dodecylbenzene Sulfonic Acid, Erucamidopropyl Hydroxysultaine, Ethylhexeth-3 Carboxylic Acid, Ethyl PEG-15 Cocamine Sulfate, Glyceryl Capryl Ether, Hex- yldecanoic Acid, Hydrogenated Coconut Acid, Hydrogenated Laneth-25, Hydrogenated Men- haden Acid, Hydrogenated Palm Acid, Hydrogenated Palm Kernel Amine Oxide, Hydrogenat- ed Tallow Acid, Hydrogenated Tallowamine Oxide, Hydrogenated Tallow Betaine, Hydrogen- ated Talloweth-25, Hydrogenated Tallowoyl Glutamic Acid, Hydrolyzed Candida Bombicola Extract, Hydroxyceteth-60, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxyethylbutyl- amine Laureth Sulfate, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Alkoxypropylamine Oxide, Hydroxylauryl / Hydroxymyristyl Betaine, Hydroxystearic Acid, Hydroxysuccinimidyl C10-40 lsoalkyl Acidate, Hydroxysuccinimidyl C21- 22 lsoalkyl Acidate, Hydroxysultaines, IPDI / PEG-15 Soyamine Oxide Copolymer, IPDI / PEG-15 Soyethonium Ethosulfate Copolymer, IPDI / PEG-15 Soy Glycinate Copolymer, lsoceteth-30, lsolaureth-4 Phosphate, lsopolyglyceryl-3 Dimethicone, lsopolyglyceryl-3 Dimethiconol, lso- propanolamine Lanolate, lsopropylamine Dodecylbenzenesulfonate, lsostearamidopropyla- mine Oxide, lsostearamidopropyl Betaine, lsostearamidopropyl Morpholine Oxide, lsos- teareth-8, lsosteareth-16, lsosteareth-22, lsosteareth-25, lsosteareth-50, lsostearic Acid, lsos- tearoyl Hydrolyzed Collagen, Jojoba Oil PEG-150 Esters, Jojoba Wax PEG-80 Esters, Jojoba Wax PEG-120 Esters, Laneth-20, Laneth-25, Laneth-40, Laneth-50, Laneth-60, Laneth-75, Lan- olin Acid, Lauramidopropylamine Oxide, Lauramidopropyl Betaine, Lauramidopropyl Hy- droxysultaine, Lauramine Oxide, Lauraminopropionic Acid, Laurdimoniumhydroxypropyl Decylglucosides Chloride, Laurdimoniumhydroxypropyl Laurylglucosides Chloride, Laureth- 16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38, Laureth-40, Lau-reth-3 Carboxylic Acid, Laureth-4 Carboxylic Acid, Laureth-5 Carboxylic Acid, Laureth- 6 Car- boxylic Acid, Laureth-8 Carboxylic Acid, Laureth-10 Carboxylic Acid, Laureth-11 Carboxylic Acid, Laureth-12 Carboxylic Acid, Laureth-13 Carboxylic Acid, Laureth-14 Carboxylic Acid, Laureth-17 Carboxylic Acid, Laureth-6 Citrate, Laureth-7 Citrate, Laureth-1 Phosphate, Lau- reth-2 Phosphate, Laureth-3 Phosphate, Laureth-4 Phosphate, Laureth-7 Phosphate, Laureth- 8 Phosphate, Laureth-7 Tartrate, Laurie Acid, Laurimino Bispropanediol, Lauriminodipropionic Acid, Lauroamphodipropionic Acid, Lauroyl Beta-Alanine, Lauroyl Collagen Amino Acids, Lau- royl Ethyltrimonium Methosulfate, Lauroyl Hydrolyzed Collagen, Lauroyl Hydrolyzed Elastin, Lauroyl Methyl Glucamide, Lauroyl Sarcosine, Lauroyl Silk Amino Acids, Lauryl Betaine, Lauryl Dimethicone / Polyglycerin-3 Crosspolymer, Lauryldimoniumhydroxypropyl Cocoglucosides Chloride, Lauryl Glucoside, Laurylglucosides Hydroxypropyltrimonium Chloride, Lauryl Glycol Hydroxypropyl Ether, Lauryl Hydroxysultaine, Lauryl Malamide, Lauryl Methylglucamide, Lau- ryl / Myristyl Glycol Hydroxypropyl Ether, Lauryl / Myristyl Wheat Bran / Straw Glycosides, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Pyrrolidone, Lauryl Sultaine, Lino- leic Acid, Linolenic Acid, Linseed Acid, Lysine Cocoate, Macadamia Seed Oil Glycereth-8 Es- ters, Magnesium Coceth Sulfate, Magnesium Coco-Sulfate, Magnesium Isododecylbenzene- sulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Lau- reth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfonate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myreth Sulfate, Magnesium Oleth Sulfate, Magnesium / TEA-Coco-Sulfate, Manicouagan Clay, MEA-Cocoate, MEA-Laureth-6 Carboxylate, MEA- Laureth Sulfate, MEA-Lauryl Sulfate, MEA PPG-6 Laureth-7 Carboxylate, MEA-PPG-8-Steareth-7 Carboxylate, MEA-Undecylenate, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, Methoxy PEG-450 Amidoglutaroyl Succinimide, Methoxy PEG-450 Amido Hydroxysuccinimidyl Suc- cinamate, Methoxy PEG-450 Maleimide, Methyl Morpholine Oxide, Milkamidopropyl Amine Oxide, Milkamidopropyl Betaine, Minkamidopropylamine Oxide, Minkamidopropyl Betaine, MIPA C12-15 Pareth Sulfate, MIPA-Dodecylbenzenesulfonate, MIPA-Laureth Sulfate, MIPA- Lauryl Sulfate, Mixed lsopropanolamines Lanolate, Mixed lsopropanolamines Lauryl Sulfate, Mixed lsopropanolamines Myristate, Morpholine Oleate, Morpholine Stearate, Myreth-3 Car- boxylic Acid, Myreth-5 Carboxylic Acid, Myristalkonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristami- dopropyl Hydroxysultaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myrista- mine Oxide, Myristaminopropionic Acid, Myristic Acid, Myristoyl Ethyltrimonium Methosul- fate, Myristoyl Glutamic Acid, Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine, Myristyl / Cetyl Amine Oxide, Myristyldimoniumhydroxypropyl Cocoglucosides Chlo- ride, Myristyl Glucoside, Myristyl Phosphate, Nonoxynol-20, Nonoxynol-23, Nonoxynol-25, Nonoxynol-30, Nonoxynol-35, Nonoxynol-40, Nonoxynol-44, Nonoxynol-50, Nonoxynol-100, Nonoxynol-120, Nonoxynol-5 Carboxylic Acid, Nonoxynol-8 Carboxylic Acid, Nonoxynol-10 Carboxylic Acid, Nonoxynol-3 Phosphate, Nonoxynol-4 Phosphate, Nonoxynol-6 Phosphate, Nonoxynol-9 Phosphate, Nonoxynol-10 Phosphate, Nonyl Nonoxynol-30, Nonyl Nonoxynol-49, Nonyl Nonoxynol-100, Nonyl Nonoxynol-150, Nonyl Nonoxynol-7 Phosphate, Nonyl Nonoxynol-8 Phosphate, Nonyl Nonoxynol-9 Phosphate, Nonyl Nonoxynol-10 Phosphate, Nonyl Nonoxynol-11 Phosphate, Nonyl Nonoxynol-15 Phosphate, Nonyl Nonoxynol-24 Phosphate, Oatamidopropyl Betaine, Octoxynol-16, Octoxynol-25, Octoxynol-30, Octoxynol- 33, Octoxynol-40, Octoxynol-70, Octoxynol-20 Carboxylic Acid, Octyldodeceth-20, Oc- tyldodeceth-25, Octyldodeceth-30, Oleamidopropylamine Oxide, Oleamidopropyl Betaine, Oleamidopropyl Hydroxysultaine, Oleamine Oxide, Oleic Acid, Oleoyl Hydrolyzed Collagen, Oleoyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Olivamidopropylamine Oxide, Olivamidopropyl Betaine, Olive Acid, Oli- voyl Hydrolyzed Wheat Protein, Ophiopogon Extract Stearate, Ozonized Oleth-10, Ozonized PEG-10 Oleate, Ozonized PEG-14 Oleate, Ozonized Polysorbate 80, Palm Acid, Pal- mamidopropyl Betaine, Palmeth-2 Phosphate, Palmitamidopropylamine Oxide, Palmitami- dopropyl Betaine, Palmitamine Oxide, Palmitic Acid, Palmitoyl Collagen Amino Acids, Pal- mitoyl Glycine, Palmitoyl Hydrolyzed Collagen, Palmitoyl Hydrolyzed Milk Protein, Palmitoyl Hydrolyzed Wheat Protein, Palmitoyl Keratin Amino Acids, Palmitoyl Oligopeptide, Palmitoyl Silk Amino Acids, Palm Kernel Acid, Palm Kernelamidopropyl Betaine, Peach Kernel Oil Glycereth-8 Esters, Peanut Acid, PEG-10 Castor Oil, PEG-40 Castor Oil, PEG-44 Castor Oil, PEG-50 Castor Oil, PEG-54 Castor Oil, PEG-55 Castor Oil, PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocamine, PEG-8 Cocamine, PEG-12 Cocamine, PEG-150 Dibehenate, PEG-90 Diisos- tearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Co- coate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soyate, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, PEG-28 Glyceryl Tallowate, PEG-80 Glyceryl Tallowate, PEG-82 Glyceryl Tallowate, PEG-130 Glyceryl Tallowate, PEG-200 Glyceryl Tallowate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG- 54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogen- ated Castor Oil, PEG-30 Hydrogenated Lanolin, PEG-70 Hydrogenated Lanolin, PEG-50 Hy- drogenated Palmamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isos- tearate, PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG- 30 Isostearate, PEG-40 Isostearate, PEG- 26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG- 70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide, PEG-3 Lau- ramine Oxide, PEG-20 Laurate, PEG-32 Laurate, PEG-75 Laurate, PEG-150 Laurate, PEG-70Mango Glycerides, PEG-20 Mannitan Laurate, PEG-8 Methyl Ether Dimethicone, PEG-120 Me- thyl Glucose Dioleate, PEG-80 Methyl Glucose Laurate, PEG-120 Methyl Glucose Trioleate, PEG-4 Montanate, PEG-30 Oleamine, PEG-20 Oleate, PEG-23 Oleate, PEG-32 Oleate, PEG-36 Oleate, PEG-75 Oleate, PEG-150 Oleate, PEG-20 Palmitate, PEG-150 Polyglyceryl-2 Tristearate, PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG- 3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Co- polymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copoly- mer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 Copolymer, PEG / PPG-20 / 60 Copolymer, PEG / PPG- 20 / 65 Copolymer, PEG / PPG-22 / 25 Copolymer, PEG / PPG-28 / 30 Copolymer, PEG / PPG-30-35 Copolymer, PEG / PPG-30 / 55 Copolymer, PEG / PPG-35 / 40 Copolymer, PEG / PPG-50 / 40 Copolymer, PEG / PPG-150 / 35 Copolymer, PEG / PPG-160 / 30 Copolymer, PEG / PPG-190 / 60 Copolymer, PEG / PPG-200 / 40 Copolymer, PEG / PPG-300 / 55 Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethicone, PEG-26-PPG-30 Phosphate, PEG / PPG-4 / 2 Propylheptyl Ether, PEG / PPG-6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG- 10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG- 32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG- 10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glycerides, PEG-75 Shorea Butter Glycerides, PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolate, PEG-75 Sorbitan Lanolate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG- 44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Ole- ate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterol, PEG-2 Stearamide Carboxylic Acid, PEG-9 Steara- mide Carboxylic Acid, PEG-20 Stearate, PEG-23 Stearate, PEG-25 Stearate, PEG-30 Stearate, PEG-32 Stearate, PEG-35 Stearate, PEG-36 Stearate, PEG-40 Stearate, PEG-45 Stearate, PEG- 50 Stearate, PEG-55 Stearate, PEG-75 Stearate, PEG-90 Stearate, PEG-100 Stearate, PEG- 120 Stearate, PEG-150 Stearate, PEG-45 Stearate Phosphate, PEG-20 Tallate, PEG-50 Tallow Am- ide, PEG-2 Tallowamide DEA, PEG-20 Tallowate, PEG-66 Trihydroxystearin, PEG-200 Trihy- droxystearin, PEG-60 Tsubakiate Glycerides, Pelargonic Acid, Pentadoxynol-200, Pheneth-6 Phosphate, Poloxamer 105, Poloxamer 108, Poloxamer 182, Poloxamer 183, Poloxamer 184, Poloxamer 188, Poloxamer 217, Poloxamer 234, Poloxamer 235, Poloxamer 237, Poloxamer 238, Poloxamer 288, Poloxamer 334, Poloxamer 335, Poloxamer 338, Poloxamine 908, Polox- amine 1508, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydime- thylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Di- laurate, Polyglyceryl-20 Heptacaprylate, Polyglyceryl-20 Hexacaprylate, Polyglyceryl-2 Lauryl Ether, Polyglyceryl-10 Lauryl Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pen- tacaprylate, Polyglyceryl-10 Pentacaprylate, Polyglyceryl-3 Polydimethylsiloxyethyl Dimethi- cone, Polyglyceryl-6 Tetracaprylate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Tricaprylate, Polyglyceryl-10 Trilaurate, Polyquaternium- 77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium- 82, Pomaderris Kumerahou Flow-er / Leaf Extract, Poria Cocos Extract, Potassium Abietoyl Hydrolyzed Collagen, Potassium Ba- bassuate, Potassium Behenate, Potassium C9-15 Alkyl Phosphate, Potassium C11-15 Alkyl Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Potassium Capryloyl Glutamate, Potassium Capryloyl Hydrolyzed Rice Protein, Potas- sium Castorate, Potassium Cocoate, Potassium Cocoyl Glutamate, Potassium Cocoyl Glycinate, Potassium Cocoyl Hydrolyzed Casein, Potassium Cocoyl Hydrolyzed Collagen, Po- tassium Cocoyl Hydrolyzed Corn Protein, Potassium Cocoyl Hydrolyzed Keratin, Potassium Cocoyl Hydrolyzed Oat Protein, Potassium Cocoyl Hydrolyzed Potato Protein, Potassium Co- coyl Hydrolyzed Rice Bran Protein, Potassium Cocoyl Hydrolyzed Rice Protein, Potassium Co- coyl Hydrolyzed Silk, Potassium Cocoyl Hydrolyzed Soy Protein, Potassium Cocoyl Hydrolyzed Wheat Protein, Potassium Cocoyl Hydrolyzed Yeast Protein, Potassium Cocoyl PCA, Potassi- um Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Cornate, Potassium Cyclocar- boxypropyloleate, Potassium Dihydroxyethyl Cocamine Oxide Phosphate, Potassium Dimethi- cone PEG-7 Phosphate, Potassium Dodecylbenzenesulfonate, Potassium Hempseedate, Po- tassium Hydrogenated Cocoate, Potassium Hydrogenated Palmate, Potassium Hydrogenated Tallowate, Potassium Hydroxystearate, Potassium Isostearate, Potassium Lanolate, Potassium Laurate, Potassium Laureth-3 Carboxylate, Potassium Laureth-4 Carboxylate, Potassium Lau- reth-5 Carboxylate, Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate, Po- tassium Laureth Phosphate, Potassium Lauroyl Collagen Amino Acids, Potassium Lauroyl Glu- tamate, Potassium Lauroyl Hydrolyzed Collagen, Potassium Lauroyl Hydrolyzed Pea Protein, Potassium Lauroyl Hydrolyzed Soy Protein, Potassium Lauroyl PCA, Potassium Lauroyl Pea Amino Acids, Potassium Lauroyl Sarcosinate, Potassium Lauroyl Silk Amino Acids, Potassium Lauroyl Wheat Amino Acids, Potassium Lauryl Phosphate, Potassium Lauryl Sulfate, Potassium Linoleate, Potassium Metaphosphate, Potassium Methyl Cocoyl Taurate, Potassium Myristate, Potassium Myristoyl Glutamate, Potassium Myristoyl Hydrolyzed Collagen, Potassium Oc- toxynol-12 Phosphate, Potassium Oleate, Potassium Oleoyl Hydrolyzed Collagen, Potassium Olivate, Potassium Olivoyl Hydrolyzed Oat Protein, Potassium Olivoyl Hydrolyzed Wheat Protein, Potassium Olivoyl / Lauroyl Wheat Amino Acids, Potassium Olivoyl PCA, Potas- sium Palmate, Potassium Palmitate, Potassium Palmitoyl Hydrolyzed Corn Protein, Potassium Palmitoyl Hydrolyzed Oat Protein, Potassium Palmitoyl Hydrolyzed Rice Protein, Potassium Palmitoyl Hydrolyzed Sweet Almond Protein, Potassium Palmitoyl Hydrolyzed Wheat Protein, Potassium Palm Kernelate, Potassium Peanutate, Potassium Rapeseedate, Potassium Ricino- leate, Potassium Safflowerate, Potassium Soyate, Potassium Stearate, Potassium Stearoyl Hy- drolyzed Collagen, Potassium Tallate, Potassium Tallowate, Potassium Taurate, Potassium Taurine Laurate, Potassium Trideceth-3 Carboxylate, Potassium Trideceth-4 Carboxylate, Po- tassium Trideceth-7 Carboxylate, Potassium Trideceth-15 Carboxylate, Potassium Trideceth- 19 Carboxylate, Potassium Trideceth-6 Phosphate, Potassium Trideceth-7 Phosphate, Potassi- um Tsubakiate, Potassium Undecylenate, Potassium Undecylenoyl Hydrolyzed Collagen, Po- tassium Undecylenoyl Hydrolyzed Rice Protein, PPG-30- Buteth-30, PPG-36-Buteth-36, PPG- 38-Buteth-37, PPG-30-Capryleth-4 Phosphate, PPG-10 Cetyl Ether Phosphate, PPG-2 C9-11 Pareth-8, PPG-1-Deceth-5, PPG-3-Deceth-2 Carboxylic Acid, PPG-30 Ethylhexeth-4 Phos-phate, PPG-20-Glycereth-30, PPG-2 Hydroxyethyl Coco / lsostearamide, PPG-2- lsodeceth-8, PPG-2-lsodeceth-10, PPG-2-lsodeceth-18, PPG-2-lsodeceth-25, PPG-4-lsodeceth-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Acid, Rice Bran Acid, Rice Oil Glycereth-8 Esters, Ricinoleamidopropyl Betaine, Ric- inoleic Acid, Ricinoleth-40, Safflower Acid, Sapindus Oahuensis Fruit Extract, Saponaria Offici- nalis Root Powder, Saponins, Sekken-K, Sekken-Na / K, Sekken Soji, Sekken Soji-K, Sesame Oil Glycereth-8 Esters, Sesamidopropylamine Oxide, Sesamidopropyl Betaine, Shea Butterami- dopropyl Betaine, Shea Butter Glycereth-8 Esters, Sodium Arachidate, Sodium Arganam- pohoacetate, Sodium Astrocaryum Murumuruate, Sodium Avocadoate, Sodium Babassuam- phoacetate, Sodium Babassuate, Sodium Babassu Sulfate, Sodium Behenate, Sodium Bisgly- col Ricinosulfosuccinate, Sodium Bis- Hydroxyethylglycinate Coco-Glucosides Crosspolymer, Sodium Bis-Hydroxyethylglycinate Lauryl- Glucosides Crosspolymer, Sodium Borageami- dopropyl PG-Dimonium Chloride Phosphate, Sodium Butoxynol-12 Sulfate, Sodium Butylglu- cosides Hydroxypropyl Phosphate, Sodium C13-17 Alkane Sulfonate, Sodium C14-18 Alkane Sulfonate, Sodium C12-15 Alkoxypropyl Iminodipropionate, Sodium C10-16 Alkyl Sulfate, Sodium C11-15 Alkyl Sulfate, Sodium C12-13 Alkyl Sulfate, Sodium C12-15 Alkyl Sulfate, So- dium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate, Sodium C9-22 Alkyl Sec Sulfonate, Sodium C14-17 Alkyl Sec Sulfonate, Sodium Caprate, Sodium Caproamphoacetate, Sodium Caproamphohydroxypropylsulfonate, Sodium Caproamphopropionate, Sodium Caproyl Me- thyltaurate, Sodium Caprylate, Sodium Capryleth-2 Carboxylate, Sodium Capryleth-9 Carbox- ylate, Sodium Capryloamphoacetate, Sodium Capryloamphohydroxypropylsulfonate, Sodium Capryloamphopropionate, Sodium Capryloyl Glutamate, Sodium Capryloyl Hydrolyzed Wheat Protein, Sodium Caprylyl PG-Sulfonate, Sodium Caprylyl Sulfonate, Sodium Castorate, Sodium Ceteareth-13 Carboxylate, Sodium Cetearyl Sulfate, Sodium Ceteth-13 Carboxylate, Sodium Cetyl Sulfate, Sodium Cocamidopropyl PG-Dimonium Chloride Phosphate, Sodium Co- caminopropionate, Sodium Coceth Sulfate, Sodium Coceth-30 Sulfate, Sodium Cocoabut- teramphoacetate, Sodium Cocoa Butterate, Sodium Cocoamphoacetate, Sodium Cocoam- phohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cocoate, Sodium Co- co / Babassu / Andiroba Sulfate, Sodium Coco / Babassu Sulfate, Sodium Cocoglucosides Hy- droxypropyl Phosphate, Sodium Cocoglucosides Hydroxypropylsulfonate, Sodium Coco- Glucoside Tartrate, Sodium Cocoglyceryl Ether Sulfonate, Sodium Coco / Hydrogenated Tallow Sulfate, Sodium Cocoiminodiacetate, Sodium Cocomonoglyceride Sulfate, Sodium Co- comonoglyceride Sulfonate, Sodium Coco PG-Dimonium Chloride Phosphate, Sodium Coco- Sulfate, Sodium Coco Sulfoacetate, Sodium Cocoyl Alaninate, Sodium Cocoyl Amino Acids, Sodium Cocoyl Collagen Amino Acids, Sodium Cocoyl Glutamate, Sodium Cocoyl Glutami- nate, Sodium Cocoyl Glycinate, Sodium Cocoyl / Hydrogenated Tallow Glutamate, Sodium Cocoyl Hydrolyzed Collagen, Sodium Cocoyl Hydrolyzed Keratin, Sodium Cocoyl Hydrolyzed Rice Protein, Sodium Cocoyl Hydrolyzed Silk, Sodium Cocoyl Hydrolyzed Soy Protein, Sodium Cocoyl Hydrolyzed Sweet Almond Protein, Sodium Cocoyl Hydrolyzed Wheat Protein, Sodium Cocoyl Hydrolyzed Wheat Protein Glutamate, Sodium Cocoyl Isethionate, Sodium Cocoyl Methylaminopropionate, Sodium Cocoyl Oat Amino Acids, Sodium Co-coyl / Palmoyl / Sunfloweroyl Glutamate, Sodium Cocoyl Proline, Sodium Cocoyl Sarcosinate, Sodium Cocoyl Taurate, Sodium Cocoyl Threoninate, Sodium Cocoyl Wheat Amino Acids, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14- 18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Cornamphopropionate, Sodium Cotton- seedamphoacetate, Sodium C13-15 Pareth-8 Butyl Phosphate, Sodium C9-11 Pareth-6 Car- boxylate, Sodium C11-15 Pareth-7 Carboxylate, Sodium C12-13 Pareth-5 Carboxylate, Sodi- um C12-13 Pareth-8 Carboxylate, Sodium C12-13 Pareth-12 Carboxylate, Sodium C12-15 Pareth-6 Carboxylate, Sodium C12-15 Pareth-7 Carboxylate, Sodium C12-15 Pareth-8 Car- boxylate, Sodium C14-15 Pareth-8 Carboxylate, Sodium C12-14 Sec-Pareth-8 Carboxylate, Sodium C14-15 Pareth-PG Sulfonate, Sodium C12-13 Pareth-2 Phosphate, Sodium C13-15 Pareth-8 Phosphate, Sodium C9-15 Pareth-3 Sulfate, Sodium C10-15 Pareth Sulfate, Sodium C10-16 Pareth-2 Sulfate, Sodium C12-13 Pareth Sulfate, Sodium C12-15 Pareth Sulfate, Sodi- um C12-15 Pareth-3 Sulfate, Sodium C13-15 Pareth-3 Sulfate, Sodium C12-14 Sec-Pareth-3 Sulfate, Sodium C12-15 Pareth-3 Sulfonate, Sodium C12-15 Pareth-7 Sulfonate, Sodium C12- 15 Pareth-15 Sulfonate, Sodium Deceth-2 Carboxylate, Sodium Deceth Sulfate, Sodium Decylbenzenesulfonate, Sodium Decylglucosides Hydroxypropyl Phosphate, Sodium Decyl- glucosides Hydroxypropylsulfonate, Sodium Dilaureth-7 Citrate, Sodium Dilaureth-10 Phos- phate, Sodium Dilinoleamidopropyl PG-Dimonium Chloride Phosphate, Sodium Dilinoleate, Sodium Dioleth-8 Phosphate, Sodium Dodecylbenzenesulfonate, Sodium Ethyl 2- Sul- folaurate, Sodium Glyceryl Oleate Phosphate, Sodium Grapeseedamidopropyl PG-Dimonium Chloride Phosphate, Sodium Grapeseedamphoacetate, Sodium Grapeseedate, Sodium Hempseedamphoacetate, Sodium Hexeth-4 Carboxylate, Sodium Hydrogenated Cocoate, Sodium Hydrogenated Cocoyl Methyl Isethionate, Sodium Hydrogenated Palmate, Sodium Hydrogenated Tallowate, Sodium Hydrogenated Tallowoyl Glutamate, Sodium Hydroxylau- ryldimonium Ethyl Phosphate, Sodium Hydroxypropyl Palm Kernelate Sulfonate, Sodium Hy- droxypropylphosphate Decylglucoside Crosspolymer, Sodium Hydroxypropylphosphate Lau- rylglucoside Crosspolymer, Sodium Hydroxypropylsulfonate Cocoglucoside Crosspolymer, Sodium Hydroxypropylsulfonate Decylglucoside Crosspolymer, Sodium Hydroxypropyl- sulfonate Laurylglucoside Crosspolymer, Sodium Hydroxystearate, Sodium Isostearate, Sodi- um lsosteareth-6 Carboxylate, Sodium Isosteareth- 11 Carboxylate, Sodium Isostearoampho- acetate, Sodium Isostearoamphopropionate, Sodium N- lsostearoyl Methyltaurate, Sodium Laneth Sulfate, Sodium Lanolate, Sodium Lardate, Sodium Lauramido Diacetate, Sodium Lau- raminopropionate, Sodium Laurate, Sodium Laureth-3 Carboxylate, Sodium Laureth-4 Car- boxylate, Sodium Laureth-5 Carboxylate, Sodium Laureth-6 Carboxylate, Sodium Laureth-8 Carboxylate, Sodium Laureth-11 Carboxylate, Sodium Laureth-12 Carboxylate, Sodium Lau- reth-13 Carboxylate, Sodium Laureth-14 Carboxylate, Sodium Laureth-16 Carboxylate, Sodi- um Laureth-17 Carboxylate, Sodium Laureth Sulfate, Sodium Laureth-5 Sulfate, Sodium Lau- reth- 7 Sulfate, Sodium Laureth-8 Sulfate, Sodium Laureth-12 Sulfate, Sodium Laureth-40 Sulfate, Sodium Laureth-7 Tartrate, Sodium Lauriminodipropionate, Sodium Lauroamphoace- tate, Sodium Lauroamphohydroxypropylsulfonate, Sodium Lauroampho PG-Acetate Phos- phate, Sodium Lauroamphopropionate, Sodium Lauroyl Aspartate, Sodium Lauroyl CollagenAmino Acids, Sodium Lauroyl Glycine Propionate, Sodium Lauroyl Hydrolyzed Collagen, So- dium Lauroyl Hydrolyzed Silk, Sodium Lauroyl Hydroxypropyl Sulfonate, Sodium Lauroyl Isethionate, Sodium Lauroyl Methylaminopropionate, Sodium Lauroyl Methyl Isethionate, Sodium Lauroyl Millet Amino Acids, Sodium Lauroyl / Myristoyl Aspartate, Sodium Lauroyl Oat Amino Acids, Sodium Lauroyl Sarcosinate, Sodium Lauroyl Silk Amino Acids, Sodium Lauroyl Taurate, Sodium Lauroyl Wheat Amino Acids, Sodium Lauryl Diethylenediaminoglycinate, Sodium Lauryl Glucose Carboxylate, Sodium Laurylglucosides Hydroxypropyl Phosphate, So- dium Laurylglucosides Hydroxypropylsulfonate, Sodium Lauryl Glycol Carboxylate, Sodium Lauryl Hydroxyacetamide Sulfate, Sodium Lauryl Phosphate, Sodium Lauryl Sulfate, Sodium Lauryl Sulfoacetate, Sodium Linoleate, Sodium Macadamiaseedate, Sodium Mangoampho- acetate, Sodium Mangoseedate, Sodium / MEA Laureth-2 Sulfosuccinate, Sodium Methoxy PPG-2 Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Me- thyl Myristoyl Taurate, Sodium Methyl Oleoyl Taurate, Sodium Methyl Palmitoyl Taurate, So- dium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium Methyl 2- Sulfopalmi- tate, Sodium Methyltaurate Isopalmitamide, Sodium Methyltaurine Cocoyl Methyltaurate, Sodium Myreth Sulfate, Sodium Myristate, Sodium Myristoamphoacetate, Sodium Myristoyl Glutamate, Sodium Myristoyl Hydrolyzed Collagen, Sodium Myristoyl Isethionate, Sodium Myristoyl Sarcosinate, Sodium Myristyl Sulfate, Sodium Nonoxynol-6 Phosphate, Sodium Nonoxynol-9 Phosphate, Sodium Nonoxynol-1 Sulfate, Sodium Nonoxynol-3 Sulfate, Sodium Nonoxynol-4 Sulfate, Sodium Nonoxynol-6 Sulfate, Sodium Nonoxynol-8 Sulfate, Sodium Nonoxynol-10 Sulfate, Sodium Nonoxynol-25 Sulfate, Sodium Octoxynol-2 Ethane Sulfonate, Sodium Octoxynol-2 Sulfate, Sodium Octoxynol-6 Sulfate, Sodium Octoxynol-9 Sulfate, Sodi- um Oleate, Sodium Oleoamphoacetate, Sodium Oleoamphohydroxypropylsulfonate, Sodium Oleoamphopropionate, Sodium Oleoyl Hydrolyzed Collagen, Sodium Oleoyl Isethionate, So- dium Oleth Sulfate, Sodium Oleyl Methyl Isethionate, Sodium Oleyl Sulfate, Sodium Olivam- phoacetate, Sodium Olivate, Sodium Olivoyl Glutamate, Sodium Palmamphoacetate, Sodium Palmate, Sodium Palm Glyceride Sulfonate, Sodium Palmitate, Sodium Palmitoyl Hydrolyzed Collagen, Sodium Palmitoyl Hydrolyzed Wheat Protein, Sodium Palmitoyl Sarcosinate, Sodi- um Palm Kernelate, Sodium Palm Kerneloyl Isethionate, Sodium Palmoyl Glutamate, Sodium Passiflora Edulis Seedate, Sodium Peanutamphoacetate, Sodium Peanutate, Sodium PEG-6 Cocamide Carboxylate, Sodium PEG-8 Cocamide Carboxylate, Sodium PEG-4 Cocamide Sul- fate, Sodium PEG-3 Lauramide Carboxylate, Sodium PEG-4 Lauramide Carboxylate, Sodium PEG-8 Palm Glycerides Carboxylate, Sodium Pentaerythrityl Hydroxypropyl lminodiacetate Dendrimer, Sodium Propoxy PPG-2 Acetate, Sodium Rapeseedate, Sodium Ricebranampho- acetate, Sodium Ricinoleate, Sodium Ricinoleoamphoacetate, Sodium Rose Hipsamphoace- tate, Sodium Rosinate, Sodium Safflowerate, Sodium Saffloweroyl Hydrolyzed Soy Protein, Sodium Sesameseedate, Sodium Sesamphoacetate, Sodium Sheabutteramphoacetate, Sodi- um Soyate, Sodium Soy Hydrolyzed Collagen, Sodium Stearate, Sodium Stearoamphoacetate, Sodium Stearoamphohydroxypropylsulfonate, Sodium Stearoamphopropionate, Sodium Stearoyl Casein, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Corn Protein, Sodium Stearoyl HydrolyzedSilk, Sodium Stearoyl Hydrolyzed Soy Protein, Sodium Stearoyl Hydrolyzed Wheat Protein, Sodium Stearoyl Lactalbumin, Sodium Stearoyl Methyl Isethionate, Sodium Stearoyl Oat Pro- tein, Sodium Stearoyl Pea Protein, Sodium Stearoyl Soy Protein, Sodium Stearyl Dimethyl Glycine, Sodium Stearyl Sulfate, Sodium Sunflowerseedamphoacetate, Sodium Surfactin, So- dium Sweetalmondamphoacetate, Sodium Sweet Almondate, Sodium Tallamphopropionate, Sodium Tallate, Sodium Tallowamphoacetate, Sodium Tallowate, Sodium Tallow Sulfate, So- dium Tamanuseedate, Sodium Taurate, Sodium Taurine Cocoyl Methyltaurate, Sodium Tau- rine Laurate, Sodium / TEA-Lauroyl Collagen Amino Acids, Sodium / TEA-Lauroyl Hydrolyzed Collagen, Sodium / TEA-Lauroyl Hydrolyzed Keratin, Sodium / TEA- Lauroyl Keratin Amino Ac- ids, Sodium / TEA-Undecylenoyl Collagen Amino Acids, Sodium / TEA- Undecylenoyl Hydro- lyzed Collagen, Sodium / TEA-Undecylenoyl Hydrolyzed Corn Protein, Sodium / TEA- Undecylenoyl Hydrolyzed Soy Protein, Sodium / TEA-Undecylenoyl Hydrolyzed Wheat Protein, Sodium Theobroma Grandiflorum Seedate, Sodium Trideceth-3 Carboxylate, Sodium Tride- ceth-4 Carboxylate, Sodium Trideceth-6 Carboxylate, Sodium Trideceth-7 Carboxylate, Sodi- um Trideceth-8 Carboxylate, Sodium Trideceth-12 Carboxylate, Sodium Trideceth-15 Carbox- ylate, Sodium Trideceth-19 Carboxylate, Sodium Trideceth Sulfate, Sodium Tridecylbenzene- sulfonate, Sodium Tridecyl Sulfate, Sodium Trimethylolpropane Hydroxypropyl lminodiace- tate Dendrimer, Sodium Undeceth-5 Carboxylate, Sodium Undecylenate, Sodium Undecylen- oamphoacetate, Sodium Undecylenoamphopropionate, Sodium Undecylenoyl Glutamate, Sodium Wheat Germamphoacetate, Sorbeth-160 Tristearate, Soy Acid, Soyamidopropylamine Oxide, Soyamidopropyl Betaine, Soybean Oil Glycereth-8 Esters, Stearamidopropylamine Ox- ide, Stearamidopropyl Betaine, Stearamine Oxide, Steareth-15, Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth- 40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyltri- monium Chloride, Stearoyl Glutamic Acid, Stearoyl Sarcosine, Stearyl Betaine, Stearyldimoni- umhydroxypropyl Butylglucosides Chloride, Stearyldimoniumhydroxypropyl Decylglucosides Chloride, Stearyldimoniumhydroxypropyl Laurylglucosides Chloride, Sulfated Castor Oil, Sul- fated Coconut Oil, Sulfated Glyceryl Oleate, Sulfated Olive Oil, Sulfated Peanut Oil, Sunflow- eramide MEA, Sunflower Seed Acid, Sunflowerseedamidopropyl Hydroxyethyldimonium Chloride, Sunflower Seed Oil Glycereth-8 Esters, Tall Oil Acid, Tallow Acid, Tallowamidoprop- ylamine Oxide, Tallowamidopropyl Betaine, Tallowamidopropyl Hydroxysultaine, Tallowamine Oxide, Tallow Betaine, Tallow Dihydroxyethyl Betaine, Tallowoyl Ethyl Glucoside, TEA-Abietoyl Hydrolyzed Collagen, TEA-C12-14 Alkyl Phosphate, TEA-C10-15 Alkyl Sulfate, TEA-C11-15 Alkyl Sulfate, TEA- C12-13 Alkyl Sulfate, TEA-C12-14 Alkyl Sulfate, TEA-C12-15 Alkyl Sulfate, TEA C14-17 Alkyl Sec Sulfonate, TEA-Canolate, TEA-Cocamide Diacetate, TEA-Cocoate, TEA- Coco-Sulfate, TEA-Cocoyl Alaninate, TEA-Cocoyl Glutamate, TEA-Cocoyl Glutaminate, TEA- Cocoyl Glycinate, TEA-Cocoyl Hydrolyzed Collagen, TEA-Cocoyl Hydrolyzed Soy Protein, TEA- Cocoyl Sarcosinate, TEA- Dimethicone PEG-7 Phosphate, TEA-Dodecylbenzenesulfonate, TEA- Hydrogenated Cocoate, TEA- Hydrogenated Tallowoyl Glutamate, TEA-lsostearate, TEA- lsostearoyl Hydrolyzed Collagen, TEA- Lauraminopropionate, TEA-Laurate, TEA- Laurate / Myristate, TEA-Laureth Sulfate, TEA-Lauroyl Collagen Amino Acids, TEA-Lauroyl Glu-tamate, TEA-Lauroyl Hydrolyzed Collagen, TEA-Lauroyl Keratin Amino Acids, TEA-Lauroyl Me- thylaminopropionate, TEA-Lauroyl / Myristoyl Aspartate, TEA- Lauroyl Sarcosinate, TEA-Lauryl Phosphate, TEA-Lauryl Sulfate, TEA-Myristaminopropionate, TEA- Myristate, TEA-Myristoyl Hydrolyzed Collagen, TEA-Oleate, TEA-Oleoyl Hydrolyzed Collagen, TEA- Oleoyl Sarcosinate, TEA-Oleyl Sulfate, TEA-Palmitate, TEA-PaIm Kernel Sarcosinate, TEA-PEG-3 Cocamide Sulfate, TEA-Rosinate, TEA-Stearate, TEA-Tallate, TEA-T ridecylbenzenesulfonate, TEA- Undecylenate, TEA-Undecylenoyl Hydrolyzed Collagen, Tetramethyl Decynediol, Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate, TIPA-Laureth Sulfate, TIPA-Lauryl Sulfate, TIPA-Myristate, TIPA- Stearate, Tocopheryl Phosphate, Trehalose Undecylenoate, TM-C12-15 Pareth-2 Phosphate, TM-C12-15 Pareth-6 Phosphate, TM-C12-15 Pareth-8 Phosphate, TM-C12-15 Pareth-10 Phosphate, Trideceth-20, Trideceth-50, Trideceth-3 Carboxylic Acid, Trideceth-4 Carboxylic Acid, Trideceth-7 Carboxylic Acid, Trideceth-8 Carboxylic Acid, Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecylbenzenesulfonic Acid, Trilau- reth-9 Citrate, Trimethylolpropane Hydroxypropyl Bis-Hydroxyethylamine Dendrimer, Triso- dium Lauroampho PG-Acetate Chloride Phosphate, Undecanoic Acid, Undeceth-5 Carboxylic Acid, Undecylenamidopropylamine Oxide, Undecylenamidopropyl Betaine, Undecylenic Acid, Undecylenoyl Collagen Amino Acids, Undecylenoyl Glycine, Undecylenoyl Hydrolyzed Colla- gen, Undecylenoyl Wheat Amino Acids, Undecyl Glucoside, Wheat Germ Acid, Wheat Ger- mamidopropylamine Oxide, Wheat Germamidopropyl Betaine, Yucca Schidigera Leaf / Root / Stem Extract, Yucca Schidigera Stem Extract, Zinc Coceth Sulfatea and Zinc Coco- Sulfate.

[0033] Preferred are one or more compounds selected from the group consisting of Sodium Laureth Sulfate, Cocamidopropyl Betaine, Sodium Cocoamphoacetate, CocoGlucoside and Ammonium Lauryl Sulfosuccinate.

[0034] The percentage content of surfactants in the preparations may be from 0.1 to 10% by weight and is preferably from 0.5 to 5% by weight, based on the preparation. Oil bodies

[0035] Suitable oil bodies, which form constituents of the O / W emulsions, are, for example, Guerbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of linear C6-C22-fatty acids with linear or branched C6-C22-fatty alcohols or esters of branched C6-C 13-carboxylic acids with linear or branched C6-C 22-fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate,behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl be- henate and erucyl erucate. Also suitable are esters of linear C6-C22-fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of C18-C38- alkylhydroxy carboxylic acids with linear or branched C6-C 22-fatty alcohols, in particular Dioctyl Malate, esters of linear and / or branched fatty acids with polyhydric alcohols (such as, for example, propylene glycol, dimerdiol or trimertriol) and / or Guerbet alcohols, triglycerides based on C6-C10-fatty acids, liquid mono- / di- / triglyceride mixtures based on C6-C18-fatty acids, esters of C6- C22-fatty al- cohols and / or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, es- ters of C2- C12-dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon at- oms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C6-C22-fatty alco- hol carbonates, such as, for example, Dicaprylyl Carbonate (Cetiol® CC), Guerbet carbonates, based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of benzoic acid with linear and / or branched C6-C22-alcohols (e.g. Finsolv® TN), linear or branched, sym- metrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as, for example, dicaprylyl ether (Cetiol® OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicones, silicone methicone grades, etc.) and / or aliphatic or naphthenic hydrocarbons, such as, for example, squalane, squalene or dialkylcy- clohexanes. Emulsifiers

[0036] Other non-ionic or cationic surfactants may also be added to the preparations as emulsifiers, including for example: • products of the addition of 2 to 30 mol ethylene oxide and / or 0 to 5 mol propylene oxide onto linear C8-22 fatty alcohols, onto C12-22 fatty acids and onto alkyl phenols con- taining 8 to 15 carbon atoms in the alkyl group; • C12 / 18fatty acid monoesters and diesters of addition products of 1 to 30 mol ethylene oxide onto glycerol; • glycerol mono- and diesters and sorbitan mono- and diesters of saturated and unsatu- rated fatty acids containing 6 to 22 carbon atoms and ethylene oxide addition products thereof; • addition products of 15 to 60 mol ethylene oxide onto castor oil and / or hydrogenated castor oil; • polyol esters and, in particular, polyglycerol esters such as, for example, polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimerate isos- tearate. Mixtures of compounds from several of these classes are also suitable; • addition products of 2 to 15 mol ethylene oxide onto castor oil and / or hydrogenatedcastor oil; • partial esters based on linear, branched, unsaturated or saturated C6 / 22 fatty acids, ricin- oleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, - dipentaerythritol, sugar alcohols (for example sorbitol), alkyl glucosides (for example methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (for example cellulose); • mono-, di and trialkyl phosphates and mono-, di- and / or tri-PEG-alkyl phosphates and salts thereof; • wool wax alcohols; • polysiloxane / polyalkyl polyether copolymers and corresponding derivatives; • mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol and / or mixed esters of C6-22fatty acids, methyl glucose and polyols, preferably glycerol or polyglycer- ol, • alkyl and / or alkenyloligoglycosides; • polyalkylene glycols and • glycerol carbonate.

[0037] The addition products of ethylene oxide and / or propylene oxide onto fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or onto castor oil are known commercially available products. They are homo- logue mixtures of which the average degree of alkoxylation corresponds to the ratio between the quantities of ethylene oxide and / or propylene oxide and substrate with which the addi- tion reaction is carried out. C12 / 18fatty acid monoesters and diesters of addition products of ethylene oxide onto glycerol are known as lipid layer enhancers for cosmetic formulations. The preferred emulsifiers are described in more detail as follows:

[0038] Partial glycerides. Typical examples of suitable partial glycerides are stearic acid monoglyceride, stearic acid diglyceride, hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid mono- glyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, lino- leic acid monoglyceride, linoleic acid diglyceride, linolenic acid monoglyceride, linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid mono- glyceride, malic acid diglyceride, mixed esters of citric acid and stearic or oleic acid with glyc- erol and technical mixtures thereof which may still contain small quantities of triglyceride from the production process. Addition products of 1 to 30 and preferably 5 to 10 mol eth- ylene oxide onto the partial glycerides mentioned are also suitable.

[0039] Sorbitan esters. Suitable sorbitan esters are sorbitan monoisostearate, sorbitan ses- quiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquieru- cate, sorbitan dierucate, sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquiricino- leate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomale- ate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and technical mixtures thereof. Addition products of 1 to 30 and preferably 5 to 10 mol ethylene oxide onto the sorbitan esters mentioned are also suitable.

[0040] Polyglycerol esters. Typical examples of suitable polyglycerol esters are Polyglyceryl- 2 Dipolyhydroxystearate (Dehymuls®PGPH), Polyglycerin-3-Diisostearate (Lameform®TGI), Polyglyceryl-4 Isostearate (Isolan®GI 34), Polyglyceryl-3 Oleate, Diisostearoyl Polyglyceryl-3 Diisostearate (Isolan® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care®450), Poly- glyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether (Chimexane®NL), Polyglyceryl-3 Distearate (Cremophor® GS 32) and Polyglyceryl Polyricinoleate (Admul®WOL 1403), Polyglyceryl Dimerate Isostearate and mixtures thereof. Examples of other suitable polyolesters are the mono-, di- and triesters of trimethylol propane or pentaerythritol with lauric acid, cocofatty acid, tallow fatty acid, pal- mitic acid, stearic acid, oleic acid, behenic acid and the like optionally reacted with 1 to 30 mol ethylene oxide.

[0041] Alkyl and / or alkenyl oligoglycosides. Alkyl and / or alkenyl oligoglycosides, their preparation and their use are known from the prior art. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols containing 8 to 18 carbon atoms. With regard to the glycoside residue, monoglycosides, in which a cyclic sugar residue is gly- cosidically bonded to the fatty alcohol, as well as oligomeric glycosides with a degree of oli- gomerization up to preferably about 8 are suitable. The degree of oligomerization is a statis- tical mean value based on a homolog distribution customary for such technical products.

[0042] Tetraalkyl ammonium salts. Cationically active surfactants comprise the hydropho- bic high molecular group required for the surface activity in the cation by dissociation in aqueous solution. A group of important representatives of the cationic surfactants are the tetraalkyl ammonium salts of the general formula: (R1R2R3R4N+) X-. Here R1 stands for C1-C8 alk(en)yl, R2, R3and R4, independently of each other, for alk(en)yl radicals having 1 to 22 car- bon atoms. X is a counter ion, preferably selected from the group of the halides, alkyl sulfates and alkyl carbonates. Cationic surfactants, in which the nitrogen group is substituted with two long acyl groups and two short alk(en)yl groups, are particularly preferred.

[0043] Esterquats. A further class of cationic surfactants particularly useful as co-surfactants for the present invention is represented by the so-called esterquats. Esterquats are generallyunderstood to be quaternised fatty acid triethanolamine ester salts. These are known com- pounds which can be obtained by the relevant methods of preparative organic chemistry. Reference is made in this connection to International patent application WO 91 / 01295 A1, according to which triethanolamine is partly esterified with fatty acids in the presence of hy- pophosphorous acid, air is passed through the reaction mixture and the whole is then quaternised with dimethyl sulphate or ethylene oxide. In addition, German patent DE 4308794 C1 describes a process for the production of solid esterquats in which the quaterni- sation of triethanolamine esters is carried out in the presence of suitable dispersants, prefer- ably fatty alcohols.

[0044] Typical examples of esterquats suitable for use in accordance with the invention are products of which the acyl component derives from monocarboxylic acids corresponding to formula RCOOH in which RCO is an acyl group containing 6 to 10 carbon atoms, and the amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are ca- proic acid, caprylic acid, capric acid and technical mixtures thereof such as, for example, so- called head-fractionated fatty acid. Esterquats of which the acyl component derives from monocarboxylic acids containing 8 to 10 carbon atoms, are preferably used. Other esterquats are those of which the acyl component derives from dicarboxylic acids like malonic acid, suc- cinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebac- ic acid and / or dodecanedioic acid, but preferably adipic acid. Overall, esterquats of which the acyl component derives from mixtures of monocarboxylic acids containing 6 to 22 carbon atoms, and adipic acid are preferably used. The molar ratio of mono and dicarboxylic acids in the final esterquat may be in the range from 1:99 to 99:1 and is preferably in the range from 50:50 to 90:10 and more particularly in the range from 70:30 to 80:20. Besides the quater- nised fatty acid triethanolamine ester salts, other suitable esterquats are quaternized ester salts of mono- / dicarboxylic acid mixtures with diethanolalkyamines or 1,2-dihydroxypropyl dialkylamines. The esterquats may be obtained both from fatty acids and from the corre- sponding triglycerides in admixture with the corresponding dicarboxylic acids. One such pro- cess, which is intended to be representative of the relevant prior art, is proposed in European patent EP 0750606 B1. To produce the quaternised esters, the mixtures of mono- and dicar- boxylic acids and the triethanolamine - based on the available carboxyl functions - may be used in a molar ratio of 1.1:1 to 3:1. With the performance properties of the esterquats in mind, a ratio of 1.2:1 to 2.2:1 and preferably 1.5:1 to 1.9:1 has proved to be particularly ad- vantageous. The preferred esterquats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9. Superfatting agents and consistency factors

[0045] Superfatting agents may be selected from such substances as, for example, lanolin and lecithin and also polyethoxylated or acylated lanolin and lecithin derivatives, polyol fattyacid esters, monoglycerides and fatty acid alkanolamides, the fatty acid alkanolamides also serving as foam stabilizers.

[0046] The consistency factors mainly used are fatty alcohols or hydroxyfatty alcohols con- taining 12 to 22 and preferably 16 to 18 carbon atoms and also partial glycerides, fatty acids or hydroxyfatty acids. A combination of these substances with alkyl oligoglucosides and / or fatty acid N-methyl glucamides of the same chain length and / or polyglycerol poly-12- hydroxystearates is preferably used. Thickening agents and rheology additives

[0047] Suitable thickeners are polymeric thickeners, such as Aerosil® types (hydrophilic sili- cas), polysaccharides, more especially xanthan gum, guar-guar, agar-agar, alginates and tylo- ses, carboxymethyl cellulose and hydroxyethyl cellulose, also relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids, polyacrylates (for example Carbo- pols® [Goodrich] or Synthalens® [Sigma]), polyacrylamides, polyvinyl alcohol and polyvinyl pyrrolidone, surfactants such as, for example, ethoxylated fatty acid glycerides, esters of fatty acids with polyols, for example pentaerythritol or trimethylol propane, narrow-range fatty alcohol ethoxylates and electrolytes, such as sodium chloride and ammonium chloride. Film formers

[0048] Suitable film formers encompass the following species: Product INCI Declaration Oleocraft LP 20 PA (MV) Polyamide-8 Oleocraft MP 30 PA (MV) Polyamide-3 Trimethylpentanediol / Adipic Acid / Glycerin WetFilm Crosspolymer CosmoSurf CE 100 Octyldodecyl Citrate Crosspolymer TegoCare 450 Polyglyceryl-3 Methyl Glucose Distearate Performa V6112 C28-52 Olefin / Undecylenic Acid Copolymer Floraester Jojoba K100 Hydrolyzed Jojoba esters, Jojoba Esters, Aqua KP545 Cyclopentasiloxane Acrylates / Dimethicone copolymer Volarest Acrylates / Beheneth-25 Methacylate Copolymer Dermacryl E Polymer Styrene / Acrylates Copolymer Baycusan C1001 Polyurethane Hybridur 875 Polymer Polyurethane-2 and Polymethyl Methacrylate Dermacryl 2.0 Polymer Acrylates / Octylacrylamide CopolymerSymEffekt Sun Beeswax (Cera Alba) (and) Sodium Stearoyl Lactylate Pullulan Pullulan Xanthan Gum Xanthan Gum Microcrystalline cellulose (and) Sphingomonas ferment ex- PemuPur™ START Polymer tract (and) Cellulose gum SOLAGUM™ AX Acacia Senegal Gum & Xanthan Gum Natpure Cellgum Plus Microcrystalline Cellulose (and) Cellulose Gum AMISOFT® HS-11P Sodium Stearoyl Glutamate Hydrogenated Polycyclopentadiene (and) Caprylic / Capric Koboguard® 5400 CCT Triglyceride Glyceryl Hydrogenated Rosinate (And) Caprylic / Capric Tri- KOBOGUARD® NATURAL 2063-CCT glyceride (And) Tocopherol LaraCare® A 200 Galactoarabinan Wacker BELSIL® CDM 3526 VP C26-28 Alkyl Dimethicone Silsoft 034 Caprylyl Methicone Dowsil 2503 Cosmetic Wax Stearyl Dimethicone (and) Octadecene Antaron™ V 216 VP / Hexadecene Copolymer Antaron™ WP-660 Triacontanyl PVP LexFilm™ Sun Natural MB Capryloyl Glycerin / Sebacic Acid Copolymer Tego SP 13 Sun Up Poly C10-30 Alkyl Acrylate Sunspheres™ BIO SPF Booster Microcrystalline Cellulose Polymers

[0049] Suitable cationic polymers are, for example, cationic cellulose derivatives such as, for example, the quaternized hydroxyethyl cellulose obtainable from Amerchol under the name of Polymer JR 400®, cationic starch, copolymers of diallyl ammonium salts and acrylamides, quaternized vinyl pyrrolidone / vinyl imidazole polymers such as, for example, Luviquat® (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides such as, for example, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen (Lamequat® L, BASF), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such as, for example, amodimethicone, copolymers of adipic acid and dimethylaminohy- droxypropyl diethylenetriamine (Cartaretine®, Sandoz), copolymers of acrylic acid with dime- thyl diallyl ammonium chloride (Merquat®550, Lubrizol), polyaminopolyamides and cross- linked water-soluble polymers thereof, cationic chitin derivatives such as, for example, quaternized chitosan, optionally in microcrystalline distribution, condensation products of dihaloalkyls, for example dibromobutane, with bis-dialkylamines, for example bis-dimethylamino-1,3-propane, cationic guar gum such as, for example, Jaguar®CBS, Jaguar®C- 17, Jaguar®C-16 of Celanese, quaternized ammonium salt polymers such as, for example, Mirapol®A-15, Mirapol®AD-1, Mirapol®AZ-1 of Miranol and the various polyquaternium types (for example 6, 7, 32 or 37) which can be found in the market under the tradenames Rheocare®CC or Ultragel®300.

[0050] Suitable anionic, zwitterionic, amphoteric and nonionic polymers are, for example, vinyl acetate / crotonic acid copolymers, vinyl pyrrolidone / vinyl acrylate copolymers, vinyl ace- tate / butyl maleate / isobornyl acrylate copolymers, methyl vinylether / maleic anhydride copol- ymers and esters thereof, uncrosslinked and polyol-crosslinked polyacrylic acids, acrylamido- propyl trimethylammonium chloride / acrylate copolymers, octylacrylamide / methyl methacry- late / tert.-butylaminoethyl methacrylate / 2-hydroxypropyl methacrylate copolymers, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymers, vinyl pyrroli- done / dimethylaminoethyl methacrylate / vinyl caprolactam terpolymers and optionally deri- vatized cellulose ethers and silicones. Pearlizing waxes

[0051] Suitable pearlising waxes are, for example, alkylene glycol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially cocofatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic, optionally hydroxy- substituted carboxylic acids with fatty alcohols containing 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; fatty compounds, such as for example fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates which contain in all at least 24 car- bon atoms, especially laurone and distearylether; fatty acids, such as stearic acid, hydroxys- tearic acid or behenic acid, ring opening products of olefin epoxides containing 12 to 22 car- bon atoms with fatty alcohols containing 12 to 22 carbon atoms and / or polyols containing 2 to 15 carbon atoms and 2 to 10 hydroxyl groups and mixtures thereof. Silicones

[0052] Suitable silicones can be chosen from the group consisting of: Acefylline Methylsilanol Mannuronate, Acetylmethionyl Methylsilanol Elastinate Acrylates / Behenyl, Acry- late / Dimethicone Methacrylate Copolymer, Acrylates / Behenyl Methacrylate / Dimethicone Methacrylate Copolymer, Acrylates / Bis-Hydroxypropyl Dimethicone Crosspolymer, Acry- lates / Dimethicone Copolymer, Acrylates / Dimethicone Methacrylate / Ethylhexyl Acrylate Co- polymer, Acrylates / Dimethiconol Acrylate Copolymer, Acrylates / Ethylhexyl Acry- late / Dimethicone Methacrylate Copolymer, Acrylates / Octylacrylamide / Diphenyl Amodimethi- cone Copolymer, Acrylates / Polytrimethylsiloxymethacrylate Copolymer, Acrylates / Propyl Tri- methicone Methacrylate Copolymer, Acrylates / Stearyl Acrylate / Dimethicone Methacrylate Copolymer, Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / Dimethicone Meth-acrylate Copolymer, Acrylates / Trifluoropropylmethacrylate / Polytrimethyl Siloxymethacrylate Copolymer, Amino Bispropyl Dimethicone, Aminoethylaminopropyl Dimethicone, Aminopro- pyl Dimethicone, Aminopropyl Phenyl Trimethicone, Aminopropyl Triethoxysilane, Ammoni- um Dimethicone PEG-7 Sulfate, Amodimethicone, Amodimethicone Hydroxystearate, Amodimethicone / Silsesquioxane Copolymer, Ascorbyl Carboxydecyl Trisiloxane, Ascorbyl Methylsilanol Pectinate, Behenoxy Dimethicone, Behentrimonium Dimethicone PEG-8 Phthalate, Behenyl Dimethicone, Bisamino PEG / PPG-41 / 3 Aminoethyl PG-Propyl Dimethi- cone, Bis-Aminopropyl / Ethoxy Aminopropyl Dimethicone, Bis(Butylbenzoate) Diaminotriazine Aminopropyltrisiloxane, Bis-Butyldimethicone Polyglyceryl-3, Bis- Butyloxyamodimethicone / PEG-60 Copolymer, Bis(C13-15 Alkoxy) Hydroxybutamidoamodi- methicone, Bis(C13-15 Alkoxy) PG- Amodimethicone, Bis-(C1-8 Alkyl Lauroyl Lysine Decylcar- boxamide) Dimethicone, Bis-Cetyl Cetyl Dimethicone, Bis-Cetyl / PEG-8 Cetyl PEG-8 Dimethi- cone, Bis-Diphenylethyl Disiloxane, Bis-Ethyl Ethyl Methicone, Bis- Gluconamidoethylaminopropyl Dimethicone, Bis-Hydrogen Dimethicone, Bis- Hydroxyethox- ypropyl Dimethicone Bis-Hydroxylauryl, Dimethicone / IPDI Copolymer, Bis- Hydroxy / Methoxy Amodimethicone, Bis-Hydroxypropyl Dimethicone Behenate, Bis-Hydroxypropyl Dimethi- cone / SMDI Copolymer, Bis-lsobutyl PEG-14 / Amodimethicone Copolymer, Bis-lsobutyl PEG- 15 / Amodimethicone Copolymer, Bis-lsobutyl PEG / PPG-20 / 35 / Amodimethicone Copolymer, Bis- lsobutyl PEG / PPG-10 / 7 / Dimethicone Copolymer, Bis-lsobutyl PEG-24 / PPG- 7 / Dimethicone Copolymer, Bis-PEG-1 Dimethicone, Bis-PEG-4 Dimethicone, Bis-PEG-8 Dime- thicone, Bis-PEG-12 Dimethicone,Bis-PEG-20 Dimethicone, Bis-PEG-12 Dimethicone Beeswax, Bis-PEG-12 Dimethicone Candelillate, Bis-PEG-15 Dimethicone / IPDI Copolymer, Bis-PEG-15 Methyl Ether Dimethicone, Bis- PEG-18 Methyl Ether Dimethyl Silane, Bis-PEG / PPG-14 / 14 Dimethicone, Bis-PEG / PPG-15 / 5 Dimethicone, Bis-PEG / PPG-18 / 6 Dimethicone, Bis-PEG / PPG- 20 / 20 Dimethicone, Bis-PEG / PPG- 16 / 16 PEG / PPG-16 / 16 Dimethicone, Bis-PEG / PPG-20 / 5 PEG / PPG-20 / 5 Dimethicone, Bisphenylhexamethicone, Bis-Phenylpropyl Dimethicone, Bispol- yethylene Dimethicone, Bis- (Polyglyceryl-3 Oxyphenylpropyl) Dimethicone, Bis-(Polyglyceryl- 7 Oxyphenylpropyl) Dimethicone, Bis-PPG-15 Dimethicone / IPDI Copolymer, Bis(PPG-7 Unde- ceneth-21) Dimethicone, Bis-Stearyl Dimethicone, Bis-Trimethoxysilylethyl Tetramethyl- disiloxyethyl Dimethicone, Bis-Vinyldimethicone, Bis-Vinyl Dimethicone / Dimethicone Copol- ymer, Borage Seed Oil PEG-7 Dimethicone Esters, Butyl Acrylate / C6-14 Perfluoroalkylethyl Acrylate / Mercaptopropyl Dimethicone Copolymer, Butyl Acrylate / Hydroxypropyl Dimethi- cone Acrylate Copolymer, Butyl Dimethicone Acrylate / Cyclohexylmethacrylate / Ethylhexyl Acrylate Copolymer, Butyldimethicone Methacrylate / Methyl Methacrylate Crosspolymer, t- Butyl Dimethyl SiIyI Grape Seed Extract, Butyl Polydimethylsiloxyl Eth- ylene / Propylene / Vinylnorbornene Copolymer, C6-8 Alkyl C3-6 Alkyl Glucoside Dimethicone, C20-24 Alkyl Dimethicone,C24-28 Alkyl Dimethicone, C26-28 Alkyl Dimethicone, C30-45 Alkyl Dimethicone, C30-60 Alkyl Dimethicone, C32 Alkyl Dimethicone, C30-45 Alkyl Dimethi- cone / Polycyclohexene Oxide Crosspolymer, C26-28 Alkyldimethylsilyl Polypropylsilsesquiox- ane, C30-45 Alkyldimethylsilyl Polypropylsilsesquioxane, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C26-28 Alkyl Methicone, C30-45 Alkyl Methicone, C20-28 Alkyl Per-fluorodecylethoxy Dimethicone, C26-54 Alkyl Tetradecyl Dimethicone, Capryl Dimethicone, Caprylyl Dimethicone Ethoxy Glucoside, Caprylyl Methicone, Caprylyl Trimethicone, Carboxy- decyl Trisiloxane, Castor Oil Bis-Hydroxypropyl Dimethicone Esters Cerotyl Dimethicone, Ce- tearyl Dimethicone Crosspolymer, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Cetearyl Methicone, Cetrimonium Carboxydecyl PEG-8 Dimethicone, Cetrimonium Dimethi- cone PEG-7 Phthalate, Cetyl Behenyl Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone / Bis- Vinyldimethicone Crosspolymer, Cetyl Hexacosyl Dimethicone, Cetyloxy Dimethicone, Cetyl PEG-8 Dimethicone, Cetyl PEG / PPG-15 / 15 Butyl Ether Dimethicone, Cetyl PEG / PPG-7 / 3 Dime- thicone, Cetyl PEG / PPG-10 / 1 Dimethicone, Cetyl Triethylmonium Dimethicone PEG-8 Phthalate, Cetyl Triethylmonium Dimethicone PEG-8 Succinate, Copper Acetyl Tyrosinate Me- thylsilanol, Copper PCA Methylsilanol, C4-14 Perfluoroalkylethoxy Dimethicone, Cycloethox- ymethicone, Cycloheptasiloxane, Cyclohexasiloxane, Cyclomethicone, Cyclopentasiloxane, Cyclophenylmethicone, Cyclotetrasiloxane,mCyclovinylmethicone, Cystine Bis-PG-Propyl Silanetriol, DEA PG-Propyl PEG / PPG-18 / 21 Dimethicone, Diisostearoyl Trimethylolpropane Siloxy Silicate, Dilauroyl Trimethylolpropane Siloxy Silicate, Dilinoleamidopropyl Dimethyla- mine Dimethicone PEG-7 Phosphate, Dimethicone, Dimethicone Crosspolymer, Dimethicone Crosspolymer-3, Dimethicone / Divinyldimethicone / Silsesquioxane Crosspolymer, Dimethicone Ethoxy Glucoside, Dimethicone Hydroxypropyl Trimonium Chloride, Dimethi- cone / Mercaptopropyl Methicone Copolymer, Dimethicone PEG-15 Acetate Dimethicone PEG-8 Adipate, Dimethicone PEG-7 Avocadoate, Dimethicone PEG-8 Avocadoate, Dimethi- cone PEG-8 Beeswax, Dimethicone PEG-8 Benzoate, Dimethicone PEG-8 Borageate, Dimethi- cone PEG-7 Cocoate, Dimethicone / PEG-10 Crosspolymer, Dimethicone / PEG-10 / 15 Crosspol- ymer, Dimethicone / PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG- 8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG-8 Lanolate, Dimethicone PEG-8 Laurate, Dimethicone PEG-8 Meadowfoamate, Dimethicone PEG-7 Octyldodecyl Citrate, Di- methicone PEG-7 Olivate, Dimethicone PEG-8 Olivate, Dimethicone PEG-7 Phosphate, Dime- thicone PEG-8 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG-7 Phthalate, Dimethicone PEG-8 Phthalate, Dimethicone PEG-8 Polyacrylate, Dimethicone PEG / PPG- 20 / 23 Benzoate, Dimethicone PEG / PPG-7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phos- phate, Dimethicone PEG-7 Succinate, Dimethicone PEG-8 Succinate, Dimethicone PEG-7 Sul- fate, Dimethicone PEG-7 Undecylenate, Dimethicone PG-Diethylmonium Chloride, Dimethi- cone / Phenyl Vinyl Dimethicone Crosspolymer, Dimethicone / Polyglycerin-3 Crosspolymer, Dimethicone / PPG-20 Crosspolymer, Dimethicone Propylethylenediamine Behenate, Dimethi- cone Propyl PG-Betaine, Dimethicone / Silsesquioxane Copolymer, Dimethicone Silylate, Dime- thicone? / inyl Dimethicone Crosspolymer, Dimethicone / Vinyltrimethylsiloxysilicate Crosspol- ymer, Dimethiconol, Dimethiconol Arginine, Dimethiconol Beeswax, Dimethiconol Behenate, Dimethiconol Borageate, Dimethiconol Candelillate, Dimethiconol Carnaubate, Dimethiconol Cysteine, Dimethiconol Dhupa Butterate, Dimethiconol Fluoroalcohol Dilinoleic Acid, Dime- thiconol Hydroxystearate, Dimethiconol lllipe Butterate, Dimethiconol / IPDI Copolymer, Dime- thiconol Isostearate, Dimethiconol Kokum Butterate, Dimethiconol Lactate, Dimethiconol Meadowfoamate, Dimethiconol Methionine, Dimethiconol / Methylsilanol / Silicate Crosspoly-mer, Dimethiconol Mohwa Butterate, Dimethiconol Panthenol, Dimethiconol Sal Butterate, Dimethiconol / Silica Crosspolymer, Dimethiconol / Silsesquioxane Copolymer, Dimethiconol Stearate, Dimethiconol / Stearyl, Methicone / Phenyl Trimethicone Copolymer, Dimethoxysilyl Ethylenediaminopropyl Dimethicone, Dimethylaminopropylamido PCA Dimethicone, Dime- thyl Oxobenzo Dioxasilane, Dimethylsilanol Hyaluronate, Dioleyl Tocopheryl Methylsilanol, Diphenyl Amodimethicone, Diphenyl Dimethicone, Diphenyl Dimethicone Crosspolymer Di- phenyl Dimethicone? / inyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer, Diphenylethyl Benzyloxy Dilsiloxane, Diphenylisopropyl Dimethicone, Diphenylsiloxy Phenyl / Propyl Trime- thicone, Diphenylsiloxy Phenyl Trimethicone Disiloxane, Disodium Amodimethicone Disuccin- amide, Disodium PEG-12 Dimethicone Sulfosuccinate, Disodium PEG-8 Lauryl Dimethicone Sulfosuccinate, Divinyldimethicone / Dimethicone Copolymer, Divinyldimethi- cone / Dimethicone Crosspolymer, Drometrizole Trisiloxane, Ethylhexyl Acry- late / VP / Dimethicone Methacrylate Copolymer, Ethyl Methicone, Ethyl Trisiloxane, Fluoro C2-8 Alkyldimethicone, Gluconamidopropyl Aminopropyl Dimethicone, 4-(2-Beta- Glucopyranosiloxy) Propoxy-2-Hydroxybenzophenone, Glyceryl Undecyl Dimethicone, Glycidoxy Dimethicone, Hexadecyl Methicone, Hexyl Dimethicone, Hexyl Methicone, Hex- yltrimethoxysilane, Hydrogen Dimethicone, Hydrogen Dimethicone / Octyl Silsesquioxane Co- polymer, Hydrolyzed Collagen PG-Propyl Dimethiconol, Hydrolyzed Collagen PG-Propyl Me- thylsilanediol, Hydrolyzed Collagen PG-Propyl Silanetriol, Hydrolyzed Keratin PG-Propyl Me- thylsilanediol, Hydrolyzed Sesame Protein PG-Propyl Methylsilanediol, Hydrolyzed Silk PG- Propyl Methylsilanediol, Hydrolyzed Silk PG-Propyl Methylsilanediol Crosspolymer, Hydro- lyzed Soy Protein / Dimethicone PEG-7 Acetate, Hydrolyzed Soy Protein PG-Propyl Me- thylsilanediol, Hydrolyzed Vegetable Protein PG-Propyl Silanetriol, Hydrolyzed Wheat Pro- tein / Cystine Bis-PG-Propyl Silanetriol Copolymer, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Acetate, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Phosphate Copolymer, Hydro- lyzed Wheat Protein PG-Propyl Methylsilanediol, Hydrolyzed Wheat Protein PG-Propyl Silan- etriol, Hydroxyethyl Acetomonium PG-Dimethicone, Hydroxypropyldimethicone, Hydroxy- propyl Dimethicone Behenate, Hydroxypropyl Dimethicone Isostearate, Hydroxypropyl Dime- thicone Stearate, Isobutylmethacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isobutylmethacrylate / Trifluoroethylmethacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, lsopentyl Trimethoxycinnamate Trisiloxane, lsopolyglyceryl-3 Dimethicone, lsopolyglyceryl-3 Dimethiconol, lsopropyl Titanium Triisostearate / Triethoxysilylethyl, Polydi- methylsiloxyethyl Dimethicone Crosspolymer, lsostearyl Carboxydecyl PEG-8 Dimethicone, Lactoyl Methylsilanol Elastinate, Lauryl Dimethicone, Lauryl Dimethicone PEG-15 Crosspoly- mer, Lauryl Dimethicone PEG- 10 Phosphate, Lauryl Dimethicone / Polyglycerin-3 Crosspoly- mer, Lauryl Methicone, Lauryl PEG-8 Dimethicone, Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG / PPG-18 / 18 Methicone, Lauryl Phenylisopropyl Methicone, Lauryl Phenylpropyl Methicone, Lauryl Polydimethylsiloxyethyl Dimethicone / Bis-Vinyldimethicone Crosspolymer, Lauryl Polyglyceryl-3 Polydimethylsiloxy- ethyl Dimethicone, Lauryl Trimethicone, Linoleamidopropyl PG-Dimonium Chloride Phos- phate Dimethicone, Methacryloyl Propyltrimethoxysilane, Methicone, Methoxy Amodimethi-cone / Silsesquioxane Copolymer, Methoxycinnamidopropyl Polysilsesquioxane, Methox- ycinnamoylpropyl Silsesquioxane Silicate, Methoxy PEG-13 Ethyl Polysilsesquioxane, Methoxy PEG / PPG-7 / 3 Aminopropyl Dimethicone, Methoxy PEG / PPG-25 / 4 Dimethicone, Methoxy PEG-10 Propyltrimethoxysilane, Methyleugenyl PEG- 8 Dimethicone, Methylpolysiloxane Emulsion, Methylsilanol Acetylmethionate, Methylsilanol Acetyltyrosine, Methylsilanol Ascor- bate, Methylsilanol Carboxymethyl Theophylline, Methylsilanol Carboxymethyl Theophylline Alginate, Methylsilanol Elastinate, Methylsilanol Glycyrrhizinate, Methylsilanol Hydroxyproline, Methylsilanol Hydroxyproline Aspartate, Methylsilanol Mannuronate, Methylsilanol PCA, Me- thylsilanol PEG-7 Glyceryl Cocoate, Methylsilanol / Silicate Crosspolymer, Methylsilanol Spiruli- nate, Methylsilanol Tri-PEG-8 Glyceryl Cocoate, Methyl Trimethicone, Methyltrimethoxysilane, Myristylamidopropyl Dimethylamine Dimethicone PEG-7 Phosphate, Myristyl Methicone, Myristyl Trisiloxane, Nylon-611 / Dimethicone Copolymer, PCA Dimethicone, PEG-7 Amodime- thicone, PEG-8 Amodimethicone, PEG-8 Cetyl Dimethicone, PEG-3 Dimethicone, PEG-6 Dime- thicone, PEG-7 Dimethicone, PEG-8 Dimethicone, PEG-9 Dimethicone, PEG-10 Dimethicone, PEG-12 Dimethicone, PEG-14 Dimethicone, PEG-17 Dimethicone, PEG-10 Dimethicone Cross- polymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimethicone / Dimer Dilinoleic Acid Copolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-8 Distearmonium Chloride PG-Dimethicone, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG- 15 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Polydimethylsiloxy- ethyl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Methicone Acetate, PEG-6 Methyl Ether Dimethicone, PEG- 7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG- 9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dime- thicone, PEG-32 Methyl Ether Dimethicone, PEG-8 Methyl Ether Triethoxysilane, PEG-10 No- nafluorohexyl Dimethicone Copolymer, PEG-4 PEG-12 Dimethicone, PEG-8 PG-Coco- Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG / PPG-20 / 22 Butyl Ether Dimethicone, PEG / PPG-22 / 22 Butyl Ether Dimethicone, PEG / PPG-23 / 23 Butyl Ether Di- methicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-27 / 9 Butyl Ether Dimethicone, PEG / PPG-3 / 10 Dimethicone, PEG / PPG-4 / 12 Dimethicone, PEG / PPG-6 / 4 Dimethicone, PEG / PPG-6 / 11 Dimethicone, PEG / PPG-8 / 14 Dimethicone, PEG / PPG-8 / 26 Dimethicone, PEG / PPG-10 / 2 Dimethicone, PEG / PPG-12 / 16 Dimethicone, PEG / PPG- 12 / 18 Dimethicone, PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone, PEG / PPG-20 / 15 Dimethicone, PEG / PPG-20 / 20 Dimethicone, PEG / PPG-20 / 23 Dimethicone, PEG / PPG-20 / 29 Dimethicone, PEG / PPG-22 / 23 Dimethicone, PEG / PPG-22 / 24 Dimethicone, PEG / PPG-23 / 6 Dimethicone, PEG / PPG-25 / 25 Dimethicone, PEG / PPG-27 / 27 Dimethicone, PEG / PPG-30 / 10 Dimethicone, PEG / PPG-25 / 25 Dimethicone / Acrylates Copolymer, PEG / PPG-20 / 22 Methyl Ether Dimethi- cone, PEG / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dime- thicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Tri- fluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorocaprylyl riethoxysilylethyl Methicone, Perfluorononyl Dimethicone, Perfluorononyl Dimethicone / Methicone / Amodimethicone Crosspolymer, Perfluorononylethyl Carboxydecyl Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Hexacosyl Dimethi- cone, Perfluorononylethyl Carboxydecyl Lauryl / Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl Dimethicone, Perfluorononylethyl Carboxydecyl PEG-8 Dimethicone, Perfluorononylethyl Carboxydecyl PEG-10 Dimethicone, Perfluorononylethyl Dimethi- cone / Methicone Copolymer, Perfluorononylethyl PEG-8 Dimethicone, Perfluorononylethyl Stearyl Dimethicone, Perfluorooctylethyl / Diphenyl Dimethicone Copolymer, Perfluo- rooctylethyl Triethoxysilane, Perfluorooctylethyl Trimethoxysilane, Perfluorooctylethyl Trisiloxane, Perfluorooctyl Triethoxysilane, PG-Amodimethicone, Phenethyl Dimethicone, Phenethyl Disiloxane, Phenyl Dimethicone, Phenylisopropyl Dimethicone, Phenyl Methicone, Phenyl Methiconol, Phenylpropyldimethylsiloxysilicate, Phenylpropyl Ethyl Methicone, Phenyl Propyl Trimethicone, Phenyl Propyl Trimethicone / Diphenylmethicone, Phenyl Trimethicone, Platinum Divinyldisiloxane, Polyacrylate-6, Polydiethylsiloxane, Polydimethylsiloxyethyl Dime- thicone / Bis-Vinyldimethicone Crosspolymer, Polydimethylsiloxyethyl Dimethicone / Methicone Copolymer, Polydimethylsiloxy PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy PPG- 13 Butyl Ether Silsesquioxane, Polyglyceryl-3 Disiloxane Dimethicone, Polyglyceryl- 3 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, Polyglyceryl-3 Polydime- thylsiloxyethyl Dimethicone, Poly(Glycol Adipate) / Bis-Hydroxyethoxypropyl Dimethicone Co- polymer, Polymethylsilsesquioxane, Polymethylsilsesquioxane / Trimethylsiloxysilicate, Poly- phenylsilsesquioxane, Polypropylsilsesquioxane, Polysilicone-1, Polysilicone-2, Polysilicone-3, Polysilicone-4, Polysilicone-5, Polysilicone-6, Polysilicone-7, Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone-12, Polysilicone-13, Polysilicone-14, Polysilicone- 15, Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysili- cone-21, Polysilicone-18 Cetyl Phosphate, Polysilicone-1 Crosspolymer, Polysilicone-18 Stea- rate, Polyurethane-10, Potassium Dimethicone PEG-7 Panthenyl Phosphate, Potassium Dime- thicone PEG- 7 Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG-27 Dimethicone, PPG-4 Oleth-10 Dimethicone, Propoxytetramethyl Piperi- dinyl Dimethicone, Propyl Trimethicone, Quaternium-80, Retinoxytrimethylsilane, Silanediol Salicylate, Silanetriol, Silanetriol Arginate, Silanetriol Glutamate, Silanetriol Lysinate, Silanetriol Melaninate, Silanetriol Trehalose Ether, Silica, Silica Dimethicone Silylate, Silica Dimethyl Si- lylate, Silica Silylate, Silicon Carbide, Silicone Quaternium-1, Silicone Quaternium-2, Silicone Quaternium-2 Panthenol Succinate, Silicone Quaternium-3, Silicone Quaternium-4, Silicone Quaternium-5, Silicone Quaternium-6, Silicone Quaternium-7, Silicone Quaternium-8, Silicone Quaternium-9, Silicone Quaternium-10, Silicone Quaternium-11, Silicone Quaternium-12, Silicone Quaternium-15, SiliconeQuaternium-16, Silicone Quaternium-16 / Glycidoxy Dimethi- cone Crosspolymer, Silicone Quaternium-17, Silicone Quaternium- 18, Silicone Quaternium- 19, Silicone Quaternium-20, Silicone Quaternium-21, Silicone Quaternium- 22, Silicone Qua- ternium-24, Silicone Quaternium-25, Siloxanetriol Alginate, Siloxanetriol Phytate, Simethi- cone, Sodium Carboxydecyl PEG-8 Dimethicone, Sodium Dimethicone PEG-7 Acetyl Methyl- taurate, Sodium Hyaluronate Dimethylsilanol, Sodium Lactate Methylsilanol, Sodium Mannu-ronate Methylsilanol, Sodium PCA Methylsilanol, Sodium PG-Propyldimethicone Thiosulfate Copolymer, Sodium PG-Propyl Thiosulfate Dimethicone, Sodium Propoxyhydroxypropyl Thio- sulfate Silica, Sorbityl Silanediol, Soy Triethoxysilylpropyldimonium Chloride, Stearalkonium Dimethicone PEG-8 Phthalate, Stearamidopropyl Dimethicone, Steardimonium Hydroxypro- pyl Panthenyl PEG-7 Dimethicone Phosphate Chloride, Steardimonium Hydroxypropyl PEG-7 Dimethicone Phosphate Chloride, Stearoxy Dimethicone, Stearoxymethicone / Dimethicone Copolymer, Stearoxytrimethylsilane, Stearyl Aminopropyl Methicone, Stearyl Dimethicone, Stearyl / Lauryl Methacrylate Crosspolymer, Stearyl Methicone, Stearyl Triethoxysilanek, Stearyl Trimethicone, Styrene / Acrylates / Dimethicone Acrylate Crosspolymer, Sty- rene / Acrylates / Dimethicone Copolymer, TEA-Dimethicone PEG-7 Phosphate, Tetrabutoxy- propyl Trisiloxane, Tetramethyl Hexaphenyl Tetrasiloxane, Tetramethyl Tetraphenyl Trisilox- ane, Tocopheryloxypropyl Trisiloxane, Trideceth-9 PG-Amodimethicone, Triethoxycapry- lylsilane, Triethoxysilylethyl Dimethicone / Methicone Copolymer, Triethoxysilylethyl Polydime- thylsiloxyethyl Dimethicone, Triethoxysilylethyl Polydimethylsiloxyethyl Hexyl Dimethicone, Triethoxysilylpropylcarbamoyl Ethoxypropyl Butyl Dimethicone, Trifluoromethyl C1-4 Alkyl Dimethicone, Trifluoropropyl Cyclopentasiloxane, Trifluoropropyl Cyclotetrasiloxane, Tri- fluoropropyl Dimethicone, Trifluoropropyl Dimethicone / PEG-10 Crosspolymer, Trifluoropro- pyl Dimethicone / Trifluoropropyl Divinyldimethicone Crosspolymer, Trifluoropropyl Dimethi- cone / Vinyl Trifluoropropyl, Dimethicone / Silsesquioxane Crosspolymer, Trifluoropropyl Dime- thiconol, Trifluoropropyldimethyl / trimethylsiloxysilicate, Trifluoropropyl Methicone, Tri- methoxycaprylylsilane, Trimethoxysilyl Dimethicone, Trimethyl Pentaphenyl Trisiloxane, Tri- methylsiloxyamodimethicone, Trimethylsiloxyphenyl Dimethicone, Trimethylsiloxysilicate, Trimethylsiloxysilicate / Dimethicone Crosspolymer, Trimethylsiloxysilicate / Dimethiconol Crosspolymer, Trimethylsiloxysilylcarbamoyl Pullulan, Trimethylsilyl Hydrolyzed Conchiolin Protein PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Hydrolyzed Silk PG-Propyl Methylsilanediol Crosspolymer, Trimethylsilyl Hydrolyzed Wheat Protein PG-Propyl Me- thylsilanediol Crosspolymer, Trimethylsilyl Pullulan, Trimethylsilyl Trimethylsiloxy Glycolate, Trimethylsilyl Trimethylsiloxy Lactate, Trimethylsilyl Trimethylsiloxy Salicylate, Triphenyl Trime- thicone, Trisiloxane, Tris-Tributoxysiloxymethylsilane, Undecylcrylene Dimethicone, Vinyl Di- methicone, Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer, Vinyl Dimethi- cone / Methicone Silsesquioxane Crosspolymer, Vinyldimethyl / Trimethylsiloxysilicate Stearyl Dimethicone Crosspolymer, VP / Dimethiconylacrylate / Polycarbamyl / Polyglycol Ester, Zinc Carboxydecyl Trisiloxane and Zinc Dimethicone PEG-8 Succinate and mixtures thereof.

[0053] More preferably the silicones to be contained in the mixture according to the inven- tions are Dimethicone, Cyclomethicone, Phenyl Trimethicone, Cyclohexasiloxane and Cyclo- pentasiloxane. A detailed overview of suitable volatile silicones can be found in Todd et al. in Cosm. Toil. 91, 27 (1976).Waxes and stabilizers

[0054] Besides natural oils used, waxes may also be present in the preparations, more espe- cially natural waxes such as, for example, candelilla wax, carnauba wax, Japan wax, espar- tograss wax, cork wax, guaruma wax, rice oil wax, sugar cane wax, ouricury wax, montan wax, beeswax, shellac wax, spermaceti, lanolin (wool wax), uropygial fat, ceresine, ozocerite (earth wax), petrolatum, paraffin waxes and microwaxes; chemically modified waxes (hard waxes) such as, for example, montan ester waxes, sasol waxes, hydrogenated jojoba waxes and syn- thetic waxes such as, for example, polyalkylene waxes and polyethylene glycol waxes.

[0055] Metal salts of fatty acids such as, for example, magnesium, aluminium and / or zinc stearate or ricinoleate may be used as stabilizers. Primary sun protection filters

[0056] Primary sun protection filters in the context of the invention are, for example, organic substances (light filters) which are liquid or crystalline at room temperature and which are capable of absorbing ultraviolet radiation and of releasing the energy absorbed in the form of longer-wave radiation, for example heat.

[0057] The formulations according to the invention advantageously contain at least one UV- A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic pigment. Formulations according to the invention preferably contain at least one UV-B filter or a broadband filter, more particularly preferably at least one UV-A filter and at least one UV-B filter.

[0058] The UV filters cited below which can be used within the context of the present inven- tion are preferred but naturally are not limiting. UV filters which are preferably used are se- lected from the group consisting of one, two, three, four, five or more of the following spe- cies: INCI Declaration Product / Trademark 4-Methylbenzylidene Camphor Neo Heliopan® MBC Benzophenone-3 Neo Heliopan® BB Benzophenone-4 Benzophenone-4, Benzophenone-5 Benzophenone-8 Benzylidene Camphor Sulfonic Acid Mexoryl SL Bis-(Diethylaminohydroxybenzoyl Benzoyl) Piperazine HAA299 (nano) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine Neo Heliopan® BMT Butyl Methoxydibenzoylmethane Neo Heliopan® 357Camphor Benzalkonium Methosulfate Mexoryl SK Cinoxate Diethylamino Hydroxy benzoyl Hexyl Benzoate Uvinul® A Plus Diethylhexyl Butamido Triazone Uvasorb® HEB Disodium Phenyl Dibenzimidazole Tetrasulfonate Neo Heliopan® AP Drometrizole Trisiloxane Mexoryl XL Ethylhexyl Dimethyl PABA Ethylhexyl Dimethyl PABA Ethylhexyl Methoxycinnamate Neo Heliopan® AV Ethylhexyl Salicylate Neo Heliopan® OS Ethylhexyl Triazone Neo Heliopan® EHT Homosalate Neo Heliopan® HMS Isoamyl p-Methoxycinnamate Menthyl Anthranilate Neo Heliopan® MA Methoxypropylamino Cyclohexenylidene Ethoxyethylcyanoacetate Mexoryl® 400 Methylene Bis-Benzotriazolyl Tetramethylbutylphenol Tinosorb®M Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (nano) Tinosorb®M Octocrylene Neo Heliopan® 303 PABA PEG-25 PABA Phenylbenzimidazole Sulfonic Acid Neo Heliopan® Hydro Phenylene Bis-Diphenyltriazine TriasorbTMPolyacrylamidomethyl Benzylidene Camphor Mexoryl SW Polysilicone-15 Parsol® SLX TEA-Salicylate Terephthalylidene Dicamphor Sulfonic Acid Mexoryl SX Titanium Dioxide Titanium Dioxide (nano) Tris-biphenyl triazine / Tris-biphenyl triazine (nano) Tinosorb® A2B Zinc Oxide Zinc Oxide (nano)

[0059] Particularly preferred UV filters encompass: INCI-Declaration Product / Trademark UVB UVA UVB / UVA Homosalate Neo Heliopan® HMS X Benzophenone-3 Neo Heliopan® BB X Phenylbenzimidazole Sulfonic Acid Neo Heliopan® Hydro X Butyl Methoxydibenzoylme- thane Neo Heliopan® 357 X Octocrylene Neo Heliopan® 303 X Ethylhexyl Methoxycinnamate Neo Heliopan® AV X Isoamyl p-Methoxycinnamate Neo Heliopan® E1000 X Ethylhexyl Triazone Neo Heliopan® EHT X 4-Methylbenzylidene Camphor Neo Heliopan® MBC X Ethylhexyl Salicylate Neo Heliopan® OS X Disodium Phenyl Dibenzimid- azole Tetrasulfonate Neo Heliopan® AP X Bis-Ethylhexyloxyphenol Meth- oxyphenyl Triazine Neo Heliopan® BMT X Titanium Dioxide (nano) SymTio® S X Zinc Oxide Neo Heliopan® ZnO 300 X Zinc Oxide (nano) Neo Heliopan® ZnO 40 X Menthyl Anthranilate Neo Heliopan® MA X

[0060] In a preferred embodiment the sun protection filter forming component (ii) repre- sents a blend of UV-A- and UV-B-filters selected from the group consisting of homosalate, octocrylene, bis-ethylhexyloxyphenol methoxyphenyl triazine, butyl methoxydibenzoylme- thane, ethylhexyl salicylate and mixtures thereof. Particular preferred is a blend of all these filters which is commercially available in the market under the trademark NeoHeliopan® Flat (SYMRISE), which also subject to WO 2020088778 A1.

[0061] Suitable pigments encompass oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirco- nium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminium (Al2O3), cerium (e.g. Ce2O3) and / or mixtures thereof.

[0062] In a further preferred embodiment, a formulation according to the invention contains a total amount of sunscreen agents, i.e. in particular UV filters and / or inorganic pigments (UV filtering pigments) so that the formulation according to the invention has a light protection factor of greater than or equal to 5 and up to 50. Such formulations according to the inven- tion are particularly suitable for protecting the skin and hair.Secondary sun protection filters

[0063] Besides the groups of primary sun protection factors mentioned above, secondary sun protection factors of the antioxidant type may also be used. Secondary sun protection factors of the antioxidant type interrupt the photochemical reaction chain which is initiated when UV rays penetrate into the skin. Typical examples are amino acids (for example glycine, histidine, tyrosine, tryptophane) and derivatives thereof, imidazoles (for example urocanic acid) and derivatives thereof, peptides, such as D,L-carnosine, D-carnosine, L-carnosine and derivatives thereof (for example anserine), carotinoids, carotenes (for example alpha- carotene, beta-carotene, lycopene) and derivatives thereof, chlorogenic acid and derivatives thereof, liponic acid and derivatives thereof (for example dihydroliponic acid), aurothioglu- cose, propylthiouracil and other thiols (for example thioredoxine, glutathione, cysteine, cys- tine, cystamine and glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, alpha-linoleyl, cholesteryl and glyceryl esters thereof) and their salts, dilaurylthiodi- propionate, distearylthiodipropionate, thiodipropionic acid and derivatives thereof (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and sulfoximine compounds (for example butionine sulfoximines, homocysteine sulfoximine, butionine sulfones, penta-, hexa- and hepta-thionine sulfoximine) in very small compatible dosages, also (metal) chelators (for example alpha-hydroxyfatty acids, palmitic acid, phytic acid, lactoferrine), alpha-hydroxy acids (for example citric acid, lactic acid, malic acid), humic acid, bile acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and derivatives thereof, unsaturated fatty acids and derivatives thereof (for example linoleic acid, oleic acid), folic acid and derivatives thereof, ubiquinone and ubiq- uinol and derivatives thereof, vitamin C and derivatives thereof (for example ascorbyl palmi- tate, Mg ascorbyl phosphate, ascorbyl acetate), tocopherols and derivatives (for example vit- amin E acetate), vitamin A and derivatives (vitamin A palmitate) and coniferyl benzoate of benzoin resin, rutinic acid and derivatives thereof, glycosyl rutin, ferulic acid, furfurylidene glucitol, carnosine, butyl hydroxytoluene, butyl hydroxyanisole, nordihydroguaiac resin acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and derivatives thereof, man- nose and derivatives thereof, superoxide dismutase, titanium dioxide (for example disper- sions in ethanol), zinc and derivatives thereof (for example ZnO, ZnSO4), selenium and deriva- tives thereof (for example selenium methionine), stilbenes and derivatives thereof (for exam- ple stilbene oxide, trans-stilbene oxide) and derivatives of these active substances suitable for the purposes of the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids).

[0064] Advantageous inorganic secondary light protection pigments are finely dispersed metal oxides and metal salts which are also mentioned in WO 2005 123101 A1. The total quantity of inorganic pigments, in particular hydrophobic inorganic micro-pigments in the finished cosmetic preparation according to the present invention is advantageously from 0.1 to 30% by weight, preferably 0.5 to 10.0% by weight, in each case based on the total weight of the preparation.

[0065] Also preferred are particulate UV filters or inorganic pigments, which can optionally be hydrophobed, can be used, such as the oxides of titanium (TiO2), zinc (ZnO), iron (Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminium (Al2O3), cerium (e.g. Ce2O3) and / or mixtures thereof. Biogenic agents and antioxidants

[0066] Biogenic active substances include, for example, tocopherol, tocopherol acetate, to- copherol palmitate, ascorbic acid, (deoxy)ribonucleic acid and its fragmentation products, β- glucans, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudoceramides, essential oils, plant extracts, such as such as prunus extract, bambaranus extract and vitamin complexes.

[0067] Antioxidants interrupt the photochemical reaction chain which is triggered when UV radiation penetrates the skin. Typical examples are amino acids (e.g. glycine, histidine, tyro- sine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides like D,L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. -carotene, lycopene) and their derivates, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolic acid), aurothioglucose, propylthiou- racil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamin and their gly- cosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, linoleyl, choles- teryl and glyceryl esters) and their salts Dilaurylthiodipropionate, ditearylthiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleo- sides and salts) as well as sulfoximine compounds (e.g. (e.g. buthionine sulfoximines, homo- cysteine sulfoximines, butionine sulfones, penta-, hexa-, heptathionine sulfoximines) in very low tolerated dosages (e.g. pmol to mol / kg), furthermore (metal) chelators (e.g. hydroxy fatty acids, palmitic acid, phytinic acid, lactoferrin), hydroxy acids (e.g. (e.g. citric acid, lactic acid, malic acid), humic acid, gallic acid, bile extracts, bilirubin, biliverdin, EDTA, EGTA and their derivatives, unsaturated fatty acids and their derivatives (e.g. linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (e.g. ascorbyl palmitate, Mg-ascorbyl phosphate, ascorbylacetate), tocoph- erols and derivatives (e.g. vitamin E acetate), vitamin A and derivates (vitamin A palmitate) as well as conifer aryl benzoate of benzoic resin, rutinic acid and its derivatives, glycosylrutin, ferulic acid, furfurylidene glucitol, carnosine, butyl hydroxytoluene, butylhydroxyanisole, nor- dihydroguaiac resin acid, nordihydroguajaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, zinc and its derivatives (e.g. e.g. ZnO, ZnSO4) selenium and its derivatives (e.g. selenium-methionine), stilbenes and their derivatives (e.g. styrene oxide, trans-stilbene oxide) and the derivatives suitable for the invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these named active substances.Actives modulating hair pigmentation

[0068] Preferred active ingredients for hair lightening are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyranone), kojic acid derivatives, preferably kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol deriva- tives, preferably 4-alkylresorcinols and 4-(1-phenylethyl)1,3-dihydroxybenzene (phenylethyl resorcinol), cyclohexylcarbamates (preferably one or more cyclohexyl carbamates disclosed in WO 2010 / 122178 and WO 2010 / 097480), sulfur-containing molecules, preferably glutathione or cysteine, alpha-hydroxy acids (preferably citric acid, lactic acid, malic acid), salts and esters thereof, N-acetyl tyrosine and derivatives, undecenoyl phenylalanine, gluconic acid, chro- mone derivatives, preferably aloesin, flavonoids, 1-aminoethyl phosphinic acid, thiourea de- rivatives, ellagic acid, nicotinamide (niacinamide), zinc salts, preferably zinc chloride or zinc gluconate, thujaplicin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably senkyunolide, vinyl guiacol, ethyl guiacol, dionic acids, preferably octodecene dionic acid and / or azelaic acid, inhibitors of nitrogen oxide synthesis, preferably L-nitroarginine and derivatives thereof, 2,7-dinitroindazole or thiocitrulline, metal chelators (preferably alpha-hydroxy fatty acids, phytic acid, humic acid, bile acid, bile extracts, EDTA, EGTA and derivatives thereof), retinoids, soy milk and extract, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for skin and hair lightening, the latter preferably used in the form of an extract from plants, preferably bearberry extract, rice extract, papaya extract, turmeric extract, mulberry extract, bengkoang extract, nutgrass ex- tract, liquorice root extract or constituents concentrated or isolated therefrom, preferably glabridin or licochalcone A, artocarpus extract, extract of rumex and ramulus species, extracts of pine species (pinus), extracts of vitis species or stilbene derivatives isolated or concentrat- ed therefrom, saxifrage extract, scutelleria extract, grape extract and / or microalgae extract, in particular Tetraselmis suecica Extract.

[0069] Advantageous skin and hair tanning active ingredients in this respect are substrates or substrate analogues of tyrosinase such as L-tyrosine, N-acetyl tyrosine, L-DOPA or L- dihydroxyphenylalanine, xanthine alkaloids such as caffeine, theobromine and theophyl-line and derivatives thereof, proopiomelanocortin peptides such as ACTH, alpha-MSH, peptide analogues thereof and other substances which bind to the melanocortin receptor, peptides, pyrimidines, folic acid, copper salts such as copper gluconate, chloride or pyrrolidonate, 1,3,4-oxadiazole-2-thiols such as 5-pyrazin-2-yl-1,3,4-oxadiazole-2-thiol, curcumin, zinc di- glycinate (Zn(GIy)2), manganese(ll) bicarbonate complexes ("pseudocat-alases") as described for example in EP 0 584 178, tetrasubstituted cyclohexene deriva-tives as described for ex- ample in WO 2005 / 032501 , isoprenoids as described in WO 2005 / 102252 and in WO 2006 / 010661 , melanin derivatives such as Melasyn-100 and MelanZe, diacyl glycerols, ali- phatic or cyclic diols, psoralens, prostaglandins and ana-logues thereof, activators of adenyl- ate cyclase and compounds which activate the transfer of melanosomes to keratinocytes such as serine proteases or agonists of the PAR-2 receptor, extracts of plants and plant parts of thechrysanthemum species, san-guisorba species, walnut extracts, urucum extracts, rhubarb ex- tracts, microalgae extracts, in particular Isochrysis galbana, trehalose, erythru-lose and dihy- droxyacetone. Flavonoids which bring about skin and hair tinting or brown-ing (e.g. querce- tin, rhamnetin, kaempferol, fisetin, genistein, daidzein, chrysin and api-genin, epicatechin, diosmin and diosmetin, morin, quercitrin, naringenin, hesperidin, phloridzin and phloretin) can also be used.

[0070] The amount of the aforementioned examples of additional active ingredients for the modulation of skin and hair pigmentation (one or more compounds) in the products accord- ing to the invention is then preferably 0.00001 to 30 wt.%, preferably 0.0001 to 20 wt.%, par- ticularly preferably 0.001 to 5 wt.%, based on the total weight of the preparation. Hair growth activators or inhibitors

[0071] Formulations and products according to the present invention may also comprise one or more hair growth activators, i.e. agents to stimulate hair growth. Hair growth activators are preferably selected from the group consisting of pyrimidine derivatives such as 2,4- diaminopyrimidine-3-oxide (Aminexil), 2,4-diamino-6-piperidinopyrimidine-3-oxide (Minox- idil) and derivatives thereof, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidinopyrimidine and its derivatives, xanthine alkaloids such as caffeine, theobromine and theophylline and derivatives thereof, quercetin and derivatives, dihydroquercetin (taxifolin) and derivatives, potassium channel openers, antiandrogenic agents, synthetic or natural 5-reductase inhibi- tors, nicotinic acid esters such as tocopheryl nicotinate, benzyl nicotinate and C1-C6 alkyl nicotinate, proteins such as for example the tripeptide Lys-Pro-Val, diphencypren, hormons, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, cyproterone acetate, spironolactone and other diuretics, calcineurin inhibitors such as FK506 (Tacrolimus, Fujimycin) and its derivatives, Cyclosporin A and derivatives thereof, zinc and zinc salts, polyphenols, procyanidins, proanthocyanidins, phytosterols such as for example beta-sitosterol, biotin, eugenol, (±)-beta-citronellol, panthenol, glycogen for example from mussels, extracts from microorganisms, algae, plants and plant parts of for example the genera dandelion (Leontodon or Taraxacum), Orthosiphon, Vitex, Coffea, Paullinia, Theobroma, Asiasarum, Cucurbita or Styphnolobium, Serenoa repens (saw palmet- to), Sophora flavescens, Pygeum africanum, Panicum miliaceum, Cimicifuga racemosa, Gly- cine max, Eugenia caryophyllata, Cotinus coggygria, Hibiscus rosa-sinensis, Camellia sinensis, Ilex paraguariensis, Isochrysis galbana, licorice, grape, apple, barley or hops or / nd hydroly- sates from rice or wheat.

[0072] Alternatively, formulations and products according to the present invention may comprise one or more hair growth inhibitors (as described above), i.e. agents to reduce or prevent hair growth. Hair growth inhibitors are preferably selected from the group consisting of activin, activin derivatives or activin agonists, ornithine decarboxylase inhibitors such as alpha-difluoromethylornithine or pentacyclic triterpenes like for example ursolic acid, betulin,betulinic acid, oleanolic acid and derivatives thereof, 5alpha-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, gamma-glutamyl transpeptidase inhibitors, transglutaminase inhibitors, soybean-derived serine protease inhib- itors, extracts from microorganisms, algae, different microalgae or plants and plant parts of for example the families Leguminosae, Solanaceae, Graminae, Asclepiadaceae or Cucurbita- ceae, the genera Chondrus, Gloiopeltis, Ceramium, Durvillea, Glycine max, Sanguisorba offici- nalis, Calendula officinalis, Hamamelis virginiana, Arnica montana, Salix alba, Hypericum per- foratum or Gymnema sylvestre. Physiological warming agents

[0073] Physiological warming agents can be selected from the group consisting of capsaicin, dihydrocapsaicin, nordihydrocapsaicin, homocapsaicin, homodihydrocapsaicin nonivamid, vannilyl butyl ether, and chili extracts. Anti-inflammatory agents

[0074] Suitable anti-inflammatory agents may be selected from the group formed by: (i) steroidal anti-inflammatory substances of the corticosteroid type, in particular hydro- cortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexame- thasone, dexamethasone phosphate, methylprednisolone or cortisone, (ii) non-steroidal anti-inflammatory substances, in particular oxicams such as piroxicam or tenoxicam, salicylates such as aspirin, disalcid, solprin or fendosal, acetic acid deriv- atives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clindanac, fenamates such as mefenamic, meclofenamic, flufenamic or niflumic, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenyl- butazone, oxyphenylbutazone, febrazone or azapropazone, (iii) natural or naturally occuring anti-inflammatory substances or substances that alleviate reddening and / or itching, in particular extracts or fractions from camomile, Aloe vera, Commiphora species, Rubia species, willow, willow-herb, oats, calendula, arnica, St John's wort, honeysuckle, rosemary, Passiflora incarnata, witch hazel, ginger or Echina- cea, or single active compounds thereof, (iv) histamine receptor antagonists, serine protease inhibitors (e.g. of Soy extracts), TRPV1 antagonists (e.g. 4-t-Butylcyclohexanol), NK1 antagonists (e.g. Aprepitant, Hydroxy- phenyl Propamidobenzoic Acid), cannabinoid receptor agonists (e.g. Palmitoyl Etha- nolamine) and TRPV3 antagonists.Anti-microbial agents

[0075] Suitable anti-microbial agents are, in principle, all substances effective against Gram- positive bacteria, such as, for example, 4- hydroxybenzoic acid and its salts and esters, N-(4- chlorophenyl)-N'-(3,4- dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether (triclo- san), 4-chloro-3,5-dimethyl-phenol, 2,2'-methylenebis(6-bromo-4- chlorophenol), 3-methyl- 4-(1-methylethyl)phenol, 2-benzyl-4-chloro-phenol, 3-(4-chlorophenoxy)-1,2-propanediol, 3- iodo-2-propynyl butylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, oil of cloves, menthol, mint oil, farnesol, phenoxy- ethanol, glycerol monocaprate, glycerol monocaprylate, glycerol monolaurate (GML), diglyc- erol monocaprate (DMC), 1,3-propanediol monocaprylate, 4-hydroxy acetophenone, salicylic acid N-alkylamides, such as, for example, n-octylsalicylamide or n- decylsalicylamide. Enzyme inhibitors

[0076] Suitable enzyme inhibitors are, for example, esterase inhibitors. These are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and, in particular, triethyl citrate (Hydagen CAT). The substances inhibit enzyme activity, thereby reducing the formation of odour. Other substances which are suitable esterase inhib- itors are sterol sulfates or phosphates, such as, for example, lanosterol, cholesterol, campes- terol, stigmasterol and sitosterol sulfate or phosphate, dicarboxylic acids and esters thereof, such as, for example, glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, mo- noethyl adipate, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and esters thereof, such as, for example, citric acid, malic acid, tartaric acid or diethyl tartrate, and zinc glycinate. Odour absorbers and antiperspirant active agents

[0077] Suitable odour absorbers are substances which are able to absorb and largely retain odour-forming compounds. They lower the partial pressure of the individual components, thus also reducing their rate of diffusion. It is important that perfumes must remain unim- paired in this process. Odour absorbers are not effective against bacteria. They comprise, for example, as main constituent, a complex zinc salt of ricinoleic acid or specific, largely odour- neutral fragrances which are known to the person skilled in the art as "fixatives", such as, for example, extracts of labdanum or styrax or certain abietic acid derivatives. The odour masking agents are fragrances or perfume oils, which, in addition to their function as odour masking agents, give the deodorants their respective fragrance note. Perfume oils which may be men- tioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances are extracts from flowers, stems and leaves, fruits, fruit peels, roots, woods, herbs and grasses, needles and branches, and resins and balsams. Also suitable are animal products, such as, for example, civet and castoreum. Typical synthetic fragrance compounds are products of theester, ether, aldehyde, ketone, alcohol, and hydrocarbon type. Fragrance compounds of the ester type are, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styrallyl pro- pionate and benzyl salicylate. The ethers include, for example, benzyl ethyl ether, and the aldehydes include, for example, the linear alkanals having 8 to 18 carbon atoms, citral, citron- ellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal, the ketones include, for example, the ionones and methyl cedryl ketone, the alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linaool, phenylethyl alcohol and terpineol, and the hydrocarbons include mainly the terpenes and balsams. Preference is, however, given to using mixtures of different fragrances which together produce a pleasing fragrance note. Essential oils of relatively low volatility, which are mostly used as aroma components, are also suitable as perfume oils, e.g. sage oil, camomile oil, oil of cloves, melissa oil, mint oil, cinna- mon leaf oil, linden flower oil, juniperberry oil, vetiver oil, olibanum oil, galbanum oil, labda- num oil and lavandin oil. Preference is given to using bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, α-hexylcinnamaldehyde, geraniol, benzylacetone, cyc- lamen aldehyde, linalool, boisambrene forte, ambroxan, indole, hedione, sandelice, lemon oil, mandarin oil, orange oil, allyl amyl glycolate, cyclovertal, lavandin oil, clary sage oil, β- damascone, geranium oil bourbon, cyclohexyl salicylate, Vertofix coeur, iso-E-super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, irotyl and floramat alone or in mixtures.

[0078] Suitable astringent antiperspirant active ingredients are primarily salts of aluminium, zirconium or of zinc. Such suitable antihydrotic active ingredients are, for example, aluminium chloride, aluminium chlorohydrate, aluminium dichlorohydrate, aluminium sesquichlorohy- drate and complex compounds thereof, e.g. with 1,2- propylene glycol, aluminium hydroxy- allantoinate, aluminium chloride tartrate, aluminium zirconium trichlorohydrate, aluminium zirconium tetrachlorohydrate, aluminium zirconium pentachlorohydrate and complex com- pounds thereof, e.g. with amino acids, such as glycine. Film formers and anti-dandruff agents

[0079] Standard film formers are, for example, chitosan, microcrystalline chitosan, quater- nized chitosan, polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid and salts thereof and similar compounds.

[0080] Suitable antidandruff agents are Pirocton Olamin (1-hydroxy-4-methyl-6-(2,4,4- trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), Baypival®(Climbazole), Keto- conazol® (4-acetyl-1-{4-[2-(2,4-dichlorophenyl) r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxylan-c- 4-ylmethoxyphenyl}-piperazine, ketoconazole, elubiol, selenium disulfide, colloidal sulfur, sulfur polyethylene glycol sorbitan monooleate, sulfur ricinol polyethoxylate, sulfur tar distil- late, salicylic acid (or in combination with hexachlorophene), undecylenic acid, monoethano-lamide sulfosuccinate Na salt, Lamepon®UD (protein / undecylenic acid condensate), zinc py- rithione, aluminium pyrithione and magnesium pyrithione / dipyrithione magnesium sulfate. Carriers and hydrotropes

[0081] Preferred cosmetics carrier materials are solid or liquid at 25°C and 1013 mbar (in- cluding highly viscous substances) as for example glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water and mixtures of two or more of said liquid carrier materials with water. Optionally, these preparations according to the invention may be produced using preservatives or solubilizers. Other preferred liquid carrier substances, which may be a component of a preparation according to the invention are se- lected from the group consisting of oils such as vegetable oil, neutral oil and mineral oil.

[0082] Preferred solid carrier materials, which may be a component of a preparation accord- ing to the invention are hydrocolloids, such as starches, degraded starches, chemically or physically modified starches, dextrins, (powdery) maltodextrins (preferably with a dextrose equivalent value of 5 to 25, preferably of 10 – 20), lactose, silicon dioxide, glucose, modified celluloses, gum arabic, ghatti gum, traganth, karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar flour, carob bean flour, alginates, agar, pectin and inulin and mixtures of two or more of these solids, in particular maltodextrins (preferably with a dextrose equiva- lent value of 15 – 20), lactose, silicon dioxide and / or glucose.

[0083] In addition, hydrotropes, for example ethanol, isopropyl alcohol or polyols, may be used to improve flow behaviour. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols may contain other functional groups, more especially amino groups, or may be modified with nitrogen. Typical examples are • glycerol; • alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene gly- col, butylene glycol, hexylene glycol and polyethylene glycols with an average molecu- lar weight of 100 to 1000 Dalton; • technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10, such as for example technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight; • methylol compounds such as, in particular, trimethylol ethane, trimethylol propane, trimethylol butane, pentaerythritol and dipentaerythritol; • lower alkyl glucosides, particularly those containing 1 to 8 carbon atoms in the alkyl group, for example methyl and butyl glucoside; • sugar alcohols containing 5 to 12 carbon atoms, for example sorbitol or mannitol, • sugars containing 5 to 12 carbon atoms, for example glucose or sucrose;• amino sugars, for example glucamine; • dialcoholamines, such as diethanolamine or 2-aminopropane-1,3-diol. Preservatives and / or product protection agents

[0084] Suitable preservatives are listed in Appendix 6, Parts A and B of the Kosmetikver- ordnung (“Cosmetics Directive”).

[0085] Suitable species can be selected from the group consisting of preservatives selected from the group consisting of benzoic acid and para-hydroxybenzoic acid, their esters and salts, benzyl benzoate, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, levulinic acid and its salts, anisic acid and its salts, perillic acid and its salts, cinnamic acid and its salts, formaldehyde and paraformaldehyde, 4-hydroxy benzaldehyde, ortho-, meta-, and para-anisic aldehyde, cinnamic aldehyde, cinnamic alcohol, 2-hydroxybiphenyl ether and its salts, 2-zinc-sulfidopyridine N-oxide, inorganic sulfites and bisulfites, sodium iodate, chlorobutanolum, 4-ethylmercury-(II)5-amino-1,3-bis(2- hydroxybenzoic acid), its salts and esters, dehydracetic acid, formic acid, 1,6-bis(4-amidino-2- bromophenoxy)-n-hexane and its salts, the sodium salt of ethylmercury-(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecylenic acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)- 5-methyl-hexahydropyrimidine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3- propanediol, 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N’-(3,4-dichlorophenyl)-urea, 4- chloro-m-cresol, 2,4,4’-trichloro-2’-hydroxy-diphenyl ether, 4-chloro-3,5-dimethylphenol, 1,1’-methylene-bis(3-(1-hydroxymethyl-2,4-dioximidazolidin-5-yl)urea), poly- (hexamethylenediguanide) hydrochloride, (Benzyloxymethoxy)-methanol hexamethylenetet- ramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azonia-adamantane chloride, 1-(4-chlorophenoxy)-1- (1H-imidazol-1-yl)-3,3-dimethyl-2-butanone, 1,3-bis-(hydroxymethyl)-5,5-dimethyl-2,4- imidazolidinedione, 1,2-dibromo-2,4-dicyanobutane, 2,2’-methylene-bis(6-bromo-4- chlorophenol), bromochlorophene, mixture of 5-chloro-2-methyl-3(2H)-isothiazolinone, 2- methyl-3(2H)-isothiazolinone and with magnesium chloride and magnesium nitrate, 2-Octyl- 2H-isothiazol-3-one, 1,2-benzisothiazol-3(2H)-one, 2-benzyl-4-chlorophenol, 3-(4- Chlorphenoxy)-1,2-propanediol (Chlorphenesin), 2-chloroacetamide, chlorhexidine, chlorhex- idine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, N-alkyl(C12-C22)trimethyl- ammonium bromide and chloride, 4,4-dimethyl-1,3-oxazolidine, N-hydroxymethyl-N-(1,3- di(hydroxymethyl)-2,5-dioxoimidazolidin-4-yl)-N’-hydroxy-methylurea, 1,6-bis(4-amidino- phenoxy)-n-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propanediol, hyamines, alkyl-(C8-C18)-dimethyl-benzyl-ammonium chloride, alkyl-(C8-C18)-dimethyl-benzylammonium bromide, alkyl-(C8-C18)-dimethyl-benzyl- ammonium saccharinate, benzyl hemiformal, 3-iodo-2-propynyl butylcarbamate, sodium hy- droxymethyl-aminoacetate or sodium hydroxymethyl-aminoacetate, imidazolidinylurea, dia- zolidinylurea, sodium hydroxymethylglycinate, DMDM hydantoin, Tropolone, (Eth- ylendioxy)dimethanol, 2-Brom-2-(brommethyl)pentandinitril, N-(3-Aminopropyl)-N-dodecylpropan-1,3-diamin, α,α‘,α“-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol, pyri- dine-2-thiol-1-oxide, sodium salt, Tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo[4,5- d]imidazol-2,5(1H,3H)-dion, 1,3-bis(hydroxymethyl) -1-(1,3,4-tris(hydroxy-methyl)-2,5- dioxoimidazolidin-4-yl)urea (Diazolidinyl Urea), 1,3-Bis(hydroxy-methyl)-5,5- dimethylimidazolidine-2,4-dione, 3-Acetyl-2-hydroxy-6-methyl-4H-pyran-4-one, cetyl pyridi- um chloride, caprylhydroxamic acid, sorbohydroxamic acid and their mixtures; 1,3- propanediol, methyl propanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2- decanediol, 1,5-pentanediol, 1,6-hexanediol, 1,8-octanediol, 1,2-decanediol, ethylhexylglycer- in, hexoxy-propan-1,2-diol, heptoxy- propan-1,2-diol, octoxy-propan-1,2-diol, 3-phenoxy- propan-1,2-diol, 3-benzyloxy-propan-1,2-diol, 3-phenylethyloxy-propan-1,2-diol, 3- phenylpropyloxy-propan-1,2-diol, 3-methylbenzyloxy-propan-1,2-diol, sorbitan caprylate, triclosan, climbazole, Octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)- pyridone, 2-aminoethanol), chitosan, farnesol, 2-butyloctanoic acid, 2-Benzylheptan-1-ol, glycerol monolaurate, bis(2-pyridylthio)zinc 1,1'-dioxide, N,N'-(decane-1,10-diyldipyridin-1- yl-4-ylidene)-dioctan-1-amine dihydrochloride (octenidine dihydrochloride), thymol, eugenol, benzyl alcohol, 2-phenyethyl alcohol, 3-phenyl propanol, 2-phenoxyethanol, 1-phenoxy- propan-2-ol, 3-phenoxypropanol, benzyloxymethanol, 4-hydroxyacetophenone and mixtures thereof. Fragrances and perfume oils Suitable fragrances and perfume oils can be selected from the group consisting of • alcohols, • aldehydes, • amines, amides, nitriles, • esters, • ethers, • ketones, • lactones • and mixtures thereof. In the following these groups are illustrated by various examples, distinguishing between fragrances or perfume oil which are known to the expert by their tradenames or their trivial names.Alcohols

[0086] Suitable alcohols known to the expert by their tradenames are provided in the follow- ing table: CAS IUPAC name Trade name 139504-68-0 1-(2-tert-butylcyclohexyl)oxybutan-2-ol Amber core 128-37-0 2,6-di-tert-butyl-p-cresol BHT Ionol (Z)-3-methyl-5-(2,2,3-trimethyl-1-cyclopent-3- 67801-20-1 enyl)pent-4-en-2-ol Ebanol 63500-71-0 4-methyl-2-(2-methylpropyl)oxan-4-ol Florosa / Pyranol [(1R,2S)-1-methyl-2-[[(1R,3S,5S)-1,2,2-trimethyl-3- 198404-98-7 bicyclo[3.1.0]hexanyl]methyl]cyclopropyl]methanol Javanol (3R)-1-[(1R,6S)-2,2,6-trimethylcyclohexyl]hexan-3-ol; 70788-30-6 (3S)-1-[(1R,6S)-2,2,6-trimethylcyclohexyl]hexan-3-ol Norlimbanol 55066-48-3 3-methyl-5-phenylpentan-1-ol Phenoxanol (E)-3,3-dimethyl-5-(2,2,3-trimethyl-3-cyclopenten-1- 107898-54-4 yl)-4-penten-2-ol Polysantol 25634-93-9 5-(3-methylphenyl)pentan-1-ol Rosaphen 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1- yl)pentan-2-ol Reaction products of (2,2,3-trimethylcyclopent-3- en-1-yl)acetaldehyde and butan-2-one, hydrogen- ated 1471313-03-7; 3-methyl-5-(2,2,3-trimethyl-1-cyclopent-3- 65113-99-7 enyl)pentan-2-ol Sandalore (2E)-2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)- 106185-75-5; buten-1-ol; 2-ethyl-4-(2,2,3-trimethyl-3- 28219-61-6 cyclopenten-1-yl)-2-buten-1-ol Sandranol 81782-77-6 (E)-4-methyldec-3-en-5-ol Undecavertol 3-[5,5,6-Trimethylbicyclo[2.2.1]hept-2-yl]cyclohexan- 70955-71-4 1-ol Sandela

[0087] Suitable alcohols known to the expert by their trivial names are provided in the fol- lowing table: CAS IUPAC name Trivial name 111-27-3 hexan-1-ol Alcohol C 6 111-87-5 octan-1-ol Alcohol C 8112-30-1 decan-1-ol Alcohol C10 112-53-8 dodecan-1-ol Alcohol C12 (1R,2S,4R)-1,7,7-Trimethyl- 464-43-7, bicyclo[2.2.1]heptan-2-ol, (1S,2R,4S)-1,7,7-Trimethyl- 464-45-9 bicyclo[2.2.1]heptan-2-ol Borneol (1S,2S,4S)-1,7,7-Trimethyl- bicyclo[2.2.1]heptan-2-ol, (1R,2R,4R)-1,7,7-Trimethyl- 16725-71-6, bicyclo[2.2.1]heptan-2-ol Isoborneol 106-22-9 3,7-dimethyloct-6-en-1-ol Citronellol 7540-51-4 (-)-3,7-dimethyloct-6-en-1-ol L-Citronellol 2785-87-7 2-methoxy-4-propylphenol Dihydro Eugenol 18479-58-8 2,6-dimethyloct-7-en-2-ol Dihydro Myrcenol 100-86-7 2-methyl-1-phenylpropan-2-ol Dimethyl Benzyl Carbinol 10339-55-6 3,7-dimethylnona-1,6-dien-3-ol Ethyl Linalool 97-53-0 2-methoxy-4-(prop-2-en-1-yl)phenol Eugenol 106-24-1 (2E)-3,7-dimethylocta-2,6-dien-1-ol Geraniol 928-96-1 (Z)-hex-3-en-1-ol Cis-3-Hexenol 3-[5,5,6-trimethylbicyclo[2.2.1]hept-2-yl]cyclohexan- 3407-42-9 1-ol Isobornyl Cyclohexanol 78-70-6 3,7-dimethylocta-1,6-dien-3-ol Linalool 7212-44-4 3,7,11-trimethyldodeca-1,6,10-trien-3-ol Nerolidol 60-12-8 2-phenylethanol Phenylethyl alcohol Phenylethyl Dimethyl Car- 103-05-9 2-methyl-4-phenylbutan-2-ol binol 122-97-4 3-phenylpropan-1-ol Phenylpropyl Alcohol 94-86-0 Propenyl Guaethol 137-00-8 2-(4-methyl-1,3-thiazol-5-yl)ethanol Sulfurol 98-55-5 p-menth-1-en-8-ol alpha-Terpineol 78-69-3 3,7-dimethyloctan-3-ol Tetrahydro Linalool 89-83-8 5-methyl-2-propan-2-ylphenol ThymolAldehydes

[0088] Suitable aldehydes known to the expert by their tradenames are provided in the fol- lowing table: CAS IUPAC name Trade name 141-13-9 2,6,10-trimethylundec-9-enal Adoxal; Farenal Cyclohexanemethanol, .alpha.,3,3-trimethyl-, 25225-08-5 formate Aphermate 18127-01-0 4-(1, 1-dimethylethyl)-Benzenepropanal Bourgeonal 929253-05-4 6-methoxy-2,6-dimethyloctanal Calypsone 5462-06-6 4-methoxy-.alpha.-methyl-Benzenepropanal Canthoxal 65405-84-7 α,2,2,6-Tetramethylcyclohexenebutanal Cetonal 8,8-dimethyl-1,2,3,4,5,6,7,8-octahydro-2- 68991-96-8; naphthaldehyde, 1,2,3,4,5,6,7,8-Octahydro- 68991-97-9 5,5-dimethyl-2-naphthalenecarboxaldehyde cyclomyral 4-(octahydro-4,7-methano-5H-inden-5- 30168-23-1 ylidene butanal Dupical 71077-31-1 4,8-Dimethyl-4,9-decadienal Floral Super 67634-15- 3-(4-ethylphenyl)-2,2-dimethylpropanal / 3- 5 / 67634-14-4 (2-ethylphenyl)-2,2-dimethylpropanal Florazon .beta.-methyl-3-(1-methylethyI)- 12509-85-5 Benzenepropanal Florhydral 91212-36-1 Cyclodecanecarboxaldehyde ethyl phenylglycidate 1205-17-0 Methylenedioxyphenyl-methylpropanal Helional 41496-43-9 α,4-Dimethylbenzenepropanal Jasmorange, Satinaldehyde 68039-49-6; (Z,E)-2,4-dimethyl cyclohex-3-ene-1- Ligustral, Tripalal, Cyclal C, 68737-61-1 carbaldehyde Vertocitral 80-54-6 3-(4-tert-butylphenyl)butanal Lilial 199445-85-7 (1R)-β,4-Dimethyl-3-cyclohexene-1-propanal Liminal (4R)-4-(1-Methylethyl)-1-cyclohexene-1- 1378867-81-2 propanal Lilybelle (4S)-4-(1-Methylethyl)-1-cyclohexene-1- 1378867-82-3 propanal Lilybelle Isomer 4-(4-Hydroxy-4-methyl-pentyl)-3-cyclohexen- 130066-44-3 1-carboxyaldehyde Lyral 6-methyl-1-8-yI-methyleth I-bicyclo[2.2.2]oct- 67845-30-1 5-ene-2-carboxaldehyde Maceal 106-72-9 (±)-2,6-Dimethyl-5-heptenal Melonal54082-68-7 (E)-2,6,10-trimethylundeca-5,9-dienal Oncidal 33885-51-7 6,6-Dimethyl-2-norpinene-2-propionaldehyde Pinoacet aldehyde 1-Methyl-4-(4-methyl-3-pentenyl)cyclohex-3- 119652-81-2; ene-1-carboxaldehyde, 6,6-Dimethyl-2- 52475-86-2 norpinene-2-propionaldehyde Precyclemone B 16251-77-7 3-Phenylbutanal Trifernal Octahydro-5-methoxy-4,7-methano-1H- 86803-90-9 indene-2-carboxaldehyde Scentenal rel-(3aR,4R,5R,7R,7aR)-Octahydro-4,7- 145374-28-3 methano-1H-indene-5-carboxaldehyde Vertral 4-(4-methyl pent-3-enyl) cyclohex-3-ene-1- 37677-14-8 carbaldehyde Vertomugal

[0089] Further on, aldehydes known to expert by their trivial name are provided in the following ta- ble: CAS IUPAC name Trivial name 123-11-5 4-Methoxybenzaldehyde Anisic Aldehyde 100-52-7 Benzaldehyde Benzaldehyde 5392-40-5 (E / Z)-3,7-Dimethylocta-2,6-dienal citral 106-23-0 3,7-dimethyl-6-0ctenal Citronellal 104-55-2 3-phenylprop-2-enal Cinnamaldehyde 122-03-2 4-(1-m ethylethyl)-Benzal dehyde Cuminic Aldehyde 103-95-7 2-methyl-3-(4-propan-2-ylphenyl)propanal cyclamen aldehyde 5988-91-0 3,7-dimethyl-Octanal Dihydrocitronellal 20407-84-5 (E)-2-Dodecenal trans-2-dodecanal 121-32-4 3-ethoxy-4-hydroxybenzaldehyde Ethyl Vanillin 141-27-5 trans-3,7-dimethylocta-2,6-dienal Geranial 120-57-0 1,3-Benzodioxole-5-carboxaldehyde Heliotropin / Piperonal 6728-26-3 trans-2-Hexenal trans-2-hexenal 101-86-0; 165184-98-5 2-Hexyl-3-phenyl-2-propenal Alpha-hexyl-cinnamic aldehyde 93-53-8 2-Phenylpropanal Hydratropic Aldehyde 107-75-5 3,7-dimethyl-7-hydroxyoctanal Hxdroxy Citronellal 2,4,6-trimeth 1-3-Cyclohexene-l- 1335-66-6 carboxaldehyde Isocyclocitral 3613-30-7 7-Methoxy-3,7-dimethyloctanal Methoxycitronellal106-26-3 (2Z)-3,7-dimethylocta-2,6-dienal Neral 122-78-1 Benzeneacetaldehyde Phenylacetaldehyde 21944-98-9 4-Dodecenal Tangerinal 2-methyl-3-(4-(2-methyl propyl)phenyl) pro- 6658-48-6 panal Cyclamen Homoaldehyde 121-33-5 4-hydroxy-3-methoxybenzaldehyde Vanillin Amines, amides, and nitriles

[0090] Suitable amines, amides and nitriles known to the expert by their tradenames or by their trivial names are provided in the following table: CAS IUPAC name Trade name 51566-62-2 3,7-dimethyloct-6-enenitrile Argunitril 53243-59-7; 53243-60-0; 93893-89-1 (E / Z)-3-methyl-5-phenylpent-2-enenitrile Citronitrile 61792-11-8 3,7-dimethylnona-2,6-dienenitrile Lemonile 38462-23-6 4-[(3E)-4,8-dimethylnona-3,7-dienyl]pyridine Maritima 22629-49-8 tridec-2-enenitrile Ozonil 10461-98-0 2-cyclohexylidene-2-phenylacetonitrile Peonile 120-72-9 1H-indoleIndoleEsters

[0091] Suitable esters known to the expert by their tradenames are presented in the follow- ing table: CAS IUPAC name Trade name 20298-69-5; 88- cis-2-tert-butylcyclohexyl acetate, (2-tert- Argumex HC / LC 41-5 butylcyclohexyl) acetate 77-83-8 ethyl 3-methyl-3-phenyloxirane-2-carboxylate Aldehyde C16 so-called 68901-15-5 prop-2-enyl 2-cyclohexyloxyacetate Cyclogalbanat 4707-47-5 methyl 2,4-dihydroxy-3,6-dimethylbenzoate Evernyl35206-51-0 4-methylpentan-2-yl (E)-but-2-enoate Frutinat 57934-97-1; ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1- Givescone 77851-07-1 carboxylate 24851-98-7 methyl 3-oxo-2-pentylcyclopentaneacetate Hedione 141773-73-1 2-(1-(3',3'-dimethyl-1'-cyclohexyl)ethoxy)-2- Helvetolide methyl propyl propanoate 5413-60-5 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl Herbalflorat acetate 67633-96-9 [(Z)-hex-3-enyl] methyl carbonate Leafovert 39255-32-8 ethyl 2-methylpentanoate Manzanate 236391-76-7 2-[1-(3,3-Dimethylcyclohexyl)ethoxy]-2- Romandolide oxoethyl propionate 15848-49-4 ethyl 2-cyclopent-2-en-1-ylacetate Sultanene 29066-34-0; 89- (1S,2R,5S)-5-methyl-2-(1-methylethyl)- Symfresh RF / Menthylacetate 48-5 cyclohexanolacetate + [(1R,2S,5R)-5-methyl-2- propan-2-ylcyclohexyl]-acetate 25265-77-4 3-hydroxy-2,2,4-trimethylpentyl 2- Symfresh NX methylpropanoate 68083-58-9 (4-methyl-4-phenylpentan-2-yl)-acetate Vertikolacetat

[0092] Suitable esters known to the expert by their trivial names encompass are provided in the following table: CAS IUPAC name Trivial name 67634-00-8 prop-2-enyl 2-(3-methylbutoxy)acetate Allyl Amyl Glycolate 123-68-2 prop-2-enyl hexanoate Allyl Caproate 2705-87-5 prop-2-enyl 3-cyclohexylpropanoate Allyl Cyclohexyl Propionate 142-19-8 prop-2-enyl heptanoate Allyl Heptoate 140-11-4 benzyl acetate Benzyl Acetate 118-58-1 benzyl 2-hydroxybenzoate Benzyl Salicylate150-84-5 3,7-dimethyloct-6-enyl acetate Citronellyl Acetate Dimethyl Benzyl Carbinyl Ace- 151-05-3 (2-methyl-1-phenylpropan-2-yl) acetate tate Dimethyl Benzyl Carbinyl Butyr- 10094-34-5 (1-cyclohexyl-2-methylpropan-2-yl) butanoate ate 105-54-4 ethyl butanoate Ethyl Butyrate 123-66-0 ethyl hexanoate Ethyl Caproate Trans / Cis-2,4-Ethyl Decadieno- 3025-30-7 ethyl (2E,4Z)-deca-2,4-dienoate ate 7452-79-1 ethyl 2-methylbutanoate Ethyl-2-Methyl Butyrate 105-95-3 1,4-dioxacycloheptadecane-5,17-dione Ethylene Brassylate 105-87-3 trans-3,7-dimethyl-2,6-octadien-1-yl ethanoate Geranyl Acetate 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden- 17511-60-3; 5-yl propionate, 3a,4,5,6,7,7a-hexahydro-1H- 68912-13-0 4,7-methanoinden-6-yl propionate Herbyl Propionate 1708-82-3 (3)-hex-3-en-1-yl acetate Cis / Trans-3-Hexenyl Acetate 3681-71-8 (Z)-hex-3-enyl acetate Cis-3 Hexenyl Acetate 16491-36-4 [(Z)-hex-3-enyl] butanoate Cis-3 Hexenyl Butyrate 41519-23-7 [(Z)-hex-3-enyl] 2-methylpropanoate Cis-3-Hexenyl Isobutyrate 65405-77-8 [(Z)-hex-3-enyl] 2-hydroxybenzoate Cis-3-Hexenyl Salicylate 142-92-7 hexyl acetate Hexyl Acetate 2639-63-6 hexyl butanoate Hexyl Butyrate 2349-07-7 hexyl 2-methylpropanoate Hexyl Isobutyrate 6259-76-3 hexyl 2-hydroxybenzoate Hexyl Salicylate 123-92-2 3-methylbutyl acetate Isoamyl Acetate [(1R,4S,6R)-1,7,7-trimethyl-6- 125-12-2 bicyclo[2.2.1]heptanyl] acetate Isobornyl Acetate 110-19-0 2-methylpropyl acetate Isobutyl Acetate 5912-87-8; 93- (E)-2-Methoxy-4-prop-1-en-1-ylphenyl acetate; 29-8 (2-methoxy-4-prop-1-enylphenyl) acetate Isoeugenyl Acetate 115-95-7 3,7-dimethylocta-1,6-dien-3-yl acetate Linalyl Acetate 111-80-8 methyl non-2-ynoate Methyl Octin Carbonate141-12-8 [(2Z)-3,7-dimethylocta-2,6-dienyl] acetate Neryl Acetate 103-52-6 2-phenylethyl butanoate Phenylethyl Butyrate 103-53-7 2-phenylethyl (E)-3-phenylprop-2-enoate Phenylethyl Cinnamate 1191-16-8 3-methylbut-2-enyl acetate Prenyl Acetate 93-92-5 1-phenylethyl acetate Styralyl Acetate 85-91-6 methyl 2-methylaminobenzoate Methylanthranilat Ethers

[0093] Suitable ethers known to the expert by their tradenames are provided in the following table: CAS IUPAC Name Trade name (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyl- 2,4,5,5a,7,8,9,9b-octahydro-1H- 6790-58-5 benzo[e][1]benzofuran Ambroxide 67663-01-8 5-hexyl-4-methyloxolan-2-one Aprifloren 2550-59-6; 3100- 36-5; 88642-03-9 cyclohexadec-2-en-1-one Aurelione 68845-36-3 3,4-diethyl-2,5-dimethylcyclohex-2-en-1-one Azarbre 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8- 1222-05-5 hexamethylcyclopenta(g)-2-benzopyran Galaxolide 59323-76-1, 261- (2R,4S)-2-methyl-4-propyl-1,3-oxathiane; 2- 699-8 methyl-4-propyl-1,3-oxathiane Oxane / Oxanthia 3,7'-Dimethyl-3,4,4a,5,8,8a-hexahydrospiro-(1,4- 41816-03-9 methanonaphthalene- 2(1H),2'-oxirane) Rhubofix

[0094] Suitable ethers known to the expert by their trivial names are provided in the following table: CAS IUPAC Name Trivial name 4180-23-8 1-methoxy-4-[prop-1-enyl]benzene Anethol 73018-51-6 3,7-dimethyl-1,6-octadien-3-ol, acid-isomerized Lime Oxide93-04-9 2-methoxynaphthalene Nerolin Yara Yara 14576-08-0 4-(2-methoxypropan-2-yl)-1-methylcyclohexene Orange Flower Ether Ketones

[0095] Suitable ketones known to the expert by their tradenames are provided in the follow- ing table: CAS IUPAC Name Trade name 7-methyl-3,4-dihydro-2H-1,5-benzodioxepin-3- 249-320-4 one Calone 1,2,3,5,6,7-hexahydro-1,1,2,3,3-pentamethyl-4H- 251-649-3 inden-4-one Cashmeran [3R-(3α,3aβ,6α,7β,8aα)]-octahydro-6-methoxy- 3,6,8,8-tetramethyl-1H-3a,7-methanoazulene; 19870-74-7; (3R,3aS,6R,7R,8aS)-octahydro-6-methoxy-3,6,8,8- 67874-81-1 tetramethyl-1H-3a,7-methanoazulene Cedramber 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro- 3738-00-9 1H-benzo[e][1]benzofuran Cetalox 56973-85-4 1-(5,5-dimethyl-1-cyclohexenyl)pent-4-en-1-one Dynascone, Galbascone 102322-83-8; 1-[bis(2-hydroxypropyl)amino]propan-2-ol; 5- 81925-81-7 methylhept-2-en-4-one Filbertone 5471-51-2 4-(4-hydroxyphenyl)butan-2-one Frambinon 3100-36-5 (8E)-cyclohexadec-8-en-1-one Globanone 4-(2,5,6,6-tetramethylcyclohex-2-enyl)but-3-en- 201-219-6 2-one Alpha Irone 1-(2,3,8,8-tetramethyl-1,3,4,5,6,7- 54464-57-2 hexahydronaphthalen-2-yl)ethanone Iso E Super 2550-52-9 cyclohexadecanone Isomuscone 5,5,9,13-tetramethyl-14,16- 57345-19-4 dioxatetracyclo[11.2.1.01,10.04,9]hexadecane Ketamber 7011-83-8 5-hexyl-5-methyloxolan-2-one Lactojasmone (E)-3-methyl-4-(2,6,6-trimethyl-1-cyclohex-2- 127-51-5 enyl)but-3-en-2-one Methyl Ionone Gamma Coeur N-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1- 1335-46-2 en-3-one Methyl Ionone Gamma Pure 63314-79-4; (5E)-3-methylcyclopentadec-5-en-1-one; (5E)-3- 82356-51-2 methylcyclopentadec-5-en-1-one Muscenone541-91-3 3-methylcyclopentadecan-1-one Muscone 2-[2-(4-methyl-1-cyclohex-3- 95962-14-4 enyl)propyl]cyclopentan-1-one Nectaryl 23911-56-0 1-(3-methyl-1-benzofuran-2-yl)ethan-1-one Nerolione octahydro-7-methyl-1,4-methanonaphthalen- 41724-19-0 6(2H)-one Plicatone 1-(3,5,5,6,8,8-hexamethyl-6,7-dihydronaphthalen- 1506-02-1; 2-yl)ethanone; 1-(3,5,5,6,8,8-hexamethyl-6,7- 21145-77-7 dihydronaphthalen-2-yl)ethanone Tonalide 65443-14-3 2,2,5-trimethyl-5-pentylcyclopentan-1-one Veloutone

[0096] Suitable ketones known to the expert by their trivial names are provided in the follow- ing table: CAS IUPAC Name Trivial name (E)-1-(2,6,6-trimethyl-1-cyclohexa-1,3-dienyl)but- 23696-85-7; 2-en-1-one; (E)-1-(2,6,6-trimethyl-1-cyclohexa- 23726-93-4 1,3-dienyl)but-2-en-1-one Damascenone (E)-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-2- 24720-09-0 en-1-one Alpha Damascone (E)-1-(2,6,6-trimethyl-1-cyclohexenyl)but-2-en-1- 23726-91-2; one; 1-(2,6,6-trimethyl-1-cyclohexenyl)but-2-en- 35044-68-9 1-one Beta Damascone 1-(2,6,6-trimethyl-1-cyclohex-3-enyl)but-2-en-1- 57378-68-4; one; [1α(E),2β]-1-(2,6,6-trimethylcyclohex-3-en-1- 71048-82-3 yl)but-2-en-1-one Delta Damascone 17283-81-7 4-(2,6,6-trimethyl-1-cyclohexenyl)butan-2-one Beta Dihydro Ionone 1128-08-1 3-methyl-2-pentylcyclopent-2-en-1-one Dihydro Jasmone .4940-11-8 2-ethyl-3-hydroxypyran-4-one Ethyl Maltol 695-06-7 5-ethyloxolan-2-one Gamma Hexalactone (E)-4-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-3- 127-41-3 en-2-one Alpha Ionone 79-77-6, 14901- (E)-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3- 07-6 buten-2-one Beta Ionone 25524-95-2 6-[(Z)-pent-2-enyl]oxan-2-one Jasmin Lactone 32764-98-0 6-(pent-3-en-1-yl)tetrahydro-2H-pyran-2-one Jasmolactone CNC 3-methyl-2-[(Z)-pent-2-enyl]cyclopent-2-en-1- 488-10-8 one Jasmone Cis 118-71-8 3-hydroxy-2-methylpyran-4-one MaltolN-1-(2,6,6-trimethyl-1-cyclohex-2-enyl)pent-1- 1335-46-2 en-3-one Methyl Ionone Lactones

[0097] Suitable lactones known to expert by their tradenames are provided in the following table: CAS IUPAC Name Trade name 104-67-6 5-heptyloxolan-2-one Aldehyde C14 So-Called 203-219-1 5-pentyloxolan-2-one Aldehyde C18 So-Called 28645-51-4 (9Z)-17-oxacycloheptadec-9-en-1-one Ambrettolide 111879-80-2; (12E)-1-oxacyclohexadec-12-en-2-one; (3E)- 34902-57-3 oxacyclohexadec-3-en-2-one Globalide 106-02-5 16-oxacyclohexadecan-1-one Supra Macrolide

[0098] Further on, lactones known to expert by their trivial name are compiled in the follow- ing table: CAS IUPAC Name Trivial name 705-86-2 6-pentyloxan-2-one Delta Decalactone 706-14-9 5-hexyloxolan-2-one Gamma Decalactone 104-50-7 5-butyloxolan-2-one Gamma Octalactone 16409-43-1 4-methyl-2-(2-methylprop-1-enyl)oxane Rose Oxide High Cis Etherical oils and extracts

[0099] Suitable fragrances and perfume oils are provided in the following table: CAS Name 8015-62-1; 84455-19-6 Ambrette Seed Absolue 8015-65-4; 90320-49-3 Amyris Oil 8015-64-3; 84775-41-7 Angelica Root Oil 68650-44-2; 72869-69-3 Apricot Seed Oil8022-37-5; 84775-75-7; 68991-20-8 Artemisia Oil 8015-73-4; 84775-71-3 Basil Oil 8006-78-8; 85085-61-6 Bay Oil 8012-89-3 Beeswax Abs 9000-05-9; 9000-72-0 Benzoin Resinoid 8007-75-8; 89957-91-5; 68648-33-9 Bergamot Oil 958663-49-5 Boya 68188-03-4; 91722-93-9 Cabreuva Oil 8013-10-3; 90046-02-9 Cade Oil 68606-83-7; 93686-30-7 Cananga Oil Java 8000-42-8; 85940-31-4 Caraway Oil 8000-66-6; 85940-32-5 Cardamom Abs. / Oil 8015-88-1; 84929-61-3 Carrot Seed Oil 8007-80-5; 84961-46-6 Cassia Oil 8023-82-3; 89958-31-6 Cassie Abs. A Egypt 68606-81-5; 97676-19-2 Cassis Abs. Burgundy 8023-83-4; 92704-04-6 Castroreum Abs. 8007-20-3; 90131-58-1 Cedar Leaf Oil 68990-83-0; 91722-61-1 Cedarwood Oil 8000-27-9; 85085-29-6; 85085-41-2 Cedarwood Oil 8023-85-6; 92201-55-3 Cedarwood Oil Atlas 8015-90-5; 89997-35-3 Celery Seed Oil 8002-66-2; 84082-60-0 Chamomile Oil Blue 8015-92-7; 84649-86-5 Chamomile Oil Roman 8015-91-6; 84649-98-9 Cinnamon Bark Oil 8015-91-6; 84649-98-9 Cinnamon Leaf Oil 8016-26-0; 89997-74-0 Cistus Labdanum Abs.SIS 8016-26-0; 89997-74-0 Cistus Oil 8000-29-1; 91771-61-8 Citronella Oil Formosa / Java 8016-63-5; 84775-83-7 Clary Sage Oil 8000-34-8; 84961-50-2; 97-53-0 Clove Bud Oil 8000-34-8; 84961-50-2; 97-53-0 Clove Leaf Oil 8001-31-8 Coconut Oil 8001-61-4 Copaiba Balsam Oil8008-52-4; 84775-50-8 Coriander Oil 8014-13-9; 84775-51-9 Cumin Oil 8013-86-3; 84696-07-1 Cypress Oil 68916-60-9; 91771-62-9 Cypriol Oil 8016-03-3; 91844-86-9 Davana Oil 8006-75-5; 90028-03-8 Dill Weed Oil 8016-26-0; 89997-74-0 Dynamone 8023-89-0; 9000-75-3 Elemi Oil / Gum 8016-88-4; 90131-45-6 Estragon Oil 8000-48-4; 85203-56-1 Eucalyptus Oil Citriodora 8006-84-6; 84455-29-8 Fennel Oil Sweet 8007-47-4 Fir Balsam Abs. 68917-51-1; 84696-13-9 Fucus Abs. 8023-91-4; 93165-40-3 Galbanum Oil 8000-46-2; 90082-51-2 Geranium Oil 8007-08-7; 84696-15-1 Ginger Extract / Oil 8016-20-4; 90045-43-5 Grapefriut Oil White 8016-23-7; 89958-10-1 Guaiac Wood Oil 8030-55-5 Gurjun Balsam Oil 8031-00-3; 92128-62-6 Hay Abs 8016-26-0; 89997-74-0 Hydrocarboresin B 8023-95-8; 90045-56-0 Immortelle Abs. 8022-96-6; 90045-94-6 Jasmin Abs. 1034798-23-6; 91770-14-8 Jasmin Abs. Sambac 8002-68-4; 84603-69-0 Juniper Berry Oil R.S 8016-26-0; 89997-74-0 Labdanum Abs. / Resinoide 8002-41-3; 84603-73-6 Laurel Noble Leaf Oil FLS 8022-15-9; 91722-69-9 Lavandin Oil 8000-28-0; 90063-37-9 Lavender Oil White 8008-56-8; 84929-31-7 Lemon Oil 68917-33-9; 84929-31-7 Lemon Oil Terpenes 8008-56-8; 84929-31-7 Lemon Oil Winter 8007-02-1; 91844-92-7 Lemongrass Oil 61789-92-2; 68991-39-9; 90082-82-9 Lentisque Abs.8008-26-2; 90063-52-8 Lime Oil 68917-71-5; 90063-52-8 Lime Oil Terpenes 68855-99-2; 90063-59-5 Litsea Cubeba Oil 97952-46-0 Longoza Oil 8016-31-7; 84837-06-9 Lovage Root Oil 8008-45-5; 84082-68-8 Mace Oil Dist. Low Safrol 8007-12-3; 84082-68-8 Mace Oil 8006-76-6; 92457-18-6 Magnolia Flower Oil 8006-76-6; 92457-18-6 Magnolia Leaf Oil 8008-31-9; 84929-38-4 Mandarin Oil 8015-01-8; 84082-58-6 Marjoram Oil 68917-18-0; 90063-97-1 Mentha Arv. Oil 8031-03-6; 93685-96-2; 98903-76-5 Mimosa Abs. 9000-50-4; 90028-68-5 Mousse C Abs. 8016-37-3; 84929-26-0 Myrrh Oil 8008-46-6; 84082-67-7 Myrtle Oil 68917-12-4; 90064-26-9 Narcisse Abs. 72968-50-4; 8016-38-4 Neroli Oil 8008-45-5; 84082-68-8 Nutmeg Oil 8016-36-2; 8050-07-5 Olibanum Oil 100084-96-6; 8021-36-1 Opoponax Oil / Resinoid 68916-04-1; 72968-50-4 Orange Flower Abs. 8008-57-9; 8028-48-6; 68916-04-1; 72968-50-4 Orange Oil 336185-21-8; 84012-24-8 Origanum Oil 68917-05-5; 92347-21-2 Osmanthus Abs. 8014-19-5; 84649-81-0 Palmarosa Oil 8000-68-8; 84012-33-9 Parsley Leaf Oil 8000-68-8; 84012-33-9 Parsley Seed Oil 8014-09-3; 84238-39-1 Patchouli Oil 8006-82-4; 84929-41-9 Pepper Black Oil 102242-62-6; 97404-53-0 Pepper Oil / Abs. Sichuan Type 8006-90-4; 84082-70-2 Peppermint Oil 8007-00-9 Peru Balsam Oil 72968-50-4; 8014-17-3 Petitgrain Bigaeade Abs.8048-51-9; 84929-31-7 Petitgrain Oil Citronnier 8006-77-7; 84929-57-7 Pimento Leaf Oil 8023-99-2; 84012-35-1 Pine Needle Abs. 8021-29-2; 91697-89-1; 8021-28-1; 85085-34-3 Pine Needle Oil 1175539-64-6; 949495-68-5 Pink Pepper Leaf Oil 949495-68-5 Red Berry Extract 68917-52-2; 94334-31-3 Red Berry Oil 8007-01-0; 90106-38-0; 97660-07-6; 84604-12-6 Rose Abs. 8000-25-7; 84604-14-8 Rosemary Oil 91770-72-8; 943609-24-3 Rum CO2 Extract 8022-56-8; 84082-79-1 Sage Officinale Oil Dalm 8024-35-9; 92875-02-0; 1070895-66-7; 91845-48-6; 8006-87-9; 84787-70-2 Sandalwood Oil 8008-79-5; 84696-51-5 Spearmint Oil 8016-78-2; 84837-04-7 Spike Oil 68952-43-2; 84650-59-9 Star Anise Oil 8046-19-3; 94891-28-8 Styrax Oil 8007-69-0; 90320-37-9 Sweet Almond Oil 8016-84-0; 91770-75-1 Tagetes Oil 8016-85-1; 93686-22-7 Tangerine Cravo Oil Brazil 68647-73-4; 85085-48-9 Tea Tree Oil 8007-20-3; 91770-83-1 Thuja Oil 8007-46-3; 85085-75-2 Thyme Oil 102242-62-6; 91770-90-0 Timut Pepper Oil 8024-04-2; 90028-06-1 Tonka Bean Abs. 8024-05-3; 94334-35-7 Tuberose Abs. 8024-37-1; 84775-52-0 Tumeric Oil 8006-64-2 Turpentine Oil 8024-06-4; 84650-63-5 Vanilla Abs 8016-96-4; 84238-29-9 Vetiver Oil / Abs 8024-08-6; 90147-36-7 Violet Leaves Abs. 68916-76-7; 84012-44-2 Wheat Bran Abs. 8008-93-3; 84929-19-1 Wormwood Oil 8006-81-3; 83863-30-3 Ylang Ylang OilDyes

[0100] Suitable dyes are any of the substances suitable and approved for cosmetic purpos- es as listed, for example, in the publication “Kosmetische Färbemittel” of the Farbstoff- kommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, pages 81 to 106. Examples include cochineal red A (C.I. 16255), patent blue V (C.I. 42051), indigotin (C.I. 73015), chlorophyllin (C.I. 75810), quinoline yellow (C.I. 47005), titanium dioxide (C.I. 77891), indanthrene blue RS (C.I. 69800) and madder lake (C.I. 58000). Luminol may also be present as a luminescent dye. Advantageous coloured pigments are for example titanium dioxide, mica, iron oxides (e.g. Fe2O3 Fe3O4, FeO(OH)) and / or tin oxide. Advantageous dyes are for example carmine, Berlin blue, chromium oxide green, ultramarine blue and / or manga- nese violet. Preparations

[0101] Preferred compositions according to the present inventions are selected from the group of products for treatment, protecting, care and cleansing of the skin and / or hair or as a make-up product, preferably as a leave-on product (meaning that the one or more com- pounds stay on the skin and / or hair for a longer period of time, compared to rinse-off prod- ucts).

[0102] The formulations according to the invention are preferably in the form of an emul- sion, e.g. W / O (water-in-oil), O / W (oil-in-water), W / O / W (water-in-oil-in-water), O / W / O (oil- in-water-in-oil) emulsion, PIT emulsion, Pickering emulsion, emulsion with a low oil content, micro- or nanoemulsion, a solution, e.g. in oil (fatty oils or fatty acid esters, in particular C6- C32fatty acid C2-C30esters) or silicone oil, dispersion, suspension, creme, lotion or milk, de- pending on the production method and ingredients, a gel (including hydrogel, hydrodisper- sion gel, oleogel), spray (e.g. pump spray or spray with propellant) or a foam or an impreg- nating solution for cosmetic wipes, a detergent, e.g. soap, synthetic detergent, liquid wash- ing, shower and bath preparation, bath product (capsule, oil, tablet, salt, bath salt, soap, etc.), effervescent preparation, a skin care product such as e.g. an emulsion (as described above), ointment, paste, gel (as described above), oil, balsam, serum, powder (e.g. face powder, body powder), eau de perfume, eau de toilette, after-shave, a mask, a pencil, stick, roll-on, pump, aerosol (foaming, non-foaming or post-foaming), a deodorant and / or antiperspirant, mouth- wash and mouth rinse, a foot care product (including keratolytic, deodorant), an insect repel- lent, a sunscreen, aftersun preparation, a shaving product, aftershave balm, pre- and after- shave lotion, a depilatory agent, a hair care product such as e.g. shampoo (including 2-in-1 shampoo, anti-dandruff shampoo, baby shampoo, shampoo for dry scalps, concentrated shampoo), conditioner, hair tonic, hair water, hair rinse, styling creme, pomade, perm and setting lotion, hair spray, styling aid (e.g. gel or wax), hair smoothing agent (detangling agent, relaxer), hair dye such as e.g. temporary direct-dyeing hair dye, semi-permanent hair dye,permanent hair dye, hair conditioner, hair mousse, eye care product, make-up, make-up re- mover or baby product.

[0103] Auxiliary substances and additives can be included in quantities of 5 to 99 % b.w., preferably 10 to 80 % b.w., based on the total weight of the formulation. The amounts of cosmetic or dermatological auxiliary agents and additives and perfume to be used in each case can easily be determined by the person skilled in the art by simple trial and error, de- pending on the nature of the particular product.

[0104] The preparations can also contain water in a quantity of up to 99 wt.-percent., pref- erably from about 5 to about 80 wt.-percent and more preferably either from about 10 to about 50 or from about 60 to about 80 wt.-percent based on the total weight of the prepara- tion. FOOD COMPOSITIONS

[0105] Another object of the present invention refers to food compositions, preferably chewing gums, candies and beverages, comprising the modulators or blends of modulators as defined above in a working amount, for example about 0.001 to about 1 % b.w., preferably about 0.01 to about 0.5 % b.w. and particularly from about 0.1 to about 2 % b.w. – calculated on the composition(s).

[0106] Food compositions according to the invention are any preparations or compositions comprising the compositions according to the invention which are suitable for consumption and are used for nutrition or enjoyment purposes, and are generally products which are in- tended to be introduced into the human or animal oral cavity, to remain there for a certain time and then either be eaten (e.g. ready-to-eat foodstuffs or feeds, see also herein below) or removed from the oral cavity again (e.g. chewing gums). Such products include any sub- stances or products which in the processed, partially processed or unprocessed state are to be ingested by humans or animals. They also include substances which are added to orally consumable products during their manufacture, preparation or treatment and which are in- tended to be introduced into the human or animal oral cavity.

[0107] The food compositions according to the invention also include substances which in the unchanged, treated or prepared state are to be swallowed by a human or animal and then digested; in this respect, the orally consumable products according to the invention also include casings, coatings or other encapsulations which are to be swallowed at the same time or which may be expected to be swallowed. The expression "orally consumable product" co- vers ready-to-eat foodstuffs and feeds, that is to say foodstuffs or feeds that are already complete in terms of the substances that are important for the taste. The expressions "ready- to-eat foodstuff" and "ready-to-eat feed" also include drinks as well as solid or semi-solid ready-to-eat foodstuffs or feeds. Examples which may be mentioned are frozen products, which must be thawed and heated to eating temperature before they are eaten. Productssuch as yoghurt or ice-cream as well as chewing gums or hard caramels are also included among the ready-to-eat foodstuffs or feeds.

[0108] Preferred food compositions according to the invention also include “semi-finished products”. Within the context of the present text, a semi-finished product is to be understood as being an orally consumable product which, because of a very high content of flavourings and taste-imparting substances, is unsuitable for use as a ready-to-eat orally consumable product (in particular foodstuff or feed). Only by mixing with at least one further constituent (e.g. by reducing the concentration of the flavourings and taste-imparting substances in question) and optionally further process steps (e.g. heating, freezing) is the semi-finished product converted into a ready-to-eat orally consumable product (in particular foodstuff or feed). Examples of semi-finished products which may be mentioned here are

[0109] Food composition according to the invention preferably comprises one or more preparations for nutrition or enjoyment purposes. These include in particular (reduced- calorie) baked goods (e.g. bread, dry biscuits, cakes, other baked articles), confectionery (e.g. chocolates, chocolate bars, other products in bar form, fruit gums, dragées, hard and soft caramels, chewing gum), non-alcoholic drinks (e.g. cocoa, coffee, green tea, black tea, (green, black) tea drinks enriched with (green, black) tea extracts, rooibos tea, other herbal teas, fruit- containing soft drinks, isotonic drinks, refreshing drinks, nectars, fruit and vegetable juices, fruit or vegetable juice preparations), instant drinks (e.g. instant cocoa drinks, instant tea drinks, instant coffee drinks), meat products (e.g. ham, fresh sausage or raw sausage prepara- tions, spiced or marinated fresh or salt meat products), eggs or egg products (dried egg, egg white, egg yolk), cereal products (e.g. breakfast cereals, muesli bars, precooked ready-to-eat rice products), dairy products (e.g. full-fat or reduced-fat or fat-free milk drinks, rice pudding, yoghurt, kefir, cream cheese, soft cheese, hard cheese, dried milk powder, whey, butter, but- termilk, partially or completely hydrolysed milk-protein-containing products), products made from soy protein or other soybean fractions (e.g. soy milk and products produced therefrom, drinks containing isolated or enzymatically treated soy protein, drinks containing soy flour, preparations containing soy lecithin, fermented products such as tofu or tempeh or products produced therefrom and mixtures with fruit preparations and optionally flavours), fruit prepa- rations (e.g. jams, sorbets, fruit sauces, fruit fillings), vegetable preparations (e.g. ketchup, sauces, dried vegetables, frozen vegetables, precooked vegetables, boiled-down vegetables), snacks (e.g. baked or fried potato crisps or potato dough products, maize- or groundnut- based extrudates), fat- and oil-based products or emulsions thereof (e.g. mayonnaise, re- moulade, dressings, in each case full-fat or reduced-fat), other ready-made dishes and soups (e.g. dried soups, instant soups, precooked soups), spices, spice mixtures and in particular seasonings which are used, for example, in the snacks field, sweetener preparations, tablets or sachets, other preparations for sweetening or whitening drinks or other foods. The prepa- rations within the scope of the invention can also be used in the form of semi-finished prod- ucts for the production of further preparations for nutrition or enjoyment purposes. The preparations within the scope of the invention can also be in the form of capsules, tablets(uncoated and coated tablets, e.g. enteric coatings), dragées, granules, pellets, solids mix- tures, dispersions in liquid phases, in the form of emulsions, in the form of powders, in the form of solutions, in the form of pastes, or in the form of other preparations which can be swallowed or chewed, and in the form of food supplements.

[0110] The preparations can also be in the form of capsules, tablets (uncoated and coated tablets, e.g. enteric coatings), dragées, granules, pellets, solids mixtures, dispersions in liquid phases, in the form of emulsions, in the form of powders, in the form of solutions, in the form of pastes, or in the form of other preparations which can be swallowed or chewed, for exam- ple in the form of food supplements.

[0111] The semi-finished products are generally used for the production of ready-to-use or ready-to-eat preparations for nutrition or enjoyment purposes.

[0112] Further constituents of a ready-to-eat preparation or semi-finished product for nu- trition or enjoyment purposes can be conventional base substances, auxiliary substances and additives for foods or enjoyment foods, for example water, mixtures of fresh or processed, vegetable or animal base or raw substances (e.g. raw, roast, dried, fermented, smoked and / or boiled meat, bone, cartilage, fish, vegetables, herbs, nuts, vegetable juices, vegetable pastes or mixtures thereof), digestible or non-digestible carbohydrates (e.g. sucrose, maltose, fruc- tose, glucose, dextrins, amylose, amylopectin, inulin, xylans, cellulose, tagatose), sugar alco- hols (e.g. sorbitol, erythritol), natural or hardened fats (e.g. tallow, lard, palm fat, cocoa fat, hardened vegetable fat), oils (e.g. sunflower oil, groundnut oil, maize germ oil, olive oil, fish oil, soya oil, sesame oil), fatty acids or their salts (e.g. potassium stearate), proteinogenic or non-proteinogenic amino acids and related compounds (e.g. ^-aminobutyric acid, taurine), peptides (e.g. glutathione), natural or processed proteins (e.g. gelatin), enzymes (e.g. pepti- dases), nucleic acids, nucleotides, taste correctors for unpleasant taste impressions, further taste modulators for further, generally not unpleasant taste impressions, other taste- modulating substances (e.g. inositol phosphate, nucleotides such as guanosine monophos- phate, adenosine monophosphate or other substances such as sodium glutamate or 2- phenoxypropionic acid), emulsifiers (e.g. lecithins, diacylglycerols, gum arabic), stabilisers (e.g. carrageenan, alginate), preservatives (e.g. benzoic acid and its salts, sorbic acid and its salts), antioxidants (e.g. tocopherol, ascorbic acid), chelators (e.g. citric acid), organic or inorganic acidifying agents (e.g. acetic acid, phosphoric acid), additional bitter substances (e.g. quinine, caffeine, limonene, amarogentine, humulone, lupulone, catechols, tannins), substances that prevent enzymatic browning (e.g. sulfite, ascorbic acid), ethereal oils, plant extracts, natural or synthetic colourings or colouring pigments (e.g. carotinoids, flavonoids, anthocyans, chloro- phyll and derivatives thereof), spices, trigeminally active substances or plant extracts contain- ing such trigeminally active substances, synthetic, natural or nature-identical flavourings or odorants as well as odour correctors.

[0113] Food compositions according to the invention, for example those in the form of preparations or semi-finished products, preferably comprise a flavour composition in order tocomplete and refine the taste and / or odour. A preparation can comprise as constituents a solid carrier and a flavour composition. Suitable flavour compositions comprise, for example, synthetic, natural or nature-identical flavourings, odorants and taste-imparting substances, reaction flavourings, smoke flavourings or other flavour-giving preparations (e.g. protein (partial) hydrolysates, preferably protein (partial) hydrolysates having a high arginine content, barbecue flavourings, plant extracts, spices, spice preparations, vegetables and / or vegetable preparations) as well as suitable auxiliary substances and carriers. Particularly suitable here are the flavour compositions or constituents thereof which produce a roasted, meaty (in par- ticular chicken, fish, seafood, beef, pork, lamb, mutton, goat), vegetable-like (in particular tomato, onion, garlic, celery, leek, mushroom, aubergine, seaweed), spicy (in particular black and white pepper, cardamom, nutmeg, pimento, mustard and mustard products), fried, yeast-like, boiled, fatty, salty and / or pungent flavour impression and accordingly can enhance the spicy impression. The flavour compositions generally comprise more than one of the mentioned ingredients.

[0114] The food compositions of the present invention are preferably selected from the group comprising • confectionery, preferably reduced-calorie or calorie-free confectionery, preferably se- lected from the group comprising muesli bar products, fruit gums, dragées, hard cara- mels and chewing gum, • non-alcoholic drinks, preferably selected from the group comprising green tea, black tea, (green, black) tea drinks enriched with (green, black) tea extracts, rooibos tea, other herbal teas, fruit-containing low-sugar or sugar-free soft drinks, isotonic drinks, nectars, fruit and vegetable juices, fruit and vegetable juice preparations, • instant drinks, preferably selected from the group comprising instant (green, black, rooibos, herbal) tea drinks, • cereal products, preferably selected from the group comprising low-sugar and sugar- free breakfast cereals and muesli bars, • dairy products, preferably selected from the group comprising reduced-fat and fat-free milk drinks, yoghurt, kefir, whey, buttermilk and ice-cream, • products made from soy protein or other soybean fractions, preferably selected from the group comprising soy milk, products produced from soy milk, drinks containing iso- lated or enzymatically treated soy protein, drinks containing soy flour, preparations containing soy lecithin, products produced from preparations containing soy lecithin and mixtures with fruit preparations and optionally flavours, • sweetener preparations, tablets and sachets, • sugar-free dragées, • ice-cream, with or without milk-based constituents, preferably sugar-free.Food grade emulsifiers

[0115] The preferred food grade emulsifiers encompass the following groups: • Lecithin; • Fatty acid derivatives, such as for example polyglycerol esters (PGE), polysorbates („TWEEN“), stearoyl lactylates, propylene glycol esters (PGMS), and sucrose esters; • Polyglycerol Polyricinoleate (PGPR); • Ammonium Phosphatide (AMP); • Mono and Diglycerides of C6-C22 saturated or unsaturated fatty acids; and mixtures thereof. Aroma or flavoring compounds

[0116] Aroma compounds and flavouring agents forming group (c) are well known in the art and can be chosen from synthetic flavouring liquid and / or oils derived from plants leaves, flowers, fruits and so forth, and combinations thereof. Representative flavouring liquids in- clude: artificial, natural or synthetic fruit flavours such as eucalyptus, lemon, orange, banana, grape, lime, apricot and grapefruit oils and fruit essences including apple, strawberry, cherry, orange, pineapple and so forth; bean and nut derived flavours such as coffee, cocoa, cola, peanut, almond and so forth; and root derived flavours such as licorice or ginger.

[0117] Suitable aroma or flavouring compounds encompass the following species: • 12-methyltridecanal; • acetaldehyde; • acetanisole; • acethylthiazole-2; • acethylthiazoline-2; • acetic acid; • acetyl methylcarbinol; • acetyl pyrazine-2; • acetyl pyridine-2; • allyl capronate; • allyl isothiocyanate;• amyl cinnamaldehyde-alpha; • anethole; • anisaldehyde-para; • anisic alcohol; • benzaldehyde; • benzyl acetate; • borneol-l; • butyl acetate; • butylidene phthalide-3; • butyric acid; • camphor; • caproic acid; • carvacrol; • carvomenthone; • carvon-d; • carvon-l; • carvylacetate-cis; • caryophyllene; • cineole-1;4; • cineole-1;8; • cinnamalcohol; • cinnamaldehyde; • cinnamyl acetate; • citral; • citronellal; • citronellol; • citronellyl acetate;• cresol • cuminaldehyde; • cyclopentadecanolide; • damascenone-alpha; • damascenone-beta; • damascone-alpha; • damascoe-beta; • decadienal-2;4; • decadienal-2;4; • decalactone delta; • decalacton gamma; • decanal; • dehydromenthofurolactone; • diallyl disulfide; • diethylpyrazine-2;3; • dihydroanethol; • dihydrocarvone; • dihydrocoumarin; • dihydroionone-beta; • dihydromenthofurolactone; • dihydronootkatone; • dimethyl lanthranilate; • dimethyl isopropyldithiazine; • dimethyl pyrazine; • dimethyl sulfide; • diphenyloxide; • divanilline;• d-menthol; • d-menthone; • d-menthyl acetate; • dodecalactone-delta; • dodecalactone-gamma; • epithiomenthan-1;8; • ethyl acetate; • ethyl butyrate; • ethyl capronate; • ethyl caprylate; • ethyl cinnamate; • ethyl isobutyrate; • ethyl isovaleria-nate; • ethyl lactate; • ethyl maltol; • ethyl methyl butyrate-2; • ethyl methyl thiopropionate; • ethyl phenol-4; • ethyl vanillin; • eugenol; • fenchol; • filbertone; • frambinone methyl ether; • frambinone; • furaneol; • furfurylthiol; • geraniol;• geranyl acetate; • geranyl isobutyrate; • guaiacol; • heliotropin; • heptalactone-gamma; • heptanone-2; • heptenal-Z-4; • hexalactone-gamma; • hexanal • hexanol; • hexenol-E-2; • hexenol-Z-3; • hexenyl acetate-E-2; • hexenyl acetate-Z-3; • hexenyl capronate-Z-3; • hexyl acetate; • hexyl cinnamaldehyde-alpha; • hotrienol; • indole; • ionon-beta; • ionone-alpha; • isoamyl acetate; • isoamyl butyrate; • isoamyl isovaerianate; • isobutyl acetate; • isobutyl thiazole; • isobutylmethoxypyrazine• isobutyraldehyde; • isoeugenol; • Isomenthon; • isopropylmethoxypyrazine; • isopropylmethylpyrazine-2;4; • isopulegol; • isova-leraldehyde; • jasmine lactone; • jasmon cis; • ketoisophorone; • limonene-d; • linalool oxide; • linalool-d; • linalool-l; • linalyl acetate; • l-menthol; • l-menthone; • l-menthyl acetate; • maltol; • massoilactone; • melonal; • menthadienyl acetate; • menthofurolactone; • menththiol-1;8; • methional; • methoxymethylpyrazine-2;3; • methyl anthranilate;• methyl butyl acetate-2; • methyl butyrate; • methyl cinnamate; • methyl dihydrojasmonate; • methyl furanthiol-2;3; • methyl jasmonate; • methyl salicylate; • methyl tetrahydrofuranthiol-2;3; • methyl thiobutyrate; • methyl thiohexyl acetate-1;3; • methylcyclopen-tenolone; • methylthiohexanol-1;3; • myrtenal; • naringin; • neo-menthol; • neral; • nerol; • nerylacetate; • nonadienal-2;4; • nonadienal-2;6; • nonalactone delta; • nonalactone gamma; • nonenal-E-2; • nonenal-Z-6; • nonenol-Z-6; • nootkatone; • octalactone gamma;• octalactone delta; • octanal • octenol-1;3; • pellitorin; • pentenone-1;3; • pentyl acetate; • phenyl ethyl acetate; • phenyl ethyl alcohol; • phenyl acetaldehyde; • pinene-alpha; • pinene-beta; • piperitanate; • piperitone • prenyl thioacetate; • prenyl thiol; • reubenamine; • rose oxide; • rubescenamine; • sabinene hydrate; • scatole; • sotolone; • styrolyl acetate; • terpinenol-4; • terpineol; • thiohexanol-1;3; • thiohexyl acetate-1;3; • thiomenthanone-8;3;• thiopentanone-4;4;2; • thymol; • tridecatrienal; • trimethyl pyrazine; • undecadienal-2;4; • undecalactone-gamma and delta; • undecatriene; • vanillin; • vinyl guaiacol; • whisky lactone; and mixtures thereof.

[0118] In particular preferred aroma or flavouring compounds encompass menthol, cineol, eugenol, thymol, cinnamic aldehyde, peppermint oil, spearmint oil, eucalyptus oil, thyme oil, cinnamon oil, clove oil, spruce needle oil, fennel oil, sage oil, aniseed oil, star anise oil, cham- omile oil, and caraway oil, and their mixtures. Sweeteners

[0119] The term "sweeteners" here denotes substances having a relative sweetening power of at least 25, based on the sweetening power of sucrose (which accordingly has a sweeten- ing power of 1). Sweeteners to be used in an orally consumable product (in particular food- stuff, feed or medicament) according to the invention (a) are preferably non-cariogenic and / or have an energy content of not more than 5 kcal per gram of the orally consumable product.

[0120] Advantageous sweeteners in a preferred orally consumable product (in particular foodstuff, feed or medicament) according to the invention are selected from the following groups: (a) Naturally occurring sweeteners, preferably selected from the group comprising miracu- lin, monellin, mabinlin, thaumatin, curculin, brazzein, pentaidin, D-phenylalanine, D- tryptophan, and extracts or fractions obtained from natural sources, comprising those amino acids and / or proteins, and the physiologically acceptable salts of those amino acids and / or proteins, in particular the sodium, potassium, calcium or ammonium salts, neohesperidin dihydrochalcone, naringin dihydrochalcone, stevioside, steviolbioside, rebaudiosides, in particular rebaudioside A, rebaudioside B, rebaudioside C, rebaudi- oside D, rebaudioside E, rebaudioside F, rebaudioside G, rebaudioside H, dulcosidesand rubusoside, suavioside A, suavioside B, suavioside G, suavioside H, suavioside I, suavioside J, baiyunoside 1, baiyunoside 2, phlomisoside 1, phlomisoside 2, phlomi- soside 3 and phlomisoside 4, abrusoside A, abrusoside B, abrusoside C, abrusoside D, cyclocaryoside A and cyclocaryoside I, osladin, polypodoside A, strogin 1, strogin 2, strogin 4, selligueain A, dihydroquercetin 3-acetate, perillartin, telosmoside A15, perian- drin I-V, pterocaryosides, cyclocaryosides, mukuroziocides, trans-anethole, trans- cinnamaldehyde, bryosides, bryonosides, bryonodulcosides, carnosiflosides, scandeno- sides, gypenosides, trilobatin, phloridzin, dihydroflavanols, hematoxylin, cyanin, chloro- genic acid, albiziasaponin, telosmosides, gaudichaudioside, mogrosides, mogroside V, hernandulcins, monatin, phyllodulcin, glycyrrhetinic acid and derivatives thereof, in par- ticular glycosides thereof such as glycyrrhizine, and the physiologically acceptable salts of those compounds, in particular the sodium, potassium, calcium or ammonium salts; and extracts or concentrated fractions of the extracts, selected from the group compris- ing thaumatococcus extracts (katamfe plant), extracts from Stevia ssp. (in particular Ste- via rebaudiana), swingle extracts (Momordica or Siratia grosvenorii, Luo-Han-Guo), ex- tracts from Glycerrhyzia ssp. (in particular Glycerrhyzia glabra), extracts from Rubus ssp. (in particular Rubus suavissimus), citrus extracts and extracts from Lippia dulcis; (b) Synthetic sweet-tasting substances, preferably selected from the group comprising magap, sodium cyclamate or other physiologically acceptable salts of cyclamic acid, acesulfame K or other physiologically acceptable salts of acesulfame, neohesperidin di- hydrochalcone, naringin dihydrochalcone, saccharin, saccharin sodium salt, aspartame, superaspartame, neotame, alitame, advantame, perillartin, sucralose, lugduname, carrelame, sucrononate and sucrooctate. Thickeners

[0121] Advantageous thickeners in a preferred orally consumable product (in particular foodstuff, feed or medicament) according to the invention are selected from the group com- prising: crosslinked polyacrylic acids and derivatives thereof, polysaccharides and derivatives thereof, such as xanthan gum, agar-agar, alginates or tyloses, cellulose derivatives, for exam- ple carboxymethylcellulose or hydroxycarboxymethylcellulose, fatty alcohols, monoglycerides and fatty acids, polyvinyl alcohol and polyvinylpyrrolidone.

[0122] Preference is given according to the invention to an orally consumable product (in particular foodstuff or feed) which comprises milk thickened with lactic acid bacteria and / or cream thickened with lactic acid bacteria and which preferably is selected from the group comprising yoghurt, kefir and quark.

[0123] A food composition according to the invention comprising milk thickened with lactic acid bacteria and / or cream thickened with lactic acid bacteria is advantageously an orally consumable product which comprises a probiotic, wherein the probiotic is preferably selected from the group comprising Bifidobacterium animalis subsp. lactis BB-12, Bifidobacterium an-imalis subsp. lactis DN-173 010, Bifidobacterium animalis subsp. lactis HN019, Lactobacillus acidophilus LA5, Lactobacillus acidophilus NCFM, Lactobacillus johnsonii La1, Lactobacillus casei immunitass / defensis, Lactobacillus casei Shirota (DSM 20312), Lactobacillus casei CRL431, Lactobacillus reuteri (ATCC 55730) and Lactobacillus rhamnosus (ATCC 53013). Additives for chewing gums

[0124] Particular preference is given to an orally consumable product (in particular food- stuff, feed or medicament) according to the invention that is a chewing gum and comprises a chewing-gum base. The chewing-gum base is preferably selected from the group comprising chewing-gum or bubble-gum bases. The latter are softer, so that gum bubbles can also be formed therewith. Preferred chewing-gum bases according to the invention include, in addi- tion to the natural resins or the natural latex chicle that are traditionally used, elastomers such as polyvinyl acetate (PVA), polyethylene, (low or medium molecular weight) polyisobu- tene (PIB), polybutadiene, isobutene-isoprene copolymers (butyl rubber), polyvinyethyl ether (PVE), polyvinylbutyl ether, copolymers of vinyl esters and vinyl ethers, styrene-butadiene copolymers (styrene-butadiene rubber, SBR) or vinyl elastomers, for example based on vinyl acetate / vinyl laurate, vinyl acetate / vinyl stearate or ethylene / vinyl acetate, as well as mixtures of the mentioned elastomers, as described, for example, in EP 0 242 325, US 4,518,615, US 5,093,136, US 5,266,336, US 5,601,858 or US 6,986,709. In addition, chewing-gum bases that are preferably to be used according to the invention preferably comprise further constituents such as, for example, (mineral) fillers, plasticisers, emulsifiers, antioxidants, waxes, fats or fatty oils, such as, for example, hardened (hydrogenated) vegetable or animal fats, mono-, di- or tri-glycerides. Suitable (mineral) fillers are, for example, calcium carbonate, titanium dioxide, silicon dioxide, talcum, aluminium oxide, dicalcium phosphate, tricalcium phosphate, magne- sium hydroxide and mixtures thereof. Suitable plasticisers, or agents for preventing adhesion (detackifiers), are, for example, lanolin, stearic acid, sodium stearate, ethyl acetate, diacetin (glycerol diacetate), triacetin (glycerol triacetate), triethyl citrate. Suitable waxes are, for ex- ample, paraffin waxes, candelilla wax, carnauba wax, microcrystalline waxes and polyethylene waxes. Suitable emulsifiers are, for example, phosphatides such as lecithin, mono- and di- glycerides of fatty acids, for example glycerol monostearate.

[0125] Chewing gums according to the invention (in particular as disclosed above) prefera- bly comprise constituents such as sugars of different types, sugar substitutes, other sweet- tasting substances, sugar alcohols (in particular sorbitol, xylitol, mannitol), ingredients having a cooling effect, taste correctors for unpleasant taste impressions, further taste-modulating substances (e.g. inositol phosphate, nucleotides such as guanosine monophosphate, adeno- sine monophosphate or other substances such as sodium glutamate or 2-phenoxypropionic acid), humectants, thickeners, emulsifiers, stabilisers, odour correctors and flavours (e.g. euca- lyptus-menthol, cherry, strawberry, grapefruit, vanilla, banana, citrus, peach, blackcurrant, tropical fruits, ginger, coffee, cinnamon, combinations (of the mentioned flavours) with mintflavours as well as spearmint and peppermint on their own). The combination inter alia of the flavours with further substances that have cooling, warming and / or mouth-watering proper- ties is of particular interest. INDUSTRIAL APPLICATION

[0126] Another object of the present invention refers to a non-therapeutic method for modulating TRPM8 receptors and effecting a cooling sensation, comprising or consisting of the following steps: (a) providing a modulator as defined above or a blend of modulators as defined above; (b) bringing said compound or blend into contact with human skin or mucous membranes.

[0127] Also claimed is the non-therapeutic use of the TRPM8 modulators as defined above or the blends as defined above for modulating TRPM8 receptors for effecting a cooling sen- sation on human skin or mucous membranes.

[0128] Finally, the application covers the use of the TRPM8 modulators as defined above or the blends as defined above for masking unpleasant flavours of fluorine derivatives and bitter compounds; and / or enhance and / or boost the performance of a flavour, a sweetener or a soothing agent.

[0129] For the avoidance of doubt it is emphasized that the specific methods and uses ac- cording to the present invention includes all preferred combinations, ranges and preferred embodiments ass explained above, therefore, a repetition is not necessary.EXAMPLES ___________________________________________________________________________________________________ Example 1 (2E)-3-(1,3-benzodioxol-5-yl)-N-phenyl-N-(tetrahydro-2-methyl-3-furanyl)-2-propenamide

[0130] N-Phenyltetrahydro-2-methylfuran-3-amine is synthesized by reductive amination (A) of dihydro-2-methylfuran-3(2H)-one and aniline. This is achieved using either stochio- metric amounts of lithium aluminum hydride, sodium boron hydride or other organoboron hydrides, or via the catalytic reduction with hydrogen with a metal catalyst. The normally used metal-based catalyst, like Palladium, Platinum, Ruthenium, Rhodium, Iridium, Nickel, or other Raney / Urushibara metal catalysts, both heterogenous and homogenous are all more or less efficient for this transformation. Let it be known, that at this point an enantiomeric excess can be generated by specific catalysts and / or additives, which are known by a skilled person in the field.

[0131] In the next step (B), (2E)-3-(1,3-benzodioxol-5-yl)-N-phenyl-N-(tetrahydro-2methyl- 3-furanyl)-2-propenamide is synthesized by reaction of N-phenyltetrahydro2-methylfuran-3- amine and (2E)-3-(1,3-benzodioxol-5-yl)-2-propenoyl chloride. The acid chloride is generated from (2E)-3-(1,3-benzodioxol-5-yl)-2-propenoic acid, which can for example be achieved by the reaction with thionyl chloride or similar.

[0132] Different toothpaste compositions were prepared and their bitter taste judged by a panel of 5 experienced testers on a scale from (5) = extremely bitter to (1) = almost no bitter taste. The compositions and results are compiled in Table A. Example 1 is according to the invention, Examples C1 and C2 serve for comparison. Provided are mean values. Table A Reduction of bitter tasting Composition C1 C2 1 Deionised water Ad 100 Glycerol 20,00 20,00 20,00 Solbrol M (sodium salt) 0,15 0,15 0,15 Sodium monofluor phosphate 0,76 0,76 0,76 Saccharin 0,20 0,20 0,20 Dicalciumphosphate dihydrate 36,00 36,00 36,00 Aerosil 200 3,00 3,00 3,00 Sodium carboxymethyl cellulose 1,20 1,20 1,20 Sodium lauryl sulfate 1,30 1,30 1,30 - 0.01 - - - 0.01 Bitter taste 4.2 3.4 2.0

[0133] The examples and comparative examples show, that the compound according to the invention shows a seriously better masking behavior when compared with the closest prior art, which differs only in one methyl group.FORMULATION EXAMPLES FOR COSMETIC COMPOSITIONS

[0134] The following examples F1 to F35 show various formulations for cosmetic composi- tions. Frescolat Fuji stands for the cooling agent according to formula (II). Table F1 Liquid soap; transparent (Amounts in % b.w.) Ingredients INCI Name Amount Tagat O 2 PEG-20 Glyceryl Oleate 2.5 Coconut oil diethanolamine condensate Cocamide DEA 5.0 Abil B 8842 Cyclomethicone 0.5 Sodium laurylethersulfate. 28% Sodium Laureth Sulfate 35.0 Tego-Betaine L7 Cocamidopropyl Betaine 5.0 Coconut acid. Potassium salt. Potassium Soap.25% 20.0 Oleate Hydrolite® 5 1,2-propanediol 0.4 Frescolat Fuji 0.3 Water Water Ad 100 Table F2 Syndet soap; liquid (Amounts in % b.w.) Ingredients INCI Name Amount Elfan OS 46 Sodium Olefin C14-C16 Sulfonate 35.5 Armoteric LB Lauryl Betaine 8.0 Elfan SG 10.0 Elfacos GT 282 L Talloweth-60 Myristyl Glycol 3.0 PCL-Liquid 100 Cetearyl Ethylhexanoate 4.0 Hydrolite® 5 Green Hydrolite® 5 Green 0.4 Preservative Methylchloroisothiazolinone 0.1 Frescolat Fuji 0.4 Water Water Ad 100Table F3 Cosmetic lotion for body wash (Amounts in % b.w.) Ingredients INCI Name Amount Disodium Laureth Sulfosuccinate. Co- Lumerol K 28 camidopropyl Betaine. Magnesium Lau- 33.0 ryl Sulfate Amphotensid B 4 Cocamidopropyl Betaine 10.0 Perlglanzmittel GM 4055 MIPA-Pareth-25 Sulfate. Glycol Stearate 4.0 Sodium Chloride Sodium Chloride 2.0 Avocado oil Persea Gratissima (Avocado) Oil 3.0 Water Water Ad 100 Hydrolite® 5 Hydrolite® 5 Green 0.5 Phenoxyethanol. Methyldibromo Glu- Euxyl® K727 0.3 taronitrile. Isothiazolinones Frescolat Fuji 0.6 Table F4 Cosmetic lotion for body wash with Triclosan (Amounts in % b.w.) Ingredients INCI Name Amount Texapon N 25 Sodium Laureth Sulfate 37.5 Lamepon S Potassium Cocoyl Hydrolyzed Collagen 28.0 Hydrogenated Tallow Glycerides. TEA- Lamesoft LMG 5.0 Cocoyl Hydrolyzed Collagen Glyceryl Laurate. TEA-Cocoyl Hydrolyzed Lamesoft 156 5.0 Collagen Sodium Chloride Sodium Chloride 1.7 Irgasan DP 300 Triclosan 0.5 Water Water Ad 100 Hydrolite® 5 Hydrolite® 5 Green 0.3 Phenoxyethanol. Benzoic Acid. Dehydro- Euxyl® K703 0.4 acetic Acid Frescolat Fuji 0.4Table F5 Intimate wash (Amounts in % b.w.) Ingredients INCI Name Amount Cocamidopropyl Betaine. Glyceryl Tegobetaine HS 15.0 Laurate Tagat L 2 PEG-20 Glyceryl Laurate 2.0 Arlacide G Chlorhexidine Digluconate 0.1 Rewoquat B 50 Benzalkonium Chloride 0.1 Lactic Acid. 80% Lactic Acid 0.1 Water Water Ad 100 Hydrolite® 5 Hydrolite® 5 Green 0.2 Potassium Sorbate. Benzyl Alcohol. Phe- Euxyl® K700 0.3 noxyethanol Frescolat Fuji 0.5 Table F6 Liquid soap (Amounts in % b.w.) Ingredient INCI Amount Deionized water Water 2.0 Soap bases mix Sodium tallowates / palmitates 95.8 Titanium dioxide Titanium dioxide 1.0 Hydrolite® 5 Hydrolite® 5 Green 1.2 Preservatives Phenoxyethanol 0.5 Frescolat Fuji 0.5Table F7 Shaving foam (Amounts in % b.w.) Ingredients Amount Dem. Water 77.2 Triethanolamine 4.0 Edenor L2 SM (Stearinic acid. Palmitinic acid) (Cognis) 5.3 Laureth-23 3.0 Stearylalcohol 0.5 Sodium lauryl sulfate 3.0 Extrapone Seaweed (water. propylene glycol. potassium iodide. Fucus Vesiculosus 1.0 Extract) Dragosantol (Bisabolol. Farnesol) 0.1 1,2-pentanediol (Hydrolite® 5) 1.0 Euxyl® K220 (Methylisothiazolinone. Ethylhexylglyerol) 0.6 Frescolat Fuji 0.3 Propane. butane 4.2 Bar 4.0 Table F8 Depilatory cream (Amounts in % b.w.) Ingredients Amount Cetearyl alcohol 10.0 Ceteareth-12 2.0 PCL-Liquid (Cetearylethylhexanoate. Isopropylmyristate) 3.0 Dragosantol (Bisabolol. Farnesol) 0.1 Edenor L2 SM (Stearinic acid. Palmitinic acid) 1.0 Dem. Water 52.2 Urea 5.0 Dem. Water 10.0 Calcium thioglycolate 6.0 Sodium hydroxide solution. 10 % 10.0 1,2-pentanediol (Hydrolite® 5) 0.5 Neo Dragocid Powder (Methyl parabene. sorbinic acid. Dehydro acetic acid. Propyl 0.2 parabene) Frescolat Fuji 0.4Table F9 After Shave Tonic (Amounts in % b.w.) Ingredients INCI Amount Water (Aqua). Pentylene Glycol. Sodium Lauryl Sul- foacetate. SodiumOleoyl Sarcosinate. Sodium Chlo- SymSol® PF-3 3.00 ride. Disodium Sulfoacetate. SodiumOleate. Sodium Sulfate SymSitive® 1609 Pentylene Glycol.4-t-Butylcyclohexan ol 1.00 Frescolat® ML Menthyl Lactate 0.30 Glycerol 99.5 P. Glycerol 5.00 Water Water (Aqua) Ad 100 Extrapone® Glacier Water Glycerol. Water (Aqua) 1.00 GW Butylene Glycol. Pentylene Glycol. Hydroxyphenyl SymCalmin® 0.50 Propamidobenzoic Acid Dragosine® Carnosine 0.10 Hydrolite® 5 Pentylene Glycol 5.00 Ethanol 96 % Alcohol Denat. 5.00 Colour Pigment Colour Pigment 0.05 Hydrolite® 5 1,2-pentanediol 0.15 Frescolat Fuji Hydroxyacetophenone 1.00 Table F10 Deodorant formulation in the form of a roll-on gel (Amounts in % b.w.) Ingredients Amount 1.3-butylene glycol 2.00 PEG-40-hydrogenated castor oil 2.00 Hydroxyethylcellulose 0.50 1,2-pentanediol (Hydrolite® 5) 0.30 1.3-propanediol 0.50 3-phenylpropanol 0.40 Ethylhexyl glycerin 0.10 Frescolat Fuji 0.50 Water ad 100.00Table F11 Clear deo anti-perspirant roll-on (Amounts in % b.w.) Ingredients INCI Amount Methocel E4M Premium Hydroxypropyl Methylcellulose 0.50 Water Water (Aqua) Ad 100 Trideceth-9. PEG-5 Ethylhexanoate. Water Neo-PCL Water Soluble N 1.00 (Aqua) PEG-40 Hydrogenated Castor Oil. Trideceth- Solubilizer 3.00 9. Propylene Glycol. Water (Aqua) Deolite Dimethyl Phenylpropanol. Pentylene Glycol 0.50 Locron LW Aluminium Chlorohydrate 25.00 Aloe Vera Gel Concentrate 10 / 1 Aloe Barbadensis Leaf Juice 1.00 Propylene Glycol -1.299 P GC Propylene Glycol 4.00 Ethanol 96 % Alcohol Denat. 30.00 Hydrolite® 5 1,2pentanediol 1.00 Frescolat Fuji Hydroxyacetophenone 0.25 Table F12 Deodorant stick (Amounts in % b.w.) Ingredients Amount Sodium stearate 8.00 PPG-3 Myristyl ether 70.00 1.2-propylene glycol 10.00 1.1-dimethyl-3-phenylpropanol 0.20 2-butyloctanoic acid 0.20 1,2-pentanediol (Hydrolite® 5) 0.60 Heptoxy-1.2-propanediol 0.20 Phenoxyethanol 0.30 Frescolat Fuji 0.50 Water Ad 100Table F13 Zirconium suspensoid antiperspirant stick (Amounts in % b.w.) Ingredients INCI Amount PCL Liquid 100 Cetearyl ethylhexanonate to 100 Silicone Fluid 345 Cyclomethicone 10.00 CRODACOL C90 Cetyl Alcohol 8.00 SYNCROWAX HGLC C18-36 Triglyceride 8.00 CRODAMOL PTC Pentaerythritol Tetracaprylate / Caprate 5.00 SYNCROWAX HRC Tribehenin 4.00 VOLPO N5 Oleth-5 1.00 Titanium Dioxide 1.00 Rezal 36GP Aluminium Tetrachlorohydrex GLY 20.00 Dry Flo C Aluminium Starch Octenyl Succinate 22.50 Hydrolite® 5 1,2-pentanediol 0.60 Preservative Phenoxyethanol 0.40 Hexoxy-1.2-propanediol 0.10 Frescolat Fuji 0.40 Table F14 Deodorant pump spray with SymClariol (Amounts in % b.w.) Ingredients INCI Amount SymClariol® Decylene Glycol 0.50 PEG-40 Hydrogenated Castor Oil. Trideceth-9. Solubilizer 4.00 Propylene Glycol. Water (Aqua) Neo-PCL Water Soluble N Trideceth-9. PEG-5 Ethylhexanoate. Aqua 1.50 Bisabolol. Zingiber Officinale SymRelief® 0.10 (Ginger) Root Extract Water Water (Aqua) Ad 100 1.2 Propylene Glycol Propylene Glycol 6.00 Hydrolite® 5 1,2-pentanediol 0.40 SymDiol® 68 1.2-Hexanediol. Caprylyl Glycol 0.20 Frescolat Fuji 0.40Table F15 Antiperspirant formulations (Amounts in % b.w.) Ingredients Amounts Reach AZP-908 SUF 24.00 Cyclomethicone (Pentamer) Ad 100 Polydecene (Silkflo 364 NF) 17.50 Neo Heliopan OS (ethylhexyl salicylate) 2.50 L-Menthyl lactate (Frescolate ML) 0.25 Polyethylene 3.00 Hydrogenated castor oil 2.00 Promyristyl PM-3 7.00 PEG-8 Distearate 3.00 Silicon dioxide (Cab-O-Sil M-5) 1.00 Stearyl alcohol 15.00 Octyldodecanol 0.10 1,2-pentanediol (Hydrolite® 5) 0.80 3-Phenylpropanol 0.40 Frescolat Fuji 0.60 Table F16 Deodorant spray with Triclosan (Amounts in % b.w.) Ingredients Amount PEG-40-hydrogenated castor oil 3.00 Ethylhexylglycerol (Octoxyglycerol) 0.80 Ethanol 40.00 Citrate buffer 0.50 Triclosan ^ (5-chloro-2-(2.4-dichlorophenoxy)phenol) 0.25 1,2-pentanediol (Hydrolite® 5) 0.75 Phenoxyethanol 0.40 Frescolat Fuji 0.40 Water Ad 100Table F17 O / W lotion (Amounts in % b.w.) Ingredients Amount Paraffin oil 5.00 Isopropyl palmitate 5.00 Cetyl alcohol 2.00 Beeswax 2.00 Ceteareth-20 2.00 PEG-20-glyceryl stearate 1.50 Glycerol 3.00 1,2-pentanediol (Hydrolite® 5) 0.30 Methylparaben 0.30 Frescolat Fuji 0.60 Water ad 100.00 Table F18 Body lotion (Amounts in % b.w.) Ingredients Amount Cetearyl Alcohol 2.00 Ethylhexyl Isononanoate 5.00 Cetearyl Ethylhexanoate. Isopropyl Myristate 3.00 Glyceryl Oleate Citrate. Caprylic / Capric Triglyceride 4.00 Water (Aqua) 79.50 Carbomer 0.30 Sodium Benzoate 0.100 Propylene Glycol 5.00 Sodium Hydroxide 30% solution 0.30 1,2-pentanediol (Hydrolite® 5) 0.30 Triethylene Glycol. Imidazolidinyl Urea. Methylparaben. Propylparaben. Dehydroacetic 0.30 Acid Frescolat Fuji 0.20Table F19 Cream (Amounts in % b.w.) Ingredients Amount Paraffin oil 10.00 Ozokerite 4.00 Vaseline 4.00 Vegetable oil 10.00 Wool wax alcohol 2.00 Aluminum stearate 0.40 1,2-pentanediol (Hydrolite® 5) 2.00 Phenoxyethanol 0.50 Frescolat Fuji 0.50 Water ad 100.00 Table F20 Cream (Amounts in % b.w.) Ingredients INCI Amount Dracorin® CE Glyceryl Stearate Citrate 1.00 Lanette® O Cetearyl Alcohol 2.00 Cutina® GMS-V Glyceryl Stearate 1.00 Tegosoft® MM Myristyl Myristate 1.00 Xiameter® PMX-0246. Cyclosiloxane Cyclohexasiloxane (and) Cyclopentasiloxane 0.50 Dragoxat® 89 Ethylhexyl Isononanoate 2.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 4.00 Neutral Oil Caprylic / Capric Triglyceride 4.00 Carbopol® Ultrez 21 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.20 Keltrol® CG-T Xanthan Gum 0.10 Water Water (Aqua) Ad 100 Glycerol 99.5 P. Glycerol 3.00 Propylene Glycol -1.299 P GC Propylene Glycol 2.00 Sodium Benzoate Sodium Benzoate 0.10 Sodium Hydroxide 10% solution Sodium Hydroxide 0.50 Hydrolite® 5 1,2-pentanediol 0.30Dehydroacetic Acid. Benzoic Acid. Phenoxy- Euxyl® K702 ethanol.Polyaminopropyl Biguanide. Ethylhexyl- 0.30 glycerin Frescolat Fuji 0.70 Table F21 Hand and body cream (Amounts in % b.w.) Ingredients INCI Amount Glyceryl Oleate Citrate. Caprylic / Capric Triglycer- Dracorin® GOC 2.00 ide PCL-Solid Stearyl Heptanoate. Stearyl Caprylate 2.50 Lanette® O Cetearyl Alcohol 1.50 Cutina® GMS-V Glyceryl Stearate 1.00 Dragoxat® 89 Ethylhexyl Isononanoate 3.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 7.00 Isodragol® Triisononanoin 4.00 Xiameter® PMX-0345 Cyclosiloxane Cyclopentasiloxane (and) Cyclohexasiloxane 0.50 Water Water (Aqua) Ad 100 Carbopol® Ultrez 21 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.20 Keltrol® CG-RD Xanthan Gum 0.10 Glycerol 85 P. Glycerol 3.00 Water (Aqua). Butylene Glycol. Glycerol. Avena DragoBetaGlucan 1.50 Sativa (Oat) Kernel Extract Potassium Sorbat Potassium Sorbate 0.10 Sodium Hydroxide 10% solution Sodium Hydroxide 0.50 Hydrolite® 5 1,2-pentanediol 0.20 Methyl-. Butyl-. Ethyl-. Propyl. Isobutylparaben. Euxyl® K300 0.30 Phenoxyethanol. Frescolat Fuji 0.30Table F22 Face cream (Amounts in % b.w.) Ingredients INCI Amount Potassium Cetyl Phosphate. Hydrogenated Palm Emulsiphos® 1.50 Glycerides Cutina® GMS-V Glyceryl Stearate 1.70 Lanette® O Cetearyl Alcohol 3.00 Tegosoft® MM Myristyl Myristate 1.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 1.00 Isodragol® Triisononanoin 3.00 Dragoxat® 89 Ethylhexyl Isononanoate 4.00 Avocado Oil Persea Gratissima (Avocado) Oil 3.00 Abil® 350 Dimethicone 0.50 Covi-ox® T-70 Tocopherol 0.10 Edeta® BD Disodium EDTA 0.10 Carbopol® Ultrez 21 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.30 Keltrol® CG-RD Xanthan Gum 0.150 Water Water (Aqua) Ad 100 Glycerol 99.5 P. Glycerol 4.00 Propylene Glycol -1.299 P GC Propylene Glycol 3.00 Maltodextrin. Rubus Fruticosus (Blackberry) Leaf SymMatrix® 0.50 Extract Sodium Hydroxide 10% solution Sodium Hydroxide 0.50 Hydrolite® 5 1,2-pentanediol 0.30 Euxyl® K712 Sodium Benzoate. Potassium Sorbate 0.20 Frescolat Fuji 0.60Table F23 Moisturizing body care cream (Amounts in % b.w.) Ingredient Amount PEG-7 hydrogenated castor oil 6.00 Cetearyl ethyl hexanoate 10.00 Isopropyl myristate 5.00 Mineral oil 7.00 Shea Butter (Butyrospermum parkii) 0.50 Aluminum stearate 0.50 Magnesium stearate 0.50 Bisabolol 0.20 Quaternium-18-Hectorit 0.70 Dipropylene glycol 5.0 Magnesium sulfate 0.70 1,2-pentanediol (Hydrolite® 5) 4.00 Preservative (Phenoxyethanol) 0.20 Frescolat Fuji 0.40 Aqua dem. 58.90Table F24 Anti-wrinkle cream (Amounts in % b.w.) Ingredients Amount Glyceryl Stearate Citrate 1.00 Glyceryl Laurate 1.00 Cetearyl Alcohol (and) Myristyl Myristate 3.00 Cetearyl Ethylhexanoate 4.00 Mineral oil 4.00 Cyclohexasiloxane 0.50 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.20 Water Ad 100 1.2-Hexanediol 2.00 Sodium Hydroxide 10% solution 0.10 Narcissus Tazetta Bulb Extract 1.00 1,2-pentanediol (Hydrolite® 5) 0.30 Frescolat Fuji 0.50Table F25 Functional skin oil for disinfection (Amounts in % b.w.) Ingredients INCI Amount Neutral Oil Caprylic / Capric Triglyceride Ad 100 Sweet Almond Oil Prunus Dulcis 20.00 Dragoxat® 89 Ethylhexyl Isononanoate 4.00 Isopropyl Palmitate Isopropyl Palmitate 6.00 PCL-Liquid 100 Cetearyl Ethylhexanoate 15.00 Dragosantol® 100 Bisabolol 0.20 Retinyl Acetate In Oil (1 Mio. Ie / G) Retinyl Acetate 0.50 Vitamin E Acetate Tocopheryl Acetate 0.50 Covi-ox® T-70 Tocopherol 0.10 Hydrolite® 5 1,2-pentanediol 0.30 Preservative Methyl-. Butyl-. Ethyl-. Propylparaben 0.30 Frescolat Fuji 0.40 Table F26 Septic wound cream (Amounts in % b.w.) Ingredients (INCI) Amount Sorbitan Isostearate. Hydrogenated Castor Oil. Ceresin. Beeswax (Cera Alba) 6.00 Petrolatum 21.00 Cera Alba 5.00 Cetearyl Alcohol 7.00 Prunus Dulcis 7.00 Lanolin 5.00 Paraffinum Liquidum 12.00 Water (Aqua) Ad 100 Panthenol 7.00 Magnesium Sulfate 0.70 1,2-pentanediol (Hydrolite® 5) 1.00 Tocopheryl Acetate 1.00 Phenoxyethanol 0.50 Frescolat Fuji 0.50Table F27 Moisturizing and disinfecting face mask (Amounts in % b.w.) Ingredients INCI Amount Water Water (Aqua) Ad 100 Stabileze QM PVM / Ma Decadiene Crosspolymer 0.50 Biotive® L-Arginine Arginine 0.75 Glycerol. Water (Aqua). Laminaria Saccharina Actipone® Laminaria Saccharina GW 1.00 Extract Water (Aqua). Propylene Glycol. Cucumis Sa- Extrapone® Cucumber 1.00 tivus (Cucumber) Juice Glycerol 99.5 P. Glycerol 7.00 Neo Actipone® Soap Nutshell Sapindus Mukurossi Peel Extract 0.50 Colour I Colour 0.01 Hydrolite® 5 Pentylene Glycol 5.00 PEG-40 Hydrogenated Castor Oil. Trideceth-9. Solubilizer 0.60 Water (Aqua) Hydrolite® 5 1,2-pentanediol 0.08 Preservative Phenoxyethanol 0.40 Frescolat Fuji 0.40Table F28 Sprayable disinfecting gel (Amounts in % b.w.) Ingredients INCI Amount Water Water (Aqua) Ad 100 Stabileze QM PVM / Ma Decadiene Crosspolymer 0.25 Sodium Hydroxide 10% solution Sodium Hydroxide 0.40 Coffein pure Caffeine 0.50 Propylene Glycol. Water (Aqua). Glucose. Aescu- Extrapone® Horse Chestnut lus Hippocastanum (Horse Chestnut) Seed Ex- 1.00 tract. Lactic Acid Hydrolite® 5 1,2-pentanediol 3.00 1.3 Butylene Glycol Butylene Glycol 5.00 Biotive® Esculin Sesquihydrate Esculin 0.30 Ethanol 96 % Alcohol Denat. 10.00 PEG-40 Hydrogenated Castor Oil. Trideceth-9. Solubilizer 0.50 Water (Aqua) Preservative Phenoxyethanol 0.70 Frescolat Fuji 0.30Table F29 Mineral wash and cleaning gel (Amounts in % b.w.) Ingredients INCI Amount Water Water (Aqua) Ad 100 Pionier® NP 37 G Sodium Carbomer 1.50 Water (Aqua). Pentylene Glycol. Sodium Lauryl Sulfoacetate. SodiumOleoyl Sarcosinate. Sodi- SymSol® PF-3 5.00 um Chloride. Disodium Sulfoacetate. Sodi- umOleate. Sodium Sulfate Water (Aqua). Pentylene Glycol. Glycerol. Sodi- Hydroviton® 24 um Lactate. Lactic Acid. Serine. Urea. Sorbitol. 1.00 Sodium Chloride. Allantoin Extrapone® Silk GW Water (Aqua). Glycerol. Hydrolyzed Silk 1.00 Hydrolite® 5 Green Hydrolite® 5 Green 4.00 Water (Aqua). Propylene Glycol. Algin. Gellan Gum. Xanthan Gum. CalciumChloride. CI 12490 Actipearls Red Star # DH10402 / 6 1.00 (Pigment Red 5). Mica (CI 77019). Titanium Di- oxide (CI 77891) 1,2-pentanediol (Hydrolite® 5) 1,2-pentanediol 0.50 3-Phenylpropanol 0.70 Frescolat Fuji 0.30Table F30 Anti-acne wash (Amounts in % b.w.) Ingredients (INCI) Amount Water (Aqua) 45.70 Polyquaternium-7 0.50 Cocamidopropyl Betaine 9.000 9.00 Coco Glucoside 2.000 2.00 Polysorbate 80. Glycerol. Gossypium Herbaceum. (Cotton) Seed Oil. Water (Aqua) 1.00 Trideceth-9. PEG-5 Ethylhexanoate. Water (Aqua) 1.00 Glycereth-90 Isostearate. Laureth-2 0.50 Sodium Laureth Sulfate 37.000 37.00 Glycerol. Triticum Vulgare (Wheat) Gluten. Water (Aqua) 1.00 Sodium Chloride 0.30 1,2-pentanediol (Hydrolite® 5) 1.00 Frescolat Fuji 0.50Table F31 Cosmetic sun protection composition (Amounts in % b.w.) Ingredient Amount Ethylhexyl cinnamic acid 7.50 Benzophenon-3 2.00 Polyglyceryl dimer soyate 0.80 Sorbitane stearate 1.00 Tocopheryl acetate 0.50 Glyceryl stearate. PEG-100 Stearate 3.00 PEG-40. hydrogenated castor oil 1.00 Titanium dioxide. aluminum oxide hydrate. Dimethicon / Methicon Copolymer 3.00 Butyrospermum parkii (Shea Butter) 1.00 C12-15 alkyl benzoate 6.50 Butylene glycol 5.00 Xanthan gum 0.30 Disodium EDTA 0.10 Allantoin 0.10 Polyacryl amide. C13-14 isoparaffin. Laureth-7 1.00 1,2-pentanediol (Hydrolite® 5) 5.00 4-t Butylcyclohexanol 1.00 Preservatives (Methyl-. Butyl-. Ethyl-. Propylparaben. Phenoxyethanol) 0.30 Frescolat Fuji 0.60 Aqua dem. Ad 100Table F32 Toilet cleaner (Amounts in % b.w.) Ingredients Amount Water 93.0 Kelzan ASX-T 0.5 Parafin sulfonate. sodium salt 1.0 Citric acid 5.0 Colorant (FD & C Yellow No. 6) 0.1 1,2-pentanediol (Hydrolite® 5) 0.3 Preservative (Benzisothiazolinone. Glutaral) 0.05 Frescolat Fuji 0.6 Table F33 Dish washing concentrate (Amounts in % b.w.) Ingredients Amount Sodium laurylsulfate 31.0 Propane-1.2-diole 6.0 Ethyl alcohol 96% 7.0 Palm tree glucosides 6.0 Coco betaine 18.0 1,2-pentanediol (Hydrolite® 5) 0.4 Frescolat Fuji 0.5 Water 31.6Table F34 Dish washing concentrate (Amounts in % b.w.) Ingredients Amount Palm tree glucosides 4.0 Sodium lauryl sulfate 45.0 Coco betaine 8.0 Ethyl alcohol 96% 1.0 Colorant (C.I. Pigment Blue 15) 0.05 1,2-pentanediol (Hydrolite® 5) 0.2 Frescolat Fuji 0.7 Water Ad 100 Table F35 Solution for wet wipes (Amounts in % b.w.) Ingredients INCI Amount SymSol® PF-3 Water (Aqua). Pentylene Glycol. Sodium Lauryl 2.00 Sulfoacetate. SodiumOleoyl Sarcosinate. Sodi- um Chloride. Disodium Sulfoacetate. Sodi- umOleate. Sodium Sulfate Dragosantol® 100 Bisabolol 0.10 Glycerol 99.5 P. Glycerol 5.00 Water Water (Aqua) Ad 100 Hydrolite® 5 1,2-pentanediol 5.00 D-Panthenol 75 W Panthenol 0.80 DragoCalm® Water (Aqua). Glycerol. Avena Sativa (Oat) Ker- 1.00 nel Extract Witch Hazel-Distillate Hamamelis Virginiana (Witch Hazel) Water. 1.00 Water (Aqua). Alcohol Allplant Essence® Org. Rose Gera- Pelargonium Graveolens Flower / Leaf / Stem Wa- 1.00 nium P ter Preservative Phenoxyethanol 0.30 Frescolat Fuji 0.50

Claims

WHAT CLAIMED IS ___________________________________________________________________________________________________ 1. TRPM8 modulators according to Formula (I)in which the substituents have the following meanings: R1 or mono- or polynuclear aryl, arylalkyl and heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6 alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S; R2 mono- or polynuclear aryl, arylalkyl and heteroaryl groups carrying 1, 2, 3 or 4 iden- tical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6 alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S; R3 Independently from each other hydrogen; halogens; linear or branched C1-C6alkyl groups optionally bearing 1, 2, 3 or 4 identical or different substituents selected R4 from the group consisting of NH2, OH, SH, halogens or linear or branched C1-C6 alkyl groups; linear or branched C1- to C6-alkoxy groups optionally carrying 1, 2, 3 R5 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens or C1-C6-alkoxy groups; mono- or polynuclear aryl, arylalkyl and R6 heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1- R7 C6-alkyl groups; the heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms which are the same or different and are selected from the group consisting of O, N and S,or two adjacent radicals R3, R4, R5, R6 and R7 together with the carbon atoms to which they are attached form a 4-, 5-, 6- or 7-membered, mono- or polyunsaturat- ed heterocyclic ring optionally bearing 1, 2, 3, 4 or 5 identical or different substitu- ents selected from the group consisting of linear or branched C1-C6alkyl groups, and having 1, 2 or 3 ring heteroatoms, identical or different, selected from the group consisting of O, N and S;; R8 independently from each other linear or branched C1-C6 alkyl or alkoxy groups, or C2-C6alkenyl groups; R9 R10 X linear or branched C1-C6alkylene groups or C2-C6alkenylene groups; Y hydrogen, linear or branched C1-C6alkylene groups or C2-C6alkenylene groups; Z oxygen or sulfur 2. TRPM8 modulators according to Claim 1, wherein to the substituents of Formula (I) have the following meanings: R1 R2 mono- or polynuclear aryl, arylalkyl and heteroaryl groups carrying 1, 2, 3 or 4 iden- tical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S; R3 independently from each other hydrogen; halogens; linear or branched C1-C6 alkyl groups optionally bearing 1, 2, 3 or 4 identical or different substituents selected R4 from the group consisting of NH2, OH, SH, halogens or linear or branched C1-C6alkyl groups; linear or branched C1- to C6-alkoxy groups optionally carrying 1, 2, 3 R5 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens or C1-C6-alkoxy groups; mono- or polynuclear aryl, arylalkyl and R6 heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1- R7 C6-alkyl groups; the heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms which are the same or different and are selected from the group consisting of O, N and S, or two adjacent radicals R3, R4, R5, R6 and R7 together with the carbon atoms to which they are attached form a 4-, 5-, 6- or 7-membered, mono- or polyunsaturat- ed heterocyclic ring optionally bearing 1, 2, 3, 4 or 5 identical or different substitu-ents selected from the group consisting of linear or branched C1-C6alkyl groups, and having 1, 2 or 3 ring heteroatoms, identical or different, selected from the group consisting of O, N and S;; R8 each of them being methyl R9 R10 X linear or branched C1-C4 alkylene groups or C2-C4 alkenylene groups; Y hydrogen Z oxygen 3. TRPM8 modulators according to Claim 1, wherein to the substituents of Formula (I) have the following meanings: R1 mono- or polynuclear aryl, arylalkyl and heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1-C6alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms, identical or different, selected from the group consisting of O, N and S; R2 mono- or polynuclear aryl, arylalkyl and heteroaryl groups carrying 1, 2, 3 or 4 iden- tical or different substituents selected from the group consisting of linear or branched C1-C6alkyl groups; said heteroaryl groups having 1, 2, 3 or 4 ring heteroa- toms, identical or different, selected from the group consisting of O, N and S; R3 Independently from each other hydrogen; halogens; linear or branched C1-C6 alkyl groups optionally bearing 1, 2, 3 or 4 identical or different substituents selected R4 from the group consisting of NH2, OH, SH, halogens or linear or branched C1-C6alkyl groups; linear or branched C1- to C6-alkoxy groups optionally carrying 1, 2, 3 R5 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens or C1-C6-alkoxy groups; mono- or polynuclear aryl, arylalkyl and R6 heteroaryl groups optionally carrying 1, 2, 3 or 4 identical or different substituents selected from the group consisting of NH2, OH, SH, halogens, linear or branched C1- R7 C6-alkyl groups; the heteroaryl groups having 1, 2, 3 or 4 ring heteroatoms which are the same or different and are selected from the group consisting of O, N and S, or two adjacent radicals R3, R4, R5, R6 and R7 together with the carbon atoms to which they are attached form a 4-, 5-, 6- or 7-membered, mono- or polyunsaturat- ed heterocyclic ring optionally bearing 1, 2, 3, 4 or 5 identical or different substitu- ents selected from the group consisting of linear or branched C1-C6 alkyl groups, and having 1, 2 or 3 ring heteroatoms, identical or different, selected from the group consisting of O, N and S;;R8 Each of them being methyl R9 R10 X linear or branched C1-C4 alkylene groups or C2-C4 alkenylene groups; Y hydrogen Z oxygen 4. A TRPM8 modulator according to formula (II)5. A cooling blend comprising or consisting of (a) compounds according to formula (I) and (b) at least one additional physiological cooling agent different from compound (a).

6. The blend according to Claim 5, wherein component (a) is the compound according to formula (II) 7. The blend according to any of the Claims 5 or 6, wherein components (a) and (b) are present in a ratio by weight of from about 0.1:99.9 to about 99.9:0.

1.

8. A cosmetic composition comprising at least one modulator according to Claims 1, 2 or 3 or the blend of modulators according to Claim 4.

9. The composition of Claim 8 representing a skin care composition or an oral care com- position.

10. The composition of any of Claims 8 or 9, comprising at least one modulator according to Claims 1 or 3 or the blend of modulators according to Claim 4 in an amount of from about 0.001 to about 1 – calculated on the total composition.

11. A food composition comprising at least one modulator according to Claims 1, 2 or 3 or the blend of modulators according to Claim 4.

12. The composition of Claim 11, comprising at least one modulator according to Claims 1, 2 or 3 or the blend of modulators according to Claim 4 in an amount of from about 0.001 to about 0.1 – calculated on the total composition.

13. A non-therapeutic method for modulating TRPM8 receptors and effecting a cooling sensation, comprising or consisting of the following steps: (a) providing a modulator according to Claims 1, 2 or 3 or a blend of modulators ac- cording to Claim 4; (b) bringing said compound or blend into contact with hum skin or mucous mem- branes.

14. The non-therapeutic use of the TRPM8 modulators according to Claims 1, 2 or 3 or the blends according to Claim 4 for modulating TRPM8 receptors for effecting a cooling sensation on human skin or mucous membranes.

15. The use of the TRPM8 modulators according to Claims 1, 2 or 3 or the blends according to Claim 4 for masking unpleasant flavors of fluorine derivatives and bitter compounds; and / or enhance and / or boost the performance of a flavor, a sweetener or a soothing agent.

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