Purification of pa66 oligomers
A depolymerization and separation process using water as a solvent effectively recovers polyamide oligomers and fillers from end-of-life plastics, addressing the inefficiencies in existing recycling methods and enabling their reuse in polymer production.
Patent Information
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- BASF SE
- Filing Date
- 2025-12-12
- Publication Date
- 2026-06-18
AI Technical Summary
Existing recycling processes for polyamide-based plastics, particularly those reinforced with fillers like glass fibers, struggle to separate and recover the different components effectively, leading to inefficient recycling and reuse of materials.
A process involving depolymerization with water as a solvent, followed by controlled cooling and separation techniques, allows for the recovery of polyamide oligomers and fillers from end-of-life materials, enabling their reuse in polymer production.
The process effectively separates fillers from polyamide plastics, preserving the molecular weight of the polymer and allowing for the recovery of reusable oligomers and fillers, facilitating the recycling of polyamide-based materials.
Abstract
Description
240855W001Purification of PA66 oligomersThe present invention relates to a process for treating a polymeric material (PM) comprising a polyamide based polymer, preferably a polyamide 66 based polymer, and at least one insoluble filler (F1). The process comprises the steps of providing a polymeric material (PM) comprising a polyamide based polymer and at least one filler (F1) and a solvent composition (SC) comprising water; preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC); subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D 1 ) and a depolymerization time t(D1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1); separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer; cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer, separating soluble monomers of the polyamide based polymer and short chained oligomers from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer. Furthermore, the present invention is directed to the use of a mixture obtainable or obtained by a process according to the present invention, for preparing a polyamide.Polyamide based polymers and mixtures of polyamides are widely used, for example in the production of textiles and composites. The resulting end-of-life materials and waste are difficult to recycle without separating the components first. In recycling processes, often mixtures are obtained comprising soluble degradation products of the polymers as well as insoluble parts. Different approaches have been described in the literature.WC2024008847 describes the separation of a plastic solvolysis mixture by membrane filtration to separate off catalyst in a solvent mixture consisting of alcohols, glycols, amines and mixtures thereof.US5430068 describes a process for the solvent-based separation of polyamides from filler materials involving a polyol or aliphatic carboxylic acid and successive precipitation of the polyamide from said solvent. However, this invention aims at sustaining the molecular weight of the polymer in a recycling process without further remonomerization steps, which limits the work-up and purification options.Furthermore, modern, high resilience composite plastics are often based on reinforced, in particular glass fiber-rein- forced thermoplastics, in particular polyamides. In many processes disclosed in the state of the art, the fillers are not recovered or damaged and cannot be reused.It was an object of the present invention to provide a process, which allows recycling polyamide engineering plastics comprising filler and recovering the different compounds for recycling purposes.240855W001- 2 -According to the present invention, this object is achieved by a process for treating a polymeric material (PM) comprising a polyamide based polymer, preferably a polyamide 66 based polymer, and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide based polymer, preferably a polyamide 66 based polymer, and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D 1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer,(f) separating soluble monomers of the polyamide based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer.According to a preferred embodiment of the present invention, this object is achieved by a process for treating a polymeric material (PM) comprising a polyamide 66 based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide 66 based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);240855W001- 3 -(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide 66 based polymer (D1) comprising a depolymerization temperature T(D1 ) and a depolymerization time t(D1 ) obtaining a mixture (M-1 ) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide 66 based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide 66 based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide 66 based polymer,(f) separating soluble monomers of the polyamide 66 based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide 66 based polymer.It was surprisingly found that the process according to the presented invention allows to separate the filler from polyamides, in particular PA66 engineering plastics, from end-of-life waste-streams. Surprisingly, it was found that by using the specific conditions for the depolymerization according to the present invention significantly reduce the degree of depolymerization of the polyamide and it is possible to isolate the oligomers of the polyamide. It has surprisingly been found that the separation can be achieved by fractionating precipitation and / or fractionating crystallization. The oligomers can be subjected to polymerization conditions to obtain polyamides, thus enabling the reuse of the polymers. By stepwise depolymerization and separation of the insoluble fraction oligomers can be obtained from the reaction mixture.The unit Kelvin has the same scaling as the unit degrees Celsius. Accordingly, a temperature difference of 1 Kelvin corresponds to a difference of 1 degree Celsius. The temperature of 0 Kelvin corresponds to -273.15 degrees Celsius.The process according to the present invention comprises steps (a), (b), (c), (d), (e), and (f) and optionally further steps. According to step (a), a polymeric material (PM) and a solvent composition (SC) comprising water are provided. According to step (b), a mixture (M-0) is prepared from the polymeric material (PM) and the solvent composition (SC).240855W001- 4 -The polymeric material (PM) comprises a polyamide based polymer and at least one filler (F1) and may comprise further polymeric materials or additives. Preferably, the polymeric material (PM) comprises the polyamide based polymer in an amount of from 5 to 95 % by weight, more preferable in an amount of from 65 to 95 % by weight, in particular in an amount of from 70 to 90 % by weight based on the polymeric material.Preferably, the polyamide based polymer is a polyamide 66 based polymer. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the polyamide based polymer is a polyamide 66 based polymer.Preferably, the filler (F1) is a fibrous filler. According to a further embodiment, the present invention is also directed to a process as disclosed above, wherein the filler (F1) is a fibrous filler, preferably a fibrous filler selected from the group consisting of glass fibers, carbon fibers, aramid fibers, potassium titanate fibers, fibers composed of liquidcrystal polymers, metal fibers, polyester fibers, polyamide fibers, organic fibrous fillers and inorganic fibrous fillers.Regarding the polymeric material (PM) which is provided according to (a), it is preferred that it is provided in solid form, more preferably in the form of particles such as granules. The polymeric material (PM) preferably is an end-of- life material, in particular an end-of-life material obtained from textiles, composite materials, or automotive shredder residue. The polymeric material (PM) may preferably be an automotive shredder residue, in particular a polymer enriched automotive shredder residue, more preferable a polyamide 6 / polyamide 66 enriched automotive shredder residue. In a preferred embodiment, the starting polymer or polyamide-containing compositions are mechanically comminuted to an average particle size from 0.1 to 50 mm, preferably from 5 to 20 mm before splitting. The comminution can be carried out in a commercial mill, for example in a cutting mill, or, preferably, in particular when the compositions used contain hard materials such as metal inserts, for example bolts, in a hammer mill.Metal parts present in the material thus comminuted can be removed in a drying separation process using an air table, preferably with subsequent induction separation, using for example a free-fall tube separator, for complete removal of the metal parts, or in a wet separation process.The term "particle” as used in this context of the present invention comprises optionally preformed granules, and also comprises shredded pieces.The solvent composition (SC) comprises water and may comprise further solvents. Preferably, the pH value of the solvent composition (SC) is in the range of from 4.0 to 11 .0, more preferably from 6.0 to 8.0. Suitable further solvents are for example alcohols such as for example monools, diols or triols, preferably alcohols selected from methanol, ethanol, propanol, iso-propanol, ethylene glycol diethylene glycol and glycerol. Also suitable are polar solvents such as for example sulfolan or ethylene carbonate.240855W001- 5 -Preferably, mixture (M-0) comprises the polymeric material (PM) and the solvent composition (SC) in a ratio in the range of from 1:20 to 1 :1, in particular in the range of from 1 :10 to 1 :2.Mixture (M-0) may comprise further components such as for example other polymers. Preferably, mixture (M-0) only comprises small amounts of polyesters or polyurethanes, for example less than 1 % by weight of a polymer selected from the group consisting of polyesters and polyurethanes, more preferable less than 1 % by weight of a polymer selected from the group consisting of polyesters and polyurethanes, more preferable less than 0.1 % by weight of a polymer selected from the group consisting of polyesters and polyurethanes, more preferable less than 0.01 % by weight of a polymer selected from the group consisting of polyesters and polyurethanes.Preferably mixture (M-0) comprises metal hydroxides, in particular sodium hydroxide and potassium hydroxide, in an amount of less than 5 % by weight, preferably less than 1 % by weight, more preferable less than 1 % by weight, more preferable less than 0.1 % by weight, more preferable less than 0.01 % by weight, more preferable less than 0.001 % by weight. Particularly preferable, mixture (M-0) is free of sodium hydroxide and potassium hydroxide.According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein mixture (M-0) comprises metal hydroxides, in particular sodium hydroxide and potassium hydroxide, in an amount of less than 5 % by weight. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein mixture (M-0) is free of sodium hydroxide and potassium hydroxide.Preferably mixture (M-0) comprises acids such as sulfuric acid and hydrochloric acid, in an amount of less than 5 % by weight, preferably less than 1 % by weight, more preferable less than 1 % by weight, more preferable less than 0.1 % by weight, more preferable less than 0.01 % by weight, more preferable less than 0.001 % by weight. Particularly preferable, mixture (M-0) is free of sulfuric acid and hydrochloric acid.According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein mixture (M-0) comprises acids such as sulfuric acid and hydrochloric acid, in an amount of less than 5 % by weight. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein mixture (M-0) is free of sulfuric acid and hydrochloric acid.According to step (c) of the process, mixture (M-0) is subjected to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D 1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1). The term "soluble oligomers” in the context of the present invention means that the oligomers are soluble in mixture (M1) under the conditions of step (c) of the process, in particular at the depolymerization temperature T(D1).240855W001- 6 -Suitable methods and conditions for the depolymerization are in principle known to the person skilled in the art. Suitable depolymerization conditions (D1) may be chosen in wide ranges. Suitable is for example a temperature T(D1) in the range of from 100 to 350°C, preferably 150 to 350°C, more preferably 250 to 300°C. The depolymerization time t(D1) is at least 0.25 hours and may preferably be in the range of from 0.25 to 6 hours, preferably in the range of from 0.5 to 6 hours, in particular from 1 to 4 hours. The factor F(D1)=T(D1) x t(D1) is in the range of from 150 to 10000 K*h, preferably in the range of from 260 to 3700 K*h. The depolymerization may for example be carried out at a pH in the range of from 4.0 to 11 .0, more preferable in the range of from 6.0 to 8.0. It has been found that the specific conditions for the treatment according to (c) allow to achieve stepwise depolymerization yielding products which can be easily separated from the resulting mixture.According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 100 to 350°C and a depolymerization time t(D 1 ) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 150 to 350°C and a depolymerization time t(D 1 ) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the depolymerization is carried out at a pH in the range of from 4 to 11 .The process further comprises step (d). according to step (d), the filler (F1) is separated from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer.Suitable methods for separation are in principle known to the person skilled in the art. Suitable methods are for example filtration, centrifugation, or decantation. Suitable methods may also be combined depending on the nature of the filler (F1) and the polyamide based polymer or the soluble oligomers and monomers of the polyamide based polymer respectively. Step (d) is carried out at a temperature T2 which preferably is in the range of from 100 to 400°C, more preferable in the range of from 120 to 300°C, in particular in the range of from 160 to 220°C. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the separation according to step (d) is carried out at a temperature in the range of from 100 to 400°C.Particularly suitable separation methods are for example filtration steps. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the separation according to step (d) is carried out by filtration at a temperature in the range of from 100 to 400°C or by filtration or centrifugation.240855W001- 7 -It has been found that separation using filtration at a pressure in the range of from 1 to 100 bar, in particular in the range of from 20 to 60 bar, preferably using filters having a pore size in the range of from 2 to 500 m is particularly suitable for the separation according to step (d). According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the separation according to step (d) is carried out by filtration at a pressure in the range of from 5 to 60 bar and a temperature in the range of from 100 to 400°C. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the separation according to step (d) is carried out by centrifugation, sedimentation or filtration, preferably by filtration at a pressure in the range of from 5 to 60 bar and a temperature T2 in the range of from 100 to 400°C. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the filtration is carried out at a pressure in the range of from 1 to 100 bar, preferably with a differential pressure in the range of from 5 to 60 bar, more preferable in the range of from 20 to 60 bar. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the separation according to step (d) is carried out using filters having a pore size in the range of from 2 to 500 m.Step (d) may also comprise further washing steps, in particular washing with the solvent composition (SC). Depending on the nature of the insoluble components, in particular the filler (F1 ), the mixture comprising the filler (F1) and optionally further insoluble components may be subjected to further steps to recycle filler (F1) and optionally further insoluble components.According to a further embodiment, the present invention is also directed to a process as disclosed above, wherein the filler (F1) is a fibrous filler, preferably a fibrous filler selected from the group consisting of glass fibers, carbon fibers, aramid fibers, potassium titanate fibers, fibers composed of liquid-crystal polymers, metal fibers, polyester fibers, polyamide fibers, organic fibrous fillers and inorganic fibrous fillers.According to the process of the present invention, also further additives (F2) may be present in the polymeric material (PM) which may also be separated from the polymer. According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the polymeric composition (PM) comprises a further additive (F2) selected from dyes, pigments, UV absorbers, fillers, flame retardants, antistatic agents, antibacterial agent, and nucleating agents.The process according to the present invention further comprises step (e). Mixture (M-3) obtained in step (d) is cooled according to step (e) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M- 3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer. Temperature T3 typically is in the range of from 1 to 100°C. The cooling rate applied in step (e) is in the range of from 1 to 120°C / h. preferably, the cooling rate is in the range of from 10 to 100°C / h 30 to 60 °C / h. Cooling to temperature T3 typically is achieved in a time of 0.1 to 10 hours, preferably 0.5 to 6 hours Suitable method for cooling are in principle known.240855W001- 8 -According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the cooling according to step (e) is achieved using a cooling rate of 10 to 100°C per hour.According to step (f), soluble monomers of the polyamide based polymer and short chained oligomers are separated from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer. If present, also additives or fragments of additives and water soluble impurities are separated from mixture (M-4) comprising oligomers of the polyamide based polymer in step (f). Typically, step (f) is carried out at temperature T3. Temperature T3 preferably is in the range of from 1 to 100°C.Additives or fragments of additives and further water soluble components may for example be impurities which are present in the polymeric material (PM) or additives or fragments of additives from impurities of other polymeric materials which may be present in waste streams. Also water soluble monomers of polymeric impurities may be present.According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the separation according to step (f) is carried out at a temperature T3 in the range of from 1 to 100°C.Separation according to step (f) may be achieved by any suitable method, for example filtration, centrifugation or decantation.Mixture (M-4) comprising the insoluble oligomers may be purified, for example by further washing steps. It has been found that further washing and filtration steps allows to separate the oligomers from remaining impurities.The mixture (M-4) or the treated mixture (M-4) or also mixture (M-3) may also be used for the preparation of polyamides. Suitable conditions for the polymerization are in principle known and are for example disclosed in US4313870, US9534083 or in Ullmann's Encyclopedia of Industrial Chemistry, "Polyamides” Herzog, B., Kohan, M.I., Mestema- cher, S.A., Pagilagan, R.U., Redmond, K. and Sarbandi, R. (2024). Mixture (M-4) or treated mixture (M-4) may for example be used together with further monomers. Catalysts and suitable additives may be added.According to a further embodiment, the present invention is also directed to the process as disclosed above, wherein the process further comprises(g) subjecting mixture (M-3) or mixture (M-4) to polymerization conditions suitable to prepare a polyamide based polymer, obtaining a recycled polyamide.It is also possible according to the present invention to subject mixture (M-4) comprising the insoluble oligomers to a further depolymerization step. It is for example possible to expose the mixture to alkaline or acidic conditions to achieve depolymerization of the oligomers. Suitable methods and conditions for the depolymerization are in principle known to the person skilled in the art.240855W001- 9 -Suitable conditions for the depolymerization may for example include treatment with a base, preferably in an amount of from 2.0 to 3.0 equivalents of inorganic base per repeating unit, preferably 2.0 to 2.2 equivalents. Bases such as alkali metal hydroxides or earth alkali metal hydroxides, for example sodium hydroxide or potassium hydroxide may be used in a suitable solvent such as for example a mixture of water and a short-chained aliphatic alcohol, for example methanol or ethanol.In the context of the present invention, it is preferable to reuse the monomers or oligomers obtained or the dissolved polymer obtained or the isolated polymer obtained, in particular for the preparation of polyamide. According to a further aspect, the present invention is also directed to the use of mixture (M-4), obtainable or obtained by a process as disclosed above, for preparing polyamide. According to a further aspect, the present invention is also directed to the use of one or more monomers or oligomers, obtainable or obtained by a process as disclosed above, for preparing polyamide. In particular, the present invention is directed to the use of mixture (M-3) or mixture (M-4), obtainable or obtained by a process according to the invention, for preparing polyamide.Also the filler (F1) may be reused according to the present invention. According to a further aspect, the present invention is also directed to a filler, obtainable or obtained by a process according to the process as disclosed above, exhibiting one or more of the following properties: a diameter of the fibers in a range of from 5 to 35 m, preferably in the range of from 6 to 25 pm, in particular in the range of from 8 to 17 pm; an average length of the fibers in the range of from 100 to 600 pm, preferably in the range of from 200 to 500 pm, in particular in the range of from 250 to 450 pmThe length and the diameter of the fibers are determined using optical methods preferably according to the method disclosed in the examples section.Due to the specific process of the present invention the properties of the filler obtained are suitable to reuse the filler. According to the present invention, the filler obtained is suitable to be reused as a filler for the preparation of polymeric materials, such as reinforced polymeric materials, in particular reinforced polyamides. According to a further aspect, the present invention therefore is also directed to the use of the filler obtainable or obtained by a process as disclosed above, for preparing a polymeric product.According to a further aspect, the present invention is also directed to a process preferably a process as disclosed above, comprising the step: converting the monomer and / or oligomer and / or recycled polyamide obtainable by or obtained by the process as disclosed above or a chemical material obtainable by or obtained by the process as disclosed above to obtain a product.240855W001- 10 -According to a further embodiment, the present invention is also directed to a process as disclosed above, wherein the product is selected from:I) building block or monomer; or ii) polymer, preferably polymer A, polymer composition, preferably polymer composition A, or polymer product, preferably polymer product A; or ill) industrial use polymer, industrial use surfactant, descaling compound, industrial use biocide, industrial use solvent, industrial use dispersant, composition thereof or formulation thereof; or iv) agrochemical composition, agrochemical formulation auxiliary or agrochemically active ingredient; or v) active pharmaceutical ingredient or intermediate thereof, pharmaceutical excipient, animal feed additive, human food additive, dietary supplements, aroma chemical or aroma composition; or vi) aqueous polymer dispersion, preferably polyurethane or polyurethane - poly(meth)acrylate hybrid polymer dispersion, emulsion, binder for paper and fiber coatings, UV-curable acrylic polymer for hot melts and coatings polyisocyanates, hyperbranched polyester polyol, polymeric dispersant for inorganic binder compositions, unsaturated polyester polyol or 100% curable composition; or vii) cosmetic surfactant, emollient, wax, cosmetic polymer, UV filter, further cosmetic ingredient or composition or formulation thereof; or viii) polymer B, polymer composition B, coating composition, other functional composition, foil, molded body, coating or coated substrate.According to a further embodiment, the present invention is also directed to a process as disclosed above, wherein the content of the polymeric material (PM) in the polymer product is 1 weight-% or more, preferably 2 weight- % or more, more preferably 5 weight-% or more, more preferably 15 weight-% or more, more preferably 30 weight-% or more, more preferably 40 weight-% or more, more preferably 60 weight-% or more, more preferably 80 weight-% or more, more preferably 90 weight-% or more, more preferably 95 weight-% or more; and / or wherein the content of the polymeric material (PM) in the polymer product is 100 weight-% or less, preferably 95 weight-% or less, more preferably 90 weight-% or less, more preferably 50 weight-% or less, more preferably 25 weight-% or less, more preferably 10 weight-% or less; and preferably wherein the content is determined based on identity preservation and / or segregation and / or mass balance and / or book and claim chain of custody models, preferably based on mass balance, preferably the International Sustainability and Carbon Certification (ISCC) standard.The publication Prior Art Disclosure; Issue 684; paragraphs
[1000] to
[8005] ; ISSN: 2198-4786; published: February 12, 2024 will be regarded as Reference RF1, which is incorporated herein by reference in its entirety. Preferably, the product is a product as described in Reference RF1; paragraphs
[1000] to
[8005] , Preferably, the process described herein is further a process for the production of a product.240855W001- 11 -The converting step to obtain the product preferably comprises one or more step(s) as described below and can be performed by conventional methods well known to a person skilled in the art. The converting step preferably comprises one or more step(s) selected from: recycling, preferably depolymerizing, gasifying, pyrolyzing, and / or steam cracking; and / or purifying, preferably crystallizing, (solvent) extracting, distilling, evaporating, hydrotreating, absorbing, adsorbing and / or subjecting to ion exchanger; and / or assembling, preferably foaming, synthesizing, chemical conversion, chemically transforming, polymerizing and / or compounding; and / or forming, preferably foaming, extruding and / or molding; and / or finishing, preferably coating and / or smoothing.In addition, the one or more step(s) are described in detail in Reference RF1 ; paragraphs
[1000] to
[8005] ,The term "building block”, as used herein, comprises compounds, which are in a gaseous or liquid state under standard conditions of 0°C and 0.1 MPa. Building blocks are typically used in chemical industry to form secondary products, which provide a higher structural complexity and / or higher molecular weight than the building block on which the secondary product is based. The building block is preferably selected from the group consisting of hydrogen, carbon monoxide, carbon dioxid, ethylene oxide, ethylene glycols, syngas comprising a mixture of hydrogen and carbon monoxide, alkanes, alkenes, alkynes and aromatic compounds. The alkanes, alkenes, alkynes and aromatic compounds comprise in particular 1 to 12 carbon atoms, respectively.The term "monomer”, as used herein, comprises molecules, which can react with each other to form polymer chains by polymerization. The monomer is preferably selected from the group consisting of (meth)acrylic acid, salts of (meth)acrylic acid; in particular sodium, potassium and zinc salts; (meth)acrolein and (meth)acrylates. (Meth)acry- lates comprising 1 to 22 carbon atoms are preferred, in particular comprising 1 to 8 carbon atoms. The terms (meth)acrylic acid, (meth)acrolein or (meth)acrylate relate to acrylic acid, acrolein or acrylate and also to methacrylic acid, methacrolein or methacrylate, where applicable. Further, the monomer can be selected from hexamethylenediamine (HMD) and adipic acid.The building block can further be an intermediate compound. The term "intermediate compound”, as used herein, comprises organic reagents, which are applied for formation of compounds with higher molecular complexity. The intermediate compound can be selected for example from the group consisting of phosgene, polyisocyanates and propylene oxide. The polyisocyanates are in particular aromatic di- and polyisocyanates, preferably toluene diisocyanate (TDI) and / or diphenylmethane diisocyanate (MDI).The building block and the monomer and typical converting step(s) to obtain the building block or monomer are described in more detail in paragraphs
[1000] to
[1012] of Reference RF1.240855W001- 12 -The term "polymer A”, as used herein, comprises thermoplastic, e.g., polyamide or thermoplastic polyurethane, thermoset, e.g., polyurethane, elastomer, e.g., polybutadiene, or a copolymer or a mixture thereof and is defined in more detail in paragraphs
[2001] to
[2007] of Reference RF1.The term "polymer composition A”, as used herein, comprises all compositions comprising a polymer as described above and one or more additive(s), e.g. reinforcement, colorant, modifier and / or flame retardant, and is defined in more detail in paragraph
[2008] of Reference RF1.The term "polymer product A”, as used herein, comprises any product comprising the polymer A and / or polymer composition A as described above and is defined in more detail in paragraphs
[2009] and
[2010] of Reference RF1. The step(s) to obtain the polymer, preferably polymer A, polymer composition, preferably polymer composition A or polymer product, preferably polymer product A is / are described in more detail in paragraph
[2011] of Reference RF1 .The term "industrial use polymer”, as used herein, comprises rheology, polycarboxylate, alkoxylated polyalkylenamine, alkoxylated polyalkylenimine, polyether-based, dye inhibition and soil release cleaning polymers defined in more detail in paragraphs
[3035] to
[3044] of Reference RF1. The term "industrial use surfactant”, as used herein, comprises non-ionic, anionic and amphoteric industrial use surfactants defined in more detail in paragraphs
[3008] to
[3034] of Reference RF1. The term "industrial use descaling compound”, as used herein, comprises non-phosphate based builders (NPB) and phosphonates (CoP) described in more detail in paragraphs
[3001] to
[3005] of Reference RF1. The term "industrial use biocide”, as used herein, refers to a chemical compound that kills microorganisms or inhibits their growth or reproduction defined in more detail in paragraphs
[3006] to
[3007] of Reference RF1. The term "industrial use solvent”, as used herein, comprises alkyl amides, alkyl lactamides, alkyl esters, lactate esters, alkyl diester, cyclic alkyl diester, cyclic carbonates, aromatic aldehydes and aromatic esters defined in more detail in paragraphs
[3045] to
[3055] of Reference RF1. The term "industrial use dispersant”, as used herein, comprises anionic and non-ionic industrial use dispersants defined in more detail in paragraphs
[3056] to
[3058] of Reference RF1. The term "composition and / or formulation thereof' with reference to the industrial use polymers, industrial use surfactants, descaling compounds and / or industrial use biocides refers to industrial use compositions and / or institutional use products and / or fabric and home care products and / or personal care products defined in more detail in paragraph
[3059] of Reference RF1. The converting step(s) to obtain the industrial use polymer, industrial use surfactant, descaling compound and / or industrial use biocide are defined in more detail in paragraph
[3060] of Reference RF1 . The converting steps to obtain the industrial use composition or formulation of the industrial use polymer, industrial use surfactant, descaling compound and / or industrial use biocide are defined in more detail in paragraph
[3061] of Reference RF1.The term "agrochemical composition”, as used herein, typically relates to a composition comprising an agrochemi- cally active ingredient and at least one agrochemical formulation auxiliary. Examples of agrochemical compositions, active ingredients and auxiliaries are described in more detail in Reference RF1 , paragraph
[4001] ,240855W001- 13 -The agrochemical composition may take the form of any customary formulation. The agrochemical compositions are prepared in a known manner, e.g. described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005. The converting step(s) to obtain the agrochemically active ingredients and auxiliaries may be conducted in analogy to the production step(s) of their analogues that are based on petrochemicals or other precursors that are not gained by recycling processes. In addition, conversion to compounds mentioned in sections "Polymer” and "Cosmetic surfactant, emollient, wax, cosmetic polymer, UV filter, further cosmetic ingredient or compositions or formulations thereof” may be performed as described in these sections as well as the respective paragraphs in Reference RF1.The term active pharmaceutical ingredients and / or intermediates thereof, as used herein, comprises substances that provide pharmacological activity or other direct effect in the diagnosis, cure, mitigation, treatment, or prevention of disease, or to affect the structure or any function of the body. Intermediates thereof are isolated products that are generated during a multi-step route of synthesis of an active pharmaceutical ingredient. The term pharmaceutical excipients, as used herein, comprises compounds or compound mixtures used in compositions for various pharmaceutical applications, which are not substantially pharmaceutically active on itself. Active pharmaceutical ingredients and / or intermediates thereof and pharmaceutical excipients are defined in more detail in paragraph
[5001] of Reference RF1.The converting step(s) to obtain the active pharmaceutical ingredients and / or intermediates thereof and pharmaceutical excipients may comprise one or more synthesis steps and can be performed by conventional synthesis and techniques well known to a person skilled in the art.The terms animal feed additives, human food additives, dietary supplements, as used herein, comprises Vitamins, Pro-Vitamins and active metabolites thereof including intermediates and precursors, especially Vitamin A, B, E, D, K and esters thereof, like acetate, propionate, palmitate esters or alcohols thereof like retinol or salts thereof and any combinations thereof; Tetraterpenes, especially isoprenoids like carotenoids and xanthophylls including their intermediates and precursors as well as mixtures and derivates thereof, especially beta carotene, Canthaxanthin, Citranax- anthin, Astaxanthin, Zeaxanthin, Lutein, Lycopene, Apocarotenoids, and any combinations thereof; organic acids, especially formic acid, propionic acid and salts thereof, such as sodium, calcium or ammonium salts, and any combinations thereof, such as but not limited to mixtures of formic acid and sodium formiate, propionic acid and ammonium propionate, formic acid and propionic acid, formic acid and sodium formiate and propionic acid, propionic acid and sodium propionate and formic acid and sodium formiate; glycerides of carboxylic acids and short and medium chain fatty acids, conjugated linoleic acids, such as omega-6 fatty acid (C18:2) methyl ester and 1 ,2-propandiol and beverage stabilizers, such as polyvinylpyrrolidone-polymer or poly-vinylimidazole / polyvinylpyrrolidone-copolymer. Animal feed additives, human food additives and dietary supplements are defined in more detail in paragraph
[5002] of Reference RF1.240855W001- 14 -The converting step(s) to obtain the animal feed additives, human food additives, dietary supplements may comprise one or more synthesis steps and can be performed by conventional synthesis and techniques well known to a person skilled in the art.The terms aroma chemical and aroma composition as used herein, comprise a volatile organic substance with a molecular weight between 70-250 g / mol comprising a functional group with a carbon skeleton of C5-C16 carbon atoms comprising linear, branched, cyclic, for example with a ring size of C5-C18, bicyclic or tricyclic aliphatic chains and but not necessarily one or more unsaturated structural elements like double bonds, triple bonds, aromatics or heteroaromatics and preferably the one or more additional functional groups are selected from alcohol, ether, ester, ketone, aldehyde, acetal, carboxylic acid, nitrile, thiol, amine. In one aspect, the aroma chemical is a terpene-based aroma chemical, for example selected from monoterpenes and monoterpenoids, sesquiterpenes and sesquiterpe- noids, diterpenes, triterpenes or tetraterpenes. Aroma chemicals can be combined with further aroma chemicals to give an aroma composition. Aroma chemicals and aroma compositions are defined in more detail in paragraph
[5003] of Reference RF1 .The converting step(s) to obtain the aroma chemical and aroma composition may comprise one or more synthesis steps and can be performed by conventional synthesis and techniques well known to a person skilled in the art.The term "aqueous polymer dispersion”, as used herein, comprises aqueous composition(s) comprising dispersed polymer(s) and is defined in more detail in the section
[6001] entitled "aqueous polymer dispersion” of Reference RF1. The dispersed polymer(s) may be selected from acrylic emulsion polymer(s), styrene acrylic emulsion poly- mer(s), styrene butadiene dispersion(s), aqueous dispersion(s) comprising composite particles, acrylate alkyd hybrid dispersion(s), polyurethane(s) (including UV-curable polyurethanes) and polyurethane - poly(meth)acrylate hybrid polymer(s). The term "emulsion polymer”, as used herein, comprises polymer(s) made by free-radical emulsion polymerization. Aqueous polyurethane dispersion(s) are defined in more detail in the section
[6002] entitled "Polyurethane dispersions” of Reference RF1. UV-curable polyurethane(s) is / are defined in more detail in the section
[6017] of Reference RF1. Polyurethane - poly(meth)acrylate hybrid polymer(s) is / are defined in more detail in the section
[6016] of Reference RF1 .The term "polymeric dispersant”, as used herein, comprises preferably polymer(s) comprising polyether side chain, in particular polycarboxylate ether polymer(s) and polycondensation product(s) defined in more detail in paragraph
[6020] entitled "Polymeric dispersant” of Reference RF1.The converting (polymerization) step(s) to obtain the aqueous polymer dispersion(s) comprising emulsion polymer(s) is / are defined in more detail in the section
[6003] entitled "Emulsion polymerization” of Reference RF1.The converting (polymerization) step(s) to obtain the aqueous polyurethane dispersion(s) is / are defined in more detail in the section
[6014] entitled "Process for the preparation of aqueous polyurethane dispersions” and section [6017)] entitled "Aqueous UV-curable polyurethane dispersions, their preparation and use and compositions containing them” of Reference RF1 .240855W001- 15 -Composition(s) and uses of aqueous polymer dispersion(s) and of polymeric dispersant(s) are defined in more detail in the following sections of Reference RF1 : section
[6004] entitled "Uses of aqueous polymer dispersions”, section
[6005] entitled "Binders for architectural and construction coatings” section
[6006] entitled "Binders for paper coating” section
[6007] entitled "Binders for fiber bonding” section
[6008] entitled "Adhesive polymers and adhesive compositions” section
[6015] entitled "Aqueous polyurethane dispersions suitable for use in coating compositions” section
[6016] entitled "Aqueous polyurethane - poly(meth)acrylate hybride polymer dispersions suitable for use in coating compositions” section
[6017] entitled "Aqueous UV-curable polyurethane dispersions, their preparation and use and compositions containing them” section
[6018] entitled "Inorganic binder compositions comprising polymeric dispersants and their use”
[6019] 100% curable coating compositionsUV-crosslinkable poly(meth)acrylate(s) and its / their uses are defined in more detail in section
[6009] entitled "UV- crosslinkable poly(meth)acrylates for use in UV-curable solvent-free hotmelt adhesives and their use for making pressure-sensitive self-adhesive articles” of Reference RF1.Polyisocyanate(s), composition(s) comprising them and their uses are defined in more detail in section
[6010] entitled "Polyisocyanates” of Reference RF1.Hyperbranched polyester polyol(s) and its / their uses are defined in more detail in section
[6011] entitled "Organic solvent based hyperbranched polyester polyols suitable for use in coating compositions” of Reference RF1. The converting step(s) to obtain the hyperbranched polyester polyols is / are defined in more detail in the section
[6012] entitled "Preparation of organic solvent based hyperbranched polyester polyols” of Reference RF1 . Coating compositions) comprising hyperbranched polyester polyol(s), polyisocyanate(s) and additive(s) and substrate(s) coated therewith are defined in more detail in section
[6013] entitled "Organic solvent based two component coating compositions comprising hyperbranched polyester polyols and polyisocyanates” of Reference RF1.Unsaturated polyester polyol(s), solvent-based coating composition(s) comprising said unsaturated polyester pol- yol(s) and substrate(s) for coating with said coating composition(s) are defined in more detail in section
[6018] entitled "Organic solvent based coating composition comprising unsaturated polyester polyols” of Reference RF1. 100% curable coating composition(s) is / are defined in more detail in section
[6019] of Reference RF1.Polymeric dispersant(s) for inorganic binder compositions is / are defined in more detail in section
[6020] of Reference RF1. The inorganic binder composition(s) comprising the polymeric dispersants and their use are defined in more detail in section
[6021] of Reference RF1. The converting step(s) to obtain the polymeric dispersant(s) are defined in more detail in section
[6020] of Reference RF1. The term "inorganic binder composition” comprising the polymeric240855W001- 16 - dispersant(s), as used herein, comprises preferably in particular hydraulically setting compositions and compositions comprising calcium sulfate and is defined in more detail in section
[6021] of Reference RF1 entitled "Inorganic binder compositions comprising the polymeric dispersant and their use”. Specific building material formulation(s) comprising polymeric dispersant(s) or building product(s) produced by a building material formulation comprising a polymeric dispersant are disclosed in more detail in section
[6021] of Reference RF1.The term "cosmetic surfactant”, as used herein, comprises non-ionic, anionic, cationic and amphoteric surfactants and is defined in more detail in paragraph
[7002] of Reference RF1. The term "emollient”, as used herein, refers to a chemical compound used for protecting, moisturizing, and / or lubricating the skin and is defined in more detail in paragraph
[7003] of Reference RF1. The term "wax”, as used herein, comprises pearlizers and opacifiers and is defined in more detail in paragraph
[7004] of Reference RF1. The term "cosmetic polymer”, as used herein, comprises any polymer that can be used as an ingredient in a cosmetic formulation and is defined in more detail in paragraph
[7005] of Reference RF1. The term "UV filter”, as used herein, refers to a chemical compound that blocks or absorbs ultraviolet light and is defined in more detail in paragraph
[7006] of Reference RF1 . The term "further cosmetic ingredient”, as used herein, comprises any ingredient suitable for making a cosmetic formulation. Several sources disclose cosmetically acceptable ingredients. E. g. the database Cosing on the internet pages of the European Commission discloses cosmetic ingredients and the International Cosmetic Ingredient Dictionary and Handbook, edited by the Personal Care Products Council (PCPC), discloses cosmetic ingredients. The term "composition and / or formulation thereof' with reference to the cosmetic surfactant, emollient, wax, cosmetic polymer, UV filter and / or further cosmetic ingredient refers to personal care and / or cosmetic compositions or formulations defined in more detail in paragraph
[7007] of Reference RF1. The converting step(s) to obtain the cosmetic surfactant, emollient, wax, cosmetic polymer, UV filter or further cosmetic ingredient is / are defined in more detail in paragraph
[7008] of Reference RF1 .The terms "polymer B”, "polymer composition B”, "coating composition”, "other functional composition”, "foil”, "molded body”, "coating” and "coated substrate” are well known to the person skilled in the art and are defined in more detail from paragraph
[8000] to
[8005] of Reference RF1.The present invention is further illustrated by the following set of embodiments and combinations of embodiments resulting from the dependencies and back-references as indicated. In particular, it is noted that in each instance where a range of embodiments is mentioned, for example in the context of a term such as "The process of any one of embodiments 1 to 3", every embodiment in this range is meant to be explicitly disclosed for the skilled person, i.e. the wording of this term is to be understood by the skilled person as being synonymous to "The process of any one of embodiments 1, 2 and 3". Further, it is explicitly noted that the following set of embodiments represents a suitably structured part of the general description directed to preferred aspects of the present invention, and, thus, suitably supports, but does not represent the claims of the present invention.240855W001- 17 -1 . Process for treating a polymeric material (PM) comprising a polyamide based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D 1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer,(f) separating soluble monomers of the polyamide based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer.2. The process according to embodiment 1 , wherein the polyamide based polymer is a polyamide 66 based polymer.3. Process for treating a polymeric material (PM) comprising a polyamide based polymer and at least one insoluble filler (F1), wherein the polyamide based polymer is a polyamide 66 based polymer, the process comprising(a) providing a polymeric material (PM) comprising a polyamide based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);240855W001- 18 -(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D1 ) and a depolymerization time t(D1 ) obtaining a mixture (M-1 ) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer,(f) separating soluble monomers of the polyamide based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer.4. The process according to any one of embodiments 1 to 3, wherein the cooling according to step (e) is achieved using a cooling rate of 10 to 100°C per hour.5. Process for treating a polymeric material (PM) comprising a polyamide based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D 1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer;240855W001- 19 -(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 10 to 100°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer,(f) separating soluble monomers of the polyamide based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer.6. The process according to any one of embodiments 1 to 5, wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 150 to 350°C and a depolymerization time t(D1) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.7. The process according to any one of embodiments 1 to 6, wherein the depolymerization is carried out at a pH in the range of from 4 to 11.8. The process according to any one of embodiments 1 to 7, wherein mixture (M-0) comprises metal hydroxides, in particular sodium hydroxide and potassium hydroxide, in an amount of less than 5 % by weight.9. The process according to any one of embodiments 1 to 8, wherein mixture (M-0) comprises acids such as sulfuric acid and hydrochloric acid, in an amount of less than 5 % by weight10. The process according to any one of embodiments 1 to 9, wherein the separation according to step (d) is carried out at a temperature in the range of from 100 to 400°C.11 . The process according to any one of embodiments 1 to 10, wherein the separation according to step (d) is carried out by centrifugation, sedimentation or filtration, preferably by filtration at a pressure in the range of from 5 to 60 bar and a temperature T2 in the range of from 100 to 400°C.12. The process according to any one of embodiments 1 to 11 , wherein the separation according to step (f) is carried out at a temperature T3 in the range of from 1 to 100°C.13. Process for treating a polymeric material (PM) comprising a polyamide based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);240855W001- 20 -(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D 1) and a depolymerization time t(D 1 ) obtaining a mixture (M-1 ) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer,(f) separating at a temperature T3 in the range of from 1 to 100°C soluble monomers of the polyamide based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer.14. The process according to any one of embodiments 1 to 13, wherein the process further comprises(g) subjecting mixture (M-3) or mixture (M-4) to polymerization conditions suitable to prepare a polyamide based polymer, obtaining a recycled polyamide.15. Process for treating a polymeric material (PM) comprising a polyamide based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D 1) and a depolymerization time t(D 1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1);240855W001- 21 -(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer,(f) separating soluble monomers of the polyamide based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer,(g) subjecting mixture (M-3) or mixture (M-4) to polymerization conditions suitable to prepare a polyamide based polymer, obtaining a recycled polyamide.16. Process for treating a polymeric material (PM) comprising a polyamide based polymer and at least one insoluble filler (F1), wherein the polyamide based polymer is a polyamide 66 based polymer, the process comprising(a) providing a polymeric material (PM) comprising a polyamide based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide based polymer (D1) comprising a depolymerization temperature T(D 1 ) and a depolymerization time t(D1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide based polymer,240855W001- 22 -(f) separating soluble monomers of the polyamide based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide based polymer,(g) subjecting mixture (M-3) or mixture (M-4) to polymerization conditions suitable to prepare a polyamide based polymer, obtaining a recycled polyamide.17. The process according to any one of embodiments 1 to 16, wherein the insoluble compound (F1) is selected from the group consisting of glass fibers.18. The process according to any one of embodiments 1 to 17, wherein the polymeric composition (PM) comprises a further additive (F2) selected from dyes, pigments, UV absorbers, fillers, flame retardants, antistatic agents, antibacterial agent, and nucleating agents.19. Use of mixture (M-3) or mixture (M-4), obtainable or obtained by a process according to any one of embodiments 1 to 18, for preparing polyamide.20. Process, preferably according to any one of the embodiments 1 to 18, comprising the step: converting the monomer and / or oligomer and / or recycled polyamide obtainable by or obtained by the process according to any one of embodiments 1 to 18 or a chemical material obtainable by or obtained by the process according to any one of embodiments 1 to 18 to obtain a product.21 . Process according to embodiment 20, wherein the product is selected from:I) building block or monomer; orII) polymer, preferably polymer A, polymer composition, preferably polymer composition A, or polymer product, preferably polymer product A; or ill) industrial use polymer, industrial use surfactant, descaling compound, industrial use biocide, industrial use solvent, industrial use dispersant, composition thereof or formulation thereof; or iv) agrochemical composition, agrochemical formulation auxiliary or agrochemically active ingredient; or v) active pharmaceutical ingredient or intermediate thereof, pharmaceutical excipient, animal feed additive, human food additive, dietary supplements, aroma chemical or aroma composition; or vi) aqueous polymer dispersion, preferably polyurethane or polyurethane - poly (meth)acry late hybrid polymer dispersion, emulsion, binder for paper and fiber coatings, UV-curable acrylic polymer for hot melts and coatings polyisocyanates, hyperbranched polyester polyol, polymeric dispersant for inorganic binder compositions, unsaturated polyester polyol or 100% curable composition; or240855W001- 23 - vii) cosmetic surfactant, emollient, wax, cosmetic polymer, UV filter, further cosmetic ingredient or composition or formulation thereof; or viii) polymer B, polymer composition B, coating composition, other functional composition, foil, molded body, coating or coated substrate22. Process according to any one of embodiments 20 or 21 , wherein the content of the polymeric material (PM) in the product is 1 weight-% or more, preferably 2 weight- % or more, more preferably 5 weight-% or more, more preferably 15 weight-% or more, more preferably 30 weight-% or more, more preferably 40 weight-% or more, more preferably 60 weight-% or more, more preferably 80 weight-% or more, more preferably 90 weight-% or more, more preferably 95 weight-% or more; and / or wherein the content of the polymeric material (PM) in the polymer product is 100 weight-% or less, preferably 95 weight-% or less, more preferably 90 weight-% or less, more preferably 50 weight-% or less, more preferably 25 weight-% or less, more preferably 10 weight-% or less; and preferably wherein the content is determined based on identity preservation and / or segregation and / or mass balance and / or book and embodiment chain of custody models, preferably based on mass balance, preferably the International Sustainability and Carbon Certification (ISCC) standard.23. Process for treating a polymeric material (PM) comprising a polyamide 66 based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide 66 based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide 66 based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide 66 based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide 66 based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide 66 based polymer,240855W001- 24 -(f) separating soluble monomers of the polyamide 66 based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide 66 based polymer.24. The process according to embodiment 23, wherein the cooling according to step (e) is achieved using a cooling rate of 10 to 100°C per hour.25. The process according to any one of embodiments 23 or 24, wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 100 to 350°C and a depolymerization time t(D1) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.26. The process according to any one of embodiments 23 or 24, wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 150 to 350°C and a depolymerization time t(D1) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.27. Process for treating a polymeric material (PM) comprising a polyamide 66 based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide 66 based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide 66 based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide 66 based polymer, and the filler (F1), wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 100 to 350°C and a depolymerization time t(D1) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.;(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide 66 based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide 66 based polymer,240855W001- 25 -(f) separating soluble monomers of the polyamide 66 based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide 66 based polymer.28. Process for treating a polymeric material (PM) comprising a polyamide 66 based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide 66 based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide 66 based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide 66 based polymer, and the filler (F1), wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 150 to 350°C and a depolymerization time t(D1) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.;(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide 66 based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide 66 based polymer,(f) separating soluble monomers of the polyamide 66 based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide 66 based polymer.29. The process according to embodiment 27 or 28, wherein the cooling according to step (e) is achieved using a cooling rate of 10 to 100°C per hour.30. The process according to any one of embodiments 23 to 29, wherein the depolymerization is carried out at a pH in the range of from 4 to 11 .240855W001- 26 -31 . The process according to any one of embodiments 23 to 30, wherein mixture (M-0) comprises metal hydroxides, in particular sodium hydroxide and potassium hydroxide, in an amount of less than 5 % by weight.32. The process according to any one of embodiments 23 to 31 , wherein mixture (M-0) comprises acids such as sulfuric acid and hydrochloric acid, in an amount of less than 5 % by weight.33. The process according to any one of embodiments 23 to 32, wherein the separation according to step (d) is carried out at a temperature in the range of from 100 to 400°C.34. Process for treating a polymeric material (PM) comprising a polyamide 66 based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide 66 based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide 66 based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide 66 based polymer, and the filler (F1), wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 100 to 350°C and a depolymerization time t(D1) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.;(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide 66 based polymer, wherein the separation according to step (d) is carried out at a temperature in the range of from 100 to 400°C;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide 66 based polymer,(f) separating soluble monomers of the polyamide 66 based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide 66 based polymer.240855W001- 27 -35. Process for treating a polymeric material (PM) comprising a polyamide 66 based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide 66 based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide 66 based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide 66 based polymer, and the filler (F1), wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 150 to 350°C and a depolymerization time t(D1) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.;(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide 66 based polymer, wherein the separation according to step (d) is carried out at a temperature in the range of from 100 to 400°C;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide 66 based polymer,(f) separating soluble monomers of the polyamide 66 based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide 66 based polymer.36. The process according to embodiment 34 or 35, wherein the cooling according to step (e) is achieved using a cooling rate of 10 to 100°C per hour.37. The process according to any one of embodiments 34 to 36, wherein the depolymerization is carried out at a pH in the range of from 4 to 11 .38. The process according to any one of embodiments 34 to 37, wherein mixture (M-0) comprises metal hydroxides, in particular sodium hydroxide and potassium hydroxide, in an amount of less than 5 % by weight.240855W001- 28 -39. The process according to any one of embodiments 34 to 38, wherein mixture (M-0) comprises acids such as sulfuric acid and hydrochloric acid, in an amount of less than 5 % by weight.40. The process according to any one of embodiments 23 to 39, wherein the separation according to step (d) is carried out by centrifugation, sedimentation or filtration, preferably by filtration at a pressure in the range of from 5 to 60 bar and a temperature T2 in the range of from 100 to 400°C.41 . The process according to any one of embodiments 23 to 40, wherein the separation according to step (f) is carried out at a temperature T3 in the range of from 1 to 100°C.42. The process according to any one of embodiments 23 to 41 , wherein the process further comprises(g) subjecting mixture (M-3) or mixture (M-4) to polymerization conditions suitable to prepare a polyamide based polymer, obtaining a recycled polyamide.43. The process according to any one of embodiments 23 to 42, wherein the insoluble compound (F1 ) is selected from the group consisting of glass fibers.44. The process according to any one of embodiments 23 to 43, wherein the polymeric composition (PM) comprises a further additive (F2) selected from dyes, pigments, UV absorbers, fillers, flame retardants, antistatic agents, antibacterial agent, and nucleating agents.45. Use of mixture (M-3) or mixture (M-4), obtainable or obtained by a process according to any one of embodiments 23 to 44, for preparing polyamide.46. Process, preferably according to any one of the embodiments 23 to 44, comprising the step: converting the monomer and / or oligomer and / or recycled polyamide obtainable by or obtained by the process according to any one of embodiments 23 to 44 or a chemical material obtainable by or obtained by the process according to any one of embodiments 23 to 44 to obtain a product.47. Process according to embodiment 46, wherein the product is selected from:I) building block or monomer; or ii) polymer, preferably polymer A, polymer composition, preferably polymer composition A, or polymer product, preferably polymer product A; or ill) industrial use polymer, industrial use surfactant, descaling compound, industrial use biocide, industrial use solvent, industrial use dispersant, composition thereof or formulation thereof; or240855W001- 29 - iv) agrochemical composition, agrochemical formulation auxiliary or agrochemically active ingredient; or v) active pharmaceutical ingredient or intermediate thereof, pharmaceutical excipient, animal feed additive, human food additive, dietary supplements, aroma chemical or aroma composition; or vi) aqueous polymer dispersion, preferably polyurethane or polyurethane - poly(meth)acrylate hybrid polymer dispersion, emulsion, binder for paper and fiber coatings, UV-curable acrylic polymer for hot melts and coatings polyisocyanates, hyperbranched polyester polyol, polymeric dispersant for inorganic binder compositions, unsaturated polyester polyol or 100% curable composition; or vii) cosmetic surfactant, emollient, wax, cosmetic polymer, UV filter, further cosmetic ingredient or composition or formulation thereof; or viii) polymer B, polymer composition B, coating composition, other functional composition, foil, molded body, coating or coated substrate.48. Process according to any one of embodiments 46 or 47, wherein the content of the polymeric material (PM) in the product is 1 weight-% or more, preferably 2 weight- % or more, more preferably 5 weight-% or more, more preferably 15 weight-% or more, more preferably 30 weight-% or more, more preferably 40 weight-% or more, more preferably 60 weight-% or more, more preferably 80 weight-% or more, more preferably 90 weight-% or more, more preferably 95 weight-% or more; and / or wherein the content of the polymeric material (PM) in the polymer product is 100 weight-% or less, preferably 95 weight-% or less, more preferably 90 weight-% or less, more preferably 50 weight-% or less, more preferably 25 weight-% or less, more preferably 10 weight-% or less; and preferably wherein the content is determined based on identity preservation and / or segregation and / or mass balance and / or book and embodiment chain of custody models, preferably based on mass balance, preferably the International Sustainability and Carbon Certification (ISCC) standard.The present invention is further explained by the following examples.ExamplesIn a suitable 250 ml autoclave, 60 g PA66 composite material was added (containing 42 g of PA66 and 18 g of glass fibers). 115 g of water was added and the mixture was heated to 250°C while stirring. A pressure of 37 bar was achieved. The reaction mixture was kept at this temperature for 4 hours and stirred. The solution of PA 66 oligomers was then separated from the glass fibers by a frit by forcing the solution through the frit at 250°C into a second autoclave heated to 250°C. The glass fibers were obtained as a residue after further drying in a vacuum as a fluffy residue (18 g). The filtrate was slowly cooled to room temperature within about 4 hours. The yield was 150 g of a white solid aqueous suspension. The white residue was filtered off with a pressure filter nozzle at room temperature. Therefore, 3 bar of nitrogen was applied during filtration. The yield was 67 g of a white solid (55% solids content), as240855W001- 30 - well as 68 g of a mother liquor that was evaporated on the rotary evaporator. 5 g of a white solid were obtained from the mother liquor.The white solid obtained from the mother liquor can be dried and then used as feedstock in a gasification. The glass fibers can either be used directly or after workup, e.g. heating and sizing, in a PA66 polymer compound.Literature citedW02024008847 US5430068US4313870US9534083Ullmann's Encyclopedia of Industrial Chemistry, "Polyamides” Herzog, B., Kohan, M.I., Mestemacher, S.A., Pagilagan, R.U., Redmond, K. and Sarbandi, R. (2024).
Claims
240855W001- 31 -Claims1 . Process for treating a polymeric material (PM) comprising a polyamide 66 based polymer and at least one insoluble filler (F1), the process comprising(a) providing a polymeric material (PM) comprising a polyamide 66 based polymer and at least one filler (F1) and a solvent composition (SC) comprising water;(b) preparing a mixture (M-0) from the polymeric material (PM) and the solvent composition (SC);(c) subjecting mixture (M-0) to conditions for at least partially depolymerizing the polyamide 66 based polymer (D1) comprising a depolymerization temperature T(D1) and a depolymerization time t(D1) obtaining a mixture (M-1) comprising the solvent composition (SC), soluble oligomers and optionally monomers of the polyamide 66 based polymer, and the filler (F1);(d) separating the filler (F1) from mixture (M-1) at a temperature T2 obtaining mixture (M-2) comprising the filler (F1), and mixture (M-3) comprising the solvent composition (SC) and soluble oligomers and optionally monomers of the polyamide 66 based polymer;(e) cooling mixture (M-3) to a temperature T3 using a cooling rate of 1 to 120°C per hour to obtain a mixture (M-3*) comprising the solvent composition (SC), and insoluble oligomers and optionally soluble monomers of the polyamide 66 based polymer,(f) separating soluble monomers of the polyamide 66 based polymer and short chained oligomers and optionally further water soluble components from mixture (M-3*) obtaining mixture (M-4) comprising oligomers of the polyamide 66 based polymer.
2. The process according to claim 1 , wherein the cooling according to step (e) is achieved using a cooling rate of 10 to 100°C per hour.
3. The process according to any one of claims 1 or 2, wherein the depolymerization is carried out at a depolymerization temperature T(D1) in the range of from 100 to 350°C and a depolymerization time t(D1) of at least 0.25 hours, preferably in the range of from 0.25 to 6 hours.
4. The process according to any one of claims 1 to 3, wherein the depolymerization is carried out at a pH in the range of from 4 to 11 .240855W001- 32 -5. The process according to any one of claims 1 to 4, wherein mixture (M-0) comprises metal hydroxides, in particular sodium hydroxide and potassium hydroxide, in an amount of less than 5 % by weight.
6. The process according to any one of claims 1 to 5, wherein mixture (M-0) comprises acids such as sulfuric acid and hydrochloric acid, in an amount of less than 5 % by weight.
7. The process according to any one of claims 1 to 6, wherein the separation according to step (d) is carried out at a temperature in the range of from 100 to 400°C and / or wherein the separation according to step (d) is carried out by centrifugation, sedimentation or filtration, preferably by filtration at a pressure in the range of from 5 to 60 bar and a temperature T2 in the range of from 100 to 400°C.
8. The process according to any one of claims 1 to 7, wherein the separation according to step (f) is carried out at a temperature T3 in the range of from 1 to 100°C.
9. The process according to any one of claims 1 to 8, wherein the process further comprises(g) subjecting mixture (M-3) or mixture (M-4) to polymerization conditions suitable to prepare a polyamide based polymer, obtaining a recycled polyamide.
10. The process according to any one of claims 1 to 9, wherein the insoluble compound (F1) is selected from the group consisting of glass fibers.11 . The process according to any one of claims 1 to 10, wherein the polymeric composition (PM) comprises a further additive (F2) selected from dyes, pigments, UV absorbers, fillers, flame retardants, antistatic agents, antibacterial agent, and nucleating agents.
12. Use of mixture (M-3) or mixture (M-4), obtainable or obtained by a process according to any one of claims 1 to 11, for preparing polyamide.
13. Process, preferably according to any one of the claims 1 to 11, comprising the step: converting the monomer and / or oligomer and / or recycled polyamide obtainable by or obtained by the process according to any one of claims 1 to 11 or a chemical material obtainable by or obtained by the process according to any one of claims 1 to 11 to obtain a product.
14. Process according to claim 13, wherein the product is selected from:I) building block or monomer; or240855W001- 33 - ii) polymer, preferably polymer A, polymer composition, preferably polymer composition A, or polymer product, preferably polymer product A; or ill) industrial use polymer, industrial use surfactant, descaling compound, industrial use biocide, industrial use solvent, industrial use dispersant, composition thereof or formulation thereof; or iv) agrochemical composition, agrochemical formulation auxiliary or agrochemically active ingredient; or v) active pharmaceutical ingredient or intermediate thereof, pharmaceutical excipient, animal feed additive, human food additive, dietary supplements, aroma chemical or aroma composition; or vi) aqueous polymer dispersion, preferably polyurethane or polyurethane - poly(meth)acrylate hybrid polymer dispersion, emulsion, binder for paper and fiber coatings, UV-curable acrylic polymer for hot melts and coatings polyisocyanates, hyperbranched polyester polyol, polymeric dispersant for inorganic binder compositions, unsaturated polyester polyol or 100% curable composition; or vii) cosmetic surfactant, emollient, wax, cosmetic polymer, UV filter, further cosmetic ingredient or composition or formulation thereof; or viii) polymer B, polymer composition B, coating composition, other functional composition, foil, molded body, coating or coated substrate.
15. Process according to any one of claims 13 or 13, wherein the content of the polymeric material (PM) in the product is 1 weight-% or more, preferably 2 weight- % or more, more preferably 5 weight-% or more, more preferably 15 weight-% or more, more preferably 30 weight-% or more, more preferably 40 weight-% or more, more preferably 60 weight-% or more, more preferably 80 weight-% or more, more preferably 90 weight-% or more, more preferably 95 weight-% or more; and / or wherein the content of the polymeric material (PM) in the polymer product is 100 weight-% or less, preferably 95 weight-% or less, more preferably 90 weight-% or less, more preferably 50 weight-% or less, more preferably 25 weight-% or less, more preferably 10 weight-% or less; and preferably wherein the content is determined based on identity preservation and / or segregation and / or mass balance and / or book and claim chain of custody models, preferably based on mass balance, preferably the International Sustainability and Carbon Certification (ISCC) standard.