Methods for the preparation of alkynes

A multistep process for synthesizing alkynes using metals and haloalkanes in controlled reaction conditions addresses the inefficiencies of conventional methods, achieving high yields and recyclability of reactants.

WO2026128668A1PCT designated stage Publication Date: 2026-06-18CHEVRON PHILLIPS CHEMICAL COMPANY LP

Patent Information

Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
CHEVRON PHILLIPS CHEMICAL COMPANY LP
Filing Date
2025-12-11
Publication Date
2026-06-18

AI Technical Summary

Technical Problem

Conventional synthesis schemes for alkynes often require harsh reaction conditions, costly raw materials, and result in poor yields with many by-products that cannot be reused or recycled.

Method used

A multistep process involving the reaction of a metal with an alkyne reactant to form a metal acetylide or propynide, followed by contacting it with a haloalkane to produce a metal salt and C4-C20 alkynes, utilizing suitable solvents and conditions to enhance yield and selectivity.

🎯Benefits of technology

The process achieves high yields of C4-C20 alkynes with minimal by-products, allowing for efficient production and recycling of reactants, thereby reducing costs and environmental impact.

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Abstract

Alkyne compounds are produced by contacting a metal and an alkyne reactant comprising acetylene and / or propyne in a first reaction medium to form a first reaction mixture comprising a metal acetylide and / or a metal propynide, and then contacting the metal acetylide and / or the metal propynide with a haloalkane in a second reaction medium to form a second reaction mixture comprising a metal salt and a 1-alkyne and / or a 2-alkyne. Representative alkynes that can be produced using this process include 1-hexyne, 2-hexyne, 2-heptyne, and the like.
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