Emulsifying composition
Patent Information
- Application Number
- PCT/EP2026/057376
- Authority / Receiving Office
- WO · WO
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2025-03-24
- Filing Date
- 2026-03-17
- Publication Date
- 2026-10-01
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Abstract
Description
[0001] 202400047 Foreign Filing 1
[0002] Emulsifying composition
[0003] Field of the invention
[0004] The invention relates to an emulsifying composition comprising one or more emulsifying agents EA and one or more special diesters D wherein the mass ratio m(emulsifying agent EA) / m(diester D) is in the range between Xm1 to Xm2, with Xm1 = 1 / 50, and Xm2 = 5, and wherein emulsifying agent EA is selected from the group of anionic emulsifiers, cationic emulsifiers, amphoteric emulsifiers and non-ionic emulsifiers.
[0005] Prior art
[0006] Emulsions of aqueous and oil phases constitute the main fraction of numerous cosmetic formulations. A variety of oil phase constituents and emollients are used, most of which are currently obtained from fossil petroleum sources. Increasing attention for sustainability aspects of cosmetic products, however, has recently shifted the focus of formulation development towards avoiding components of fossil origin. Accordingly, formulation components from renewable sources have been used increasingly. Typically, cosmetic emollients require viscosities in the range of 3 -200 mPas at room temperature, surface tension in the range of 25 - 33 mN / m, medium to low polarity, and medium to good spreading behavior. Additionally, suitable components should contribute to other desirable characteristics of cosmetic formulations as e.g. good dermatological compatibility, good moisturizing properties, elegant appearance, easy application, optimal sensory impression, storage stability and possibly cleansing and nourishing effects for the skin. Importantly, the range of options for renewable components is further limited by the need to avoid components of tropical origin to reduce negative impacts on fragile ecosystems. In view of these limitations there is substantial interest in providing sustainable emulsifying compositions for cosmetic applications.
[0007] EP4110279A1 discloses dispersant compositions comprising alkyl polyglucosides and diisopropyl adipate. Adipic acid, although currently sourced mostly from petrochemical sources, could be obtained from renewable resources. However, effectiveness of diisopropyl adipate as a emollient is limited in numerous formulation settings.
[0008] Accordingly, there is a need for emulsifying compositions that overcome the limitations of prior art compositions.202400047 Foreign Filing 2
[0009] Description of the invention
[0010] The present invention relates to an emulsifying composition comprising
[0011] one or more emulsifying agents EA and
[0012] one or more diesters D
[0013] O
[0014]
[0015] wherein R1and R2are independently selected from linear or branched, saturated or unsaturated C2-C36-alkyl groups, and
[0016] wherein the mass ratio m(emulsifying agent EA) / m(diester D) is in the range between Xm1 to Xm2, with
[0017] Xm1 = 1 / 50, and
[0018] Xm2 = 5, and
[0019] wherein emulsifying agent EA is selected from the group of anionic emulsifiers, cationic emulsifiers, amphoteric emulsifiers and non-ionic emulsifiers.
[0020] Costa et al. describe in Quimica Nova, 1986, 9 (3), 221 the synthesis of 3-alkyladipic acid dimethyl esters starting from eugenol, a natural phenylpropanoid found in essential oils especially from clove, nutmeg, cinnamon, basil, and bay leaf. No dialkyl esters of 3-alkyladipic acid of alcohols higher than methanol have been described. Likewise, only dimethyl esters of various 3-alkyladipic acids are obtained from Costa et al. in Tetrahedron Letters, 1985, 26 (35), 4155-4158.
[0021] In preferred embodiments the emulsifying compositions of the present invention are emulsifying compositions for cosmetic applications.
[0022] It is obvious that said one or more diesters D is not accounted as said one or more emulsifying agents EA.
[0023] In preferred embodiments of the present invention emulsifying agent EA is selected from the group of anionic emulsifiers and non-ionic emulsifiers.202400047 Foreign Filing 3
[0024] In further preferred embodiments of the present invention emulsifying agent EA is selected from the group of silicone surfactants (e.g., dimethicone copolyol), fatty acids and their salts (e.g., stearic acid and sodium stearate), ethoxylated fatty alcohols (e.g., polyoxyethylene (20) cetyl - stearyl ethers), hydrogenated ethoxylated castor oils (e.g., polyoxyethylene (7) hydrogenated castor oil) , alkyl polyglycosides (preferably C15-C22 alkyl polyglycosides), orthophosphoric acid esters (e.g., cetyl phosphate), partial esters of fatty acids with polyols, preferably with at least one selected from glycerol, polyglycerol, sorbitan, or sorbitol (e.g., glyceryl monostearate or sorbitan monooleate) and their ethoxylates.
[0025] In further preferred embodiments of the present invention emulsifying agent EA is selected from either partial esters of fatty acids with at least one selected from glycerol, polyglycerol, sorbitan, and sorbitol and ethoxylates of partial esters of fatty acids with at least one selected from glycerol, polyglycerol, sorbitan, and sorbitol, and mixtures thereof.
[0026] In particularly preferred embodiments of the present invention emulsifying agent EA is a partial ester of a fatty acid with polyglycerol.
[0027] In even more particularly preferred embodiments of the present invention emulsifying agent EA is a partial ester of fatty acids with 6 to 36 carbon atoms with polyglycerol, wherein further, emulsifying agent EA has a saponification number of 30 to 300 mg KOH / g and wherein the saponification number is determined according to Ph. Eur. 2.5.6.
[0028] In even more particularly preferred embodiments of the present invention emulsifying agent EA is a partial ester of fatty acids with 6 to 36 carbon atoms with polyglycerol, wherein further, preferably, emulsifying agent EA has a saponification number of 100 to 200 mg KOH / g and wherein the saponification number is determined according to Ph. Eur. 2.5.6.
[0029] In even more particularly preferred embodiments of the present invention emulsifying agent EA is Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate, for example sold under the tradename ISOLAN® GPS, or Polyglyceryl-3 Distearate; Glyceryl Stearate Citrate, for example sold under the tradename dermofeel® NO MB.
[0030] Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate and Polyglyceryl-3 Distearate; Glyceryl Stearate Citrate are the respective INCI (International Nomenclature of Cosmetic Ingredients) names of the substances.
[0031] Most preferably emulsifying agent EA is Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate.
[0032] In preferred embodiments of the present invention R1and R2are independently selected from linear or branched, saturated or unsaturated C2-C22-alkyl groups.202400047 Foreign Filing 4
[0033] In further preferred embodiments of the present invention R1and R2are independently selected from linear or branched, saturated or unsaturated C2-Cia-alkyl groups.
[0034] In particularly preferred embodiments of the present invention R1and R2are independently selected from ethyl, propyl, isopropyl, butyl, 2-methyl-propyl, 2-butyl (sec-butyl), pentyl, pentan-2-yl (sec-amyl), pentan-3-yl, 2-methyl-butyl, 3-methyl-butyl (isoamyl), 3-methyl-butan-2-yl, 2,2-dimethyl-propyl, hexyl, 2-methyl-pentyl, 4-methyl-pentyl, 4-methyl-pentan-2-yl, 2-ethyl-butyl, heptyl, heptan-2-y I, heptan-3-yl, heptan-4-yl, 2,4-dimethyl-pentan-3-yl, octyl, octan-2-yl, 2-ethyl-hexyl, 2,3-dimethyl-hexyl, 2,2,4-trimethyl-pentyl, nonyl, nonan-5-yl, 3,5-dimethyl-heptan-4-yl, 2,6,-dimethyl-heptan-4-yl, 3,5,5-trimethyl-hexyl, decyl, undecyl, undecan-6-yl, dodecyl, 2,6,8-trimethyl-nonan-4-yl, tridecyl, tetradecyl, pentadecyl, hexadecyl, Z-9-hexadecen-1-yl, heptadecyl, octadecyl, isostearyl (mixture of regioisomers), oleyl (Z-9-octadecen-1-yl), elaidyl (E-9-octadecen-1-yl), linoleyl (cis,cis-9,12-Octadecadien-1-yl), y-linolenyl (6,9,12-Octadecatrien-1-yl), nonadecyl, icosanyl (arachidyl), docosanyl, tetracosanyl (lignoceryl), hexacosanyl (ceryl), octacosanyl, triacontanyl.
[0035] In preferred embodiments of the present invention the mass ratio m(emulsifying agent EA) / m(diester D) is in the range between Xm1 to Xm2, with
[0036] Xm1 = 1 / 10, and
[0037] Xm2 = 1 / 2.
[0038] In preferred embodiments of the present invention the emulsifying composition further comprises at least one preservative selected from tocopherol, triethyl citrate, glyceryl caprylate, benzoic acid, sodium levulinate, potassium sorbate, phenoxyethanol, methylpropanediol, caprylyl glycol, phenylpropanol, ethylhexylglycerin and benzyl alcohol.
[0039] In further preferred embodiments of the present invention the emulsifying composition further comprises at least one humectant selected from glycerol, 1 ,2-propylene glycol, 1 ,3-propanediol, diglycerol, dipropylene glycol, xylitol, sorbitol, maltitol, 1,2-butylene glycol, 1,3-butylene glycol, 1,2-pentylene glycol, 1,2-hexylene glycol, lactic acid, creatine and urea.
[0040] In a particularly preferred embodiment of the present invention the emulsifying composition comprises glycerol as a humectant.
[0041] In another aspect the present invention further relates to emulsions comprising
[0042] an aqueous phase, and
[0043] a dispersed phase comprising at least one liposoluble compound with a logP value greater than 0, preferably greater than 0 and lower than or equal to 15,
[0044] the emulsion further comprising an emulsifying composition according to the present invention.
[0045] In preferred embodiments the present invention further relates to emulsions comprising
[0046] an aqueous phase, and202400047 Foreign Filing 5
[0047] a dispersed phase comprising at least one liposoluble compound with a logP value greater than or equal to 1 and lower than or equal to 15,
[0048] the emulsion further comprising an emulsifying composition according to the present invention. In more preferred embodiments the present invention further relates to emulsions comprising an aqueous phase, and
[0049] a dispersed phase comprising at least one liposoluble compound with a logP value greater than or equal to 1 and lower than or equal to 10,
[0050] the emulsion further comprising an emulsifying composition according to the present invention. LogP, also called LogKow (octanol / water partition coefficient), is a measure of the differential solubility of chemical compounds between octanol and water. LogP is equal to the logarithm of the ratio of the concentrations of the substance studied in octanol and in water: logP = log(Co / Cw). This value is a measure of the hydrophilic or hydrophobic (liposoluble) character of a molecule. If logP of a substance is positive that substance is more soluble in octanol than in water and vice versa. According to the invention, a liposoluble compound has a logP value greater than 0. Preferred liposoluble compounds according to the present invention have logP values greater than or equal to 1 and lower than or equal to 15. More preferred liposoluble compounds according to the present invention have logP values greater than or equal to 1 and lower than or equal to 10.
[0051] In preferred embodiments the present invention relates to formulations comprising at least one component selected from the group of emollients, further emulsifiers, thickeners / viscosity regulators / stabilizers / consistency enhancers, UV light protection filters, antioxidants, humectants, solids and fillers, pigments, film formers, pearlescence / opacifying additives, deodorant and antiperspirant active ingredients, insect repellents, self-tanning agents, perfumes, preservatives, propellants, conditioners, dyes, cosmetic active ingredients, care additives, superfatting agents, solvents. Numerous representatives of these individual groups of substances are known to people of skill in the art and, further, can be found for example in W02009138306 (A1). The amounts of the respective additives to be used are governed by their intended use. With respect to this, reference is made to standard handbooks known to the people of skill in the art in this field, e.g. K. Schrader, "Grundlagen und Rezepturen der Kosmetika [Fundamentals and principles of cosmetics]", 2nd edition, pages 329 to 341 , Huthig Buch Verlag Heidelberg. Guide formulations for typical applications are known in the art and have been published for example in brochures of the manufacturers of the respective ingredients. Such formulations can be adapted to specific applications by routine optimization experiments.
[0052] In more preferred embodiments the present invention relates to formulations comprising at least one component selected from the group of humectants, emollients, further emulsifiers, stabilizers / consistency enhancers, perfumes, preservatives, UV light protection filters, antioxidants, pigments and cosmetic active ingredients.202400047 Foreign Filing 6
[0053] In even more preferred embodiments, the present invention relates to formulations comprising at least one component selected from the group of emulsifiers, humectants, antioxidants, and preservatives.
[0054] In yet another aspect the present invention further relates to the use of an emulsifying composition according to the present invention for emulsifying a liposoluble compound with a logP value greater than 0, preferably greater than 0 and lower than or equal to 15.
[0055] Examples:
[0056] General procedure for the preparation of dialkylesters:
[0057] A mixture of monofunctional alcohol (2.00-2.20 equiv.), dicarboxylic acid (1.0 equiv.), 0.5% (w / w) para-toluenesulfonic acid and 0.05% (w / w) hypophosphorous acid (HPA) was heated to a reaction temperature of 150 °C over the course of 3 h using a Dean-Stark apparatus with nitrogen passing through. The resulting reaction water was continuously removed until an acid number of less than 5 mg KOH / g was reached. The mixture was cooled to room temperature, neutralized with 50% aq. potassium hydroxide solution according to the acid number, washed with water, dried, and submitted to vacuum filtration. Typically, the reaction was performed on a scale of 200-300 g.
[0058] Example 1 (inventive): Dialkylester of 3-propyladipic acid with butan-1-ol
[0059] A mixture of butan-1-ol (95.3 g, 1.29 mol) and 3-propyladipic acid (110 g, 0.58 mol) was heated to a reaction temperature of 150 °C over the course of 3 h in the presence of 1.03 g paratoluenesulfonic acid and 0.103 g hypophosphorous acid (HPA) using a Dean-Stark apparatus with nitrogen passing through. The resulting reaction water was continuously removed until an acid number of less than 5 mg KOH / g was reached. The mixture was cooled to room temperature, neutralized with 50% aq. potassium hydroxide solution according to the acid number, washed with water, dried, and submitted to vacuum filtration. A yellow to light brown oil was obtained with a purity of >98% according to GC analysis.202400047 Foreign Filing 7
[0060] Overview Examples 1 (inventive) to 8b (inventive):
[0061] Examples 2 (inventive) to 8 (inventive) were prepared according to the general procedure for the preparation of dialkylesters.
[0062] Reference Dicarboxylic Alcohol Alcohol Product Purity of the acid equiv. Appearance obtained used dialkylester according to GC analysis Example 1 3- butan-1-ol 2.2 yellow to >98% (inventive) propyladipic light brown
[0063] acid (A) oil
[0064] Example 2 3- fusel alcohol 2.2 yellow to >98% (inventive) propyladipic (technical mixture of light brown
[0065] acid (A) 3-methyl-butan-1-ol oil
[0066] and 2-methyl-butan- 1-ol)
[0067] Example 3 3- 1 -octanol 2.2 yellow to >98% (inventive) propyladipic light brown
[0068] acid (A) oil
[0069] Example 4 3- isobutanol (2- 2.2 yellow to >98% (inventive) propyladipic methylpropan-1-ol) light brown
[0070] acid (A) oil
[0071] Example 5 3- 2-ethyl-butan-1-ol 2.2 yellow to >98% (inventive) propyladipic light brown
[0072] acid (A) oil
[0073] Example 6 3- 2-ethyl-hexan-1-ol 2.2 yellow to >98% (inventive) propyladipic light brown
[0074] acid (A) oil
[0075] Example 7 3- octan-2-ol 2.2 yellow to >98% (inventive) propyladipic light brown
[0076] acid (A) oil
[0077] Example 8 3- Isononanol (mixture 2.2 yellow to >95% (inventive) propyladipic of low-branched C9 light brown
[0078] acid (A) oxo alcohols; Evonik) oil
[0079] Example 3- 3,7-Dimethyloctan-1 - 2.1 yellow to >95% 8b propyladipic ol (Dihydrocitronellol) light brown
[0080] (inventive) acid (A) oil
[0081]
[0082] 202400047 Foreign Filing 8
[0083] Example 9 (non-inventive): Commercially available TEGOSOFT DEC (INCI: Diethylhexyl Carbonate) from Evonik Industries
[0084] Commercially available Diethylhexyl Carbonate, for example TEGOSOFT® DEC from Evonik Industries, is a non-biobased emollient for cosmetic applications. It has found widespread use in skin care due to its good spreadability and light skin feel. In sun care it is used due to its good solubility for crystalline UV filters.
[0085] Example 10 (non-inventive): Commercially available TEGOSOFT Cl (INCI: Cetearyl Isononanoate) from Evonik Industries
[0086] Commercially available Cetearyl Isononanoate, for example TEGOSOFT® Cl from Evonik Industries, is an emollient for cosmetic applications which is only partially based on renewable raw materials. It has found widespread use in skin care due to its balanced sensory profile.
[0087] Example 11 (non-inventive): Commercially available CETIOL® B (INCI: Dibutyl Adipate) from BASF.
[0088] Commercially available Dibutyl Adipate, for example CETIOL® B from BASF, is a dialkylester of adipic acid and a non-biobased emollient for cosmetic applications. It has found widespread use in sun care due to its good solubilization capabilities for crystalline UV filters such as Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (BEMT).
[0089] Example 11b (non-inventive): (3-Ethyladipic acid bis-dihydrocitronellyl ester
[0090] / 3-Ethyladipic acid bis-dihydrocitronellyl ester was prepared as described in example 3 of DE1286692B.
[0091] Example 12: Stability of a W / O emulsion upon storage
[0092] The dialkyl esters of 3-propyladipic acid according to the invention can be used as typical cosmetic oils in emulsions, in particular if these are to contain a very high proportion of or are exclusively based on naturally based raw materials. The formulations resulting from this are characterized by a good stability, especially with regard to their stability at elevated temperatures, and are thereby preferred in comparison with emulsions which use other naturally based or petrochemically-based202400047 Foreign Filing 9
[0093] oils, which can be regarded as first alternatives. The water-in-oil emulsions shown in Table 1 were prepared.
[0094] Table 1 : Water-in-oil emulsions. Figures in percentage by weight. Conventional preparation of lotions on the 200 g scale. Phase A is heated to 80°C, Phase B (ambient temperature) is added to A using a dropping funnel and stirred at 500 rpm for 2 min with the MIG stirrer, then homogenized at 1300 rpm for 3 min.
[0095] Formulation 1a 1b 1c 1d 1e 1f 1g A Isolan® GPS
[0096] (Polyglyceryl-4
[0097] 2.50 2.50 2.50 2.50 2.50 2.50 2.50 Di isoste a rate / P o ly hy d roxy stea rate / S e ba
[0098] cate)
[0099] Example 1 (according to the invention) 12.0
[0100] 0
[0101] Example 3 (according to the invention) 12.0
[0102] 0
[0103] Example 5 (according to the invention) 12.0
[0104] 0
[0105] Example 6 (according to the invention) 12.0
[0106] 0
[0107] Example 9 (Diethylhexyl Carbonate; not 12.0 according to the invention) 0
[0108] Example 10 (Cetearyl Isononanoate; 12.0 not according to the invention) 0 Example 11 (Dibutyl Adipate; not 12.0 according to the invention) 0 Tegosoft® DC (Decyl Cocoate) 6.50 6.50 6.50 6.50 6.50 6.50 6.50 Prunus Amygdalus Dulcis (Sweet
[0109] 2.50 2.50 2.50 2.50 2.50 2.50 2.50 Almond) Oil
[0110] Hydrogenated Castor Oil 0.25 0.25 0.30 0.25 0.25 0.25 0.25 Cera Alba 0.25 0.25 0.25 0.25 0.25 0.25 0.25 dermosoft® GMCY (Glyceryl Caprylate) 0.50 0.50 0.50 0.50 0.50 0.50 0.50 dermofeel® Toco 70 non GMO
[0111] (Tocopherol, Helianthus Annuus 0.20 0.20 0.20 0.20 0.20 0.20 0.20 (Sunflower) Seed Oil)
[0112] B Water to to to to to to to 100 100 100 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 3.00
[0113]
[0114] 202400047 Foreign Filing 10
[0115] Zinc Sulfate (Zinc Sulfate Heptahydrate) 1.50 1.50 1.50 1.50 1.50 1.50 1.50
[0116]
[0117] The viscosities of all the formulations in Table 1 were found to be comparable (5-30 Pa s;
[0118] Brookfield viscosity, measured with spindle 5, 10 rpm, at 25°C). All formulations after preparation are viscous and homogeneous. After storage at ambient temperature for three months, a clear phase separation appears for the formulations 1 e, 1 f and 1 g containing Examples 9, 10 and 11 (not according to the invention). However, the emulsions containing dialkyl esters of 3-propyladipic acid (formulations 1 a through 1 d based on examples 1 , 3, 5 and 6 according to the invention) were found to be perfectly stable.
[0119] Example 13: Sensory evaluation of a W / O lotion as compared to Diethylhexyl Carbonate
[0120] The formulations shown in Table 2 were prepared. The influence on the feeling on the skin of the formulations was investigated by a test panel. Fourteen trained people each applied a defined amount of approx. 25 pl of the formulations to a defined test field on the inside of the forearm without knowing the composition of the formulations. The formulations were spread in the test field with the help of a finger through circular movements until noticeable absorption was achieved (maximum 60 circles). The parameters of stickiness, absorption, ease of distribution and waxiness were assessed on a scale from 0 to 10 during the spreading of the sample on the skin.
[0121] Table 2: Water-in-Oil Emulsions. Figures in percentage by weight. Conventional preparation of lotions on the 200 g scale. Phase A is heated to 80°C, Phase B (ambient temperature) is added to A using a dropping funnel and stirred at 500 rpm for 2 min with the MIG stirrer, then homogenized at 1300 rpm for 3 min.
[0122] Formulation 2a 2b 2c 2d A Isolan® GPS
[0123] (Polyglyceryl-4 2.50 2.50 2.50 2.50 Diisostearate / Polyhydroxystearate / Sebacate)
[0124] Example 11 (Dibutyl Adipate; not according to the
[0125] 10.00
[0126] invention)
[0127] Example 1 (according to the invention) 10.00
[0128] Example 2 (according to the invention) 10.00 Example 4 (according to the invention) 10.00 Tegosoft® DC MB (Decyl Cocoate) 7.00 7.00 7.00 7.00 Prunus Amygdalus Dulcis (Sweet Almond) Oil 2.00 2.00 2.00 2.00 Zinc Stearate 0.50 0.50 0.50 0.50 Hydrogenated Castor Oil 0.30 0.30 0.30 0.30
[0129]
[0130] 202400047 Foreign Filing 11
[0131] Cera Alba 0.20 0.20 0.20 0.20 dermofeel® Toco 70 non GMO
[0132] 0.20 0.20 0.20 0.20 (Tocopherol, Helianthus Annuus (Sunflower) Seed Oil)
[0133] B Water to to to to 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 Zinc Sulfate (Zinc Sulfate Heptahydrate) 1.50 1.50 1.50 1.50 Panthenol 0.50 0.50 0.50 0.50 Sorbitol (97% in water) 1.50 1.50 1.50 1.50 Verstatil® TBG MB
[0134] 1.00 1.00 1.00 1.00 (Triethyl Citrate; Glyceryl Caprylate; Benzoic Acid)
[0135]
[0136] Table 3 shows that the formulations 2b, 2c and 2d with Examples 1 , 2 and 4, in comparison to formulation 2a with Example 11 (Dibutyl Adipate; not according to the invention), are significantly less sticky, show much better absorption, can be better distributed and have a lower waxiness.
[0137] Table 3:
[0138] Formulation # Stickiness Absorption Ease of Wax in ess Distribution Formulation 2a with Example 11 (Dibutyl
[0139] 5 4 4 4 Adipate; not according to the invention)
[0140] Formulation 2b with Example 1 1 8 7 2 Formulation 2c with Example 2 3 6 6 2 Formulation 2d with Example 4 3 6 7 3
[0141]
[0142] Example 13b: Sensory evaluation of a W / O lotion as compared to Example 3 from DE 1286692B ((3-Ethyladipic acid bis-dihydrocitronellyl ester)
[0143] The formulations shown in Table 2b were prepared. The influence on the feeling on the skin of the formulations was investigated by a test panel. Fourteen trained people each applied a defined amount of approx. 25 pl of the formulations to a defined test field on the inside of the forearm without knowing the composition of the formulations. The formulations were spread in the test field with the help of a finger through circular movements until noticeable absorption was achieved (maximum 60 circles). The parameters of stickiness, absorption, ease of distribution and waxiness were assessed on a scale from 0 to 10 during the spreading of the sample on the skin.
[0144] Table 2b: Water-in-Oil Emulsions. Figures in percentage by weight. Conventional preparation of ##lotions# on the 200 g scale. Phase A is heated to 80°C, Phase B (ambient temperature) is added202400047 Foreign Filing 12
[0145] to A using a dropping funnel and stirred at 500 rpm for 2 min with the MIG stirrer, then homogenized at 1300 rpm for 3 min.
[0146] Formulation 2e 2f A Isolan® GPS
[0147] 2.50 2.50 (Polyglyceryl-4 Diisostearate / Polyhydroxystearate / Sebacate)
[0148] Example 11b (p-ethyladipic acid bis-dihydrocitronellyl ester; not according
[0149] 10.00 to the invention)
[0150] Example 8b (3-propyladipic acid bis-dihydrocitronellyl ester) 10.00 Tegosoft® DC MB (Decyl Cocoate) 7.00 7.00 Prunus Amygdalus Dulcis (Sweet Almond) Oil 2.00 2.00 Zinc Stearate 0.50 0.50 Hydrogenated Castor Oil 0.30 0.30 Cera Alba 0.20 0.20 dermofeel® Toco 70 non GMO
[0151] 0.20 0.20 (Tocopherol, Helianthus Annuus (Sunflower) Seed Oil)
[0152] B Water to to 100 100 Glycerin 3.00 3.00 Zinc Sulfate (Zinc Sulfate Heptahydrate) 1.50 1.50 Panthenol 0.50 0.50 Sorbitol (97% in water) 1.50 1.50 Verstatil® TBG MB
[0153] 1.00 1.00 (Triethyl Citrate; Glyceryl Caprylate; Benzoic Acid)
[0154]
[0155] Table 3b shows that the formulation 2f with Example 8b (3-propyladipic acid bis-dihydrocitronellyl ester) in comparison to formulation 2e with Example 11b (p-ethyladipic acid bis-dihydrocitronellyl ester; not according to the invention), are significantly less sticky, show much better absorption, can be better distributed and have a lower waxiness.
[0156] Table 3b:
[0157] Formulation # Stickiness Absorption Ease of Wax in ess Distribution Formulation 2e with Example 11 b (p- ethyladipic acid bis-dihydrocitronellyl 5 4 4 4 ester; not according to the invention)
[0158] Formulation 2f with Example 8b (3- propyladipic acid bis-dihydrocitronellyl 2 6 6 3 ester; according to the invention)
[0159]
[0160] 202400047 Foreign Filing 13
[0161] Example 14: Sensory evaluation of a O / W lotion as compared to cetearyl isononanoate and diethylhexyl carbonate
[0162] The formulations shown in Table 4 were prepared. The influence on the feeling on the skin of the formulations was investigated by a test panel. Ten trained people each applied a defined amount of approx. 25 pl of the formulations to a defined test field on the inside of the forearm without knowing the composition of the formulations. The formulations were spread in the test field with the help of a finger through circular movements until noticeable absorption was achieved (maximum 60 circles). The parameters of whitening, oiliness, absorption and tackiness were assessed on a scale from 0 to 10 during the spreading of the sample on the skin and also the parameters of oiliness, absorption and tackiness again after five minutes.
[0163] Table 4: Oil-in-Water Emulsions. Figures in percentage by weight. Conventional preparation of lotions on the 200 g scale. Phase A and B are heated to 70-75°C, Phase B is added to A and homogenized at 20500 rpm with an UltraTurrax for 90 s, then cooled down to 40°C, Phase C is added and stirred at 13500 rpm with an UltraTurrax for 30 s. Phase D is then added.202400047 Foreign Filing 14
[0164] Formulation 3a 3b 3c 3d 3e A dermofeel® NC MB
[0165] (Polyglyceryl-3 Distearate; Glyceryl Stearate 3.00 3.00 3.00 3.00 3.00 Citrate)
[0166] Tego® Alkanol 1618 (Cetearyl Alcohol) 1.00 1.00 1.00 1.00 1.00 Example 10 (Cetearyl Isononanoate; not
[0167] 12.00
[0168] according to the invention)
[0169] Example 9 (Diethylhexyl Carbonate; not
[0170] 12.00
[0171] according to the invention)
[0172] Example 1 (according to the invention) 12.00
[0173] Example 3 (according to the invention) 12.00 Example 7 (according to the invention) 12.00 dermofeel® Toco 70 non GMO
[0174] (Tocopherol, Helianthus Annuus (Sunflower) 0.20 0.20 0.20 0.20 0.20 Seed Oil)
[0175] B Water to to to to to 100 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 3.00 C Xanthan Gum (Keltrol CG-SFT, CP Kelco) 0.20 0.20 0.20 0.20 0.20 D Verstatil® SL non GMO (Aqua; Sodium
[0176] 1.50 1.50 1.50 1.50 1.50 Levulinate; Potassium Sorbate)
[0177]
[0178] Table 4
[0179] Formulation # Whitenin Oilines Absorptio Stickines Oilines Absorptio Tackines g s n s s n (5min) s (5min)
[0180] (5min)
[0181] Formulation
[0182] 3a with
[0183] Example 10
[0184] (Cetearyl 5 7 3 4 7 4 5 Isononanoate
[0185] ; non- inventive)
[0186] Formulation
[0187] 3b with
[0188] Example 9 4 7 3 4 8 3 4 (Diethylhexyl
[0189] carbonate;
[0190]
[0191] 202400047 Foreign Filing 15
[0192] non- inventive)
[0193] Formulation
[0194] 3c with 2 3 5 2 2 7 2 Example 1
[0195] Formulation
[0196] 3d with 1 4 5 1 4 6 1 Example 3
[0197] Formulation
[0198] 3e with 3 4 6 1 3 6 2 Example 7
[0199]
[0200] The results in Table 4 show that O / W lotions containing oils according to the invention are of higher quality sensorially than O / W lotions containing oils not according to the invention as formulations 3c, 3d and 3e show less whitening, less oiliness quicker absorption among other benefits.
[0201] Example 15: Perception of odor
[0202] Example 9, 11 and 11 b (all not according to the invention) and Examples 1 , 8 and 8b (all according to the invention) were submitted to an odor panel. For this, 25 mL samples were provided in 50 mL wide neck sample bottles which were then closed and stored at ambient temperature for 2 h. The odor test took place in an odorless place. Four test persons sniffed the samples in succession and subsequently gave an assessment for each sample individually, with the following classification: (1) good assessment, (2) moderate assessment and (3) poor assessment. The test result results as mean value of the assessments.
[0203] Example 9 Example Example 11b (fi- Example Example Example 8b (3- (Diethylhexy 11 ethyladipic acid 1 8 propyladipic I carbonate; (Dibutyl bis- (accordin (accord in acid bis- non- Adipate; dihydrocitronelly g to the g to the dihydrocitronelly inventive) non- I ester; not invention) invention) I ester,
[0204] inventive according to the according to the ) invention) invention) Test
[0205] result
[0206] of the 2.3 2.3 2.1 1.8 1.3 1.2 odou
[0207] rtest
[0208]
[0209] 202400047 Foreign Filing 16
[0210] These results show that Examples 1.8 and 8b (according to the invention), in comparison with Examples 9, 11 and 11 b (not according to the invention), lead to a perception of improved odor.
[0211] Example 15: Perception of odor hold / retention
[0212] Example 11b ( / 3-ethyladipic acid bis-dihydrocitronellyl ester; not according to the invention), Example 8b (3-propyladipic acid bis-dihydrocitronellyl ester), the solutions of Example 11b and 8b in 95% ethanol and the respective formulations 2e (with Example 11 b; / 3-ethyladipic acid bis-dihydrocitronellyl ester; not according to the invention) and 2f (with Example 8b; 3-propyladipic acid bis-dihydrocitronellyl ester) were submitted to a special odor panel and evaluated for odor hold / retention. Ten trained people each applied a defined amount of approx. 25 pl of the samples to a defined test field on the inside of the forearm without knowing the composition of the samples. The samples were spread in the test field with the help of a finger through circular movements until noticeable absorption was achieved (maximum 60 circles). The odor intensity of each test field was characterized between 0 and 10 (O=not noticeable odor intensity, 10= extremely high odor intensity) and evaluated after 10min, 30min, 1h and 3h to assess the odor hold difference. This parameter is very important for the application performance of cosmetic products including emulsions and perfumes. The longer the odor hold is, the more attractive the cosmetic product and consumer prefer to use and rebuy this product with longer odor hold.
[0213] Example 11b Example 8b 5% Example 5% Example Formulati Formulati ( / 3-ethyladipic (3- 11b ( / 3- 8b (3- on 2e on 2f acid bis- propyladipic ethyladipic propyladipic
[0214] dihydrocitron acid bis- acid bis- acid bis- ellyl ester; dihydrocitron dihydrocitron dihydrocitron
[0215] not according ellyl ester) ellyl ester; ellyl ester) in
[0216] to the not according 95% Ethano.
[0217] invention), to the
[0218] invention) in
[0219] 95% Ethanol
[0220] Odor 4 5 Intensi
[0221] 6 7 4 6
[0222] ty
[0223] 10min
[0224] Odor 2 3 Intensi
[0225] 3 5 2 4
[0226] ty
[0227] 30min
[0228]
[0229] 202400047 Foreign Filing 17
[0230] Odor 1 2 Intensi 2 5 1 3
[0231] ty 1h
[0232] Odor 1 2 Intensi 2 4 1 3
[0233] ty 3h
[0234]
[0235] These results show that Example 8b according to the invention, in comparison with Example 11 b not according to the invention, lead to a perception of improved odor hold / retention as pure substance, as 5% solution in 95% ethanol and in a cosmetic formulation.
[0236] Formulation Examples
[0237] The following examples demonstrate the applicability of the diesters according to the invention in different cosmetic formulations and their compatibility with various other ingredients such as emulsifiers, stabilizers, preservatives or active compounds like UV-filters or antimicrobial drugs which are usually challenging to formulate. The application of the invention is not limited to the formulations shown. The preparation of the examples has been done according to common standard methods.
[0238] The sample formulations listed below were prepared with each of the diesters of examples 1 to 8b according to the invention (hereinafter marked "Example X"); nine different formulations were thus prepared for each example formulation.
[0239] Natural body spray with moisturizing properties
[0240] Phase Ingredient w / w- w / w- w / w- w / w-% w / w- w / w- w / w- % % % % % % TEGO®Care LTP
[0241] A (Sorbitan Laurate; Polyglyceryl- 2.50 3.00
[0242] 4 Laurate; Dilauryl Citrate)
[0243] TEGO®Care PBS 6
[0244] (Polyglyceryl-6 Stearate; 3.00 3.00 3.00 3.00 3.00 Polyglyceryl-6 Behenate)
[0245] TEGOSOFT®LO MB (Lauryl
[0246] 5.50 7.00 8.00 8.00 8.00 8.00 8.00 Oleate)
[0247] Example X 3.00 1.50 3.00 3.00 3.00 3.00 3.00 TEGOSOFT®DC MB (Decyl
[0248] 6.00 7.00 3.00 4.00 4.00 4.00 2.00 Cocoate)
[0249]
[0250] 202400047 Foreign Filing 18
[0251] Dodecane (Plantasens® Flash
[0252] 2.00 2.00 80, Clariant)
[0253] Water ad ad ad ad ad ad B ad 100
[0254] 100 100 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 4.00 Gellan Gum (Kelcogel CG-HA,
[0255] 0.10 0.05 0.05 0.05 0.05 0.0.5 CP Kelco)
[0256] Xanthan Gum (Keltrol CG-SFT,
[0257] 0.10 0.05 0.05 0.05 0.05 CP Kelco)
[0258] Genuvisco Carrageenan CG- 0.05 0.05
[0259] 131 (Carrageenan)
[0260] dermsosoft®OMP
[0261] C (Methylpropandiol; Caprylyl 2.50 2.50 2.50 2.50 2.50 2.50 2.50 Glycol; Penylpropanol)
[0262]
[0263] Regenerating anti-aging Serum
[0264] Phase Ingredient w / w- w / w- w / w- w / w- % % % % A TEGO®Care 165 (Glyceryl Stearate; PEG-100 Stearate) 3.00 3.00 3.00 3.00 TEGO® Alkanol 18 (Stearyl Alcohol) 0.50 0.50 0.50 0.50 Isononyl Isononanoate 4.00 4.00 4.00 4.00 Example X 3.00 3.00 3.00 3.00 Hydrogenated Polyisobutene 3.00 3.00 3.00 3.00 TEGOSOFT®APM (PPG-3 Myristyl Ether) 3.00 3.00 3.00 2.00 Tocopherol 0.50 0.50 0.50 0.50 ad ad ad ad B Aqua
[0265] 100 100 100 100 Butylene Glycol 5.00 5.00 5.00 5.00 SKINMIMICS® (Ceteareth-25; Glycerin; Cetyl Alcohol;
[0266] Behenic Acid; Cholesterol; Ceramide NP; Ceramide NS;
[0267] 2.50 2.50 2.50 2.50 Ceramide EOS; Ceramide EOP; Ceramide AP; Caprooyl
[0268] Phytosphingosine; Caprooyl Sphingosine)
[0269] Polyacrylamide; C13-14 Isoparaffin; Laureth-7 (Sepigel
[0270] C 0.75 0.75 0.75 0.75 305, Seppic)
[0271] Z Phenoxyethanol, Perfume q.s. q.s. q.s. q.s.
[0272]
[0273] Body cream 1
[0274] Phase Raw material w / w w / w w / w w / w w / w w / w w / w % % % % % % %
[0275]
[0276] 202400047 Foreign Filing 19
[0277] dermofeel® NC (Polyglyceryl-3
[0278] A Distearate; Glyceryl Stearate 4.00 4.00
[0279] Citrate)
[0280] ECOHANCE® Care PS 3
[0281] 3.00 3.00 3.00 3.00 3.00 (Polyglyceryl-3 Distearate)
[0282] TEGO® Alkanol 1618 (Cetearyl
[0283] 1.50 1.20 1.00 1.00 1.00 1.80 1.80 Alcohol)
[0284] TEGOSOFT® CT (Caprylic / Capric
[0285] 4.50 4.50 0.50 0.50 0.50 4.50 4.50 Triglyceride)
[0286] Example X 4.00 4.00 4.00 4.00 4.00 2.00 2.00 Dodecane (Plantasens® Flash
[0287] 2.00 2.00 80, Clariant)
[0288] TEGOSOFT® LO MB (Lauryl
[0289] 8.50 8.50 8.50 Oleate)
[0290] dermofeel® sensolv MB (Isoamyl
[0291] 1.50 1.50 1.50
[0292] laurate)
[0293] Tocopherol 0.50 0.50 0.50 0.50 0.50 0.50 ECOHANCE® Soft Baobab
[0294] 6.00 7.00 7.00 7.00 (Adansonia Digitata Seed Oil)
[0295] TEGO® Care Eco CAT MB
[0296] (Distearoylisopropyl Dimonium 4.00 3.00 3.00 3.00 Methosulfate)
[0297] VARISOFT®TA 100
[0298] 2.50 1.50 1.50 (Distearyldimonium Chloride)
[0299] HyaCare 50 (Hydrolyzed
[0300] 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Hyaluronic Acid)
[0301] ad ad ad ad ad ad ad B Aqua
[0302] 100 100 100 100 100 100 100 Glycerin 7.00 7.00 7.00 7.00 7.00 7.00 7.00 Skinmimics® (Ceteareth-25;
[0303] Glycerin; Cetyl Alcohol; Behenic
[0304] Acid; Cholesterol; Ceramide NP;
[0305] Ceramide NS; Ceramide EOS; 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Ceramide EOP; Ceramide AP;
[0306] Caprooyl Phytosphingosine;
[0307] Caprooyl Sphingosine)
[0308] Xanthan Gum (Keltrol CG-SFT,
[0309] C 0.50
[0310] CP Kelco)
[0311]
[0312] 202400047 Foreign Filing 20
[0313] Genuvisco Carrageenan CG-131
[0314] 0.50 0.50 0.50 0.50 0.50 0.50 (Carrageenan)
[0315] dermosoft® Heptyl MB
[0316] D 2.00 1.00 (Heptylglycerin)
[0317] Z Preservative, Perfume q.s. q.s. q.s. q.s. q.s. q.s. q.s.
[0318]
[0319] 202400047 Foreign Filing 21
[0320] Hydrating Body cream long-lasting moisturizing properties
[0321] Pha Raw material w / w w / w w / w w / w w / w w / w w / w w / w se % % % % % % % % dermofeel® NC
[0322] A (Polyglyceryl-3 Distearate; 2.00 2.00 2.00 2.00 2.00 2.00 Glyceryl Stearate Citrate)
[0323] ECOHANCE® PS 3
[0324] 3.00 3.00 (Polyglyceryl-3 Distearate)
[0325] TEGO® Alkanol 1618
[0326] 1.80 1.80 (Cetearyl Alcohol)
[0327] TEGOSOFT® CT
[0328] (Caprylic / Capric 4.50 4.50 4.50 4.50 4.50 4.50 4.50 4.50 Triglyceride)
[0329] Dodecane (Plantasens®
[0330] Flash 80, Clariant)
[0331] TEGOSOFT® LO MB
[0332] 8.50 8.50 8.50 4.50 8.50 8.50 8.50 8.50 (Lauryl Oleate)
[0333] Example X 5.0 5.0 5.0 6.0 6.0 5.0 5.0 5.0 Tocopherol 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 ECOHANCE® Soft Baobab
[0334] (Adansonia Digitata Seed 4.00 2.00
[0335] Oil)
[0336] TEGO® Care Eco CAT MB
[0337] (Distearoylisopropyl 1.00 1.00
[0338] Dimonium Methosulfate)
[0339] VARI SO FT® TA 100
[0340] (Distearyldimonium 1.50 1.00 1.00 1.00 1.00 1.50 Chloride)
[0341] HyaCare 50 (Hydrolyzed
[0342] 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Hyaluronic Acid)
[0343] ad ad ad ad ad ad ad ad B Aqua
[0344] 100 100 100 100 100 100 100 100 Glycerin 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 Skinmimics® (Ceteareth-25;
[0345] Glycerin; Cetyl Alcohol;
[0346] Behenic Acid; Cholesterol;
[0347] 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 Ceramide NP; Ceramide
[0348] NS; Ceramide EOS;
[0349] Ceramide EOP; Ceramide
[0350]
[0351] 202400047 Foreign Filing 22
[0352] AP; Caprooyl
[0353] Phytosphingosine; Caprooyl
[0354] Sphingosine)
[0355] Xanthan Gum (Keltrol CG- c 0.50 0.50 0.50 0.50 0.20 SFT, CP Kelco)
[0356] Genuvisco Carrageenan
[0357] 0.50 0.50 0.50 0.20 CG-131 (Carrageenan)
[0358] dermosoft® Heptyl MB
[0359] 0.50 0.10 (Heptylglycerin)
[0360] z Preservative, Perfume q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s.
[0361]
[0362] Rich natural cream for enhanced elasticity
[0363] Phase Ingredient w / w- w / w- w / w- w / w- w / w- w / w- w / w- % % % % % % % TEGO®Care PSC 3 (Polyglyceryl- A 3.00
[0364] 3 Dicitrate / Stearate)
[0365] Symbiomuls® GC (Glyceryl
[0366] Stearate Citrate; Cetearyl Alcohol; 3.50
[0367] Glyceryl Caprylate)
[0368] dermofeel® NC (Polyglyceryl-3
[0369] Distearate (and) Glyceryl Stearate 2.50 2.50 2.50 3.00 3.00 Citrate)
[0370] TEGIN®M Pellets (Glyceryl
[0371] 0.90 0.30 0.90 0.90 0.90 0.50 0.50 Stearate)
[0372] TEGO® Alkanol 1618 (Cetearyl
[0373] 0.60 0.30 0.60 0.60 0.60 0.60 0.60 Alcohol)
[0374] TEGOSOFT®P (Isopropyl
[0375] 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Palmitate)
[0376] Prunus Amygdalus Dulcis Oil 5.00 5.00 5.00 5.00 5.00 5.00 5.00 TEGOSOFT®CT (Caprylic / Capric
[0377] 4.50 4.50 2.50 2.50 2.50 4.50 4.50 Triglyceride)
[0378] Undecane, Tridecane (Cetiol®
[0379] 2.00 Ultimate, BASF)
[0380] Squalane (Plantasens® Squalane,
[0381] 2.00
[0382] Clariant)
[0383] Dodecane (Plantasens® Flash 80,
[0384] 2.00
[0385] Clariant)
[0386] Triisostearin 3.50 3.50 3.50 3.50 3.50 3.50 3.50 Example X 6.00 6.00 4.00 4.00 4.00 4.00 4.00
[0387]
[0388] 202400047 Foreign Filing 23
[0389] ECOHANCE® Remo XP
[0390] 2.00 (Sorbity l / Xylity 1 Pelargonate)
[0391] TEGOSOFT®LO (Lauryl Oleate) 4.00 6.00 6.00 TEGOSOFT®AC MB (Isoamyl
[0392] 2.00 2.00 2.00 2.00
[0393] Acetate)
[0394] ad ad ad ad ad ad ad B Aqua
[0395] 100 100 100 100 100 100 100 Glycerin 3.00 4.00 3.00 3.00 3.00 5.00 5.00 Gellan Gum 0.10 0.10 0.10 CYAMOPSIS TETRAGONOLOBA
[0396] 0.05 0.05 GUM
[0397] Xanthan Gum (Keltrol CG-SFT,
[0398] 0.30 0.30 0.30 0.30 0.30 0.30 0.30 CP Kelco)
[0399] C Sodium hydroxide (10 % in water) q.s. q.s. q.s. q.s. q.s. q.s. q.s.
[0400] dermofeel®E 74 A non GMO
[0401] D (Tocopheryl Acetate; Helianthus 0.5
[0402] Annuus (Sunflower) Seed Oil)
[0403] Verstatil®TBG MB (Triethyl
[0404] Citrate; Glyceryl Caprylate; 1.2
[0405] Benzoic Acid)
[0406] Preservative q.s. q.s. q.s. q.s. q.s. q.s. Z Perfume q.s. q.s. q.s. q.s. q.s. q.s. q.s.
[0407]
[0408] Deep Comfort silky Body butter
[0409] Phase Raw material w / w w / w w / w w / w w / w w / w w / w w / w % % % % % % % % A dermofeel® NC
[0410] (Polyglyceryl-3
[0411] 3.00 3.00 3.00 3.00 3.00
[0412] Distearate; Glyceryl
[0413] Stearate Citrate)
[0414] Sodium Stearoyl
[0415] Glutamate (Emulgin® 3.00 3.00 3.00 SG, BASF)
[0416] TEGO® Alkanol 1618
[0417] 4.00 4.00 4.00 4.00 4.00 4.00 4.00 4.00 (Cetearyl Alcohol)
[0418] TEGIN® M Pellets
[0419] 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 (Glyceryl Stearate)
[0420] TEGOSOFT® OER
[0421] 6.00
[0422] (Oleyl Erucate)
[0423]
[0424] 202400047 Foreign Filing 24
[0425] Example X 4.00 4.00 4.00 4.00 8.00 8.00 8.00 8.00 TEGOSOFT®LO MB
[0426] 6.00 6.00 6.00 6.00 (Lauryl Oleate)
[0427] Oenothera
[0428] BiennisSeed Extract
[0429] 2.00
[0430] (Life's G LA™ '10' n- 6 Oil, DSM)
[0431] Squalane
[0432] (Plantasens® 2.00
[0433] Squalane, Clariant)
[0434] Helianthus Annuus
[0435] 5.50 5.50 5.50 5.50 5.50 5.50 5.50 5.50 (Sunflower) Seed Oil
[0436] Butyros permum
[0437] 6.00 6.00 6.00 4.00 6.00 6.00 6.00 6.00 Parkii (Shea) Butter
[0438] Theobroma Cacao
[0439] 6.00 6.00 4.00 6.00 6.00 6.00 6.00 6.00 (Cocoa) Seed Butter
[0440] dermofeel® Toco 70
[0441] non GMO
[0442] (Tocopherol;
[0443] 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Helianthus Annuus
[0444] (Sunflower) Seed
[0445] Oil)
[0446] B Aqua ad100 ad 100 ad 100 ad100 ad 100 ad100 ad 100 ad100 Glycerin 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Xanthan Gum
[0447] (Keltrol CG-SFT, CP 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Kelco)
[0448] dermosoft® Heptyl
[0449] D 0.50
[0450] MB (Heptylglycerin)
[0451] Preservative,
[0452] Z q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s.
[0453] Perfume
[0454]
[0455] 202400047 Foreign Filing 25
[0456] O / W Sun Lotion with moisturizing effect
[0457] Phas Raw material w / w w / w w / w w / w w / w w / w w / w- w / w w / w w / w e -% -% -% -% -% -% % -% -% -% AXOL® C 62 Pellets
[0458] 2.5 2.5 2.5 2.5 2.5 2.5 2.5 A (Glyceryl Stearate 2.50
[0459] 0 0 0 0 0 0 0 Citrate)
[0460] Potassium Cetyl 1.5 1.5
[0461] Phosphate 0 0
[0462] TEGO® Alkanol 1618 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0
[0463] 1.00
[0464] (Cetearyl Alcohol) 0 0 0 0 0 0 0 0 TEGOSOFT®LO MB 6.0 6.0 6.0 1.0 1.0 1.0 1.0
[0465] 1.00
[0466] (Lauryl Oleate) 0 0 0 0 0 0 0 Dicaprylyl Ether 1.0
[0467] (Cetiol®OE, BASF) 0
[0468] Dodecane
[0469] 1.0
[0470] (Plantasens® Flash 80,
[0471] 0
[0472] Clariant)
[0473] 3.0 3.0 3.0 8.0 8.0 8.0 10.0 9.0 9.0 9.0 Example X
[0474] 0 0 0 0 0 0 0 0 0 0 TEGO® SP 13 Sun Up
[0475] 1.5 2.0
[0476] MB (Poly C10-30 Alkyl
[0477] 0 0 Acrylate)
[0478] 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Diisopropyl Adipate 3.00
[0479] 0 0 0 0 0 0 0 0 0 Butyloctyl Salicylate
[0480] 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 (HallBrite BHB, The 2.00
[0481] 0 0 0 0 0 0 0 0 0 HallStar Company)
[0482] 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Tocopheryl Acetate 0.20
[0483] 0 0 0 0 0 0 0 0 0 1.0 1.0 1.0 1.0 1.0 1.0
[0484] Dimethicone (5 mPas)
[0485] 0 0 0 0 0 0
[0486] Butyl
[0487] 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Methoxydibenzoylmeth 1.50
[0488] 0 0 0 0 0 0 0 0 0 ane
[0489] Diethylamino
[0490] Hydroxybenzoyl Hexyl 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0
[0491] 4.00
[0492] Benzoate (Uvinul® A 0 0 0 0 0 0 0 0 0 Plus, BASF)
[0493]
[0494] 202400047 Foreign Filing 26
[0495] 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Ethylhexyl Triazone 2.00
[0496] 0 0 0 0 0 0 0 0 0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Ethylhexyl Salicylate 5.00
[0497] 0 0 0 0 0 0 0 0 0 8.0 8.0 8.0 8.0 8.0 8.0 8.0 8.0 8.0 Octocrylene 8.00
[0498] 0 0 0 0 0 0 0 0 0 Ethylhexyl 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5
[0499] 1.50 methoxycrylene 0 0 0 0 0 0 0 0 0 Titanium Dioxide;
[0500] 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 B Tri methoxy caprylylsila 1.00
[0501] 0 0 0 0 0 0 0 0 0 ne
[0502] 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 C Glycerin 3.20
[0503] 0 0 0 0 0 0 0 0 0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 EDTA 0.02
[0504] 2 2 2 2 2 2 2 2 2 ad ad ad ad ad ad ad ad ad ad Aqua
[0505] 100 100 100 100 100 100 100 100 100 100 Acrylates / C10-30 Alkyl 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 D 0.10
[0506] Acrylate Crosspolymer 0 0 0 0 0 0 0 0 0 Sodium Hydroxide
[0507] E q.s q.s q.s q.s q.s q.s q.s q.s q.s q.s (10% in water)
[0508] Z Preservative, Perfume q.s q.s q.s q.s q.s q.s q.s q.s q.s q.s
[0509]
[0510] Ultra-comfortable waterproof Sun Spray SPF 30
[0511] Pha Raw material w / w / w / w / w / w / w / w / w / w / w / w / se w- w- w- w- w- w- w- w- w- w- w- w- % % % % % % % % % % % % A TEGO® Care PBS
[0512] 6 MB (Polyglyceryl- 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 6 Stearate,
[0513] 0 0 0 0 0 0 0 0 0 0 0 Polyglyceryl-6
[0514] Behenate)
[0515] Sodium Stearoyl
[0516] Glutamate 3.0 (Emulgin SG, 0 BASF)
[0517] C12-15 Alkyl 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Benzoate 0 0 0 0 0 0 0 0 0 0 0 0
[0518]
[0519] 202400047 Foreign Filing 27
[0520] TEG 0® FILMSTAR
[0521] One MB
[0522] 1.5 1.0 3.0 (Polyglyceryl-3
[0523] 0 0 0 Stearate / Sebacate
[0524] Crosspolymer)
[0525] LexFilm™ Sun
[0526] Natural MB
[0527] 0.5 1.5 2.5 (Capryloyl
[0528] 0 0 0 Glycerin / Sebacic
[0529] Acid Copolymer)
[0530] TEGOSOFT®LO 2.0 2.0 1.0 1.0 1.0 1.0 3.0 3.0 3.0 3.0 3.0 3.0 MB (Lauryl Oleate) 0 0 0 0 0 0 0 0 0 0 0 0 Bisethylhexyloxyphen
[0531] 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 ol Methoxyphenyl
[0532] 0 0 0 0 0 0 0 0 0 0 0 0 Triazine (Tinosorb
[0533] S, BASF)
[0534] Example X 8.0 6.0 6.0 6.0 6.0 2.0
[0535] 8.0 2.0 3.0 3.0 3.0 3.0 0 0 0 0 0 0
[0536] Butyl
[0537] 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Methoxydibenzoyl
[0538] 0 0 0 0 0 0 0 0 0 0 0 0 methane
[0539] Homosalate 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0
[0540] 0 0 0 0 0 0 0 0 0 0 0 0 Ethylhexyl 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Salicylate 0 0 0 0 0 0 0 0 0 0 0 0 Octocrylene 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0
[0541] 0 0 0 0 0 0 0 0 0 0 0 0 TEGO® Feel C 10 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 (Cellulose) 0 0 0 0 0 0 0 0 0 0 0 0 B Water ad ad ad ad ad ad ad ad ad ad ad ad 10 10 10 10 10 10 10 10 10 10 10 10 0 0 0 0 0 0 0 0 0 0 0 0 Gellan Gum
[0542] 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 (Kelcogel CG-HA,
[0543] 3 3 3 3 3 3 3 3 3 3 3 3 CP Kelco)
[0544] EDTA 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
[0545] 5 5 5 5 5 5 5 5 5 5 5 5
[0546]
[0547] 202400047 Foreign Filing 28
[0548] Glycerin 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0
[0549] 0 0 0 0 0 0 0 0 0 0 0 0 Acrylates / C10-30
[0550] 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Alkyl Acrylate
[0551] 0 0 0 0 0 0 0 0 0 0 0 0 Crosspolymer
[0552] c Phenylbenzimidazo 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 le Sulfonic Acid 0 0 0 0 0 0 0 0 0 0 0 0 Tromethamine 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8
[0553] 8 8 8 8 8 8 8 8 8 8 8 8 7.1 7.1 7.1 7.1 7.1 7.1 7.1 7.1 7.1 7.1 7.1 7.1 Aqua
[0554] 2 2 2 2 2 2 2 2 2 2 2 2 E Tromethamine
[0555] q.s q.s q.s q.s q.s q.s q.s q.s q.s q.s q.s q.s (T risaminomethane
[0556] , 30% in water)
[0557] F dermofeel® OMP
[0558] (Methylpropanediol 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 , Caprylyl Glycol, 0 0 0 0 0 0 0 0 0 0 0 0 Phenylpropanol)
[0559]
[0560] Revitalizing Cationic Hand Creme
[0561] Phas Raw material w / w w / w w / w w / w w / w / w- e -% -% -% -% w- % %
[0562] A VARISOFT®TA 100 (Distearyldimonium 3.5
[0563] 3.50 3.50 3.50 3.50 3.50 Chloride) 0 TEGIN®M Pellets (Glyceryl Stearate) 1.5
[0564] 1.50 1.50 1.50 1.50 1.50
[0565] 0 TEGO® Alkanol 18 (Stearyl Alcohol) 1.0
[0566] 1.00 1.00 1.00 1.00 1.00
[0567] 0 13.0 13.0 13.0 5.0 TEGOSOFT®LO MB (Lauryl Oleate) 3.00 7.00
[0568] 0 0 0 0
[0569] 10.0 Example X 1.00 1.0 10.0 5.0 5.00
[0570] 0 ECOHANCE®Soft Baobab (Adansonia 5.0
[0571] 6.00 5.00 Digitata Seed oil) 0 TEGOSOFT®DEC (Diethylhexyl Carbonate) 8.0
[0572] 8.00 8.00 8.00 8.00 8.00
[0573] 0 TEGOSOFT®CR (Cetyl Ricinoleate) 1.0
[0574] 1.00 1.00 1.00 1.00 1.00
[0575] 0
[0576]
[0577] 202400047 Foreign Filing 29
[0578] Triisostearin 1.0
[0579] 1.00 1.00 1.00 1.00 1.00
[0580] 0 B TEGO® Cosmo C 100 (Creatine) 0.5
[0581] 0.50 0.50 0.50 0.50 0.50
[0582] 0 Glycerin 3.0
[0583] 3.00 3.00 3.00 3.00 3.00
[0584] 0 ad ad ad ad ad ad Aqua
[0585] 100 100 100 100 100 100 Z Preservative, Parfum q. s. q. s. q. s. q.s. q.s. q. s.
[0586]
[0587] (PEG free) AP / Deo roll-on
[0588] Phase Raw material w / w- w / w- w / w- w / w- w / w- w / w- % % % % % % A TEGO® Care APD 18 (Polyglyceryl-6
[0589] Stearate; Polyglyceryl-6 Behenate;
[0590] 5.00 5.00 3.50 3.30 3.30 C18-22 Hydroxyalkyl Hydroxypropyl
[0591] Guar)
[0592] Steareth-2 3.20 Steareth-20 0.80 Cetearyl Alcohol 1.50 0.5 0.5 TEGOSOFT®CT MB (Caprylic / Capric
[0593] 5.7 2.00 Triglyceride)
[0594] Dicaprylyl Ether (Cetiol® OE, BASF) 3.00 TEGOSOFT®LO MB (Lauryl Oleate) 2.50 5.00 5.00 0.5 Example X 2.50 0.50 1.00 0.50 0.50 5.00 TEGODEO®PY 88 G (Zinc Ricinoleate) 1.00 1.00 TEGO® Cosmo P 813 MB
[0595] 0.50 0.50 (Polyglyceryl-3 Caprylate)
[0596] B ad ad ad ad ad ad Aqua
[0597] 100 100 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 Potassium Alum 5.00
[0598] Aluminum Chlorohydrate 50% aq. 20.00 20.00 20.00 Citric Acid, 50% in water q.s. q.s.
[0599] C Preservative, Perfume q.s. q.s. q.s. q.s. q.s. q.s.
[0600]
[0601] Milky Deo Roll-On for sensitive skin
[0602] Phase Raw material w / w- w / w- w / w- w / w- % % % %
[0603]
[0604] 202400047 Foreign Filing 30
[0605] A dermofeel®GSC SG (Glyceryl Stearate Citrate) 0.40 0.40 0.40 0.40 ECOHANCE®Soft Baobab (Adansonia digitata Seed
[0606] 0.50 0.50
[0607] Oil)
[0608] TEGOSOFT® OER MB (Oleyl Erucate) 0.50 dermosoft®decalact deo MB (Sodium Caproyl / Lauroyl
[0609] 0.30 0.30 0.30 0.30 Lactylate; Triethyl Citrate; Salvia Officinalis (Sage) Oil)
[0610] dermosoft®G 3 CY MB (Polyglyceryl-3 Caprylate) 0.30 0.30 0.30 0.30 dermofeel®sensolv MB (Isoamyl Laurate) 0.50 0.50 0.50 0.50 dermofeel®TEC eco (Triethyl Citrate) 5.00 5.00 5.00 5.00 TEGODEO®PY 88 G (Zinc Ricinoleate) 1.00 1.00 1.00 1.00 Example X 2.00 2.00 1.00 1.00 B ad ad ad ad Aqua
[0611] 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 Trisodium Citrate Dihydrate (Sodium Citrate) 0.30 0.30 0.30 0.30 Xanthan Gum FNCSP-PC (Xanthan Gum) 0.90 0.90 0.90 0.90 Genuvisco Carrageenan CG-131 (Carrageenan) 0.10 0.10 0.10 0.10 dermosoft®7GA MB (Aqua; Glycerin; Heptylglycerin;
[0612] 2.60 2.60 2.60 2.60 Sodium Anisate)
[0613] Citric Acid, 20% sol. in water q.s. q.s. q.s. q.s. Z Perfume q.s. q.s. q.s. q.s.
[0614]
[0615] Renewal Body Oil Release Lotion
[0616] Phase Raw material w / w- w / w- w / w- w / w- w / w- w / w- % % % % % % TEGO® Care PBS 6 (Polyglyceryl-6
[0617] A 3.00 3.00 3.00 3.00 3.00 Stearate, Polyglyceryl-6 Behenate)
[0618] ECOHANCE®Care PS 3
[0619] 3.00
[0620] (Polyglyceryl-3 Distearate)
[0621] TEGOSOFT® DEC (Diethylhexyl
[0622] 2.00 2.00 2.00 2.00 2.00 2.00 Carbonate)
[0623] TEGOSOFT® LO MB (Lauryl Oleate) 26.00 26.00 26.00 26.00 26.00 16.00 TEGOSOFT® OER (Oleyl Erucate) 10.00 10.00 10.00 10.00 10.00 10.00 TEGOSOFT® CT (Caprylic / Capric
[0624] 15.00 15.00 15.00 15.00 Triglyceride)
[0625] Example X 10.00 10.00 5.00 5.00 5.00 2.50 TEGOSOFT® AC (Isoamyl Cocoate) 10.00 10.00 10.00 10.00 10.00 10.00 TEGO® Feel C 10 (Cellulose) 1.00 1.00 1.00 1.00 1.00 1.00
[0626]
[0627] 202400047 Foreign Filing 31
[0628] ad ad ad ad ad ad B Aqua
[0629] 100 100 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 Phenoxyethanol, Ethylhexylglycerin
[0630] C (Euxyl PE 9010, Schulke & Mayr 0.70 0.70 0.70 0.70 0.70 0.70 GmbH)
[0631] D Citric Acid (10% in water) q.s. q.s. q.s. q.s. q.s. q.s.
[0632]
[0633] W / O-Make up foundation
[0634] Pha Raw Material w / w / w / w / w / w w / w / w / w / w / se w- w- w- w- -% w- w- w- w- w- % % % % % % % % % A ISOLAN® 17 (Polyglyceryl-4
[0635] Di isoste a rate / P o ly hy d roxy stea r
[0636] ate / Sebacate (and)
[0637] Caprylic / Capric Triglyceride 4.0 4.0 4.0 3.0 2.0 3.0 2.0 2.0 2.0 (and) Polyglyceryl-3 Oleate 0 0 0 0 0 0 0 0 0 (and) Diisostearoyl
[0638] Polyglyceryl-3 Dimer
[0639] Dilinoleate)
[0640] TEGO® FILMSTAR One MB
[0641] (Polyglyceryl-3 1.5 1.0 Stearate / Sebacate 0 0 Cross polymer)
[0642] LexFilm™ Sun Natural MB
[0643] 0.7 1.0 (Capryloyl Glycerin / Sebacic
[0644] 5 0 Acid Copolymer)
[0645] ISOLAN® GPS (Polyglyceryl-4
[0646] 1.0
[0647] Diisostearate /
[0648] 0
[0649] Polyhydroxystearate / Sebacate
[0650] Dehymuls PGPH (Polyglyceryl- 1.5
[0651] 2 Dipolyhydroxystearate) 0
[0652] Cithrol PG3PR (Polyglyceryl-3 2.0
[0653] Poly ricinoleate) 0
[0654] ABIL® EM 90 (Cetyl PEG / PPG- 1.5 1.5 1.5 3.0 10 / 1 Dimethicone) 0 0 0 0 dermofeel® sensolv (Isoamyl 7.0 7.0 7.0 6.0 5.0 7.0 2.5 2.5 2.5 6.0 Laurate) 0 0 0 0 0 0 0 0 0 0
[0655]
[0656] 202400047 Foreign Filing 32
[0657] Decyl Cocoate 4.0 4.0 4.0 4.0 4.0 3.0
[0658] 0 0 0 0 0 0 Isopropyl Myristate 6.0 6.0 6.0 6.0 4.5 4.5 4.5 0 0 0 0 0 0 0 Caprylic / Capric Triglyceride 4.0 3.0 3.0 3.0 4.0
[0659] 0 0 0 0 0 Diethylhexyl Carbonate 4.0 5.0 5.0 5.0 0 0 0 0 Dimethicone 15.
[0660] 00
[0661] TEGOSOFT® LO (Lauryl 2.0 2.0 2.0 5.0 2.0 4.5 Oleate) 0 0 0 0 0 0 Example X 5.0 5.0
[0662] 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0
[0663] 0 0
[0664] Cl 77891 (and) Hydrogenated 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 Lecithin 0 0 0 0 0 0 0 0 0 0 Cl 77492 (and) Hydrogenated 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 Lecithin 0 0 0 0 0 0 0 0 0 0 Cl 77491 (and) Hydrogenated 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Lecithin 5 5 5 5 5 5 5 5 5 5 Cl 77499 (and) Hydrogenated 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Lecithin 0 0 0 0 0 0 0 0 0 0 Disteardimonium Hectorite 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 dimethicone, propylencarbonat 0 0 0 0 0 0 0 0 0 0 B Wasser ad ad ad ad ad ad ad ad ad ad
[0665] 10 10 10 10 10 10 10 10 10
[0666] 100
[0667] 0 0 0 0 0 0 0 0 0 Sodium chloride 1.0 1.0 1.0 1.0 1.5
[0668] 0 0 0 0 0
[0669] Magnesium Sulfate 1.5 2.0 2.0 2.0 2.0 Hepta hydrate 0 0 0 0 0 Glycerin 3.0 3.0 3.0 3.0 3.0 5.0 5.0 5.0 5.0 5.0
[0670] 0 0 0 0 0 0 0 0 0 0 C Phenoxyethanol, Caprylyl 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Glycol 0 0 0 0 0 0 0 0 0 0
[0671]
[0672] Make up with wrinkle filler effect
[0673] Phase Raw Material w / w- w / w- w / w- w / w- % % % %
[0674]
[0675] 202400047 Foreign Filing 33
[0676] A dermofeel® viscolid MB (Hydrogenated Vegetable
[0677] 3.50 3.50 3.50 3.50 Oil)
[0678] TEGOSOFT® CR MB (Cetyl Ricinoleate) 2.50 2.50 2.50 2.50 Copernicia Cerifera (Carnauba) Wax 1.00 1.00 1.00 1.00 TEGOSOFT® LO MB (Lauryl Oleate) 30.00 35.00 30.00 35.00 Example X 5.00 0.10 7.00 1.00 ad ad ad ad Persea Gratissima (Avocado) Oil 100 100 100 100 Prunus Amygdalus Dulcis (Sweet Almond) Oil 3.50 3.50 3.50 3.50 Argania Spinosa Kernel Oil 0.50 0.50 0.50 0.50 dermofeel® Toco 70 non GMO
[0679] (Tocopherol; Helianthus Annuus (Sunflower) Seed 0.50 0.50 0.50 0.50 Oil)
[0680] TEGO® Feel C 10 (Cellulose) 22.90 22.90 22.90 22.90 Unipure White LC 981 HLC (Cl 77891;
[0681] 15.00 15.00 15.00 15.00 Hydrogenated Lecithin, Sensient)
[0682] Unipure Yellow LC 182 HLC (Cl 77492;
[0683] 1.20 1.20 1.20 1.20 Hydrogenated Lecithin, Sensient)
[0684] Unipure Red LC 381 HLC (Cl 77491; Hydrogenated
[0685] 0.70 0.70 0.70 0.70 Lecithin, Sensient)
[0686] Unipure Black LC 989 HLC (Cl 77499;
[0687] 0.20 0.20 0.20 0.20 Hydrogenated Lecithin, Sensient)
[0688] Titanium Dioxide; Silica; Mica; Alumina (RonaFlair
[0689] 0.50 0.50 0.50 0.50 Softshade, Merck)
[0690] Titanium Dioxide; Mica; Tin Oxide (RonaFlair
[0691] 0.20 0.20 0.20 0.20 Balance Blue, Merck)
[0692] Perfume q.s. q.s. q.s. q.s.
[0693]
[0694] 202400047 Foreign Filing 34
[0695] W / O sun care - Sun Cream, SPF 50+
[0696] Phase Ingredients w / w- w / w- w / w- w / w- w / w- w / w- % % % % % % A ISOLAN® 17 MB (Polyglyceryl-4
[0697] Diisostearate / Polyhydroxystearate /
[0698] Sebacate; Caprylic / Capric 4.30 4.30 4.30 4.30 4.30 4.30 Triglyceride; Polyglyceryl-3 Oleate;
[0699] Diisostearoyl Polyglyceryl-3 Dimer
[0700] Dilinoleate)
[0701] Microcrystalline Wax
[0702] 0.30 0.30 0.30 0.30 0.30 0.30 Hydrogenated Castor Oil
[0703] 0.30 0.30 0.30 0.30 0.30 0.30 TEGOSOFT® DEC (Diethylhexyl
[0704] Carbonate) 8.20 4.20 2.20 2.20 2.20 2.20
[0705] TEGOSOFT® XC (Phenoxyethyl
[0706] 4.00 4.00 4.00 4.00 4.00 Caprylate)
[0707] Dermofeel sensolv MB (Isoamyl
[0708] 2.00 2.00 2.00 2.00 Laurate)
[0709] Example X 4.00 2.00 4.00 4.00 4.00 4.00 TEGO® FILMSTAR One MB
[0710] (Polyglyceryl-3 Stearate / Sebacate
[0711] 0.50 Crosspolymer)
[0712] LexFilm™ Sun Natural MB 0.50
[0713] Uvinul A plus (Diethylamino
[0714] Hydroxybenzoyl Hexyl Benzoate) 6.00 6.00 6.00 6.00 6.00 6.00
[0715] Tinosorb S (Bis- Ethylhexyloxyphenol 7.00 7.00 7.00 7.00 7.00 7.00 Methoxyphenyl Triazine)
[0716] Ethylhexyl Salicylate 5.00 5.00 5.00 5.00 5.00 5.00 Ethylhexyl Methoxycinnamate 8.00 8.00 8.00 8.00 8.00 8.00 Parsol TX (Titanium Dioxide (and)
[0717] 6.00 6.00 6.00 6.00 6.00 6.00 Silica (and) Dimethicone)
[0718]
[0719] 202400047 Foreign Filing 35
[0720] Verstatil® BOB (Benzyl Alcohol; 1.00 1.00 1.00 1.00 1.00 1.00 Caprylyl Glycol; Benzoic Acid)
[0721] B Water (Aqua) add add
[0722] add to add to add to add to to to
[0723] 100 100 100 100 100 100
[0724] Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 Zinc Sulfate Hepta hydrate 1.00 1.00 1.00 1.00 1.00 1.00 Z Perfume q.s. q.s. q.s. q.s. q.s. q.s.
[0725]
[0726] All Day Sun Protection Lotion SPF 30
[0727] Phase Ingredient w / w% w / w% w / w% w / w% A TEGO® Care PBS 6 MB (Polyglyceryl-6
[0728] Stearate (and) Polyglyceryl-6 Behenate)
[0729] 3.00 3.00 3.00 3.00
[0730] TEGIN® M Pellets MB (Glyceryl Stearate)
[0731] 0.50 0.50 0.50 0.50 TEGO® Alkanol 1618 MB (Cetearyl Alcohol)
[0732] 0.50 0.50 0.50 0.50 TEGO® FILMSTAR One MB (Polyglyceryl-3
[0733] Stearate / Sebacate Crosspolymer) 1.50 1.50 1.50
[0734] dermofeel® sensolv MB (Isoamyl Laurate)
[0735] 5.50 0.50 5.50 5.50 TEGOSOFT® LO MB (Lauryl Oleate)
[0736] 2.50 2.50 2.50 2.50 TEGOSOFT XC MB
[0737] 2.50
[0738] Butylenglycol Dicaprylate / Caprate
[0739] 3.00 3.00 Example X
[0740] 5.00 5.00 2.00 2.00 Tinosorb S (Bis-Ethylhexyloxyphenol
[0741] Methoxyphenyl Triazine)
[0742] 4.00 4.00 4.00 4.00
[0743]
[0744] 202400047 Foreign Filing 36
[0745] Diethylamino Hydroxybenzoyl Hexyl Benzoate
[0746] 4.00 4.00 4.00 4.00
[0747] Ethylhexyl Salicylate 1.50 1.50 1.50 1.50 Ethylhexyl Triazone
[0748] 1.00 1.00 1.00 1.00 Eusolex T-S (Titanium Dioxide; Alumina;
[0749] Stearic Acid) 2.00 2.00 2.00 2.00
[0750] dermofeel® Toco 70 non GMO (Tocopherol;
[0751] Helianthus Annuus (Sunflower) Seed Oil)
[0752] 0.20 0.20 0.20 0.20
[0753] B Water (Aqua) add to add to add to add to 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 Disodium EDTA 0.05 0.05 0.05 0.05 C Keltrol CG-SFT (Xanthan Gum) 0.50 0.50 0.50 0.50 D Water (Aqua) 3.56 3.56 3.56 3.56 Phenylbenzimidazole Sulfonic Acid
[0754] 1.00 1.00 1.00 1.00 Tromethamine 0.44 0.44 0.44 0.44 E Verstatil® BOB (Benzyl Alcohol; Caprylyl
[0755] 1.20 1.20 1.20 1.20 Glycol; Benzoic Acid)
[0756]
[0757] High spreading Body spray
[0758] Phase Ingredients w / w% w / w% w / w% w / w% w / w% w / w% A dermofeel® easymuls plus
[0759] 3.00 3.00 3.00 3.00 3.00 3.00 (Glyceryl Oleate Citrate)
[0760] TEGOSOFT® LO MB (Lauryl
[0761] 12.00 12.00 6.00 1.00 1.00 Oleate)
[0762] dermofeel® sensolv MB
[0763] 6.00 6.00 Example X
[0764] 12.00 12.00 5.00 12.00 8.00 6.00 B Water (Aqua) add to add to add to add to add to add to 100 100 100 100 100 100
[0765]
[0766] 202400047 Foreign Filing 37
[0767] dermosoft® Pentiol eco
[0768] 3.00 3.00 3.00 3.00 3.00 3.00 (Pentylene Glycol)
[0769] Kelcogel CG-HA(Gellan Gum) 0.10 0.10 0.10 0.10 0.10 Genuvisco Carrageenan CG- 0.10 0.10
[0770] 131 (Carrageenan)
[0771] c dermosoft® OMP
[0772] (Methylpropanediol, Caprylyl 2.50 2.50 2.50 2.50 2.50 2.50 Glycol, Phenylpropanol)
[0773] D Sodium Hydroxide, 10% sol. in
[0774] q.s. q.s. q.s. q.s. q.s. q.s. water
[0775]
[0776] Hydration & Wrinkle reduction O / W sunscreen
[0777] Phase Ingredients w / w- w / w- w / w- w / w- w / w- w / w- % % % % % % A TEGO® Care PBS 6 MB (Polyglyceryl- 6 Stearate (and) Polyglyceryl-6 4.00 4.00 4.00 4.00 4.00 4.00 Behenate)
[0778] ABIL® Care XL 80 MB (Bis-PEG / PPG- 20 / 5 PEG / PPG-20 / 5 Dimethicone;
[0779] 0.67 0.67 0.67
[0780] Methoxy PEG / PPG-25 / 4 Dimethicone;
[0781] Caprylic / Capric Triglyceride)
[0782] TEGO® SP 13 Sun Up MB (Poly C10- 1.50 1.50 1.50 1.50 1.50 1.50 30 Alkyl Acrylate)
[0783] TEGIN® M Pellets MB (Glyceryl
[0784] 0.20 0.20 0.20 0.20 0.20 0.20 Stearate)
[0785] TEGO® Alkanol 1618 MB (Cetearyl
[0786] 0.20 0.20 0.20 0.20 0.20 0.20 Alcohol)
[0787] TEGOSOFT® DEC (Diethylhexyl
[0788] 7.00 5.00 1.00 2.00 3.00 2.00 Carbonate)
[0789] TEGOSOFT® XC (Phenoxyethyl
[0790] 1.00 0.50 5.00 2.00 Caprylate)
[0791] dermofeel® sensolv MB (Isoamyl
[0792] 2.00 0.70 2.00 Laurate)
[0793] Example X 3.00 3.00 7.00 5.00 1.00 3.00 TEGO® FILMSTAR One MB
[0794] (Polyglyceryl-3 Stearate / Sebacate
[0795] 0.5
[0796] Crosspolymer)
[0797]
[0798] 202400047 Foreign Filing 38
[0799] INQP70TMD (Titanium Dioxide;
[0800] Isononyl Isononanoate;
[0801] 16.4 16.4 16.4 16.4 16.4 16.4 Polyhydroxystearic Acid; Hydrogen
[0802] Dimethicone; Dimethicone)
[0803] GCP55ZSG (Zinc Oxide;
[0804] Caprylic / Capric Triglyceride;
[0805] 24.3 24.3 24.3 24.3 24.3 24.3 Polyhydroxystearic Acid; Stearoyl
[0806] Glutamic Acid)
[0807] B Water (Aqua) add add add add add add to to to to to to 100 100 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 3.00 3.00 HyaCare® 50(Hydrolyzed Hyaluronic
[0808] 0.10 0.10 0.10
[0809] Acid)
[0810] HyaCare® (Sodium Hyaluronate) 0.10 0.10 0.10
[0811] TEGO® Pep UP (Tetrapeptide-4,
[0812] 1.00 1.00 1.00
[0813] Glycerin, Water)
[0814] Xanthan Gum 0.50 0.50 0.50 0.2 0.50 Genuvisco Carrageenan CG-131
[0815] 0.5 0.2 (Carrageenan)
[0816] C dermosoft® OMP (Methylpropanediol,
[0817] Caprylyl Glycol, Phenylpropanol) 2.50 2.50 2.50 2.50 2.50 2.50
[0818]
[0819] W / O make-up Foundation
[0820] Phase Ingredients w / w% w / w% w / w% w / w% w / w% w / w% A ISOLAN® GPS (Polyglyceryl-4
[0821] Diisostearate / Polyhydroxy- 4.00 2.00 4.00 4.00 4.00 stearate / Sebacate)
[0822] KF-6038 (Lauryl PEG-9
[0823] Polydimethylsiloxyethyl 4.00 2.00
[0824] Dimethicone)
[0825] Cutina HR 0.50 0.50 0.50 0.50 0.50 0.50 TEGO® FILMSTAR One MB
[0826] (Polyglyceryl-3 Stearate / Sebacate 1.00 1.00 1.00 1.00 1.00 1.00 Crosspolymer)
[0827] TEGOSOFT® DC MB (Decyl
[0828] 9.00 18.00 18.00 18.00 18.00 6.00 Cocoate)
[0829]
[0830] 202400047 Foreign Filing 39
[0831] Example X 9.00 1.00 5.00 1.00 5.00 12.00 TEGOSOFT® AC MB (Isoamyl
[0832] 5.00 4.00 4.00 4.00 3.00 5.00 Cocoate)
[0833] TEGOSOFT® LO MB (Lauryl
[0834] 1.00 1.00 1.00 2.00 oleate)
[0835] Safflower Oil, pressed, organic 5.00 2.50 5.00 (Carthamus Tinctorius Seed Oil)
[0836] ECOHANCE® Soft Baobab
[0837] 7.00 7.00 7.00 2.50 (Adansonia Digitata Seed Oil)
[0838] AEROSIL 200 VV / EA-PH 0.30 0.30 0.30 0.30 0.30 0.30 Phytosphingosine
[0839] 0.10 0.10 0.10 0.10 0.10 0.10 (Phytosphingosine)
[0840] dermofeel® TocoBalance
[0841] (Tocopherol; Helianthus Annuus 0.10 0.10 0.10 0.10 0.10 0.10 (Sunflower) Seed Oil)
[0842] Unipure White LC 987 BA (Cl
[0843] 77891 , Persea Gratissima Oil,
[0844] 5.00 5.00 5.00 5.00 5.00 5.00 Hydrogenated Vegetable Oil,
[0845] Tocopherol)
[0846] Unipure Yellow LC 182 BA (Cl
[0847] 77492, Persea Gratissima Oil,
[0848] 1.20 1.20 1.20 1.20 1.20 1.20 Hydrogenated Vegetable Oil,
[0849] Tocopherol)
[0850] Unipure Red LC 381 BA (Cl
[0851] 77491 , Persea Gratissima Oil,
[0852] 0.20 0.20 0.20 0.20 0.20 0.20 Hydrogenated Vegetable Oil, Cl
[0853] 77499, Tocopherol)
[0854] Unipure Black LC 989 BA (Cl
[0855] 77499, Persea Gratissima Oil,
[0856] 0.1 0.1 0.1 0.1 0.1 0.1 Hydrogenated Vegetable Oil,
[0857] Tocopherol)
[0858] Eusolex T-S (Titanium Dioxide;
[0859] 3.00 3.00 3.00 3.00 3.00 3.00 Alumina; Stearic Acid)
[0860] Zano M (Zinc Oxide) 6.00 6.00 6.00 6.00 6.00 6.00 B Water (Aqua) add to add to add to add to add to add to 100 100 100 100 100 100 Glycerin 5.00 5.00 5.00 5.00 5.00 5.00
[0861]
[0862] 202400047 Foreign Filing 40
[0863] TEGO® Natural Betaine (Betaine) 1.00 1.00 1.00 1.00 1.00 1.00 RonaCare Zinc Sulfate(Zinc
[0864] Sulfate) 1.50 1.50 1.50 1.50 1.50 1.50
[0865] c dermosoft® 250 eco
[0866] 0.30 0.30 0.30 0.30 0.30 0.30 (Phenylpropanol)
[0867] Perfume q.s. q.s. q.s. q.s. q.s. q.s.
[0868]
[0869] Daily wear cationic lotion with UV protection
[0870] Phase Ingredients w / w% w / w% w / w% w / w% A TEGO® Care Eco CAT MB (Distearoylisopropyl
[0871] 5.00 5.00 5.00 5.00 Dimonium Methosulfate)
[0872] TEGIN® M Pellets MB (Glyceryl Stearate) 0.30 0.30 0.30 0.30 TEGO® Alkanol 1618 MB (Cetearyl Alcohol) 5.40 5.40 5.40 5.40 TEGOSOFT® TN (C12-15 Alkyl Benzoate) 4.00 4.00 3.00 TEGOSOFT® DEC (Diethylhexyl Carbonate) 3.00 3.00 3.00 TEGOSOFT® CR MB (Cetyl Ricinoleate) 1.00 1.00 1.00 Example X 8.00 5.00 8.00 5.00 TEGO® FILMSTAR One MB (Polyglyceryl-3
[0873] 1.50 Stearate / Sebacate Crosspolymer)
[0874] Triisostearin 1.00 1.00 1.00 1.00 Butyl Methoxydibenzoylmethane 3.00 3.00 3.00 3.00 Ethylhexyl Salicylate 4.00 4.00 4.00 4.00 Octocrylene 7.00 7.00 7.00 7.00 B Water (Aqua) ad to ad to ad to ad to 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 Tromethamine 0.30 0.30 0.30 0.30 TEGO® Cosmo C 100(Creatine) 0.50 0.50 0.50 0.50 Z Verstatil® TBO (Triethyl Citrate; Caprylyl Glycol;
[0875] 1.00 1.00 1.00 1.00 Benzoic Acid)
[0876]
[0877] Daily Facial Cream, SPF 25
[0878] Phase Ingredients w / w% w / w% w / w% w / w%
[0879]
[0880] 202400047 Foreign Filing 41
[0881] Carbomer (Carbomer Homopolymer C) 0.15 0.15 0.15 AXOL® C 62 Pellets MB (Glyceryl Stearate
[0882] 2.50 2.50 2.50 2.50 Citrate)
[0883] TEGO® Alkanol 1618 MB (Cetearyl Alcohol) 0.80 0.80 0.80 0.80 TEGIN® M Pellets MB (Glyceryl Stearate) 2.00 2.00 2.00 2.00 TEGOSOFT® DEC (Diethylhexyl Carbonate) 4.00 4.00 4.00 TEGOSOFT® XC MB (Phenoxyethyl
[0884] 5.00 5.00 5.00 3.00 Caprylate)
[0885] TEGOSOFT® CR MB (Cetyl Ricinoleate) 0.80 0.80 0.80 0.80 Example X 4.00 4.00 8.00 8.00 TEGO® FILMSTAR One MB (Polyglyceryl-3
[0886] 1.50 Stearate / Sebacate Crosspolymer)
[0887] Xanthan Gum 0.30 0.30 0.30 0.30 Tocopheryl Acetate 0.50 0.50 0.50 0.50 Butyl Methoxydibenzoylmethane 5.00 5.00 5.00 5.00 Homosalate 5.00 5.00 5.00 5.00 Octocrylene 6.00 6.00 6.00 6.00 Ethylhexyl Triazone 4.00 4.00 4.00 4.00 B Water (Aqua) add to add to add to add to 100 100 100 100 Glycerin 3.00 3.00 3.00 3.00 Nylon-12 3.00 3.00 3.00 3.00 Cyclomethicone (and) Dimethicone
[0888] 2.00 2.00 2.00 2.00 Crosspolymer
[0889] Sodium Hydroxide, 10% sol. in water q.s. q.s. q.s. q.s. Preservative, Perfume q.s. q.s. q.s. q.s.
[0890]
[0891] Hydrating Foot Care Cream
[0892] Phase Ingredients w / w% w / w% w / w% ISOLAN® PDI (Diisostearoyl Polyglyceryl-3 Dimer
[0893] A 3.50 3.50 3.50 Dilinoleate)
[0894] dermofeel® viscolid MB (Hydrogenated Palm Oil;
[0895] 1.00 1.00 1.00 Hydrogenated Rapeseed Oil)
[0896]
[0897] 202400047 Foreign Filing 42
[0898] Cera Alba 1.00 1.00 1.00 Hydrogenated Castor Oil 1.00 1.00 1.00 Butyrospermum Parkii (Shea) Butter 1.00 1.00 1.00 TEGOSOFT® LO MB (Lauryl Oleate) 10.00 10.00 TEGOSOFT® DC MB (Decyl Cocoate) 6.00 3.00 6.00 Example X 2.00 4.00 12.00 Prunus Amygdalus Dulcis (Sweet Almond) Oil 6.00 6.00 6.00 Zinc Stearate 1.00 1.00 1.00 Triacetin (Glyceryl Triacetate) 0.50 0.50 0.50 dermofeel® Toco 70 non GMO (Tocopherol; Helianthus
[0899] 0.20 0.20 0.20 Annuus (Sunflower) Seed Oil)
[0900] Water (Aqua) add to add to add to B
[0901] 100 100 100 Glycerin 5.00 5.00 5.00 Butylene Glycol 3.00 3.00 3.00 Sodium Chloride 2.00 2.00 2.00 Verstatil® SL non GMO (Aqua; Sodium Levulinate;
[0902] 1.50 1.50 1.50 Potassium Sorbate)
[0903] Panthenol 0.50 0.50 0.50 dermosoft® 250 eco (Phenylpropanol) 0.05 0.05 0.05 C Urea 5.00 5.00 5.00 Water (Aqua) 5.00 5.00 5.00
[0904]
[0905] 202400047 Foreign Filing 43
[0906] Water free Oil for Sun Care, SPF 50
[0907] Phas w / w w / w w / w w / w w / w w / w w / w w / w w / w Ingredient
[0908] e % % % % % % % % % Diethylhexyl Butamido
[0909] 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 A Triazone
[0910] Ethylhexyl Salicylate 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Ethylhexyl Triazone 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 Butyl
[0911] Methoxydibenzoylmetha 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 ne
[0912] Diethylamino
[0913] Hydroxybenzoyl Hexyl 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 Benzoate
[0914] Bis-Ethylhexyloxyphenol
[0915] Methoxyphenyl 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 8.00 Trianzone
[0916] TEGOSOFT® DC MB 13.7 23.7 18.7 24.5
[0917] - - - B (Decyl Cocoate) 0 0 0 0
[0918] TEGOSOFT® XC
[0919] 30.0 30.0 30.0 30.0 30.0 17.0 17.0 17.0 12.0 (Phenoxyethyl
[0920] 0 0 0 0 0 0 0 0 0 Caprylate)
[0921] ECOHANCE® Soft
[0922] 10.0
[0923] Baobab (Adansonia - 5.00 - - - - 0
[0924] Digitata Seed Oil)
[0925] TEGOSOFT® DEC 10.0 55.0 14.0 15.0 15.0 15.0 15.0 15.0
[0926] 4.50
[0927] (Diethylhexyl Carbonate) 0 0 0 0 0 0 0 0
[0928] 10.0 24.5 19.0 37.5 15.0 15.0 Example X 5.00 0.50 1.00
[0929] 0 0 0 0 0 0 TEGOSOFT® TN(C12- 18.5 15.0 15.0
[0930] - - - - - - 15 Alkyl Benzoate) 0 0 0 TEGOSOFT® CT
[0931] (Caprylic / Capric 7.50 7.50 Triglyceride)
[0932] 10.0
[0933] Ethanol 5.00
[0934] 0
[0935] dermofeel® E 74 A non
[0936] GMO (Tocopheryl 0.50 0.50 0.50 - - - - - - C Acetate, Helianthus
[0937]
[0938] 202400047 Foreign Filing 44
[0939] Annuus (Sunflower)
[0940] Seed Oil)
[0941] dermofeel® Toco 70 non
[0942] GMO
[0943] (Tocopherol; Helianthus 0.30 0.30 0.30 - - - - - - Annuus (Sunflower)
[0944] Seed Oil)
[0945]
[0946] Perfume (Eau de Parfum, Eau de Toilette, Eau de Cologne)
[0947] Phase Ingredient w / w- w / w- w / w- w / w- w / w- % % % % % A Ethanol 80.0 85.0 85.0 95.0 97.5 Example X 5.0 2.5 10.0 1.5 0.5 Fragrance q.s. q.s q.s. q.s q.s
[0948]
Claims
202400047 Foreign Filing 45Claims1. Emulsifying composition comprisingone or more emulsifying agents EA andone or more diesters DODwherein R1and R2are independently selected from linear or branched, saturated or unsaturated C2-C36-alkyl groups, andwherein the mass ratio m(emulsifying agent EA) / m(diester D) is in the range between Xm1 to Xm2, withXm1 = 1 / 50, andXm2 = 5, andwherein emulsifying agent EA is selected from the group of anionic emulsifiers, cationic emulsifiers, amphoteric emulsifiers and non-ionic emulsifiers.
2. Emulsifying composition according to claiml ,wherein emulsifying agent EA is selected from the group of anionic emulsifiers and non-ionic emulsifiers.
3. Emulsifying composition according to claiml ,wherein emulsifying agent EA is selected from the group of silicone surfactants, fatty acids and their salts, ethoxylated fatty alcohols, hydrogenated ethoxylated castor oils, alkyl polyglycosides, orthophosphoric acid esters, partial esters of fatty acids with polyols and their ethoxylates.
4. Emulsifying composition according to any one of claims 1 and 3,wherein emulsifying agent EA is selected from either partial esters of fatty acids with at least one selected from glycerol, polyglycerol, sorbitan and sorbitol or ethoxylates of partial esters of fatty acids with at least one selected from glycerol, polyglycerol, sorbitan and sorbitol, and mixtures thereof.
5. Emulsifying composition according to any one of claims 1 , 3 and 4,wherein emulsifying agent EA is a partial ester of a fatty acid with polyglycerol.202400047 Foreign Filing 466. Emulsifying composition according to claim 5,wherein emulsifying agent EA is a partial ester of fatty acids with 6 to 36 carbon atoms with polyglycerol,wherein emulsifying agent EA has a saponification number of 30 to 300 mg KOH / g and wherein the saponification number is determined according to Ph. Eur. 2.5.6.
7. Emulsifying composition according to any one of claims 1 to 6,wherein R1and R2are independently selected from linear or branched, saturated or unsaturated C2-C22-alkyl groups.
8. Emulsifying composition according to any one of claims 1 to 7,wherein R1and R2are independently selected from linear or branched, saturated or unsaturated C2-Cia-alkyl groups.
9. Emulsifying composition according to any one of claims 1 to 6,wherein R1and R2are independently selected from ethyl, propyl, isopropyl, butyl, 2-methyl- propyl, 2-butyl, pentyl, pentan-2-yl, pentan-3-yl, 2-methyl-butyl, 3-methyl-butyl, 3-methyl- butan-2-yl, 2,2-dimethyl-propyl, hexyl, 2-methyl-pentyl, 4-methyl-pentyl, 4-methyl-pentan-2- yl, 2-ethyl-butyl, heptyl, heptan-2-yl, heptan-3-yl, heptan-4-yl, 2,4-dimethyl-pentan-3-yl, octyl, octan-2-yl, 2-ethyl-hexyl, 2,3-dimethyl-hexyl, 2,2,4-trimethyl-pentyl, nonyl, nonan-5-yl, 3,5- dimethyl-heptan-4-yl, 2,6,-dimethyl-heptan-4-yl, 3,5,5-trimethyl-hexyl, decyl, undecyl, undecan-6-yl, dodecyl, 2,6,8-trimethyl-nonan-4-yl, tridecyl, tetradecyl, pentadecyl, hexadecyl, Z-9-hexadecen-1-yl, heptadecyl, octadecyl, isostearyl, oleyl, elaidyl, linoleyl, y-linolenyl, nonadecyl, icosanyl, docosanyl, tetracosanyl, hexacosanyl, octacosanyl, triacontanyl.
10. Emulsifying composition according to any one of claims 1 to 9,wherein the mass ratio m(emulsifying agent EA) / m(diester D) is in the range between Xm1 to Xm2, withXm1 = 1 / 10, and Xm2 = 1 / 2.
11. Emulsifying composition according to any one of claims 1 to 9, further comprising at least one preservative selected from tocopherol, triethyl citrate, glyceryl caprylate, benzoic acid, sodium levulinate, potassium sorbate, phenoxyethanol, methylpropanediol, caprylyl glycol, phenylpropanol, ethylhexylglycerin, benzyl alcohol.
12. Emulsifying composition according to any one of claims 1 to 10, further comprising at least one humectant selected from glycerol, 1 ,2-propylene glycol, 1 ,3-propanediol, diglycerol, dipropylene glycol, xylitol, sorbitol, maltitol, 1,2-butylene glycol, 1,3-butylene glycol, 1,2- pentylene glycol, 1,2-hexylene glycol, lactic acid, creatine, urea.202400047 Foreign Filing 4713. Emulsion comprisingan aqueous phase, anda dispersed phase comprising at least one liposoluble compound with a logP value greater than 0, preferably and lower than or equal to 15,the emulsion further comprising an emulsifying composition according to any one of claims 1 to 11.
14. Use of an emulsifying composition according to any one of claims 1 to 11 for emulsifying a liposoluble compound with a logP value greater than 0, preferably and lower than or equal to 15.